铬尖晶石和石榴石的相变:大陆科学钻探CCSD-PP3孔超镁铁岩超高压变质作用的证据

PP3超镁铁岩主要岩石类型有纯橄岩和石榴石橄榄岩,两者为渐变,主要矿物为橄榄石、铬尖晶石、石榴石、单斜辉石和斜方辉石.铬尖晶石的Cr#[Cr/(Cr+Mg) ×100]从51~89变化,TiO₂和MnO₂值分别低于0.26%和0.46%.铬尖晶石矿物表现为4期次演化的特点,反映了从岩浆期、榴辉岩相、角闪岩相和绿片岩相演化特征.随着超镁铁岩的演化,铬尖晶石表现为Cr#不断增大,而Mg#[Mg×100/(Mg+Fe2+) ]不断减少、氧逸度不断增加的过程.PP3铬尖晶石反映了地幔来源,为大陆岩石圈超镁铁岩特征,后期随折返而演化.从石榴石与铬尖晶石相互转变过程看出,PP3超镁铁岩经历了深度加大的过程,超镁铁岩曾经到达100km以上的岩石圈地幔深处.在绿片岩相-绿片角闪岩相变质过程中,铬尖晶石中Cr、Mg和Al减少,Fe相对增加,产生富Cr尖晶石变质作用样式.晚期剪切变形等次生变化影响了铬尖晶石矿物成分.      

Sulfide Petrology of Spinel and Garnet Pyroxenite Layers from Mantle-derived Spinel Lherzolite Massifs of Arieg`, Northeastern Pyrenees, France

Pyroxenite layers in the orogenic spinel lherzolite massifsof Ari?ge are porphyroclastic textured and range in compositionfrom spinel websterite to garnet clinopyroxenite. Each pyroxenitetype forms individual layers or occurs as part of compositelayers in which the Opx/Cpx and Sp/Gt ratios decrease from marginsto core. They are interpreted as crystalline segregations separatedby flow crystallization from continental tholeiites en routeto the surface. The primary magmatic phases consist of Al-richpyroxenes, together with a minor amount of spinel, which startedto crystallize at 1400?C and 20–22 kb pressure; the pyroxeneshave locally survived plastic strains and subsolidus rccrystallizationsand now occur in the form of clinopyroxene and orthopyroxenemegacrysts displaying unmixing features. Although the differentiated silicate liquid was fully expelledduring the flow crystallization process, the layered pyroxeniteshave concentrated the highly incompatible elements S and Cuand locally display significant chalcophile platinum-group elementenrichment (Pd, Pt). Cu and S behave coherently over the wholerange of pyroxenite composition; their highest concentrationsare found in the thinnest websterite layers or at the marginof composite layers. Microscopic investigation of 214 polishedthin sections shows these elements to be present as accessoryCu-Fe-Ni sulfides interstitial among the silicate phase or formingdiscrete bodies included in the relic pyroxene megacrysts. Allthese features indicate the presence of a sulfide liquid, immisciblewith the silicate magma, during the crystallization of the layeredpyroxenites. Sulfide liquid immiscibility probably occurredin response to thermal contrast between the pyroxenites andthe cooler surrounding peridotites. It is proposed that the megacryst-hosted sulfide inclusionswere trapped as linear arrays arranged on host megacryst growthplanes. Due to the slow cooling and complex unmixing historyof the megacrysts, these arrays have been transformed into coarse,isolated sulfide inclusions by subsolidus migration and spheroidizationprocesses. They started to crystallize at T = 1200?C as monosulfidesolid solution (MSS), probably coexisting with a minor amountof Ni- and Cu-rich sulfide liquid down to r=900?C. The reconstructionof the bulk chemistry of each individual inclusion reveals significantbetween-inclusion variations of Cu/Ni+ Fe and Ni/Fe ratios,which would result from strain-induced immobilization of theseliquids. On cooling, the high-temperature MSS has decomposedbelow 230?C into Ni-rich pyrrhotite, nickeliferous pentlandite,chalcopyrite and minor pyrite. The post-magmatic history ofthe interstitial sulfide grains was not unlike that of the inclusions,except at near-surface temperatures where the primary sulfidesresulting from unmixing of MSS have been partly altered intosecondary sulfides by serpentinizing aqueous fluids. In spite of these post-magmatic alterations, the inclusionsand the interstitial sulfide phases are remarkably homogeneousas regards their bulk Ni/Cu ratio, which is close to 3. Thisvalue is characteristic of sulfide separated from primary ratherthan partially differentiated tholeiitic melts. It is thus concludedthat the continental tholeiite parent to the layered pyroxeniteswas saturated with sulfides when it left its mantle source regioaIn this aspect, it would not be different from MORBs which containsimilar sulfide compositions. In both cases, sulfide fractionationcannot be ignored in models for chalcophile trace element fractionationduring initial evolution of these magmas.     

