Geological parameters affecting the marble production in the quarries along the southern flank of the Menderes Massif, in SW Turkey

The Mugla province is one of the major marble producing regions located in the southern flank of the Menderes Massif in SW Turkey. The Menderes Massif is a regionally metamorphosed massif with an old Pan-African core and cover successions from the Permo–Carboniferous to Paleocene. There are four major metamorphic carbonate horizons in the cover successions exploited for the marble production. These horizons are located within the Permo–Carboniferous, Triassic, Upper Cretaceous and Paleocene successions along the southern flank of the Menderes Massif. Here the world wide known marbles with names such as the Mugla Black, the Milas White, Veined, Pearl, Aubergine, Lilac and Lemony, the Mugla White and the Aegean Bordeaux are found.

Detailed geological studies were carried out in selected marble quarries representing the different stratigraphic levels to determine the geological parameters affecting the marble production in the southern flank of the Menderes Massif in SW Turkey. The geological parameters such as bedding, joints, schist interlayers and mica filled joints affecting the block production from the marble beds are considered to be primary features. The presence of dolomite bands and lenses, abnormal sized calcite crystals and emery minerals which affect the slab and the production qualities and appearances are considered to be secondary geological parameters. The primary and secondary geological parameters affecting the marble productions at different stratigraphical levels in SW Turkey, are determined and the practical aspects of these findings are discussed.     

Petrographical and geochemical investigation of the Triassic marbles associated with Menderes massif metamorphics,Kavaklıdere,Muğla,SW Turkey

Vast marble deposits occur in a cover sequence of the Menderes Massif, SW Turkey. Four major marble deposits are recognized in Mu?la province based on the stratigraphic levels. These are Permo-Carboniferous aged black marbles (1), Triassic aged marbles (2), Upper Cretaceous aged marbles (3), and Paleocene aged pelagic marbles (4). This study deals with Triassic aged marbles of the southern part of the Menderes Massif. The Triassic marbles from SW Turkey consist of two big marble horizons in the Çayboyu (ÇM) and Kestanecik (KM) regions. The characteristic samples are collected from different stratigraphic levels in marble deposits in the ÇM and KM horizons. Mineralogical and major, trace, and rare earth element (REE) analyses of marble, limestone, and schist were conducted on these samples to reveal their petrographical and geochemical characteristics. The ÇM horizon is represented by calcitic marble layers. Nickel, cobalt, manganese, and iron elements filled in fractures, fissures, and intergranular spaces of calcite crystals and these elements give the pinky colour to the marble from the ÇM horizon. KM marbles were deformed, metamorphosed, and recrystallized under greenschist facies P–T conditions. As a result of the metasomatic reaction of magnesium and manganese rich fluids with marbles, dolomite, and manganese, minerals such as rhodochrosite and pyrolusite have crystallized along vein walls and layers in the KM horizon. Dolomitization was determined in KM marbles, whereas ÇM marbles show the character of limestone. MgO, MnO, Fe₂O₃, Ni, and Zn contents of marbles from the KM horizon are higher than those of ÇM marbles due to metasomatic reactions. The Sr content in white coloured marbles ranges between 11.20 ppm and 112.20 ppm and this concentration reaches up to 272.70 ppm due to metasomatic reactions and fluid intake. The REE content of Triassic marbles is independent of the abundance of carbonate and the REE enrichment observed due to syn-metamorphic fluid flow. The significant negative Eu anomaly in REE patterns indicates that the protoliths of Triassic marbles are carbonate rocks of sedimentary origin.     

