吉林陨石雨样品中宇宙成因核素Mn^54、Co^57和K^40的深度变化

Cosmogenic radioactive nuclides, particularly K^40, Mn^54 and Co^57 are measured in meteorites Nos. Ⅰ,Ⅱ and Ⅴ from the Kirin meteorite shower which is very seldom to be met with in world history in the sense of its scale. Brief accounts are given of the distribution of cosmogenic nuclides with depth, the characteristics of cosmicray induced reactions and that of target nuclides, the energy region of bombarding particles, and the relative positions of meteorites Ⅰ,Ⅱ and Ⅴ with respect to the original meteoroid. The variations in Mn^54, Co^57 and K^40 with depth in No. I Kirin meteorite provides an excellent example for studies in this field.     

地质体中氨基酸及其对映体的分析方法

Separation and analytical methods are dealt with for amino acids and their enantiomers in samples of geological interest. Agreement is obtained for Jflin meteorite and fossil bones between the analyses of the authors‘ lab and those given by laboratories in other countries.     

吉林Ⅰ号陨石陨硫铁微量系统分析

Mierospecimons of troilite from the Jilin meteorite No. Ⅰ, weighing only 200--500 micrograms, have been determined for S, Fe, Ni and Co. The sample is firstly decomposed by 6 N hydrochloric acid mixed with hydroxylanine hydrochloride at room tcmperature. Simultaneously, tellurium ions (To^4 ) are added to combine with divalent sulfur into TeS2. Excess tellurium is determined spectrophotometrieally. The sulfur content is indirectly obtained by substracting the excess tellurium from the total amount added. After extraction and separation, each of the other elements is colormetrically determined. The results are satisfactory.     

吉林陨石中的异戊间二烯烷烃

Isoprenoid compounds in the Jilin meteorite are isolated and identified by a combined chromatography-mass spectrometry. In the chromatographic part of this instrumentation, the open glass capillary is coated with SE^30 carrier. Chromatographic and mass spectrometric evidence of the existance of pristane and phytane in the Jilin meteorite has been presented and the possible origin of these compounds briefly discussed     

An Experimental Styudy on Gold Solubility in Amino Acid Solution and Its Geological Significance

The experiments on gold solubility in amino acid solution mdicate that gold is very intensively soluble in amino acid(or other organic acids),which is extensively present in geological bodies,and is most soluble in histidine.The temperature and concentration,acidity and type of amino acid in the solution are important factors affecting gold-amino acid complexing. The solubility of gold in amino acid is different under different conditions of temperature, amino acid concentration and pH value of the solution,At 80℃ and pH=6-8,gold is most soluble in amino acid.Gold dispersed in water and rocks could be concentrated and transported by amino acid and then precipitated in favorable loci.Amino acids might have played an important role in metallogenesis as well as in the formation of source beds of gold.Nitrogen,oxygen and sulfur in amino acid might have reacted with gold to form soluble complex ions.     

Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.     

西乌珠穆沁陨石和渑池陨石的初步研究

The Xi Ujumqin meteorite fell in Aug. 1980 at Xi Ujumqin County, Nei Monggol, China.This chondrite can be classified as L6 type based on the bulk chemical analysis (6wt% metal iron, 24% total iron, olivine Fa-26) and the textural feature of complete intergrowth of the chondrules with the matrix, The Mianchi meteorite is a type Hs chondrite that fell in Sep, 1980 at Mianchi County,Henan, China. Apart from porphyritic, barred, radial, cryptocrystanine chondrules, many intermediate-type or mixed-type chondrules are observed in the Mianchi meteorite under the microscope. It is suggested that the origin of chondrules showing different textures depend on the primeval compositions and cooling rates,     

吉林陨石中包裹体特征，形成温度及其意义的探讨

Glass and gas inclusions have been observed in olivine and other minerals in 30 doubly polished tin sections of Jilin meteorites, indicating that there must have been melting And condensation stages during the process of meteorite formation. Temperatures of formation have been determined by homogenization and quenching runs,giving 1050-200℃ and 502℃ for glass and gas inclusions respectively, Meanwhile,the fibrous radial crystals of pyroxene have been notieed to grow when heated over 800℃. These observations are in general agreement with the available experimental data and theoretical calculations regarding meteorite.     

