Molybdenite Re–Os and albite Ar/Ar dating of Cu–Au–Mo and magnetite porphyry systems in the Yangtze River valley and metallogenic implications

The area of the Middle–Lower Yangtze River valley, Eastern China, extending from Wuhan (Hubei province) to western Zhenjiang (Jiangsu province), hosts an important belt of Cu–Au–Mo and Fe deposits. There are two styles of mineralization, i.e., skarn/porphyry/stratabound Cu–Au–Mo–(Fe) deposits and magnetite porphyry deposits in several NNE-trending Cretaceous fault-bound volcanic basins. The origin of both deposit systems is much debated. We dated 11 molybdenite samples from five skarn/porphyry Cu–Au–Mo deposits and 5 molybdenite samples from the Datuanshan stratabound Cu–Au–Mo deposit by ICP-MS Re–Os isotope analysis. Nine samples from the same set were additionally analyzed by NTIMS on Re–Os. Results from the two methods are almost identical. The Re–Os model ages of 16 molybdenite samples range from 134.7 ± 2.3 to 143.7 ± 1.6 Ma (2σ). The model ages of the five samples from the Datuanshan stratabound deposit vary from 138.0 ± 3.2 to 140.8 ± 2.0 Ma, with a mean of 139.3 ± 2.6 Ma; their isochron age is 139.1 ± 2.7 Ma with an initial Os ratio of 0.7 ± 8.1 (MSWD = 0.29). These data indicate that the porphyry/skarn systems and the stratabound deposits have the same age and suggest an origin within the same metallogenic system. Albite ⁴⁰Ar/³⁹Ar dating of the magnetite porphyry deposits indicates that they formed at 123 to 125 Ma, i.e., 10–20 Ma later. Both mineralization styles characterize transitional geodynamic regimes, i.e., the period around 140 Ma when the main NS-trending compressional regime changed to an EW-trending lithospheric extensional regime, and the period of 125–115 Ma of dramatic EW-trending lithospheric extension.     

Evaluation of fluidized bed asbestos segregator to determine erionite in soil

Three sets of soil samples were collected by the National Institute for Occupational Safety and Health and one set by South Dakota School of Mines & Technology from in and around the Slim Buttes Land Unit of the Sioux Ranger District of the Custer–Gallatin National Forest in the northwest of South Dakota. The rocks forming the Slim Buttes are sedimentary clays, sands and gravels including re-worked volcanic ash-falls in which the zeolite mineral erionite has crystallized during diagenesis in a fibrous form or morphology similar to that of asbestos. The samples were prepared using the fluidized bed asbestos segregator (FBAS) and analyzed by phase contrast microscopy (PCM) or transmission electron microscopy to detect the presence of mineral fibers. FBAS–PCM results compared to semi-quantitative polarized light microscopy (PLM) and X-ray diffraction analysis indicated a recovery of approximately 1% and a linear relationship that likely can be extrapolated to concentrations well below the 1% detection limit of PLM. There were small variations between a PCM count of 10 fibers to a count of 100 fibers (or a maximum of 200 microscopic fields of view), which indicates the possibility of rapid turnaround of results. Although the four sets of samples examined in this work were collected by slightly different techniques, some tentative conclusions can be drawn about the distribution of erionite in soils. Erionite was detected in almost every soil sample, even those taken several miles from the outcrop, but without any distribution indicating recent transportation from the current volcaniclastic sediment outcrops. Removal of more extensive volcaniclastic sediments through erosion may have resulted in remnant material in soils, including erionite crystals, but this possibility requires further study. Although we have demonstrated that erionite in soils can be detected through FBAS–PCM, we have not attempted to correlate those results with human inhalation exposure through activity-based sampling, and thus, any risk inherent in working these soils is unknown.     

Confidence levels for tsunami-inundation limits in northern Oregon inferred from a 10,000-year history of great earthquakes at the Cascadia subduction zone

To explore the local tsunami hazard from the Cascadia subduction zone we (1) evaluate geologically reasonable variability of the earthquake rupture process, (2) specify 25 deterministic earthquake sources, and (3) use resulting vertical coseismic deformations for simulation of tsunami inundation at Cannon Beach, Oregon. Maximum runup was 9–30 m (NAVD88) from earthquakes with slip of ~8–38 m and M _w ~8.3–9.4. Minimum subduction zone slip consistent with three tsunami deposits was 14–15 m. By assigning variable weights to the source scenarios using a logic tree, we derived percentile inundation lines that express the confidence level (percentage) that a Cascadia tsunami will not exceed the line. Ninety-nine percent of Cascadia tsunami variation is covered by runup ≤30 m and 90% ≤16 m with a “preferred” (highest weight) value of ~10 m. A hypothetical maximum-considered distant tsunami had runup of ~11 m, while the historical maximum was ~6.5 m.     

