Identification of hydrogeochemical zones in postglacial buried valley aquifer (Wielkopolska Buried Valley aquifer,Poland)

This article presents the difficulty in identifying the hydrochemical zoning of a semi-confined aquifer, characterised by a relative small spatial differentiation of groundwater chemistry. It is shown that multivariate statistical methods can be used for the recognition and interpretation of the groundwater chemistry distribution in an aquifer. The hydrochemical zonation caused by both natural and anthropogenic processes was identified using factor analyses in combination with a classical interpretation of the hydrogeological material. The interpretation of the groundwater chemistry allows both identification of the aquifer recharge mechanism and verification of the groundwater-flow system.     

Study of geothermal water intrusion due to groundwater exploitation in the Puebla Valley aquifer system, Mexico

Significant intrusion of geothermal water into fresh groundwater takes place in the Puebla Valley aquifer system, Mexico. The decline in the potentiometric surface due to the overexploitation of the groundwater induces this intrusion. This hydrological system comprises three aquifers located in Plio-Quaternary volcanic sediments and Mesozoic calcareous rocks. The hydraulic balance of the aquifer shows that the annual output exceeds the natural inputs by 12 million m³. Between 1973 and 2002, a drop in the potentiometric surface, with an 80 m cone of depression, was identified in a 5-km-wide area located southwest of the city of Puebla. Chemical analyses performed on water samples since 1990 have shown an increase in total dissolved solids (TDS) of more than 500 mg/L, coinciding with the region showing a cone of depression in the potentiometric surface. A three-dimensional flow and transport model, based on the hydrogeological and geophysical studies, was computed by using the MODFLOW and MT3D software. This model reproduces the evolution of the aquifer system during the last 30 years and predicts for 2010 an additional drawdown in the potentiometric surface of 15 m, and an increase in the geothermal water intrusion.     

A synthetic study of geophysics-based modelling of groundwater flow in catchments with a buried valley

Groundwater models simulating flow in buried valleys interacting with regional aquifers are often based on hydrogeological models interpreted from dense geophysical datasets and scarce borehole data. For three simple synthetic cases, it is demonstrated that alternative methods of inversion of transient electro-magnetic (TEM) data can lead to very different interpretations of the hydrogeology inside and surrounding a buried valley. The alternative interpreted hydrogeological models are used in numerical modelling of groundwater flow to a pumping well. It is demonstrated that the alternative models result in quite different groundwater-model predictions of capture zone, recharge area, and groundwater age for the pumping well. It is briefly demonstrated that model calibration against hydraulic head data is not likely to improve the predictions or to identify the structural error of the interpreted hydrogeological models. It is therefore concluded that when TEM-based resistivity models are interpreted to construct the hydrogeological framework of a groundwater model, it must be done cautiously with support from deep borehole information. Too much reliance on geophysical mapping can lead to seriously wrong hydrogeological models and correspondingly wrong groundwater-model predictions.     

Use of alternative conceptual models to assess the impact of a buried valley on groundwater vulnerability

A buried valley incised into a sequence of pre-Quaternary sediments is shown to seriously affect the vulnerability of groundwater. Often the existence of buried valleys is not known or is not described explicitly in a hydrogeological model. In the present study, two numerical groundwater models, representing two alternative conceptual models, were produced to help quantify the effect of the valley on groundwater vulnerability. One model included the buried valley and the other did not. Both models were subjected to calibration and were found to describe hydraulic head and river discharge equally well. Even though the two models showed similar calibration statistics; fluxes, travel paths and travel times were affected by the inclusion of the buried valley. The recharge area and the groundwater age of potential abstraction wells placed in the pre-Quaternary deep aquifers surrounding the buried valley were different for the two models, with significantly higher vulnerability when the valley was included in the model. Based on the results of the present study, it is concluded that a buried valley may not always be detectable when calibrating a wrong conceptual model. If reliable results should be obtained a good geological model has to be constructed.     

