Effects of stem density upon sediment retention by salt marsh cord grass,Spartina alterniflora loisel

A laboratory experiment was conducted to determine whether retention of waterborne sand by salt marsh cordgrass, Spartina alterniflora Loisel, is directly related to the number of stems per unit area. Waves generated in a trough washed over a sloping beach planted with S. alterniflora sprigs: a range of stem densities (0–108 stems/m²) was examined in separate trials. The amount of sand accumulated after 60 waves is a positive nonlinear function of stem density. The greatest accretion coincided with the highest stem density tested. Shape of the beach profile was also strongly influenced by the number of stems per m².     

Responses of coastal lagoon plant communities to levels of nutrient enrichment: A mesocosm study

An experiment was conducted to quantify the effects of different levels of nutrient enrichment on the plant communities of temperate coastal lagoons, specifically the lagoons of the northeast U.S. Ten mesocosms, each containing coastal water, lagoon sediments, and plants and animals found in natural lagoons, were subjected to five levels of enrichment. Two mesocosms served as controls, and received no experimental nutrient additions. The remaining 8 mesocosms were enriched in duplicate with ammonium plus phosphate at 1.0 and 0.11 mmol N or P m^?2 d^?1, 2.0 and 0.19 mmol N or P m^?2 d^?1, 4.0 and 0.35 mmol N or P m^?2 d^?1, and 8.0 and 0.67 N or P mmol m^?2 d^?1. At all levels of enrichment, and through much of the experiment, water column concentrations of dissolved inorganic nitrogen (DIN) were drawn down to background levels. Despite the efficient drawdown of added DIN even at the highest loadings, differences in plant biomass among the 5 treatments were difficult to detect. Enrichment at the highest loadings increased standing stocks of phytoplankton for one month mid-experiment. No significant effect of loading could be detected for dry biomass of eelgrass (Zostera marina), epiphytic material, drift macroalgae, or for all plant components combined. The experiment has demonstrated that the enrichment responses of coastal lagoons can be diverse, especially at intermediate loadings.     

Chemical oxidation of N,N-diethyl-m-toluamide by sulfate radical-based oxidation: kinetics and mechanism of degradation

A study was undertaken in order to understand the kinetics and mechanism of the chemical oxidation of N,N-diethyl-m-toluamide, an insect repellent, by sulfate radical. In this experiment, sulfate radical was generated using peroxymonosulfate with iron(II) and cobalt(II) as activator. The second-order rate constant for the reaction of the sulfate radical with N,N-diethyl-m-toluamide was found to be (1.9 ± 0.1) × 10⁹ M^?1 s^?1 at pH 7 and a temperature of 25 °C. Experiments for the chemical oxidation of N,N-diethyl-m-toluamide in river water and secondary wastewater revealed that the percentage of the removal of N,N-diethyl-m-toluamide was slightly influenced by the water matrices. However, the selected oxidation systems are not effective for the removal of N,N-diethyl-m-toluamide in seawater. Transformation by-products of N,N-diethyl-m-toluamide generated using peroxymonosulfate/iron(II) sulfate, peroxymonosulfate/iron(II) chloride, peroxymonosulfate/cobalt(II) sulfate and peroxymonosulfate/cobalt(II) chloride systems were identified. The results indicated that there are slight differences in the distributions of the transformation by-products detected depending on the activator. The common transformation by-products detected in all selected oxidation systems are N,N-diethylbenzamide, N-ethyl-m-toluamide, N,N-dimethyl-m-toluamide, N-ethyl-N-acetyl-m-toluamide, 2-(diethylamino)-1-m-tolylethanone, monohydroxylated N-ethyl-m-toluamide, and dihydroxylated N,N-diethyl-m-toluamide. Monohydroxylated N,N-diethyl-m-toluamide were detected only when the peroxymonosulfate/iron(II) system was applied. For the peroxymonosulfate/cobalt(II) systems, additional isomers of monohydroxylated N-ethyl-m-toluamide were detected. Peroxymonosulfate/cobalt(II) also transformed 2-(diethylamino)-1-m-tolylethanone into N-ethyl-N-(2-oxo-2-m-tolylethyl)acetamide and monohydroxylated 2-(ethyl(vinyl)amino)-1-m-tolylethanone as transformation by-products.     

