Sedimentological,modal analysis and geochemical studies of desert and coastal dunes,Altar Desert,NW Mexico

Sedimentological, compositional and geochemical determinations were carried out on 54 desert and coastal dune sand samples to study the provenance of desert and coastal dunes of the Altar Desert, Sonora, Mexico. Grain size distributions of the desert dune sands are influenced by the Colorado River Delta sediment supply and wind selectiveness. The desert dune sands are derived mainly from the quartz‐rich Colorado River Delta sediments and sedimentary lithics. The dune height does not exert a control over the grain size distributions of the desert dune sands. The quartz enrichment of the desert dune sands may be due to wind sorting, which concentrates more quartz grains, and to the aeolian activity, which has depleted the feldspar grains through subaerial collisions. The desert dune sands suffer from little chemical weathering and they are chemically homogeneous, with chemical alteration indices similar to those found in other deserts of the world. The desert sands have been more influenced by sedimentary and granitic sources. This is supported by the fact that Ba and Sr concentration values of the desert sands are within the range of the Ba and Sr concentration values of the Colorado River quartz‐rich sediments. The Sr values are also linked to the presence of Ca‐bearing minerals. The Zr values are linked to the sedimentary sources and heavy mineral content in the desert dunes. The Golfo de Santa Clara and Puerto Peñasco coastal dune sands are influenced by long shore drift, tidal and aeolian processes. Coarse grains are found on the flanks whereas fine grains are on the crest of the dunes. High tidal regimens, long shore drift and supply from Colorado Delta River sediments produce quartz‐rich sands on the beach that are subsequently transported into the coastal dunes. Outcrops of Quaternary sedimentary rocks and granitic sources increase the sedimentary and plutonic lithic content of the coastal dune sands. The chemical index of alteration (CIA) values for the desert and coastal dune sands indicate that both dune types are chemically homogeneous. The trace element values for the coastal dune sands are similar to those found for the desert dune sands. However, an increase in Sr content in the coastal dune sands may be due to more CaCO₃ of biogenic origin as compared to the desert dune sands. Correlations between the studied parameters show that the dune sands are controlled by sedimentary sources (e.g. Colorado River Delta sediments), since heavy minerals are present in low percentages in the dune sands, probably due to little heavy mineral content from the source sediment; grain sizes in the dune sands are coarser than those in which heavy minerals are found and/or the wind speed might not exert a potential entrainment effect on the heavy mineral fractions to be transported into the dune. A cluster analysis shows that the El Pinacate group is significantly different from the rest of the dune sands in terms of the grain‐size parameters due to longer transport of the sands and the long distance from the source sediment, whereas the Puerto Peñasco coastal dune sands are different from the rest of the groups in terms of their geochemistry, probably caused by their high CaCO₃ content and slight decrease in the CIA value. Copyright © 2006 John Wiley & Sons, Ltd.     

Downstream changes in quartz OSL sensitivity in modern river sand reflects sediment source variability: Case studies from Rocky Mountain and Andean rivers

OSL (optically stimulated luminescence) sensitivity of quartz has been shown to either (1) record downstream sediment transport related to increased number and duration of light exposure cycles or (2) be a function of source geology, presenting a potential tool to track sediment provenance. To test these competing models this study leverages a suite of modern river samples from an extensional basin system in the Rocky Mountains of western USA (Bear River) and a retroarc foreland basin system in the southern Central Andes of Argentina (Río San Juan) to understand the relationships among quartz luminescence sensitivity, sediment transport distance, and catchment lithologies. We compare our results with petrographic analysis of the river sand composition, and characterization of the lithology and morphometrics of the river catchments. Samples taken along the Bear River and its major tributaries in the Rocky Mountains show a progressive downstream decrease in quartz OSL sensitivity that records variation in sediment provenance and steady contribution of lower OSL sensitivity quartz recycled from Palaeozoic passive margin stratigraphy. Andean river sand samples from the Rio San Juan network exhibit pervasive low sensitivity quartz derived from Andean arc volcanic rocks and recycled Neogene foreland basin strata. These modern river sand data do not show increased sensitivity with transport distance and instead indicates that in these landscapes, quartz OSL sensitivity is an intrinsic property of the source rock. Our study shows that river sands primarily composed of older, recycled low-strained quartz derived from quartzite lithologies exhibit the highest quartz sensitivity values. Moderate quartz OSL sensitivity values are observed in rivers with young igneous quartz derived directly from the volcanic and intrusive rocks. Conversely, microcrystalline quartz in chert lithic grains or polycrystalline quartz found in composite metamorphic lithic grains record the lowest quartz OSL sensitivity values. Determining the controlling factors of quartz sensitivity in river sand provides a current baseline for resolving paleogeographic and paleodrainage histories in the sedimentary record and provides further understanding of how sediments are eroded, transported, and deposited in fluvial systems with diverse tectonic settings and geologic source rocks.     