胶东—苏北石榴石二辉橄榄岩形成条件及年代

在胶东—苏北地区,由石榴石二辉橄榄岩、尖晶石二辉橄榄岩、石榴石辉石岩、榴辉岩、斜辉辉橄岩和纯橄岩组成的杂岩成群和成带分布,延长590km。该岩带越过郯庐断裂带延伸至大别山,全长约1200km。岩带内石榴石二辉橄榄岩与尖晶石橄榄岩伴生,组成较大的岩块,并且与榴辉岩伴生,曾被作者确定为一种有层序的岩套。石榴石二辉橄榄岩的Sm-Nd同位素年龄为925±53Ma,矿物地质温度计和压力计表明其形成于115—160km深部,温度为800—1371℃。该石榴石二辉橄榄岩平衡温度和压力符合大陆地温线,而不同于中国东部沿海地区玄武岩中包体石榴石二辉橄榄岩,后者的平衡温度压力符合于大洋地温线。     

Mantle-Melt Interaction Recorded in Spinel Lherzolite Xenoliths from the Alligator Lake Volcanic Complex, Yukon, Canada

Magmas which have equilibrated with the Earth's upper mantleare generally assumed to be compositionally buffered by spinellherzolite as represented by Cr-diopside series xenoliths foundin alkaline lavas. The fact that the mineral equilibria preservedin such xenoliths typically reflect re-equilibration at sub-solidusmantle conditions, however, has discouraged attempts to usethe compositional variation observed in spinel lherzolite xenolithsto constrain the compositions of melts extracted from the uppermantle. A suite of mantle-derived xenoliths from the AlligatorLake volcanic center in the southern Yukon, Canada, exhibitsa bimodal xenolith population consisting of lherzolites, themost fertile of which approach pyrolite in composition, andrelatively depleted harzburgites. If a source-residue relationshipis assumed between the two, then the extracted melt was a picriticmagma (17 wt. per cent MgO, 23 Mg cation units) with low Febut relatively high Si contents, similar to picritic lavas associatedwith subduction margins. The compositional variation within the lherzolite xenoliths,however, is not towards the majority of the harzburgite xenoliths,but towards relatively rare, Fe-rich harzburgites. Reactionsobserved between the xenoliths and their alkaline host lavasmay provide an analogue for the upper mantle process which producedthis trend. The observed reactions result in the loss of anAl and Si-rich melt associated with the preferential destructionof pyroxene and spinel and a concomitant rise in the Fe contentof residual olivine. The result of such an interaction in theupper mantle would be the development of a Fe and oli vine-richresidue similar to the observed Fe-rich harzburgites. In turn,the magma responsible would be forced to evolve towards moreSi-rich, but Fe-poor compositions than would otherwise be possibleby closed system, crystal fractionation. A comparison with other mantle xenolith suites indicates thatthe compositional spectra of many of those associated with continentalalkaline basalts can be interpreted in terms of the extractionof picritic magmas similar to that calculated for AlligatorLake. Xenolith suites from oceanic islands such as Hawaii, incontrast, contain fertile lherzolites which are considerablymore Fe-rich than pyrolite. The associated refractory xenoliths,however, are similar to those at Alligator Lake and their derivationfrom such fertile lherzolites would require the extraction ofa picritic melt which was both Fe and Si-rich, similar to theobserved tholeiitic picritcs of the shield-building stage ofHawaiian volcanism. Alternately, the Fe-rich lherzolites mayrepresent samples of upper mantle which have reacted extensivelywith the relatively Fe-rich Hawaii magmas. Xenolith suites fromkimberlites, on the otheT hand, are dominated by refractoryharzburgites which are richer in Si but poorer in Fe than theAlligator Lake harzburgites. They suggest that the lower continentallithosphere is both more orthopyroxene-rich and more depletedthan the upper mantle sampled by alkaline basalts. In general,the derivation of depleted harzburgite xenoliths by the partialmelting of a pyrolite mantle source seems to require the extractionof picritic magmas. If the majority of terrestrial basalticmagmas are not derived from picritic parental magmas, they requirethe existence of mantle source regions more Fe-rich than standardpyrolite models.     

