Multiple zircon growth within early Archaean tonalitic gneiss from the Ancient Gneiss Complex, Swaziland

UPb age determinations by ion microprobe reveal multiple episodes of zircon growth and recrystallization within a single sample of tonalitic gneiss from the Ancient Gneiss Complex. The oldest episode at3644 ± 4Ma(2σ) produced the dominant type of zircon, characteristically purplish-brown and massive in texture; this probably constitutes unaltered zircon precipitated from the original magma. Recrystallization accompanied (and obscured) by early Pb loss took place within the oldest grains at3504 ± 6Ma and3433 ± 8Ma. Whole new grains grew at these times also. We interpret the post-3644 Ma growth as due to episodic deformational and metamorphic events that transformed the tonalite pluton into foliated banded gneiss. In addition, many grains are visibly overgrown by two layers of younger zircon of different colour and texture, dated at2986 ± 20Ma and2867 ± 30Ma. Euhedral, finely-zoned whole grains having the 2986 Ma age are present also, evidently contributed by very thin felsic veins associated with the nearby Lochiel granite. The age of3644 ± 4Ma combined with precise zircon UPb dating of volcanics from the Onverwacht Group reported elsewhere demonstrates that at least part of the Ancient Gneiss Complex is older than the Barberton Greenstone Belt.     

Further U-Pb dates on zircons from the early Precambrian rocks of the Godthaabsfjord area,West Greenland

U-Pb analyses of zircons from the Godthaabsfjord area in West Greenland yield dates of 2530 ± 30 m.y. for the Qo?rqut granite, 2820 ± 50 m.y. for the Nu?k gneiss, 2600–2900 m.y. for Malene-type supracrustal rocks, and >3800 m.y. for Isua supracrustal rocks. The zircon data are in accord with the stratigraphic sequence except for the Malene supracrustal zircons, which appear to have been variably affected by later metamorphism that did not reset the Nu?k or Amîtsoq zircons in the same area.     

Indosinian anatexis of Paleoproterozoic granites in the east Cathaysia Block,South China

Granulite facies metamorphism and crustal anatexis exist in the East Cathaysia Block, the exact timing of granulite facies partial melting and its link with orogenesis have not been well constrained. In this study, we carried out petrography, whole rock geochemistry, and zircon U–Pb dating, trace elements and Hf isotopes analyses on Dazhe gneissic granite and banded migmatite from the Badu Group in southwest Zhejiang province in the East Cathaysia Block. The melts were produced through the dehydration of biotite, such as biotite + quartz + plagioclase = orthopyroxene + K-feldspar + melt and biotite + quartz + plagioclase + sillimanite = garnet + K-feldspar + melt. Zircons from these rocks show clear core-rim structure and yield rim and core concordant ages at 233 Ma and 1.83 Ga, respectively. The zircon rims suggesting the melts and the cores are suggesting the protolith of Dazhe gneissic granite and banded migmatite were crystallized from an evolving magma. The zircon cores and rims have negative ε_Hf(t) = −2.2 ~ −6.3 and ε_Hf(t) = −22.8 ~ −32.4, and they give suggestion of the presence of Neoarchean components. Although the major-element compositions of the gneissic granite and banded migmatite are slightly different, the trace-element spider diagram and REE pattern show they are similar, and then we find that the protoliths are A-type granodiorite/diorite. Combined with the published data, we suggested that the Dazhe gneissic granite and banded migmatite were formed through granulite facies partial melting at 233 Ma, which was promoted by crustal shortening and thickening of the collision orogeny between East Cathaysia Block and an unknown terrane with a NNE trend structure line. The protoliths (granite or granodiorite) of Dazhe gneissic granite and banded migmatite crystallized at 1.83 Ga by reworking of the Neoarchean components of East Cathaysia Block. The Paleoproterozoic (1912–1819 Ma) collisional orogeny and the later intraplate rifting stage are corresponding to the aggregation and breakup of the Columbia supercontinent.     