Impact of the unpredictable changes in agricultural groundwater use on long-term sustainable exploitation: the case study of Bouhefna-Haffouz aquifer system,central Tunisia

Long-term exploitation schemes in many regions are often based solely on hydrodynamic factors, while the agricultural use of groundwater undergoes significant changes over time. The Bouhefna-Haffouz aquifer system in central Tunisia is one of those cases where an aquifer exploitation scheme was well designed hydrodynamically to address the political needs at the time. Fifty years later, a numerical groundwater model has been conducted to assess the sustainability of the scheme. Results show that the scheme aimed to lower the groundwater level to reduce overflow to Merguellil Wadi and maintain it at a level that benefits agricultural profitability. This caused loss of the Merguellil baseflow, forcing farmers to switch from traditional irrigation canals to deep wells and motor pumps, thereby disrupting the hydrological budget even further. The numerical model indicates that the flow to the wadi reached zero in 1978, the average flow by vertical leakage decreased from 8 hm³ in 1970 to 2 hm³ in 2020, and the horizontal percolation between the regional aquifer units increased from 1 hm³ in 1970 to 6 hm³ in 2020. Although the groundwater exploitation scheme was not previously considered a factor in local hydrological changes, the results of this study demonstrate the significant impact of societal behavior following the scheme’s implementation on the hydrological budget of Merguellil Wadi.

     

A study on the impact of weathering in groundwater chemistry of a hard rock aquifer

Hydrogeochemistry of groundwater in hard rock terrain are mainly governed by lithology and land use practices. A study area near Madurai region of central Tamil Nadu was selected with various litho-units and a hard rock sedimentary contact with an unconformity. Land use practices in these regions are also varied with lithology. The study was conducted by collecting 54 groundwater samples spatially covering the major litho-units. Collected samples were analyzed for electrical conductivity, pH, total dissolved solids (TDS), temperature, Ca, Mg, Na, K, Cl, HCO₃, NO₃, H₄SiO₄, PO₄, and SO₄. The results of the samples analyzed found to vary spatially. Dominance of ion shows that the alkalies are predominant and HCO₃ is the dominant anion. Piper facies show that the samples are alkali-carbonate type indicating the predominance of weathering. Most of the parameters exceed the drinking water permissible limit. Standard plots and statistical analysis also indicate weathering as the major process governing the hydrogeochemistry of the groundwater in the region. Relative mobility of cations indicates that the rate of liberation of alkalies from the lithology is more prominent.     

Provenance of buried esker groundwater: the case of Vars-Winchester esker aquifer,Eastern Ontario,Canada

An innovative mode of groundwater recharge to a buried esker aquifer is considered. The current conceptual model affords a natural safeguard to underlying aquifers from the overlying muds. A hypothesis of groundwater recharge to a buried esker aquifer via preferential pathways across its overlying muds is tested here by heuristic numerical one-dimensional and two-dimensional modeling simulations. The hypothesis has been tested against two other conventionally accepted scenarios involving: (1) distal esker outcrop areas and (2) remote shallow-bedrock recharge areas. The main evidence comes from documented recharge pressure pulses in the overlying mud aquitard and in the underlying esker hydraulic-head time series for the Vars-Winchester esker aquifer in Eastern Ontario, Canada. These perturbations to the potentiometric surface are believed to be the aquifer response to recharge events. The migration rate of these pressure pulses is directly related to the hydraulic diffusivity of the formation. The measured response time and response amplitude between singular radar precipitation events and well hydrographs constituted the heuristic model calibration targets. The main evidence also includes mud-layering deformation (water escape features) which was observed in seismic surveys of the over-esker muds. These disturbed stratigraphic elements provide a realistic mechanism for migrating water to transit through the muds. The effective hydraulic conductivities of these preferential pathways in the muds were estimated to be between 2?×?10^?6 and 7?×?10^?6 m/s. The implications of these findings relate to the alleged natural safeguard of these overlying muds.     

