三峡水库澎溪河春季水华期p(CO2)及影响因素分析

在三峡水库澎溪河回水区春季水华连续暴发期间(2010年4月10日至5月25日),对渠马至河口总计5个采样断面进行监测。结果表明水华期间水体叶绿素a(Chla),溶解氧(DO)及CO₂分压(p(CO₂))分层现象明显,表层水体受浮游植物光合作用的影响p(CO₂)较低,并且日照充足时,水体为CO₂的汇。研究期间表层水体p(CO₂)最小值出现在4月25日双江断面,为4.3Pa,吸收通量为-0.28 mmol/(m2·h)。p(CO₂)随水深迅速增加,并在10～15m趋于稳定。偏最小二乘回归分析(PLS)表明澎溪河水华期间,浮游植物的生长代谢是控制p(CO₂)的关键因素,水温与p(CO₂)负相关,但并不构成对p(CO₂)的绝对影响。通过引用Ep(CO₂)/ADO参数,观测到了澎溪河水体水华暴发的3个阶段,期间澎溪河表层水体经历了从碳汇到碳源最后又回到碳汇的过程。     

Hydrography of the eastern Arabian Sea during summer monsoon 2002

Hydrographic observations in the eastern Arabian Sea (EAS) during summer monsoon 2002 (during the first phase of the Arabian Sea Monsoon Experiment (ARMEX)) include two approximately fortnight-long CTD time series. A barrier layer was observed occasionally during the two time series. These ephemeral barrier layers were caused byin situ rainfall, and by advection of low-salinity (high-salinity) waters at the surface (below the surface mixed layer). These barrier layers were advected away from the source region by the West India Coastal Current and had no discernible effect on the sea surface temperature. The three high-salinity water masses, the Arabian Sea High Salinity Water (ASHSW), Persian Gulf Water (PGW), and Red Sea Water (RSW), and the Arabian Sea Salinity Minimum also exhibited intermittency: they appeared and disappeared during the time series. The concentration of the ASHSW, PGW, and RSW decreased equatorward, and that of the RSW also decreased offshore. The observations suggest that the RSW is advected equatorward along the continental slope off the Indian west coast.     

Geomorphological and seismostratigraphic evidence for multidirectional polyphase glaciation of the northern Celtic Sea

High-resolution seismic and bathymetric data offshore southeast Ireland and LIDaR data in County Waterford are presented that partially overlap previous studies. The observed Quaternary stratigraphic succession offshore southeast Ireland (between Dungarvan and Kilmore Quay) records a sequence of depositional and erosional events that supports regional glacial models derived from nearby coastal sediment stratigraphies and landforms. A regionally widespread, acoustically massive facies interpreted as the ‘Irish Sea Till’ infills an uneven, channelized bedrock surface overlying irregular mounds and deposits in bedrock lows that are probably earlier Pleistocene diamicts. The till is truncated and overlain by a thin, stratified facies, suggesting the development of a regional palaeolake following ice recession of the Irish Sea Ice Stream. A north–south oriented seabed ridge to the north is interpreted as an esker, representing southward flowing subglacial drainage associated with a restricted ice sheet advance of the Irish Ice Sheet onto the Celtic Sea shelf. Onshore topographic data reveal streamlined bedforms that corroborate a southerly advance of ice onto the shelf across County Waterford. The combined evidence supports previous palaeoglaciological models. Significantly, for the first time, this study defines a southern limit for a Late Midlandian Irish Ice Sheet advance onto the Celtic Sea shelf. © 2020 John Wiley & Sons, Ltd.     

Seismic stratigraphic analysis of non-marine Lower Cretaceous strata in the Wessex and North Celtic Sea Basins

