青藏高原东南缘点苍山-哀牢山杂岩带中片麻岩的变质演化及深熔作用特征

片麻岩是点苍山-哀牢山变质杂岩带最常见的岩石类型,主要由夕线石榴黑云二长片麻岩、石榴黑云斜长片麻岩以及含十字石蓝晶夕线石榴片麻岩所组成,其原岩的化学成分与华北克拉通典型孔兹岩系十分相似.岩相学、成因矿物学和变质反应性质研究以及温压条件估算结果表明,研究区片麻岩类岩石变质峰期的温压条件为T=700～770℃,P=0.5～0.8GPa,已达到或接近麻粒岩相变质,晚期退变质阶段的温压条件为T=600～650℃,P=0.35～0.45GPa.片麻岩变质演化的P-T轨迹具有顺时针型式.在麻粒岩相变质阶段,片麻岩类岩石普遍发生深熔作用,主要表现为含水矿物黑云母的脱水熔融和长英质矿物的部分熔融.该项研究对于进一步揭示青藏高原东南缘点苍山-哀牢山造山带的变质演化深熔作用机理及动力学过程具有重要的科学意义.     

Fluid inclusion studies on the Koraput Alkaline Complex,Eastern Ghats Province,India: Implications for mid-Neoproterozoic granulite facies metamorphism and exhumation

Following ultrahigh temperature granulite metamorphism at ∼1 Ga, the Eastern Ghats Province of India was intruded by the Koraput Alkaline Complex, and was subsequently re-metamorphosed in the granulite facies in the mid-Neoproterozoic time. Fluid inclusion studies were conducted on silica undersaturated alkali gabbro and syenites in the complex, and a pre-metamorphic pegmatitic granite dyke that intrudes it. High density (1.02–1.05 g/cc), pseudo-secondary pure CO₂ inclusions are restricted to metamorphic garnets within the gabbro and quartz within the granite, whereas moderate (∼0.92–0.95 g/cc) and low density (∼0.75 g/cc) secondary inclusions occur in garnet, magmatic clinopyroxene, plagioclase, hornblende and quartz. The isochores calculated for high density pseudo-secondary inclusions pass very close to the peak metamorphic window (∼8 kbar, 750 °C), and are interpreted to represent the fluid present during peak metamorphism that was entrapped by the growing garnet. Microscopic round inclusions of undigested, relict calcite in garnet suggest that the CO₂ present during metamorphism of the complex was internally derived through carbonate breakdown. Pure to low salinity (0.00–10.1 wt% NaCl equivalent) aqueous intra-/intergranular inclusions showing unimodal normal distribution of final ice-melting temperature (T_m) and temperature of homogenization (T_h) are present only in quartz within the granite. These represent re-equilibrated inclusions within the quartz host that were entrapped at the metamorphic peak. Rare, chemically precipitated graphite along the walls of carbonic inclusions is interpreted as a post-entrapment reaction product formed during decompression. The fluid inclusion evidence is consistent with rapid exhumation of a thickened lower crust following the mid-Neoproterozoic granulite facies metamorphic event. The study suggests that mantle CO₂, transported by alkaline magma into the crust, was locked up within carbonates and released during granulite metamorphism.     

高压-超高压变质岩石中石榴石的环带和成因

在俯冲带变质过程中,石榴石是高压-超高压变质榴辉岩和片麻岩的常见变质矿物。由于石榴石具有难熔和流体中的低溶解能力的特点,通常可以很好地保存下来,并且能够保留复杂的化学成分环带,以及不同类型的矿物或流体包裹体,为解释石榴石寄主岩石经历的变质演化历史提供了重要信息。石榴子石的主微量元素成分受控于很多因素,如全岩成分、变质的温压条件、控制石榴子石形成的相关变质反应、与石榴子石共生的矿物种类和成分等。因此,在利用石榴石探讨超高压变质的演化历史时,对石榴石进行系统的主要元素、微量元素、氧同位素以及矿物包裹体分析,以及相互间的成因关系。同时,对石榴石中的锆石或独居石包裹体并进行原位U-Pb定年和微量元素分析,可以为变质石榴石的形成时代提供直接的时间制约。深入研究超高压变质岩中石榴石的生长阶段,不仅可以为含石榴石寄主岩石的变质过程提供岩石学和地球化学证据,而且对于理解石榴石的形成机制、生长规律及其变质化学动力学过程具有重要的科学意义。     

