Total ozone variations in the tropical belt: An application for quality of ground based measurements

Summary The study of the regime of ozone variations in the huge tropical belt (25° S to 25° N), which are, in general, very small and zonally nearly symmetric, permits to establish a statistical model for estimating the ozone deviations using Total Ozone Mapping Spectrometer (TOMS) data. The equatorial stratospheric winds at 25 and 50hPa and the solar flux at 10.7 cm are used as major predictors and the linear trend was also estimated. The 10m/sec stratospheric wind change is related to1.2% ozone change at the equator, to practically no change in the 8–15° belts and up to 1.4% change with opposite phase over the tropics in spring but nearly zero change in fall. The solar cycle related amplitude is about 1.4% per 100 units of 10.7 cm solar flux. The ozone trends are negative: not significant over the equator and about –2% per decade (significant at 95% level) over the tropics. The latter could have been enforced by the 2 to 4% lower ozone values during 1991–1993, part of which might be related to the effects of the Mt. Pinatubo eruption, but might also be due to the strong QBO. The estimated deviations are verified versus reliable observations and the very good agreement permits applying the model for quantitative quality control of the reported ozone data from previous years. The standard deviation of the difference between observed ozone deviations and those estimated from the model is only 0.9–1.6% for yearly mean, that means instruments used for total ozone observations in the tropical belt should have systematic error of less than 1%. Cases when the discrepancies between the model and reported observations at a given station exceed 2–3% for time interval of 2 or more years should be verified.With 17 Figures     

Influence of the 11-year solar cycle on the effects of the equatorial quasi-biennial oscillation, manifesting in the extratropical northern atmosphere

Using the longest and most reliable ozonesonde data sets grouped for four regions (Japan, Europe, as well as temperate and polar latitudes of Canada) the comparative analysis of regional responses of ozone, temperature, horizontal wind, tropopause and surface pressure on the equatorial quasi-biennial oscillation (QBO effects), manifesting in opposite phases of the 11-year solar cycle (11-yr SC) was carried out. The impact of solar cycle is found to be the strongest at the Canadian Arctic, near one of two climatological centres of polar vortex, where in solar maximum conditions the QBO signals in ozone and temperature have much larger amplitudes, embrace greater range of heights, and are maximized much higher than those in solar minimum conditions. The strengthening of the temperature QBO effect during solar maxima can explain why correlation between the 11-yr SC and polar winter stratospheric temperature is reversed in the opposite QBO phases. At the border of polar vortex the 11-yr SC also modulates the QBO effect in zonal wind, strengthening the quasi-biennial modulation of polar vortex during solar maxima that is associated with strong negative correlation between stratospheric QBO signals in zonal wind and temperature. Above Japan the QBO effects of ozone, temperature, and zonal wind, manifesting in solar maxima reveal the downward phase dynamics, reminding similar feature of the zonal wind in the equatorial stratosphere. Above Europe, the QBO effects in solar maxima reveal more similarity with those above Japan, while in solar minima with the effects obtained at the Canadian middle-latitude stations. It is revealed that the 11-yr SC influences regional QBO effects in tropopause height, tropopause temperature and surface pressure. The influence most distinctly manifest itself in tropopause characteristics above Japan. The results of the accompanying analysis of the QBO reference time series testify that in the period of 1965–2006 above 50-hPa level the duration of the QBO cycle in solar maxima is 1–3 months longer than in solar minima. The differences are more distinct at higher levels, but they are diminished with lengthening of the period.     

