Manganese deposits in northeastern European Russia and the Urals: Isotope geochemistry,genesis, and evolution of ore formation

Based on new data on the lithology, mineralogy, chemistry, and isotopic composition of manganese carbonate ores and rocks at the deposits and occurrences in the Novaya Zemlya Archipelago, the Pai-Khoi, and the Urals, as well as using data from the literature, the main Phanerozoic basins of manganese deposition have been established in the geological history of Laurasia, Pangea, and Siberian paleocontinents. The formation conditions of manganese ore gradually changed from hydrothermal-sedimentary in the Middle Paleozoic to sedimentary-diagenetic in Mesozoic and Cenozoic. The ore was also formed under catagenetic conditions. Carbon of oxidized organic matter plays a substantial role in the formation of manganese carbonates.     

The problem of rock assimilation by Somma-Vesuvius magma

Mineralogical and chemical compositions of ejected carbonate inclusions of Vesuvian gaseous phase are compared with those of carbonate sediments of the Somma-Vesuvius area. The basement of Vesuvius mainly consists of Mesozoic limestones. Most of these are characterized by extremely low insoluble residues. In this area thick dolomite beds occur in the Triassic system only. A calcareous layer of approximately 100 to 150 meters thickness characterized by high Sr contents (0.19% Sr in the average) is to be found within the Triassic dolostones. Several carbonate ejecta also show high Sr contents (0.1% Sr) but chemical composition of some of these ejecta differs somewhat from that of the Triassic layer high in Sr. Contact with the volcanic volatile phase and melt has produced some alterations in the composition of many ejecta. Magnesian calcites are abundant and periclase, brucite, tremolite, phlogopite and magnesite were found in the ejecta examined. Silicon, manganese, iron, zinc and, to a smaller extent, potassium and copper have been most probably transported from the volcanic gas phase into ejected carbonate inclusions. Owing to metasomatic actions of the volcanic volatile components, rearrangement and alteration of Ca and Mg contents occurred in the carbonate minerals of several ejecta. Under the influence of volcanic pressure and temperature, magnesium content originally in dolomite might be transformed into the calcite structure. \(\frac{{{\text{MgO}}}}{{{\text{CaO + MgO}}}}\) molar ratios of several carbonate ejecta do not correspond with those found in sedimentary limestones and dolostones. It cannot be proved whether the Mg of the mixed calcite-dolomite ejecta has been partially introduced from the volatiles or lost from the carbonate phases.     

Immiscible silicate-carbonate liquids as evidenced from ocellar diabase dykes,southeast Sinai

Diabase dykes containing spherical patches of carbonate intrude the Tarr albitite complex of SE Sinai. The morphology of these dykes indicates a highly gas-charged magma. Petrographic evidence points toward equilibrium during cooling of immiscible carbonate ocelli and silicate matrix. Dolomite is the main component of these ocelli, which are geochemically and isotopically similar to carbonatite. However, the low total REE content, and the presence of considerable marble in the country rock, suggest a process of stoping and melting of carbonate, followed by the “in situ” development of silicate-carbonate immiscibility.     

Carbonatite nomenclature

Based upon the composition of carbonatites of the Fen Complex in Norway and the Alnö Complex in Sweden, the following nomenclature of carbonatitic rocks is suggested: Carbonatites (> 70 % carbonate minerals), sub-divided into the calcitic sövites and alvikites, the dolomitic to ankeritic rauhaugites and beforsites and the alkali-carbonatitic lengaite. Silico-carbonatites are rocks with 50–70 % carbonate minerals. They are subdivided into silico-sövites, silico-alvikites, silico-rauhaugite and silico-beforsite.     

Grenville tectonic events and evolution of the Yenisei Ridge at the western margin of the Siberian Craton

Geological, petrologic, geochemical, and isotopic geochronological evidence for Grenville events at the western margin of the Siberian Craton are considered. These events were related to assembly of the Rodinia supercontinent. Multiple manifestations of riftogenic and within-plate magmatism at the final stage of orogenic evolution gave rise to breakdown of Rodinia and the formation of the Paleoasian ocean. The results allowed us to develop a new concept on the Precambrian geological evolution of the Yenisei Ridge and the processes that created its tectonic structure. The chronological sequence of events in the history of the Transangarian Yenisei Ridge is based on geological evidence and isotopic dating of Precambrian complexes variable in geodynamic nature. Four tectonic stages dated at 1.4?1.1, 1.1?0.9, 0.90?0.85, and 0.8?0.6 Ga were controlled by collision and extension recognized from large regional linear crustal structural elements. The evolution of the Transangarian Yenisei Ridge, which lasted for ～650 Ma, corresponds in duration to supercontinental cycles that begin from rifting and breakdown of the predated supercontinent and was completed by orogeny and the formation of a new supercontinent. The regional geodynamic history correlates with the synchronous sequence and similar style of tectonothermal events at the periphery of the large Precambrian Laurentia and Baltica cratons. This is evidenced by paleocontinental reconstructions, which confirm close spatiotemporal links of Siberia with cratons in the northern Atlantic 1400?600 Ma ago and indicate incorporation of the Siberian Craton into the ancient Nuna and Rodinia supercontinents.     

