Assessment of cadmium contamination in the sediments of Changjiang （Yangtze） River by reflectance spectroscopy

The Takab area in NW of Iran is an important gold mineralized region with a long history of gold mining. In this study ASTER data is used to evaluate environmental effects of gold mining. The results show that mining activities have resulted in release of potentially toxic metals （PTMs） in the area. Principal component analysis （PCA） of ASTER data is used to map sources of PTMs and their secondary hosts （iron oxides） through alteration mapping. The results show that selective PCA is a robust yet time consuming technique for alteration mapping. A color composite is created for finding common hydrothermally altered rocks. The created color composite successfully mapped the known deposits and anomalous areas identified by geological survey of Iran. Because of the low spatial resolution of ASTER sensor, the iron oxide mapping is restricted to the wider portions of the streams. Spectral analyses confirm the presence of hematite and goethite in stream sediments. This is in accordance with measured pH values.     

Isotopic composition of dissolved boron and its geochemical behavior in a freshwater-seawater mixture at the estuary of the Changjiang （Yangtze） River

The isotopic composition of dissolved boron, in combination with the elemental concentrations of B, Cl and salinities in freshwater-seawater mixed samples taken from the estuary of the Changjiang River, the largest one in China, was investigated in detail in this study. Brackish water and seawater samples from the estuary of the Changjiang River were collected during low water season in November, 1998. Boron isotopic compositions were determined by the Cs2BO^＋2-graphite technique with a analytical uncertainty of 0.2‰ for NIST SRM 951 and an average analytical uncertainty of 0.8‰ for the samples. The isotopic compositions of boron, expressed in δ^11B, and boron concentrations in the Changjiang River at Nanjing and seawater from the open marine East Sea, China, are characterized by δ^11B values of -5.4‰ and 40.0‰, as well as 0.0272 and 4.43 mg B/L, respectively. Well-defined correlations between δ^11B values, B concentrations and Cl concentrations are interpreted in terms of binary mixing between fiver input water and East Sea seawater by a process of straightforward dilution. The offsets of δ^11B values are not related to the contents of clastic sediment and to the addition of boron. These relationships favor a conservative behavior of boron at the estuarine of the Changjiang River.     

Changes in nutrient uptake of phytoplankton under the interaction between sunlight and phosphate in the Changjiang （Yangtze） River Estuary

We conducted ship-board incubation experiments to investigate changes in nutrient uptake of phytoplankton under different phosphate concentrations and irradiances in the Changjiang River Estuary and its adjacent waters in China. Under 100% natural irradiance the uptake rates of phosphate, silicate, and nitrate were accelerated at high phosphate levels （1.84 μM）, while under low irradiance （about 50% natural irradiance） their uptake rates were restrained at the high but stimulated greatly at the intermediate phosphate concentrations （1.26 μM）, as the growth of phytoplankton, changes in nitrite and ammonium uptake didn＇t follow an obvious pattern. Our results also showed that there were linear relationships between nitrate, silicate and phosphate uptake at different phosphate concentrations under low and high irradiances, and the growth period of phytoplankton was prolonged both at the high phosphate concentrations under high irradiance and at the intermediate concentrations under low irradiance, suggesting that the limitation of phytoplankton growth mainly reflected changes in its growth period, and because no such environment （low irradiance and low phosphate concentrations） actually existed in a high turbidity zone, phytoplankton blooms hardly occurred there. In the absence of irradiance, denitrification occurred readily and phytoplankton was kept decreasing, which resulted in phosphate regeneration.     

Benthic nutrient fluxes in the intertidal flat within the Changjiang （Yangtze River） Estuary

In an annual cycle from March 2005 to February 2006, benthic nutrient fluxes were measured monthly in the Dongtan intertidal flat within the Changjiang （Yangtze River） Estuary. Except for NH4^＋, there always showed high fluxes from overlying water into sediment for other four nutrients. Sediments in the high and middle marshes, covered with halophyte and consisting of macrofauna, demonstrated more capabilities of assimilating nutrients from overlying water than the low marsh. Sampling seasons and nutrient concentrations in the overlying water could both exert significant effects on these fluxes. Additionally, according to the model provided by previous study, denitrification rates, that utilizing NO3- transported from overlying water （Dw） in Dongtan sediments, were estimated to be from -16 to 193 μmol·h^-1·m^-2 with an average value of 63 μmol·h^-1·m^-2 （n=18）. These estimated values are still underestimates of the in-situ rates owing to the lack of consideration of DN, i.e., denitrification supported by the local NO3^- production via nitrification.     

Water chemical behavior at Yangtze （Changjiang） River estuary

Geochemical cycling has received wide attention due to the need to understand the pathways of pollutants through our present environment. In this regard the Yangtze River plays a significant role in putting those pollutants into the East China SeafWorld Oceans. The Yangtze River is of high sedimentation rate and water discharge. The watershed covers variable climate regions from temperate to subtropical and from semiarid to humid. Twenty three （23） sampling locations at the estuary have been selected for understanding the dynamic relationships. The elements （Cl^-, SO4^2-, Na^＋, K^＋, and Ca^2＋） show conservative behavior during mixing of fresh water with saline water whereas Mg^2＋, Mn^2＋ show a non-conservative pattern . The relationships between Na^＋/SO4^2- and Cl^-/SO4^2- molar ratios show a mixing of more than two water sources.     