Origin and Metamorphism of Corundum‐Rich Metabauxites at Mt. Ismail in the Southern Menderes Massif,SW Turkey

The corundum‐rich metabauxites, found at the northwest limb of an NE–SW‐trending isoclinal recumbent fold at Mt. Ismail, are enclosed in thick‐bedded platform‐type marbles of Late Cretaceous age, surrounding the polymetamorphic core series in the southern part of the Menderes Massif (SW Turkey). The metabauxite horizons observed as typically boudine‐like structure, extend laterally over c. 3 km and are 1 to 5 m thick. These rocks have dominant mineral assemblages of corundum (～50 modal %), chloritoid (～30 modal %), white mica (margarite, muscovite), diaspore, Fe–Ti‐Oxides (ilmenite, ilmenohematite, rutile), and goethite, limonite, pyrite, tourmaline (uvite, schorl) as minor phases. Chemical analyses of whole rock samples and the mineral assemblage indicate that coexisting minerals of metabauxites are highly aluminous. A number of minerals (e.g. chloritoid and margarite) display a large compositional variation reflecting the initial chemical inhomogenetiy of the karstbauxites. The field observations, trace‐element accumulation coefficients, concentration of elements such as Cr, Zr, Ga and Ni and low amounts of immobile elements all suggest that the studied corundum‐rich metabauxites can be classified as karstbauxites, and are more likely to be a product of weathering of intermediate igneous or argillaceous parental rocks, similar to the karstic Tauric bauxites in the Central Taurides (Seydi ?ehir region) and probably are similar in age (Cenomanian–Turonian). In respect of tectono‐metamorphic evolution, the studied corundum‐rich metabauxites were regionally metamorphosed at ～5–6 kbar pressure and 500–600°C as a consequence of the Barrovian metamorphism referred to as the ‘Main Menderes Metamorphism’ related to the ophiolitic obduction onto the Menderes platform from the Izmir–Ankara Suture during the Middle Eocene.     

Stratigraphy of Upper Cretaceous–Palaeogene sequences in the southern and eastern Menderes Massif (western Turkey)

The stratigraphy of the uppermost levels of the Menderes Massif is controversial and within its details lie vital constraints to the tectonic evolution of south-western Turkey. Our primary study was carried out in four reference areas along the southern and eastern Menderes Massif. These areas lie in the upper part of the Menderes metamorphic cover and have a clear stratigraphic relationship and contain datable fossils. The first one, in the Akbük-Milas area, is located south-east of Bafa Lake where the Milas, then KLzLla<aç and KazLklL formations are well exposed. There, the Milas formation grades upwards into the KLzLla<aç formation. The contact between the KLzLla<aç and the overlying KazLklL formation is not clearly seen but is interpreted as an unconformity. The Milas and KLzLla<aç formations are also found north of Mu<la, in the region of Yata<an and KavaklLdere. In these areas, the Milas formation consists of schists and conformably overlying platform-type, emery and rudist-bearing marbles. Rudists form the main palaeontological data from which a Santonian-Campanian age is indicated. The KLzLla<aç formation is characterized by reddish-greyish pelagic marbles with marly-pelitic interlayers and coarsening up debris flow deposits. Pelagic marbles within the formation contain planktonic foraminifera and nanoplankton of late Campanian to late Maastrichtian age. The KazLklL formation is of flysch type and includes carbonate blocks. Planktonic foraminifera of Middle Palaeocene age are present in carbonate lenses within the formation. In the Serinhisar-Tavas area, Mesozoic platform-type marbles (YLlanlL formation) belonging to the cover series of the Menderes Massif exhibit an imbricated internal structure. Two rudist levels can be distinguished in the uppermost part of the formation: the first indicates a middle-late Cenomanian age and the upper one is Santonian to Campanian in age. These marbles are unconformably covered by the Palaeocene-Early Eocene Zeybekölentepe formation with polygenetic breccias. In the Çal-Denizli area, the Menderes massif succession consists of cherty marbles and clastic rocks with metavolcanic lenses. The Lower-Middle Eocene zalvan formation lies unconformably on this sequence and is interpreted as equivalent to the marble horizons at Serinhisar but with pelagic facies. The zalvan formation consists of shale, mafic volcanic rock, lenses of limestone and blocks of recrystallized limestone. The zalvan formation is dated here for the first time by Early-Middle Eocene foraminifera and nanoplankton from the matrix of the formation. An angular unconformity exists between the Upper Cretaceous and Lower Tertiary sequences, suggesting that a phase of deformation affected the southern and eastern part of the Menderes Massif at this time. This deformation may be caused by initial obduction of the Lycian ophiolite onto the passive margin to the north of the Menderes carbonate platform during the latest Cretaceous. Drowning of the platform led to termination of carbonate deposition and deposition of deep water flysch-like clastic sediments.     