Textural and compositional controls on modern beach and dune sands,New Zealand

Textural, compositional, physical and geophysical determinations were carried out on 111 beach and dune sand samples from two areas in New Zealand: the Kapiti–Foxton coast sourced by terranes of andesite and greywackes and the Farewell Spit–Wharariki coast sourced by a wide variety of Paleozoic terranes. Our aim is to understand how long‐shore drift, beach width and source rock control the sedimentological and petrographic characteristics of beach and dune sands. Furthermore, this study shows the usefulness of specific minerals (quartz, plagioclase with magnetite inclusions, monomineralic opaque grains) to interpret the physical processes (fluvial discharges, long‐shore currents, winds) that distribute beach and dune sands in narrow and wide coastal plains. This was done by means of direct (grain size and modal analyses) and indirect (specific gravity, magnetic/non‐magnetic separations M/NM, magnetic susceptibility measurements, hysteresis loops) methods. Results are compared with beach sands from Hawaii, Oregon, the Spanish Mediterranean, Elba Island and Southern California. Compositionally, the Kapiti–Foxton sands are similar to first‐order immature sands, which retain their fluvial signature. This results from the high discharge of rivers and the narrow beaches that control the composition of the Kapiti–Foxton sands. The abundance of feldspar with magnetite inclusions controls the specific gravity of the Kapiti–Foxton sands due to their low content of opaque minerals and coarse grain size. Magnetic susceptibility of the sands is related mainly to the abundance of feldspars with Fe oxides, volcanic lithics and free‐opaque minerals. The Farewell Spit–Wharariki sands are slightly more mature than the Kapiti–Foxton sands. The composition of the Farewell Spit–Wharariki sands does not reflect accurately their provenance due to the prevalence of long‐shore drift, waves, little river input and a wide beach. Low abundance of feldspar with magnetite inclusions and free opaque grains produces poor correlations between specific gravity (Sg) and Fe oxide bearing minerals. The small correlation between opaque grains and M/NM may be related to grain size. The magnetic susceptibility of Farewell Spit–Wharariki sands is low due to the low content of grains with magnetite inclusions. Hysteresis and isothermal remnant magnetization (IRM) agree with the magnetic susceptibility values. Copyright © 2006 John Wiley & Sons, Ltd.     

Paleoenvironmental interpretations of Quaternary reef deposits based on comparisons of 10 selected modern and fossil larger foraminifera from the Ryukyu Islands, Japan

Abstract A new method for reconstructing depositional environments of larger foraminifera‐bearing limestones is proposed. First, depth and spatial distributions of empty tests of 10 foraminiferal taxa in a 1–2 mm size fraction were examined using 32 surface sediment samples collected from depths shallower than 200 m, located to the west of Miyako Island, Ryukyu Islands, northwest Pacific. Distributional ranges of empty tests in the 1–2 mm size fraction appear to be more limited than those including other size fractions in previous reports, partly because larger empty tests of each taxon are less easily transported than smaller ones. Multivariate analyses (Q‐mode cluster analysis and non‐metric multidimensional scaling ordination) based on binary (presence/absence) data of the 10 taxa delineate four sample groups, each of which corresponds to different depositional environments: nearshore zone/bay inlet; back‐reef to fore‐reef; outer shelf to shelf slope; and shelf slope distant from coral reefs. Next, these modern data were applied to reconstruct the depositional environment of a rock section distributed in the Shiratorizaki area (Irabu Island, Ryukyu Islands), which consists of larger foraminiferal limestone of the Pleistocene Ryukyu Group. Multivariate analyses were performed on the fossil plus the modern foraminiferal data to explore the possible relationship of the fossil associations with variations in modern associations, demonstrating that the fossil foraminiferal associations resemble the modern outer shelf associations. The modern analog technique was also applied to estimate paleobathymetry using fossil foraminiferal data. The results indicate that the section studied was deposited in outer shelf environments at depths between 53.5 and 98.6 m. These paleoenvironmental interpretations are consistent with previous studies based on sedimentary facies and the computer‐based expert system. The modern dataset and methods used in our work would be particularly useful for paleoenvironmental reconstructions of Quaternary reef and shelf carbonates along active margins of the northwest Pacific.     