Pan-African and early Paleozoic tectonothermal events in the Nyainrong microcontinent: Constraints from geochronology and geochemistry

To better understand the Pan-African-early Paleozoic tectonothermal events of the Nyainrong microcontinent and the constraints on its tectonic evolution, here we report the results of zircon LA-ICP-MS U-Pb dating and geochemical features of Amdo gneiss in the Nyainrong microcontinent. The outcrops of Amdo gneiss is about 30 km south of Amdo County in northern Tibet. The field occurrence, mineral composition, textural characteristics, and whole-rock geochemical features of the four gneiss samples indicate the protolith of the gneisses is intermediate-acid intrusive rock. Gneiss zircon trace element tracing and genetic analysis shows that zircon has typical characteristics of magmatic zircon. The ²⁰⁶Pb/²³⁸U concordant age of zircon is 505–517 Ma, corresponding to the Middle-Late Cambrian, which is the formation age of the protolith. The samples have characteristics of high silicon, alkali-rich, alkalic rate AR =1.73–3.7, the differentiation index DI = 70.78–90.28; rock aluminum saturation index ranges from 1.02 to 1.05, FeO / MgO ranges from 2.63 to 4.50, 10000 × Ga/Al ranges from 2.12 to 2.41, and P₂O₅ and Al₂O₃ content decreased with SiO₂ increasing. Th and Y contents have a good positive correlation with Rb content; the genetic type of protolith of the gneiss is the differentiation of subalkaline over aluminum I-type granite. Combined with regional data, the tectonic setting of the Amdo gneiss protolith is closely related to the collision orogenic process. The preliminary view is that the Middle-Late Cambrian magmatic events developed on the microcontinent could be the result of Andean-type orogeny along the Gondwana super-continental margin after the end of the Pan-African orogeny.     

Geology of the Grove Mountains in East Antarctica——New evidence for the final suture of Gondwana Land

As the core block of the East Gondwana Land, the East Antarctic Shield was traditionally thought, before 1992, as an amalgamation of a number of Archaean-Paleoproterozoic nuclei, be-ing welded by Grenville aged mobile belts during 1400—900 Ma, while the …     

A study on the Dushiling tungsten-copper deposit in the Miao’ershan-Yuechengling area,Northern Guangxi,China: Implications for variations in the mineralization of multi-aged composite granite plutons

The polymetallic Dushiling W-Cu deposit is a large, altered, skarn-type deposit, located in the northeastern part of the Miao'ershan-Yuechengling pluton, China. Two types of granite have been identified in the deposit: a medium-grained porphyritic biotite granite, and a medium- to fine-grained biotite granite. Both are spatially and temporally related to ore bodies, suggesting they may be the source of mineralization in the deposit. A medium- to fine-grained porphyritic biotite granite is exposed at the surface in the region of mineralization. U-Pb dating of zircons yielded magmatic ages of 423 Ma for the medium-grained porphyritic biotite granite and 421 Ma for the medium- to fine-grained porphyritic biotite granite, while a younger age(217 Ma) obtained for surface samples indicates later diagenesis. Thus, magmatism occurred during the Caledonian and Indosinian, respectively. The petrological and geochemical characteristics of the two Caledonian granites show that both are calc-alkaline and peraluminous.They are moderately enriched in Cs, Rb, U, and REE, and strongly depleted in Sr,Ba,P,and Ti; they show similar REE behavior,including negative Eu anomalies. These geochemical similarities suggest that the two granites were derived from the same source,although they were emplaced during different stages of the evolution of the magma. Furthermore, the granites are associated with mineralization, suggesting they were the source of mineralization in the Dushiling W-Cu deposit. Sm-Nd ages of scheelite from the Dushiling W-Cu deposit indicate that metallogenesis occurred at 417±35 Ma, while the two types of titanite, intergrown with scheelite, yield U-Pb ages of 423–425 Ma(in altered granite sample) and 218 Ma(in skarn sample). These ages place the main mineralization event in the late Caledonian, and later magmatic-hydrothermal activity occurred in the Indosinian. The ages obtained for the Dushiling W-Cu deposit in the western Nanling Range, northern Yuechengling, together with the occurrence and ages of the Niutangjie W deposit in southern Yuechengling, provide insight into the process of ore concentration during the Caledonian and Indosinian.     

