Analysis of the degree of contamination and evolution in the last 100 years of the composition of the bed sediments of the Anllóns Basin

In this study, five cores of the Anllóns River bed sediments were analyzed in order to evaluate the downcore and downstream variations in their chemical composition. The first step was the evaluation of the metal distribution in the bulk (<2 mm) and fine fractions (<63 μm). The analysis revealed that most of the metals followed the same trend in both fractions, although the fine fraction presented usually higher concentrations. However, the concentration of both fractions tended to equalize with increasing contamination. No general increase was observed in the metal concentrations toward the surface which could be attributed to recent anthropogenic contributions. Instead, the distributions were homogeneous or peaked at various depths downcore. The most important historical feature was observed at the mouth of the river, at 96-cm depth, corresponding to the end of the eighteenth century. Upcore increased metal concentrations in parallel with increased fine fraction occurred from this depth, which were attributed to a bridge construction and consequent changes in sediment dynamics. As the metal concentrations can be influenced by variations in texture or other sediment characteristics, the second step was to evaluate the efficiency of several normalized indexes in the assessment of the degree of contamination, by calculating the enrichment factor (EF), the geoaccumulation index (I _GEO) and the pollution load index (PLI). The EFs obtained were <10, thus revealing little anthropogenic inputs to the basin. The I _GEO produced higher values when compared with the EFs. Instead of absolute EF or I _GEO absolute values, the use of cumulative probability plots allowed identifying more accurately potential outliers indicating contamination. Only one population was identified for Zn and Pb, with a reduced number of outliers at the highest concentrations for Pb. As shown, a more complex plot with the outliers identified at C4 and C5. Finally, the PLI allowed determining the absence of a significant contamination in the bed sediments. The bioavailable and non-geogenic fractions contribute up to a 90% of the total concentrations in the case of As and Cu, and showed similar (dissimilar) profiles in comparison with total metals. Also, the quality guidelines were surpassed, so the high solubility of As, Zn, Pb and Ni in the sediments revealed the need to monitor the bed sediment quality of the Anllóns River.     

Dyke emplacement in the Narmada rift zone and implications for the evolution of Deccan Traps

正Dykes are primarily extensional fractures that form perpendicular to the minimum principal compressive stress,which have been extensively studied in the world during the past decades for various reasons including the     

Jurassic formation and Eocene subduction of the Zermatt–Saas-Fee ophiolites: implications for the geodynamic evolution of the Central and Western Alps

The Zermatt–Saas-Fee ophiolites (ZSFO) are one of the best preserved slices of eclogitic oceanic crust in the Alpine chain. They formed during the opening of the Mesozoic Tethys and underwent subduction to HP/UHP conditions during Alpine compression. A cathodoluminescence-based ion microprobe (SHRIMP) dating of different zircon domains from metagabbros and oceanic metasediments was carried out to constrain the timing of formation and subduction of this ophiolite, two fundamental questions in Alpine geodynamics. The formation of the ophiolitic sequence is constrained by the intrusion ages of the Mellichen and the Allalin metagabbros (164.0 ± 2.7 Ma and 163.5 ± 1.8 Ma) obtained on magmatic zircon domains. These data are in line with the maximum deposition age for Mn-rich metasediments which overlie the mafic rocks at Lago di Cignana (161 ± 11 Ma) and at Sparrenflue (ca. 153–154 Ma). An Eocene age of 44.1 ± 0.7 Ma was obtained for whole zircons and zircon rims from an UHP eclogite and two metasediments at Lago di Cignana. One of the Eocene zircons contains a rutile inclusion indicating formation at HP conditions. As the temperature and pressure peak of these rocks nearly coincide, the Eocene zircons probably constrain the age for the deepest subduction of the ZSFO. This Eocene age for the UHP metamorphism implies that the ZSFO were subducted later than the Adriatic margin (Sesia-Lanzo Zone) and before the Late Eocene subduction of the European continental crust below Apulia. A scenario with three subduction episodes propagating in time from SE to NW is proposed for the geological evolution of the Central and Western Alps. Received: 1 December 1997 / Accepted: 8 April 1998     

Generations of spreading basins and stages of breakdown of Wegener’s Pangea in the geodynamic evolution of the Arctic Ocean