Chert and its sodium-silicate precursors in sodium-carbonate lakes of East Africa

Chert has formed from two sodium-silicate minerals, magadiite (NaSi₇,O₁₃(OH)₃·3H₂O) and kenyaite (NaSi₁₁O_20.5(OH)₄·3H₂O), in uppermost Pleistocene deposits of lakes Magadi and Natron in Kenya and Tanzania. The chert consists of finely crystalline quartz and characteristically forms nodules of irregular shape with white coatings having reticulate surface patterns. Similar nodules are widespread in lower and middle Pleistocene lacustrine deposits in the vicinity of Lake Magadi, Lake Natron, and Olduvai Gorge. Although magadiite and kenyaite are absent in the lower and middle Pleistocene deposits, the chert in these beds probably formed from a sodium-silicate precursor. All of the chert-bearing sediments were deposited in saline, alkaline lakes rich in dissolved sodium carbonate-bicarbonate.Magadiite (and chert) may form either thin, widespread deposits or localized masses which may be cross-cutting. Thin, widespread layers of magadiite have been precipitated by mixing of silica-rich brine with fresh water in a chemically stratified lake; localized masses may have been formed by interaction of brine with fresher water entering the floor or margin of the lake. Magadiite and kenyaite can alter to chert in contact with sodium-carbonate brine and possibly by leaching with relatively fresh water over a period of 20,000 years or less.The siliceous zeolites clinoptilolite and erionite predominate in trachyte tuffs associated with magadiite and chert; less-siliceous phillipsite predominates in trachyte tuffs of chert-free sequences.     

Molybdenite Re–Os and albite 40Ar/39Ar dating of Cu–Au–Mo and magnetite porphyry systems in the Yangtze River valley and metallogenic implications

The area of the Middle–Lower Yangtze River valley, Eastern China, extending from Wuhan (Hubei province) to western Zhenjiang (Jiangsu province), hosts an important belt of Cu–Au–Mo and Fe deposits. There are two styles of mineralization, i.e., skarn/porphyry/stratabound Cu–Au–Mo–(Fe) deposits and magnetite porphyry deposits in several NNE-trending Cretaceous fault-bound volcanic basins. The origin of both deposit systems is much debated. We dated 11 molybdenite samples from five skarn/porphyry Cu–Au–Mo deposits and 5 molybdenite samples from the Datuanshan stratabound Cu–Au–Mo deposit by ICP-MS Re–Os isotope analysis. Nine samples from the same set were additionally analyzed by NTIMS on Re–Os. Results from the two methods are almost identical. The Re–Os model ages of 16 molybdenite samples range from 134.7 ± 2.3 to 143.7 ± 1.6 Ma (2σ). The model ages of the five samples from the Datuanshan stratabound deposit vary from 138.0 ± 3.2 to 140.8 ± 2.0 Ma, with a mean of 139.3 ± 2.6 Ma; their isochron age is 139.1 ± 2.7 Ma with an initial Os ratio of 0.7 ± 8.1 (MSWD = 0.29). These data indicate that the porphyry/skarn systems and the stratabound deposits have the same age and suggest an origin within the same metallogenic system. Albite ⁴⁰Ar/³⁹Ar dating of the magnetite porphyry deposits indicates that they formed at 123 to 125 Ma, i.e., 10–20 Ma later. Both mineralization styles characterize transitional geodynamic regimes, i.e., the period around 140 Ma when the main NS-trending compressional regime changed to an EW-trending lithospheric extensional regime, and the period of 125–115 Ma of dramatic EW-trending lithospheric extension.     

