华北克拉通南缘豫西下汤地区2.3 Ga岩浆作用和1.94 Ga变质作用

本文报道了华北克拉通南缘豫西鲁山下汤地区古元古代片麻状花岗岩和黑云角闪斜长片麻岩的全岩地球化学和锆石SHRIMP U-Pb年龄和Hf同位素组成。岩石呈包体形式存在于中元古代花岗岩中。片麻状花岗岩具深熔特征,岩浆锆石年龄为2.30Ga;岩石高SiO2和K2O,低ΣFeO、MgO和CaO,具稀土总量较高(ΣREE=165.8×10-6)、轻重稀土分离较强[(La/Yb)n=37.8]及弱负铕异常(Eu/Eu*=0.76)的稀土模式;εNd(t)(t=2.30Ga)=-0.75;tDM(Nd)=2.66Ga。黑云角闪斜长片麻岩变质原岩为辉长闪长岩,捕获锆石年龄为2.25Ga;岩石低SiO2和MgO,高Al2O3和P2O5,具稀土总量高(ΣREE=373.4×10-6)、轻重稀土分离不强[(La/Yb)n=9.4]及较强负铕异常(Eu/Eu*=0.44)的稀土模式;εNd(t)(t=2.25Ga)=-1.21;tDM(Nd)=2.75Ga。片麻状花岗岩和黑云角闪斜长片麻岩都记录了1.94Ga变质锆石年龄。片麻状花岗岩的岩浆锆石组成域的εHf(t)(t=2.30Ga)=-6.71～0.38,tDM1(Hf)=2627～2910Ma,tDM2(CC)(Hf)=2823～3255Ma。黑云角闪斜长片麻岩的捕获锆石组成域的εHf(t)(t=2.25Ga)=-19.58～-1.73,tDM1(Hf)=2664～3360Ma,tDM2(CC)(Hf)=2968～4011Ma。结合前人资料,得出如下结论:华北克拉通南缘豫陕晋结合部地区存在一规模较大的约2.3Ga地质体分布区;华北克拉通南缘很可能存在规模巨大的>2.7Ga基底;中部造山带与孔兹岩带具有类似的古元古代晚期构造热事件演化历史。     

华北克拉通南缘下汤地区古元古代构造热事件——地球化学特征、锆石SHRIMP U-Pb定年和Hf同位素研究

本文报道了华北克拉通南缘鲁山县下汤地区早前寒武纪变质基底岩石的地球化学、锆石定年和Hf同位素组成。上太华岩群两个变质沉积岩样品的变质锆石年龄为1.91~1.93 Ga,由于变质作用强烈改造,碎屑锆石真正的形成年龄难以确定。碎屑锆石ε_(Hf)(t)和t_(DMW(CC))(Hf)分别为-0.26~10.41和2244~2958 Ma。一个变质辉长闪长岩样品的捕获锆石年龄为2.32 Ga,变质锆石年龄为1.93 Ga。捕获锆石的ε_(Hf)(t)和t_(DM2(CC))(Hf)分别为-1.79~2.22和2695~2940 Ma。两个片麻状奥长花岗岩样品的岩浆锆石和变质锆石年龄分别为1.93 Ga和1.92 Ga,岩浆锆石的ε_(Hf)(t)和t_(DM2(CC))(Hf)分别为-3.30~1.30和2481~2764 Ma。一个片麻状正长花岗岩样品的岩浆锆石和变质锆石年龄分别为1.93 Ga和1.92 Ga,岩浆锆石的ε_(Hf)(t)和t_(DM2(CC))(Hf)分别为-3.67~2.40和2415~2788 Ma。结合地球化学和前人研究结果,可得出如下结论:(1)上太华岩群形成时代形成于古元古代早期;(2)进一步支持了该区存在约2.3 Ga岩浆作用的认识;(3)发现广泛分布的1.91~1.93 Ga壳源奥长花岗岩和正长花岗岩;(4)确定1.91~1.94 Ga变质作用在该区广泛发育。     

Petrogenesis of Kejie Granite in the Northern Changning-Menglian Zone, Western Yunnan: Constraints from Zircon U-Pb Geochronology, Geochemistry and Hf Isotope