Magmatic arc metamorphism: petrology and temperature history of metabasic rocks in the Coastal Cordillera of northern Chile

We investigated the metamorphic cooling history of underplated magmatic rocks at midcrustal depth. Granulites and amphibolites occur within the Jurassic magmatic belt of the Coast Range south of Antofagasta in northern Chile between 23°25' and 24°20' S. The protoliths of the metamorphic rocks are basic intrusions of Early Mesozoic age. They are part of the magmatically formed crust, and the essentially dry magmas were emplaced in an extensional regime. The granulites (clinopyroxene–orthopyroxene–plagioclase) show all stages of fabric development from magmatic to granoblastic fabrics. Pyroxene compositions were reset at temperatures around 800°  C independent of the stage of textural equilibration. The granulites were partially amphibolitized at upper amphibolite facies temperatures of 600–700°  C. Following cooling, a possible reheating to greenschist facies temperatures around 500°  C is indicated by prograde zoning in magnetite–ilmenite pairs. Mineral assemblages are not suitable for barometry, but a conservative estimation of the garnet-in reaction at given whole-rock compositions suggests maximum pressures in the granulite facies of around 5 kbar, and similar pressures are indicated by phengite barometry for the greenschist facies. The P–T  path of granulite–amphibolite metamorphism is one of slow cooling from magmatic temperatures with heterogeneous deformation. The thinning of the pre-Andean (Precambrian–Triassic) crust was apparently compensated by the magmatic underplating and this special tectonomagmatic setting caused the prolonged residence of the accreted rocks at midcrustal levels.     

冀东地区新太古代麻粒岩相变质作用及其大地构造意义

冀东地区的早前寒武纪基底保留有太古宙克拉通普遍发育的"穹窿-龙骨构造",如卢龙-双山子表壳岩系呈近南北向带状分布于以TTG片麻岩为主构成的太平寨卵形构造域、迁安片麻岩穹窿和安子岭片麻岩穹窿之间,洒河桥线性构造带呈北东向切割太古宙构造线分布。在太平寨卵形域和洒河桥线性带中常见有零散分布的麻粒岩相表壳岩块体和古元古代变质基性岩墙。表壳岩块体包括基性和泥砂质麻粒岩和BIF型铁矿等,变质基性岩墙也发育高压麻粒岩相组合,变质锆石年龄为～1.81Ga。本文总结了近年来对该区麻粒岩的研究进展。太平寨卵形域中的基性麻粒岩以中粒二辉麻粒岩为主,有些样品的角闪石周围出现叠加变质形成的微粒矿物组合,个别样品见辉石周围发育石榴石冠状体,形成‘红眼圈’结构;利用稀土元素温度计确定二辉麻粒岩的峰期达到了～1000℃的超高温条件,麻粒岩中的锆石仅记录新太古代末期变质年龄(～2.50Ga),与周围TTG质岩石的结晶时间近于相同。洒河桥线性带中的基性麻粒岩以细粒高压麻粒岩组合为主,偶见中粒二辉麻粒岩残留,其峰期P-T条件分别为800～860℃/1.0～1.2GPa和950～1070℃/1.0GPa;麻粒岩中锆石主体记录新太古代末期变质年龄,但出现少量古元古代变质锆石(1.97～1.83Ga),石榴石-全岩Lu-Hf等时线年龄为1.77～1.78Ga。由此推测太平寨和洒河桥地区都经历了新太古代末期超高温麻粒岩相变质作用,又在古元古代晚期遭受了高压麻粒岩相差异性叠加,太平寨地区受叠加较弱,仍然保留太古宙的卵形构造,而洒河桥一带受叠加较强,形成了线性变形带。太平寨卵形域的泥砂质麻粒岩可识别出4阶段的变质矿物组合:包括包体组合、峰期组合、固相线(或最后)组合以及叠加组合。相平衡模拟表明固相线组合的P-T条件为870～890℃/～0.7GPa,峰期组合可达到1000℃/1.1GPa,石榴石中富钙斜长石包体指示麻粒岩早期经历了低压高温变质阶段。由此构建麻粒岩P-T轨迹为逆时针型,包括3个阶段:低压加热至超高温(AG-I),近等温升压至压力峰期(～1.1GPa)(AG-II),和峰后降压降温至固相线(AG-IIIa)以及在亚固相线下的降温降压过程(AG-IIIb)。锆石定年表明泥砂质麻粒岩原岩沉积年龄稍早于2.50Ga,变质年龄为2.48～2.50Ga。泥砂质麻粒岩的峰期变质条件和时代均与二辉麻粒岩一致,叠加组合的P-T条件与高压麻粒岩相似,反映泥砂质麻粒岩也受到了古元古代晚期变质作用影响。依据太平寨麻粒岩的逆时针型P-T轨迹,推测麻粒岩相变质作用包括如下构造过程:(i)AG-I指示表壳岩层受到后续地幔极高温岩浆喷发被埋深加热,或者受到下部TTG质岩浆海的加热过程;(ii)AG-II指示被加热的岩石(总伴有BIF铁矿层)被破碎并在在密度驱动下沉入岩浆海深部,达到下地壳深度;(iii)AG-IIIa/b对应沉入岩浆海深部的岩石伴随穹窿上升发生减压冷却的过程。很多地质观测和数值模拟研究表明太古宙克拉通的形成受太古宙特有的垂直构造体制控制,与太古代之后线性造山带的构造体制完全不同。     

