Ordovician Proto–basin in South China and its Tectonic Implications: Evidence from the Detrital Zircon U–Pb Ages of the Ordovician in Central Hunan,China

Caledonian orogeny is another important tectonic event in South China Block after the breakup of the Rodinia supercontinent. With a view to constrain the tectonic evolution and proto–basin in South China, this paper reports the geochemical and zircon U-Pb dating data of the Ordovician strata in central Hunan, South China. Geochemical features and paleocurrent directions suggest that the lower Ordovician deposited in a passive continental margin basin with a provenance of quartzose components and...     

U–Pb LA–ICP–MS Age of Detrital Zircons from the Lower Riphean and Upper Vendian Deposits of the Luga–Ladoga Monocline

The results of LA–ICP–MS U–Pb analyses of detrital zircons from the Precambrian deposits of Luga–Ladoga monocline are discussed. The age spectra of the zircons separated from the Riphean to Upper Vendian sandstones from the Shotkusa-1 well demonstrate dominance of the Paleo- and Mesoproterozoic grains while the Archaean zircons are subordinate. The Riphean debris sources were local swells of the Northern Ladoga basement. The sequence interval presumably corresponding to the Vasilieostrov Formation (Upper Vendian) has yielded not only Paleo- and Mesoproterozoic zircon ages, but Neoproterozoic as well, implying a Timanide provenance: these zircons (527 ± 9 and 516 ± 13 Ma) allow deposition of a significant part of the Shotkusa-1 sequence at the very beginning of the Cambrian.     

Detrital Zircon U–Pb Geochronology and Provenance of Bayan Obo Group, Northern Margin of North China Craton: New Implications for the Position of NCC in Rodinia

The paleoposition of North China Craton in Rodinia has long been in controversial. This paper mainly focuses on the U–Pb geochronological studies of detrital zircons obtained from Bayan Obo Group exposed in the Shangdu area, Inner Mongolia, aiming to provide more information for interprating this problem. Based on the acquired data, this paper comes to the following conclusions. Firstly, the depositional age of Bayan Obo Group might be from Meso– to Neoproterozoic according to the zircons U–Pb dating results. The lower succession of this group, namely Dulahala and Jianshan formations deposited between 1800 and 1650 Ma. The Halahuogete and Bilute formations deposited between 1500 and 1350 Ma. For Baiyinbaolage and Hujiertu formations, their depositional age was 1250–900 Ma. Secondly, for the provenance of Bayan Obo Group, this paper believes detrital zircons with age of 2.51–2.71 Ga and 2.00–2.48 Ga were from Guyang, Xi Ulanbulang and Zhuozi area; the Khondalite Belt provided detrital zircons with age of 1.95–1.80 Ga; zircons with age of 1.60–1.75 Ga might come from granitic rocks in Miyun Area. The magmatism after 1.60 Ga was rarely recorded in the NCC, therefore those zircons with ages younger than 1.60 Ga might come from outside of NCC. The magmatism with the same age existed in Baltic, Amazonia and Laurentia. Based on previous paleomagnetic researches, this paper proposes that NCC might receive detritus from Baltic during 1560–1350 Ma and had affinity with Laurentia and Amazonia at ～0.9 Ga in Rodinia. Baltic, Amazonia and Laurentia might be potential provenances for non–NCC detritus in Bayan Obo Group.     

Detrital zircon U–Pb geochronology of Permian strata in the Galilee Basin,Queensland, Australia