The Kejie pluton is located in the north of the Changning-Menglian suture zone. The rock types are mainly biotite-granite. Zircon LA-ICP-MS U-Pb dating indicates that the Kejie pluton emplaced at about 80–77 Ma, Late Cretaceous. The Kejie pluton samples are characterized by high SiO2(71.68%–72.47%), K2O(4.73%–5.54%), total alkali(K2O + Na2O = 8.21%–8.53%), K2O/Na2O ratios(1.36–1.94) and low P2O5(0.13%–0.17%), with A/CNK of 1.025–1.055; enriched in U, Th, and K, depleted in Ba, Nb, Sr, Ti, P and Eu. They are highly fractionated, slightly peraluminous I-type granite. The two samples of the Kejie pluton give a large variation of εHf(t) values(-5.04 to 1.96) and Hf isotope crustal model ages of 1.16–1.5 Ga. Zircon Hf isotopes and zircon saturation temperatures of whole-rock(801°C–823°C) show that the mantle-derived materials maybe have played a vital role in the generation of the Kejie pluton. The Kejie pluton was most likely generated in a setting associated with the eastward subduction of the neo-Tethys ocean, where intrusion of mantle wedge basaltic magmas in the crust caused the anatexis of the latter, forming hybrid melts, which subsequently experienced high-degree fractional crystallization.     

Polymetamorphism of the Variscan Basement of the Moldanubian Black Forest （Germany） Documented in Zircon and Garnet Minerals from Gneisses

High-grade metamorphic Variscan basement is exposed in the Moldanubian zone of the Black Forest (BF), being the internal zone of the European Variscan belt. Zircon grains from K-rich felsic orthogneisses and an anatectic paragneiss in the Moldanubian Black Forest demonstrate a multi-stage crystallization at ～ 600 Ma, ～ 480 Ma, ～ 400 - 380 Ma, and ～350 Ma. The last three stages of crystallization probably represent metamorphic overprint during pre-Variscan and Variscan metamorphism.Using stepwise leaching procedures, garnet minerals from felsic orthogneisses as well as paragneisses in the Moldanubian Black Forest yielded Early Carboniferous Sm-Nd ages (～ 330- 340 Ma), which are consistent with the well-constrained Variscan HT metamorphic event,and Early Palaeozoic ( ～480 Ma) to Devonian ( ～400 - 370 Ma) Pb-Pb ages. The coincidence of growth time for zircon and garnet minerals at Early Palaeozoic is interpreted as dating a metamorphic event. These garnet data demonstrate that the Moldanubian BF basement underwent at least two metamorphic events during the Early Palaeozoic and Early Carboniferous.During the Variscan HT metamorphism, the Sm-Nd system of garnet was disturbed, but not the U-Pb system, implying the peak metamorphic temperature was lower than ～800℃.     

冀东古元古代基性岩墙群的年龄及地球化学:～2.1Ga伸展及～1.8Ga变质

以往华北克拉通早前寒武纪地质的研究主要集中于东、西部陆块的2.5Ga事件及中部带的2.2~2.0Ga、1.95~1.8Ga事件的研究,最近通过工作发现东部陆块内部亦有~2.1Ga、~1.8Ga事件的记录。我们通过对冀东石门变质基性岩墙群进行离子探针锆石U-Pb测年和地球化学研究,表明基性岩墙的形成年龄为2162±27Ma,经历了1820±7.8Ma的变质作用;其围岩英云闪长质片麻岩形成于2531±14Ma,紧接着经历了2513±15Ma的麻粒岩相变质,虽与石门基性岩墙共同经历了~1.8Ga变质作用,但并没有新生的该期变质锆石记录。石门基性岩墙SiO_2含量介于50.38%~51.08%,MgO含量为4.29%~5.81%,具有较低的Mg#值(32~41),属于拉斑玄武岩类;其轻稀土略为富集,具有弱的负铕异常,富集大离子亲石元素(Rb、Ba),亏损高场强元素(Nb、Ta、Ti),具有低正的εNd(t)值(1.47)和正的εHf(t)值(1.88~8.80),其Hf模式年龄与基性岩墙的形成年龄接近,介于2206~2338Ma,推测石门基性岩墙的玄武质岩浆来自于亏损地幔的部分熔融并经历了结晶分异和地壳混染过程,形成于陆内裂谷的构造背景。本文认为~2.1Ga的岩浆活动为华北陆块在新太古代末克拉通化后,经历的一次强烈的伸展事件,可能导致了原有基底发生了裂解。     