超高压变质作用过程中的流体——来自苏鲁超高压变质岩岩石学、氧同位素和流体包裹体研究的限定

苏鲁造山带超高压变质岩岩石学、氧同位素、流体包裹体和名义上无水矿物的研究表明,流体-岩石相互作用在大陆地壳的俯冲与折返过程中起到多重的重要作用,并形成了复杂的流体演化过程：（1）大陆表壳岩通过与高纬度大气降水的交换作用被广泛水化,并获得了异常低的氧同位素成分;（2）在水化陆壳物质的俯冲过程中发生了一系列的进变质脱水反应,所释放的流体主要结合进了高压、超高压含水矿物和名义上无水超高压矿物;（3）在超高压变质过程中,以水为主的变质流体通过选择性的吸收使其盐度逐渐升高,并在峰期出现高密度、高盐度的H2O或CO2-H2O流体。有机质的分解反应在局部形成了以CO2、N2、CH4或它们的混合物为主要成分的变质流体;（4）名义上无水超高压矿物的结构水出溶是早期退变质流体的主要来源,并在局部富集形成了高压变质脉体;（5）透入性的中、低盐度水流体活动使超高压变质岩通过一系列的水化反应转变成角闪岩相变质岩;（6）沿韧性剪切带和脆性破碎带的强烈水流体活动为绿片岩相退变质作用和低压石英脉的形成提供了变质流体;（7）可变盐度的H2O或CO2-H2O流体是整个超高压变质岩形成与折返过程中的主要流体,但局部的流体．岩石相互作用形成了非极性的变质流体。     

Preservation of high‐P rocks coupled to rock composition and the absence of metamorphic fluids

Eclogites, blueschists and greenschists are found in close proximity to one another along a 1‐km coastal section where the Cyclades Blueschist Unit (CBU) is exposed on SE Syros, Greece. Here, we show that the eclogites and blueschists experienced the same metamorphic history: prograde lawsonite blueschist facies metamorphism at 1.2–1.9 GPa and 410–530°C followed, at 43–38 Ma, by peak blueschist/eclogite facies metamorphism at 1.5–2.1 GPa and 520–580°C. We explain co‐existence of eclogites and blueschists by compositional variation probably reflecting original compositional layering. It is also shown that the greenschists record retrogression at 0.34 ± 0.21 GPa and T = 456 ± 68°C. This was spatially associated with a shear zone on a scales of 10–100‐m and veins on a scale of 1–10‐cm. Greenschist facies metamorphism ended at (or shortly after) 27 Ma. We thus infer a period of metamorphic quiescence after eclogite/blueschist facies metamorphism and before greenschist facies retrogression which lasted up to 11–16 million years. We suggest that this reflects an absence of metamorphic fluid flow at that time and conclude that greenschist facies retrogression only occurred when and where metamorphic fluids were present. From a tectonic perspective, our findings are consistent with studies showing that the CBU is (a) a high‐P nappe stack consisting of belts in which high‐P metamorphism and exhumation occurred at different times and (b) affected by greenschist facies metamorphism during the Oligocene, prior to the onset of regional tectonic extension.     