Late Alpine evolution of the central Menderes Massif, western Turkey

The central Menderes Massif (western Turkey) is characterized by an overall dome-shaped Alpine foliation pattern and a N-NNE-trending stretching lineation. A section through the southern flank of the central submassif along the northern margin of Büyük Menderes graben has been studied. There, asymmetric non-coaxial fabrics indicate that the submassif has experienced two distinct phases of Alpine deformation: a top-to-the N-NNE contractional phase and a top-to-the S-SSW extensional event. The former fabrics are coeval with a regional prograde Barrovian-type metamorphism at greenschist to upper-amphibolite facies conditions. This event, known as the main Menderes metamorphism, is thought to be the result of internal imbrication of the Menderes Massif rocks along south-verging thrust sheets during the collision of the Sakarya continent in the north and the Anatolide-Tauride platform in the south across the Gzmir-Ankara suture during the (?)Palaeocene-Eocene. Top-to-the S-SSW fabrics, represented by a well-developed ductile shear band foliation associated with inclined and/or curved foliation, asymmetric boudins, and cataclasites, were clearly superimposed on earlier contractional fabrics. These fabrics are interpreted to be related to a low-grade (greenschist?) retrogressive metamorphism and a continuum of deformation from ductile to brittle in the footwall rocks of a south-dipping, presently low-angle normal fault that accompanied Early Miocene orogenic collapse and continental extension in western Turkey. A similar tectono-metamorphic history has been documented for the northern flank of the dome along the southern margin of the Gediz graben with top-to-the N-NNE extensional fabrics. The exhumation of the central Menderes Massif can therefore be attributed to a model of symmetric gravity collapse of the previously thickened crust in the submassif area. The central submassif is thus interpreted as a piece of ductile lower-middle crust that was exhumed along two normal-sense shear zones with opposing vergence and may be regarded as a typical symmetrical metamorphic core complex. These relationships are consistent with previous models that the Miocene exhumation of the Menderes Massif and Cycladic Massif in the Aegean Sea was a result of bivergent extension.     

Sm-Nd isotope and trace element evidence for heterogeneous igneous protoliths of Variscan mafic blueschists in the East Krkonoše Complex (West Sudetes,NE Bohemian Massif,Czech Republic)

Granitoid rocks of the southern Menderes Massif, SW Turkey include widespread possibly Ediacaran high-grade granitic orthogneisses and younger (Tertiary) sheets, sills and/or dikes of variably deformed tourmaline-bearing leucogranites. The latter are confined to the immediate footwall of the regional-scale ductile southern Menderes shear zone. Although both sets of granitoid rocks are essentially calc-alkaline and peraluminous, the syn- to post-collisional tourmaline-bearing leucogranites are chemically distinguishable from both the granitoid orthogneisses and from two sets of mostly sodic siliceous dyke rocks. The leucogranites were generated by partial melting induced by shear heating during the waning stages of the Eocene main Menderes metamorphism and associated top-to-the-NNE thrusting along the southern Menderes ductile shear zone, which transported schists northwards over the granitoid orthogneisses of the core Menderes complex. Upward migration and emplacement of leucogranitic melt weakened formerly sheared rocks, so that when thrust-related deformation ceased it facilitated rapid crustal extension along the shear zone. The emplacement of leucogranites, in turn, promoted the reactivation of the southern Menderes shear zone as a top-to-the-SSW extensional feature. Continued extensional deformation affected the leucogranites which became parallel to the shear-zone foliation; local S-C fabrics were also generated. The additional occurrence of less or almost undeformed leucogranites suggests that the latest stages of extension might have induced adiabatic decompressional melting. Hence the leucogranite melt generation and emplacement in the southern Menderes Massif occurred in pulses. Both compressional and extensional processes played key roles in melt generation, emplacement, deformation and exhumation of the massif.