SHRIMP Zircon U-Pb Dating of Gabbro and Granite from the Huashan Ophiolite, Qinling Orogenic Belt, China： Neoproterozoic Suture on the Northern Margin of the Yangtze Craton

The recently identified Huashan ophiolitic melange was considered as the eastern part of the Mianliie suture in the Qinling orogenic belt. SHRIMP zircon U-Pb geochronology on gabbro from the Huashan ophiolite and granite intruding basic volcanic rocks indicates crystallization ages of 947±14 Ma and 876±17 Ma respectively. These ages do not support a recently proposed Hercynian Huashan Ocean, but rather favor that a Neoproterozoic suture assemblage (ophiolite) is incorporated into the younger (Phanerozoic) Qinling orogenic belt.     

Geochronology and Isotope Geochemistry of the Xiqiu Spilite—Keratophyre in Zhejiang Province,China

Spilite- keratophyre is a key member of the Shuangxiwu Group volcanic series in Zhejiang Province. Presented in this paper are the reliable Sm- Nd internal isochron age (1012±28 Ma, Є_Nd(T)=4.4±0.1) and whole- rock Rb- Sr isochron age (972±40 Ma,I_Sr=0.70327±8) obtained for the first time by the authors. From the available Nd, Sr and O isotope data in conjunction with the major and trace elements data it is suggested that the Xiqiu spilite- keratophy re is the product of island- arc volcanism during the late Middle Proterozoic.     

Paleoproterozoic crustal evolution of the Hengshan–Wutai–Fuping region, North China Craton

An arguable point regarding the Neoarchean and Paleoproterozoic crustal evolution of the North China Craton（NCC）is whether the tectonic setting in the central belt during the mid-Paleoproterozoic（2.35-2.0 Ga）was dominated by an extensional regime or an oceanic subduction-arc regime.A review of the midPaleoproterozoic magmatism and sedimentation for the Hengshan-Wutai-Fuping region suggests that a back-arc extension regime was dominant in this region.This conclusion is consistent with the observation that the 2.35-2.0 Ga magmatism shows a typical bimodal distribution where the mafic rocks mostly have arc affinities and the acidic rocks mainly comprise highly-fractioned calc-alkaline to alkaline（or A-type）granites,and that this magmatism was coeval with development of extensional basins characteristic of transgressive sequences with volcanic interlayers such as in the Hutuo Group.Although the final amalgamation of the NCC was believed to occur at ～1.85 Ga,recent zircon U-Pb age dating for mica schist in the Wutai Group suggests a collisional event may have occurred at ～1.95 Ga.The metamorphic ages of ～1.85 Ga,obtained mostly from the high-grade rocks using the zircon U-Pb approach,most probably indicate uplifting and cooling of these high-grade terranes.This is because（i）phase modeling suggests that newly-grown zircon grains in highgrade rocks with a melt phase cannot date the age of peak pressure and temperature stages,but the age of melt crystallization in cooling stages;（ii）the metamorphic P-T paths with isobaric cooling under 6-7 kb for the Hengshan and Fuping granulites suggest their prolonged stay in the middle-lower crust;and（iii）the obtained metamorphic age data show a continuous distribution from 1.95 to 1.80 Ga.Thus,an alternative tectonic scenario for the Hengshan-Wutai-Fuping region involves：（i）formation of a proto-NCC at ～2.5 Ga;（ii）back-arc extension during 2.35-2.0 Ga resulting in bimodal magmatism and sedimentation in rifting basins on an Archean basement;?     

Metallogenic age and fluid evolution of the Kangshan Au-polymetallic deposit in the southern margin of the North China Craton: Constraints from monazite U-Pb age,and in-situ trace elements and S isotopes of pyriteSCIEI北大核心CSCD