Processes affecting groundwater chemistry in a zone of saline intrusion into an urban sandstone aquifer

Samples have been collected from inflows into railway tunnels in the Triassic sandstone aquifer beneath Liverpool and the Mersey Estuary, England, U.K. These provide a profile through a saline–freshwater mixing zone. Analyses were made of major anions and cations, δ³⁴S and δ¹⁸O in SO₄, δ¹³C in dissolved inorganic C and ⁸⁷Sr/⁸⁶Sr. The data demonstrate that the presence of a low permeability fault exerts a strong control on the local groundwater chemistry. On the estuary side of the fault, groundwater chemistry is dominated by mixing of intruding estuary water, which is modified by SO₄ reduction and calcite dissolution, with fresh groundwater. The environment of SO₄ reduction in the tidal estuary is one of repeated reduction and re-oxidation of S in an open system and has resulted in virtually no change in S isotopic composition, but an enrichment in residual SO₄ δ¹⁸O of 1.5‰. Groundwater chemistry on the landward side of the fault is primarily the result of recharge in an urban environment. There is also evidence that saline water has been present in this region of the aquifer in the past and that this has now been flushed by fresh groundwaters. This saline water was either transported along the landward side of the fault from nearer the estuary or more probably transmitted across the fault. Both mechanisms would have been driven by large landward head gradients caused by heavy industrial abstraction earlier this century. This has produced a zone of groundwaters depleted in Ca and radiogenic Sr and enriched in Na as a result of ion exchange between the fresh groundwaters and the aquifer previously occupied by more saline water. Sulphur isotopic composition, however, shows no variation since SO₄ does not undergo significant ion exchange. A tracer test from a borehole to the tunnels showed multiple breakthroughs to some locations indicating a number of different flow paths through the aquifer. The maximum flow velocity recorded in this test was 140 m/d suggesting flow along fractures.     

Effects of groundwater exploitation on the Borjomi mineral water reservoir in Georgia

The mineral water at Borjomi has been bottled since the 19th century. Currently, the production comes from the regulated artesian flow of 11 boreholes. The total yield is about 540 m³/day. The mineral water is of sodium, hydrogen carbonate and CO₂ type with mineralization up to 7.5 g/l and a temperature up to 40°C. Long-term observation has enabled the history of the structure of the Borjomi mineral water to be reconstructed from the beginning of its exploitation until the present. The hydrogeological structure of the Borjomi locality is very complex, but on the regional scale it occupies a relatively small area. The hydraulically well-defined and closed structure allows a simple conceptual model for each of the three main sectors to be designed. These are, namely, the Central, the Vaschlovani and the Likani sectors. The long-term extraction limits are about 190 m³/day in the Central sector, 300 m³/day in the Vashlovani sector and 77 m³/ day in the Likani sector.     

Geologic factors controlling groundwater chemistry in the coastal aquifer system of Douala/Cameroon: implication for groundwater system functioning

Douala city, located in the littoral province of Cameroon, receives abundant rainfall quantities due to its geographical position in the Gulf of Guinea and bears considerable surface water and groundwater resources. Due to socioeconomic development and rapid demographic growth in the city and its consequences of unplanned urbanization and improper sanitation system, these water resources are poorly protected and managed. Streams in the Wouri watershed receive large amounts of wastewater discharge, and hundreds of boreholes have been drilled into the aquifer system without any management plan. A detailed hydrodynamic and hydrogeochemistry study in Douala town and its environs was conducted to get a better insight into the groundwater system functioning in order to provide information for the sustainable management and protection of the groundwater resource. Two field campaigns were carried out with 187 samples collected and analyzed for major ions, stable isotopes (¹⁸O, ²H), and tritium ³H. The results of the sampling have shown that the weathering of silicate minerals is the dominant geochemical process affecting groundwater chemistry in this system. However, acid rainfall in the humid climate has also caused carbonate mineral dissolution, amorphous silica deposition, and ion exchange reactions to occur in aquifers in the region. The various water types identified were categorized into four major clusters C1 to C4, based on the major ion composition and the local hydrogeological conditions. Environmental isotope data reveal that modern-to-submodern waters occur in the phreatic Quaternary/Mio-Pliocene and Oligocene/Upper Eocene aquifers, respectively. These results corroborate with the conceptual model built where modern groundwater types indicated silicate mineral weathering and calcite dissolution (C1 and C2), whereas submodern groundwater mostly showed silica deposition, ion exchange, and, to a lesser extent, carbonate mineral dissolution (C3 and C4). This improved understanding of the aquifer system functioning is essential to provide a reasonable basis for effective control measures and sustainable water management.     