The proximal marine record of Somma–Vesuvius volcanic activity in the Naples and Salerno bays,Eastern Tyrrhenian Sea,during the last 3 kyrs

The tephrostratigraphic analysis of nine gravity cores acquired on the continental shelf of the Naples and Salerno bays documents the proximal record of Somma–Vesuvius volcanic activity during the latest Holocene (last 3 kyrs). Five tephra layers from southern Naples Bay and three tephra layers from northern Salerno Bay were recognised in cores and their sedimentologic structures, textural parameters, stratigraphy and major and trace-element composition described.     

Spectral and petrologic analyses of basaltic sands in Ka'u Desert (Hawaii) – implications for the dark dunes on Mars

Dark aeolian deposits on Mars are thought to consist of volcanic materials due to their mineral assemblages, which are common to basalts. However, the sediment source is still debated. Basaltic dunes on Earth are promising analogs for providing further insights into the assumed basaltic sand dunes on Mars. In our study we characterize basaltic dunes from the Ka'u Desert in Hawaii using optical microscopes, electron microprobe, and spectral analyses. We compare the spectra of terrestrial and Martian dune sands to determine possible origins of the Martian dark sediments. Our results show that the terrestrial sands consist primarily of medium to coarse sand‐sized volcanic glass and rock fragments as well as olivine, pyroxene, and plagioclase minerals. Grain shapes range from angular to subrounded. The sample composition indicates that the material was derived from phreatomagmatic eruptions partially with additional proportions of rock fragments from local lava flows. Grain shape and size indicate the materials were transported by aeolian processes rather than by fluvial processes. Spectral analyses reveal an initial hydration of all terrestrial samples. A spectral mineralogical correlation between the terrestrial and Martian aeolian sands shows a similarity consistent with an origin from volcanic ash and lava. We suggest that the Martian deposits may contain similar abundances of volcanic glass, which has not yet been distinguished in Martian spectral data. Copyright © 2011 John Wiley & Sons, Ltd.     

Mechanical compaction and ultrasonic velocity of sands with different texture and mineralogical composition

This study presents the results of experimental compaction while measuring ultrasonic velocities of sands with different grain size, shape, sorting and mineralogy. Uniaxial mechanical compaction tests up to a maximum of 50 MPa effective stress were performed on 29 dry sand aggregates derived from eight different sands to measure the rock properties. A good agreement was found between the Gassmann saturated bulk moduli of dry and brine saturated tests of selected sands. Sand samples with poor sorting showed low initial porosity while sands with high grain angularity had high initial porosity. The sand compaction tests showed that at a given stress well‐sorted, coarse‐grained sands were more compressible and had higher velocities (Vp and Vs) than fine‐grained sands when the mineralogy was similar. This can be attributed to grain crushing, where coarser grains lead to high compressibility and large grain‐to‐grain contact areas result in high velocities. At medium to high stresses the angular coarse to medium grained sands (both sorted sands and un‐sorted whole sands) showed high compaction and velocities (Vp and Vs). The small grain‐to‐grain contact areas promote higher deformation at grain contacts, more crushing and increased porosity loss resulting in high velocities. Compaction and velocities (Vp and Vs) increased with decreasing sorting in sands. However, at the same porosity, the velocities in whole sands were slightly lower than in the well‐sorted sands indicating the presence of loose smaller grains in‐between the framework grains. Quartz‐poor sands (containing less than 55% quartz) showed higher velocities (Vp and Vs) compared to that of quartz‐rich sands. This could be the result of sintering and enlargement of grain contacts of ductile mineral grains in the quartz‐poor sands increasing the effective bulk and shear stiffness. Tests both from wet measurements and Gassmann brine substitution showed a decreasing Vp/Vs ratio with increasing effective stress. The quartz‐rich sands separated out towards the higher side of the Vp/Vs range. The Gassmann brine substituted Vp and Vs plotted against effective stress provide a measure of the expected velocity range to be found in these and similar sands during mechanical compaction. Deviations of actual well log data from experimental data may indicate uplift, the presence of hydrocarbon, overpressure and/or cementation. Data from this study may help to model velocity‐depth trends and to improve the characterization of reservoir sands from well log data in a low temperature (<80–100^o C) zone where compaction of sands is mostly mechanical.     