The petrogenesis and implications of deformed late Caledonian–early Hercynian granites in the Wuyi area,South China

Precambrian basement rocks have been affected by Caledonian thermal metamorphism. Caledonian‐aged zircon grains from Precambrian basement rocks may have resulted from thermal metamorphism. However, Hercynian ages are rarely recorded. Zircon U–Pb Sensitive High Resolution Ion Microprobe (SHRIMP) dating reveals that zircon ages from the Huyan, Lingdou, and Pengkou granitic plutons can be divided into two groups: one group with ages of 398.9 ±5.3 Ma, 399 ±5 Ma, and 410.2 ±5.4 Ma; and a second group with ages of 354 ±11 Ma, 364.6 ±6.7 Ma, and 368 ±14 Ma. The group of zircon U–Pb ages dated at 410–400 Ma represent Caledonian magmatism, whereas the 368–354 Ma ages represent the age of deformation, which produced gneissosity. The three plutons share geochemical characteristics with S‐type granites and belong to the high‐K calc‐alkaline series of peraluminous rocks. They have (⁸⁷Sr/⁸⁶Sr)_i ratios of 0.710 45–0.724 68 and εNd(t) values of ?7.33 to ?10.74, with two‐stage Nd model ages (T_DM2) ranging from 1.84 Ga to 2.10 Ga. Magmatic zircon εHf(t) values range from ?3.79 to ?8.44, and have T_DMC ages of 1.65–1.93 Ga. The data suggest that these granites formed by partial melting of Paleoproterozoic to Mesoproterozoic continental crust. A collision occurred between the Wuyi and Minyue microcontinents within the Cathaysia Block and formed S‐type granite in the southwest Fujian province. The ca 360 Ma zircon U–Pb ages can represent a newly recognized period of deformation which coincided with the formation of the unified Cathaysia Block.     

The stratigraphy of the 3.5-3.2 Ga Barberton Greenstone Belt revisited: A single zircon ion microprobe study

Recent field and geochemical studies indicate a need to test the stratigraphy of the ca. 3.5 Ga Barberton Greenstone Belt as it is presently adopted [1,2]. This work uses the ion microprobe SHRIMP, to attempt such a test. Results show that: (1) Volcaniclastic sediments of the Theespruit Formation (< 3453 ± 6Ma) could be younger than the (structurally) overlying mafic and ultramafic volcanics of the Komati Formation (3482 ± 5Ma). A major structural discontinuity may therefore exist between the two formations. (2) An age of 3538 ± 6Ma established for a tectonic wedge of tonalitic gneiss within the Theespruit Formation confirms the presence of a sialic basement and deformed unconformity below that unit. The tonalitic gneiss is the oldest unit yet recorded within the greenstone belt, equal in age to the older components of the adjacent Ancient Gneiss Complex. (3) The interpreted ages of felsic volcanic rocks from both the Hooggenoeg (3445 ± 8Ma) and Theespruit Formations and the nearby Theespruit Pluton (3437 ± 6Ma) are essentially the same, and corroborate field and geochemical evidence that the felsic units were probably cogenetic and emplaced simultaneously as high-level equivalents of trondjhemite-tonalite plutons that intrude the greenstone belt at its southwestern extremity. (4) Felsic-intermediate volcanic-volcaniclastic rocks locally separating the two major groups (the Fig Tree and Moodies Groups) which overlie the Onverwacht Group record a second major peak of tonalitic magmatism in the Barberton terrain at about 3250 Ma. This is close to the age of the Kaap Valley tonalite pluton which intrudes the Barberton Greenstone Belt at ca. 3226 Ma along its northwestern margin. The present results indicate the Barberton Greenstone Belt is part of an allochthonous sequence containing major tectonic and stratigraphic breaks, with a protracted history; of which the last 200 million years, at least, evolved within a tectonically active convergent environment.     