Calculation of Garnet Fractionation in Metamorphic Rocks, with Application to a Flat-Top, Y-rich Garnet Population from the Ruhla Crystalline Complex, Central Germany

A mathematical approach is presented for the calculation ofthe major and trace element fractionation that is caused bygrowth of zoned garnet in metamorphic rocks. This approach isbased on textural and compositional parameters directly obtainedfrom natural examples. It takes into account the mode and compositionof all unzoned minerals, as well as the mode, crystal size distributionand zonation patterns of garnet grains of different sizes withina certain rock volume. These parameters can be used to fit functionsfrom which the amount of garnet fractionation at each step ofa garnet growth history can be calculated. The approach is testedfor two compositionally distinct domains within a single garnet–biotitegneiss sample from the Ruhla Crystalline Complex. This samplecontains unusual flat-top garnet grains with Y₂O₃-rich cores.It is shown that MnO, FeO and Y₂O₃ are extremely fractionatedduring garnet growth, but in different ways, and that MnO fractionationdoes not obey a Rayleigh function. To demonstrate the influenceof garnet fractionation on P–T path estimates, quantitativephase diagrams in the model system Na₂O–K₂O–CaO–MnO–FeO–MgO–Al₂O₃–TiO₂–SiO₂–H₂Oare constructed by means of the computer software THERMOCALC.The good agreement between calculated and observed mineral assemblagesand garnet compositions for all fractionation steps indicatesthat the new approach can be used to infer detailed P–Tpaths, even for rocks that contain complexly zoned garnet grains.The results indicate that garnet growth in the metapelite underinvestigation occurred along a linear P–T path from 470°Cand 2·7 kbar to 580°C and 8·5 kbar. The resultsalso show that garnet cores with high Y₂O₃ contents of about1 wt % nucleated over a temperature interval of c. 90°C,indicating that Y in garnet is relatively insensitive to temperaturechanges. KEY WORDS: garnet; fractionation; pseudosection; yttrium; THERMOCALC     

Petrogenesis of Garnet Lherzolite and Megacrystalline Nodules from the Thumb, Navajo Volcanic Field

Garnet Iherzolite and megacrystalline nodules from The Thumbcomprise the deepest mantle sample recovered from the diatremesand intrusions of the Four Corners area. Discrepancies betweenvarious geothermometers applied to these nodules are believedto reflect zoning of Fe in garnets as well as problems in calibrationof the geothermometers. Because the pyroxenes are not zoned,the pyroxene solvus method probably provides more reliable temperatureestimates for this nodule suite than methods based on partitioningof Fe and Mg with garnet. The preferred T-P range of the nodules,950–1230 °C and 32–40 kb, is thought to reflecta localized perturbation of the ambient geotherm by a diapiricor igneous intrusion. Garnet Iherzolites with coarse texture show a trend from fertileto refractory compositions consistent with variable depletionby partial melting. These nodules are interpreted as previouslydepleted mantle rocks, most of which were relatively littleaffected by the thermal perturbation. Garnet Iherzolites withsheared texture are enriched in Fe and Ti relative to the coarseIherzolites and are suggested to have formed by deformationand metasomatism of the coarse lherzolites during intrusionof magma related to the thermal perturbation. The texturallydiverse ‘megacrystalline’ nodules are interpretedas precipitates from this liquid. They are similar to discretenodules from kimberlite pipes, but have unique characteristicsof their own. The above relationships are thought to recordthe process of deep-seated intrusion and partial crystallizationof evolved liquids, possibly related to the host lamprophyre,shortly before the time of eruption.     

