Hypervelocity capture of meteoritic particles in nonsilica aerogels

Abstract– The Stardust mission captured particles from the comet 81P/Wild 2 in gradient density silica aerogel and returned the collected samples to earth in 2006. The analyses of these particles have revealed several new insights into the formation of our solar system. However, since the aerogel used as the capture material was silica, the elemental analyses of the silica‐rich particles were made more complicated in certain ways due to the mixing of the silicon of the particles and that of the aerogel. By using a nonsilica aerogel, future elemental analyses of silica–rich particles captured in aerogel could be made more straightforward. Resorcinol/formaldehyde (RF), alumina, and zirconia aerogels were impact tested with meteoritic fragments and the captured fragments were mapped with synchrotron‐based X‐ray microprobe (XRM) and the particles were analyzed with X‐ray fluorescence (XRF). The resorcinol/formaldehyde aerogel proved to be the best capture material, in that it could be keystoned and XRF could be used to locate and analyze particles that were less than 10 μm.     

Rapid extraction of dust impact tracks from silica aerogel by ultrasonic microblades

Abstract— In January 2006, NASA's Stardust mission will return with its valuable cargo of the first cometary dust particles captured at hypervelocity speeds in silica aerogel collectors and brought back to Earth. Aerogel, a proven capture medium, is also a candidate for future sample return missions and low‐Earth orbit (LEO) deployments. Critical to the science return of Stardust as well as future missions that will use aerogel is the ability to efficiently extract impacted particles from collector tiles. Researchers will be eager to obtain Stardust samples as quickly as possible; tools for the rapid extraction of particle impact tracks that require little construction, training, or investment would be an attractive asset. To this end, we have experimented with diamond and steel microblades. Applying ultrasonic frequency oscillations to these microblades via a piezo‐driven holder produces rapid, clean cuts in the aerogel with minimal damage to the surrounding collector tile. With this approach, intact impact tracks and associated particles in aerogel fragments with low‐roughness cut surfaces have been extracted from aerogel tiles flown on NASA's Orbital Debris Collector (ODC) experiment. The smooth surfaces produced during cutting reduce imaging artifacts during analysis by scanning electron microscopy (SEM). Some tracks have been dissected to expose the main cavity for eventual isolation of individual impact debris particles and further analysis using techniques such as transmission electron microscopy (TEM) and nano‐secondary ion mass spectrometry (nanoSIMS).     

Three‐dimensional textural and compositional analysis of particle tracks and fragmentation history in aerogel

Abstract— We report analyses of aerogel tracks using (1) synchrotron X‐ray computed microtomography (XRCMT), (2) laser confocal scanning microscopy (LCSM), and (3) synchrotron radiation X‐ray fluorescence (SRXRF) of particles and their paths resulting from simulated hypervelocity impacts (1–2), and a single ～1 mm aerogel track from the Stardust cometary sample collector (1–3). Large aerogel pieces can be imaged sequentially, resulting in high spatial resolution images spanning many tomographic fields of view (‘lambda‐tomography’). We report calculations of energy deposited, and tests on aromatic hydrocarbons showing no alteration in tomography experiments. Imaging at resolutions from ～17 to ～1 micron/pixel edge (XRCMT) and to <100 nm/pixel edge (LCSM) illustrates track geometry and interaction of particles with aerogel, including rifling, particle fragmentation, and final particle location. We present a 3‐D deconvolution method using an estimated point‐spread function for aerogel, allowing basic corrections of LCSM data for axial distortion. LCSM allows rapid, comprehensive, non‐destructive, high information return analysis of tracks in aerogel keystones, prior to destructive grain extraction. SRXRF with LCSM allows spatial correlation of grain size, chemical, and mineralogical data. If optical methods are precluded in future aerogel capture missions, XRCMT is a viable 3D imaging technique. Combinations of these methods allow for complete, nondestructive, quantitative 3‐D analysis of captured materials at high spatial resolution. This data is fundamental to understanding the hypervelocity particle‐aerogel interaction histories of Stardust grains.     

