Lunar dust and lunar simulant activation and monitoring

Abstract— NASA plans to resume human exploration of the Moon in the next decade. One of the pressing concerns is the effect that lunar dust (the fraction of the lunar regolith <20 μm in diameter) will have on systems, both human and mechanical, due to the fact that various problems were caused by dust during the Apollo missions. The loss of vacuum integrity in the lunar sample containers during the Apollo era ensured that the present lunar samples are not in the same condition as they were on the Moon; they have been passivated by oxygen and water vapor. To mitigate the harmful effects of lunar dust on humans, methods of “reactivating” the dust must be developed for experimentation, and, ideally, it should be possible to monitor the level of activity to determine methods of deactivating the dust in future lunar habitats. Here we present results demonstrating that simple grinding, as a simple analog to micrometeorite crushing, is apable of substantially activating lunar dust and lunar simulant, and it is possible to determine the level of chemical activity by monitoring the ability of the dust to produce hydroxyl radicals in aqueous solution. Comparisons between ground samples of lunar dust, lunar simulant, and quartz reveal that ground lunar dust is capable of producing over three times the amount of hydroxyl radicals as lunar simulant and an order of magnitude more than ground quartz.     

The effects of space weathering on Apollo 17 mare soils: Petrographie and chemical characterization

Abstract— The lunar soil characterization consortium, a group of lunar‐sample and remote‐sensing scientists, has undertaken the extensive task of characterization of the finest fractions of lunar soils, with respect to their mineralogical and chemical makeup. These compositional data form the basis for integration and modeling with the reflectance spectra of these same soil fractions. This endeavor is aimed at deciphering the effects of space weathering of soils on airless bodies with quantification of the links between remotely sensed reflectance spectra and composition. A beneficial byproduct is an understanding of the complexities involved in the formation of lunar soil. Several significant findings have been documented in the study of the <45 μm size fractions of selected Apollo 17 mare soils. As grain size decreases, the abundance of agglutinitic glass increases, as does the plagioclase, whereas the other minerals decrease. The composition of the agglutinitic glass is relatively constant for all size fractions, being more feldspathic than any of the bulk compositions; notably, TiO₂ is substantially depleted in the agglutinitic glass. However, as grain size decreases, the bulk composition of each size fraction continuously changes, becoming more Al‐rich and Fe‐poor, and approaches the composition of the agglutinitic glasses. Between the smallest grain sizes (10–20 and < 10 μm), the I_S/FeO values (amount of total iron present as nanophase Fe⁰) increase by greater than 100% (>2x), whereas the abundance of agglutinitic glass increases by only 10–15%. This is evidence for a large contribution from surface‐correlated nanophase Fe⁰ to the I_S/FeO values, particularly in the <10 μm size fraction. The surface nanophase Fe⁰ is present largely as vapor‐deposited patinas on the surfaces of almost every particle of the mature soils, and to a lesser degree for the immature soils (Keller et al., 1999a). It is reasoned that the vapor‐deposited patinas may have far greater effects upon reflectance spectra of mare soils than the agglutinitic Fe⁰.     

Ultra‐reduced phases in Apollo 16 regolith: Combined field emission electron probe microanalysis and atom probe tomography of submicron Fe‐Si grains in Apollo 16 sample 61500

The lunar regolith contains a variety of chemically reduced phases of interest to planetary scientists and the most common, metallic iron, is generally ascribed to space weathering processes (Lucey et al. 2006 ). Reports of silicon metal and iron silicides, phases indicative of extremely reducing conditions, in lunar samples are rare (Anand et al. 2004 ; Spicuzza et al. 2011 ). Additional examples of Fe‐silicides have been identified in a survey of particles from Apollo 16 sample 61501,22. Herein is demonstrated the utility of low keV electron probe microanalysis (EPMA), using the Fe Ll X‐ray line, to analyze these submicron phases, and the necessity of accounting for carbon contamination. We document four Fe‐Si and Si⁰ minerals in lunar regolith return material. The new Fe‐Si samples have a composition close to (Fe,Ni)₃Si, whereas those associated with Si⁰ are close to FeSi₂ and Fe₃Si₇. Atom probe tomography of (Fe,Ni)₃Si shows trace levels of C (60 ppma and nanodomains enriched in C, Ni, P, Cr, and Sr). These reduced minerals require orders of magnitude lower oxygen fugacity and more reducing conditions than required to form Fe⁰. Documenting the similarities and differences in these samples is important to constrain their formation processes. These phases potentially formed at high temperatures resulting from a meteorite impact. Whether carbon played a role in achieving the lower oxygen fugacities—and there is evidence of nearby carbonaceous chondritic material—it remains to be proven that carbon was the necessary component for the unique existence of these Si⁰ and iron silicide minerals.     