我国古代陨石的研究

Preliminary results of our study an ancient meteorite records by the end of the Ching dynasty are presented in the present paper. Early in 645 B.C. there were formal records on meteorite falls and cosmoganesis of meteorites. The utinization of iron meteorites for making weapons alloyed with bronze has a history of more than 3000 years (in the Shang and Zhou dynasties). By the time of 1064 (in the Sung dynasty) iron meteorites were well doeum anted. The geographical distribution and falling time of meteorites are also mentioned. The maximum number of meteorite falls was recorded in May and June against the minimum number in December in a year.33 serious calamities caused by meteorite f alls themselves, and several interesting records on meteorite falls are also described in this paper.     

吉林陨石球粒的结构及构造

comparatively evident chondritie structure is observed in the Jilin meteorite. Chondrules range from 0.2 to 3mm in diameter, averaging 0.6mm. Chondrules can be divided into the following types according to the principal minerals crystallized and structure-texture characteristics: (1) Olivine chondrules. In terms of their structure they can be subdivided into prophyritic, grated, barred, sub swirlling internal flow and granular chondrulcs; (2) Orthopyroxene ahondrules. Textural types found are fan-like, radial,parallel fibrous, porphyritic and irregular; (3) Olivineorthopyroxene chondrules; (4)Glass or devitrified chondrules; (5) Ni-Fe chondrules and (6) Troilite-olivine chondrules. Among them, porphyritic and granular olivine chondrules and various kinds of radial orthopyroxene chondrules are most common. In addition, also have been recognized the overlapping of two or more chondrules and chondrules coated with glassy crust. The structure and texture of chondrules indicate that they were originated from molten silicate droplets through rapid cooling prior to the formation of the meteorite parent body. Rapid fusion may be induced on the surface of a few solidified chondrules by solar impulse wave or nebula lightning and, if rapid cooling followed, this would give rise to the appearance of glassy crust. Collision between chondrulcs may result in a variety of chondrule fragments and crystal debris. In some cases, collision is also considered to be responsible for the entrench, inclusion and overlapping textures in ehondrules. After the formation of the meteorite parent body recrystallization of chondrules may take place as a result of thermal metamorphism.     

吉林陨石中有机色素和卟啉化合物的初步研究

This paper discribes the extraction of porphyrin compounds and related pigments from Jilin meteorite with 9:1 (v/v) benzene and methanol mixture. After removal of sulfur and asphalts the hexane solution of the extract is eluted through a silica jel chromatographic column with hexane, benzene, and acetone successively.Nickel porphyrin, vanadium porphyrin and chlorins are found in the benzene eluate and their content are estimated to be 0.008 ppm, 0.006 ppm and 0.002 ppm respectively.The aliphatie hydrocarbons in the meteorite are estimated to be approximately 74pp.The results are summarized and discussed.     

吉林陨石的不透明矿物

Opaque minerals in the Jilin meteorite inelude kamacite, taenite troilite, chromite, ilmenite, schreibersite, pyrite, pyrrhotite, chalcopyrite, sphalerite and graphite.Five of the above-mentioned minerals have been discussed in more detail in terms of optical and physical properties, chemical composition, coexisting relationship, and the order of crystallization. It is indicated from this study that, with the exception of a small amount of Ni-Fe cbondrules, silicate minerals are the first to erystallize followed by chromite, ilmenite at the early stage of nebula condensation, while Ni-Fe phase in the matrix is considered to be of a more later erigin. At the late stage of nebula condensation troilite resulted from the reaction of Ni-Fe metal with residual H2S vapor. As indicated by the occurrence of coarse grained Ni-Fe metal, the recrystallization of troilite and the apparent Neumann lines in kamaeite, it is expected that opaque minerals in the Jilin metevrite have undergone different degrees of thermal and impact metamorphisms.     