Non-marine strata of Early Cretaceous age ('Wealden facies') are found at outcrop in the type localities of the Wessex Basins, southern England (and adjacent subsurface) and in extensive and thick successions filling the North Celtic Sea Basin. Sedimentology, paleontology, petrology and geochemistry have traditionally been used as evidence in determining the climatic, tectonic and sea level controls on Wealden facies, sedimentary processes and stratigraphy. Analysis of seismic data, through seismic facies and sequence stratigraphic analysis, allows direct comparison of the Wealden in these basins and new interpretations to be made of the tectonic and depositional influences. In the north-eastern end of the North Celtic Sea Basin, tectonic controls on seismic facies can be demonstrated and are related to coarse-grained fan-delta horizons documented in core. In the south-western North Celtic Sea Basin, adjacent to the Cretaceous proto-Atlantic, tectonic controls are less apparent, and changes in relative sea level were probably more important in controlling the preservation of stratigraphic sequences. Where the non-marine Lower Cretaceous succession is imaged clearly, the stratigraphic similarity between parts of the North Celtic Sea and the Weald and Channel Basins suggests a wider control by relative sea-level fluctuations. However, important variations in seismic facies within the basins indicate localized, dominant tectonic control. The recognition of a very distinctive 'lower' Wealden seismic facies, observed as undulatory (?channelized) and downlapping reflections, is contrasted with either the parallel or synsedimentary fault-dominated 'upper' Wealden facies. These seismic characteristics reflect the previously recognized climatic/tectonic change from Hastings to Weald Clay Group environments. The debate on tectonics versus eustacy is further complicated: palaeoclimate appears to be a third process responsible for stratigraphic variation.     

Global change and the biogeochemistry of the North Sea: the possible role of phytoplankton and phytoplankton grazing

Phytoplankton plays a dominant role in shelf biogeochemistry by producing the major part of organic matter. Part of the organic matter will reach the sediment where diagenetic processes like denitrification, apatite formation or burial will remove nutrients from the biogeochemical cycle. In this article current knowledge on the decadal plankton variability in the North Sea is summarized and possible implications of these changes for the biogeochemistry of the North Sea are discussed. Most of the observed interdecadal dynamics seem to be linked to large-scale oceanographic and atmospheric processes. Prominent changes in the North Sea ecosystem have taken place around 1979 and 1988. In general, the phytoplankton color (CPRS indicator of phytoplankton biomass) reached minimum values during the end of the 1970s and has increased especially since the mid 1980s. Changes with a similar timing have been identified in many time series from the North Sea through the entire ecosystem and are sometimes referred to as regime shifts. It is suggested that the impact of global change on the local biogeochemistry is largely driven by the phyto- and zooplankton dynamics during spring and early summer. At that time the extent of zooplankton–phytoplankton interaction either allows that a large part of the new production is settling to the sediment, or that a significant part of the new production including the fixed nutrients is kept within the pelagic system. The origin of the extent of the phytoplankton–zooplankton interaction in spring is probably set in the previous autumn and winter. In coastal areas, both large-scale atmospheric and oceanographic changes as well as anthropogenic factors influence the long-term dynamics. Due to eutrophication, local primary production nowadays still is up to five times higher than during pre-industrial conditions, despite a decreasing trend. Recently, introduced species have strengthened the filter feeder component of coastal ecosystems. Especially in shallow coastal seas like the Wadden Sea, this will enhance particle retention, shift organic matter degradation to the benthic compartment and enhance nutrient removal from the biogeochemical cycle by denitrification or apatite formation.     

Reconstruction of phytoplankton productivity and community structure in the South Yellow Sea

The sedimentary environment and ecological system in the South Yellow Sea (SYS) changed dramatically due to sea level change caused by glacial-interglacial cycles. The authors report the use of marine biomarkers (brassicasterol, dinosterol and C³⁷ alkenones) and terrigenous biomarkers (C²⁸+C³⁰+C³² n-alkanols) in core DLC70-3 from the SYS to reconstruct the variation in the phytoplankton productivity and community structure and possible mechanisms during the middle Pleistocene. The results show that the primary productivity and that of single algae presented a consistent trend for the whole core during the middle Pleistocene, which was high during interglacial periods and low during glacial periods, with the highest being in marine isotope stage (MIS) 5–9 and MIS 19–21. The main reason is that the Yellow Sea Warm Current (YSWC) carried much of high temperature, high salinity water into the SYS, causing upwelling and vertical mixing and stirring, which increased the nutrient supply in the photosynthetic layer. The phytoplankton community structure mainly showed an increase in the relative content of haptophytes in MIS 5–9 and MIS 19–21, while the relative content of diatoms and dinoflagellates decreased; there was no evidence for a haptophyte content in other stages. The results reveal a shift from a coccolitho-phorid-dominated community during MIS 5 –9 and MIS 19 –21 to a diatom-dominated community during the other stages, mainly as a result of surface salinity variation, attributed to the invasion of the YSWC during high sea level periods.     