Time evolution and temperatures of hypervelocity impact‐generated tracks in aerogel

Abstract— Aerogel collectors have been used to capture cometary, interplanetary, and interstellar dust grains by NASA's Stardust mission, highlighting their importance as a scientific instrument. Due to the fragile and heterogeneous nature of cometary dust grains, their fragments are found along the walls of tracks that are formed during the capture process. These fragments appear to experience a wide range of thermal alteration and the causes of this variation are not well understood at a theoretical level as physical models of track formation are not well developed. Here, a general model of track formation that allows for the existence of partially and completely vaporized aerogel material in tracks is developed. It is shown that under certain conditions, this general track model reduces to the kinetic “snowplow” model that has previously been proposed. It is also shown, based on energetic considerations, that track formation is dominated by an expansion that is snowplow‐like in the later stages of track formation. The equation of motion for this snowplow‐like stage can be solved analytically, thus placing constraints on the amount of heating experienced by cometary dust fragments embedded in track walls. It is found that the heating of these fragments, for a given impact velocity, is expected to be greater for those embedded in larger tracks. Given the expected future use of aerogels for sample return missions, the results presented here imply that the choice of aerogel compositions can have a significant effect on the modification of samples captured and retrieved by these collectors.     

Investigation of ion beam techniques for the analysis and exposure of particles encapsulated by silica aerogel: Applicability for Stardust

Abstract— In 2006, the Stardust spacecraft will return to Earth with cometary and perhaps interstellar dust particles embedded in silica aerogel collectors for analysis in terrestrial laboratories. These particles will be the first sample return from a solid planetary body since the Apollo missions. In preparation for the return, analogue particles were implanted into a keystone of silica aerogel that had been extracted from bulk silica aerogel using the optical technique described in Westphal et al. (2004). These particles were subsequently analyzed using analytical techniques associated with the use of a nuclear microprobe. The particles have been analyzed using: a) scanning transmission ion microscopy (STIM) that enables quantitative density imaging; b) proton elastic scattering analysis (PESA) and proton backscattering (PBS) for the detection of light elements including hydrogen; and c) proton‐induced X‐ray emission (PIXE) for elements with Z > 11. These analytical techniques have enabled us to quantify the composition of the encapsulated particles. A significant observation from the study is the variable column density of the silica aerogel. We also observed organic contamination within the silica aerogel. The implanted particles were then subjected to focused ion beam (FIB) milling using a 30 keV gallium ion beam to ablate silica aerogel in site‐specific areas to expose embedded particles. An ion polished flat surface of one of the particles was also prepared using the FIB. Here, we show that ion beam techniques have great potential in assisting with the analysis and exposure of Stardust particles.     

Energy loss and impact cratering in aerogels: theory and experiment

Aerogel collectors have been deployed in low-Earth orbit to collect orbital debris and micrometeorites. An array of silica aerogel collectors is currently en-route back to Earth following an encounter with the Comet Wild-2 on board the Stardust spacecraft. Stardust is returning, for laboratory analysis, cometary and interstellar dust grains which impacted into the aerogel collectors at hypervelocities. While the morphology of impact craters in aerogels has been studied empirically, a theoretical understanding of the physical mechanisms responsible for the formation of impact craters in these solids is lacking. Here we propose and test a model of compaction driven impact cratering in aerogels. Our model derives impact crater dimensions directly from energy and momentum deposition.     

