张家口市万全煤田煤层地下气化开发条件研究

根据万全煤田地质构造、水文地质、地层岩性、煤类与煤质、煤层(组)厚度与夹矸的具体分布特点，对万全煤田煤层地下气化开发条件及其前景进行了较为全面的分析和研究，对今后本区煤炭资源开发利用具有一定的指导意义。     

用高岭石夹矸层对比茂名煤田煤层

我队在开展广东茂名煤田的普查勘探工作中,发现下第三系褐煤里具有一定对比特征的高岭石泥岩夹矸层。此种高岭石泥岩夹矸层在煤田中分布面积广,岩性特征明显,层位稳定,在煤田普查勘探中,凭它进行煤层对比,方法简单,依据可靠,从而解决了煤田煤层对比问题。      

冀北榆树沟煤矿区褐煤地下气化地质条件分析

通过对冀北沽源县榆树沟煤矿白芈系青石砬组含煤地层地质条件进行分析,认为仵该矿区进行煤炭地下气化是可行的。研究区构造简单,为一轴向近东西向的舒缓向斜,主要煤层厚度大,最大平均厚度为24.31m。可采煤层顶板多为泥岩、炭质泥岩,尤其是煤系上覆的“三趾马红土”层,对气体有良好的圈闭作用。由于褐煤的灰分含量高,26％～49．03％,地下气化时对煤层顶板影响小,主要煤层埋藏浅200—300m,水文地质条件简单,根据诸多因素分析认为该矿区适合进行褐煤地下气化开采。     

铜川矿区太原组5#煤层高岭石泥岩夹矸的成因及其在煤层对比中的意义

陕西省铜川矿区位于渭北煤田西端,5#煤层发育于石炭系太原组上部,是本区主采煤层之一。其中的高岭石泥岩夹矸,岩性特殊,分布稳定,不仅是良好的煤岩层对比标志,也是有经济价值的陶瓷原料与耐火材料。本文在研究高岭石泥岩夹矸性质的基础上,探讨其成因及其在煤层对比中的应用。      

贵州省六盘水煤田煤炭地下气化资源评价

根据六盘水煤田已有的大量文献、煤勘、钻探、物化探等地质资料,研究区内各赋煤构造单元含煤地层的水文地质情况、煤层发育情况、煤厚、煤质、埋深、上覆地层及下伏地层情况、工程地质条件、构造发育条件、有害元素情况等;结合最新矿权分布情况;立足贵州省地质构造复杂、薄煤层占比较高、煤层群发育的现状;基于FAHP构建煤炭地下气化资源评价层次结构模型,建立8个一级评价指标和24个二级评价指标,采用模糊层次综合评价法进行六盘水煤田煤炭地下气化资源评价。评价面积共计4 091.81km~2,可进行煤炭地下气化的资源总量647亿t;其中有利区资源量90亿t,面积1 140.62km~2;一般区资源量287亿t,面积1 398.79km~2,潜力区资源量270亿t,面积1 552.4km~2。评价结果显示六盘水煤田煤炭地下气化潜力巨大,可着重在有利区内进行工程示范。     

陕西渭北煤田5#煤层粘土岩夹矸的研究

渭北煤田面积约１０万ｋｍ２。分布于太原组顶部５＃煤层中的粘土岩夹矸，上部层位分为两上分层，上分层夹矸厚度薄，下分层夹矸厚约０２ｍ，俗称“２００矸”；下部层位夹矸厚度变化较大。该文详细论述了粘土岩夹矸的岩矿特征。根据“２００矸”中含有副象β－石英、高透长石、锆石、磁铁矿等高温矿物组合，特有的粒序层理和岩性在全煤田十分稳定等特点，表明其原始物质来源于降落火山灰。根据ＴｉＯ２／Ａｌ２Ｏ３比值的明显变化，探讨了陆源组分的加入对火山灰蚀变粘土岩夹矸化学成分的影响。以“２００矸”为等时标志层，解决了５＃煤层在区域上的对比。     

河北省褐煤资源赋存分布特征与勘查开发利用前景分析

河北省辖区内赋存、分布的褐煤资源形成于早白垩世和第三纪，但由于煤层顶底板岩石固结程度差，建井开采时井巷变形严重，维护困难，致使大量褐煤资源未得以开发利用。根据已有资料分析，褐煤含煤区地质构造条件简单、水文地质条件简单、主要呵采煤层顶板以泥岩或炭质泥岩为主，岩石致密，透气性差。褐煤本身透气性好，燃点低，没有粘结性，挥发分高．受热容易膨胀破裂，诸多因素都表明适合采用煤炭地下气化的开采方式进行开发利用，因此有必要加强我省褐煤资源的地质勘查工作和煤炭地下气化工艺的研究，为今后褐煤开发利用奠定基础。     

合山煤田首次发现植物化石

合山煤田是广西的一个重要煤炭基地。煤系为晚二叠世合山组,该组地层(包括煤层的顶、底板及一些夹矸在内)90%以上为海相灰岩和硅质岩,产丰富的海相动物化石,在煤层底部的炭质泥岩中,仅见有植物化石碎片。      