Burrow distributions and population estimates for the fiddler crabsUca spinicarpa andUca longisignalis in a Gulf of Mexico salt marsh

The distribution of fiddler crab (Uca spinicarpa andU. longisignalis) burrows in coastal marsh habitats is described, and the influence of substratum characteristics on the distributions of each is examined. Burrow densities were higher in vegetated areas than in sparsely vegetated and nonvegetated areas. Elevation and landward distance from shoreline (water's edge) also co-varied with burrow densities along transects. Burrow aperture diameters and burrow numbers m^?2 exhibited seasonal variations for both species ofUca. The depth of burrows increased with increased distance from the water's edge (approximate mean sea level) along transects into the marsh. A significant correlation between burrow aperture diameter and carapace width of the inhabitant enabled subsequent estimates of size and biomass in populations. Mean burrow densities forU. longisignalis ranged from a high of 182 m^?2 in September 1992 to a low of 26 m^?2 in May–June 1992. Mean burrow densities forU. spinicarpa ranged from a high of 46 m^?2 in March April 1993 to a low of 29 m^?2 in May–June 1992. Estimates of mean biomass ranged from 17.6 g AFDW m^?2 to 13.2 g AFDW m^?2 for aU. longisignalis-dominated site and from 6.5 g AFDW m^?2 to 4.9 g AFDW m^?2 for aU. spinicarpa dominated site. Field observations and laboratory soil-choice tests demonstrated that, in mixed populations,U. spinicarpa preferred to burrow in substrates of higher percent clay than didU. longisignalis.     

PG 1316+678: A young pre-cataclysmic binary with weak reflection effects

The PG 1316+678 star is classified as a pre-cataclysmic binary, as is evidenced by its photometric and spectroscopic observations. Its orbital period is determined to be P _orb = 3.3803^d, which coincides with the photometric period. The intensities of the emission HI and HeI lines are shown to vary synchronously with the brightness of the object (Δm _V = 0.065 ^m , Δm _R = 0.08 ^m ). These variations arise as the UV radiation from the DAO white dwarf is reflected from the surface of the cold companion. The parameters of the binary are estimated and the time of its evolution after the common-envelope phase is determined to be t ≈ 240 000 years. Thus, PG 1316+678 is a young pre-cataclysmic NN Ser variable with the smallest known photometric reflection effect.     

Effect of nitrogen addition on soil organic carbon in freshwater marsh of Northeast China

Increased nitrogen (N) input to ecosystems could alter soil organic carbon (C) dynamics, but the effect still remains uncertain. To better understand the effect of N addition on soil organic C in wetland ecosystems, a field experiment was conducted in a seasonally inundated freshwater marsh, the Sanjiang Plain, Northeast China. In this study, litter production, soil total organic C (TOC) concentration, microbial biomass C (MBC), organic C mineralization, metabolic quotient (qCO₂) and mineralization quotient (qmC) in 0–15 cm depth were investigated after four consecutive years of N addition at four rates (CK, 0 g N m^?2 year^?1; low, 6 g N m^?2 year^?1; moderate, 12 g N m^?2 year^?1; high, 24 g N m^?2 year^?1). Four-year N addition increased litter production, and decreased soil organic C mineralization. In addition, soil TOC concentration and MBC generally increased at low and moderate N addition levels, but declined at high N addition level, whereas soil qCO₂ and qmC showed a reverse trend. These results suggest that short-term N addition alters soil organic C dynamics in seasonally inundated freshwater marshes of Northeast China, and the effects vary with N fertilization rates.     

Clay mineral weathering and contaminant dynamics in a caustic aqueous system: II. Mineral transformation and microscale partitioning

Microscopic and spectroscopic studies were conducted to assess mineral transformation processes in aqueous suspensions of illite (Il), vermiculite (Vm) and montmorillonite (Mt) that were subjected to weathering in a simulated high-level radioactive tank waste leachate (0.05 m Al_T, 2 m Na⁺, 1 m NO₃⁻, pH ∼14, Cs⁺ and Sr²⁺ present as co-contaminants). Time series (0 to 369 d) experiments were conducted at 298 K, with initial [Cs]₀ and [Sr]₀ concentrations from 10⁻⁵ to 10⁻ mol kg⁻. Incongruent clay dissolution resulted in an accumulation of secondary aluminosilicate precipitates identified as nitrate-sodalite, nitrate-cancrinite and zeolite X, by molecular spectroscopy and electron microscopy (XRD, IR, NMR, SEM-EDS and TEM-EDS). Contaminant fate was dependent on competing uptake to parent clays and weathering products. TEM-EDS results indicated that high Il affinity for Cs was due to adsorption at frayed edge sites. The Il system also comprised Sr-rich aluminous precipitates after 369 d reaction time. In Mt systems, Cs and Sr were co-precipitated into increasingly recalcitrant spheroidal precipitates over the course of the experiment, whereas contaminant association with montmorillonite platelets was less prevalent. In contrast, Cs and Sr were found in association with weathered Vm particles despite the formation of spheroidal aluminosilicate precipitates that were comparable to those formed from Mt dissolution.     