Noble gases,nitrogen and cosmic ray exposure age of the Sulagiri chondrite

The Sulagiri meteorite fell in India on 12 September 2008,LL6 chondrite class is the largest among all the Indian meteorites.Isotopic compositions of noble gases(He,Ne,Ar,Kr and Xe) and nitrogen in the Sulagiri meteorite and cosmic ray exposure history are discussed.Low cosmogenic(~(22)Ne/~(21)Ne)_c ratio is consistent with irradiation in a large body.Cosmogenic noble gases indicate that Sulagiri has a 4πcosmic-ray exposure(CRE) age of 27.9 ± 3.4 Ma and is a member of the peak of CRE age distribution of IX chondrites.Radiogenic ~4He and ~(40)Ar concentrations in Sulagiri yields the radiogenic ages as 2.29 and4.56 Ca,indicating the loss of He from the meteorite.Xenon and krypton are mixture of Q and spallogenic components.     

吉林陨石的烃类和嘌呤、嘧啶化合物

Preliminary investigation was earried out on the Jilin meteorite for hydrocarbonand nitrogen-bearing organic compounds. It shows that the meteorite contains 68 ppm of soluble organic matter, among which the normal alkanes amount to 0.36---0.48 ppm,with carbon number distribution ranging from C17 to C31, and the aromatic hydrocarbons herein are mainly composed of polyalkyl-substituted less condensed rings. Purine derivatives and pyrimidine have also been found. A discussion is given as to the origin of these organic substanees.     

东海沉积物中脂肪酸分布特征

Monocarboxylic acids and dicarboxylic acids in sea-floor sediments of the Jizhou Island and estuarine sediments at the Yangtze River mouth have been examined by using thin layer chromatography and gas chromatography as well as computerized gas chromatography-mass spectrometry. Free and bound fatty acids distributed in the sea-floor sediments show remarkable even/odd predominances except for sample 8138. Monocarboxylic acids show a unimodal distribution, ranging from n-C14 to n-C32. with the maximum at n-C16 while dicarboxylic acids also show a unimodal distribution, ranging from di-Cl6 to di-C32 with the maximum at di-C24 or di-C28. Evidence from the distribution of fatty adds in the East China Sea sediments indicatesthat these monoearboxylic acids are probably derived from algal debris and,these dicarboxylic acids are derived from terrigenous higher plant detritus.     

月岩（70017—291）的X光电子能谱（XPS）初步研究

Using X-ray photoemission spectroscopy (XPS), the Preliminary results on the lunar basalt sample (70017-291)are shown in the paper. Major elements (O, Si,Al, Fe, Ca, Mg, Ti, etc.) of the lunar sample are similar to that of the Jilin meteorite and the Allende meteorite. The valence of iron in the sample has also been studied in detail. The authors suggest that Fe^ may be differentiated from Fe^ in the XPS spectra in terms of the satellite lines of Fe(2p3/2).     

Bulk Chemical Composition of the Ningqiang Carbonaceous Chondrite： An Issue of Classification

The Ningqiang meteorite is a fall carbonaceous chondrite, containing various Ca-, Al-rich inclusions that usually escaped from secondary events such as high-temperature heating and low- temperature alteration. However, it has not yet been classified into any known chemical group. In order to address this issue, 41 elements of the bulk Ningqiang meteorite were analyzed using inductively coupled plasma mass spectrometry （ICP-MS） and inductively coupled plasma atom emission spectrometry （ICP-AES） in this study. The Allende （CV3） carbonaceous chondrite and the Jilin （H5） ordinary chondrite were also measured as references, and our analyses are consistent with the previous results. Rare earth and other refractory lithophile elements are depleted in Ningqiang relative to both Allende and mean CK chondrites. In addition, the REE pattern of Ningqiang is nearly flat, while that of Allende shows slight enrichment of LREE relative to HREE. Siderophile elements of Ningqiang are close to those of mean CK chondrites, but lower than those of Allende. Our new analyses indicate that Ningqiang cannot be classified into any known group of carbonaceous chondrites, consistent with previous reports.     