A clear distinction may also be made between the composition of granite-hosted tourmalines and those from metasedimentary schists. Tourmalines from a pebble of uncertain provenance in the Gökçay metaconglomerate plotted with schist-hosted tourmalines, suggesting that it was unlikely to be derived from granitoid gneiss. This crucial piece of evidence suggests that the presence of a major (Pan-African) unconformity at the so-called “core (orthogneiss)-cover (schist)” boundary in the southern Menderes Massif is unnecessary.     

Performance Prediction of Large-Diameter Circular Saws Based on Surface Hardness Tests for Mugla (Turkey) Marbles

Surface hardness tests such as Shore hardness (SH) and Schmidt hammer rebound hardness (SR) may provide a quick and inexpensive measure of rock hardness, which may be widely used for estimating the mechanical properties of rock material such as strength, sawability, drillability and cuttability. In the marble industry, circular sawing with diamond sawblades constitutes a major cost in the processing. Therefore, several models based on the relations between hourly slab production (P _hs), rock surface hardness (SH and SR) and mineral grain size (S _cr) were developed using the data obtained from field and laboratory measurements on five different marbles quarried in the Mugla Province of Turkey. The models which include surface hardness and crystal size may as well be used for the prediction of sawability (hourly slab production) of carbonate rocks using large-diameter circular saws.     

Presence and tectonic significance of Cretaceous rudist species in the so-called Permo-Carboniferous Göktepe Formation,central Menderes metamorphic massif,western Turkey

A schist sequence of the central Menderes Massif, in which lenses of fossiliferous marbles are found, is observed in the southern flank of the Aydn Mountain, north of Kök (Aydn), around Erikavak village. These rocks have been considered as Permo-Carboniferous in age and are included in the Göktepe Formation of earlier studies. However, some rudist species are described from thickly bedded gray marbles that have a concordant contact with the overlying schist sequence. Although the rudists have been metamorphosed, it is observed that some contain fossils are well enough preserved to determine the following rudist fauna: Hippurites lapeirousei (GOLDFUSS), Hippurites nabresinensis FUTTERER, Hippurites cf. colliciatus WOODWARD. This rudist fauna dates the schist sequence as Santonian–Campanian. The schist sequence is overlain by a thick tectonostratigraphic pile of orthogneiss which has been interpreted as the Pan-African metamorphic core of the Menderes Massif. A widespread cataclastic and mylonitic zone is present between the underlying rudist-bearing marbles and the structurally overlying orthogneiss sequence. The existing kinematic studies in the footwall and hangingwall of this tectonic contact reveal two different phases of deformations, a contractional phase followed by an extensional phase. During the contractional event, which occurred at 36 Ma, the orthogneiss sequence was thrust faulted northwards over the schist sequence. This thrust fault was later reactivated as a low-angle normal fault beneath a supradetachment sedimentary basin of Early-Middle Miocene age. The fossil discoveries of this study and the existing kinematic studies reveal that a new structural model for the central Menderes Massif in which the tectonometamorphic units form a major southward closing recumbent fold needs to be reviewed.     