Geology of the Grove Mountains in East Antarctica

Grove Mountains consists mainly of a series of high-grade (upper amphibolite to granulite facies) metamorphic rocks, including felsic granulite, granitic gneiss, mafic granulite lenses and charnockite, intruded by late tectonic gneissic granite and post-tectonic granodioritic veins. Geochemical analysis demonstrates that the charnockite, granitic gneiss and granite belonged to aluminous A type plutonic rocks, whereas the felsic and mafic granulite were from supracrustal materials as island-arc, oceanic island and middle oceanic ridge basalt. A few high-strained shear zones disperse in regional stable sub-horizontal foliated metamorphic rocks. Three generations of ductile deformation were identified, in which D₁ is related to the event before Pan-African age, D₂ corresponds to the regional granulite peak metamorphism, whereas D₃ reflects ductile extension in late Pan-African orogenic period. The metamorphic reactions from granitic gneiss indicate a single granulite facies event, but 3 steps from mafic granulite, with P-T condition of M1 800°C, 9.3×10⁵ Pa; M₂ 800–810°C, 6.4 × 10⁵ Pa; and M₃ 650°C have been recognized. The U-Pb age data from representative granitic gneiss indicate (529±14) Ma of peak metamorphism, (534±5) Ma of granite emplacement, and (501±7) Ma of post-tectonic granodioritic veins. All these evidences suggest that a huge Pan-African aged mobile belt exists in the East Antarctic Shield extending from Prydz Bay via Grove Mountains to the southern Prince Charles Mountains. This orogenic belt could be the final suture during the Gondwana Land assemblage.     

U–Pb zircon geochronology of the Hida gneiss and granites in the Kamioka area,Hida Belt

A new U–Pb dating and oxygen isotope analysis of zircons collected from a granitic mylonite and an undeformed granite in the Kamioka area, in the Hida Belt of southwest Japan, was conducted using a sensitive high‐resolution ion microprobe (SHRIMP) to restrict the timing of the mylonitization in the Funatsu Shear Zone, which is situated on the eastern and southeastern margins of the Hida Belt. Here, undeformed granite intrudes into the granitic mylonite deformed by mylonitization in the Funatsu Shear Zone. The granitic mylonite and the undeformed granite yielded U–Pb zircon ages of 242.6 ±1.9 Ma and 199.1 ±1.9 Ma, respectively. The granitic mylonite and the undeformed granite also yielded zircon oxygen isotope ratios (δ¹⁸O_VSMOW) of 7.74 ±0.37 ‰ and 5.74 ±0.17 ‰, which suggests that these rocks are derived from different magmas. Therefore, the timing of the mylonitization in the Funatsu Shear Zone is constrained to be at least 242.6–199.1 Ma, which is consistent with other data from the Tateyama area. The U–Pb zircon ages of the banded gneiss in the Kamioka area also reveals that the protolith is a sedimentary rock deposited at approximately 256 Ma, and regional metamorphism occurred at 245.0 ±6.6 Ma, which indicates that the mylonitization in the Funatsu Shear Zone occurred after the metamorphism in the Hida Belt. These geochronological and geochemical data give new insight into the relationship between the Hida Belt and the eastern margin of the Asian continent: the geochronological and geochemical data in this study support the possibility that the Funatsu Shear Zone is comparable with the Cheongsan Shear Zone located at the center of the Ogcheon Belt on the Korean Peninsula.     