The surface free energies of talc and pyrophyllite

The components of the interfacial surface tension of talc and pyrophyllite were determined by measuring the rate of the capillary rise of a number of liquids through thin, sedimented deposits of the powdered minerals. The rate of capillary rise of a liquid in a powder is related to the contact angle between the liquid and the solid by the Washburn equation. The contact angles thus derived were used to determine the apolar (Lifshitzvan der Waals) component, γ ^LW , and the polar, electronacceptor and electron-donor parameters, γ ^⊕ and γ ^? respectively, of the Lewis acid/base component of the total interfacial surface energy using the Young equation. The values of γ ^LW for talc and pyrophyllite (31.5 and 34.4 mJ/m²) are slightly smaller than for smectite clay minerals (e.g., the value for hectorite is 39.9 mJ/m²), the electron donor parameter values are roughly comparable for talc and pyrophyllite (γ ^⊕ = 2.4 and 1.7 mJ/m²) as are the values of the electron acceptor parameter (γ ^? = 2.7 and 3.2 mJ/m²). The well-known hydrophobicity of these two minerals is due to the remarkably small value (for silicate minerals) of γ ^?(γ^⊕ is normally small or zero for silicates and many other oxides). The small values of both γ ^⊕ and γ ^? mean that the Lewis acid/base interactions between talc or pyrophyllite and highly polar water molecules are very weak. In contrast, low-charge smectites, the minerals most similar chemically and structurally to talc and pyrophyllite, have much greater values of γ ^? (≥ 30 mJ/m²) and are hydrophyllic.     

Large-scale stochastic linear inversion using hierarchical matrices

Stochastic inverse modeling deals with the estimation of functions from sparse data, which is a problem with a nonunique solution, with the objective to evaluate best estimates, measures of uncertainty, and sets of solutions that are consistent with the data. As finer resolutions become desirable, the computational requirements increase dramatically when using conventional solvers. A method is developed in this paper to solve large-scale stochastic linear inverse problems, based on the hierarchical matrix (or ? ² matrix) approach. The proposed approach can also exploit the sparsity of the underlying measurement operator, which relates observations to unknowns. Conventional direct algorithms for solving large-scale linear inverse problems, using stochastic linear inversion techniques, typically scale as ??(n ² m+nm ²), where n is the number of measurements and m is the number of unknowns. We typically have n ? m. In contrast, the algorithm presented here scales as ??(n ² m), i.e., it scales linearly with the larger problem dimension m. The algorithm also allows quantification of uncertainty in the solution at a computational cost that also grows only linearly in the number of unknowns. The speedup gained is significant since the number of unknowns m is often large. The effectiveness of the algorithm is demonstrated by solving a realistic crosswell tomography problem by formulating it as a stochastic linear inverse problem. In the case of the crosswell tomography problem, the sparsity of the measurement operator allows us to further reduce the cost of our proposed algorithm from ??(n ² m) to $\mathcal {O}(n^{2} \sqrt {m} + nm)$ . The computational speedup gained by using the new algorithm makes it easier, among other things, to optimize the location of sources and receivers, by minimizing the mean square error of the estimation. Without this fast algorithm, this optimization would be computationally impractical using conventional methods.     