Chronological succession in the formation of spreading basins is considered in the context of reconstruction of breakdown of Wegener’s Pangea and the development of the geodynamic system of the Arctic Ocean. This study made it possible to indentify three temporally and spatially isolated generations of spreading basins: Late Jurassic-Early Cretaceous, Late Cretaceous-Early Cenozoic, and Cenozoic. The first generation is determined by the formation, evolution, and extinction of the spreading center in the Canada Basin as a tectonic element of the Amerasia Basin. The second generation is connected to the development of the Labrador-Baffin-Makarov spreading branch that ceased to function in the Eocene. The third generation pertains to the formation of the spreading system of interrelated ultraslow Mohna, Knipovich, and Gakkel mid-ocean ridges that has functioned until now in the Norwegian-Greenland and Eurasia basins. The interpretation of the available geological and geophysical data shows that after the formation of the Canada Basin, the Arctic region escaped the geodynamic influence of the Paleopacific, characterized by spreading, subduction, formation of backarc basins, collision-related processes, etc. The origination of the Makarov Basin marks the onset of the oceanic regime characteristic of the North Atlantic (intercontinental rifting, slow and ultraslow spreading, separation of continental blocks (microcontinents), extinction of spreading centers of primary basins, spreading jumps, formation of young spreading ridges and centers, etc., are typical) along with retention of northward propagation of spreading systems both from the Pacific and Atlantic sides. The aforesaid indicates that the Arctic Ocean is in fact a hybrid basin or, in other words, a composite heterogeneous ocean in respect to its architectonics. The Arctic Ocean was formed as a result of spatial juxtaposition of two geodynamic systems different in age and geodynamic style: the Paleopacific system of the Canada Basin that finished its evolution in the Late Cretaceous and the North Atlantic system of the Makarov and Eurasia basins that came to take the place of the Paleopacific system. In contrast to traditional views, it has been suggested that asymmetry of the northern Norwegian-Greenland Basin is explained by two-stage development of this Atlantic segment with formation of primary and secondary spreading centers. The secondary spreading center of the Knipovich Ridge started to evolve approximately at the Oligocene-Miocene transition. This process resulted in the breaking off of the Hovgard continental block from the Barents Sea margin. Thus, the breakdown of Wegener’s Pangea and its Laurasian fragments with the formation of young spreading basins was a staged process that developed nearly from opposite sides. Before the Late Cretaceous (the first stage), the Pangea broke down from the side of Paleopacific to form the Canada Basin, an element of the Amerasia Basin (first phase of ocean formation). Since the Late Cretaceous, destructive pulses came from the side of the North Atlantic and resulted in the separation of Greenland from North America and the development of the Labrador-Baffin-Makarov spreading system (second phase of ocean formation). The Cenozoic was marked by the development of the second spreading branch and the formation of the Norwegian-Greenland and Eurasia oceanic basins (third phase of ocean formation). Spreading centers of this branch are functioning currently but at an extremely low rate.     

Proportions of massive-sulfide and strata-bound lead-zinc mineralization during the Earth’s evolution

Massive-sulfide base-metal deposits of the volcanic rock association and strata-bound Pb-Zn deposits in terrigenous and carbonate-terrigenous formations contain over 70% of the total world reserves of Pb and Zn. It has been found, based on an analysis of original databases on the corresponding mineral deposits found all over the world, that correlation in time and distribution in the Earth’s geological evolution of massive-sulfide deposits of the volcanic-rock association and lead-zinc deposits of the SEDEX type, as well as their reserves, was determined by changes in tectonic settings, by the evolution of the composition of the continental lithosphere, and by irreversible changes in the atmosphere, hydrosphere, and biosphere of the Earth.     