南极洲东部普里兹湾海域重磁场特征及地壳结构

普里兹湾位于南极洲东部大陆边缘,其深部地壳结构特征对认识白垩纪冈瓦纳古陆裂解和新生代大陆边缘形成具有重要意义.本文利用重磁、多道反射地震、声纳浮标折射地震和ODP钻井数据对普里兹湾海域的深部地壳结构进行了研究.研究结果显示,普里兹凹陷表现为典型的盆地负重力异常特征,其沉积基底较深,而在四夫人浅滩为高幅重力正异常,其沉积基底普遍抬升.在大陆架中部存在SW-NE向条带状基底的抬升,且呈朝NE向逐渐变深的趋势.在中大陆架外侧,均衡残余重力异常呈V字形负异常条带状分布,其两翼分别与四夫人浅滩和弗拉姆浅滩外的大陆坡相连.该异常带在大陆架中部向陆的偏移可能是由于古大陆架边缘的地形影响,推测其与普里兹冲积扇同属于洋陆过渡带向陆的部分,在重力模拟剖面表现为地壳向海逐渐减薄.普里兹冲积扇的地壳厚度较薄,平均为6 km,最薄处可达4.6 km,并且根据洋陆过渡带向海端的位置,推测可能属于接近洋壳厚度的过渡壳.重力异常分区的走向与兰伯特地堑在普里兹湾的构造走向基本一致,可能主要反映了二叠纪-三叠纪超级地幔柱对普里兹湾的裂谷作用的影响.该区域的自由空间重力异常和均衡残余异常均表现为超过100×10^-5m/s²的高幅正异常特征,可能由位于大陆架边缘的巨厚沉积体负载在高强度岩石圈之上的区域挠曲均衡作用所导致,可能与该区域第二期裂谷期之后的沉积间断以及快速进积加厚的演化过程有关.普里兹湾磁力异常的走向与重力异常明显不同,大致可分为东北高幅正异常区和西南低幅异常区.重磁异常在走向上的差异反映高磁异常主要来源于岩浆作用形成的铁镁质火成岩的影响,并且岩浆作用的时代不同于基底隆升的时代,而可能形成于前寒武纪或者南极洲和印度板块裂谷期间(白垩纪).     

Pseudotachylytes from the Koktokay-Ertai fault zone, Xinjiang, China, and their seismogeologic implications

Multi-period of pseudotachylytes of variable occurrences and shapes are widely outcropped in Haizikou and Mukurasen sections of the Koktokay-Ertai fault zone. They consist of clasts and matrix. The clasts comprise fine fragments of the host rock (mylonite) and quartz grains, while the matrix consists of cryptocrystalline and glassy materials which contain fibrous and radial microlites. The chemical compositions of the pseudotachylytes resemble those of the host rocks. Their features indicate that the pseudotachylytes were formed from local melting of the mylonites during the rapid movement of the fault, and that the formation depth was 10—12 km. The geologic event that produced pseudotachylytes is believed to be paleoearthquake. Project supported by the Joint Earthquake Science Foundation.     

A distribution‐free statistical method for the spatial characterization of dune granulometry: an example from the Strzelecki Desert,South Australia

Distribution‐free statistical methods of comparative data analysis have identi?ed subtle granulometric differences attributed to the evolution of barchan form at Gurra‐Gurra waterhole. Geomorphic locations on the barchan dunes display statistically signi?cant grain‐size differences that assist in the interpretation of aeolian processes. In summer, very ?ne sands mantle the dunescape and are the fraction that most affects the parameters of sorting and skewness. The sur?cial sedimentological character is one of subtle contrasts between the processes of grain winnowing and intergranular protection. The second and third moment measures are parameters that best demonstrate the spatial granulometric differences. Dune‐forming processes at Gurra‐Gurra have produced dune sands that have a very narrow range of grain size, which, in turn, re?ects textural and mineralogical maturity, and hence an extensive transport history. The statistical techniques employed in this study can also be used for the comparison of temporal (seasonal) sedimentological change, and for the granulometric analysis and association of process for dunes of different morpho‐types. Copyright © 2004 John Wiley & Sons, Ltd.     