High-pressure–low-temperature metamorphism of metasedimentary rocks, southern Menderes Massif, western Turkey

Kilometer-scale lenses of quartz-rich metasedimentary rocks crop out in a discontinuous belt along the southern margin of the Menderes Massif, Turkey, and preserve evidence for high-pressure–low-temperature (HP–LT) metamorphism related to subduction of a continental margin during Alpine orogeny. Kyanite schist, quartzite, and quartz veins contain kyanite + phengite + Mg-chlorite, and the veins also contain magnesiocarpholite. A deformed carbonate metaconglomerate juxtaposed with the quartzite-dominated unit does not contain HP index minerals, and likely represents the tectonized boundary of the siliceous rocks with adjacent marble. The HP–LT rocks (10–12 kbar, 470–570 °C) record different pressure conditions than the adjacent, apparently lower pressure Menderes metasedimentary sequence. Despite this difference there is disagreement as to whether these HP–LT rocks are part of the Menderes sequence or are related to the tectonically overlying Cycladic blueschist unit. If the former, the entire southern Menderes Massif experienced HP–LT metamorphism but the evidence has been obliterated from most rocks; if the latter, rocks recording different metamorphic-kinematic conditions experienced different tectonic histories and were tectonically juxtaposed during thrusting. Based on observations and data in this study, the second model better accounts for the differences in P–T-deformation histories of the southern Menderes Massif rocks, and suggests that the HP–LT rocks are not part of the Menderes cover sequence.     

Granitoid rocks of the southern Menderes Massif (southwestern Turkey): field evidence for Tertiary magmatism in an extensional shear zone

Recent field campaign in the southern Menderes Massif in southwestern Turkey revealed that the so-called ‘core of the massif’ comprises two distinct types of granitoid rocks: an orthogneiss (traditionally known as augen gneisses) and leucocratic metagranite, where the latter is intrusive into the former and the structurally overlying ‘cover’ schists. These differ from one another in intensity of deformation, degree of metamorphism and kinematics. The orthogneiss display penetrative top-to-the-N–NNE fabrics formed under upper-amphibolite facies conditions during the Eocene main Menderes metamorphism (MMM), whereas foliation and stretching lineation exists in the leucocratic metagranites but are not strongly developed. The leucocratic metagranites show evidence of syn- to post-emplacement deformation in a series of weakly developed top-to-the-S–SSW fabrics formed under lower greenschist-facies (?) conditions. Leucocratic metagranite bodies occur all along the augen gneiss–schist contact in the southern Menderes Massif; they are emplaced as sheet-like bodies into country rocks (previously deformed and metamorphosed during a top-to-the-N–NNE Alpine orogeny) along a ductile extensional shear zone, located between orthogneisses and metasediments, which was possibly active during emplacement. The data presently available indicate that emplacement and associated ductile extensional deformation occurred during Late Oligocene–Early Miocene time. These results confirm previous contentions that there are Tertiary granites in this part of the Menderes Massif.     

Stratigraphic and metamorphic inversions in the central Menderes Massif: a new structural model

The Menderes Massif is a large area of dominantly Tertiary metamorphic rocks in western Turkey. It is bordered in the west by the Cycladic Metamorphic Complex with Eocene high-pressure/low-temperature (HP/LT) metamorphism. In the Central Menderes the AydLn mountains are made up of a thrust stack of Eocene age. At the base of the thrust stack, greenschist-facies Paleozoic metasediments of the Menderes Massif form an inverted stratigraphic sequence. The Barrovian-type metamorphism is also inverted with garnet-bearing metapelites lying over the lower-grade biotite-bearing metapelites. The P-T conditions in the garnet zone are estimated as 530°C and 8 kbar. This schist sequence of the central Menderes Massif is interpreted as the inverted lower limb of a major southward closing recumbent fold, with the southern Menderes Massif representing a section from the near hinge of this fold. The Paleozoic metamorphic rocks of the central Menderes Massif are tectonically overlain by gneiss klippen possibly originating from the sheared and southward translated core of the Menderes fold. Lying also tectonically over the Paleozoic metamorphic rocks is a major thrust sheet belonging to the Cycladic metamorphic complex. It consists of garnet micaschist, Mesozoic marble, serpentinite and amphibolitised eclogite. Although it has a highly sheared internal structure, it probably represents an initially coherent sequence that has undergone HP/LT metamorphism during the Eocene. The AydLn mountains are dominated by contractional structures with subordinate extensional structures.     