Spinel–sapphirine–quartz bearing composite inclusion within garnet from an ultrahigh-temperature pelitic granulite: Implications for metamorphic history and P–T path

We report here a multiphase mineral inclusion composed of quartz, plagioclase, K-feldspar, sapphirine, spinel, orthopyroxene, and biotite, in porphyroblastic garnet within a pelitic granulite from Rajapalaiyam in the Madurai Granulite Block, southern India. In this unique textural association, hitherto unreported in previous studies, sapphirine shows four occurrences: (1) as anhedral mineral between spinel and quartz (Spr-1), (2) subhedral to euhedral needles mantled by quartz (Spr-2), (3) subhedral to anhedral mineral in orthopyroxene, and (4) isolated inclusion with quartz (Spr-4). Spr-1, Spr-2, and Spr-4 show direct grain contact with quartz, providing evidence for ultrahigh-temperature (UHT) metamorphism at temperatures exceeding 1000 °C. Associated orthopyroxene shows high Mg/(Fe + Mg) ratio ( 0.75) and Al₂O₃ content (up to 9.6 wt.%), also suggesting T > 1050 °C and P > 10 kbar during peak metamorphism.

Coarse spinel (Spl-1) with irregular grain morphology and adjacent quartz grains are separated by thin films of Spr-1 and K-feldspar, suggesting that Spl-1 and quartz were in equilibrium before the stability of Spr-1 + quartz. This texture implies that the P–T conditions of the rock shifted from the stability field of spinel + quartz to sapphirine + quartz. Petrogenetic grid considerations based on available data from the FMAS system favour exhumation along a counterclockwise P–T trajectory. The irregular shape of the inclusion and chemistry of the inclusion minerals are markedly different from the matrix phases suggesting the possibility that the inclusion minerals could have equilibrated from cordierite-bearing silicate-melt pockets during the garnet growth at extreme UHT conditions.     

华南晚古生代末超高温变质作用:以十万大山花岗岩中麻粒岩包体为例

广西东南部大容山-十万大山地区过铝质(S型)花岗岩中包含丰富的副变质麻粒岩包体.部分麻粒岩包体保留了尖晶石+石英、斜方辉石+夕线石±石英等超高温变质矿物组合,指示这些麻粒岩包体曾经历了超高温变质作用.矿物温压估算结果显示:峰期温压条件为7.5～8.0kbar,950～1000℃,峰后退变质温压条件为3.2～3.7kba...     

利用石榴橄榄岩重建大陆俯冲带的古动力学环境及其演化过程

本文提出一种对于造山带石榴橄榄岩的简单概念分类模型。该模型将造山带石榴橄榄岩划分为地幔楔型和俯冲带型两种类型,根据所记录温压条件及P-T轨迹的差异,地幔楔型石榴橄榄岩进而被划分为A-D四个亚类,分别对应不同厚度的克拉通型岩石圈地幔及普通大陆岩石圈地幔环境中冷的/古老的/稳定的地幔环境及与之对应的相对热的/年轻的/活动地幔环境。我们选择研究程度较高的斯堪的纳维亚加里东期造山带及我国柴北缘造山带中出露的石榴橄榄岩来检验该模型的适用性。出露于挪威西片麻岩地区的Mg-Cr型及Fe-Ti型石榴橄榄岩分别属于地幔楔型的A亚类(来自于古老的/冷的/厚的/亏损的克拉通岩石圈地幔)及壳源俯冲带石榴橄榄岩,而来自Seve,Troms和Linds地体的石榴橄榄岩则属于地幔楔型的C亚类(来自于古老的/冷的/薄的/亏损的大陆岩石圈地幔)后经历俯冲过程变为俯冲带石榴橄榄岩。对我国柴北缘超高压带绿梁山石榴橄榄岩的检验结果相对复杂。前人的研究表明绿梁山石榴橄榄岩存在三种不同的成因方式,对应分类模型中的:1)D亚类橄榄岩(阿拉斯加型岩浆岩堆晶体);2)壳源俯冲带型石榴橄榄岩;3)A亚类来自克拉通岩石圈地幔的太古代石榴橄榄岩。检验结果表明,该分类模型能较好的解释斯堪的纳维亚加里东期造山带中的石榴橄榄岩的出露规律,岩石学及矿物学特征及不同期次矿物之间的年代学关系,但对于我国绿梁山石榴橄榄岩的成因分类仍需进一步研究。假设该分类模型能适用于大多研究程度较高的造山带石榴橄榄岩,起到决定性作用的两个分类参数为地幔楔形成初期的平均温度(T)及造山带岩石圈地幔的厚度(P)。熔融作用发生的时间及深度同样是区分不同类型石榴橄榄岩的重要因素。     