浅析煤层瓦斯赋存的影响因素

煤层瓦斯是一种自生自储式天然气资源。煤层瓦斯赋存情况除与瓦斯生成量的多少有关外,主要的影响因素还包括煤田地质构造演化、井田地质构造、煤的变质程度、煤层埋深及上覆基岩厚度、煤层顶底板岩性、水文地质条件等。     

华北地区京西煤田侏罗纪煤层中伊利石矿物学特征及成因

为了探讨伊利石对煤化作用和沉积环境的指示作用，以华北地区京西煤田侏罗纪煤层夹矸为研究对象，采用X射线衍射方法（XRD）和X射线荧光方法（XRF）分别测定煤层夹矸的矿物组成和化学组成，研究夹矸中伊利石矿物学特征及成因。结果表明，京西煤田侏罗纪煤层夹矸主要由伊利石、绿泥石和石英组成，其中，伊利石质量分数平均为62.92%。将XRD数据和XRF数据进行对比分析，计算得到伊利石平均化学式为（K_0.37（NH₄）_0.03）Al₂（Si_3.60Al_0.40O₁₀）（OH）₂。京西煤田煤层夹矸中伊利石主要由高岭石转化而来，伊利石的NH₄+占层间阳离子的比例具有随沉积古盐度升高而逐渐升高的趋势，n（Si）/n（Al）Ⅳ具有随煤化程度升高而逐渐降低的趋势，这表明京西煤田侏罗纪煤层夹矸中的伊利石矿物学特征对沉积环境和煤化作用具有一定的指示作用。      

南屯煤矿下组煤开采水文地质条件

分析了兖州南屯煤矿下组煤开采的水文地质条件,绘制了下组煤灰岩厚度等值线图、单位涌水量等值线图、灰岩含水层渗透系数等值线图、14灰至奥陶系间距等值线图,分析了隔水层、断裂导水的可能性,总结了南屯煤矿下组煤水害特征以及对安全生产产生的影响特性.     

辽宁红阳煤田控煤构造与深部煤炭资源潜力

针对辽宁红阳煤田局部采区浅部煤炭资源逐渐枯竭的问题,通过煤田构造发育规律和演化史研究、油气地震勘探资料解译、平衡剖面恢复等技术和方法,预测了该煤田深部及外围煤炭资源的赋存状况、远景勘探开发区及煤炭资源量。结果显示:煤田二区为正常背斜的控煤构造,-1500m以浅的煤炭资源储量为83148万t;煤田南部岳家堡背斜往南发育,徐往子勘探区东部存在一个低次序含煤向、背斜构造,可作为远景勘探区,估算-1500m以浅的煤炭资源量为1.85亿t。      

Hydrocarbon generation from coal,extracted coal and bitumen rich coal in confined pyrolysis experiments

Three sets of pyrolysis experiments were performed on extracted coal (R_o% 0.39), coal (initial bitumen 13.5 mg/g coal) and bitumen enriched coal (total bitumen 80.9 mg/g coal) at two heating rates of 2 °C/h and 20 °C/h in confined systems (gold capsules). For all three experiments, the yields of bitumen, Σn-C₈₊, aromatic components and ΣC_2–5 at first increase and then decrease with increasing EASY%R_o and reach the highest values within the EASY%R_o ranges of 0.67–1.08, 1.07–1.19, 1.46–1.79 and 1.46–1.68, respectively. In contrast, C₁/ΣC_1–5 ratio at first decreases and then increases with EASY%R_o and reaches a minimum value in EASY%R_o range of 0.86–1.08, closely corresponding to the maximum values of the yields of bitumen and Σn-C₈₊. Methane yields increase consistently with EASY%R_o. Nearly half of the maximum yield of methane from kerogen was generated at EASY%R_o > 2.2. The differences in methane yields among the three experiments at the same thermal stress are relatively minor at EASY%R_o < 2.2, but are greater with thermal stress at EASY%R_o > 2.2. This demonstrates that the kerogen always retained relatively more hydrogen and hydrocarbon generative potential at the postmature stage of bitumen rich coal than the extracted coal or coal.The maximum yield of ethane is 20–25% higher in the bitumen rich coal experiment than the extracted coal or coal, while the maximum yields of C₃, C₄ and C₅ in the former are double to triple those in the latter. This result demonstrates that the added bitumen in bitumen rich coal substantially increased the generation of these wet gases. However, the averaged values of activation energies (with the same frequency factors) for both the generation and cracking of individual wet gases are similar and do not show consistent trends among the three experiments. For all three experiments, activation energies for the generation and cracking of wet gases are significantly lower than those in previously published oil pyrolysis experiments with same frequency factors (Pan et al., 2012; Organic Geochemistry 45, 29–47). Methane δ¹³C values at the maximum temperature or EASY%R_o are close to those of initial wet gases, especially C₃, implying that the major part of methane shared a common initial precursor with wet gases, i.e., free and bound liquid alkanes.     