Methods of Three-part Quantitative Assessments of Undiscovered Mineral Resources: Examples from Victoria,Australia

Quantitative mineral resource assessments following the 3-part form rely on grade and tonnage models and probabilistic estimates of the number of undiscovered deposits. Assessments completed in Victoria, Australia, indicate that undiscovered mineral resources can be effectively estimated using grade and tonnage sub-models constructed using only medium- and large-tonnage deposits. Numbers of undiscovered deposits can be estimated on the basis of expert judgement or entirely by statistical means. Appropriate mathematical aggregation of individual expert views, expressed at interactive expert workshops, provides robust estimates of the number of undiscovered deposits. Underestimation of uncertainty, which is common in expert judgement, can be compensated by the statistical modification of individual interval estimates. In this study, the linear opinion pool was used as a simple and robust method of mathematical aggregation of multiple expert estimates of the number of undiscovered deposits. A general regression model, which estimates numbers of undiscovered deposits based on the size of the geologically permissive area and the median deposit tonnage, provided results generally compatible with those based on expert judgement or local deposit density models.     

Re–Os pseudo-isochron of disseminated ore from the Kalatongke Cu–Ni sulfide deposit,Xinjiang, Northwest China: Implications for Re–Os dating of magmatic Cu–Ni sulfide deposits

Re–Os dating of disseminated ore from the Kalatongke Cu–Ni sulfide mineral deposit, Xinjiang, Northwest (NW) China, yields an apparent isochron age of 433 ± 31 Ma with an apparent initial ¹⁸⁷Os/¹⁸⁸Os (433 Ma) ratio of 0.197 ± 0.027. This apparent age is older than not only the zircon U–Pb age of the host intrusion (287 ± 5 Ma, Han et al., 2004) but also the stratigraphic age of the intruded country rock. Thus, the regression line is a pseudo-isochron. However, previous Re–Os dating of massive ores of the same deposit yielded an age that is consistent, within analytical uncertainty, with the zircon U–Pb age (Zhang et al., 2008). This relationship is similar to that observed in the Jinchuan deposit, NW China. Therefore, we suggested that the same mechanism, post-segregation diffusion of Os (Yang et al., 2008), is applicable to the Kalatongke deposit.Re–Os isotopic studies of Kalatongke, Jinchuan and representative magmatic Cu–Ni sulfide deposits suggest that the massive ores of mafic–ultramafic-rock-associated Cu–Ni sulfide deposits would yield geologically meaningful Re–Os age, whereas a pseudo-isochron would be obtained for the disseminated ores. Therefore, to obtain a geologically meaningful Re–Os age, the type of the deposit, the type of the ore and the ore-forming process should be taken into account.     

Geochemical hazard evaluation of sulphide-rich iron mines: The Rio Marina district (Elba Island,Italy)

Rio Marina mining district (Elba Island) is characterised by hematite + pyrite ore association and was exploited for iron till 1981, leaving waste rock dumps of several millions m³. The effect of open pit mining activity in this site is to produce acid mine drainage (AMD) processes leading to environmental pollution, testified by all the sampled waters (Giove stream, drainage channels, superficial pools and settling basin) which have pH values ranging from 2.08 to 3.35 and heavy metal concentrations that reach 903.16 mg/l for Fe, 45.02 mg/l for Mn, 10.08 mg/l for Zn and 1.75 mg/l for Cu. In the present work a space and time related approach to geochemical hazard evaluation was applied. The geochemical hazard is mainly related to high heavy metal concentration, acid mine drainage processes development and topographic setting. As all these parameters are related in space, hazard evaluation was performed by geostatistical methods. Fifty-four earth material samples (residual soils, waste rocks or debris materials) were collected in a central aligned 100 m mesh square grid. These were analysed for major elements by XRF, for Cu, Pb, Zn by ICP-AES and for AMD potential following the AMIRA procedure. The concentration of heavy metals was compared with Italian law limits. The overlap of Cu, Pb and Zn content maps show that at least one of these heavy metals exceed law limits in all the area. The AMD test results show that more than 50% of samples have a positive NAPP (Net Acid Producing Potential) that could reach 258.9 kg H₂SO₄/t. According to the obtained data, three main geochemical hazard classes were established and their distribution in the mining area was assessed. About 51% of the mining area surface belongs to the major hazard class, where AMD process occurs, about 49% belongs to an intermediate hazard class, where AMD process could occur only if certain conditions are met. Finally, the persistence of the AMD process in the Rio Marina area was evaluated on the basis of yearly rainfall, mining waters pH and NAPP values. A complete leaching of the first 0.25 m of the earth materials can retain the current environmental conditions for several centuries.     