The late Carboniferous to Triassic tectonic history of eastern Australia includes important periods of regional-scale crustal extension and contraction. Evidence for these periods of tectonism is recorded by the extensive Pennsylvanian (late Carboniferous) to Triassic basin system of eastern Australia. In this study, we investigate the use of U–Pb dating of detrital zircons in reconstructing the tectonic development of one of these basins, the eastern Galilee Basin of Queensland. U–Pb detrital zircon ages were obtained from samples of stratigraphically well-constrained Cisuralian and Lopingian (early and late Permian, respectively) sandstone in the Galilee Basin. Detrital zircons in these sandstones are dominated by a population with ages in the range of 300–250 Ma, and ages from the youngest detrital zircons closely approximate depositional ages. We attribute these two fundamental findings to (1) appreciable derivation of detrital zircons in the Galilee Basin from the New England Orogen of easternmost Australia and (2) syndepositional magmatism. Furthermore, Cisuralian sandstone of the Galilee Basin contains significantly more >300 Ma detrital zircons than Lopingian sandstone. The transition in detrital zircon population, which is bracketed between 296 and 252 Ma based on previous high-precision U–Pb zircon ages from Permian ash beds in the Galilee Basin, corresponds with the Hunter–Bowen Orogeny and reflects a change in the Galilee Basin from an earlier extensional setting to a later foreland basin environment. During the Lopingian foreland basin phase, the individual depocentres of the Galilee and Bowen basins were linked to form a single and enormous foreland basin that covered >300 000 km² in central and eastern Queensland.     

Re–Os and U–Pb Geochronology of the Erlihe Pb–Zn Deposit, Qinling Orogenic Belt, Central China, and Constraints on Its Deposit Genesis

The Erlihe Pb–Zn deposit is an important mine of the Pb–Zn metallogenic zone in the South Qinling Orogen. It has been considered a sedimentary exhalative deposit in previous investigations because the ore body occurs concordantly at the transitional location of an upright fold. Re and Os isotopic analyses for paragenetic pyrites with sphalerite and galena from the ore body have been used to determine the timing of mineralization and to trace the source of metallogenic materials. The Re–Os isotopic data of four pyrite samples construct an isochron, yielding a weighted average age of 226±17 Ma (mean square weighted deviation=1.7), which is considered the main mineralization age. A dioritic porphyrite vein sample, showing weaker mineralization, was also dated using the SHRIMP zircon U–Pb isotopic method to constrain the youngest metallogenic age of the ore deposit, because it distributes along a group of tensional joints cutting not only the upright fold in the deposit field, but also the main ore bodies. The dioritic porphyrite sample yields a weighted mean 206Pb/238U age of 221±3 Ma, which is slightly younger than the Re–Os isotopic isochron age of the pyrites, considered as the upper age limit of the mineralization, namely the ending age of the mineralization. The Os isotopic compositions of sulfide minerals distribute within a range between Os isotopic compositions of the crust and the mantle, indicating that the ore deposit can be derived from magma-related fluid, and the metallogenic materials are most likely derived from the mixing source of the crust and the mantle. The Erlihe Pb–Zn deposit and associated dioritic porphyrite vein, important records of Qinling tectonic–magmatism–mineralization activities, were formed during the Triassic collisional orogeny processes.     

LA–ICP–MS Isotopic U–Pb Age of Zircon from the Eldzhurty Granites and Rhyolites at the Tyrnyauz Mo–W Deposit (North Caucasus,Russia)

Doklady Earth Sciences - The isotopic U–Pb ages are estimated for zircons (for the first time by the LA–ICP–MS method) from biotite (Eldzhurty) granites and for the first time...     

Zircon U–Pb Geochronology of Baiyingaolao Formation from the Hadayingzi Region in the southern Great Xing’an Range, Northeast China