不同成因类型煤的可选性评价

煤的可选性受控于煤的聚积环境。通过对内蒙古乌达矿区主采煤层9、10、12、13和15煤中黄铁矿和粘土矿物的赋存特征与煤层成因关系的研究,发现河控下三角洲平原形成的煤层中黄铁矿含量低,粘土矿物含量高,其可选性较好;潮控下三角洲平原形成的煤层,其硫分含量高,粘土矿物含量较低,其可选性中等,而在潮坪沉积基础上形成的煤层中黄铁矿和粘土矿物的可选性最差。      

反映煤储层渗透性的参数之一——块煤率

煤储层的渗透性在很大程度上取决于煤体结构,煤体的整体结构决定煤炭筛分试验所获得的块煤率,所以块煤率可以从整体上反映煤储层的渗透性。辽中地区几个矿区煤储层块煤率与渗透率有很好的相关性,为块煤率作为评价煤储层的参数之一,提供了一个实例。      

Health impacts of coal and coal use: possible solutions

Coal will be a dominant energy source in both developed and developing countries for at least the first half of the 21st century. Environmental problems associated with coal, before mining, during mining, in storage, during combustion, and postcombustion waste products are well known and are being addressed by ongoing research. The connection between potential environmental problems with human health is a fairly new field and requires the cooperation of both the geoscience and medical disciplines. Three research programs that illustrate this collaboration are described and used to present a range of human health problems that are potentially caused by coal. Domestic combustion of coal in China has, in some cases, severely affected human health. Both on a local and regional scale, human health has been adversely affected by coals containing arsenic, fluorine, selenium, and possibly, mercury. Balkan endemic nephropathy (BEN), an irreversible kidney disease of unknown origin, has been related to the proximity of Pliocene lignite deposits. The working hypothesis is that groundwater is leaching toxic organic compounds as it passes through the lignites and that these organics are then ingested by the local population contributing to this health problem. Human disease associated with coal mining mainly results from inhalation of particulate matter during the mining process. The disease is Coal Worker's Pneumoconiosis characterized by coal dust-induced lesions in the gas exchange regions of the lung; the coal worker's “black lung disease”.     

张集井田13-1煤缩小防水煤柱开采实践

本文简要阐述了张集井田的水文地质特征,从煤矿开采过程中围岩及地表移动规律的角度出发,论证了张集井田防水煤柱留设高度的可行性,并付之实践,取得了成功的经验.     

Fine coal covering for preventing spontaneous combustion of coal pile

In order to investigate the effect of fine coal covering around the bottom of coal stockpile on spontaneous combustion prevention, a two-dimensional math model was established to numerically simulate the fine coal covering coal pile and a coal pile temperature-rising experimental system was setup to study the two-dimensional heat and mass transfer characteristics of air diffusion in the horizontal direction and air heat convection in the vertical direction inside coal stockpiles covered by different thicknesses of fine coal. The results showed that (1) the fine coal located at the bottom of the coal pile can effectively inhibit air convection and diffusion, cut off oxygen replenishment, and prevent the temperature rise inside coal pile, and (2) thicker fine coal has more obvious effect. Finally, the field experiments on the fine coal covering coal piles for preventing self-ignition of coal pile were carried out successfully. The results showed that the uncovered or exposed coal piles self-ignited rapidly within a very short period (18 days), while the coal pile covered with 1 m fine coal lasted for 123 days with a maximum coal temperature of only 59.9 °C. The characteristics of temperature distribution and diffusion inside coal stockpile were studied, and the high-temperature region was found in the region 1.3 m high and 2–3 m deep in the coal pile. The effects of environment temperature and precipitation on self-ignition of coal pile were also analyzed in field experiment. The experimental results proved that the fine coal covering technology can effectively prevent the spontaneous combustion of coal stockpiles.     

Flow of top coal and roof rock and loss of top coal in fully mechanized top coal caving mining of extra thick coal seams

This study investigates the flow and caving characteristics of top coal and roof rock, as well as top coal loss pattern in the fully mechanized top coal caving mining of extra thick coal seams. The two dimensional discrete element numerical simulation software program, particle flow code (PFC), is used for the simulation of top coal caving and the inversion analysis. The original locations, distribution, and migration pattern of caved top coal and lost coal were obtained. The analysis shows that in the initial site of caving, the caved bodies are in the form of arc shaped strips in front of the working face. During the caving, caved bodies of different heights move towards the lower rear of the face at different speeds. The lost coal and caved roof rock are originally located at the interface between coal seam and roof, the lost coal is mainly distributed in the goaf on the floor. Behind the support, the caved top coal bodies originally are arc shaped strips, with the highest points located at the midline of the caving opening. The strips are more curved near the goaf than those near the support. During top coal caving, the strips successively cave, with the adjacent outer strip replacing the caved one. The variations of top coal loss and waste rock ratio with time reflect the different phases of top coal caving. In order to improve coal recovery and limit the amount of caved roof rock, the waste rock ratio should be controlled below 10 %. When the waste rock ratio reaches this value, the caving opening should be closed. This paper provides theoretical bases for the improvement of top coal recovery in the fully mechanized top coal caving mining of extra thick coal seams.