Discovering the stone heritage of southern Italy: technical properties of the Mondragone marble from Campania region

The results of the geological characterization of an old stone building in southern Italy, are presented here. The Mondragone marble is a slightly metamorphosed carbonate rock, which was widely employed as monumental stone in the 18th century Royal Palaces of Naples and Caserta. In this paper, for the first time, this rock has been investigated with a thorough laboratory testing program, aimed at defining its mineralogical, physical and mechanical parameters. The two most important varieties of Mondragone marble were separately tested: the yellow and grey marbles (hereafter, YM and GM, respectively). The results obtained from physical tests (open porosity, dry density, specific gravity, water absorption coefficients, ultrasonic velocity) did not show marked differences between the two materials; in contrast, the mechanical strength tests (uniaxial compressive strength, point load strength, flexural strength) showed better behaviour of YM than for GM. After a tentative comparison with other well known carbonate rocks from Italy, some considerations on the response of Mondragone marble to local weathering were conducted. In particular, the weathering typologies were related to the particular texture of the brecciated marble and the different strength resistances displayed by the various constituents of the rock.     

Mixing of geothermal and non-geothermal fluids in shallow aquifers in the Germencik-Nazilli area,Büyük Menderes Basin (SW Turkey)

This study observes groundwater hydrochemical characteristics during mixing between geothermal and non-geothermal fluids in Germencik–Nazilli area in the Büyük Menderes Basin (SW Turkey). Hydrogeochemical features of 32 non-geothermal, geothermal and surface samples were studied. The mean temperatures of the geothermal reservoirs are calculated to be 150–240 °C in Germencik field, based on Na-K-Mg geothermometry. Hydrochemical characteristics of Germencik geothermal fluid differ from non-geothermal fluids, mainly Na-Cl-HCO₃-type geothermal fluid, while non-geothermal fluid is mostly Ca-Mg-HCO₃-SO₄ type. High contents of some minor elements in geothermal fluids are most likely sourced from prolonged water-rock interaction, reflecting the signals of flow paths and residence times. A mass-balance approach was used to calculate mixing ratios between geothermal and non-geothermal fluids based on B, Cl and Na concentrations. Germencik field is considerably characterised by rising geothermal fluids and overlying non-geothermal fluids. The amount of water stored in the Quaternary aquifer evolved from a deep thermal source is low in Germencik (.5–40% geothermal fluid in non-geothermal wells). Mixing between geothermal and non-geothermal fluids has been caused by groundwater utilisation practices and is increased close to active faults. Irrigation of the shallow groundwater composition is considered as influx of low-temperature geothermal fluid.     

Effect of Construction Material on Dam Type Selection of the Büyük Karaçay Dam (Hatay, Turkey)

This paper covers the investigation of construction materials and selection of the dam type for the Büyük Karaçay Dam, which was planned to be constructed on Büyük Karaçay River 20 km to the SW of Hatay (Southern Turkey). The purposes of the dam are irrigation, domestic water supply, and producing energy. Auxiliary structures locations have been determined during the study of detailed geological maps of the dam axis and reservoir area. Quality, quantity and hauling distance of natural construction materials were effective to select different dam types. For engineering geological studies exploration boreholes were drilled at the dam site; pressuremeter tests were performed in order to determine bearing capacity and elasticity properties of rocks; pressured water tests were also performed to determine permeability of the dam site. Moreover, physical and mechanical properties of rocks were determined by the laboratory test. In the feasibility stage, the dam type was chosen as the central core rock-fill dam, depending on state of natural construction materials. In design stage dam type was changed as faced symmetrical hardfill dam. Finally, the dam type was revised again during the design stage as concrete face rockfill dam.     