Solar-wind interactions with the moon: Nature and composition of nitrogen compounds

The lunar atmosphere and magnetic field are very tenuous. The solar wind, therefore, interacts directly with the lunar surface material and the dominant nature of interaction is essentially complete absorption of solar-wind particles by the surface material resulting in no upstream bowshock, but a cavity downstream. The solar-wind nitrogen ion species induce and undergo a complex set of reactions with the elements of lunar material and the solar-wind-derived trapped elements. The nitrogen concentration indigeneous to the lunar surface material is practically nil. Therefore any nitrogen and nitrogen compounds found in the lunar surface material are due to the solar-wind implantation of nitrogen ions. The flux of the solar-wind nitrogen ion species is about 6×10³ cm^–2 s^–1. Since there is no evidence for accumulation of nitrogen species in the lunar surface material, the outflux of nitrogen species from the lunar material to the atmosphere is the same as the solar-wind nitrogen ion flux. The species of the outflux are primarily NO and NH₃, and their respective concentrations in the near surface lunar atmosphere are found by calculation to be 327 and 295 cm^–3. The calculated concentration of NH₃ seems to be consistent with the sunrise concentration results of the mass spectrometer implanted on the lunar surface. This is not the case for the concentration of NO. According to the presently calculated concentration value of NO, the mass spectrometer should have detected NO at sunrise, but no report was made for its detection. There is also discrepancy about the concentration of N₂ which is explained in this paper. The concentrations of nitrogen species in the lunar material at the time of sample collection on the Moon remained about the same when the samples were analyzed on the Earth. However, no specific experiment was planned to detect the nitrogen species in the lunar material samples.     

Dry separation of respirable lunar dust: Providing samples for the lunar airborne dust toxicity advisory group

In order to study the toxicity of lunar dust, the respirable size fraction of lunar soil needed to be separated with an apparatus that possesses the following capabilities: no use of liquid; fully recoverable sample; and use of only small sample quantities (<1 gm). We report the design of a simple apparatus that meets these requirements and implements an inertial-impaction mechanism established in aerosol science. Lunar soil was agitated at a frequency of 100 Hz using a vibration table with a containment chamber under a constant air flow. The air flow carried the lofted lunar dust particles past four impactors (four T-junction connectors), upon which a fraction of large particles were captured during the impaction. The fine particles in the air flow were then collected by an end-of-the line membrane filter. Detailed examination of particles on the filter showed that the majority (∼80-90 wt%) are <3 μm (geometric diameter), suggesting a high level of effectiveness for the apparatus.     

Lunar dust: The Hazard and Astronaut Exposure Risks

This paper reviews the characterisation of lunar dust or regolith, the toxicity of the dust and associated health effects, the techniques for assessing the health risks from dust exposure and describes the measures used or being developed to mitigate exposure. Lunar dust is formed from micrometeorite impacts onto the Moon’s surface. The hypervelocity impacts result in communition and the formation of sharp and clingy agglutinates. The dust particles vary in size with the smallest being less than 10 μm. If the chemical reactive particles are deposited in the lungs, they may cause respiratory disease. During lunar exploration, the astronaut’s spacesuits will become contaminated with lunar dust. The dust will be released into the atmosphere when the suits are removed. The exposure risks to health will need to be assessed by relating to a permissible exposure limit. During the Apollo missions, the astronauts were exposed to lunar dust. Acute health effects from dust inhalation exposure included sore throat, sneezing and coughing. Long-term exposure to the dust may cause a more serious respiratory disease similar to silicosis. On future missions the methods used to mitigate exposure will include providing high air recirculation rates in the airlock, the use of a “Double Shell Spacesuit” so that contaminated spacesuits are removed before entering the airlock, the use of dust shields to prevent dust accumulating on surfaces, the use of high gradient magnetic separation to remove surface dust and the use of solar flux to sinter and melt the regolith around the spacecraft.     