Petrographic study of the Miocene Mizunami Group,Central Japan: Detection of unrecognized volcanic activity in the Setouchi Province

A petrographic study of sandstones from the Miocene Mizunami Group in Central Japan has been performed on core samples from a single borehole, in order to evaluate the provenance of the sedimentary rock. Evaluation of the provenance is based on bulk mineral, heavy mineral and plagioclase contents and on whole rock chemical compositions. The sandstones studied are divisible into three types; the first type is characterized by the occurrence of biotite and plagioclase ranging from albite to oligoclase, the second type is characterized by the dominance of amphibole and labradorite with pyroxene (clinopyroxene > orthopyroxene), and the third type is characterized by the dominance of pyroxene (orthopyroxene > clinopyroxene) and andesine with lesser labradorite, bytownite and anorthite. The first type is interpreted to be derived from the basement granite, whereas the others were derived mostly from volcanic ash, judging from their mineral compositions. The volcanic activity that supplied the volcanic ash to the Mizunami Basin occurred in two phases, distinguishable by variations in their mineralogical and geochemical compositions, an indication of change in character of the volcanic activity. This petrographic study of the sandstones in the Mizunami Group suggests that unrecognized volcanic activity occurred around the Mizunami Basin, even though potential provenance of the volcanic ash has not yet been identified.     

Hydrothermal alteration and tectonic evolution of an intermediate- to fast-spreading back-arc oceanic crust: Late Ordovician Solund-Stavfjord ophiolite, western Norway

Abstract The Solund‐Stavfjord ophiolite complex (SSOC) in western Norway represents a remnant of the Late Ordovician oceanic lithosphere, which developed in an intermediate‐ to fast‐spreading Caledonian back‐arc basin. The internal architecture and magmatic features of its crustal component suggest that the SSOC has a complex, multistage sea floor spreading history in a supra‐subduction zone environment. The youngest crustal section associated with the propagating rift tectonics consists of a relatively complete ophiolite pseudostratigraphy, including basaltic volcanic rocks, a transition zone between the sheeted dyke complex and the extrusive sequence, sheeted dykes, and high‐level isotropic gabbros. Large‐scale variations in major and trace element distributions indicate significant remobilization far beyond that which would result from magmatic processes, as a result of the hydrothermal alteration of crustal rocks. Whereas K₂O is strongly enriched in volcanic rocks of the extrusive sequence, Cu and Zn show the largest enrichment in the dyke complex near the dyke–volcanic transition zone or within this transition zone. The δ¹⁸O values of the whole‐rock samples show a general depletion structurally downwards in the ophiolite, with the largest and smallest variations observed in volcanic rocks and the transition zone, respectively. δ¹⁸O values of epidote–quartz mineral pairs indicate 260–290°C for volcanic rocks, 420°C for the transition zone, 280–345°C for the sheeted dyke complex and 290–475°C for the gabbros. The ⁸⁷Sr/⁸⁶Sr isotope ratios show the widest range and highest values in the extrusive rocks (0.70316–0.70495), and generally the lowest values and the narrowest range in the sheeted dyke complex (0.70338–0.70377). The minimum water/rock ratios calculated show the largest variations in volcanic rocks and gabbros (approximately 0–14), and generally the lowest values and range in the sheeted dyke complex (approximately 1–3). The δD values of epidote (?1 to ?12‰), together with the δ¹⁸O calculated for Ordovician seawater, are similar to those of present‐day seawater. Volcanic rocks experienced both cold and warm water circulation, resulting in the observed K₂O‐enrichment and the largest scatter in the δ¹⁸O values. As a result of metal leaching in the hot reaction zone above a magma chamber, Zn is strongly depleted in the gabbros but enriched in the sheeted dyke complex because of precipitation from upwelling of discharged hydrothermal fluids. The present study demonstrates that the near intact effect of ocean floor hydrothermal activity is preserved in the upper part of the SSOC crust, despite the influence of regional lower greenschist facies metamorphism.     

Mineral chemistry and geothermobarometry of Moshirabad pluton,Qorveh, Kurdistan,western Iran