Tertiary evolution of the central Menderes Massif based on structural investigations of metamorphics and sedimentary cover rocks between Salihli and Kiraz (western Turkey)

Augen gneisses, mica schists, and marbles of the Menderes Massif and its sedimentary cover rocks are exposed south of the Gediz graben. The augen gneisses form the structurally lowest part of the studied lithological sequence, and are overlain by a schist complex. The structurally highest part is formed by a series of marbles. The ages of this lithological sequence range from Precambrian to Early Paleocene. Furthermore, this sequence records the tectonic evolution since the Precambrian. The sedimentary cover of the Menderes Massif consists of two groups of sediments from Early Miocene to Quaternary. The lower group, the Alayehir group, consists of Early- to mid-Miocene-aged fluvial and limnic sediments which form the lower and the upper parts, respectively. The Alayehir group is overlain by mainly fluvial sediments of the Gediz group. Both the Alayehir and the Gediz groups are separated by an angular unconformity. Six deformational phases could be distinguished within the metamorphic rocks of the Menderes Massif and its Tertiary cover. The structures which were interpreted to belong to deformational events predating the Paleocene are summarized as deformational phase D1. D1 structures were nearly completely overprinted by the subsequent deformation events. The second deformational phase D2 occurred between Early Eocene and Early Oligocene. D2 occurred contemporaneously with a Barrovian-type regional metamorphism. The third deformational phase D3 is characterized by folding of the axial planes which formed at the end of Early Oligocene. The deformational event D4 occurred during the Late Oligocene and is related to an extensional period. The deposition of the sedimentary rocks which belong to the Tertiary cover of the Menderes Massif that started in the Early Miocene was interrupted by a compressional phase (D5) during the Late Miocene. Sediments which were deposited since the Early Pliocene record structures which were related to a young extensional phase (D6). This extensional phase has continued to the Present.     

Hydrogeochemical and hydrogeological investigations of thermal waters in the Usak Area (Turkey)

Thermal waters of the Usak area have temperatures ranging from 33 to 63°C and different chemical compositions. These waters hosted by the Menderes Metamorphic rocks emerge along fault lineaments from two geothermal reservoirs in the area. The first reservoir consists of gneiss, schists, and marbles of the Menderes Metamorphic rocks. The recorded reservoir is Pliocene lacustrine limestone. Hydrogeochemical studies indicate that thermal waters were mixed with surface waters before and/or after heating at depth. The results of mineral equilibrium modeling indicate that all the thermal waters are undersaturated at discharge temperatures for gypsum, anhydrite, and magnesite minerals. Calcite, dolomite, aragonite, quartz, and chalcedony minerals are oversaturated in all of the thermal waters. Water from the reservoir temperatures of the Usak area can reach upto120°C. According to δ¹⁸O and δ²H values, all thermal and cold groundwater are of meteoric origin.     

Geochemical and geochronological evidence for Early Triassic calc-alkaline magmatism in the Menderes Massif, western Turkey

Pan-African basement rocks and a Paleozoic cover series, which were intruded by the protoliths of leucocratic orthogneisses, have been recognized in the Menderes Massif, located in the western part of the Alpine orogenic belt of Turkey. This geochemical and geochronological study focuses on the evolution of the Menderes Massif at the end of Paleozoic time. Geochemical data suggest that the crustally derived leucocratic orthogneisses have chemical composition typical of calc-alkaline and S-type granite. Zircon grains which are euhedral with typical igneous morphologies were dated by the ²⁰⁷Pb/²⁰⁶Pb evaporation method. Single-zircon dating of three samples yielded mean ²⁰⁷Pb/²⁰⁶Pb ages of 246LJ, 241LJ and 235Lj Ma. These ages are interpreted as the time of protolith emplacement in Triassic. Geological and geochronological data suggest that leucocratic granites were emplaced in a period following a metamorphic event related to the closure of the Paleo-Tethys. The leucocratic granites were metamorphosed during the Alpine orogenesis and transformed into orthogneisses. The similar Triassic magmatic event at 233DŽ Ma was also occurred, using single-zircon evaporation method, from granitic gneisses which rest upon the migmatites with tectonic contacts in Naxos, Cycladic complex. This indicates that the Menderes Massif and Cycladic complex had a common pre-Early Triassic magmatic evolution.     