The effects of geological heterogeneities and piezometric fluctuations on groundwater flow and chemistry in a hard-rock aquifer, southern India

Crystalline aquifers of semi-arid southern India represent a vital water resource for farming communities. A field study is described that characterizes the hydrodynamic functioning of intensively exploited crystalline aquifers at local scale based on detailed well monitoring during one hydrological year. The main results show large water-table fluctuations caused by monsoon recharge and pumping, high spatial variability in well discharges, and a decrease of well yields as the water table decreases. Groundwater chemistry is also spatially variable with the existence of aquifer compartments within which mixing occurs. The observed variability and compartmentalization is explained by geological heterogeneities which play a major role in controlling groundwater flow and connectivity in the aquifer. The position of the water table within the fracture network will determine the degree of connectivity between aquifer compartments and well discharge. The presented aquifer conceptual model suggests several consequences: (1) over-exploitation leads to a drop in well discharge, (2) intensive pumping may contribute to the hydraulic containment of contaminants, (3) groundwater quality is highly variable even at local scale, (4) geological discontinuities may be used to assist in the location of drinking-supply wells, (5) modeling should integrate threshold effects due to water-table fluctuations.     

南水北调水源在密怀顺水源地回灌的地下水水质变化试验

南水北调水源进京后,部分水源计划将进入密怀顺水源地回补严重亏损的地下水。水源地地下水水质的未来变化引起了人们的关注。本次研究通过开展动态含水层模拟试验,分析了南水北调水源进入含水层过程中地下水水质变化,并利用溶质运移模型,在不考虑吸附、降解等水岩相互作用等条件下,模拟了试验土柱中各常规组分的水质变化。研究表明:南水北调水源进入含水层过程中,对地下水水质的稀释作用占主导地位,其它水岩相互作用对地下水水质的影响程度较小,南水北调水源在密怀顺水源地回补地下水是可行的。为此,南水北调水源回补地下水后,不仅能够涵养并增加水源地的地下水资源,而且能够改善地下水水质,保证水源地的供水安全。     

含水层层状非均质对地下水流系统的影响

区域尺度上含水层非均质具有复杂的结构性和随机性,难以准确刻画,造成非均质对区域地下水流系统的影响机制研究不够深入。本文以鄂尔多斯盆地白垩系地下水流系统为研究实例,选择典型剖面,采用剖面二维随机数值模拟方法,通过对比不同非均质刻画方法下地下水流场的变化,探讨含水层层状非均质对地下水流系统的影响机制。结果显示,均质条件下模型各向异性（含水层水平和垂向渗透系数比值Kh/Kv）取值为1000时,地下水流场与实际条件较为接近;非均质条件下,渗透系数方差取值0.91,水平相关长度取值5000 m,Kh/Kv取值150时,接近实际条件。研究表明,在大尺度地下水流模拟研究中,采用水平相关长度、渗透系数方差和各向异性值三个变量生成的随机场能很好地刻画含水层的层状非均质特征及其对水流系统的影响控制作用。由于含水层不同尺度层状非均质的叠加效应,采用均质各向异性介质等效概化含水层层状非均质性会造成等效各向异性值偏大失真的效应。     