Statistical analysis and comparison of external factor effects on the total ozone field over the Russian territory in 1973–2007

The analysis of external factors, which are most significant for the formation of the monthly mean total ozone (TO) field and ozone transport over the Russian Federation, based on observation data obtained from about 30 ground-based stations of the ozonometric network averaged over a year, December through March and June through August, over five climatic regions, is considered. Performed spectrum and discriminant analysis allowed obtaining quantitative estimates of the impact of the Arctic Oscillation, deviation of the winter temperature of the lower polar stratosphere, quasi-biennial oscillations (QBO), 11-year solar cycle, El Niño-Southern Oscillation (ENSO) on the TO and to assess the regional differences in the effects of these factors. In December–March, in the years with a negative Arctic Oscillation phase, warm stratosphere, and the easterly QBO phase (QBO-E), the ozone content increases significantly relative to the opposite phases of oscillations on average by 35, 28, and 26 Dobson units (DU), respectively. The spectra, similar to the discriminant function, demonstrate strong influence of the 11-year solar cycle and QBO on the TO even in the summer months, while the QBO is more pronounced in the eastern part of the Russian Federation. The ENSO effect was not singled out against the general “noisy” background of the cold six-month period, when many atmospheric processes become active: however, during the summer months, in warm periods of the ENSO, the TO, at the 97% significance level, increases over most of the Russian area. The rest of the obtained results are significant at the 95–99.9% level.     

Interannual variations in total ozone fields at high latitudes of the Northern Hemisphere, November to March 1998–2005

Synoptic analysis of monthly and daily mean total ozone fields is carried out using ground-based (Roshydromet) and TOMS measurements. Large interannual changes in the evolution of the stratospheric polar vortex and the North Pacific anticyclone influence the formation and dynamics of the winter-spring ozone fields in the stratosphere of high northern latitudes. The analysis shows considerable variations in the direction of zonal ozone transport from the sector of ozone inflow from low latitudes and accumulation in the Far East depending on the winter polar stratosphere temperature and the quasi-biennial oscillation (QBO) phase. In years with the easterly QBO phase and the warm polar stratosphere, ozone at the end of winter is transported to northeastern Canada and Atlantic. In years with the easterly phase and cold polar stratosphere, ozone transport is directed to northern Eurasia. These characteristics will be verified on extensive observational data.     

Extremely low temperatures in the stratosphore and very low total ozone amount above northern and central Europe during winter 1989

On 1 February 1989, -83.5°C was recorded in 27.8 hPa over Hohenpeißenberg, the lowest temperature in the 22-year series. This was measured together with a very low total ozone amount of 266 DU. This may be compared with nearly twice this amount on 27 February 1989. The situation was very unusual: following an extremely cold winter in the Arctic stratosphere, the stratospheric cold pole was located over southern Scandinavia on 1 February in a very southerly position. The analyzed temperatures of -92 °C in 30 hPa were also unusual. Even though the low ozone amounts over Hohenpeißenberg were probably dynamically caused, an additional very small ozone decrease due to heterogeneous reactions in altitudes from 23–28 km, where the temperatures lie below -80 °C, cannot be ruled out. Extinction measurements by the orbitting SAGE II instrument indeed show polar stratospheric clouds over Europe near 50° N during the period 31 January–2 February. Also, polar stratospheric clouds were previously observed over Kiruna at similarly low temperatures and signs of a corresponding small ozone decrease were noted there.     

Long-term measurements of surface ozone in the German Democratic Republic

The ozone concentration near the earth's surface has been measured at some stations in the GDR for more than 30 yr using the wet chemical method. Even at rural stations the ozone data show a significant linear increase by about 1–3% yr^–1. The ozone increase being stronger in summer than in winter is assumed to be due to photochemical ozone production from increasing anthropogenic emissions of trace gases that are transported over long distances. A weaker ozone increase by only about 0.2% per year was observed in the free troposphere (5.5 km) from balloon-soundings at Lindenberg within the period 1975–1984. If the ozone trends continue, the ozone concentration near the surface and its seasonal amplitude will have doubled around the turn of the century as compared to the mid-fifties.     