U(Th)Pb systematics and ages of Himalayan leucogranites, South Tibet

The age and origin of five leucogranites from the High and Tethys Himalaya, and two country-rock gneisses were investigated by UPb dating of zircon fractions and single grains, and fractions of monazite. Additionally, ThU concentrations in whole rock powders and isotopic compositions of Pb in leached K-feldspars were determined. Monazites yield ages of 16.8 ± 0.6 m.y. for the Nialam migmatite-granite, 15.1 ± 0.5 m.y. for the Lhagoi Kangri granite, 14.3 ± 0.6 m.y. for a granite from Mt. Everest, and 9.8 ± 0.7 m.y. and 9.2 ± 0.9 m.y. for two varieties of the Maja granite. These data, together with monazite ages of 21.9 ± 0.2 and 24.0 ± 0.4 m.y., determined earlier on the Makalu granite [1], substantiate a period of intracontinental granite emplacements from 24 to 9 m.y. ago, i.e. from uppermost Oligocene to late Miocene times. Such a period of plutonic activity is consistent with the view that all these granites result from intracrustal melting following the collision of India with Eurasia. Furthermore, the individual ages, together with structural relationships between granites and country rocks suggest that granite formation and tectono-metamorphism occurred as alternating and strongly related processes with a periodicity of 7 to 9 m.y. Inherited lead components, present in all granite zircons point to large proportions of Precambrian material in the magma source regions, up to 2200 m.y. old.ThU systematics between monazite and country rocks indicate that U has been leached from most of the granites after crystallisation of monazite.Zircon dating of the Kangmar granite gneiss, which occurs in a window through the Tethys Himalayan sediments, shows that this pluton, transformed to a gneiss during the Alpine orogeny, crystallised in lowermost Palaeozoic times 562 ± 4 m.y. ago.     

Nature of the Precambrian metamorphic blocks in the eastern segment of Central Tianshan: Constraint from geochronology and Nd isotopic geochemistry

The Central Tianshan Tectonic Zone (CTTZ) is anarrow domain between an early Paleozoic southernTianshan passive continental margin and a late Paleo-zoic northern Tianshan arc zone, which is character-ized by the presence of numerous Precambrian meta-morphic basement blocks. Proterozoic granitoidgneisses and metamorphic sedimentary rocks,namely Xingxingxia and Kawabulag and Tianhugroups, are the most important lithological assem-blages in these metamorphic basement blocks, and alittle of …     

U-Pb and Rb-Sr dating of a polymetamorphic nappe terrain: The Caledonian Jotun nappe,southern Norway

The Caledonian Jotun nappe in the Tyin area of southern Norway has been investigated using U-Pb analysis of zircon and sphene and Rb-Sr measurements of minerals and whole rocks, with special reference to the reaction of the isotope systems to various kinds of metamorphic event. The nappe consists of Precambrian basement rocks and their cover, inversely thrust over the Baltic shield and its parautochthonous, presumably lower Paleozoic sediments during the Caledonian orogeny. While the nappe basement retained its pre-Caledonian structures, the nappe cover was penetratively deformed and metamorphosed to lower greenschist facies conditions.U-Pb analyses of zircon and sphene ofnappe basement rocks point to the crystallization of a syenitic to monzonitic magma at 1694± 20m.y., the intrusion of gabbros into the syenites and monzonites at 1252_?25⁺²⁸ m.y., and the metamorphism (upper greenschist-lower amphibolite facies) and deformation (gneissification and mylonitization) of the whole complex at 909± 16m.y. Although this latest event caused strong lead loss in all zircon populations, it had no influence on the Rb-Sr system on a whole rock scale. The Caledonian movements did not disturb the U-Pb system of zircon and sphene but strongly influenced the Rb-Sr system in certain minerals and zircon and/or its inclusions (K-feldspar and brown biotite partially, green biotite completely reset).In contrast to the nappe basement, zircons from thecover rocks show pronounced lead loss during the Caledonian metamorphism/deformation — U-Pb analysis give discordia lower intercept ages of 415± 21 m.y. and 395± 6m.y. Again, however, the Rb-Sr whole-rock system has not been reset in Caledonian time. Minerals from the same rocks which provided the zircons give Rb-Sr isochron ages of 390± 11m.y. and 386 ± 20 m.y.Comparison of U-Pb and Rb-Sr results from the nappe basement demonstrates that only the analysis of U-Pb systematics in zircon and especially sphene resolved the 900-m.y. event. Rb-Sr mineral data alone yield ambiguous results.The results from the nappe cover confirm that U-Pb analyses from penetratively deformed sediments are very useful in dating a metamorphic/tectonic event in lower greenschist facies conditions.From the measured cell dimensions of the zircon populations it is concluded that lead can be completely retained in zircon during recrystallization.     