Tectonic framework of the Celtic Sea and adjacent areas with special reference to the location of the Variscan Front

Structural trends in the Celtic Sea area indicate that Variscan deformation patterns were inherited from Caledonian basement structures, and that the regional fold alignment is arcuate with a regional WSW-ENE direction rather than WNW-ESE (Armorican). There is no lateral structural continuity between Southern Ireland and South Wales-Southwest England. Three major structural provinces arranged en échelon across the Variscan foldbelt are recognised: (a) Southwest England, where there was complex deformation of a major basin; (b) the South Wales-Mendips foreland area, with strong basement/cover interaction and (c) the Southern Ireland graben and flanking platform province. Late Palaeozoic depositional patterns indicate that Southern Ireland and Southwest England were separated by a WSW-ENE trending platform bounded on the north by the inherited Wexford Boundary Lineament and to the south by a previously unidentified major Palaeozoic fault zone, here termed the Bristol Channel Lineament. The South Wales-Mendips Variscan successions accumulated on this intervening Wales-Celtic Sea platform, and were partly influenced by rejuvenated Caledonian fault lines. It is suggested that the northern margin of the Rheno-Hercynian foldbelt (the Variscan Front) be taken along the Bristol Channel Lineament, which can be traced for some 400 km southwestwards towards the Goban Spur on the continental margin. This permits a rationalisation of both tectonic and major facies boundaries in locating the front. It is also suggested that the structurally localised nature of the Southern Ireland basin be recognised by designating it as the Southern Ireland Zone of the Variscan foldbelt.The sites of Mesozoic rifting in the Celtic Sea and adjacent areas, although complex in detail, appear to have been located along the Wexford Boundary and Bristol Channel Lineaments.     

Eustatic and hydrodynamic controls on the architecture of a deep shelf sand bank (Celtic Sea)

The architecture of a tidal sand bank in the south-eastern Celtic Sea was examined using very high-resolution seismic surveys. The bank comprises four depositional units. The lowest unit 1 is characterized by gently dipping (1–8°) strata that strike parallel to the length of the bank. Unit 1 is erosionally overlain by unit 2, which forms the bulk of the bank. This unit consists of stacked sets of downcurrent-dipping (7–12°) master bedding formed by climbing, sinuous-crested tidal dunes that are up to 20 m high. These deposits are locally incised by an anastomosed channel network (unit 3) that may represent a buried swatchway system. The upper part of the bank comprises wave-related deposits that are mainly preserved on the bank flanks (unit 4). The outer bank surface is erosional. The bank is believed to have formed during the last post-glacial sea-level rise. The facies evolution from unit 1 to unit 3 indicates an upward increase in tidal energy, mainly characterized by the thickening of dune cross-bed sets in unit 2. The majority of bank growth is inferred to have occurred in water depths of the order of 60 m. This evolution was controlled by relative sea-level rise, which is likely to have caused an episode of tidal resonance with associated strong tidal currents that were responsible for the incision of the deep, cross-cutting channels of unit 3. The transition to wave-dominated sedimentation in unit 4 is related to the decay of resonance with continued sea-level rise.     

1993—2002年中国积雪水资源时空分布与变化特征

利用1993—2002年SSM/I被动微波逐日积雪深度反演结果,研究了我国积雪水资源的分布与变化.结果表明:积雪储量近10a来没有明显的减少或增加趋势,但是存在年际间的波动;我国冬季积雪储量主要分布在东北、北疆、青藏高原东部和其边缘地区,以及华北地区;东北、北疆和青藏高原地区为我国的稳定积雪地区;青藏高原地区积雪储量小于东北地区,但年积雪日数大于东北地区.近10a最大积雪水资源量平均约为102.79km³,其中最大年份为1999/2000年度,约为131.34km³.     