Pleistocene sea‐floor fibrous crusts and spherulites in the Danakil Depression (Afar,Ethiopia)

Pleistocene fibrous aragonite fabrics, including crusts and spherules, occur in the Danakil Depression (Afar, Ethiopia) following the deposition of two distinctive Middle and Late Pleistocene coralgal reef units and pre‐dating the precipitation of evaporites. Crusts on top of the oldest reef unit (Marine Isotope Stage 7) cover and fill cavities within a red algal framework. The younger aragonite crusts directly cover coralgal bioherms (Marine Isotope Stage 5) and associated deposits. Their stratigraphic position between marine and evaporitic deposits, and their association to euryhaline molluscs, suggest that the crusts and spherules formed in restricted semi‐enclosed conditions. The availability of hard substrate controls crust formation with crusts more often found on steep palaeo‐slopes, from sea level up to at least 80 m depth, while spherules mainly occur associated with mobile substrate. Crusts reach up to 30 cm in thickness and can be microdigitate, columnar (branching and non‐branching) or non‐columnar, with laminated and non‐laminated fabrics. Two different lamination types are found within the crystalline fabrics: (i) isopachous lamination; and (ii) irregular lamination. These two types of lamination can be distinguished by the organization of the aragonite fibres, as well as the lateral continuity of the laminae. Scanning electron microscopy with energy dispersive X‐ray spectroscopy analyses on well‐preserved samples revealed the presence of Mg‐silicate laminae intercalated with fibrous aragonite, as well as Mg‐silicate aggregates closely associated with the fibrous aragonite crusts and spherules. The variety of observed fabrics results from a continuum of abiotic and microbial processes and, thus, reflects the tight interaction between microbially mediated and abiotic mineralization mechanisms. These are the youngest known isopachously laminated, digitate and columnar branching fibrous crusts associated with a transition from marine to evaporitic conditions. Understanding the context of formation of these deposits in Afar can help to better interpret the depositional environment of the widespread Precambrian sea‐floor precipitates.     

The age of supergene manganese deposits in Katanga and its implications for the Neogene evolution of the African Great Lakes Region

Supergene manganese deposits commonly contain K-rich Mn oxides with tunnel structure, such as cryptomelane, which are suitable for radiometric dating using the ³⁹Ar–⁴⁰Ar method. In Africa, Mn deposits have been dated by this method for localities in western and southern parts of the continent, whereas only some preliminary data are available for Central Africa. Here we present new ³⁹Ar–⁴⁰Ar ages for Mn oxide samples of the Kisenge deposit, in southwestern Katanga, Democratic Republic of the Congo. The samples represent supergene Mn oxide deposits that formed at the expense of primary Paleoproterozoic rhodochrosite-dominated carbonate ores. Main phases of Mn oxide formation are dated at c. 10.5 Ma, 3.6 Ma and 2.6 Ma for a core that crosses a mineralized interval. The latter shows a decrease in age with increasing depth, recording downward penetration of a weathering front. Surface samples of the Kisenge deposits also record a ≥ c.19.2 Ma phase, as well as c. 15.7 Ma, 14.2 Ma and 13.6 Ma phases. The obtained ages correspond to distinct periods of paleosurface development and stability during the Mio-Pliocene in Katanga. Because Katanga is a key area bordered to the North by the Congo Basin and to the East by the East African Rift System, these ages also provide constraints for the geodynamic evolution of the entire region. For the Mio-Pliocene, the Kisenge deposits record ages that are not systematically found elsewhere in Africa, although the 10.5–11 Ma event corresponds to a roughly simultaneous event in the Kalahari Manganese Field, South Africa. The rest of the Katanga paleosurface record differs somewhat from records for other parts of Africa, for which older, Eocene ages have been obtained. This difference is most probably related to the specific regional geodynamic context: uplift of the East African Plateau, with associated erosion, and the opening of the East African Rift System at c. 25 Ma are events whose effects, in the study area, interfere with those of processes responsible for the development of continent-wide paleosurfaces.     