Axisymmetric dusty gas jet in the inner coma of a comet: II. The case of isolated jets

The behavior of isolated pure and dusty gas jets ejected from an active spot on the sunlit side of the nucleus surface is hydrodynamically investigated in the inner coma of an H₂O-dominated comet that is assumed to have no ambient ejection of the gas and dust from the dust-covered surface except the active spot. Steady-state solutions of the expanding jets are obtained by numerically solving the axisymmetric, time-dependent, coupled hydrodynamic equations of H₂O gas and the dust in polar coordinates (r, θ, φ). The dust particles are treated as multicomponents composed of the three radii of a = 0.01, 0.1, and 1 μm. The boundary conditions of a slip wall are applied to the dust-covered surface. Discussion is given on the no-slip-wall conditions. Compared with the previous study on the jets surrounded by ambient gas and dust ejected from a nonactive region by Y. Kitamura (1986, Icarus 66, 241–257), the jet features can be clearly discerned even at large distances from the nucleus center, and the shift of the density peaks from the central axis to the wings, which was seen in the previous study, does not occur, because the jets can freely expand in the θ direction without being decelerated by the ambient gas and dust. The gas flow in the θ direction is supersonic, and consequently it is predicted that the shock waves are formed in the interactive regions among several jets. For the isolated jets with no ambient ejection, it is to be noted that the flow of the gas and dust along the nucleus surface arises in spite of the radial ejection from the active spot, and that this flow may change the surface structure. In the dusty case, the gas temperature increases immediately from 200 to ∼275°K in the vicinity of the surface owing to strong heating by the fine dust particles with the radius as small as 0.01 μm. In addition to the fine dust, the hot dust mantle (300–400°K) on the surface may considerably heat the gas near the mantle.     

The lunar dust environment

Each year the Moon is bombarded by about 10⁶ kg of interplanetary micrometeoroids of cometary and asteroidal origin. Most of these projectiles range from 10 nm to about 1 mm in size and impact the Moon at 10–72 km/s speed. They excavate lunar soil about 1000 times their own mass. These impacts leave a crater record on the surface from which the micrometeoroid size distribution has been deciphered. Much of the excavated mass returns to the lunar surface and blankets the lunar crust with a highly pulverized and “impact gardened” regolith of about 10 m thickness. Micron and sub-micron sized secondary particles that are ejected at speeds up to the escape speed of 2300 m/s form a perpetual dust cloud around the Moon and, upon re-impact, leave a record in the microcrater distribution. Such tenuous clouds have been observed by the Galileo spacecraft around all lunar-sized Galilean satellites at Jupiter. The highly sensitive Lunar Dust Experiment (LDEX) onboard the LADEE mission will shed new light on the lunar dust environment. LADEE is expected to be launched in early 2013.Another dust related phenomenon is the possible electrostatic mobilization of lunar dust. Images taken by the television cameras on Surveyors 5, 6, and 7 showed a distinct glow just above the lunar horizon referred to as horizon glow (HG). This light was interpreted to be forward-scattered sunlight from a cloud of dust particles above the surface near the terminator. A photometer onboard the Lunokhod-2 rover also reported excess brightness, most likely due to HG. From the lunar orbit during sunrise the Apollo astronauts reported bright streamers high above the lunar surface, which were interpreted as dust phenomena. The Lunar Ejecta and Meteorites (LEAM) Experiment was deployed on the lunar surface by the Apollo 17 astronauts in order to characterize the lunar dust environment. Instead of the expected low impact rate from interplanetary and interstellar dust, LEAM registered hundreds of signals associated with the passage of the terminator, which swamped any signature of primary impactors of interplanetary origin. It was suggested that the LEAM events are consistent with the sunrise/sunset-triggered levitation and transport of charged lunar dust particles. Currently no theoretical model explains the formation of a dust cloud above the lunar surface but recent laboratory experiments indicate that the interaction of dust on the lunar surface with solar UV and plasma is more complex than previously thought.     

Light scattering by complex particles in the Moon's exosphere: Toward a taxonomy of models for the realistic simulation of the scattering behavior of lunar dust