Structure and evolution of the Earth’s crust in the region of junction of the Central Asian Fold Belt and the Siberian Platform: Skovorodino–Tommot profile

An integrated geological and geophysical study was performed to investigate the region of junction of the eastern part of the Central Asian Fold Belt and the Siberian Platform in the Skovorodino–Tommot 3-DV reference profile line (52°–60° N, 122°–129° E), where the belt is separated from the Aldan–Stanovoi Shield of the Platform by a series of deep faults. The main results are as follows: Seismic, density, and geoelectric characteristics of rocks were obtained and used to determine (refine) the intracrustal boundaries of tectonic structures; large-block structure of the Earth’s crust, caused by mantle faults, and the difference between the layered structure of the crust for the shield and fold regions were established; and available paleomagnetic data were used to perform palinspastic reconstructions for 180 and 140 million years, the most productive metallogenic epoch in the region, coeval with collision processes at the closure of the Mongol-Okhotsk paleobasin.     

Structure of the Earth’s crust and tectonic evolution history of the Southern Indian Ocean (Antarctica)

The Southern Indian Ocean comprises large sedimentary basins of the Riiser-Larsen Sea (western sector); the Cosmonauts, Cooperation (Commonwealth), Davis seas (central sector); and the Mawson-d’Urville seas (eastern sector). The main tectonic provinces of the Southern Indian Ocean (Antarctica) have been outlined as a result of comprehensive interpretation of the geophysical data. Special attention is paid to determining the boundary between the rifted continental and oceanic crust. The basin of the Riiser-Larsen Sea was formed in the Early Jurassic under the action of the Karoo mantle plume. The intrusive complex, as a remote manifestation of the mantle plume, occurs along the inner boundary of the marginal rift. Opening of the ocean in the basin of Riiser-Larsen Sea started about 160 Ma ago and was characterized by rearrangement of plate motion and intense volcanic activity at the early stage. In the basin of the Cosmonauts, Cooperation, and Davis seas, the final stage of rifting was accompanied by the rise of the lithospheric mantle and by intrusive magmatism. The opening of the ocean started here 134 Ma ago. Emplacement of the Kerguelen plume resulted in jumping of ridges and detachment of continental crustal blocks from the Indian margin with the formation of the Kerguelen Plateau (microcontinent). The basin of the Mawson-d’Urville seas has evolved under conditions of long-term rifting since the Late Jurassic and is characterized by an extended zone of mantle unroofing. Breakup of the lithosphere between Australia and Antarctica developed asynchronously over a time interval of 95–65 Ma ago with propagation of MOR from the west eastward. The research was carried out using a great body of geophysical information (～140000 km of CDP seismic profiling, more than 250 stations of seismic refraction sounding, and more than 250000 km of magnetic and gravity profiles) obtained by expeditions from many countries over more than 30 years.     

From the Libyan border to the Nile – Neoproterozoic magmatism and basement evolution of southern Egypt

ABSTRACT

In southern Egypt, Neoproterozoic granitoids intrude the crust from Libya in the west to the Nile River in the east. Best exposed at Gebel Uweinat, Gebel Kamil, Bir Safsaf, Gebel El Asr and Gebel Umm Shaghir, these rocks represent the transition between the rejuvenated Archean to Paleoproterozoic crust of the east Saharan craton and the juvenile Neoproterozoic crust of the Arabian–Nubian Shield to the east. We present U-Pb zircon geochronology and whole rock geochemistry from 16 Neoproterozoic (c. 628–580 Ma) granitoids across southern Egypt which document the synchronous production of diverse compositions indicative of an intraplate or intracontinental tectonic setting. Our data better constrain the age relationships, petrogenesis, and Pan-African crustal growth associated with the amalgamation of Gondwana and contribute to understanding the crust-modifying processes that led to the development of the Saharan metacraton in the Ediacaran.     

Geologic stages of the Paleogene and Neogene evolution of the Arctic shelf in the Ob’ region (West Siberia)

The paper is concerned with the structure of the Arctic shelf sediments in the Ob’ region in the Paleogene and Neogene, sampled from boreholes drilled on the Yamal Peninsula, in the lower reaches of the Pur and Taz Rivers. The specifics of Paleogene marine sedimentation in the central and northern West Siberian Plain are studied. The effect of abiotic (tectonic) factors on the completeness of the geologic record is considered as well as the effect of recent (Oligocene-Neogene) tectonic processes on topography and sedimentation. The borehole sections are compared with the main seismic sections of the Kara Sea and Lomonosov Ridge.     