Eemian crustal deformation in the eastern Baltic area in the light of the new sites at Peski, Russia and Põhja-Uhtju, Estonia

Several Eemian (Mikulino) marine deposits are known from the northwestern part of Russia and from Estonia. The best-known deposits are situated at Mga, Russia and at Prangli, Estonia. Two new sites with clayey and silty deposits covered by till were studied for pollen and diatoms at Peski, Russia and Põhja-Uhtju, Estonia. At Peski, the deposit representing the Eemian Interglacial is 3.8 m thick at the depth of 13.4–9.6 m above present sea-level. At Põhja-Uhtju, the deposit representing the Eemian is 3.5 m thick at the depth of 47.9–51.4 m below present sea-level. Although Peski is situated at a higher altitude than Põhja-Uhtju at present, the diatom stratigraphy at these sites indicates deeper and more saline conditions in the Peski area than at Põhja-Uhtju during the Eemian. This result is similar to some previous studies, which indicate, that although the Russian deposits (e.g. Peski, Mga) are now at a higher altitude than those in Estonia (Põhja-Uhtju and Prangli), the diatoms in the Russian deposits are indicative of a considerable depth of water during the time of deposition. These deposits suggest that the Eemian shore levels ascend from Estonia eastwards, while the Late Weichselian and Holocene shorelines tilt downwards in the same general direction. The present material from Estonia and northwestern part of Russia shows marked differences between the Eemian and Late Weichselian/Holocene crustal deformations, which probably resulted from different ice loads during the final glaciation phases and probably also from different deglaciation patterns during the Saalian and Late Weichselian.     

Lead Removal from Aqueous Solution by Natural and Pretreated Zeolites

Hazardous metal cations enter water through the natural geochemical route or from the industrial wastes. Their separation and removal can be achieved by adsorptive accumulation of the cations on a suitable adsorbent. In the present work, toxic Pb(II) ions are removed from water by accumulating it on the surface of natural zeolite in three different forms; one untreated and two treated samples, one sample treated with 2 M HCI solution and other is treated with 3 M NaOH solution. Natural zeolite is mainly composed of clinoptilolite, and mordenite, with amount of non-zeolite phase (smectite and illite) and C and CT opal. The adsorption experiments are carried out using a batch process in environments of different pH, initial Pb(II) concentration, interaction time and amount of zeolites. Treated zeolite samples show high exchange capacity for Pb(II) compared to untreated sample, however, acid-treated sample shows an exceedingly good exchange capacity. Equilibrium data fitted well with the Langmuir isotherm model with maximum adsorption capacity of 115, 126, and 132 mg g⁻¹ of untreated natural zeolites, alkali-treated zeolites and acid-treated zeolites respectively. The rates of adsorption were found to confirm to pseudo-first order kinetic with good correlation and the overall rate of lead ions uptake.     

Determination of slip rate by optical dating of fluvial deposits from the Wangsan fault,SE Korea

The time-integrated slip rate in fault zones can be determined if the deformed deposits are reliably dated. Here, we report optically stimulated luminescence (OSL) ages of Late Pleistocene fluvial deposits cut by the Wangsan fault, southeastern Korea, which displaces a hanging wall block of about 28 m. Five sandy samples of the deformed Quaternary deposits were dated by quartz OSL using the single aliquot regenerative-dose (SAR) protocol. Three samples taken from the footwall block show stratigraphically consistent OSL ages of 54±7, 76±5 and 90±6 ka, from top to bottom. Two samples collected from the same layer in the hanging wall block show reproducible OSL ages of 81±5 and 82±5 ka, which are also in good agreement with the stratigraphic relationships. Our OSL ages yield an average sedimentation rate of the Quaternary deposits as around 0.04 mm a⁻¹, and a minimum value of time-integrated slip rate as 0.52 mm a⁻¹. This minimum slip rate is considerably higher than those reported earlier for Quaternary faults in southeastern Korea. The youngest OSL age (54±7 ka) constrains the maximum value of the recurrence interval of the fault movement.     

纤维矿物生物活性研究的新进展

石棉、毛沸石、硅灰石、坡缕石、海泡石、水镁石是被国际癌症研究所（ＩＡＲＣ）列为具有致癌、潜在致癌作用或具有较强生物活性的六种纤维矿物,本文综述了目前国内外对这几种纤维矿物生物活性的研究状况及最新进展     