Thermal Emplacement Model for the Alpine Lherzolite Massif at Balmuccia, Italy

The spinel lherzolite massif at Balmuccia, northwest Italy,forms an elongate north-south trending lens (4.5 x 0.5 x 1.1km) within the pre-Alpine granulite basement complex of theIvrea zone. The western contact is a mylonite fault zone formedduring late emplacement cataclastic flow near the Insubric line;to the east the lherzolite massif is separated from the granulitesby a magmatic sheath of layered pyroxenites, pyroxene pegmatitesand meta-gabbros. Pyroxene reaction zones on gabbro dikes indunite pods which lie east of the main lherzolite massif showthat emplacement occurred at pressures >9 kb, based on peridotiteequilibria studies. Phase chemistry calculations on pyroxenitesand granulites show ambient P–T conditions to have been850 °C (Cpx–Opx equilibria) and 10–13 kb (Opx–Gt;Plg–Gt–Sill–Qtz) during emplacement of thelherzolite massif. Temperature calculations on 12 peridotitesfrom throughout the massif suggest an earlier high-T stage (1200°C; Ol–Px–Sp) followed by partial re-equilibrationat lower T (850–950 °C; Cpx–Opx). The areaswithin the lherzolite massif with the highest calculated Ol–Px–Sptemperatures have the lowest Cpx–Opx temperatures, suggestingthat the apparent Cpx–Opx temperatures are due to re-equilibrationduring emplacement. The spinel lherzolite probably originatedat 12 and 20 kb, based on the mineral assemblage Ol + Opx +Cpx + Sp + Hnbd. The inferred P–T ranges put both themassif and the granulites on a geotherm that is high for continentalcrust and implies a high surface heat flow at the time of emplacement(2.2 µcal/cm² sec). The Balmuccia area later became thelocus of early Mesozoic rifting between the North and SouthAlpine plates. These relationships at Balmuccia are similarto the Great Basin of the western United States, where mantlexenoliths in young basalts that show P–T conditions of1100–1300 °C at 17–20 kb, occur in an area ofhigh heat flow (2.0 µCal/cm² sec average) and extension.This suggests an association between up-welling of mantle peridotitesbelow continents and ensialic tensional tectonics.     

Discovery of Early Paleozoic Garnet Amphibolite in theWenquan Complex,Northern Margin of the Yili Block,NW China

Objective High-pressure(HP)and ultrahigh-pressure(UHP)minerals tend to be preserved in mafic and ultramafic metamorphic rocks(e.g.eclogites and garnet amphiboli...     

Stratiform platinum-group element mineralization in the layered Northern Ultramafic Center of the Lac des Iles Intrusive Complex,Ontario, Canada

The Northern Ultramafic Centre (NUC) of the Lac des Iles Complex, Northwest Ontario hosts several platinum group element (PGE) occurrences, including the Sutcliffe Zone, which consists of four subparallel, stratiform PGE-enriched intervals exposed within the cyclically layered eastern flank of the NUC. Field relationships, mineral paragenesis and lithogeochemistry allowed for the identification of 14 cyclic cumulate sequences of two distinct types – Cyclic unit type A (CUA) and Cyclic unit type B (CUB). CUA-type and CUB-type units are interpreted to have formed from a Si-enriched and Si-poor parent magmas, respectively. PGE-enriched intervals occur in four of the CUA-type cyclic units (CUA-5, -6, -8 and -11). PGE enriched intervals are commonly associated with websterite, olivine websterite and gabbronorite containing primary disseminated sulfide (0.2–2 vol%) which are dominated by pyrrhotite, chalcopyrite, and pentlandite with minor cubanite, and troilite. In hydrothermally altered rocks enriched in PGE, primary sulfides are locally partially replaced by secondary chalcopyrite, sphalerite, heazlewoodite, and chalcocite. Palladium occurs either in solid solution with primary pentlandite or is associated with platinum group minerals (PGM) such as Pd-plumbide, Pd-telluride, and Pt-bismuthotelluride. PGMs commonly occur within primary sulfides, at contacts between primary sulfide–silicate minerals, or in association with secondary serpentine and actinolite. Gold and silver typically occur as electrum that exhibits similar textural characteristics and mineralogical associations as the PGMs.Two different chemostratigraphic patterns of PGE, Cu and S enrichment can be recognized among the mineralized CUA cycles: The first (top-loaded) occurs near the top of CUA cycles (CUA-6, -8 and -11) in websterite and/or gabbronorite, just below the levels at which CUB magmas were emplaced. The second (middle-loaded), occurs midway through the lower cycle (CUA-5) in the olivine websterite, which is overlain by CUA-6. Within the four mineralized intervals, PGE tenors average 643 ppm Pd + Pt (in 100% sulfide), Pd/Pt and Pd/Ir ratios range from 0.9 to 3.5 and 35 to 537, respectively, and S/Se ratios range between 500 and 6000. The highest PGE tenors (4377 ppm Pd + Pt) are found in the lowermost interval in serpentinized olivine websterite and have an average Pd/Pt ratio of 3.5 and a S/Se ratio of approximately 2000.It is proposed that orthomagmatic processes of fractional crystallization and dynamic magma recharge were the dominant mineralization processes triggering sulfide-saturation and PGE concentration at the Sutcliffe Zone. Textural relationships between PGM, sulfide minerals, and primary and secondary hydrous silicates suggest that late magmatic to postcumulus hydrothermal fluid infiltration occurred locally during and after sulfide mineralization of the PGE-enriched intervals. However, these fluids had a minimal effect on the distribution of PGE in the Sutcliffe Zone. The Sutcliffe Zone shares many similarities with classic stratiform PGE deposits in terms of Pd/Pt ratio, high PGE tenors, low abundance of sulfide, and PGM assemblages. However, it is distinguished from most stratiform PGE deposits by its tectonic environment and lithostratigraphic position and by the intimate spatial association of the two parental magmas that are interpreted to have been responsible for the observed chemostratigraphy and PGE enrichment.     