The Moshirabad pluton is located southwest of the Sanandaj–Sirjan Metamorphic Belt, Qorveh, western Iran. The pluton is composed of diorite, monzodiorite, quartz diorite, quartz monzodiorite, tonalite, granodiorite, granite, aplite, and pegmatite. In this study 31 samples from various rocks were chosen for whole‐rock analyses and 15 samples from different lithologies were chosen for mineral chemical studies. The compositions of minerals are used to describe the nature of magma and estimate the pressure and temperature at which the Moshirabad pluton was emplaced. Feldspar compositions are near the binary systems in which plagioclase compositions range from An₅ to An₅₃ and alkali‐feldspar compositions range from Or₉₁ to Or₉₇. Mafic minerals in the plutonic rocks are biotite and hornblende. Based on the composition of biotites and whole‐rock chemistry, the Moshirabad pluton formed from a calc‐alkaline magma. Amphiboles are calcic amphiboles (magnesio‐hornblende or edenite). Temperatures of crystallization, calculated with the hornblende–plagioclase thermometer, range 550–750°C. These temperatures indicate that plutonic rocks have undergone some retrogressive changes in their mineral compositions. Aluminum‐in‐hornblende geobarometry indicates that the Moshirabad pluton was emplaced at pressures of 2.3–6.0 kbar, equal to depths of 7–20 km, but with consideration of regional geology, lower pressures than the above pressure range are more probable. Alteration of amphiboles can be the reason for some overestimation of pressures.     

Grain-size dependence of sediment composition and environmental bias in provenance studies

This article investigates both experimentally and theoretically the compositional changes associated with textural effects and hydraulic sorting during sediment transport and deposition, which cause systematic distortion in quantitative provenance analysis (“environmental bias”). Traditional procedures aimed at eliminating textural noise find limited success. The Gazzi–Dickinson method cannot remove hydrodynamic-related modal variability. Multiple size-window strategies are time-consuming. Narrow or moving size-window strategies represent misleading or impractical short cuts, being less convenient options than simply analysing each sample in bulk. New concepts introduced here unravel the superposed causes of compositional variability in modern sediments. Intrasample modal variability, fundamentally explained by settling-equivalence relationships, can be accurately modelled mathematically. Intersample modal variability, principally resulting from selective entrainment, can be assessed and removed by a simple principle. In absence of provenance changes and environmental bias, the weighted average density of terrigenous grains (SRD index) should be equal, for each sample and each grain-size class of each sample, to the weighted average density of source rocks. By correcting relative abundances of detrital minerals in proportion to their densities, we can restore the appropriate SRD index for any provenance and subprovenance type in each sample or grain-size class. Modal variability is effectively reduced by this procedure, which can be applied confidently to modern sediments deposited by tractive currents in any environment. Good results are obtained even for placer sands and finest classes where heavy-mineral concentration is strongest. Such “SRD correction” also successfully compensates for biased narrow-window modes, thus providing a numerical solution of general validity to the problem of environmental bias in sedimentary petrology. After compensating for settling-equivalence and selective-entrainment effects, residual size-dependent compositional variability may be provenance-related. Minor in Ganga–Brahmaputra sediments, provenance-related effects are spectacularly displayed in the Nile basin, where volcaniclastic silt mixes with basement-derived quartzofeldspathic sand and wind-blown Saharan quartz.     

Petrotectonic setting of the provenance of Lower Siwalik sandstones of the Himalayan foreland basin,southeastern Kumaun Himalaya,India

Detailed petrography and modal analysis of 35 sandstone thin sections was carried out to determine petrotectonic setting of the provenance of the Lower Siwalik molasse of southeastern Kumaun Himalaya. The sandstones are fine‐ to coarse‐grained (0.14–0.63 mm), poorly‐ to moderately‐sorted and comprise lithic arenites, sublithic arenites and lithic greywackes. The sandstones invariably belong to the quartzolithic QtFL (Qt, total quartz; F, feldspar; L, lithic grains) and QmFLt (Qm, monocrystalline quartz; Lt, lithic grains plus polycrystalline quartz) petrofacies, and indicate their derivation from a quartzose‐ and transitional‐recycled orogen provenance under sub‐humid climatic conditions. The framework composition of the sandstones comprises abundant monocrystalline and polycrystalline quartz and low‐ to high‐grade metamorphic rock fragments, along with subordinate feldspar, characterized by low ratios of plagioclase to total feldspar, and accessory minerals. The framework composition and petrofacies characters of these texturally submature sandstones suggest their derivation mainly from the nearby located Great Himalaya terrane and subordinately from the Tethys and Lesser Himalayan terranes. A comparison of the data presented here with the previous similar data from Lower Siwalik of northwestern Pakistan, northwestern India, south‐central Kumaun, western Nepal and southeastern Nepal reveals that like the Lower Siwalik rivers in other sections, the Lower Siwalik rivers of the southeastern Kumaun too drained large parts of the Great Himalayan terrane and some parts of the Tethys and Lesser Himalayan terranes.     