Hydrogeology of thermal waters in Viterbo area, central Italy

A conceptual hydrogeological model of the Viterbo thermal area (central Italy) has been developed. Though numerous studies have been conducted on its geological, geochemical and geothermal features, there is no generalized picture defining the origin and yield of the hydrothermal system. These latter aspects have therefore become the objectives of this research, which is based on new hydrogeological and geochemical investigations. The geological setting results in the coexistence of overlapped interacting aquifers. The shallow volcanic aquifer, characterized by fresh waters, is fed from the area around the Cimini Mountains and is limited at its base by the semiconfining marly-calcareous-arenaceous complex and low-permeability clays. To the west of Viterbo, vertical upflows of thermal waters of the sulphate-chloride-alkaline-earth type with higher gas contents, are due to the locally uplifted carbonate reservoir, the reduced thickness of the semiconfining layer and the high local geothermal gradient. The hot waters (30–60°C) are the result of deep circulation within the carbonate rocks (0.5–1.8 km) and have the same recharge area as the volcanic aquifer. The upward flow in the Viterbo thermal area is at least 0.1 m³/s. This flow feeds springs and deep wells, also recharging the volcanic aquifer from below.     

Re-Os同位素定年对岩浆型Cu-Ni硫化物矿床成矿时代的制约

Re-Os同位素体系被认为是岩浆Cu-Ni硫化物矿床直接定年的有力工具。通过研究世界级典型岩浆Cu-Ni硫化物矿床的Re-Os等时线表面年龄,发现有时能得到成矿年龄,有时得到与成矿年龄不一致的表面年龄或根本得不到Re-Os等时线,还有时同一矿床的不同类型矿石给出不同的Re-Os等时线表面年龄。文章介绍了能够解释上述现象的理论模型。模型预测对与基性-超基性岩共生的Cu-Ni硫化物矿床,除一些特殊情况外,块状矿石可得到有地质意义的Re-Os等时线年龄,浸染状矿石常得到没有地质意义的假等时线;而浸染状矿石常得到有地质意义的Os同位素初始比值,而块状矿石给出的"Os同位素表面初始比值"往往没有地质意义。因此,建议在应用Re-Os同位素体系定年时要结合矿床类型、矿石类型以及成矿过程等因素综合考虑;对Re-Os数据的科学合理解释同样需要从矿床学和同位素地球化学的基本原理出发,结合矿床的实际情况,进行深入分析研究。     

Monitoring ground subsidence induced by salt mining in the city of Tuzla (Bosnia and Herzegovina)

Salt mining induced ground subsidence is a major hazard in the city of Tuzla (Northeastern sector of Bosnia and Herzegovina) and its surroundings since 1950, when solution mining of salt deposits by boreholes began. An analysis of the large (and never before processed) amount of topographical data collected during two periods: from 1956 to the Balkan War, and from 1992 to 2003 has been made. The analysis reveals a cumulative subsidence as high as 12 m during the whole period, causing damage to buildings and infrastructures within an area that includes a large portion of the historical town. Human-induced subsidence, (with rates up to 40 cm/year in the most developed area), has been investigated to recognize the areas affected by the sinking phenomenon and to produce a subsidence hazard. The time series of topographical observations have been enlarged by conducting new surveys in the urban area by modern space-geodesy methodologies, such as static relative GPS (Global Positioning System) and high resolution satellite imageries. The GPS monitoring started in 2004 and detected a decrease in the subsidence rates to 20 cm/year related to the reduction of salt exploitation. There is close correlation between the average subsidence rate and the annual amount of salt extracted.     

First Order Seismic Microzonation of Delhi,India Using Geographic Information System (GIS)

A first order seismic microzonation map of Delhi is prepared using five thematic layers viz., Peak Ground Acceleration (PGA) contour, different soil types at 6 m depth, geology, groundwater fluctuation and bedrock depth, integrated on GIS platform. The integration is performed following a pair-wise comparison of Analytical Hierarchy Process (AHP), wherein each thematic map is assigned weight in the 5-1 scale: depending on its contribution towards the seismic hazard. Following the AHP, the weightage assigned to each theme are: PGA (0.333), soil (0.266), geology (0.20), groundwater (0.133) and bedrock depth (0.066). The thematic vector layers are overlaid and integrated using GIS. On the microzonation theme, the Delhi region has been classified into four broad zones of vulnerability to the seismic hazard. They are very high (> 52%), high (38–52%), moderate (23–38%) and less ( < 23%) zones of seismic hazard. The “very high” seismic hazard zone is observed where the maximum PGA varies from 140 to 210 gal for a finite source model of M_w 8.5 in the central seismic gap. A site amplification study from local and regional earthquakes for Delhi region using Delhi Telemetry Network data shows a steeper site response gradient in the eastern side of the Yamuna fluvial deposits at 1.5 Hz. The ‘high’ seismic hazard zone occupies most of the study area where the PGA value ranges from 90 to 140 gal. The ‘moderate’ seismic hazard zone occurs on either side of the Delhi ridge with PGA value varying from 60 to 90 gal. The ‘less’ seismic hazard zone occurs in small patches distributed along the study area with the PGA value less than 60 gal. Site response studies, PGA distribution and destruction pattern of the Chamoli earthquake greatly corroborate the seismic hazard zones estimated through microzonation on GIS platform and also establishes the methodology incorporated in this study.     