Chemical Ozone Loss in the Arctic Winter 1994/95 as Determined by the Match Technique

The chemically induced ozone loss inside the Arctic vortex during the winter 1994/95 has been quantified by coordinated launches of over 1000 ozonesondes from 35 stations within the Match 94/95 campaign. Trajectory calculations, which allow diabatic heating or cooling, were used to trigger the balloon launches so that the ozone concentrations in a large number of air parcels are each measured twice a few days apart. The difference in ozone concentration is calculated for each pair and is interpreted as a change caused by chemistry. The data analysis has been carried out for January to March between 370 K and 600 K potential temperature. Ozone loss along these trajectories occurred exclusively during sunlit periods, and the periods of ozone loss coincided with, but slightly lagged, periods where stratospheric temperatures were low enough for polar stratospheric clouds to exist. Two clearly separated periods of ozone loss show up. Ozone loss rates first peaked in late January with a maximum value of 53 ppbv per day (1.6 % per day) at 475 K and faster losses higher up. Then, in mid-March ozone loss rates at 475 K reached 34 ppbv per day (1.3 % per day), faster losses were observed lower down and no ozone loss was found above 480 K during that period. The ozone loss in hypothetical air parcels with average diabetic descent rates has been integrated to give an accumulated loss through the winter. The most severe depletion of 2.0 ppmv (60 %) took place in air that was at 515 K on 1 January and at 450 K on 20 March. Vertical integration over the levels from 370 K to 600 K gives a column loss rate, which reached a maximum value of 2.7 Dobson Units per day in mid-March. The accumulated column loss between 1 January and 31 March was found to be 127 DU (36 %).     

QBO Signal in total ozone over Tibet

1. IntroductionOzone is one of the trace gases in the atmosphere distributed in 10--50 km altitude withthe maximum in 20--28 km. Ozone is significant in the following three aspects impacting theclimate and environment: 1) Ozone absorbs harmful solar ultra--violet radiation for protecting the ecological system on the Earth; 2) ozone heats the stratosphere and forces the circulation systems in this layer; 3) ozone variation in the stratosphere can change the incomingradiation at the surface leve…     

青藏高原臭氧的准两年振荡

通过对臭氧卫星观测资料及大气环流资料的分析,研究了青藏高原上空臭氧的季节和年际变化.通过分析青藏高原地区臭氧准两年振荡(QBO),并与同纬度无山区及赤道地区臭氧QBO进行比较,指出:青藏高原臭氧QBO的平均周期为29个月,平均振幅为8DU.青藏高原臭氧QBO变化位相与热带平流层纬向风场QBO相反,即热带平流层纬向西风时,青藏高原上空臭氧总量偏小,东风时臭氧总量偏大.还讨论了与青藏高原臭氧QBO相关的大气环流物质输送理论.     

A review of global stratospheric aerosol: Measurements, importance, life cycle, and local stratospheric aerosol

Stratospheric aerosol, noted after large volcanic eruptions since at least the late 1800s, were first measured in the late 1950s, with the modern continuous record beginning in the 1970s. Stratospheric aerosol, both volcanic and non-volcanic are sulfuric acid droplets with radii (concentrations) on the order of 0.1–0.5 µm (0.5–0.005 cm^− 3), increasing by factors of 2–4 (10–10³) after large volcanic eruptions. The source of the sulfur for the aerosol is either through direct injection from sulfur-rich volcanic eruptions, or from tropical injection of tropospheric air containing OCS, SO₂, and sulfate particles. The life cycle of non-volcanic stratospheric aerosol, consisting of photo-dissociation and oxidation of sulfur source gases, nucleation/condensation in the tropics, transport pole-ward and downward in the global planetary wave driven tropical pump, leads to a quasi steady state relative maximum in particle number concentration at around 20 km in the mid latitudes. Stratospheric aerosol have significant impacts on the Earth's radiation balance for several years following volcanic eruptions. Away from large eruptions, the direct radiation impact is small and well characterized; however, these particles also may play a role in the nucleation of near tropopause cirrus, and thus indirectly affect radiation. Stratospheric aerosol play a larger role in the chemical, particularly ozone, balance of the stratosphere. In the mid latitudes they interact with both nitrous oxides and chlorine reservoirs, thus indirectly affecting ozone. In the polar regions they provide condensation sites for polar stratospheric clouds which then provide the surfaces necessary to convert inactive to active chlorine leading to polar ozone loss. Until the mid 1990s the modern record has been dominated by three large sulfur-rich eruptions: Fuego (1974), El Chichón (1982) and Pinatubo (1991), thus definitive conclusions concerning the trend of non-volcanic stratospheric aerosol could only recently be made. Although anthropogenic emissions of SO₂ have changed somewhat over the past 30 years, the measurements during volcanically quiescent periods indicate no long term trend in non-volcanic stratospheric aerosol.     