Oxygen isotope evidence for submarine hydrothermal alteration of the Del Puerto ophiolite, California

The oxygen isotope compositions and metamorphic mineral assemblages of hydrothermally altered rocks from the Del Puerto ophiolite and overlying volcaniclastic sedimentary rocks at the base of the Great Valley sequence indicate that their alteration occurred in a submarine hydrothermal system. Whole rock δ¹⁸O compositions decrease progressively down section (with increasing metamorphic grade): +22.4‰ (SMOW) to +13.8 for zeolite-bearing volcaniclastic sedimentary rocks overlying the ophiolite; +19.6 to +11.6 for pumpellyite-bearing metavolcanic rocks in the upper part of the ophiolite's volcanic member; +12.3 to +8.1 for epidote-bearing metavolcanic rocks in the lower part of the volcanic member; +8.5 to +5.7 for greenschist facies rocks from the ophiolite's plutonic member; +7.6 to +5.8 for amphibolite facies or unmetamorphosed rocks from the plutonic member.

Modelling of fluid-rock interaction in the Del Puerto ophiolite indicates that the observed pattern of upward enrichment in whole rock δ¹⁸O can be best explained by isotopic exchange with discharging¹⁸O-shifted seawater at fluid/rock mass ratios near 2 and temperatures below 500°C.¹⁸O-depleted plutonic rocks necessarily produced during hydrothermal circulation were later removed as a result of tectonism. Submarine weathering and later burial metamorphism at the base of the Great Valley sequence cannot by itself have produced the zonation of hydrothermal minerals and the corresponding variations in oxygen isotope compositions. The pervasive zeolite and prehnite-pumpellyite facies mineral assemblages found in the Del Puerto ophiolite may reflect its origin near an island arc rather than deep ocean spreading center.     

Lithic fragments in the Bandelier Tuff, Jemez Mountains, New Mexico

Lithic fragments are a highly varied but significant component of the Bandelier Tuff, Jemez Mountains, New Mexico. Lithic material occurs in concentrations from trace amounts to 30 wt.%, and within the Otowi Member of the tuff has a total volume of 10 km³. Approximately 90% of the fragments are Cenozoic volcanic rocks of the Jemez volcanic field, 10% are Paleozoic sedimentary rocks, and only trace amounts are Precambrian basement. The large volume of lithic material and predominance of shallowly derived fragments requires substantial flaring of the vent near the surface. The cooling effect of ≥ 10 wt.% lithic fragments was sufficient to inhibit welding of the tuff.Many of the basement fragments appear to have been derived from a contact metamorphic zone surrounding the magma chamber. This zone is characterized by shearing and recrystallization, by development of veins of actinolite, augite, and epidote, and by alteration of hornblende to F-rich biotite. Water and fluorine involved in the alteration may have come from the magma chamber.     

Silicate-metallic spherules and the problem of the ignimbrite eruption mechanism: The Yakutinskaya volcanic depression

In the course of detailed mineralogical, geochemical, and petrological studies of volcanic rocks in the Yakutinskaya volcanic depression of the Eastern Sikhote-Alin volcanic belt (Primorye) silicate-metallic formations (small balls) were found to occur widely. This suggests a new approach to the evaluation of the mechanism that is responsible for the formation of specific large-volume ??hot?? explosions. The metallic nuclei (whose compositions vary from low-carbon cast iron to cohenite) are surrounded by symplectite, which consists of quartz, magnetite, and siliceous-potassic glass (without Na); thus, the entire formation can be considered as a siliceous-metallic spherule. Based on analyses of the gas phase, the spherules consist of hydrogen and methane. The calculation of oxidation reactions that involve these gases shows that the process entails a significant decrease of volume and heat release. This suggests that the mechanism of ??hot?? ignimbrite explosions consists of the collapse of the roof of the magma chamber into the explosion zone and the formation of a collapse caldera with the ejection of the melt and its subsequent dispersion on the surface. This is facilitated by significant overheating of magma and its saturation with hydrogen, which is accompanied by a sharp decrease in viscosity by several orders of magnitude, even for such highly siliceous melts.     