Blueschists in the Yilan area, Heilongjiang Province, are known as important parts of the Heilongjiang Complex. However, their metamorphic evolution history is still unclear. Petrographical, and mineral chemical investigations on the blueschists from the Yilan area are carried out in this study. P‐T pseudosections are calculated in the system Na₂O‐CaO‐K₂O‐MnO‐FeO‐MgO‐Al₂O₃‐SiO₂‐H₂O‐TiO₂‐O (Fe₂O₃) (NCKMnFMASHTO) with the PERPLE_X software for three blueschist samples. Peak metamorphic conditions are estimated to be 500‐525°C, 1.14‐1.2 GPa for garnet‐barroisite schist (g‐brs‐wnc‐act‐phn‐chl‐ep‐ab‐stlp); 480°C, 1.4 GPa for chlorite‐epidote glaucophane schist (gl‐brs‐wnc‐act‐chl‐ep‐stlp) and 450‐500°C, 0.95‐1.2 GPa for phengite‐glaucophane schist (gl‐wnc‐phn‐ab‐ep‐chl‐sph), which indicate that they all underwent peak metamorphism in the limit epidote‐blueschist facies conditions. Combined with the previously reported geochemical and geochronological data, the clockwise P‐T paths of the blueschists are constructed. The formation of blueschists in the study area marks the young oceanic crust subduction, and represents the final closure of the Paleo‐Asian Ocean and the beginning of the Paleo‐Pacific tectonic system. The P‐T pseudosection recorded the P‐T increasing process before the metamorphic peak and that the maximum temperature was coincident with the maximum pressure in the process, which indicates that the epidote‐blueschist facies conditions implemented in the process of subduction, rather than exhumation. The retrograde trajectory nearly coincidently retraced the prograde trajectory, which represents the similar geothermal gradient (11‐14°C/km) in the subduction and the relatively slow exhumation process.     

In situ LA–MC–ICP–MS boron isotope and zircon U–Pb age determinations of Paleoproterozoic borate deposits in Liaoning Province,northeastern China

A large number of Paleoproterozoic borate deposits are hosted by the lower units of a volcanic-sedimentary sequence in Liaoning Province, northeastern China, and are a major source of boron in China. The ore-bearing wall rocks in the deposits are serpentinized ultrabasic rocks and carbonates, with layered leptynites, leptites, amphibolites, and migmatites adjacent to the ore. Both the borate ores and country rocks contain tourmaline, although the country rocks have much lower abundances of the mineral. Based on in situ boron isotope measurements using laser ablation–multi-collector–inductively coupled plasma–mass spectrometry (LA–MC–ICP–MS), boron isotope data show that: (1) δ¹¹B values of borate ores range from + 6.8‰ to + 13.9‰ (mean + 10.8‰); (2) tourmalines from the borate ores have δ¹¹B values from + 9.5‰ to + 12.7‰; and (3) the wall rocks within the borate ores yield slightly lower δ¹¹B values ranging from + 5.7‰ to + 7.6‰, and those outside the deposits from − 9.9‰ to − 5.9‰. Positive δ¹¹B values in borates as well as in tourmalines inside the mining area indicate that boron in these Paleoproterozoic borate deposits was derived from marine evaporites. δ³⁴S_V-CDT (where V-CDT is Vienna Canyon Diablo Troilite) values of borate ores, serpentinized marbles, and anhydrites range from + 16.1‰ to + 24.7‰, whereas δ¹³C_V-PDB (where V-PDB is Vienna Pee Dee Belemnite) values of marbles range from + 3.2‰ to + 5.9‰. These isotopic characteristics are interpreted to reflect formation in a marine evaporative environment. LA–MC–ICP–MS zircon weighted²⁰⁷Pb/²⁰⁶Pb ages of leptite and serpentinized olivine basalt from the hanging wall of the borate deposits are 2139 ± 13 Ma and 2130 ± 19 Ma, respectively. Therefore, the (~ 2.2 Ga) borate deposits may have originated from marine evaporative boron-bearing sediments, which were interbedded within bimodal volcanic rocks during the early stages of development of the Liaoji rift.     