小秦岭-熊耳山金矿集区位于华北克拉通南缘,发育众多伴生铅锌银等金属的金矿,成为揭示克拉通破坏型金矿成因的天然实验室。产于小秦岭-熊耳山金矿集区内的康山金多金属矿床受控于北东向的中生代脆性断裂,赋存于新太古代变质岩和中元古代火山岩中。成矿过程可分为4个热液阶段:石英±黄铁矿阶段、石英-黄铁矿-黄铜矿-自然金阶段、多金属硫化物-自然金-石英-铁白云石阶段、石英-方解石±萤石阶段。本文获得康山金多金属矿床金成矿阶段热液独居石LA-ICP-MS U-Pb年龄为131.7±4.6Ma,与晚中生代华北克拉通破坏有关的岩浆热液成矿作用时代一致。本次研究开展的各阶段黄铁矿原位微量元素单点和扫面分析,发现第2阶段Au与Co、Ni、As呈正相关关系,且有明显的振荡环带,Cu、Ag、Sb、Pb、Bi这几种元素从黄铁矿颗粒的核部向边缘含量逐渐降低,且黄铁矿颗粒中出现富含这些元素的矿物包裹体,说明该阶段发生流体沸腾作用;而第3阶段黄铁矿中各微量元素含量为所有阶段中最低,黄铁矿无振荡环带且裂隙中有富含各微量元素的硫化物充填,说明各种元素在该阶段均得到充分卸载,且成矿流体的化学性质较稳定。结合前人关于该矿床各阶段流体包裹体分析结果,表明流体沸腾是Au的主要沉淀机制,而流体混合是Pb、Zn、Ag的主要沉淀机制。黄铁矿中微量元素含量指示,从第1阶段到第3阶段流体温度依次降低;第2和第3阶段流体fO2比第1阶段高且后两者相差不大。根据黄铁矿Co、Ni含量及比值的计算,认为第1和第2阶段黄铁矿为岩浆热液成因,第3阶段黄铁矿受围岩物质影响。黄铁矿原位S同位素分析得到第1至第3阶段黄铁矿δ34S分别为+6.6‰-+8.9‰、+5.0‰-+7.2‰和+6.0‰-+8.7‰,均与区域花岗岩类的S同位素值类似。综上所述,本文得出康山金多金属矿床形成于早白垩世与华北克拉通破坏有关的岩浆热液成矿作用。     

LA-ICPMS U-Pb Ages of Zircon from Metaleucosomes, Olongbuluke Microcontinent, North Qaidam, and Implications on the Response to the Global Rodinia Supercontinent Assembly Event in NW China

INTRODUCTION The Olongbuluke microcontinent , which wasdisintegratedfromthe northern margin of the Qaidamblock (Lu,2002) ,is composed of a two-fold base-ment with cover strata . The lower basement is themedium- to high-grade Delingha complex and theDakendaban Group, and the upper is the low-gradeWandonggou Group. The Wandonggou Group of theupper basement experienced a Late Mesoproterozoicmetamorphic event (see Yu et al .,1994) ,consistentwith the early isotopic geochronological respo…     

内蒙古狼山地区叠布斯格岩群锆石U-Pb年龄、Hf同位素特征及其对阿拉善地块构造演化的制约

阿拉善地块位于华北克拉通西端,其早前寒武纪地质演化一直存在争议。选取阿拉善地块东北缘的叠布斯格岩群为研究对象,通过锆石U-Pb定年和Lu-Hf同位素分析,探讨阿拉善地块的性质和归属及华北克拉通早期地质演化。叠布斯格岩群主要由变质沉积岩和变质火山岩组成,包括高级变质的片麻岩、大理岩、石英岩、角闪岩,并被古元古代钾质花岗岩侵入。来自叠布斯格岩群3个副片麻岩样品的LA-ICP-MS锆石U-Pb定年结果显示,叠布斯格岩群副片麻岩中碎屑锆石的207Pb/206Pb年龄范围为2.60~2.10 Ga,变质锆石的年龄显示叠布斯格岩群经历了1.98~1.90 Ga和1.90~1.79 Ga的两组峰期变质作用,指示叠布斯格岩群原岩形成于2.10~1.98 Ga。研究区未发现有太古宙岩石出露,但不排除其下部地壳中存在太古宙基底岩石的可能。碎屑锆石的Lu-Hf同位素数据结果显示,叠布斯格岩群副片麻岩中碎屑锆石的εHf(t)均为负值,指示其成岩物质源于古—中太古代(3.42~2.79 Ga)古老地壳在新太古代晚期—古元古代早期的重熔或再造。通过对比叠布斯格岩群和阴山地块、孔兹岩带的岩浆-变质事件及Hf同位素特征,推测阿拉善地块前寒武纪基底在古元古代可能是孔兹岩带的一部分。     