Variations and net transport of dissolved inorganic nutrients in the South Passage of the Changjiang （Yangtze River） Estuary

Dissolved inorganic nutrient elements were analyzed from the samples collected in the South Passage of the Changjiang (Yangtze River) Estuary in March 2003, including NH4 , NO3-, NO2- and PO43-. The water samples were collected with a Niskin sampler hourly at the near-surface, middle and near-bottom depths at the three stations -A1, A2 and A3-during two complete tidal cycles of neap tide and spring tide. Results showed that 1) the concentrations of NH4 , NO3- and NO2- were a little higher respectively during the neap tide than those during the spring tide, while PO43- showed an opposite trend, and each was higher in the ebb tide than in the flood tide, either for the neap tidal cycle or the spring tidal cycle; 2) higher stratification of the nutrients existed obviously in this area, with the concentrations of which increased from the bottom to the surface, especially for NH4 and NO3-; 3) the coefficient of variation (C.V.) values of all dissolved inorganic nutrients varied from 4.06% to 36.8% beyond different influences of the tidal current and Changjiang runoff; 4) with increasing suspended matter in the water column, the concentrations of PO43- became lower in the filtered water; and 5) the total transport of each tidal cycle was much more in the spring tide than in the neap tide, and the positive values indicated that the nutrients had been exported to the East China Sea. Studies on the variations and net transport of dissolved inorganic nutrients in the South Passage of the Changjiang Estuary will provide the scientific basis for the study of the mechanism of red tide in the East China Sea.     

Degeneration and countermeasures of water resources system of the Changjiang River Delta

Water resources system is composed of natural water subsystem and social water subsystem. And it is a complicated large system, which contains certain regional background, as well as specific framework, function and dynamic balance. The evaluation of the water resources system needs the viewpoint of sustainable development and the measurement according to water resources system carrying capacity, which holds the meaning of both water resources carrying capacity and water environment carrying capacity. The Changjiang River Delta is a very important area in China. As the local water resources are concerned, the Delta is an area lack of water as a matter of fact. The water resources system of the Delta experiences a long, intricate and degenerate period. The lack of water due to resources shortage in the 1950＇s was converted to that due to water quality from the 1980＇s. Furthermore, the status of water shortage sharpens gradually. The representations are summarized as follows： firstly, the discharge amount of wastewater and polluted water is large all along. Secondly, the pollution status of rivers, which involve the Changjiang River, the Grand Canal, the rivers in cities and the rivers in small towns and villages, is noticeable. Thirdly, water quality of Taihu Lake is worth of more attention. Therefore, the countermeasures on the reconditioning and regulating of water resources system in the Delta demands the following new strategies, such as to treat the rivers, the lakes and the seas as one overall system, to improve, harmonize and counterpoise water resources system carrying capacity, to implement the integrated management of water resources, which means the integrated management of drainage area along with the regional area, especially the integrated management of city water, and to carry on water saving and scientific use so as to increase the efficiency of water use, and so on.     

Seasonal variations of nitrogen, phosphorus and the nutrient characters in the shallow lakes along the middle and lower reaches of the Yangtze River

Lakes along the middle and lower reaches of the Yangtze River are unique shallow lake group faced with serious problems of eutrophication. In shallow lakes, there are strong interactions between surface sediment and overlying water, and the chemical, biological processes are complicated in the system. The mechanism of shallow lake eutrophication is still insufficient to instruct the harness practice. Water samples were collected quarterly in each lake center from 2000 to 2003. Chemical variables and ionic concentrations were measured in laboratory. This paper focused on the seasonal variations of NO2-N, NO3-N, NH4-N, DIP, chlorophyll a and TN ： TP ratios in 49 lakes along the middle and lower reaches of the Yangtze River. The cooperating mechanisms between N and P were investigated through the analysis of their relationships at different nutrient levels.     

Enrichment of Cd and Pb and associations with grain size in sediments in Nanjing alluvial island of Yangtze River

Intermittence belts of metal contaminated sediment have been formed along the urban riverside of the Yangtze River because of rapid urbanization and industrial development during the last three decades. Baguazhou Island, the third alluvial island in the lower reaches of the Yangtze River, was chosen to assess the contaminations level of Cd, Pb, Ni, Cr, Cu and Zn in suspended particulate matter （SPM）, recent sediments and sediment-derived soils. The relations between the metal concentrations and the grain size distributions in sediments were analyzed in order to explore the association of heavy metal settling with sediment deposition. The results showed that significantly high levels of Cd and Pb in SPM dominated enrichment factors （EFs） of recent sediments in the area of Baguazhou Island. High levels of Cd and Pb were found both in the riverine sediments and in the soils. However, the average levels of Cd and Pb in sediments were almost as twice as those in soil. About 43% of all sediment samples have EFCd≥1.5 and 14% with EFCd≥2. There are about 21% of the samples with EFPb≥1.5 and none of them has EFPb≥2. Meanwhile, soil samples with EFCd≥1.5 account for 39% of all 64 samples and no one with EFPb≥1.0. Most of the sediment samples contain more than 80% of fine grains lower than 60 μm in size, and few samples located in the site where flow eroding process dominates contain fine grains lower than 30%. Correlation analysis indicated that the concentrations of Cd and Pb in the sediments have significant relationships with grain size.     