Geochemistry and Zircon U–Pb–Hf Isotopic Systematics of the Sanchahe Quartz Monzonite Intrusion in the North Qinling Tectonic Zone,Central China： Implications for its Petrogenesis and Tectonic Setting

The Sanchahe quartz monzonite intrusion is situated in the middle segment of the North Qinling tectonic belt, Central China mainland, and consists chiefly of sanukitoid–like and granodioritic-monzogranitic rocks. The sanukitoid–like rocks are characterized by quartz monzonites, which display higher Mg#（55.0–59.0）, and enrichments in Na2 O＋K2 O（7.28–8.94 %）, Ni（21-2312 ppm）, Cr（56-4167 ppm）, Sr（553-923 ppm）, Ba（912-1355 ppm） and LREE（（La/Yb）N =9.47–15.3）, from negative to slightly positive Eu anomalies（δEu=＋0.61 to ＋1.10）, but also depletion in Nb, Ta and Ti. The granodioritic-monzogranitic rocks diaplay various Mg#of 6.00-53.0, high Na2 O＋K2 O（7.20– 8.30%）, Sr（455–1081 ppm） and（La/Yb）N（27.6–47.8）, with positive Eu anomalies（δEu=1.03–1.57） and depleted Nb, Ta and Ti. Laser ablation inductively coupled plasma mass spectrometry（LA-ICPMS） zircon U-Pb isotopic dating reveals that the sanukitoid-like rocks were emplaced at two episodes of magmatism at 457±3 Ma and 431±2 Ma, respectively. The monzogranites were emplaced at 445±7Ma. Sanukitoid–like rocks have their εHf（t） values ranging from ＋0.3 to ＋15.1 with Hf–depleted mantle model ages of 445 to 1056 Ma, and the monzogranite shows its εHf（t） values ranging from 21.6 to ＋10.8 with Hf–depleted mantle model ages of 635 to 3183 Ma. Petrological, geochemical and zircon Lu –Hf isotopic features indicate that the magmatic precursor of sanukitoid–like rocks was derived from partial melting of the depleted mantle wedge materials that were metasomatized by fluids and melts related to subduction of oceanic slab, subsequently the sanukitoid magma ascended to crust level. This emplaced mantle magma caused partial melting of crustally metamorphosed sedimentary rocks, and mixing with the crustal magma, and suffered fractional crystallization, which lead to formations of quartz monzonites. However, the magmatic precursor of the granodioritic-monzogranitic rocks were derived from partial melting of subducted oceanic slab basalts. Integrated previous investigation for the adackitic rocks in the south of the intrusion, the Sanchahe intrusion signed that the North Qinling tectonic zone was developed in an early Paleozoic transitionally tectonic background from an island arc to back–arc.     

A Practical Approach for Collecting Large‐n Detrital Zircon U‐Pb Data sets by Quadrupole LA‐ICP‐MS

A measurement procedure for the rapid acquisition of U‐Pb dates for detrital zircons by quadrupole LA‐ICP‐MS was developed. The procedure achieves a threefold increase in measurement efficiency compared with the most commonly used methods. Utilising reduced background counting times and a shortened ablation period, a throughput of ~ 130 measurements/h can be achieved. The measurement procedure was characterised and validated using data from thirty‐nine sessions acquired over a twelve‐month period. Systematic measurement error in ²⁰⁶Pb/²³⁸U dates for reference materials used for quality control with ages between 28.2 and 2672 Ma was < 1.5%. Average measurement uncertainty, including both random and systematic components, was 1–4% (2s). Interrogation of time‐resolved calculated dates and signal intensities for each measurement allows for the detection and elimination of portions of measurements exhibiting age heterogeneities, zoning, lead loss and contamination by common lead. The measurement procedure diminishes the need to acquire cathodoluminescence imagery for routine detrital zircon applications further increasing throughput and reducing cost. The utility of the measurement procedure is demonstrated by the measurement of samples previously characterised by LA‐MC‐ICP‐MS.     