On the Origin of Spinel Lherzolite Inclusions in Basaltic Rocks from Tasmania and Elsewhere

In Tasmania, peridotite inclusions occur in abundance in Cainozoicvolcanic rocks ranging in type from olivine tholeite, alkaliolivine basalt, limburgite and basanite to hawaiite, benmoreite,mugearite, and nephelinite. The inclusions are commonly of spinellherzolite, and are considered to be accidentally derived fromthe upper mantle. Some of the inclusions display textural and compositional evidenceof sub-solidus reactions that involved the production of spineland pyroxenes from more aluminous pyroxenes. These reactionsare likely to have proceeded as a consequence of falling temperatureat high pressure. Inclusion textures appear to be related totheir crystallization temperatures. The compositional variations in the coexisting minerals of theTasmanian inclusions are interrelated, and fall into two groups,one perhaps arising from variations in bulk composition, andthe other from sub-solidus equilibration over a considerablePT range. They do not result directly from processes of crystal-liquidequilibria.     

The Range of Spinel Compositions in Terrestrial Mafic and Ultramafic Rocks

Compositional fields for spinels from a wide variety of mafic–ultramaficigneous rock types and tectonic environments have been determinedfrom a global database of over 26 000 analyses. These fieldsare defined using contoured data density plots based on thespinel prism, and plots of T iO₂ vs ferric iron, for mantlexenoliths, ophiolitic rocks, continental layered intrusions,alkalic and lamprophyric rocks, tholeiitic basalts, Alaskanultramafic complexes and komatiites. Several trends appear regularlyin the various environments: a trend of widely variable Cr/(Cr+ Al) at low Fe²⁺/(Mg + Fe²⁺) (the Cr–Al trend); increasingFe³⁺, Fe²⁺/(Mg + Fe²⁺) and T iO₂ at constant Cr/(Cr + Al) (Fe–Ti trend); a trend found primarily in kimberlites, similar toFe–T i but at constant Fe²⁺/(Mg + Fe²⁺); and an unusualtrend of increasing Al found only in layered intrusions. TheCr–Al and Fe–T i trends are both found to varyingdegrees in tholeiitic basalts. The Cr–Al trend is prevalentin rocks that have equilibrated over a range of pressures, whereasthe Fe–T i trend is dominantly due to low-pressure fractionation.The most Cr-rich chromites found in nature occur in boninites,diamond-bearing kimberlites, some komatiites and ophioliticchromitites. Exceptionally reduced chromites are found in somekomatiites and in ophiolitic chromitites. Detrital chromitesfrom the Witwatersrand conglomerates are of komatiitic provenance. KEY WORDS: basalt; chromite; kimberlite; ophiolite; spinel     