Complex aromatic hydrocarbons in Stardust samples collected from comet 81P/Wild 2

Abstract– The successful return of the Stardust spacecraft provides a unique opportunity to investigate the nature and distribution of organic matter in cometary dust particles collected from comet 81P/Wild 2. Analysis of individual cometary impact tracks in silica aerogel using the technique of two‐step laser mass spectrometry demonstrates the presence of complex aromatic organic matter. While concerns remain as to the organic purity of the aerogel collection medium and the thermal effects associated with hypervelocity capture, the majority of the observed organic species appear indigenous to the impacting particles and are hence of cometary origin. While the aromatic fraction of the total organic matter present is believed to be small, it is notable in that it appears to be N rich. Spectral analysis in combination with instrumental detection sensitivies suggest that N is incorporated predominantly in the form of aromatic nitriles (R–C≡N). While organic species in the Stardust samples do share some similarities with those present in the matrices of carbonaceous chondrites, the closest match is found with stratospherically collected interplanetary dust particles. These findings are consistent with the notion that a fraction of interplanetary dust is of cometary origin. The presence of complex organic N containing species in comets has astrobiological implications as comets are likely to have contributed to the prebiotic chemical inventory of both the Earth and Mars.     

Organic compound alteration during hypervelocity collection of carbonaceous materials in aerogel

Abstract— The NASA Stardust mission brought to Earth micron‐size particles from the coma of comet 81P/Wild 2 using aerogel, a porous silica material, as the capture medium. A major challenge in understanding the organic inventory of the returned comet dust is identifying, unambiguously, which organic molecules are indigenous to the cometary particles, which are produced from carbon contamination in the Stardust aerogel, and which are cometary organics that have been modified by heating during the particle capture process. Here it is shown that 1) alteration of cometary organic molecules along impact tracks in aerogel is highly dependent on the original particle morphology, and 2) organic molecules on test‐shot terminal particles are mostly preserved. These conclusions are based on two‐step laser mass spectrometry (L²MS) examinations of test shots with organic‐laden particles (both tracks in aerogel and the terminal particles themselves).     

Macroscopic subdivision of silica aerogel collectors for sample return missions

Abstract— Silica aerogel collector tiles have been employed for the collection of particles in low Earth orbit and, more recently, for the capture of cometary particles by NASA's Stardust mission. Reliable, reproducible methods for cutting these and future collector tiles from sample return missions are necessary to maximize the science output from the extremely valuable embedded particles. We present a means of macroscopic subdivision of collector tiles by generating large‐scale cuts over several centimeters in silica aerogel with almost no material loss. The cut surfaces are smooth and optically clear allowing visual location of particles for analysis and extraction. This capability is complementary to the smaller‐scale cutting capabilities previously described (Westphal 2004; Ishii 2005a, 2005b) for removing individual impacts and particulate debris in tiny aerogel extractions. Macroscopic cuts enable division and storage or distribution of portions of aerogel tiles for immediate analysis of samples by certain techniques in situ or further extraction of samples suited for other methods of analysis. The capability has been implemented in the Stardust Laboratory at NASA's Johnson Space Center as one of a suite of aerogel cutting methods to be used in Stardust sample curation.     

Fine‐grained material of 81P/Wild 2 in interaction with the Stardust aerogel

Abstract– The deceleration tracks in the Stardust aerogel display a wide range of morphologies, which reveal a large diversity of incoming particles from comet 81P/Wild 2. If the large and dense mineral grains survived the extreme conditions of hypervelocity capture, this was not the case for the fine‐grained material that is found strongly damaged within the aerogel. Due to their low mechanical strength, these assemblages were disaggregated, dispersed, and flash melted in the aerogel in walls of bulbous deceleration tracks. Their petrologic and mineralogical properties are found significantly modified by the flash heating of the capture. Originating from a quenched melt mixture of comet material and aerogel, the representative microstructure consists of silica‐rich glassy clumps containing Fe‐Ni‐S inclusions, vesicles and “dust‐rich” patches, the latter being remnants of individual silicate components of the impacting aggregate. The average composition of these melted particle fragments is close to the chondritic CI composition. They might originate from ultrafine‐grained primitive components comparable to those found in chondritic porous IDPs. Capture effects in aerogel and associated sample biases are discussed in terms of size, chemical and mineralogical properties of the grains. These properties are essential for the grain survival in the extremely hot environment of hypervelocity impact capture in aerogel, and thus for inferring the correct properties of Wild 2 material.     