Homogenisation and trend detection analysis of broken series of solar UV-B data

Summary Statistical techniques have been developed to homogenise a broken series of clear-sky solar UV-B radiation, measured by a Robertson Berger (RB) meter over the period 1981–90 at Invercargill, New Zealand, and to analyse the series for long term trend. Statistical modelling of the quasi-linear UV-B/ozone relationship evident in the departures of daily clear-sky UV-B data and coincident satellite ozone data from their respective mean references has been used to provide a self-consistent de-seasonalised data set of UV-B and ozone departures, and to bridge a major gap in calibration that separates the data set into two periods, 1981–86 and 1988–90. The choice of UV-B reference is important to the quality of the results and particular attention was given to the methodology for defining it. Four alternative objective adjustment procedures for calibrating the 1988–90 period against the 1981–86 period were examined. Because our interest lies primarily in the higher values of summer, a UV-B-weighted procedure was chosen. The modelling and homogenisation techniques developed may have application in related analysis problems. Analysis of the data for the independent 1981–86 period showed large trends in ozone and UV-B, but this was mostly due to a period of very low ozone values during 1985. Over the whole period, 1981–90, the ozone trend was –4.7%/decade. The corresponding UV-B trend was +5.8%/decade, but this result is not independent of the corresponding ozone trend because the homogenisation procedure imposes the assumption of the derived UV-B/ozone relationship on the 1988–90 UV-B data. However, the evidence suggests there is little reason to doubt that solar UV-B radiation has increased at the site by about +6% per decade.With 10 Figures     

Intercomparison of Stratospheric Chemistry Models under Polar Vortex Conditions

Several stratospheric chemistry modules from box, 2-D or 3-D models, have been intercompared. The intercomparison was focused on the ozone loss and associated reactive species under the conditions found in the cold, wintertime Arctic and Antarctic vortices. Comparisons of both gas phase and heterogeneous chemistry modules show excellent agreement between the models under constrained conditions for photolysis and the microphysics of polar stratospheric clouds. While the mean integral ozone loss ranges from 4–80% for different 30–50 days long air parcel trajectories, the mean scatter of model results around these values is only about ±1.5%. In a case study, where the models employed their standard photolysis and microphysical schemes, the variation around the mean percentage ozone loss increases to about ±7%. This increased scatter of model results is mainly due to the different treatment of the PSC microphysics and heterogeneous chemistry in the models, whereby the most unrealistic assumptions about PSC processes consequently lead to the least representative ozone chemistry. Furthermore, for this case study the model results for the ozone mixing ratios at different altitudes were compared with a measured ozone profile to investigate the extent to which models reproduce the stratospheric ozone losses. It was found that mainly in the height range of strong ozone depletion all models underestimate the ozone loss by about a factor of two. This finding corroborates earlier studies and implies a general deficiency in our understanding of the stratospheric ozone loss chemistry rather than a specific problem related to a particular model simulation.     

Feasibility of observations of stratospheric trace gases using the Hubble Space Telescope

The stellar occultation method has been successfully used in the past from orbiting observatories to measure concentrations of certain trace gases in the Earth's mesosphere. The greatly improved spectroscopic capabilities of the Hubble Space Telescope (HST) have prompted recent suggestions for its use to measure stratospheric C10. We examine this possibility along with that for other species relevant to the chemistry of the ozone layer. We conclude that stratospheric (as opposed to mesospheric) observations with HST are not practical, in part because of its orbital and pointing characteristics, but primarily because the high opacity of stratospheric ozone over most of the band-pass of the HST's most suitable spectrometer will obscure observation of other trace species, such as C10, having mixing ratios <10^–3 that of ozone.     