Reservoir geochemistry of the Tazhong oilfield in the Tarim Basin, China, Part Ⅰ. Geochemical characteristics and genetic classification of crude oils

According to the assemblage characteristics of saturated hydrocarbon biomarkers in crude oils and their geochemical implications, this study has proposed, for the first time, the criteria for the genetic classification of crude oils in the Tazhong area of the Tarim Basin, China. Crude oils from the area studied are classified as three genetic types： type-Ⅰ is characterized by the low contents of C29 norhopane, extremely abundant contents of gammacerane, low contents of rearranged sterane and relatively high contents of regular C28 sterane; the geochemical properties of type-Ⅱ crude oils are opposite to those of type-Ⅰ crude oils; the parameters for type-Ⅲ crude oils are intermediate between type-Ⅰ and type-Ⅱ. Results of oil correlation indicated that type-Ⅰ crude oils were derived from Cambrian-Lower Ordovician hydrocarbon source rocks, type-Ⅱ curde oils originated from Middle-Upper Ordovician hydrocarbon source rocks and type-Ⅲ crude oils are of mixed origin.     

On the Origin of Petroleum Hydrocarbon Gases

The compositional variation of oil-soluble gaseous hydrocarbons in high-pressure in-place oil from more than 40 oil wells in the Northern Jiangsu oil field, China, was studied. Samples in which the effects of the factors of pressure and biodegradation had been got rid of were chosen as the representatives that could really reflect the original composition of hydrocarbon gases. Such samples were compared compositionally with their corresponding hydrocarbons formed by decarboxylation of volatile low-molecular fatty acids. Thus highly correlative regularities were found to exist between them. The numerical values of both are graphically expressed. The two curves on the diagram are very similar. These two sets of values have a simple correlation coefficient of 0.9935, which presents their genetic relation.Based on the study of the formation of gaseous hydrocarbons from decarboxylation of volatile fatty acids, the following regularities of the isomers are revealed:1) n-butyric acid + isobutyric acid = propane:2) 1 2 isopentanoic acid(2-methyl-butyric acid) + n-pentanoic acid = n-butane; and3) 1 2 isopentanoic acid(3-methyl-butyric acid) = isobutane.The thermodynamics of decarboxylation was analysed and the enthalpy change △H, entropy change △S and Gibbs free energy change △G in the following reaction were calculated:CH_3COOH(1)--CH_4(g) + CO_2(g).Thus the author considers that the reaction for the formation of hydrocarbons due to the decarboxylation of fatty acids is an exothermic one with increased entropy and decreased free energy as well as a spontaneous one. According to the CRC rule, the resultant Gibbs free energy change △G is approximately-41.84 kJ/mol, which is well within the range of the energy levels of biophysiological changes.According to the changes in odd-carbon preference in n-alkanes of petroleum and sediments and the analysis of fatty acids and amino acids, it is considered that hydrocarbon gases do not originate from pyrolysis or thermal degradation but from decarboxylation of organisms. But this biological reaction is not ordinary biochemical reaction in the artificial fermentation for generating marsh gas. On the basis of the change tendency of the fatty acid content in the fermentation liquor for marsh gas generation and the change tendency of the carbon isotopes in methane and carbon dioxide in the marsh gas, it can be judged that the biochemical reaction for forming hydrocarbon gases is a special biological one occurring after the fermentation.     

Reservoir geochemistry of the Tazhong oilfield in the Tarim Basin, China, Part Ⅰ. Geochemical characteristics and genetic classification of crude oils

According to the assemblage characteristics of saturated hydrocarbon biomarkers in crude oils and their geochemical implications, this study has proposed, for the first time, the criteria for the genetic classification of crude oils in the Tazhong area of the Tarim Basin, China. Crude oils from the area studied are classified as three genetic types: type-Ⅰ is characterized by the low contents of C29 norhopane, extremely abundant contents of gammacerane, low contents of rearranged sterane and relatively high contents of regular C28 sterane; the geochemical properties of type-Ⅱ crude oils are opposite to those of type-Ⅰ crude oils; the parameters for type-Ⅲ crude oils are intermediate between type-Ⅰ and type-Ⅱ. Results of oil correlation indicated that type-Ⅰ crude oils were derived from Cambrian-Lower Ordovician hydrocarbon source rocks, type-Ⅱ curde oils originated from Middle-Upper Ordovician hydrocarbon source rocks and type-Ⅲ crude oils are of mixed origin.