Secondary production within a seagrass bed (Zostera marina andRuppia maritima) in lower Chesapeake Bay

Monthly sampling of a 140-ha seagrass bed in the lower Chesapeake Bay, Virginia, revealed that 13 numerically and trophically important species, representing about 20% of the total community densities over the year-long study period, accounted for the production of ≈42 g dry wt m^?2 yr^?1. This estimate is likely conservative due to our assumptions on voltinism and fixed size at maturity regardless of season for the species studied. The isopodErichsonella attenuata accounted for 17.6 g dry wt m^?2 yr^?1 or 42% of the calculated total production, while the portunid decapodCallinectes sapidus and the amphipodGammarus mucronatus each accounted for 7.7 g dry wt m^?2 yr^?1. The 10 remaining species (4 peracarids, 4 molluscs, and 2 decapods) each produced less than 2 g dry wt m^?2 yr^?1. Total seagrass-associated secondary production was estimated to equal or exceed 200 g dry wt m^?2yr^?1. By applying this estimate to the entire 140-ha grassbed, we projected that, on average, 4.8 metric tons dry wt of invertebrate standing stock and 55.9 metric tons of invertebrate production occur over the year.     

Nitric oxide emissions from soils: a case study with temperate soils from Saxony, Germany

Nitrogen oxides (NO _x ) are involved in acid rain and ozone formation, as well as destruction. NO _x are climate-relevant trace gases in the atmosphere. Atmospheric NO _x originate from anthropogenic emissions (mainly combustion processes). NO from natural processes derives from thunderstorms and soil microbial processes. They may play a crucial role in soil?Catmosphere feedback processes. This study aims to investigate NO _x -emissions from soils under different land use, geographical and meteorological conditions. NO _x -emissions were quantified in both field and laboratory experiments with a closed static chamber. Disturbed soil samples have been used for laboratory experiments. A climate chamber was used to regulate soil temperature of the samples. Field experiments showed that NO-soil emissions strongly depend on soil temperature. NO-emissions from a soil under meadow showed significant daily variations, unlike soil below spruce forest. Peak emission values were 18???g NO?CN?m^?2?h^?1 above meadow and 1.3???g NO?CN?m^?2?h^?1 under forest canopy. In addition, NO-emissions of meadow and forest soil were studied in a climate chamber, enhanced by an additional experiment with agricultural soil. These experiments revealed strong exponential correlations of NO-emissions and soil temperature. Maximum values reached above 400???g NO?CN?m^?2?h^?1 from agricultural soils at soil temperatures above 50°C. This study shows that soil NO-emissions strongly depend on temperature, vegetation type and geographical position. Consequently, NO-emissions may have a positive feedback effect on climate change.     

Algal mat productivity: Comparisons in a salt marsh

This paper documents the role of salt marsh algal mats in the productivity of a southern California tidal wetland. The productivity of the mats, which are composed of filamentous bluegreen and green algae and diatoms, varies both temporally and spatially in relation to tidal inundation and overstory vegetation. The estimates of net primary productivity (NPP) were highest under the canopy ofJaumea carnosa (Less.) Gray (341 g C m^?2 yr^?1) at low elevation. Elsewhere, NPP appeared to be limited by low light (276 g C m^?2 yr^?1 underSpartina foliosa Trin.) and desiccation (185 g C m^?2 yr^?1 underBatis martima L. and 253 g C m^?2 yr^?1 underMonanthochloe littoralis Engelm). Algal NPP was from 0.8 to 1.4 times that of the vascular plant overstory NPP. It is hypothesized that the arid environment of southern California and resulting hypersaline soils reduce vascular plant cover, which leads to high algal productivity.     

Photometric properties of bars in galaxies

We have used surface photometry data for 100 barred galaxies to determine the UBVRIJHK surface brightnesses and color indices for the bars. Two peaks are observed in the distribution of the average bar B brightnesses: at 21.0^m/arcsec² and 22.2^m/arcsec², characteristic of late-and early-type galaxies, respectively. The average surface-brightness difference between the bar and the galaxy (within the 25.0^m/arcsec² isophote) increases from 1.1^m/arcsec² for SB0 galaxies to 2.3^m/arcsec² for SBc-IBm galaxies. In (U-B)₀-(B-V)₀, (B-V ₀-(V-R ₀, and (B-V)₀-(V-I)₀ two-color diagrams, for all morphological types, the bars are shifted leftward from normal color sequence for galaxies. This deviation is more pronounced for the outer than for the inner regions of the bars. Using evolutionary models, we show that this deviation is due to the scarcity of intermediate-age [(1–9)×10⁹ yrs] stars in bars. Possible origins for this anomalous composition of the stellar population are discussed.     