NUMERICAL INVESTIGATION OF QBO IN OZONE

In this paper, a two-dimensional primitive equation model, coupling dynamical, radiative andphotochemical processes, is used to simulate the quasi-biennial oscillation (QBO) in ozone. TheQBO in total ozone has been successfully simulated when the forcing of equatorial stratosphericQBO in zonal wind is imposed. The simulated characters of QBO in ozone are in close agreementwith those observed. We further analyzed the mechanism of formation and maintenance of QBO inozone. In the different phases of QBO in equatorial stratospheric wind field, the global circulationhas so great difference that it makes the effects of advection transfer and eddy transfer present aquasi-biennial periodical variation. Chemical effect and dynamical effect are basically out-of-phase.They together form and maintain the QBO in ozone. Total variation rate is a tiny difference of thetwo large amounts. At the lower level of middle-high latitudes, however, it has a phase differenceof about 1-2 months between dynamical and negative chemical effects, where the dynamical effectis comparatively greater. QBO in ozone has no clear counter effects on atmospheric circulation. The experiment resultsshow that the effects of QBO in ozone on temperature field and wind field are very small.     

Stratospheric climate and variability from a general circulation model and observations

The climate and natural variability of the large-scale stratospheric circulation simulated by a newly developed general circulation model are evaluated against available global observations. The simulation consisted of a 30-year annual cycle integration performed with a comprehensive model of the troposphere and stratosphere. The observations consisted of a 15-year dataset from global operational analyses of the troposphere and stratosphere. The model evaluation concentrates on the simulation of the evolution of the extratropical stratospheric circulation in both hemispheres. The December–February climatology of the observed zonal mean winter circulation is found to be reasonably well captured by the model, although in the Northern Hemisphere upper stratosphere the simulated westerly winds are systematically stronger and a cold bias is apparent in the polar stratosphere. This Northern Hemisphere stratospheric cold bias virtually disappears during spring (March–May), consistent with a realistic simulation of the spring weakening of the mean westerly winds in the model. A considerable amount of monthly interannual variability is also found in the simulation in the Northern Hemisphere in late winter and early spring. The simulated interannual variability is predominantly caused by polar warmings of the stratosphere, in agreement with observations. The breakdown of the Northern Hemisphere stratospheric polar vortex appears therefore to occur in a realistic way in the model. However, in early winter the model severely underestimates the interannual variability, especially in the upper troposphere. The Southern Hemisphere winter (June–August) zonal mean temperature is systematically colder in the model, and the simulated winds are somewhat too strong in the upper stratosphere. Contrary to the results for the Northern Hemisphere spring, this model cold bias worsens during the Southern Hemisphere spring (September–November). Significant discrepancies between the model results and the observations are therefore found during the breakdown of the Southern Hemisphere polar vortex. For instance, the simulated Southern Hemisphere stratosphere westerly jet continuously decreases in intensity more or less in situ from June to November, while the observed stratospheric jet moves downward and poleward.This paper was presented at the Third International Conference on Modelling of Global Climate Change and Variability, held in Hamburg 4–8 Sept. 1995 under the auspice of the Max Planck Institute for Meteorology, Hamburg. Editor for these papers is L. Dümenil.     