Kinematic analysis of Jurassic grabens of soulthern Turgai and the role of the Mesozoic stage in the evolution of the Karatau–Talas–Ferghana strike-slip fault,Southern Kazakhstan and Tian Shan

The Karatau–Talas–Ferghana Fault (KTF) extending for 1500 km from Turgai to western Tarim is one of the world’s largest intracontinental strike-slip faults. This paper overviews the evolution of the KTF, providing insight into its relatively poorly studied northern segment in the Karatau Range and Turgai, known as the Main Karatau Fault (MKF). The right-lateral strike-slip along the KTF developed during three stages in the late Permian–Triassic, Early–Middle Jurassic, and late Cenozoic. The total strike-slip decreases northward from 200 km in the Ferghana Range to 100 km in the Karatau Range and decreases to zero in southern Turgai. Kinematic analysis of Jurassic grabens compensating the strike-slip in southern Turgai shows that strike slip along the KTF in the Jurassic, previously regarded as insignificant, actually measures tens of kilometers and 50% of the total strike slip in the northern segment of this fault.     

Isotopic signatures of Paleoproterozoic granitoids from the southern São Francisco Craton and implications for the evolution of the Transamazonian Orogeny

The southern São Francisco Craton, northeastern Brazil, consists of an Archean block surrounded by a Paleoproterozoic belt related to the Transamazonian Orogeny (ca. 2.0 Ga). A calc-alkaline plutonic arc developed within the belt and the granitoid plutons comprise two distinct groups. One group displays Archean T_DM ages (3.07–2.62 Ga), ε_Nd(t) values between −11.0 and −3.8 and high initial ⁸⁷Sr/⁸⁶Sr values, and it consists mainly of peraluminous granites. T_DM ages for the other group are Paleoproterozoic (2.43–2.27 Ga), and ε_Nd(t) values range between −2.8 and +1.3; the plutons are metaluminous tonalites (trondhjemites) to granodiorites. The Transamazonian granitoids can be related to contrasting source-regions, from mantle- to crust-derived ones. A number of them are probably derived from mixing of Paleoproterozoic juvenile material and variable proportions of Archean crust material. Magmatism related to deep faulting, during the compressional stages of the Transamazonian Orogeny, is a plausible model for granitoid generation. The contribution of mantle-derived material to the granitoid sources supports the idea that a significant episode of new crust formation occurred during the Transamazonian Orogeny.     

The role of water resources in the evolution of the Israeli–Lebanese border

The current location of the border between Lebanon and Palestine, today's Israel, is a product of various competing forces. The Zionist Organization aspired to include the entire Galilee region up to the lower reaches of the Litani River (also known as the Kassimiyah River) within Palestine. The river itself was the desired northern border of the country. The Zionists supported their position by employing instrumental arguments that were largely related to the availability of water resources. On the other hand, residents of the upper Galilee, today's southern Lebanon, demanded that they be included with Lebanon. They used their trade links with Beirut, and cultural and familial ties with other parts of Lebanon to support their position. These instrumental and expressive arguments appear to have assisted in the demarcation of the border between Lebanon and Palestine. Currently, access to the water resources, not necessarily control over them, is likely to influence negotiations between Israel and Lebanon over the future of the Israeli-occupied security zone in southern Lebanon.     

On the origin and fluid content of some rare crustal xenoliths and their bearing on the structure and evolution of the crust beneath the Bakony–Balaton Highland Volcanic Field (W-Hungary)

Rarely occurring clinopyroxene-plagioclase bearing, felsic granulite and skarn xenoliths were studied from the mantle and crustal xenolith-bearing alkaline basaltic and pyroclastic localities of the Bakony–Balaton Highland Volcanic Field (W-Hungary). Geobarometry and geothermometry of the xenoliths made it possible to categorise them in three groups according to their depth of formation. The first group formed in the lower crust together with mafic and metasedimentary granulites. The second group represents magmatic intrusions of the middle crust, and the third one comprises contact metamorphic rocks of relatively shallow origin. The calculated pressure difference from the core and rim compositions of plagioclase and clinopyroxene as well as garnet breakdown reactions in some xenoliths show evidence for pressure decrease due to crustal thinning both in lower crustal and middle crustal xenoliths during formation of the Pannonian Basin. Fluid inclusion studies reveal the dominance of the CO₂-rich fluids in the whole crustal section in contrast with fluids found in mafic garnet-bearing xenoliths. Crustal stratigraphy was constructed for the periods prior to the extension and after the extension on the basis of geobarometry and geophysical data. On the basis of mineral stabilities and geothermo-barometry, we estimated that the pre-extensional thickness of the lower and upper crust may have been 27–34 and 26–28?km, respectively. Comparison of pre-extensional and present-day thickness of the lower and upper crust indicate that thinning affected both the lower and the upper portion of the crust but on a different scale. The calculated thinning factors are between 2.25 and 3.4 for the lower crust and 1.3–1.56 for the upper crust.     