浙江新昌石榴石二辉橄榄岩包体的流变特征及其地质意义

浙江新昌的石榴石二辉橄榄岩包体以残斑结构为主,并有向粒状变晶结构过渡的趋势。橄榄石组构以［０１０］呈点极密型式,而［１００］和［００１］呈大圆环带为特征。橄榄石的位错亚构造以反映高温位错蠕变的位错壁、亚晶粒构造和滑动位错环为主要特征。利用新的地质温压计计算的平衡温度和压力分别为１１５０℃～１２１０℃和２．１～２．４ＧＰａ。利用显微构造应力计计算流动应力为２２～３０ＭＰａ,利用橄榄岩高温流变律计算的应变速率和等效粘滞度分别为１０－１４～１０－１３ｓ－１和１０１９～１０２０Ｐａ·ｓ,上述数据均已达到软流圈的数值。结合其流变特征认为该区的石榴石二辉橄榄岩代表软流圈的物质,其来源深度为６８～７８ｋｍ。它反映在新生代时期本区存在有软流圈的底辟,它可能控制了该区新生代大地构造的特征及地质演化。     

Metamorphism and Anatexis in the Mafic Complex Contact Aureole, Ivrea Zone, Northern Italy

Emplacement of mantle-derived magma (magmatic accretion) isoften presumed or inferred to be an important cause of regionalgranulite facies metamorphism and crustal anatexis. The juxtapositionof mafic cumulates and regionally distributed granulite faciesrocks has led some to consider the Ivrea zone (northern Italy,Southern Alps) as an important exposure that demonstrates thiscausal relationship. However, regional PTt paths indicated bymetamorphic reaction textures and PT conditions inferred fromgeothermobarometry indicate that the emplacement of mafic plutonicrocks (Mafic Complex) at the Ivrea zone occurred during decompressionfrom ambient pressures at the regional thermal maximum. Fieldand petrographic observations, supported by PT estimates, indicatethat regional retrograde decompression and emplacement of theupper parts of the Mafic Complex probably accompanied extensionduring the Late Carboniferous–Early Permian. A spatiallyrestricted decompression-melting event accompanied final emplacement,depleting supracrustal rocks enclosed by an     

Geologic and Tectonic Setting of the Yozgat Batholith,Northern Central Anatolian Crystalline Complex,Turkey

The Yozgat Batholith lies along the northern edge of the Central Anatolian Crystalline Complex in Central Anatolia, Turkey. The batholith intruded the Paleozoic-Mesozoic metamorphics and Cretaceous ophiolitic mélange, and was nonconformably overlain by latest Maastrichtian-Paleocene and/or Eocene clastics, carbonates, and volcanics. The batholith itself may be subdivided into several mappable subunits bounded by Cretaceous ophiolitic mélange, Eocene cover, and/or faults.

Major- and trace-element as well as REE analyses of the subunits indicate that the granitoids of the Yozgat Batholith are principally metaluminous monzogranites, of subalkaline-calc-alkaline character, except for the peraluminous leucogranitoids of the Yozgat subunit. The granitoids were derived by thickening of the continental crust and related partial melting; the thickening was caused by emplacement of ophiolitic nappes during collisional events.     

Geochronology of the Spessart Crystalline Complex,Mid-German Crystalline Rise

Summary New Rb-Sr and K-Ar datings help to clarify the geologic history of the Spessart Crystalline Complex, Mid-German Crystalline Rise. The oldest dates, refined by new measurements, are recorded by whole-rock Rb-Sr analyses of the orthogneisses of the Rotgneiss Complex. These confirm a late Ordovician to Silurian age which is interpreted as the time of intrusion of the granitic precursors.Hornblendes, muscovites. and biotites from different lithostratigraphic units and rock types of the Spessart Crystalline Complex yielded K-Ar dates mainly in the range 324 to 318 Ma, an interval which conforms to the analytical precision. Two hornblendes and one muscovite show slightly older dates up to 328 Ma. On the other hand, there is a tail of younger hornblende dates towards 311 Ma, and two hornblendes gave dates as low as 293 and 274 Ma for no immediately obvious reason.The concordant dates around 324 Ma on the three different minerals may be interpreted as marking the time of a rapid uplift and cooling at about the boundary between Early and Late Carboniferous, presumably soon after culmination of the Variscan deformation and amphibolite facies metamorphism.