斯里兰卡地质演化研究的进展与评述:岩石组合、变质演化及其与冈瓦纳大陆的关系

地球表生环境的演变及生命演化过程,与地球构造过程密切相关,新元古代-寒武纪时期的冈瓦纳大陆汇聚过程见证了一系列剧变。东非造山带(ca. 650～620Ma)和Kuunga造山带(ca. 600～500Ma)是冈瓦纳大陆块体汇聚过程中形成的两条主要造山带,二者在斯里兰卡所在的区域十字交叉。因此斯里兰卡地质演化历史的准确梳理,对理解新元古代时期全球构造过程的重要意义不言而喻。斯里兰卡的四个前寒武纪地质体(Wanni、Kadugannawa、Highland和Vijayan杂岩地体)中,中部的Highland杂岩地体最古老(ca. 2000～1800Ma)、变质程度最高(普遍麻粒岩相,局部为超高温麻粒岩相),其余三个地质体主要岩石的形成时代为中元古代晚期-新元古代(ca. 1100～700Ma),岩石记录的变质级别略低于Highland地体,为角闪岩相-麻粒岩相。现有研究表明斯里兰卡几个地质体在新元古代-寒武纪时期(ca. 610～500Ma)的变质作用记录最为显著,并伴随有广泛的陆壳重熔再造。该构造热事件晚于东非造山带的变质时代(ca. 650～620Ma),与Kuunga造山带活动时间(ca. 600～500Ma)吻合度较高,这与前人提出的莫桑比克缝合带(东非造山带)穿过斯里兰卡的认识相矛盾。斯里兰卡的高级变质作用究竟是单次造山作用的结果,还是代表了两期造山事件的叠加效应,目前尚无定论。高温-超高温变质作用是斯里兰卡前寒武纪基底岩系的显著特征,其中超高温麻粒岩具有假蓝宝石+石英、紫苏辉石(Al_2O_3含量可达～13%)+夕线石、尖晶石+石英等的矿物组合,不同研究者给出超高温峰期变质温度在950～1150℃的范围内,峰期变质压力在10～16kbar的范围内,多显示顺时针演化P-T轨迹。斯里兰卡中东部地区的基性麻粒岩,发育由斜方辉石+斜长石、角闪石+斜长石或单斜辉石+斜长石组成的环绕石榴石的蠕虫状后成合晶结构,指示近等温降压的P-T演化样式,以及峰期变质作用之后地体相对快速抬升的演化过程。紫苏花岗岩在斯里兰卡不同地体中都很常见,与所有的高级变质岩(如泥质、基性麻粒岩和钙硅酸盐岩等)密切伴生,是研究斯里兰卡地质演化不可忽视的岩石类型。紫苏花岗岩的原岩成因较为复杂,其最古老部分的形成时代可能为太古宙或古元古代(～1850Ma),但是没有很好的年代学限定。部分紫苏花岗岩原岩时代为ca. 1100～750Ma,具有钙碱性弧岩浆的地球化学特征,并记录ca. 580～500Ma的变质作用,还有一部分紫苏花岗岩时代与区域麻粒岩相变质作用的峰期时代相当,为ca. 580～550Ma。在一些地区的角闪片麻岩中,还可以观察到补丁状分布的初始紫苏花岗岩,其形成时代多被认为晚于峰期麻粒岩相变质时代。斯里兰卡四个前寒武纪地质体在岩石组合、变质级别、地质年代学格架等方面的差异被普遍认同,暗示这些地质体具有不同的演化历史。但是斯里兰卡不同地质体的汇聚过程是否对应于莫桑比克洋的闭合,以及Kuunga造山带如何改造斯里兰卡的基底岩石,目前并不清楚。本文综述了前人发表的研究结果,主要从斯里兰卡不同地质体岩石组合、高温-超高温变质作用(Highland地体)、变质地质年代学及其对冈瓦纳大陆重建的启示等几个方面,对斯里兰卡地质演化研究进行归纳和小结。在此基础上提出,在斯里兰卡基底构造框架、新元古代晚期-寒武纪高温-超高温变质作用、紫苏花岗岩成因、地质演化的年代学格架、斯里兰卡在冈瓦纳大陆重建中的位置和作用、下地壳热状态和热源机制等诸多方面,还存在问题和争议,是值得未来开展深入研究的方向。     

Evolving fluid composition during prograde metamorphism in subduction zones: A new approach using carbonate-bearing assemblages in the pelitic system