Stratabound ore deposits related to synsedimentary tectonics: South-West Sardinia (Italy) and Sierra de Aracena (Spain); a comparison

Deposition of stratabound Zn-Pb-Ba ores in the Lower Cambrian carbonates in South-west Sardinia show a distinct relation with the prominent tensional tectonics in the area. A part of the mineral deposits are syngenetic (sedimentary-exhalative), other massive sulfides and/or barite are early diagenetic. Other occurrences (MVT) are from early to late-diagenetic. They are mostly confined to matrix- and cementbreccias which might be dependent on the Cambrian tectonics. The Precambrian-Lower Cambrian (?) carbonates occupying the core of the Aracena anticline, at the boundary between the provinces of Huelva and Badajoz (South-west Spain), are also an important metallotect for Zn-Pb-Ag-Ba mineralization. The ores at Aracena are stratabound (to stratiform) (Sedex) and occur as disseminations or layers in a volcano-sedimentary sequence with carbonate intercalations. Both the carbonate intervals and the ores show evidence of synsedimentary tectonics, like slumpings, slump breccias and neptunian dykes. Their deposition most likely occurred in a subtidal environment controlled by faults. Apparently, in South-west Sardinia and in the Sierra de Aracena, both sedimentary evolution and ore deposition were strictly related, and conditioned by several pulses of tensional tectonics.     

The assessment of submarine slope instability in Baiyun Sag using gray clustering method

It is a significant task to evaluate the seafloor stability for the exploitation of marine resources and the construction of marine structures. This paper analyzes the impact factors of submarine slope instability using geological and geophysical data of the Baiyun Sag in the Pearl River Mouth Basin and builds the evaluation index system of submarine slope instability. The weight of each index is calculated by analytic hierarchy process method to weaken subjective effect. Gray clustering method is applied to estimate the risk of submarine slope instability in Baiyun Sag qualitatively and quantitatively. The assessment standard is divided into five grades, and the whitening function of each gray cluster is determined by the assessment scheme. The gray evaluation weight vector of each indicator is calculated by the table-dispatching method. The gray assessment value is estimated by making the gray assessment weight vector single value, and the gray grade is determined according to the maximum principle. The evaluation results show quantitatively that the risk grade of submarine slope instability in the Baiyun Sag is medium, and the gray clustering method is reasonable and feasible.     

Structure and genesis of the Cubango Megafan in northern Namibia: implications for its hydrogeology

An exploration strategy for groundwater was established and followed in the northern Namibian Cuvelai-Etosha Basin (CEB). The data derived from transient electromagnetics, rotary-drilling, coring and sample investigation were used to refine stratigraphy and hydrostratigraphy, and to develop a 3D map of aquifers within the Cubango Megafan. The results have delineated three major aquifers. The newly found, deep-seated Ohangwena II Aquifer (KOH-2) has the potential of providing significant additional water to the water supply of northern Namibia and Angola. While near-surface aquifers carry predominantly brackish water, freshwater in the deep-seated aquifer is further extended and features good hydraulic properties. To date, only a small part of the hydrogeological potential of arid CEB has been explored and an extension of exploration is needed, including southern Angola. The combination of structural, sedimentological and hydrogeological approaches greatly advanced both the geological and hydrogeological understanding. With regard to the deep-seated aquifer, strict measures need to be applied to ensure that the water in the KOH-2 reservoir is exploited sustainably. Water control areas need to be established to ensure long-term preservation of this newly explored aquifer.     

A MEG study of the olivine and spinel forms of Mg2SiO4

In this paper we present a theoretical investigation of the structures and relative stability of the olivine and spinel phases of Mg₂SiO₄. We use both a purely ionic model, based on the Modified Electron Gas (MEG) model of intermolecular forces, and a bond polarization model, developed for low pressure silica phases, to investigate the role of covalency in these compounds. The standard MEG ionic model gives adequate structural results for the two phases but incorrectly predicts the spinel phase to be more stable at zero pressure. This is mainly because the ionic modeling of Mg₂SiO₄ only accounts for 95 percent of the lattice energy. The remainder can be attributed to covalency and many-body effects. An extension of the MEG ionic model using “many-body” pair potentials corrects the phase stability error, but predicts structures which are in poorer agreement with experiment than the standard ionic approach. In addition, calculations using these many-body pair potentials can only account for 10 percent of the missing lattice energy. This model predicts an olivine-spinel phase transition of 8 GPa, below the experimental value of 20 GPa. Therefore, in order to understand more fully the stability of these structures we must consider polarization. A two-shell bond polarization model enhances the stability of both structures, with the olivine structure being stabilized more. This model predicts a phase transition at about 80 GPa, well above the observed value. Also, the olivine and spinel structures calculated with this approach are in poorer agreement with experiment than the ionic model. Therefore, based on our investigations, to properly model covalency in Mg₂SiO₄, a treatment more sophisticated than the two-shell model is needed.     