Radiocarbon constraints on the age of the maximum advance of the British–Irish Ice Sheet in the Celtic Sea

Reconstructions of the British–Irish Ice Sheet (BIIS) during the Last Glacial Maximum (LGM) in the Celtic Sea and southern Ireland have been hampered by a paucity of well-dated stratigraphic records. As a result, the timing of the last advance of the largest outlet of the BIIS, the Irish Sea Ice Stream, to its maximum limit in the Celtic Sea has been variously proposed as being pre-last glaciation, Early Devensian and LGM. The Irish Sea Till was deposited by the Irish Sea Ice Stream during its last advance into the Celtic Sea. We present 26, stratigraphically well constrained, new AMS radiocarbon dates on glacially transported marine shells from the Irish Sea Till in southern Ireland, which constrain the maximum age of this advance. The youngest of these dates indicate that the BIIS advanced to its overall maximum limit in the Celtic Sea after 26,000–20,000 ¹⁴C yr BP, thus during the last glaciation. The most extensive phase of BIIS growth therefore appears to have occurred during the LGM, at least along the Celtic Sea and Irish margins. These data further demonstrate that the uppermost inland glacial tills, from the area of supposed “older drift” in southern Ireland, a region previously regarded as having been unglaciated during the LGM also date from the last glaciation. Thus most of southern Ireland was ice covered at the LGM. Advance of the BIIS to its maximum southern limit in the Celtic Sea may have been a short-lived glaciodynamic response facilitated by subglacial bed conditions, rather than a steady-state response to climate forcing alone.     

Impact of the Spring 2000 phytoplankton bloom in Chesapeake Bay on optical properties and light penetration in the Rhode River,Maryland

Accelerating eutrophication manifest as increasing frequency and magnitude of phytoplankton blooms threatens living resources in many estuaries. Effects of large blooms can be difficult to document because blooms are often unexpected and do not always coincide with scheduled sampling programs. Here we use continuously monitored salinity distributions and optical properties to study the spring bloom of the red tide dinoflagellate,Prorocentrumminimum, in the Rhode River, Maryland, a tributary embayment of upper Chesapeake Bay. Salinity distributions, together with weekly cruise measurements of nutrient concentrations, indicate that the bloom commenced with an influx of nitrate at the mouth due to the arrival of a freshet from the Susquehanna River. Arrival of this freshet at the mouth set up an unstable, inverse salinity gradient within the Rhode River. Continuously monitored absorption and scattering spectra indicated that increases in chlorophyll within the Rhode River initially were due to the influx of chlorophyll that had developed in the main stem of the bay. After the influx, much higher concentrations and steep spatial gradients developed within the Rhode River, subsequent to reduced mixing that accompanied re-establishment of a normal estuarine salinity gradient. We used the monitored absorption and scattering coefficients to determine the effect of the bloom on light attenuation coefficients in the Rhode River. The bloom resulted in a nearly three-fold increase in attenuation coefficient. Attenuation was dominated by chlorophyll in the early stages of the bloom and by detritus after the termination of the bloom. Although the bloom lasted only 20 d, the elevated attenuation coefficients due to the bloom exceeded values that would permit growth of submersed vascular plants for a period of about 45 d.     

Chemical characteristics of aerosols in MABL of Bay of Bengal and Arabian Sea during spring inter-monsoon: A comparative study

The chemical composition of aerosols in the Marine Atmospheric Boundary Layer (MABL) of Bay of Bengal (BoB) and Arabian Sea (AS) has been studied during the spring and inter-monsoon (March-May 2006) based on the analysis of water soluble constituents (Na⁺, NH ₄ ⁺ , K⁺, Mg²⁺, Ca²⁺, Cl^?, NO ₃ ^? and SO ₄ ^2? ), crustal elements (Al, Fe, and Ca) and carbonaceous species (EC, OC). The total suspended particulates (TSP) ranged from 5.2 to 46.6 μg m^?3 and 8.2 to 46.9 μg m^?3 during the sampling transects in the BoB and AS respectively. The water-soluble species, on average, accounted for 44% and 33% of TSP over BoB and AS respectively, with dominant contribution of SO ₄ ^2? over both the oceanic regions. However, distinct differences with respect to elevated abundances of NH ₄ ⁺ in the MABL of BoB and that of Na⁺ and Ca²⁺ in AS are clearly evident. The non-sea-salt component of SO ₄ ^2? ranging from 82 to 98% over BoB and 35 to 98% over AS; together with nss-Ca²⁺/nss-SO ₄ ^2? equivalent ratios 0.12 to 0.5 and 0.2 to 1.16, respectively, provide evidence for the predominance of anthropogenic constituents and chemical transformation processes occurring within MABL. The concentrations of OC and EC average around 1.9 and 0.4 μg m^?3 in BoB and exhibit a decreasing trend from north to south; however, abundance of these carbonaceous species are not significantly pronounced over AS. The abundance of Al, used as a proxy for mineral aerosols, varied from 0.2 to 1.9 μg m^?3 over BoB and AS, with a distinctly different spatial pattern — decreasing north to south in BoB in contrast to an increasing pattern in the Arabian Sea.     