The changing XCO₂ in fluids during the progressive metamorphism in Sanbagawa belt of the Cretaceous subduction zone, Japan, was estimated by a newly proposed method. The subduction zone meta-sediments are characterized commonly by four-phase assemblages in the CaO–NaAlO₂–KAlO₂–Al₂O₃ system with excess quartz and a CO₂–H₂O binary fluid phase. Using the common assemblage of calcite–albite–muscovite–clinozoisite, XCO₂ of the fluid was estimated to be from about 0.0001–0.0005 (the lowest grade chlorite zone), through 0.004–0.01 (garnet zone), 0.01–0.05 (albite–biotite zone) to 0.06–0.2 (oligoclase–biotite zone).The paragenetic relationship of meta-sediments from the subduction zones was compared in a wide P–T range to cover the stability fields of aragonite and jadeite. As a result, an excellent P–T–XCO₂ relationship was delineated to serve as a quantitative monitor for the evolving fluid composition during the progressive metamorphism in subduction zones.     

Multistage Metamorphic Evolution of the Trivandrum Granulite Block, Southern India

The Trivandrum Granulite Block (TGB), southern India records evidence for three distinct stages of evolution (M1–;M3) during the Pan-African high grade metamorphism, with possible temperature gradient from north to south of the terrain as detected from mineral phase equilibria thermobarometry in three classic localities, namely Nuliyam, Kunnanpara and Nellikkala. The charnockites, both incipient and massive, were formed during the first stage (M1) at temperatures higher than their host rocks, and at appreciably lower pressures. Charnockite formation was dominantly controlled by an increase in partial pressure of CO₂, along structural locales during subisothermal decompression, although an increase of potash activity could have also been an important factor in this process. The charnockites at Nellikkala in the northern margin of TGB were formed under appreciably more H₂O-rich conditions (X_H2O = 0.53±0.03) than those at Nuliyam (X_H2O = 0.25±0.02) in the southern margin. It is inferred that during the period between the metamorphic stages M1 and M2, the terrain experienced subisobaric cooling. Comparison of results from thermobarometry with data on absolute age determinations from geochronology of the metamorphic rocks in TGB allows the interpretation that the M1 metamorphic event took place during 540–;600 Ma, M2 at about 530 Ma and M3 in the interval of 440–;470 Ma. Mineralogic and thermobarometric evidence for earlier high-grade metamorphic processes, if any, have been erased from these rocks. The processes of charnockite formation and post-peak retrograde metamorphism in the TGB took place under high geothermal gradients (40–;150°/km). This probably testifies to the existence of a local heat source, either magmas at depth or mantle (plume) beneath the region. The general metamorphic cycle in the TGB is estimated to be ca. 100–;160 Ma, which is much shorter in time span than that in the other regions of southern Peninsular India such as the Karnataka Craton and the Eastern Ghats Mobile Belt. During this period, the terrain experienced rapid exhumation of approximately 6–;7 cm/year, with the total amplitude of vertical movements estimated to be about 16–;17 km.     

The fate of graphite in prograde metamorphism of pelites: An example from the Ballachulish aureole, Scotland

Graphite-bearing slates and phyllites (0.4–1.2 vol.% graphite) are progressively metamorphosed in the 3 kbar aureole of the 425 Ma Ballachulish intrusion, Scotland. Two major dehydration reactions are crossed: the chlorite-out reaction at ca. 550 °C (forming cordierite + biotite), and the muscovite-out reaction at 625 °C (forming Al₂SiO₅ + K-feldspar). Graphite persists to the highest grades and shows no significant variation in abundance with grade, except for a possible decrease in the highest grade rocks. Variable graphite abundance in rocks at the same grade reflects primary sedimentological heterogeneity. Texturally, graphite grains and aggregates in the rock matrix become coarser grained and more widely separated as grade increases. These thermally induced textural modifications of graphite are superimposed on mechanically induced features, such as graphite segregations along cleavages and crenulations, that formed prior to contact metamorphism. Mass balance modelling, assuming internal fluid generation, shows that the amount of graphite consumed during contact metamorphism in the aureole ranges between 0.1 and 0.3 vol.%, depending on the amount of chlorite and muscovite in the protolith. Because the amount of C dissolved in a C–O–H fluid decreases with increasing pressure, and the Ballachulish aureole is at relatively low pressure, these results are a maximum for regional metamorphism, suggesting that graphite will persist through a regional metamorphic cycle if it is initially present in volumes > ca. 0.2 vol.%.     