Modeling and mapping of water erosion in northeastern Algeria using a seasonal multicriteria approach

Aurès region remains one of the most exposed areas to water erosion phenomenon in Algeria, because of the strong climatic aggressiveness, the rugged relief, the predominance of sensitive land, and a vegetative cover that does not play its protective role. This article is a part of studies performed to protect agricultural and water infrastructure in this region. The main objective of this study is the cartographic modeling of an erosion hazard at the Oued Chemoura watershed, representative of the Aurès. The modeling approach uses a geographic information system and incorporates the following six factors controlling erosion: slope, friability of substrate, erodibility of soils, land cover, rainfall erosivity, and support practices. Result shows a synthetic map of the soil erosion hazard which locates the most threatened areas and priorities for possible planning interventions. A statistical study on the relationship solid–liquid flow was developed. Measurements conducted at the station of Chemoura, over the period 1969–1994, were exploited for this purpose. The results show a high specific degradation varying between 50 and 360 tons km^?2 season^?1.     

A microseismic experiment in Abu Dhabi,United Arab Emirates: implications for carbonate reservoir monitoring

A microseismic experiment utilizing a single downhole array of eight 3-component receivers was conducted in an offshore oilfield in the emirate of Abu Dhabi in the United Arab Emirates. The Lower Cretaceous Thamama Group is the major carbonate reservoir in the field producing from six zones. Microseismic data was acquired in conjunction with gas injections that took place in the Thamama IV A and IV B reservoirs during 9 days of acquisition. The aim of the experiment was to monitor the microseismic activity arising in the carbonate reservoirs as a result of gas injection. A total of 103 microseismic events were detected from two of the receivers. For the majority of these events, there were no well-defined P wave arrivals, probably due to the presence of strong background noise and the very weak microseismic signals. The results from this experiment indicate that the detected events are probably related to the microseismic activities caused by the gas injection within the Thamama IV B reservoir. Therefore, downhole microseismic monitoring methods can potentially provide valuable information about the fracture systems within the carbonate reservoirs of Abu Dhabi's oilfields.     

Mapping groundwater conditions in different geological environments in the northern area of UAE using 2D earth resistivity imaging survey

A water resources database was developed and used to characterize the geological and hydrogeological settings of groundwater aquifers in the northern part of the United Arab Emirates. An intensive 2D Earth Resistivity Imaging (ERI) survey was conducted in selected areas to assess the available groundwater resources and delineate the salt-water intrusion. Drilling information of the existing monitoring wells as well as their records of water table elevations and groundwater salinity were used to measure the horizontal and vertical variations in lithology, degree of saturation, and groundwater salinity and thus to improve the interpretation of ERI data. The results of the chemical analyses of water samples collected from the wells along with the 2D ERI survey profiles were used to obtain an empirical relationship between the inferred earth resistivity and the amount of total dissolved solids. This relationship was used along with the true resistivity sections resulting from the inversion of 2D ERI data to identify and map three zones of water-bearing formation (fresh, brackish, and salt-water zones) in the coastal areas. The results indicated that the depth to the fresh-brackish interface exceeded 50 m at the upstream of the wadies and was in the order of 10 m or less in the vicinity of shoreline. Because of the high resistivity contrast between dry and water saturated fractured rocks; this method was very successful in detecting water-filled fractures and cavities in the carbonate aquifer. The application of this method was unsuccessful in clayey aquifers as it was not possible to isolate lenses of gravel and/or saturated with saline or brackish water from the surrounding clayey materials.     

Spectral delineation of albite zone using ASTER data in Khetri Copper Belt

The Khetri Copper Belt is well known because of its economically viable Cu deposits. In this region, there is a linear narrow zone following a major crustal fracture. Along this zone, due to hydrothermal activity and subsequent alteration, a new rock, albitite has formed. The study presents an account of the spectral analysis of Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) dataset for albitite mapping in the Khetri Copper Belt. Spectral angle mapper algorithm is applied on the ASTER data taking the ground sample reflectance spectra (VNIR–SWIR) and image derived spectra (TIR) as reference spectra. The albitite-classified areas are analyzed spatially and statistically to determine the extent of albitite zone in the study area. This research is to contribute to the better understanding of the spatial extent of the albitite zone which will assist in determining the potential for the mineralization in the area. The remote sensing approach of utilizing multichannel data offers the capability to resolve the key geological features of this geologically dynamic area.     