Capture effects in carbonaceous material: A Stardust analogue study

Abstract— It is reasonable to expect that cometary samples returned to Earth by the Stardust space probe have been altered to some degree during capture in aerogel at 6.1 km/s. In order to help interpret the measured structure of these particles with respect to their original cometary nature, a series of coal samples of known structure and chemical composition was fired into aerogel at Stardust capture velocity. This portion of the study analyzed the surfaces of aerogel‐embedded particles using Raman spectroscopy. Results show that particle surfaces are largely homogenized during capture regardless of metamorphic grade or chemical composition, apparently to include a devolatilization step during capture processing. This provides a possible mechanism for alteration of some aliphatic compound‐rich phases through devolatilization of cometary carbonaceous material followed by re‐condensation within the particle. Results also show that the possibility of alteration must be considered for any particular Stardust grain, as examples of both graphitization and amorphization are found in the coal samples. It is evident that Raman G band (～1580 cm^?1) parameters provide a means of characterizing Stardust carbonaceous material to include identifying those grains which have been subjected to significant capture alteration.     

In situ observation of penetration process in silica aerogel: Deceleration mechanism of hard spherical projectiles

A large number of cometary dust particles were captured with low-density silica aerogels by NASA’s Stardust Mission. Knowledge of the details of the capture mechanism of hypervelocity particles in silica aerogel is needed in order to correctly derive the original particle features from impact tracks. However, the mechanism has not been fully understood yet. We shot hard spherical projectiles of several different materials into silica aerogel of density 60 mg cm⁻³ and observed their penetration processes using an image converter or a high-speed video camera. In order to observe the deceleration of projectiles clearly, we carried out impact experiments at two velocity ranges; ∼4 km s⁻¹ and ∼200 m s⁻¹. From the movies we took, it was indicated that the projectiles were decelerated by hydrodynamic force which was proportional to v² (v: projectile velocity) during the faster penetration process (∼4 km s⁻¹) and they were merely overcoming the aerogel crushing strength during the slower penetration process (∼200 m s⁻¹). We applied these deceleration mechanisms for whole capture process to calculate the track length. Our model well explains the track length in the experimental data set by Burchell et al. (Burchell, M.J., Creighton, J.A., Cole, M.J., Mann, J., Kearsley, A.T. [2001]. Meteorit. Planet. Sci. 36, 209-221).     

Correlated microanalysis of cometary organic grains returned by Stardust

Abstract– Carbonaceous matter in Stardust samples returned from comet 81P/Wild 2 is observed to contain a wide variety of organic functional chemistry. However, some of this chemical variety may be due to contamination or alteration during particle capture in aerogel. We investigated six carbonaceous Stardust samples that had been previously analyzed and six new samples from Stardust Track 80 using correlated transmission electron microscopy (TEM), X‐ray absorption near‐edge structure spectroscopy (XANES), and secondary ion mass spectroscopy (SIMS). TEM revealed that samples from Track 35 containing abundant aliphatic XANES signatures were predominantly composed of cometary organic matter infilling densified silica aerogel. Aliphatic organic matter from Track 16 was also observed to be soluble in the epoxy embedding medium. The nitrogen‐rich samples in this study (from Track 22 and Track 80) both contained metal oxide nanoparticles, and are likely contaminants. Only two types of cometary organic matter appear to be relatively unaltered during particle capture. These are (1) polyaromatic carbonyl‐containing organic matter, similar to that observed in insoluble organic matter (IOM) from primitive meteorites, interplanetary dust particles (IDPs), and in other carbonaceous Stardust samples, and (2) highly aromatic refractory organic matter, which primarily constitutes nanoglobule‐like features. Anomalous isotopic compositions in some of these samples also confirm their cometary heritage. There also appears to be a significant labile aliphatic component of Wild 2 organic matter, but this material could not be clearly distinguished from carbonaceous contaminants known to be present in the Stardust aerogel collector.     