Optical dating of hydromagmatic volcanoes on the southwestern coast of Jeju Island, Korea

Jeju Island, the largest Quaternary volcanic island in Korea, has formed mostly since the early Pleistocene, but its latest chronology of volcanism and sedimentation is still poorly constrained. Here we report optically stimulated luminescence (OSL) ages for two hydromagmatic volcanoes on the southwestern coast of Jeju Island, i.e., the Songaksan and Suwolbong tuff rings. The basaltic tuffs of these volcanoes contain abundant quartz sands from underlying marine sedimentary sequences. Two samples collected from the middle part of the Songaksan Tuff yielded highly reproducible quartz single-aliquot regenerative-dose (SAR) OSL ages of 7.0±0.3 ka, providing the first direct age estimate of Holocene volcanism in Jeju Island. The quartz OSL age estimate of 5.1±0.3 ka for the younger reworked basaltic tuff (the Hamori Formation) is comparable with previous radiocarbon and U-series disequilibrium dating of fossil mollusk shells. Two samples from the Suwolbong Tuff show quartz OSL age estimates of 18.3±0.7 and 18.6±0.9 ka, which are identical within error ranges and younger than the quartz OSL age estimate of 23.2±1.0 ka for the underlying Gosan Formation. This study confirms that volcanism and attendant sedimentation were active in Jeju Island until very recently.     

Water quality and hydrogeochemical characteristics of the River Buyukmelen,Duzce, Turkey

The River Buyukmelen is located in the province of Duzce in northwest Turkey and its water basin is approximately 470 km². The Aksu, Kucukmelen and Ugursuyu streams flow into the River Buyukmelen. It flows into the Black Sea with an output of 44 m³ s⁻¹. The geological succession in the basin comprises limestone and dolomitic limestone of the Yılanlı formation, sandstone, clayey limestone and marls of the Akveren formation, clastics and volcano‐clastics of the Caycuma formation, and cover units comprised of river alluvium, lacutrine sediments and beach sands. The River Buyukmelen is expected to be a water source that can supply the drinking water needs of Istanbul until 2040; therefore, it is imperative that its water quality be preserved. The samples of rock, soil, stream water, suspended, bed and stream sediments and beach sand were collected from the Buyukmelen river basin. They were examined using mineralogical and geochemical methods. The chemical constituents most commonly found in the stream waters are Na⁺, Mg²⁺, SO²⁻₄, Cl⁻ and HCO₃⁻ in the Guz stream water, Ca²⁺ in the Abaza stream water, and K⁺ in the Kuplu stream water. The concentrations of Na⁺, K⁺, Ca²⁺, Mg²⁺, SO²⁻₄, HCO⁻₃, Cl⁻, As, Pb, Ni, Mn, Cr, Zn, Fe and U in the Kuplu and Guz stream waters were much higher than the world average values. The Dilaver, Gubi, Tepekoy, Maden, Celik and Abaza streams interact with sedimentary rocks, and the Kuplu and Guz streams interact with volcanic rocks. The amount of suspended sediment in the River Buyukmelen in December 2002 was 120 mg l⁻¹. The suspended and bed sediments in the muddy stream waters are formed of quartz, calcite, plagioclase, clay (kaolinite, illite and smectite), muscovite and amphibole minerals. As, Co, Cd, Cr, Pb, Ni, Zn and U have all accumulated in the Buyukmelen river‐bed sediments. The muddy feature of the waters is related to the petrographic features of the rocks in the basin and their mineralogical compositions, as most of the sandstones and volcanic rocks (basalt, tuffite and agglomerate) are decomposed to a clay‐rich composition at the surface. Thus, the suspended sediment in stream waters increases by physical weathering of the rocks and water–rock interaction. Owing to the growing population and industrialization, water demand is increasing. The plan is to bring water from the River Buyukmelen to Istanbul's drinking‐water reservoirs. According to the Water Pollution Regulations, the River Buyukmelen belongs to quality class 1 based on Hg, Cd, Pb, As, Cu, Cr, Zn, Mn, Se, Ba, Na⁺, Cl⁻, and SO²⁻₄; and to quality class 3 based on Fe concentration. The concentration of Fe in the River Buyukmelen exceeds the limit values permitted by the World Health Organization and the Turkish Standard. Because water from the River Buyukmelen will be used as drinking water, it will have an adverse effect on water quality and humans if not treated in advance. In addition, the inclusion of Mn and Zn in the Elmali drinking‐water reservoir of Istanbul and Fe in the River Buyukmelen water indicates natural inorganic contamination. Mn, Zn and Fe contents in the waters are related to geological origin. Moreover, the River Buyukmelen flow is very muddy in the rainy seasons and it is inevitable that this will pose problems during the purification process. Copyright © 2005 John Wiley & Sons, Ltd.