Experimental modeling of the interaction of subducted carbonates and sulfur with mantle silicates

Experimental studies in the system Fe,Ni–olivine–carbonate–S (P = 6.3 GPa, T = 1050–1550°C, t = 40–60 h) aimed at modeling of the interaction of subducted carbonates and sulfur with rocks of the silicate mantle and at investigation of the likely mechanism of the formation of mantle sulfides were performed. It is shown that an association of olivine + orthopyroxene + magnesite + pyrite coexisting with a sulfur melt/fluid with dissolved Fe, Ni, and O is formed at T ≤ 1250°C. An association of low-Fe olivine, orthopyroxene, and magnesite and two immiscible melts of the carbonate and S–Fe–Ni–O compositions are formed at T ≥ 1350°C. It is shown that the reduced S-bearing fluids may transform silicates and carbonates, extract metals from the solid-phase matrix, and provide conditions for generation of sulfide melts.     

Rare earth element geochemistry of the Fen alkaline complex,Norway

Determination of rare earth element (REE) abundances in rocks of the Fen complex has shown that within rocks of the first magmatic series REE abundances increase in the order urtiteFen magmas are discussed and it is considered that parental magmas had relatively high La/Yb ratios (40–60). Utilizing petrological evidence from other alkaline complexes coupled with experimental studies it is considered that the parental magma was a carbonated nephelinite produced by limited (<10%) partial melting of the mantle. All the Fen rocks are placed in a petrogentic scheme in which a carbonated nephelinite magma undergoes liquid immiscibility, differentiation and volatile transport.     

Computerized vision for the geologist

The digital computer can be a tireless friend and assistant to the geologist. The computer has no innate intelligence, but given adequate programs to analyze and interrelate the information on maps, photos, surveys, and other material, the computer can serve as an analytical tool and consultant. To the geologist's qualitative knowledge, theories, and models can be added the possibility of the computer's mathematically precise numerical answers, confirming or refuting the original ideas. In the interactive mode in particular, a dialogue between the geologist and the computer is established, where the geologist and the computer can complement each other's abilities. The basic principles of processing two-dimensional geological data, such as maps, charts, photos, and survey results, are discussed. Some comparisons are also made between the rule-based methods of Prospector, developed at Stanford Research Institute, and the more intuitively guided image-based procedures of GIAPP, developed on the equipment at the National Research Council of Canada, in collaboration with the Geological Survey of Canada and the University of Ottawa.     

Heavy metals in Xuzhou urban roadside topsoils (China): magnetic characterization and enrichment mechanism

Heavy metal contamination is prevalent in urban areas where soil represents a significant sink. Urban topsoil samples were collected and metal concentrations including Pb, Zn, Cu, Cd, Ni and Co were measured by inductively coupled plasma mass spectrometry. All analyzed metals showed elevated concentrations compared to local background concentrations with the exception of Co. Cadmium was the metal most enriched in the analyzed area, presenting enrichment factor, on average, of 16.5. Mineral magnetic concentration parameters (χlf and SIRM) exhibited significant relationships with Pb, Zn, Cu and Cd, respectively. Zinc, Co and Ni exhibited a substantial build-up in the finest particles (<28 μm). Enrichment was positively correlated with carbonate complexation constants (but not bulk solubility products) and suggests that the dominant mechanism controlling metal enrichment in these samples is a precipitation of carbonate surfaces that subsequently adsorb metals.     

Geology and the conservation of antique monuments in Turkey

This article deals with a geological investigation carried out as a fundamental part of the conservation and static restoration of several antique churches excavated in andesitic tuff in the Göreme valley and adjacent areas of Cappadocia in Central Anatolia, Turkey. Two stages have been completed already, in 1982 and 1985, respectively, and the work is still in progress. Seismicity is not regarded as a structural hazard, but the geological history includes a series of volcanic episodes since the Oligocene (about 38 million years ago), which persisted into fairly recent times and laid down a great thickness of tuff rock. Erosion sculptured this tuff preferentially because of irregular harder, basaltic layers, which later capped rock pinnacles, the so-called peribacalars, in which churches were hewn over a thousand years ago. Because the host rock is heavily fissured, precipitation has entered and has damaged many mural paintings. These are also subject to vandalism, and efforts have been made to restore them by the usual conservation intervention. However, grouting is necessary and must take into account the porosity of the tuff, which also permits capillary rise from crypts. Sometimes, during wet episodes, water flushes into these and scours the interior walls as well. The basic problem remains geological, and the contribution of the earth sciences is very important. Thus, an engineering geology study has determined that the tuff rock is suitable both for building retaining walls and acting as a constituent in cement grout. It is expected that the UNESCO/ICCROM program to save the churches will be completed successfully within the next five years or so.