SHRIMP dating of magmatism in the Hitachi metamorphic terrane,Abukuma Belt,Japan: Evidence for a Cambrian volcanic arc

Ion microprobe dating of zircon from meta‐igneous samples of the Hitachi metamorphic terrane of eastern Japan yields Cambrian magmatic ages. Tuffaceous schist from the Nishidohira Formation contains ca 510 Ma zircon, overlapping in age with hornblende gneiss from the Tamadare Formation (ca 507 Ma), and meta‐andesite (ca 507 Ma) and metaporphyry (ca 505 Ma) from the Akazawa Formation. The latter is unconformably overlain by the Carboniferous Daioin Formation, in which a granite boulder from metaconglomerate yields a magmatic age of ca 500 Ma. This date overlaps a previous estimate for granite that intrudes the Akazawa Formation. Intrusive, volcanic, and volcaniclastic lithologies are products of a Cambrian volcanic arc associated with a continental shelf, as demonstrated by the presence of arkose and conglomerate in the lowermost Nishidohira Formation. Granitic magmatism of Cambrian age is unknown elsewhere in Japan, except for a single locality in far western Japan with a similar geological context. Such magmatism is also unknown on the adjacent Asian continental margin, with the exception of the Khanka block in far northeastern China. A ‘great hiatus’ in the Paleozoic stratigraphy of the Sino–Korean block also exists in the Hitachi terrane between Cambrian volcanic arc rocks and Early Carboniferous conglomerate, and may indicate a common paleogeographic provenance.     

U–Pb systematics in heterogeneous zircon populations from the Precambrian basement of the Maryland Piedmont

The aim of the study was — besides the dating of metamorphic events — to evaluate the effects of multi-stage crystal growth, episodic and continuous Pb loss, and U gain on the discordant age patterns found for zircon populations of the polymetamorphic Baltimore Gneiss, the Precambrian basement in the Maryland Piedmont. Eight gneiss and migmatite samples were collected at two localities in the Phoenix and Towson dome, respectively. Their zircon populations were separated into twenty-three fractions of different size and optical appearance. A low-contamination method (T.E. Krogh, 1973) was used for the U-Pb analyses.Microscopy and electron-microprobe studies revealed internal heterogeneities of the zircon crystals: at least half of the grains of each population reflect more than one stage of crystal growth, with the last stage consisting of U-poor overgrowths (U: below 400 ppm, mostly below 200 ppm). Evidence for episodic U gain and overgrown material other than zircon has not been found. On a concordia diagram the “ages” obtained by upward extrapolations (1080 and 1180 m.y.) and downward extrapolations (421 and 455 m.y.) of the best-fit lines to the data points are in fair agreement with the geochronologic data found by other investigators and the probable times of metamorphic periods of Precambrian (Grenville) and early Paleozoic (Taconic) orogenies.Models of Pb loss by continuous diffusion cannot adequately explain the discordant age patterns: these are essentially the result of superposition of episodic Pb loss and zircon overgrowth during the Taconic (and Acadian?) metamorphisms. The zircon overgrowth appears to be present in all fractions, but its influence on the U-Pb systematics is generally not perceptible because it is overridden by the effect of episodic Pb loss. For the fractions showing the most discordant ages, the contribution of Pb loss to the discordancy was found to be at least 85 %.From the microscopic picture and the isotopic data, it appears that the bulk of the zircon substance crystallized during one or several high-grade metamorphisms accompanied by migmatization and granitization of the rocks in the course of the Grenville orogeny. Under consideration of zircon ages of Baltimore Gneiss rocks of Pennsylvania, the results point to a complex Grenville metamorphic history in the Maryland and Pennsylvania Piedmont, that lasted from at least 1200 m.y. until about 980 m.y. The granulite-facies metamorphism in the West Chester Prong, Pennsylvania, may be 50–200 m.y. younger than the metamorphic events in the gneiss domes of the Baltimore area. Although it seems that real differences exist with respect to the Precambrian ages of major zircon-forming events between the Phoenix and the Towson dome, the apparent difference of about 100 m.y. should be interpreted with caution, because it is impossible, so far, to evaluate quantitatively the influence of possibly much older inherited zircon components.     