Simultaneous observations of SAO and QBO in winds, temperature and ozone in the tropical middle atmosphere over Thumba (8.5��N, 77��E)

Owing to the importance of middle atmosphere, recently, a Middle Atmospheric Dynamics (MIDAS) program was carried out during the period 2002?C2007 at Thumba (8.5°N, 77°E). The measurements under this program, involving regular radiosonde/rocket flights as well as atmospheric radars, provided long period observations of winds and temperature in the middle atmospheric region from which waves and oscillations as well as their forcing mechanisms particularly in the low-latitude middle atmosphere could be analyzed. However, a detailed analysis of the forcing mechanisms remains incomplete due to the lack of important measurements like ozone which is a significant contributor to atmospheric dynamics. Presently, profiles of ozone are available from TIMED/SABER (Thermosphere, Ionosphere, Mesosphere Energetics and Dynamics/Sounding of the Atmosphere using Broad Emission Radiometry) satellite globally from about 15 to 100?km, over multiple years since 2002. In this regard, a comprehensive study has been carried out on ozone and its variability at Quasi Biennial Oscillation (QBO) and Semiannual Oscillation (SAO) scales using TIMED/SABER ozone observations during the MIDAS campaign period. Before using the TIMED/SABER ozone measurements, an inter-comparison has been carried out with in situ measurements of ozone obtained under the Southern Hemisphere Additional Ozonesondes (SHADOZ) campaign for the year 2007 at few stations. The inter-comparison showed very good agreement between SABER and ozonesonde derived ozone profiles. After validating the SABER observations, ozone profiles are used extensively to study the QBO and SAO along with temperature and winds in the 20?C100?km height region. It is known that the SAO in mesosphere and stratosphere are in opposite phases, but the present study for the first time reports the aspect of opposite phases in the mesosphere itself. Thus, the present work attempts to study the long-period oscillations in stratosphere and mesosphere in ozone, temperature and winds simultaneously for the first time over this latitude. These observations provided a unique opportunity to explore long-period oscillations in chemistry, dynamics and thermal structure of the middle atmosphere simultaneously.     

Tropospheric Ozone at the Swedish Mountain Site Åreskutan: Budget and Trends

Ozone measurements, performed since 1987, at the Swedish TOR/EUROTRACstation Åreskutan (lat. 63.4° N, long. 13.1° E, 1250 m abovesea level) are analyzed. The annual average ozone concentration at the sitehas increased by about 0.4 ppbv (1%) per year during the period1987–1994. The corresponding trends for individual months show adecrease during April–September and an increase during the rest of theyear. The ozone budget at Åreskutan has been investigated using backtrajectories of the air parcels, and the cosmogenic radionuclide⁷Be as a tracer of stratospheric air. From a simple diagnosticmodel, it is estimated that the contribution of stratospheric ozone to theconcentrations measured at Åreskutan is 5 ppbv (or 14% of themeasured values) on average, reaching a maximum of 23 ppbv (50%),during the episodes of direct stratospheric influence. In spring, thestratospheric contribution to ozone budget at Åreskutan is at itsmaximum, and approximately equal to the net photochemical ozone productionin the air mass affecting the site, whereas in winter, it is compensated byozone chemical sink during the transport of air masses from pollutedEuropean regions, to Scandinavia.     

Vertical ozone distribution characteristics deduced from ∼ 44,000 re-evaluated Umkehr profiles (1957–2000)