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Geochronologie des Spessart-Kristallins, mitteldeutsche Kristallinschwelle

Zusammenfassung Neue Rb-Sr- und K-Ar-Datierungen liefern einen Beitrag zum Verständnis der geologischen Geschichte des Spessart-Kristallins. Die älteste radiometrische Datierung, die bislang im Spessart-Kristallin zur Verfügung steht, leitet sich aus Rb-Sr-Gesamtgesteinsanalysen von Orthogneisen des Rotgneis-Komplexes ab. Die bereits von früheren Bearbeitern gefundenen spät-ordovizischen bis silurischen Daten wurden durch neuere Messungen bestätigt. Sie werden als Intrusionsalter des granitischen Ausgangsmaterials der Rotgneise interpretiert.Hornblenden, Muscovite und Biotite aus unterschiedlichen lithostratigraphischen Einheiten und Gesteinstypen des Spessartkristallins erbrachten K-Ar-Daten vorwiegend zwischen 324 und 318 Ma, d. h. einen Streubereich, der etwa der analytischen Genauig keit entspricht. Zwei Hornblenden und ein Muscovit ergaben etwas ältere Daten bis 328 Ma. Auf der anderen Seite beobachtet man eine Reihe von jüngereren Hornblendedaten bis 311 Ma, und zwei Hornblenden von nur 293 und 274 Ma, die sich nicht ohne weiteres erklären lassen.Die konkordanten Alterswerte um 320 Ma, die für die drei Mineralarten gewonnen wurden, können als die Zeit einer raschen Hebung und Abkühlung etwa an der Grenze Unter-/Oberkarbon interpretiert werden, die vermutlich bald nach dem Höhepunkt der variscischen Deformation und amphibolit-faziellen Metamorphose erfolgte.

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Dedicated to Borwin Grauert on the occasion of his 60th birthday.

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With 6 Figures     

Garnet growth during crustal thickening in the Cascades Crystalline Core,Washington, USA

Garnet Sm–Nd and zircon U–Pb ages, and pressure–temperature–time paths elucidate Late Cretaceous crustal thickening which occurred within magmatic arc rocks of the Insular Superterrane. Voluminous tonalitic magma of the Mount Stuart batholith intruded at <3 kbar into upper crustal sedimentary rocks between 96 and 91 Ma, with initial intrusion prior to garnet growth in the metasedimentary rocks. Arc plutonism then shifted northward as crustal thickening commenced. Initial garnet growth, locally with kyanite and staurolite replacing andalusite, at c. 91 Ma was directly associated with intrusion of granodiorite to tonalite sheets at 7 kbar, north of the Mount Stuart batholith, within the Nason Ridge Migmatitic Gneiss. Subsequent heating and garnet growth, which postdates emplacement of large plutons, occurred between 88 and 86 Ma. This late garnet growth occurred at pressures of 6–8 kbar. The history of garnet growth and intrusion indicates that initial garnet zone and higher temperature metamorphism was restricted to contact aureoles. However, later widespread garnet growth at higher pressure probably resulted from heating as the orogenic wedge approached thermal equilibrium after crustal thickening. We conclude that metasedimentary rocks outside narrow contact aureoles remained at temperatures significantly below those of garnet growth and that the growth of garnet lasted <6 Myr. Heating to temperatures that stabilized garnet after pluton emplacement is compatible with intrusion of arc plutons into an accretionary wedge (Chiwaukum Schist) which was tectonically thickened and/or overthrust causing loading and thermal relaxation.     

Evidence for Modal Metasomatism in the Orogenic Spinel Lherzolite Body from Caussou (Northeastern Pyrenees, France)