冀东地区新太古代晚期的岩浆事件与地壳增生:来自岩石地球化学和锆石年龄及Hf同位素的制约

在华北克拉通东部冀东的遵化-迁西-迁安地区广泛分布有新太古代晚期的斜长角闪岩(基性火山岩)、TTG片麻岩和紫苏闪长岩/紫苏花岗岩。锆石U-Pb同位素测定表明,该区的斜长角闪岩、TTG片麻岩和紫苏闪长岩/紫苏花岗岩几乎同时形成于2529±30Ma到2555±14Ma期间。这是华北克拉通新太古代晚期一次重要的岩浆事件,并紧随有2.5Ga左右的麻粒岩相变质作用。阴极发光图像显示,TTG片麻岩和紫苏闪长岩/紫苏花岗岩中一些锆石的核部为灰黑色,具杉树叶结构或无内部结构,意味着这些锆石核部的U-Th-Pb同位素体系在变质作用期间受到了干扰或重置,因此岩浆锆石核部的207Pb/206Pb加权平均年龄通常被解释为代表岩浆事件最年轻的年龄。新太古代晚期TTG片麻岩和紫苏闪长岩/紫苏花岗岩的岩浆锆石具有正的εHf(t)值(-0.08~9.49),计算的tDM1(Hf)模式年龄介于2572~2896Ma之间,峰值年龄为2.72Ga。这表明,TTG片麻岩和紫苏闪长岩/紫苏花岗岩的母岩浆是从亏损地幔源分异出来的,且2.7Ga是研究区和华北克拉通最重要的一次地壳增生事件。地球化学和岩石成因研究表明,本区的TTG片麻岩和紫苏闪长岩/紫苏花岗岩是由来自新生地壳基性岩石部分熔融形成的岩浆通过结晶分离形成的,其中角闪石是主要的分离相矿物。地幔柱模式更有利于解释本区TTG片麻岩和紫苏闪长岩/紫苏花岗岩的成因以及冀东地区的许多其他地质特征。     

Geochemistry, Zircon U–Pb Dating and Hf Isotopic Characteristics of Neoproterozoic Granitoids in the Yaganbuyang Area, Altyn Tagh, NW China

The South Altyn continental block is an important geological unit of the Altyn Tagh orogenic belt, in which numerous Neoproterozoic granitoids crop out. Granitoids are mainly located in the Paxialayidang–Yaganbuyang area and can provide indispensable information on the dynamics of Rodinia supercontinent aggregation during the Neoproterozoic. Therefore, the study of granitoids can help us understand the formation and evolutionary history of the Altyn Tagh orogenic belt. In this work, we investigated the Yaganbuyang granitic pluton through petrography, geochemistry, zircon U–Pb chronology, and Hf isotope approaches. We obtained the following conclusions:(1) Yaganbuyang granitoids mainly consist of two-mica granite and granodiorite. Geochemical data suggested that these granitoids are peraluminous calc–alkaline or high-K calc–alkaline granite types. Zircon U–Pb data yielded ages of 939±7.1 Ma for granodiorite and ~954 Ma for granitoids, respectively.(2) The εHf(t) values of two–mica granite and granodiorite are in the range of-3.93 to +5.30 and-8.64 to +5.19, respectively. The Hf model ages(TDM2) of two-mica granite and granodiorite range from 1.59–.05 Ga and 1.62–2.35 Ga, respectively, indicating that the parental magma of these materials is derived from ancient crust with a portion of juvenile crust.(3) Granitoids formed in a collisional orogen setting, which may be a response to Rodinia supercontinent convergence during the Neoproterozoic.     

Geochronology,Mineralogy, and Geochemistry of the Tonsteins from the Permo–Carboniferous Benxi Formation,Ordos Basin,North China Craton

Tonstein layers are found worldwide in the Permo–Carboniferous coal-bearing strata. This study investigates the geochronology, mineralogy, and geochemistry of four tonstein samples from the Permo–Carboniferous Benxi Formation, Ordos Basin, North China Craton(NCC). The typical features of the studied tonsteins include thin beds, lateral continuity, angular quartz grains, and euhedral zircons with similar U-Pb ages, indicating a significant pyroclastic origin. In addition, the tonstein samples hav...     