内蒙古清水河水源地地下水允许开采量计算

为解决内蒙古清水河县城新区供水问题, 在分析水源地水文地质条件的基础上, 利用勘察获得的资料, 对评价中相关水文地质参数的确定进行了讨论。经计算, 研究区的降水入渗系数为0.19, 河流补给量为873.13 m3/d。采用均衡法进行地下水资源评价, 确定了研究区地下水允许开采量为 40 769.14 m3/d, 能够满足该区未来需水量。     

Participatory groundwater modeling for managed aquifer recharge as a tool for water resources management of a coastal aquifer in Greece

Hydrogeology Journal - A participatory modelling approach is presented for effective groundwater management at the Mediterranean coastal plain of Marathon, Greece. The main objective was to...     

Implications of Kali-Hindon inter-stream aquifer water balance for groundwater management in western Uttar Pradesh

The Kali-Hindon inter-stream region extends over an area of 395 km² within the Ganga-Yamuna interfluve. It is a fertile tract for sugarcane cultivation. Groundwater is a primary resource for irrigation and industrial purposes. In recent years, over-exploitation has resulted in an adverse impact on the groundwater regime. In this study, an attempt has been made to calculate a water balance for the Kali-Hindon inter-stream region. Various inflows and outflows to and from the aquifer have been calculated. The recharge due to rainfall and other recharge parameters such as horizontal inflow, irrigation return flow and canal seepage were also evaluated. Groundwater withdrawals, evaporation from the water table, discharge from the aquifer to rivers and horizontal subsurface outflows were also estimated. The results show that total recharge into the system is 148.72 million cubic metres (Mcum), whereas the total discharge is 161.06 Mcum, leaving a deficit balance of −12.34 Mcum. Similarly, the groundwater balance was evaluated for the successive four years. The result shows that the groundwater balance is highly sensitive to variation in rainfall followed by draft through pumpage. The depths to water level are shallow in the canal-irrigated northern part of the basin and deeper in the southern part. The pre-monsoon and post-monsoon water levels range from 4.6 to 17.7 m below ground level (bgl) and from 3.5 to 16.5 m bgl respectively. It is concluded that the groundwater may be pumped in the canal-irrigated northern part, while withdrawals may be restricted to the southern portion of the basin, where intense abstraction has led to rapidly falling water table levels.     

Impact of intense exploitation on the groundwater balance and flow within Mullusi aquifer (arid zone, west Iraq)

The main results that derived from this study is the quantitative determination of subsurface water balance and the water loses along flow line during drought decade (before 2000–2009), with intense exploitation of groundwater from water wells. The hydrogeological data are presented as spatial distribution maps and three dimensional models. The results are correlated with the main hydrogeologic control points including (storage and transmissivity coefficients, groundwater depths, aquifers thickness, lateral extensions, well productivity) to determine the preferable hydrogeologic districts for development and exploitations, avoiding groundwater depletion as captured zone flow. Based on the isotope analysis of deuterium, oxygen-18, tritium, carbon-13, and carbon-14, the recharge of the aquifer is originated to direct infiltration of atmospheric water through exposure outcrops within Hauran catchments area. The isotope compositions also show that the groundwater is a mixture of an old groundwater with modern recharge in the areas adjacent to Rutba. The fact that the Mullusi aquifer is of major importance as the water supply of people in Rutba region, particularly, for increasing demand of water resources and sustainability assessment in the future, this study developed a reliable strategic suggested plan in groundwater supply, based on groundwater exploitation and amount of safe yield within Dhabaa basin.     

Numerical analysis of subsurface deformation induced by groundwater level changes in the Bangkok aquifer system

Acta Geotechnica - Subsurface deformation due to long terms of groundwater drawdown from 1960 to 1997 and groundwater recovery from 1997 to 2016 in the upper part of the Bangkok multi-aquifer...