Tectonic significance of mafic volcanic rocks in a Mesozoic sequence of the Menderes Massif, West Turkey

The Mesozoic platform sequence of the Menderes Massif consists of thick succession of detrital and carbonate rocks. In this sequence there are mafic metavolcanic rocks at two different levels. The first level of mafic metavolcanic intercalations is in the Late Triassic detrital-rich series located in the ÇaltayL Formation, which is the lowermost unit of the Mesozoic platform. The second level of the mafic metavolcanic rocks is located in the Late Cretaceous-(?)Paleocene Selçuk Formation laying on top of the platform sequence. The ÇaltayL Formation, which is composed of mica-schists, thinly-bedded cherts, calc-schist and mafic volcanic intercalations unconformably overlie the BayLndLr Formation, which consists of mica-schists, phyllites, and white quartzites of Palaeozoic or probably older age. The mafic volcanic rocks in the ÇaltayL Formation are alkaline basalts with within plate characteristics and are formed during an intraplate extension. The ÇaltayL Formation is conformably overlain by the KayaaltL Formation represented by calc-schists, dolomitic marbles, and rudist- and emery-bearing massive marbles in ascending order. The Selçuk Formation overlies the KayaaltL Formation and consists of a mica-schist matrix with allochthonous blocks of mafic volcanic rocks, metaperidotites, metagabbros and massive marbles. The mafic volcanic rocks in the Selçuk Formation are tholeiitic basalts and are petrologically similar to mid-oceanic basalts. The geological and geochemical characteristics of the mafic metavolcanic rocks in the ÇaltayL Formation indicate that during the Late Triassic, the Menderes platform was segmented, probably by the opening of a branch of the Neotethyan Ocean. Between the Late Triassic and the Late Cretaceous, the Menderes carbonate platform was built up. During the Latest Cretaceous-Early Paleocene, a slab of oceanic crust obducted on this platform and provided slices of mafic metavolcanic rocks into the Selçuk Formation.     

Evidence from the Mesta half-graben, SW Bulgaria, for the Late Eocene beginning of Aegean extension in the Central Balkan Peninsula

The ENE-tilted Mesta half-graben contains a 3-km-thick section of Priabonian (Late Eocene) to Oligocene sedimentary and volcanic rocks that rest unconformably on basement metamorphic rocks along its west side. Basal strata dip 50–60° E and dip at progressively lower angles upward, indicating synrotational deposition. The southern part of the half-graben contains nested volcanic caldera complexes, formed during the deposition of the middle part of the sedimentary sequence, which have been rotated by about half the total rotation of the sedimentary succession. The half-graben is bounded on the east by a fault that steepens from more deeply exposed structural levels in the south (8–18° W) to shallower exposed structural levels in the north (70° W) and together with the rotation of Paleogene strata during deposition indicate the Mesta half-graben is underlain by a listric detachment fault, the Mesta detachment. Subhorizontal Middle Miocene strata that unconformably overlie tilted Paleogene strata yield an upper age limit to the extension. West and northwest of the Mesta half-graben are many other NNW-trending NE-tilted Paleogene half-grabens which we suggest are part of an important extended area in SW Bulgaria and eastern Macedonia that lies above one or more west-dipping detachment faults and date the beginning of Aegean extension in the southern Balkan region as at least as old as Priabonian. The Mesta detachment is oblique to the trend of a contemporaneous Paleogene magmatic arc in the southern Balkans and the origin of the detachment is probably related to gravitationally induced spreading of thickened hot arc crust and Hellenic trench roll back.