Characteristics of alkenones synthesized by a bloom of emiliania huxleyi in the Bering Sea

We investigated the characteristics of the alkenones produced by a bloom of Emiliania huxleyi in the eastern Bering Sea in 2000. Alkenones were detected in surface waters between 57°N and 63°N, where phosphate concentrations were low and the ammonium/nitrate ratio was high. The total alkenone content (C_37:2, C_37:3, and C_37:4) ranged from 22.0 to 349 μg g⁻¹ in suspended particles and from 0.109 to 1.42 μg g⁻¹ in surface sediments. This suggests that a large proportion of the particulate alkenones synthesized in the surface water rapidly degraded within the water column and/or at the water-sediment interface of the Bering Shelf. The change in the stable carbon isotopic composition (δ¹³C) of C_37:3 alkenone could not be explained only by variation in [CO₂(aq)] in the surface water but also depended on the growth rate of E. huxleyi. The alkenone unsaturation index (U^K′₃₇) was converted into an alkenone “temperature” with three equations [Prahl et al 1988], [Sikes et al 1997] and [Müller et al 1998]; Sikes et al.’s (1997) equation gave the best correlation with the observed sea surface temperature (SST) in the eastern Bering Sea. However, some temperatures estimated by Sikes et al.’s (1997) equation from the U^K′₃₇ varied from the observed SST, possibly because of the rapidly changing rate of alkenone synthesis in the logarithmic growth stage or the low rate of alkenone synthesis when nutrients were limiting. Temperatures estimated from U^K′₃₇ in the surface sediments (6.8-8.2°C) matched the observed SST in September (7-8°C) but differed from the annual average SST of 4 to 5°C, suggesting that most of the alkenone in the eastern Bering Sea was synthesized during limited periods, for instance, in September. The relative amounts of C_37:4 alkenone as proportions of the total alkenones (referred to as C_37:4%) were high, ranging from 18.3 to 41.4%. Low-salinity water (<32 psu) within the study area would have contributed to the high C_37:4% because a negative linear relationship between C_37:4% and salinity was found in this study.     

Structures and profiles of novel sulfur-linked chlorophyll derivatives in an Antarctic lake sediment

High performance liquid chromatography-mass spectrometry has permitted the identification of a homologous series of novel alkylsulfide derivatives of chlorophyll a containing between one and five carbon atoms, in sediment from a coastal Antarctic lake. The sulfur-containing compounds are present in varying abundance in stratigraphic horizons representing a phase when the lake was a marine basin. Throughout this marine phase photic zone anoxia is recorded by the presence of bacteriochlorophyll c and d-derivatives. Distributional variations between sulfurised and non-sulfurised chlorophyll a-derivatives throughout the sediment section studied indicate that the extent of sulfurisation is not controlled by chlorophyll a abundance alone.     

承德地区天然含锶矿泉水空间分布及特征分析

承德地区是京津冀水源涵养功能区和生态环境支撑区,为可持续开发与保护承德地区矿泉水资源,探求区域内含锶矿泉水成因并圈定矿泉水潜力区,依托承德地区项目组所开展的含锶矿泉水调查与勘探,在生态水文地质调查,地下水、泉、地表水样品采集及含锶矿泉水检测分析基础上,通过分析整理大量的含锶样品测试分析数据,针对主要岩性含锶值量化对比,以及含锶点图层叠加耦合,利用统计学中的相关分析、对比分析、因子分析,对研究区内三大岩类中主要岩性含锶值量化对比分析,明确指出了本区富含锶的岩性地层潜力层;利用GIS数据空间叠加分析等方法将区内含锶矿泉水分布与岩性、构造在空间上叠加并进行关联分析,圈定出富含锶矿泉水潜力构造区域带,分析研究区域内含锶矿泉水的分布规律特征及成因,为进一步指导研究区探寻构造带及地层中的富锶矿泉水潜力区,提供精准靶向目标;为进一步研究含锶矿泉水成因,尤其是富锶水与构造密切性、开采条件等因素深入研究提供重要基础支撑。     