It is suspected that the lunar exosphere has a dusty component dispersed above the surface by various physical mechanisms. Most of the evidence for this phenomenon comes from observations of “lunar horizon glow” (LHG), which is thought to be produced by the scattering of sunlight by this exospheric dust. The characterization of exospheric dust populations at the Moon is key to furthering our understanding of fundamental surface processes, as well as a necessary requirement for the planning of future robotic and human exploration.We present a model to simulate the scattering of sunlight by complex lunar dust grains (i.e. grains that are non-spherical and can be inhomogeneous in composition) to be used in the interpretation of remote sensing data from current and future lunar missions. We numerically model lunar dust grains with several different morphologies and compositions and compute their individual scattering signatures using the Discrete Dipole Approximation (DDA). These scattering properties are then used in a radiative transfer code to simulate the light scattering due to a dust size distribution, as would likely be observed in the lunar exosphere at high altitudes 10's of km. We demonstrate the usefulness and relevance of our model by examining mode: irregular grains, aggregate of spherical monomers and spherical grains with nano-phase iron inclusions. We subsequently simulate the scattering by two grain size distributions (0.1 and radius), and show the results normalized per-grain. A similar methodology can also be applied to the analysis of the LHG observations, which are believed to be produced by scattering from larger dust grains within about a meter of the surface.As expected, significant differences in scattering properties are shown between the analyses employing the widely used Mie theory and our more realistic grain geometries. These differences include large variations in intensity as well as a positive polarization of scattered sunlight caused by non-spherical grains. Positive polarization occurs even when the grain size is small compared to the wavelength of incident sunlight, thus confirming that the interpretation of LHG based on Mie theory could lead to large errors in estimating the distribution and abundances of exospheric dust.     

Evidence of space weathering in regolith breccias II: Asteroidal regolith breccias

Abstract– Space weathering products, such as agglutinates and nanophase iron‐bearing rims are easily preserved through lithification in lunar regolith breccias, thus such products, if produced, should be preserved in asteroidal regolith breccias as well. A study of representative regolith breccia meteorites, Fayetteville (H4) and Kapoeta (howardite), was undertaken to search for physical evidence of space weathering on asteroids. Amorphous or npFe⁰‐bearing rims cannot be positively identified in Fayetteville, although possible glass rims were found. Extensive friction melt was discovered in the meteorite that is difficult to differentiate from weathered materials. Several melt products, including spherules and agglutinates, as well as one irradiated rim and one possible npFe⁰‐bearing rim were identified in Kapoeta. The existence of these products suggests that lunar‐like space weathering processes are, or have been, active on asteroids.     

Reflectance spectra of analog basalts; implications for remote sensing of lunar geology

Lunar mare basalts, highland anorthosites and KREEP are the three major lunar rock types reported from the lunar surface. In the present study, we interpret the reflectance spectral behavior of lunar analog basalts including massive basalt, vesicular basalt and amygdaloidal basalt collected from the Deccan basaltic region, which are considered as equivalent of lunar mare basalts. Reflectance spectra of analog basalts were measured at three different environments: in the field, under controlled field conditions and in the lab. In field conditions the reflectance spectra were measured under 350-1050 nm spectral range. During controlled field and lab condition, reflectance spectra were measured under 350-2500 nm range covering the UV, visible, NIR, and SWIR regions. The spectral characteristics of basalts measured under different environments and their merits and demerits were discussed. However, lab spectra have given clear, reliable diagnostic spectral information for our present objective. The major oxides and minerals of analog basalts were compared with lunar mare basalts. The presence of Ca-pyroxene, ferrous and ferric iron and their diagnostic spectral features in basalts are discussed for study of lunar mare region.     

The optical properties of the finest fraction of lunar soil: Implications for space weathering

Abstract— The fine fraction of lunar soils (<45 μm) dominates the optical properties of the bulk soil. Definite trends can be seen in optical properties of size separates with decreasing particle size: diminished spectral contrast and a steeper continuum slope. These trends are related to space weathering processes and their affects on different size fractions. The finest fraction (defined here as the <10 μm fraction) appears to be enriched in weathering products relative to the larger size fractions, as would be expected for surface correlated processes. This <10 μm fraction tends to exhibit very little spectral contrast, often with no distinguishable ferrous iron absorption bands. Additionally, the finest fractions of highland soils are observed to have very different spectral properties than the equivalent fraction of mare soils when compared with larger size fractions. The spectra of the finest fraction of feldspathic soils flatten at longer wavelengths, whereas those of the finest fraction of basaltic soils continue to increase in a steep, almost linear fashion. This compositional distinction is due to differences in the total amount of nanophase iron that accumulates in space weathering products. Such ground‐truth information derived from the <10 μm fraction of lunar soils provides valuable insight into optical properties to be expected in other space weathering environments such as the asteroids and Mercury.     