Zircon chemistry and new laser ablation U–Pb ages for uraniferous granitoids in SW Cameroon

The Ekomedion two-mica granite,southwestern Cameroon,has potential for uranium and molybdenum mineralization.Here,we present LA-ICP-MS U-Pb ages,Lu-Hf isotope characteristics,trace element concentrations and Ti-geothermometry of zircon from this granite hosting U-Mo mineralization in pegmatitic pods.The majority of zircon are CL-dark though some CL-bright cores were also identified.U-Pb zircon age data range from 121±3 to743±11 Ma with only 5 of 34 ages being near concordant.The concordant mean age of 603±12 Ma is similar to ages of granitic intrusions along the Central African Shear Zone in Cameroon.Apparent ages with mean of261±6 Ma reveal open system behavior with respect to Pb and/or U.Zircon e Hfi values range from-20.3 to-0.3.This implies that U-Mo was remobilized during partial melting of the surrounding gneiss.Zircon Th/U>0.1 as well as an increasing Hf with decreasing Th/U indicates that fractional crystallization was the main factor that controlled U-Mo mineralization in pegmatitic pods.Y and Y/Ho ratios cluster from 29 to 33 close to the chondritic ratio of 28 and indicate fractionation of Y and Ho with low F contents during the earliest stages of crystallization.Late stage accumulation of F-rich magmatic-hydrothermal fluids impacted U-Mo mineralization as a ligand.Zircon contains a prominent negative Eu anomaly pointing to a fractionating system rich in plagioclase.Calculated Ti-in-zircon temperatures span 672℃to1232℃with the temperatures at the high end reflecting interference from mineral inclusions in the zircon grains while the lower temperature values are linked to crystallization.     

The Pan-African continental margin in northeastern Africa: evidence from a geochronological study of granulites at Sabaloka, Sudan

Ion microprobe zircon ages, a Nd model age and RbSr whole-rock dates are reported from the high-grade gneiss terrain at Sabaloka on the River Nile north of Khartoum, formally considered to be part of the Archaean/early Proterozoic Nile craton. The granulites, which are of both sedimentary and igneous derivation, occur as remnants in migmatites. Detrital zircon ages range from ≈ 1000 to ≈ 2650 Ma and prove the existence of Archaean to late Proterozoic continental crust in the sedimentary source region. The Nd model age for one sedimentary granulite is between 1.26 (T_CHUR) and 1.70 (T_DM) Ga and provides a mean crustal residence age for the sedimentary precursor. Igneous zircons in enderbitic gneiss crystallized at 719 ± 81 Ma ago, an age that also corresponds to severe Pb loss in the detrital zircons and which probably reflects the granulite event at Sabaloka. The RbSr data indicate isotopic homogenization at about 700 Ma ago in the granulites and severe post-granulite disturbance at ≈ 570 Ma in the migmatites. We associate this disturbance with hydration, retrograde metamorphism and anatexis that produced undeformed granites ≈ 540 Ma ago. The ≈ 700 Ma granulite event at Sabaloka suggests that this part of the Sudan belongs to the Pan-African Mozambique belt while the ancient Nile craton lay farther west. The gneisses studied here may represent the infrastructure of the ancient African continental margin onto which the juvenile arc assemblage of the Arabian-Nubian shield was accreted during intense horizontal shortening and crustal interstacking of a major collision event.     