The geotectonic characteristics and geodynamic evolution of the Red Sea Rift and its adjacent areasSCIEI北大核心CSCD

红海是地球上最年轻的大洋,其板块构造活动正处于威尔逊旋回的幼年期。红海南北两端分别连接着威尔逊旋回的胚胎期和终结期,即东非大裂谷和地中海。这一独特的地理位置和构造部位使其成为板块构造理论研究的圣地。本文通过对已有的地质、地球物理和地球化学资料进行综合分析,了解了红海地区的地形、重磁异常和沿脊的玄武岩地球化学组成等地质构造特征,探讨了红海裂谷的洋壳分布、地幔源区不均一性以及扩张演化历史等问题。红海地形中间深、南北两端浅,可以分为北、中北、中南、南等四段。重磁异常的条带主要出现在中南段,其他段不明显,因而限制了以往对红海扩张历史的认识。目前认为红海全段存在洋壳,红海两岸的沿岸悬崖是共轭扩张陆缘,呈向南开口的喇叭型扩张,而非对应红海岸线的梭子型。红海裂谷沿脊的地幔源区具有明显的不均一性,南段玄武岩显示E-MORB特征,表现为阿法尔地幔柱的影响。红海的发育经历了裂谷前火山作用(31~29Ma)、大陆张裂(29~13Ma)和洋底扩张(<13Ma)三个主要阶段。红海裂谷的形成演化与非洲大陆的裂解、阿法尔地幔柱的活动、新特提斯洋的闭合等密切相关,了解红海的地球动力学过程将为揭示区域大地构造演化以及板块运动规律提供依据。     

Petrology and P–T history of the Wutai amphibolites: implications for tectonic evolution of the Wutai Complex,China

The Wutai Complex represents the best preserved granite-greenstone terrane in the North China Craton. The complex comprises a sequence of metamorphosed ultramafic to felsic volcanic rocks, variably deformed granitoid rocks, along with lesser amounts of siliciclastic and carbonate rocks and banded iron formations. Petrological evidence from the Wutai amphibolites indicates four metamorphic evolutionary stages. The M₁ assemblage is composed of plagioclase+quartz+actinolite+chlorite+epidote+biotite+rutile, preserved as mineral inclusions in garnet porphyroblasts. The metamorphic conditions for this assemblage cannot be quantitatively estimated. The M₂ stage is represented by garnet porphyroblasts in a matrix of quartz, plagioclase, amphibole, biotite, rutile and ilmenite. P–T conditions for this assemblage have been estimated using the program Tweequ at 10–12 kbar and 600–650°C. The M₃ assemblage is shown by amphibole+plagioclase±ilmenite symplectic coronas around embayed garnets and yields P–T conditions of 6.0–7.0 kbar and 600–650°C. M₄ is represented by chlorite and epidote rimming garnet, chlorite rimming amphibole and epidote replacing plagioclase under greenschist-facies conditions of 400–500°C and relatively lower pressures. Taken together, the qualitative P–T estimates from M₁ and M₄ and the quantitative P–T estimates from M₂ and M₃ define a clockwise P–T path for the Wutai amphibolites.The estimated P–T path from the four stages suggests that the Wutai Complex underwent initial burial and crustal thickening (M₁+M₂), subsequent isothermal exhumation (M₃), and finally cooling and retrogression (M₄). This tectonothermal path, along with those of the Fuping and Hengshan complexes, which bound the southeast and northwest margins, respectively, of the Wutai Complex, is considered to record the early Paleoproterozoic collision between the eastern and western segments of the North China craton.