A theoretical evaluation of the lunar tidal variations in the ionospheric F2-layer

Time-varying solutions of the full continuity equation for electrons in the F2-region are obtained. The effects of production, loss, diffusion and electrodynamic ‘E × B’ drift are taken into account. The ‘E × B’ drift term consists of a solar and a lunar component. The solar component of drift is assumed diurnal with 14.6m/sec maximum upward speed at mid-day. The lunar component is assumed sinusoidal with period of half lunar day and amplitude one tenth of the solar drift; the phase is assumed to remain constant in lunar time, in accordance with Chapman's phase law.The results show that the lunar variations in the F2-region are markedly dependent on solar time and latitude. It is also shown that the average semi-diurnal lunar variations in N_mF2 and h_mF2 at any particular lunar time are almost opposite in phase to each other (i.e. out of phase by 6 hr) in the magnetic equatorial zone, and out of phase by 2 hr at moderate latitudes. The phase of δh_mF2 is 10 hr at low latitudes and 9 hr at moderate latitudes. The phase of δN_mF2 is 4 hr at low latitudes and 11 lunar hr at moderate latitudes.The results also show that the phase of the lunar semi-monthly oscillations in N_mF2 undergoes a rapid shift of about 5 lunar hr in going from 8 to 12° and the so called phase reversal occurs at about 10° lat at which the amplitude of N_mF2. becomes extremely small.These and other results are in good agreement with observations. Thus it is shown that the main features of the observed lunar tidal variations of the F2-region within 20° of the magnetic equator can be explained satisfactorily by the superposition of a small lunar drift on a large solar drift.     

Evidence of space weathering in regolith breccias I: Lunar regolith breccias

Abstract— We have analyzed a suite of lunar regolith breccias in order to assess how well space weathering products can be preserved through the lithification process and therefore whether or not it is appropriate to search for space weathering products in asteroidal regolith breccia meteorites. It was found that space weathering products, vapor/sputter deposited nanophase‐iron‐bearing rims in particular, are easily identified in even heavily shocked/compacted lunar regolith breccias. Such rims, if created on asteroids, should thus be preserved in asteroidal regolith breccia meteorites. Two additional rim types, glass rims and vesicular rims, identified in regolith breccias, are also described. These rims are common in lunar regolith breccias but rare to absent in lunar soils, which suggests that they are created in the breccia‐forming process itself. While not “space weathering products” in the strictest sense, these additional rims give us insight into the regolith breccia formation process. The presence or absence of glass and/or vesicular rims in asteroidal regolith breccias will likewise tell us about environmental conditions on the surface of the asteroid body on which the breccia was created.     

Distribution, ,movement,and evolution of the volatile elements in the lunar regolith

The abundances and distributions of carbon, nitrogen, and sulfur in lunar soils are reviewed. Carbon and nitrogen have a predominantly extra-lunar origin in lunar soils and breccias, while sulfur is mostly indigeneous to the Moon. The lunar processes which effect the movement, distribution, and evolution of carbon, nitrogen, and sulfur, along with the volatile alkali elements sodium, potassium, and rubidium during regolith processes are discussed. Possible mechanisms which may result in the addition to or loss from the Moon of these volatile elements are considered.     

Lunar Ice: Adsorbed Water on Subsurface Polar Dust

Differential scanning calorimetry indicates that adsorbed water and goethite, a product of hydrated ilmenite, are thermally stable over geologic time in the lunar polar regions. Adsorbed water can undergo burial as a result of several mechanisms, thereby achieving protection from sputtering or Lyman α radiation losses. Adsorbed, subsurface water layers on lunar dust, and any hydrated minerals present, could account for a majority of the hydrogen at the north lunar pole as well as account for a portion of that found at the south pole, particularly in small (<10 km) craters. Lunar ice, if it forms by condensation of water vapor in polar cold traps, will initially be in the form of amorphous solid water, and its rate of crystallization will depend on trap temperature and the composition of the surfaces upon which it has condensed. Between 95 and 110 K, diurnal temperature fluctuations cause surface ice deposits to migrate through the lunar regolith. Via such migration, stable and immobile layers of adsorbed water will be formed. In this temperature range, which can be expected at the margins of large craters and in smaller craters, any water resource would be a mixture of relatively unstable bulk ice and stable adsorbed water on subsurface dust and fines.     