LA‐ICP‐MS U‐Pb Geochronology of Detrital Zircons in Eastern Liaoning Province: An Early Paleozoic Formation Associated with the Gondwana Supercontinent Event

正Objective The Liao-Ji orogenic belt is a famous Paleoproterozoic orogenic belt in the East Block of the North China Craton(NCC),which extend in NE-SW direction.The geological mass in the Paleoproterozoic Liao-Ji belt is mainly composed of the Liaoji granites and metamorphic volcanic-sedimentary rocks of the Liaohe group(and its     

Paleozoic and Mesozoic Basement Magmatisms of Eastern Qaidam Basin,Northern Qinghai‐Tibet Plateau: LA‐ICP‐MS Zircon U‐Pb Geochronology and its Geological Significance

The eastern margin of the Qaidam Basin lies in the key tectonic location connecting the Qinling, Qilian and East Kunlun orogens. The paper presents an investigation and analysis of the geologic structures of the area and LA-ICP MS zircon U-Pb dating of Paleozoic and Mesozoic magmatisms of granitoids in the basement of the eastern Qaidam Basin on the basis of 16 granitoid samples collected from the South Qilian Mountains, the Qaidam Basin basement and the East Kunlun Mountains. According to the results in this paper, the basement of the basin, from the northern margin of the Qaidam Basin to the East Kunlun Mountains, has experienced at least three periods of intrusive activities of granitoids since the Early Paleozoic, i.e. the magmatisms occurring in the Late Cambrian (493.1±4.9 Ma), the Silurian (422.9±8.0 Ma-420.4±4.6 Ma) and the Late Permian-Middle Triassic (257.8±4.0 Ma-228.8±1.5 Ma), respectively. Among them, the Late Permian - Middle Triassic granitoids form the main components of the basement of the basin. The statistics of dated zircons in this paper shows the intrusive magmatic activities in the basement of the basin have three peak ages of 244 Ma (main), 418 Ma, and 493 Ma respectively. The dating results reveal that the Early Paleozoic magmatism of granitoids mainly occurred on the northern margin of the Qaidam Basin and the southern margin of the Qilian Mountains, with only weak indications in the East Kunlun Mountains. However, the distribution of Permo-Triassic (P-T) granitoids occupied across the whole basement of the eastern Qaidam Basin from the southern margin of the Qilian Mountains to the East Kunlun Mountains. An integrated analysis of the age distribution of P-T granitoids in the Qaidam Basin and its surrounding mountains shows that the earliest P-T magmatism (293.6-270 Ma) occurred in the northwestern part of the basin and expanded eastwards and southwards, resulting in the P-T intrusive magmatism that ran through the whole basin basement. As the Cenozoic basement thrust system developed in the eastern Qaidam Basin, the nearly N-S-trending shortening and deformation in the basement of the basin tended to intensify from west to east, which went contrary to the distribution trend of N-S-trending shortening and deformation in the Cenozoic cover of the basin, reflecting that there was a transformation of shortening and thickening of Cenozoic crust between the eastern and western parts of the Qaidam Basin, i.e., the crustal shortening of eastern Qaidam was dominated by the basement deformation (triggered at the middle and lower crust), whereas that of western Qaidam was mainly by folding and thrusting of the sedimentary cover (the upper crust).     

LA-ICP-MS Zircon U-Pb Geochronology of the Fine-grained Granite and Molybdenite?Re-Os?Dating in the Wurinitu Molybdenum Deposit, Inner Mongolia, China

The Wurinitu molybdenum deposit, located in Honggor, Sonid Left Banner of Inner Mongolia, China, is recently discovered and is considered to be associated with a concealed fine-grained granite impregnated with molybdenite.?The wall rocks are composed of Variscan porphyritic-like biotite granite and the Lower Ordovician Wubin’aobao Formation.?LA-ICP-MS zircon U-Pb dating of the fine-grained granite reveals two stages of zircons,?one were formed at 181.7±7.?4 Ma and?the other at 133.6±3.3 Ma. The latter age is believed to be the formation age of the fine-grained granite, while the former may reflect the age of inherited zircons, based on the morphological study of the zircon and regional geological setting. The Re-Os model age of molybdenite is 142.2±2.5?Ma, which is older than the diagenetic age of the fine-grained granite.?Therefore the authors believe that the metallogenic age of the Wurinitu molybdenum deposit should be?nearly 133.6±3.3 Ma or slightly later, i.e., Early Cretaceous.?Combined with regional geological background research, it is speculated that the molybdenum deposits were formed at the late Yanshanian orogenic cycle in the Hingganling-Mongolian orogenic belt, belonging to the relaxation epoch posterior to the compression and was associated with the closure of the Mongolia-Okhotsk?Sea.     