重庆北温泉地热水碳硫同位素特征研究

重庆市北碚区北温泉景区分布有多处自然出露温泉点,选取其中流量大于2000m3/d的北温泉(BWQ)和水文站(SWZ)两处泉点进行监测,结果显示:泉水水化学类型为SO4-Ca型,pH呈中性,其阳离子主要为Ca2+和Mg2+,阴离子主要为SO42-和HCO3-,阳离子当量变化范围为31.74～40.12 meq/L,阴离子当量变化范围为29.05 ～35.08meq/L.温泉水中δ13CHCO3-的值为-4.84‰ ～-9.73‰,计算得出CO2的δ13CCO2值集中在-11.91‰～-16.81‰之间,其参与水-岩反应的CO2为幔源和土壤混合成因.δ34SSO42-值为30.29‰～32.19‰,与四川盆地下三叠统嘉陵江组石膏中的δ34SSO2-值(28.3‰ ～ 35.4‰)一致.联系温泉水中阴阳离子含量、δ34SSO42-值与δ13CHCO3-的值认为地表雨水补给进入的是下三叠统嘉陵江组碳酸盐岩地层,发生水-岩反应且水-岩反应主要为石膏的溶解,其次是CO2进入储水层与围岩发生水化学作用生成HCO3-.     

Types and Distribution of Geological Hazards in the South China Sea

Various types of geological hazards exist in the South China Sea. In dynamics sense, they can be categorized into 5 principal genetic types related to effects of hydraulic dynamics, gaseous activity, soil mechanics, gravity and tectonism, respectively. Integrated analyses indicate that the geological hazards associated with volcanoes, earthquakes and fractures are mainly distributed in tectonically active regions, whereas those resulting from mudflows, landslides and diapirs are usually concentrated in the region of slope, that shallow gas, high pressure gas pockets and soft intercalations are major potential geological hazards in the inner shelf, and that strong hydraulic dynamics, especially storm tide, is one of the major causes of geological hazards in the littoral areas. The geological hazards that occurred in the South China Sea are also characterized by periodicity, succession and, to a certain extent, unpredictability in addition to regionalization.     

Geochemical effects of oxidation products and framboidal pyrite oxidation in acid mine drainage prediction techniques

Acid mine drainage predictive testwork associated with the Australian Mineral Industries Research Association (AMIRA) P387A Project: Prediction and Kinetic Control of Acid Mine Drainage (AMD) has critically examined static acid assessment and kinetic information from acid–base accounting techniques, including net acid production potential (NAPP), net acid generation (NAG) and column leach tests. This paper compares results on two waste rock samples that were obtained from the Kaltim Prima Coal mine (KPC) containing significant quantities of fine-grained framboidal pyrite. In agreement with other research, the authors' results indicated that framboidal pyrite is more reactive than euhedral forms due to the greater specific surface area of framboidal pyrite. This is evidenced by optical microscopy of reacted samples. Importantly, the results showed that NAPP testing is biased by the rapid acid generating oxidation of framboidal pyrite prior to, and during the acid neutralisation capacity (ANC) test. This can result in negative ANC values for samples containing significant framboidal pyrite (often “corrected” to zero kg H₂SO₄/t) when significant ANC is actually present in the sample. NAG testing using H₂O₂ indicated that samples containing a significant quantity of framboidal pyrite can result in the catalytic decomposition of the H₂O₂ prior to complete oxidation of the sulfide minerals present, requiring sequential addition of H₂O₂ for completion. A benefit of the NAG test, however, is that it assesses the net acid generation capacity of the sample without bias towards acid generation as is observed using NAPP methods. The kinetic NAG test also gives information on the reaction sequence of framboidal and euhedral pyrite. Periodic (kinetic) analysis of sub-samples from column leach tests indicated rapid oxidation of the framboidal pyrite compared to the euhedral pyrite, which was correlated with the greater framboidal pyrite surface area.Calculations to determine the sulfide/sulfate acidity derived from the oxidation of framboidal pyrite prior to; and during the ANC test have been developed to provide a better indication of the actual ANC (ANC_Actual) of the sample. Paste pH values of <pH 4–5 may be one suitable trigger mechanism for the implementation of this new method. This has led to an improved NAPP estimation of total acid production. Together with NAG and column leach testing this improved methodology has resulted in accurate AMD characterisation of samples containing acidic oxidation products and framboidal pyrite.