Lateglacial and early Holocene surface exposure ages of glacial boulders in the Taiwanese high mountain range

Glacial landforms and sediments mapped in three presently unglaciated mountain massifs, the Nanhuta Shan, the Hsueh Shan and the Yushan, support the concept of repeated, multi-stage glaciations in the Taiwanese high mountain range during the late Pleistocene. New results from surface exposure dating using in situ produced cosmogenic ¹⁰Be measured in samples taken from erratic and moraine boulders in Nanhuta Shan at altitudes between 3100 and 3500 m are presented here. The results confirm independent and previously reported Optically Stimulated Luminescence (OSL) ages and ¹⁰Be exposure ages from glacial deposits in the same area and suggest a Lateglacial and early Holocene glaciation, the so called Nanhuta glacier advance with two substages at about 12–15 ka and 9.5 ka BP. The respective equilibrium line altitudes (ELA) were calculated at 3340 m and 3440 m with corresponding ELA depressions of 610 ± 100 m and 510 ± 100 m relative to the present day (theoretical) ELA, which is estimated to be at about 3950 ± 100 m in Taiwan. Large-scale erosional landforms indicate a much wider glacier extent during an earlier stage, which is not dated in Nanhuta Shan so far. Luminescence dating from near Hsueh Shan suggests an age of marine isotope stage (MIS) 4 for this stage.     

Geological, mineralogical and geochemical characteristics of zeolite deposits associated with borates in the Bigadiç, Emet and Kirka Neogene lacustrine basins, western Turkey

The Bigadiç, Emet and Kirka lacustrine basins of western Turkey may be considered as Tibet-type graben structures that were developed during the Miocene within the Izmir-Ankara suture zone complex. The volcanic-sedimentary successions of these basins are made up of mudstone, carbonate (limestone and dolomite) and detrital rocks, and also of crystal or vitric tuffs about 135 to 200 m thick. The Degirmenli (Bigadiç), Emirler (Bigadiç) Köpenez (Emet) and Karaören (Kirka) tuffs constituting the zeolite deposits are situated beneath four borate deposits (colemanite, ulexite, borax). The most abundant diagenetic silicate minerals are K- and Ca-clinoptilolites in the zeolite deposits, and Li-rich trioctahedral smectites (stevensite, saponite and hectorite) and K-feldspar in the borate deposits. In the Degirmenli, Emirler. Köpenez and Karaören deposits, the following diagenetic faciès were developed from rhyolitic glasses rich in K and poor in Na: (glass + smectite), (K-clinoptilolite + opal-CT), (Caclinoptilolite + K-feldspar ± analcime ± quartz) and (K-feldspar+analcime+quartz). K-feldspar which is also rarely associated with phillipsite (Karaören) and heulandite (Degirmenli and Karaören), succeeds clinoptilolite and precedes analcime in these diagenetic facies where dioctahedral smectites, opal-CT and quartz are the latest minerals. No diagenetic transformations exist between clinoptilolite, K-feldspar and analcime that were formed directly from glass. The lateral facies distributions resulted from the differences in salinity and pH of pore water trapped during deposition of the tuffs, but vertical distributions in vitric tuffs seem to have been controlled by the glass/liquid ratio of the reacting system and the permeability or diffusion rate of alkali elements. The Bigadiç, Emet and Kirka zeolite deposits which were formed in saline basins rich in Ca and Mg ions, show similar chemical changes, i.e. loss of alkalis and gain in alkaline-earth elements that have taken place during the diagenetic transformation of rhyolitic glasses to dioctahedral smectites or clinoptilolite. The absence of sodic zeolites such as mordenite, erionite, chabazite and silica-rich phillipsite is mainly due to the very high K/Na ratio of the starting materials rather than initial alkaline conditions or high Na content in lake waters.