V1327 Aquilae: A New RR Lyrae variable with an extremely high radial velocity

We have carried out photometry and spectroscopy of the star V1327 Aql (R = 16 ^m ) as part of our program of observations of poorly studied cataclysmic variables using the 1.5-m optical Russian—Turkish telescope (RTT-150, Turkey) and the 6-m telescope of the Special Astrophysical Observatory of the Russian Academy of Sciences. After analyzing our photometry, we have re-classified the variable as an RR Lyrae star. Our BV R photometry during 10 nights reveals brightness variations with the period 12^h49^m, with the B, V, and R amplitudes being 1.36 ^m , 1.13 ^m , and 1.11 ^m , respectively. We derived the first estimates of the star’s atmospheric parameters from our moderate-resolution spectra: T _eff = 6280 K, log g = 3.3, [M/H] = ?1.05. The extremely high radial velocity of the star’s motion (V _R = ?470 km/s) and the star’s large distances to the Galactic center (13.1 kpc) and disk (4.2 kpc) testify to a probable extragalactic origin of this object.     

The reactivity of iron oxides towards reductive dissolution with ascorbic acid in a shallow sandy aquifer (Rømø, Denmark)

The pool of iron oxides, available in sediments for reductive dissolution, is usually estimated by wet chemical extraction methods. Such methods are basically empirically defined and calibrated against various synthetic iron oxides. However, in natural sediments, iron oxides are present as part of a complex mixture of iron oxides with variable crystallinity, clays and organics etc. Such a mixture is more accurately described by a reactive continuum covering a range from highly reactive iron oxides to non-reactive iron oxide. The reactivity of the pool of iron oxides in sediment can be determined by reductive dissolution in 10 mM ascorbic acid at pH 3. Parallel dissolution experiments in HCl at pH 3 reveal the release of Fe(II) by proton assisted dissolution. The difference in Fe(II)-release between the two experiments is attributed to reductive dissolution of iron oxides and can be quantified using the rate equation J/m₀ = k′(m/m₀)^γ, where J is the overall rate of dissolution (mol s⁻¹), m₀ the initial amount of iron oxide, k′ a rate constant (s⁻¹), m/m₀ the proportion of undissolved mineral and γ a parameter describing the change in reaction rate over time. In the Rømø aquifer, Denmark, the reduction of iron oxides is an important electron accepting process for organic matter degradation and is reflected by the steep increase in aqueous Fe²⁺ over depth. Sediment from the Rømø aquifer was used for reductive dissolution experiments with ascorbic acid. The rate parameters describing the reactivity of iron oxides in the sediment are in the range k′ = 7·10⁻⁶ to 1·10⁻³ s⁻¹ and γ = 1 to 2.4. These values are intermediate between a synthetic 2-line ferrihydrite and a goethite. The rate constant increases by two orders of magnitude over depth suggesting an increase in iron oxide reactivity with depth. This increase was not captured by traditional oxalate and dithionite extractions.     

Heat capacity and thermodynamic properties of andradite garnet,Ca3Fe2Si3O12, between 10 and 1000 K and revised values for ΔfGom (298.15 K) of hedenbergite and wollastonite

The heat capacity of synthetic andradite garnet (Ca₃Fe₂Si₃O₁₂) was measured between 9.6 and 365.5 K by cryogenic adiabatic calorimetry and from 340 to 990 K by differential scanning calorimetry. At 298.15 K C^o_p,m and S^o_m are 351.9 ± 0.7 and 316.4 ± 2.0 J/(mol·K), respectively.Andradite has a λ-peak in C^o_p,m with a maximum at 11.7 ± 0.2 K which is presumably associated with the antiferromagnetic ordering of the magnetic moments of the Fe³⁺ ions. The Gibbs free energy of formation, Δ_fG^o_m (298.15 K) of andradite is −5414.8 ± 5.5 kJ/mol and was obtained by combining our entropy and heat capacity data with the known breakdown of andradite to pseudowollastonite and hematite at ≈ 1410 to 1438 K. From a reexamination of the calcite + quartz = wollastonite equilibrium data we obtained Δ_fH^o_m (298.15 K) = − 1634.5 ± 1.8 kJ/mol for wollastonite.Between 300 and 1000 K the molar heat capacity of andradite can be represented by the equation C^o_p,m = 809.24 - 7.025 × 10−2T− 7.403 × 10³T−0.5 − 6.789 × 10⁵T−2. We have also used our thermochemical data for andradite to estimate the Gibbs free energy of formation of hedenbergite (CaFeSi₂O₆) for which we obtained Δ_fG^o_m (298.15 K) = −2674.3 ± 5.8 kJ/mol.     