Hydrogeochemistry of the Winder River and adjoining tributaries, Balochistan, Pakistan

Quantitative estimation of ground and stream waters draining through sedimentary rocks of the Pab and Mor ranges (Jurassic-Cretaceous) and the Bela ophiolite has been made. The degree of correspondence among cations and anions has been estimated in order to evaluate their mutual relationships. The abundance of major ions is interpreted to be related to bedrocks and climatic conditions, which may contribute to the genetic affiliation. The log TDS and Na/Na Ca ratio reflected supremacy of weathering of rocks with some influence of evaporation. Ionic relationship is exhibited in the form of Stiff diagrams. Patterns of ionic composition revealed high NaCl, medium Ca(HCO3)2 and low MgSO4. Piper diagram has been used to classify the hydrofacies. The important hydrogeochemical parameters have been estimated for assessment of groundwater quality for domestic purposes in accordance to WHO. Irrigation water qualities have been evaluated in terms of EC, SAR, RSC, ESP and pH.     

长江三角洲的形成和演变

文章从地质构造背景、泥沙来源、动力条件和海底坡度四个方面阐述了长江三角洲的形成条件：长江三角洲主体位于构造下沉区；塑造长江三角洲的泥沙主要来自长江，少量来自废黄河三角洲和钱塘江；长江口门地区的波浪、潮流及沿岸流的作用比较适中、海底坡度平缓，有利于三角洲的保存。文章进而对不同历史时期三角洲岸线的变迁做了描述。最后，文章对本世纪三峡工程等流域人类活动将导致的河流来沙锐减对三角洲演变的影响做了初步的展望。     

青藏高原东部长江流域盆地陆地化学风化研究

长江河水主要离子由流域盆地碳酸盐岩的风化所控制,沱沱河和楚玛尔河受蒸发盐岩影响较为明显;河水溶质载荷Si,Si/TZ *,Si/(Na* K)等指标表明,长江流域盆地地表硅酸盐岩风化还是浅表层次的;金沙江地表化学剥蚀速率为1.74×103mol/yr.km2,雅砻江为1.69×103mol/yr.km2,大渡河为1.57×103mol/yr.km2,岷江为1.88×103mol/yr.km2,长江河源区楚玛尔河为2.32×103mol/yr.km2,沱沱河为1.37×103mol/yr.km2,流域地表化学剥蚀速率可与世界上其它造山带的河流进行对比。     

黄河源区黄河袭夺长江水系之初探

对黄河源区的河流地貌研究表明,该区共发育三级阶地,其中第一、第二级阶地形成于晚更新世的末期至全新世,而第三级阶地形成于晚更新世晚期。在晚更新世晚期,多石峡被切开,黄河源区晚更新世湖泊消失,现今黄河形成。随着现今黄河的形成和晚更新世湖泊的消失,南岸支流之一的多曲向南溯源侵蚀加强,并穿越巴颜喀拉山,夺取了巴颜喀拉山南侧原属于长江流域的贝敏曲和洛曲,使分水岭向南推进了25km,袭夺的时间为晚更新世末期。     

长江干流颗粒有机碳及其同位素组成的季节性输送特征

2007年夏季和冬季对长江干流悬浮物进行了季节性采样,系统分析了悬浮物颗粒有机碳含量及稳定碳同位素的组成,研究了其空间分布以及季节变化特征。结果显示,长江干流夏季颗粒有机碳含量在0．4％～1．3％,冬季含量在0．7%-2．2％。冬季和夏季颗粒有机碳平均δ^13C值分别为-24．74‰和～24．83‰,季节性差异不大,在...     

基于FVCOM数值模拟和观察资料的长江冲淡水转向机制分析

应用FVCOM海洋模式,建立长江口附近海域海洋模型。通过径流、风场、潮汐、斜压和背景流场等不同环境因素下的数值模拟并结合"我国近海海洋综合调查与评价"专项长江口区域的调查资料进行分析,对长江冲淡水的扩展情况进行研究。数值实验再现了长江冲淡水在夏季的转向现象,通过实验对比分析发现长江冲淡水的转向主要是受风场控制,其中斜压效应、潮汐潮流、背景流场对冲淡水的转向影响不明显。长江径流和潮汐潮流只影响长江口附近的较小区域,背景流场本身比较稳定,对长江冲淡水扩展的季节变化影响不大,斜压效应在长江冲淡水转向过程中所起作用较小。