山东省沂水地区麻粒岩相变质作用演化及大地构造意义

山东沂水麻粒岩相岩石出露于断裂带中,它是断裂带中最古老的岩石。主要岩石类型有孔兹岩（石榴石－石英－条纹长石－夕线石片麻岩）、紫苏辉石麻粒岩（紫苏辉石－斜长石－厂长央片麻岩）以及紫苏花岗岩等。根据矿物共生组合、变质反应,温压条件得出本区麻粒岩相岩石经历了五个阶段的变质作用,前阶段为角闪岩相变质作用,温度条件为Ｔ＝５７５℃￣６００℃,Ｐ＝０．５９ＧＰａ;峰期他阶段经历了五个阶段的变质作用,峰前阶段为角     

内蒙古中部太古代麻粒岩递增变质成因

由早元古代造山运动早期自北西向南东推覆作用引起并使之得以保存的太古代变质作用强度逆转的剖面出露在内蒙古中部的固阳－武川地区。变质镁铁质岩石中矿物组合的变化在低级区为阳起石＋绿帘石＋绿泥石→普通角闪石＋钠长石→普通角闪石＋斜长石→石榴石（或透辉石）＋普通角闪石＋斜长石→无色角闪岩＋钠长石;在高级区为普通角闪石＋斜长石→紫苏辉石＋透辉石＋斜长石→石榴石＋透辉石（２）＋石英。这些变化已被用来恢复太古代时期从低绿片岩相到麻粒岩相的递增变质序列及尔后经历的近等压冷却的退变质作用过程。高级区变质表壳岩与低级区绿岩带的岩石组合、岩石化学、岩石地球化学和变质作用演化序列的对比研究结果表明,两者属于太古代同一火山－沉积单位。其变质程度的不同起因于在经受区域性递增变质作用时,两者处在地壳的不同位置     

川西同德和沙坝麻粒岩及其退变质岩石之间的元素迁移

利用川西麻粒岩的全岩化学组成与岩石中特征矿物的化学性质,研究了麻粒岩退变质作用的元素迁移。对紫苏辉石、普通辉石和普通角闪石的电子探针分析表明,随着麻粒岩退变质作用程度的加深,矿物的化学组成与全岩的元素迁移同步变化。由于矿物组合和岩相的转变以及地壳流体的作用,同德二辉麻粒岩在退变质至黑云角闪斜长片麻岩过程中,K,Rb,Cs,K／Na,Fe^3+和Fe3+／Fe^2+增加,Fe^2+,V,Co,Ba,Sr和Pb降低;在沙坝二辉麻粒岩退变质为含绿帘石角闪斜长片麻岩过程中,Na,Ca,Fe^3+,Zr,Hf,Nb,Ta,Rb,U,Th,REE和Fe^3+／Fe^2+增加,Fe^2+,Mg,K,Co,Zn,Cs,Pb和K／Na降低。麻粒岩退变质过程中制约不同元素迁移的主要矿物相是普通角闪石等退变质新生矿物。同德和沙坝两个麻粒岩块退变质作用中,个别元素迁移性状并不相同,这可能与原岩的性质和变质流体的成分等环境地质条件有关。     

大别山区深部地壳的变质岩石学证迹：罗田惠兰山一带的麻粒岩研究

大别杂岩中新太古代或古元古代麻粒岩相岩石分布具一定的区域规模。罗田黄土岭、惠兰山一带出露中性和基性麻粒岩,其矿物组合分别为;１．Ｇｒｔ＋Ｏｐｘ１＋Ｂｉ＋Ｋｆｓ＋Ｐｌ（Ａｎ２０）（中性）,２．Ｇｒｔ＋Ｈｂ１＋Ｏｐｘ＋Ｃｐｘ＋Ｐｌ（Ａｎ４Ｏ）＋Ｉｌｍ（基性）,它们的高峰变质条件分别为ＰＯ．８９～１．０４Ｇｐａ、Ｔ７５０～８５０℃（中性）以及Ｐ０．９～１．２９ＧＰａ、Ｔ６８２～８８０℃,平均７７１±５３℃（基性）,说明其形成深度在３０ｋｍ以上。在中性麻粒岩中发现堇青石＋石英和堇青石＋黑云母的后成合晶,分别位于Ｇｒｔ与Ｏｐｘ１之间或穿插于Ｇｒｔ晶内,退变质反应条件为Ｐ为０．４１～０．５５ＧＰａ,Ｔ＝７１０℃,属减压退变质性质;后成合晶的形态与区域面理无关,说明减压退变质反映了碰撞造山带后期的近绝热隆升。区域花岗岩或地幔热流可能是绝热隆升的热源,现今出露的深源麻粒岩有过长期居留下地壳的历史,它们的抬升剥露是后期构造事件所致。     