Multi-method radiometric dating of volcano-sedimentary layers from northern Italy: Age and duration of the Priabonian stage

A comparison between conventional KAr (biotite) ages and fission track (zircon and apatite) and UPb (zircon) ages obtained from stratigraphically well-constrained Priabonian (Late Eocene) volcano-sedimentary deposits of northern Italy is presented. Two sections at Priabona (one level) and Possagno (two levels) were dated. The application of fission track dating appears fruitful for obtaining reasonably precise (±4 to 5% 2σ errors) ages useful for time-scale calibration. The concordancy of apatite and zircon fission track ages, and the reproducibility of results provide the time of volcanic eruption and deposition. The UPb analysis of the zircons has not been unsuccessful, but discordancy does not permit accurate dating. Significant dates obtained from Possagno are: KAr method, 35.0 ± 0.5 Ma (duplicate analysis on K-rich biotite from the same level); fission track dating method, 35.8 ± 1.4 Ma (weighted mean age on 2 apatite and 3 zircon separates from the same level); UPb method, 36.7 ± 1.0 Ma (maximum age of discordant zircons from the same level). The comparison between the present results and recent multi-method and multi-laboratory results obtained from time equivalent Priabonian (Late Eocene) biotite-rich layers from the Apennines shows perfect agreement and supports the location of a Priabonian stage between about 37.5 Ma and about 33.7 (±0.5) Ma; the alternative ages preferred by the Decade of North American Geology convention should be abandoned and a large portion of this scale revised accordingly.     

UPb zircon and rutile chronology of Archean greenstone formation and gold mineralization in the Val d'Or region, Quebec

UPb geochronology provides an absolute time framework for the evolution of the Sigma gold deposit and surrounding rocks at Val d'Or, southern Abitibi subprovince. The Bourlamaque batholith, the largest pluton in the area, gives a 2699.8 ± 1.0 Ma UPb zircon age. This pluton cuts the Val d'Or Formation which hosts the mineralization. A UPb zircon age of 2704.9 ± 1.1 Ma on a felsic volcanic rock, the Colombière “rhyolite”, 13 km east of the mine dates that formation. The gold-bearing quartz vein system at Sigma is hosted by andesites and two generations of porphyry intrusions, all metamorphosed to the greenschist facies. The oldest porphyry (“porphyritic diorite”) shows the same deformation as the volcanic rocks, and has a 2703.7 ± 2.5 Ma UPb zircon age. The porphyritic diorite and volcanic rocks are cut by feldspar-porphyry dykes which post-date regional folding and have a 2694.0 ± 2.2 Ma UPb zircon age.Regional greenschist metamorphism has been dated directly, with a UPb date of 2684 ± 7 Ma on rutile in the Colombière “rhyolite”. The mineralization and hydrothermal alteration in the mine are superimposed on the metamorphic minerals. Hydrothermal rutile, from an alteration halo around the veins in andesite, has a 2599 ± 9 Ma UPb age. Textural evidence clearly indicates that the wall-rock alteration and vein filling are contemporaneous, and hence the vein system and gold mineralization appear to have developed at least 80 m.y. after the formation and metamorphism of host greenstones.     

Cretaceous volcanic-intrusive magmatism in western Guangdong and its geological significance

The Nanling Mountains lying in the southern part of South China are an economically important gran-ite-related multi-metallogenic province. The Nanling Mountains granites can be described as: temporally spanning from Caledonian to Yanshanian and spatially distributed as three EW trending zones: the north one in Zhuguangshan-Qingzhangshan, the middle one in Dadongshan-Guidong, and the south one in Fogang-Xinfengjiang with two neighboring zones’ midline having an interval of ca. latitude …