Seasonal dynamics and production of the hydromedusan Clytia hemisphaerica (Hydromedusa: Leptomedusa) in Southampton water

In 1990 and 1991, a zooplankton sampling program revealed the presence of the hydromedusan Clytia hemisphaerica (Hydromedusa: Leptomedusa) from early May through late September throughout Southampton Water. The most notable aspects of the population dynamics of C. hemisphaerica in Southampton Water were the considerable interannual variation in peak abundance—10.65 m^?3 in 1990 and 2.44 m^?3 in 1991—and temporal patterns of mean bell diameter. The suggestion of almost continuous reproduction in 1990, as indicated by high abundance and large size range on each sampling date, is in contrast to 1991, where at the Cracknore site, five cohorts were produced at 21 d to 80 d intervals. The maximum bell diameter attained in each generation was typically 10–11 mm. At the Cracknore site in 1991, in situ bell diameter growth was linear within each cohort. A trend of increased growth rate with each subsequent cohort, from 26 μg DW d^?1 to 106 μg DW d^?1 was coincident with increasing water temperature. Annual production ranged from 0.98 mg C m^?3 yr^?1 to 1.08 mg C m^?3 yr^?1 in 1990 and 0.35 mg C m^?3 yr ^?1 to 0.48 mg C m^?3 yr^?1 in 1991. Daily P: B ratios varied in each cohort from 0.05 to 0.35.     

Characteristics of landslides in western Colorado,USA

Mass movement can be activated by earthquakes, rapid snowmelt, or intense rainstorms in conjunction with gravity. Whereas mass movement plays a major role in the evolution of a hillslope by modifying slope morphology and transporting material from the slope to the valley, it is also a potential natural hazard. Determining the relationships of frequency and magnitude of landslides are fundamental to understanding the role of landslides in the study of landscape evolution, hazard assessment, and determination of the rate of hillslope denudation. We mapped 735 shallow and active landslides in the Paonia to McClure Pass area of western Colorado from aerial photographs and field surveys. The study area covers ～815 km². The frequency–magnitude relationships of the landslides illustrate the flux of debris by mass movement in the area. The comparison of the probability density of the landslides with the double Pareto curve, defined by power scaling for negative slope (α), power scaling for positive slope (β), and location of rollover (t), shows that α?=?1.1, β?=?1.9, and t?=?1,600 m² for areas of landslides and α?=?1.15, β?=?1.8, and t?=?1,900 m³ for volumes of landslides. The total area of landslides is 4.8?×?10⁶ m² and the total volume of the landslides is 1.4?×?10⁷ m³. The areas (A) and the volumes (V) of landslides are related by V?=?0.0254?×?A ^1.45. The frequency–magnitude analysis shows that landslides with areas ranging in size from 1,600 to 20,000 m² are the most hazardous landslides in the study area. These landslides are the most frequent and also do a significant amount of geomorphic work. We also developed a conceptual model of hillslope development to upland plateau driven by river incision, shallow landsliding, and deep-seated large landsliding. The gentle slope to flat upland plateau that dominated the Quaternary landscape of the study area was modified to the present steep and rugged topography by the combined action of fluvial incision and glacial processes in response to rock uplift, very-frequent shallow landsliding, and less-frequent deep-seated landsliding.     

Zn and Pb solubility and speciation in aqueous chloride fluids at T-P parameters corresponding to granitoid magma degassing and crystallization