Aeromagnetic study of peninsular India

The degree sheet Aeromagnetic maps up to 17‡N, acquired from the Geological Survey of India, have been manually redigitised at 6 minute intervals to study the long wavelength anomalies over peninsular India. These data have been collected at different survey altitude, epochs, flight line directions, etc. Great care has been taken to correct the total field map and remove the contribution due to the core field and prepare an accurate crustal anomaly map. For the first time, a regional map, depicting the NW-SE structural features north of the orthopyroxene isograd with the essentially E-W features to the south of it and revealing several well known structures, is presented. The analytical signal is calculated to delineate the source fields of these anomalies. It dramatically maps the charnockites and is able to delineate the orthopyroxene isograd. In the Dharwar region the magnetic signatures are associated with the intrusives/ iron ore bodies. Thus, we find that the source rocks of the aeromagnetic anomalies are the host province of charnockites in the SGT and the intrusives/iron ore bodies in the Dharwar belt. Gravity residuals are calculated and a tectonic map of the region is presented from the combined geopotential data.     

麻粒岩相变质作用与花岗岩成因-I:变质泥质岩/杂砂岩高温-超高温变质相平衡

麻粒岩相岩石作为洞察下地壳的窗口一直备受重视。二十世纪九十年代以来麻粒岩研究的一个重要进展是利用变质相平衡的定量研究方法模拟岩石中所发生的深熔变质反应、熔体成分变化、及熔体丢失对变质矿物组合的影响等。本文利用KASH、NKASH和KFMASH等简单体系的相平衡关系,做出P-T投影图、组分共生图解和基于固定全岩成分的P-T视剖面图解,并结合有关实验岩石学结果,讨论了高温和超高温条件下变质泥质岩和杂砂岩中的变质熔融反应、矿物组合、全岩成分与P-T条件之间的相互关系。多数变质泥质岩和杂砂岩中饱和流体固相线熔融反应可利用NKASH体系中有水流体参与的熔融反应模拟,在没有外来流体注入时,这些反应可形成<3mol%熔体。在不同体系中白云母脱水熔融反应型式及其P-T条件不同,如在NKASH和KFMASH体系中模拟计算的白云母脱水熔融反应与相应的实验结果相似,分别控制了白云母分解熔融的温度下限和上限;白云母的分解温度会随着其中Fe、Mg和Ti含量的增加而升高,也随着共生斜长石中钙长石组分增加而升高,泥质岩中白云母脱水熔融可以形成~10mol%熔体。在KFMASH体系中黑云母脱水熔融反应表现为4条单变反应,其理论计算的温度比实验模拟的结果低一些。在NCKFMASH体系或实际岩石中黑云母脱水熔融反应为滑动反应,如NCKFMASH体系中黑云母从其开始熔融到最后消失在泥质岩中可跨越~100℃,在杂砂岩中可跨越30~50℃。黑云母的稳定温度随着镁值升高而升高,其稳定上限受钛影响更大,黑云母脱水熔融可以形成超过30mol%~40mol%熔体。KFMASH体系中的相平衡模拟表明以出现斜方辉石+夕线石和假蓝宝石为特征的超高温组合易于出现于富镁泥质岩中,而对正常成分泥质岩在达到1000℃的超高温条件下,主要出现石榴石+夕线石(即夕线榴),该组合在更高温度反应形成假蓝宝石+尖晶石。利用饱和水固相线反应和白云母与黑云母分解反应可以更好地限定不同的变质相。如中压和低压条件下低角闪岩相和高角闪岩相的界限可利用NKASH体系中有水流体和白云母参与的熔融反应和亚固相线条件下的白云母分解反应限定;实验确定的泥质岩中黑云母开始熔融与消失的反应可分别用于限定高角闪岩相与(正常)麻粒岩相的界限,以及(正常)麻粒岩相和超高温麻粒岩相的界限。因此,从矿物组合角度,正常麻粒岩相可限定在黑云母开始熔融到完全消失的温度范围,超高温麻粒岩相可限定在黑云母消失(有石英存在)之后的温度范围。