Summary Umkehr observations taken during the 1957–2000 period at 15 stations located between 19 and 52° N have been reanalyzed using a significantly improved algorithm-99, developed by DeLuisi and Petropavlovskikh et al. (2000a,b). The alg-99 utilizes new latitudinal and seasonally dependent first guess ozone and temperature profiles, new vector radiative transfer code, complete aerosol corrections, gravimetric corrections, and others. Before reprocessing, all total ozone values as well as the N-values (radiance) readings were thoroughly re-evaluated. For the first time, shifts in the N-values were detected and provisionally corrected. The re-evaluated Umkehr data set was validated against satellite and ground based measurements. The retrievals with alg-99 show much closer agreement with the lidar and SAGE than with the alg-92. Although the latitudinal coverage is limited, this Umkehr data set contains ∼ 44,000 profiles and represent the longest (∼ 40 years) coherent information on the ozone behavior in the stratosphere of the Northern Hemisphere. The 14-months periods following the El-Chichon and the Mt. Pinatubo eruptions were excluded from the analysis. Then the basic climatological characteristics of the vertical ozone distribution in the 44–52° N and more southern locations are described. Some of these characteristics are not well known or impossible to be determined from satellites or single stations. The absolute and relative variability reach their maximum during winter–spring at altitudes below 24 km; the lower stratospheric layers in the middle latitudes contain ∼ 62% of the total ozone and contribute ∼ 57% to its total variability. The layer-5 (between ∼ 24 and 29 km) although containing 20% of the total ozone shows the least fluctuations, no trend and contributes only ∼ 11% to the total ozone variability. Meridional cross-sections from 19 to 52° N of the vertical ozone distribution and its variability illustrate the changes, and show poleward-decreasing altitude of the ozone maximum. The deduced trends above 33 km confirm a strong ozone decline since the mid-1970s of over 5% per decade without significant seasonal differences. In the mid-latitude stations, the decline in the 15–24 km layer is nearly twice as strong in the winter-spring season but much smaller in the summer and fall. The effect of including 1998 and 1999 years with relatively high total ozone data reduces the overall-declining trend. The trends estimated from alg-99 retrievals are statistically not significantly different from those in WMO 1998a; however, they are stronger by about 1% per decade in the lower stratosphere and thus closer to the estimates by sondes. Comparisons of the integrated ozone loss from the Umkehr measurements with the total ozone changes for the same periods at stations with good records show complete concurrence. The altitude and latitude appearances of the long-term geophysical signals like solar (1–2%) and QBO (2–7%) are investigated. Received April 12, 2001 Revised September 19, 2001     

Impact of stratospheric variability on tropospheric climate change

An improved stratospheric representation has been included in simulations with the Hadley Centre HadGEM1 coupled ocean atmosphere model with natural and anthropogenic forcings for the period 1979–2003. An improved stratospheric ozone dataset is employed that includes natural variations in ozone as well as the usual anthropogenic trends. In addition, in a second set of simulations the quasi biennial oscillation (QBO) of stratospheric equatorial zonal wind is also imposed using a relaxation towards ERA-40 zonal wind values. The resulting impact on tropospheric variability and trends is described. We show that the modelled cooling rate at the tropopause is enhanced by the improved ozone dataset and this improvement is even more marked when the QBO is also included. The same applies to warming trends in the upper tropical troposphere which are slightly reduced. Our stratospheric improvements produce a significant increase of internal variability but no change in the positive trend of annual mean global mean near-surface temperature. Warming rates are increased significantly over a large portion of the Arctic Ocean. The improved stratospheric representation, especially the QBO relaxation, causes a substantial reduction in near-surface temperature and precipitation response to the El Chichón eruption, especially in the tropical region. The winter increase in the phase of the northern annular mode observed in the aftermath of the two major recent volcanic eruptions is partly captured, especially after the El Chichón eruption. The positive trend in the southern annular mode (SAM) is increased and becomes statistically significant which demonstrates that the observed increase in the SAM is largely subject to internal variability in the stratosphere. The possible inclusion in simulations for future assessments of full ozone chemistry and a gravity wave scheme to internally generate a QBO is discussed.     

Numerical Modeling of the Influence of Physical and Chemical Factors on the Interannual Variability of Antarctic Ozone

The variability of Antarctic total column ozone in 1980–2018 is considered. The study analyzes trends in Antarctic total column ozone during the study period as well as the physical and chemical processes affecting the seasonal variability of total column ozone. The main attention is paid to the influence of dynamical processes on the stability of the Antarctic polar vortex, to the formation of polar stratospheric clouds, and to the influence of gas-phase and heterogeneous processes on the surface of polar stratospheric clouds and sulfate aerosol. The method of research is the analysis of the results of ground and satellite observations and numerical modeling of physical and chemical processes over the Antarctic using a global chemistry transport model with the dynamical parameters specified from reanalysis data.