Metasomatic mineral-bearing and/or trace element-enriched ultramaficassemblages have been reported from very few Alpine-type massifs.The small ultramafic body from Caussou (Ari?ge, northeasternPyrenees) compared with other north Pyrenean ultramafic complexesshows distinctive features which are similar to those of modallymetasomatized mantle xenoliths found in alkali basalts. It ismainly composed of clinopyroxene-rich spinel lherzolites (cpx/opxratios 1), with subordinate titanian pargasite-rich peridotites,both greatly depleted in orthopyroxene. Moreover the Caussouperidotites differ from other Ari?ge peridotites in the presenceof ilmenite, the abundance of sulfide inclusions in pyroxenesand amphiboles, higher Al, Ca, Na, K, Ti, and lower Mg contents,and enrichment in incompatible trace elements (ITE). Such mineralogicaland geochemical features are interpreted as resulting from modalmetasomatism produced by influxes of silicate melt into theperidotites. At Caussou, the metasomatic assemblage comprisesTi-pargasite+Ti-bearing clinopyr oxene+ilmenite+Ti-phlogopite+sulphide+fluid,suggesting that K, Ti, Na, ITE (including S, H₂O CO₂ and possiblyFe and Ca, were introduced by the metasomatizing agent. Thismetasomatism was probably imposed on an ultramafic associationdominated by LREE-depleted peridotites similar to the northPyrenean spinel lherzolites. These features indicate that, underupper lithospheric mantle conditions, a mafic melt locally infiltratedlherzolites by a grain-boundary percolation process and reactedwith the original mineral assemblage. The infiltration of alkali-basalticliquids into spinel peridotite led to: (1) partial dissolutionof orthopyroxene and, locally, spinel; (2) crystallization ofclinopyroxene directly from introduced melts; and (3) re-crystallization/equilibrationof pre-existing clinopyroxene with these magmatic liquids. Inthe last stage of the metasomatism, segregation of more fractionatedsilicate liquids, coexisting with a (CO₂+H₂O) fluid phase, mayhave been responsible for the crystallization of titanian pargasite,possibly by means of hydro-fracturing mechanism. The pervasive modal metasomatism at Caussou was contemporaneouswith the segregation of amphibole-bearing dykes in the Lherz-Freychin?debodies (northeast Pyrenees) (101–103 Ma). They representtwo manifestations of the same magmatic event in the lithosphericmantle, probably related the Middle Cretaceous alkaline magmatisrnof the Pyrenees.     

The geology and petrology of the Adamsfield Ultramafic Complex,Tasmania

The Adamsfield Ultramafic Complex is one of a dozen Tasmanian ultramafic-mafic and ophiolite complexes emplaced during Cambrian time in the Tasman Geosyncline.The Adamsfield complex is composed of partlyserpentinized dunites, olivine orthopyroxenites and orthopyroxenites. Rocks are commonly layered and alternately rich in olivines (Fo_93–84) and orthopy roxenes (En_94–87). Spinels are a minor but widely disseminated phase. Orthopyroxenes and spinels are poor in Al₂O₃ and TiO₂. Clinopyroxenes are rare, plagioclase or garnet have not been found.Nominal equilibration temperatures calculated from coexisting mineral assemblages range from quasi-magmatic values (1200±100 °C) for little-deformed rocks down to subsolidus values (950 °C) for deformed and reacted assemblages. Olivine kink band orientations imply that deformation also took place at lower temperatures (<800 °C) but mineral compositions apparently failed to react further.Adamsfield mineral assemblages probably crystallized originally at low pressures from highly magnesian, titania-poor tholeiitic or andesitic magmas. Fine-grained igneous rocks from the Tasmanian ultramafic-mafic and ophiolite complexes include highmagnesia andesites of appropriate compositions and comprise a distinctive compositional group termed the Low-titania Ophiolite Association, poor in TiO₂ (<0.5 wt%), P₂O₅ (<0.1 wt%) and Zr, and rich in MgO, Ni, and Cr.     

Age, Geochemistry and Petrogenesis of the Ultramafic Pipes in the Ivrea Zone, NW Italy

Pipe-like ultramafic bodies, hosting Ni–Cu–PGE sulphidedeposits, intrude the Main Gabbro and the roof metasedimentsof the Ivrea Zone, NW Italy. These bodies were emplaced at 287± 3 Ma and represent the last mantle-derived melts associatedwith an underplating event that largely drove the crustal evolutionof this area during the late Carboniferous (     

北祁连托莱山超基性岩带玉石沟地区地球化学特征

通过采用1∶20万区域地球化学调查资料,选择24个元素对祁连山玉石沟超基性岩带的区域地球化学特征进行了较为深入、系统的研究,并归纳前人相关资料,以区域化探异常为主导,结合区域地质背景及成矿规律,建立区内区域地球化学模式,对区内乃至祁连山区的区域化探异常筛选和评价及其地质找矿工作起到积极的促进作用.