Dynamical behavior of size-graded dust grains levitated in rotating magnetized astroplasmas

Our purpose is to examine the formation of different sheaths in rotating astroplasmas embedded in an ambient magnetic field. Sequel to our recent work (Das and Chakraborty in Astrophys. Space Sci., 2011) we remodeled our present study with the view to finding of robust sheath over the Earth’s Moon along with the formation of dust clouds therein. Based on using the pseudopotential analysis, a modified Sagdeev potential equation has been derived, which, in turns, quantifies the interaction of Coriolis force and magnetic field and to derive the different natures of sheath and dust atmosphere. The application of this result to the input numeric data of the lunar environment and dynamical behaviors of dust levitation has been studied. Our study finds that the dust particles having a spatial segregation within the sheath region form dust clouds in spaces.     

Understanding the mechanisms of formation of nanophase compounds from Stardust: Combined experimental and observational approach

Abstract– We have experimentally produced nanophase sulfide compounds and magnetite embedded in Si‐rich amorphous materials by flash‐cooling of a gas stream. Similar assemblages are ubiquitous, and often dominant components of samples of impact‐processed silica aerogel tiles and submicron grains from comet 81P/Wild 2 were retrieved by NASA’s Stardust mission. Although the texture and compositions of nanosulfide compounds have been reproduced experimentally, the mechanisms of formation of these minerals and their relationship with the surrounding amorphous materials have not been established. In this study, we present evidence that both of these materials may not only be produced through cooling of a superheated liquid but they may have also been formed simultaneously by flash‐cooling and subsequent deposition of a gas dominated by Fe‐S‐SiO‐O₂. In a dust generator at the Goddard Space Flight Center, samples are produced by direct gas‐phase condensation from gaseous precursors followed by deposition, which effectively isolates the effects of gas‐phase reactions from the effects of melting and condensation. High‐resolution transmission electron microscopy images and energy‐dispersive spectroscopy analysis show that these experiments replicate key features of materials from type B and type C Stardust tracks, including textures, distribution of inclusions, nanophase size, and compositional diversity. We argue that gas‐phase reactions may have played a significant role in the capture environment for nanophase materials. Our results are consistent with a potential progenitor assemblage of micron and submicron‐sized sulfides and submicron silica‐bearing phases, which are commonly observed in chondritic interplanetary dust particles and in the matrices of the most pristine chondritic meteorites.     

Search for solar-type nitrogen in the gas-rich Pesyanoe meteorite

Abstract— We report nitrogen isotopic data obtained from a stepwise gas release of two grain-size fractions of the gas-rich meteorite Pesyanoe. Cosmic-ray-produced ¹⁵N_c may be present in all temperature steps ≥600 °C, and we correct this component using spallation ²¹Ne data. The resulting ratios reveal the presence of more than one trapped N component. Indigenous N is released above 1000 °C with an isotopic signature of δ¹⁵N = ?33‰. This is consistent with the rather uniform signatures of indigenous nitrogen in enstatite meteorites. There is no evidence for the presence of “very light” N of δ¹⁵N ? ?200‰. On the other hand, a “heavy” nitrogen component appears in the temperature range 700–800 °C, and coincides with a major release of solar-type noble gases. For a two-component mixture, the isotopic shifts in this temperature range define a lower limit δ¹⁵N_corr = ?6‰ for the second component (e.g., solar-type nitrogen). However, for the case of a solar-type component, the calculated δ¹⁵N signature depends on the adopted elemental abundances. For example, adoption of the relative abundances of ¹⁴N and noble gases in lunar ilmenite 71501 yields δ¹⁵N ? +170, which is in the range of the heavier nitrogen signatures observed on the lunar surface.     

Nitrogen in diamond‐free ureilite Allan Hills 78019: Clues to the origin of diamond in ureilites

Abstract— Nitrogen and noble gases were measured in a bulk sample and in acid‐resistant carbon‐rich residues of the ureilite Allan Hills (ALH) 78019 which has experienced low shock and is free of diamond. A small amount of amorphous carbon combusting at ≤500 °C carries most of the noble gases, while the major carbon phase consisting of large crystals of graphite combusts at ≥800 °C, and is almost noble‐gas free. Nitrogen on the other hand is present in both amorphous carbon and graphite, with different δ¹⁵N signatures of ?21%_o and +19%_o, respectively, distinctly different from the very light nitrogen (about ?100%_o) of ureilite diamond. Amorphous carbon in ALH 78019 behaves similar to phase Q of chondrites with respect to noble gas release pattern, behavior towards oxidizing acids as well as nitrogen isotopic composition. In situ conversion of amorphous carbon or graphite to diamond through shock would require an isotopic fractionation of 8 to 12% for nitrogen favoring the light isotope, an unlikely proposition, posing a severe problem for the widely accepted shock origin of ureilite diamond.