The solubility of all possible Zn and Pb species in aqueous chloride fluids was evaluated by means of thermodynamic simulations in systems ZnO(PbO)-aqueous solution of NaCl (KCl, NaCl + HCl) within broad ranges of temperature (600–900°C), pressure (0.7–5 kbar), and chloride concentrations, under parameters corresponding to the crystallization and degassing of granitoid magmas in the Earth’s crust. Our simulation results demonstrate that the addition of Cl to the fluid phase in the form of Na(K)Cl and HCl significantly increases the concentrations of Cl-bearing Zn and Pb complexes and the total concentration of the metals in the solutions in equilibrium with the solid oxides. In Zn-bearing fluids, the Zn(OH) ₂ ⁰ , ZnOH⁺, and Zn(OH) ₃ ^? —hydroxyl complexes and the ZnCl ₂ ⁰ , and ZnCl⁺ chlorocomplexes, which are predominant at low Cl concentrations (C_Cl < 0.05–0.1 m) give way to ZnCl ₄ ^2? with increasing C_Cl, which becomes the predominant Zn species of the fluid at C_Cl > 0.1–0.5 m throughout the whole temperature range in question and pressures higher than 1 kbar. For Pb-bearing fluids, the T-P-X region dominated by the Pb(OH) ₂ ⁰ , and Pb(OH) ₃ ^? hydroxyl complexes is remarkably wider than the analogous region for Zn, particularly at elevated temperatures (≥700°C) in alkaline solutions. An increase in C_Cl is associated with an increase in the concentration and changes in the speciation of Pb chlorocomplexes: PbCl ₂ ⁰ → PbCl ₃ ^? → PbCl ₄ ^2? . The concentrations of Zn and Pb chlorocomplexes increase with increasing pressure, decreasing temperature, and decrease pH with the addition of HCl to the system. It is demonstrated that the solubility of ZnO at any given T-P-X in alkaline solutions with low chloride concentrations are lower than the solubility of PbO. The Zn concentration increases more significantly than with the Pb concentration with increasing C_Cl and decreasing pH, so that the Zn concentration in acidic solutions is higher than the Pb concentration over broad ranges of temperature, pressure, and Cl concentration. Chloride complexes of Zn (ZnCl ₂ ⁰ , and ZnCl ₄ ^2? ) and Pb (PbCl ₂ ⁰ , and PbCl ₃ ^? are proved to be predominant within broad T-P-X-pH ranges corresponding to the parameters under which magmatic fluid are generated. Our simulation results confirm the hypothesis that chlorocomplexes play a leading role in Zn and Pb distribution between aqueous chloride fluids and granitic melts. These simulation results are consistent with experimental data on the Zn and Pb distribution coefficients (D(Zn)^f/m and D(Pb)^f/m, respectively) between aqueous chloride fluids and granitic melts that demonstrated that (1) D(Zn)^f/m and D(Pb)^f/m increase with increasing Na and K chloride concentrations in the aqueous fluid, (2) both D(Zn)^f/m and D(Pb)^f/m drastically increase when HCl is added to the fluid, and (3) (D(Zn)^f/m is higher than D(Pb)^f/m at any given T-P-X parameters. The experimentally established decrease in D(Zn)^f/m and D(Pb)^f/m with increasing pressure (at unchanging temperature and Cl concentration) is likely explained by an increase in the alkalinity of the aqueous chloride fluid in equilibrium with granite melt and, correspondingly, a decrease in the Zn and Pb solubility in this fluid.     

Performance of activated carbon-impregnated cellulose filters for indoor VOCs and dust control

An activated carbon-impregnated cellulose filter was fabricated, and the capacity to remove dust and volatile organic compounds was evaluated in a laboratory. The adsorption capacities for benzene, toluene, ethyl benzene and m-xylene gases were compared by an adsorption isotherm test conducted as a preliminary test, showing that m-xylene and benzene were the most and least favorable for adsorption onto activated carbon, respectively. Cellulose filters were made with four levels of activated carbon contents, and dust removal was performed with all of the filters showing 99 % and higher efficiencies stable with a small variation during the experiment. Activated carbon content of 5 g in the unit filter area (125 g/m²) was found optimum for benzene, toluene, ethylbenzene and m-xylene removal, as it appeared that higher than 5 g activated carbon content was unnecessary for the improvement of its capacity. With increasing benzene, toluene, ethylbenzene and m-xylene loading, the highest removal rates were determined as 0.33–0.37 mg/cm² s for as short as 0.0046 s of air filter residence time. The rapid removal was possible because of the high surface area of the activated carbon-impregnated cellulose filter provided by powdered activated carbon, which is distinguished from the granular form in conventional activated carbon towers. As fixed within a cellulose scaffolding structure, the powdered activated carbon performed excellent benzene, toluene, ethylbenzene, and m-xylene adsorption (98.9–100 %), and at the same time, particular matters were removed in average 99.7 % efficiency after being filtered through the cellulose filter sheet.