Late Jurassic-Early Cretaceous Plutonism in the Northern Part of the Precambrian North China Craton： SHRIMP Zircon U-Pb Dating of Diorites and Granites from the Yunmengshan Geopark, Beijing

The Yunmengshan Geopark in northern Beijing is located within the Yanshan range.It contains the Yunmengshan batholith,which is dominated by two plutons:the Yunmengshan gneissic granite and the Shicheng gneissic diorite.Four samples of the Yunmengshan gneissic granite give SHRIMP zircon U-Pb ages from 145 to 141 Ma,whereas four samples of the Shicheng gneissic diorite have ages from 159 Ma to 151 Ma.Dikes that cut the Yunmengshan diorite record SHRIMP zircon UPb age of 162±2 and 156±4 Ma.The cumulative pl...     

Crustal architecture of the oblique collision belt: Insights of the spatial variation in U-Pb ages and Hf isotope of inherited zircons from the Eocene to Oligocene magmatic rocksSCIEI北大核心CSCD

在通过锆石U-Pb方法测定岩浆活动时代的过程中总会获取或多或少的继承锆石年龄数据,这些数据对于揭示岩浆岩所处构造单元的构造-岩浆事件序列具有独特优势。本文选择印度-欧亚大陆侧向碰撞带内NEE走向的始-渐新世岩浆岩带作为研究对象,详细收集、梳理该岩浆岩带内现有测年结果中的继承锆石U-Pb年代学和Hf同位素数据,采用统计分析方法,尝试探讨被该岩浆岩带穿越的扬子、印支、保山、腾冲地块的构造-岩浆事件及其序列,对比分析其大地构造亲缘性和地块拼贴历史。继承锆石U-Pb年龄频率分布和Hf同位素数据统计结果显示,扬子与印支地块记录了相同的晋宁期、加里东期、印支期构造-岩浆事件,而腾冲与保山地块则记录了相同的加里东期、印支期构造-岩浆事件。结合现有地层学、古生物和古地磁等方面数据,我们提出扬子-印支与腾冲-保山地块作为两个具有不同结晶基底的独立地块,分别就位于古生代-早中生代古大洋(原、古特提斯洋)的两侧,该大洋板块双向俯冲于这两个地块之下,在两个地块内留下了可高度对比的构造-岩浆事件。由此提出,正向碰撞带班公湖-怒江缝合带内完备的地质记录与侧向碰撞带之间的关联、哀牢山洋的构造属性等是值得深入探究的重大问题。     

Ages of Lueliang Group and Its Metamorphism in Mt.Lueliang Region,Shanxi Province：Evidence form Single Grain Zircon U—Pb Dating

Presented in this paper are the newly obtained grain zircon U-Pb ages of volcanic rocks of the Lueliang Goup and associated Kuanping granitic migmatitic gneiss in Shanxi Province.The zircon U-Pb ages of bimodal volcanic rocks(basalt and rhyolite)of the Upper Lueliang Group indicate that the rocks erupted at about 2100 Ma.So the Lueliang Group was formed during the Early Proterozoic.In the area studied the second-stage metamorphism experienced by the Lueliang Group is the dominant one which took place at about 1806 Ma.i.e.,during the late Early Proterozoic.     

Genesis and tectonic setting of Late Jurassic-Early Cretaceous granites in Nachatang area,Central Lhasa Terrane: Constraints from geochemistry,chronology and Hf isotopesSCIEI北大核心CSCD

西藏中拉萨地块东段大规模侏罗纪-白垩纪花岗岩类的成因类型及构造背景尚未得到有效约束,该时期岩浆作用的时空分布、岩石成因以及深部动力学机制等问题亟需新的深入研究。本文对中拉萨地块东段南缘那茶淌地区的花岗岩类进行了系统的岩相学、元素地球化学、年代学和锆石Hf同位素研究。LA-MC-ICPMS锆石U-Pb定年结果显示,那茶淌地区黑云母二长花岗岩成岩年龄为147±1.4Ma,花岗闪长岩年龄为140.6±1.3Ma,系晚侏罗世-早白垩世中酸性岩浆活动的产物。在元素地球化学组成上,黑云母二长花岗岩和花岗闪长岩的主量元素组成具有富SiO₂(分别为71.02%～71.81%和65.17%～66.73%)、Al₂O₃(分别为13.45%～13.57%和14.43%～15.20%)、碱金属(Na₂O+K₂O)(分别为6.79%～7.48%和6.55%～7.37%),贫TiO₂(分别为0.15%～0.21%和0.10%～0.13%)等特征,显示I型准铝-弱过铝质(A/CNK=0...