Thermal alteration of hydrated minerals during hypervelocity capture to silica aerogel at the flyby speed of Stardust

Abstract— Outside the Earth's atmosphere, silica aerogel is one of the best materials to capture finegrained extraterrestrial particles in impacts at hypervelocities. Because silica aerogel is a superior insulator, captured grains are inevitably influenced by frictional heat. Therefore, we performed laboratory simulations of hypervelocity capture by using light‐gas guns to impact into aerogels finegrained powders of serpentine, cronstedtite, and Murchison CM2 meteorite. The samples were shot at >6 km s^?1 similar to the flyby speed at comet P/Wild‐2 in the Stardust mission. We investigated mineralogical changes of each captured particle by using synchrotron radiation X‐ray diffraction (SR‐XRD), transmission electron microscope (TEM), and field emission scanning electron microscope (FE‐SEM). SR‐XRD of each grain showed that the majority of the bulk grains keep their original mineralogy. In particular, SR‐XRD and TEM investigations clearly exemplified the presence of tochilinite whose decomposition temperature is about 300 °C in the interior of the captured Murchison powder. However, TEM study of these grains also revealed that all the samples experienced melting and vesiculation on the surface. The cronstedtite and the Murchison meteorite powder show remarkable fracturing, disaggregation, melting, and vesiculation. Steep thermal gradients, about 2500 °C/μm were estimated near the surface of the grains (<2 μm thick) by TEM observation. Our data suggests that the interior of >4 μm across residual grains containing abundant materials that inhibit temperature rise would have not experienced >300 °C at the center.     

Aerogel tracks made by impacts of glycine: Implications for formation of bulbous tracks in aerogel and the Stardust mission

Abstract– Impacts of small particles of soda‐lime glass and glycine onto low density aerogel are reported. The aerogel had a quality similar to the flight aerogels carried by the NASA Stardust mission that collected cometary dust during a flyby of comet 81P/Wild 2 in 2004. The types of track formed in the aerogel by the impacts of the soda‐lime glass and glycine are shown to be different, both qualitatively and quantitatively. For example, the soda‐lime glass tracks have a carrot‐like appearance and are relatively long and slender (width to length ratio <0.11), whereas the glycine tracks consist of bulbous cavities (width to length ratio >0.26). In consequence, the glycine particles would be underestimated in diameter by a factor of 1.7–3.2, if the glycine tracks were analyzed using the soda‐lime glass calibration and density. This implies that a single calibration for impacting particle size based on track properties, as previously used by Stardust to obtain cometary dust particle size, is inappropriate.     

Three‐dimensional structures and elemental distributions of Stardust impact tracks using synchrotron microtomography and X‐ray fluorescence analysis

Abstract— Three‐dimensional structures and elemental abundances of four impact tracks in silica aerogel keystones of Stardust samples from comet 81P/Wild 2 (bulbous track 67 and carrot‐type tracks 46, 47, and 68) were examined non‐destructively by synchrotron radiation‐based microtomography and X‐ray fluorescence analysis. Track features, such as lengths, volumes and width as a function of track depth, were obtained quantitatively by tomography. A bulbous portion was present near the track entrance even in carrot‐type tracks. Each impact of a cometary dust particle results in the particle disaggregated into small pieces that were widely distributed on the track walls as well as at its terminal. Fe, S, Ca, Ni, and eight minor elements are concentrated in the bulbous portion of track 68 as well as in terminal grains. It was confirmed that bulbous portions and thin tracks were formed by disaggregation of very fine fragile materials and relatively coarse crystalline particles, respectively. The almost constant ratio of whole Fe mass to track volume indicates that the track volume is almost proportional to the impact kinetic energy. The size of the original impactor was estimated from the absolute Fe mass by assuming its Fe content (CI) and bulk density. Relations between the track sizes normalized by the impactor size and impact conditions are roughly consistent with those of previous hypervelocity impact experiments.     

Assessment and control of organic and other contaminants associated with the Stardust sample return from comet 81P/Wild 2

Abstract– Numerous potential sources of organic contaminants could have greatly complicated the interpretation of the organic portions of the samples returned from comet 81P/Wild 2 by the Stardust spacecraft. Measures were taken to control and assess potential organic (and other) contaminants during the design, construction, and flight of the spacecraft, and during and after recovery of the sample return capsule. Studies of controls and the returned samples suggest that many of these potential sources did not contribute any significant material to the collectors. In particular, contamination from soils at the recovery site and materials associated with the ablation of the heatshield do not appear to be significant problems. The largest source of concern is associated with the C present in the original aerogel. The relative abundance of this carbon can vary between aerogel tiles and even within individual tiles. This C was fortunately not distributed among a complex mixture of organics, but was instead largely present in a few simple forms (mostly as Si‐CH₃ groups). In most cases, the signature of returned cometary organics can be readily distinguished from contaminants through their different compositions, nonterrestrial isotopic ratios, and/or association with other cometary materials. However, some conversion of the carbon indigenous to the flight aerogel appears to have happened during particle impact, and some open issues remain regarding how this C may be processed into new forms during the hypervelocity impact collection of the comet dust.     

Hypervelocity capture of particles in aerogel: Dependence on aerogel properties

Capture of high-speed (hypervelocity) particles in aerogel at ambient temperatures of 175-763 K is reported. This extends previous work which has mostly focussed on conducting experiments at ambient laboratory temperatures, even though aerogels are intended for use in cosmic dust capture cells in space environments which may experience a range of temperatures (e.g., the NASA Stardust mission which collected dust at 1.81 AU and putative Mars atmospheric sampling missions). No significant change in track length (normalised to impactor size) was found over the range 175-600 K, although at 763 K a significant reduction (30%) was found. By contrast, entrance hole diameter remained constant only up to 400 K, above this sudden changes of up to 50% were observed. Experiments were also carried out at normal laboratory temperature using a wide range of aerogel densities and particle sizes. It was found that track length normalised to particle size varies inversely with aerogel density. This is a power law dependence and not linear as previously reported, with longer tracks at lower densities. Glass projectiles (up to 100 μm size) were found to undergo a variety of degrees of damage during capture. In addition to the well known acquisition of a coating (partial or complete) of molten aerogel the mechanical damage includes pitting and meridian fractures. Larger (500 μm diameter) stainless steel spheres also showed damage during capture. In this case melting and ablation occurs, suggesting surficial temperatures during impact in excess of 1400 °C. The response of the aerogel itself to passage of particles through it is reported. The presence of fan-like fractures around the tracks is attributed to cone cracking similar to that in glasses of normal density, with the difference that here it is a repetitive process as the particles pass through the aerogel.     

Sample Return Missions from Minor Bodies: Achievements, Future Plan and Observational Support

We are entering in a new era of space exploration signed by sample return missions. Since the Apollo and Luna Program, the study of extraterrestrial samples in laboratory is gathering an increased interest of the scientific community so that nowadays exploration program of the Solar System is characterized by swelling sample return missions. Beside lunar samples, the NASA Stardust mission was the first successful space mission that on 15 January 2006 brought to Earth solid extraterrestrial samples collected from comet 81P/Wild 2 coma. Grains were collected during cometary fly-by into aerogel and once on Earth have been extracted for laboratory analyses. In the coming two decades many space missions on going or under study will harvest samples from minor bodies. Measurements required for detailed analysis that cannot be performed from a robotic spacecraft, will be carried out on Earth laboratories with the highest analytical accuracy attainable so far. An intriguing objective for the next sample return missions is to understand the nature of organic compounds. Organic compounds found in Stardust grains even if processed to large extend during aerogel capturing are here reported. Major objectives of Marco Polo mission are reported. Various ground-based observational programs within the framework of general characterizations of families and classes, cometary–asteroid transition objects and NEOs with cometary albedo are discussed and linked to sample return mission.