LA‐ICP‐MS Zircon U‐Pb Age of Longtou Syenite body in South Songxian County,Southern Margin of the North China Craton

正Objective Indosinian magmatic rocks mainly locate in west Qinling Orogen,which are,however,extremely rare in east Qingling Orogen(Lu Xinxiang,2000;Zhang Guowei et al.,2001;Guo Xianqing et al.,2017).The ZhifangHuangzhuang(ZH)area in south Songxian County is located in the southern margin of the North China Craton     

Ultrafast, > 50 Hz LA‐ICP‐MS Spot Analysis Applied to U–Pb Dating of Zircon and other U‐Bearing Minerals

LA‐ICP‐MS U–Pb detrital zircon studies typically analyse 50–200 grains per sample, with the consequent risk that minor but geologically important age components (e.g., the youngest detrital zircon population) are not detected, and higher abundance age components are misrepresented, rendering quantitative comparisons between samples impossible. This study undertook rapid U–Pb LA‐ICP‐MS analyses (8 s per 18–47 μm diameter spot including baseline and ablation) of zircon, apatite, rutile and titanite using an aerosol rapid introduction system (ARIS). As the ARIS resolves individual single pulses at fast sampling rates, spot analyses require a high repetition rate (> 50 Hz) so the signal does not return to baseline and mass sweep times (> 80 ms) that span several laser pulses (i.e., major undersampling of the signal). All rapid U–Pb spot analyses employed 250–300 pulses, repetition rates of 53–65 Hz (total ablation times of 4.1–5.7 s) and low fluence (1.75–2.5 J cm^?2), resulting in pit depths of ca. 15 μm. Zircon, apatite, rutile and titanite reference material data yield an accuracy and precision (2s) of < 1% for pre‐Cenozoic reference materials and < 2% for younger reference materials. We present a detrital zircon data set from a Neoproterozoic tillite where > 1000 grains were analysed in < 3 h with a precision and accuracy comparable to conventional LA‐ICP‐MS analytical protocols, demonstrating the rapid acquisition of huge detrital data sets.     

The provenance of Western Irish Namurian Basin sedimentary strata inferred using detrital zircon U–Pb LA‐ICP‐MS geochronology

The Western Irish Namurian Basin (WINB) preserves classic examples of basin floor sequences through to slope deposits and deltaic cyclothems. Despite over 50 years of research into the WINB, its sediment provenance remains highly contested. Sedimentological arguments, including palaeocurrent vectors and palaeoslope indicators have been invoked to propose a sediment source from the NW or the west (i.e. from within Laurentia). These same indicators have been subsequently reinterpreted to reflect a southern provenance. It is not clear from sedimentological arguments alone which interpretation more accurately reflects the infilling of the WINB. Regional‐scale constraints on WINB provenance may be obtained with detrital zircon U–Pb geochronology. U–Pb LA‐ICP‐MS detrital zircon analysis was undertaken on samples from three sandstone units at different stratigraphic levels within the WINB siliciclastic sedimentary fill (Ross Formation, Tullig Sandstone, Doonlicky Sandstone). The samples are dominated by 500–700 Ma zircons, which can be correlated with Cadomian–Avalonian orogenic activity within terranes to the south of the WINB (Avalonia/Ganderia, Armorica and Iberia). In contrast, Eastern Laurentia, to the north of the WINB, was devoid of orogenic activity at this time. WINB samples also yield age populations younger than 500 Ma, and older than 700 Ma. These are not diagnostic of a particular source terrane and thus could be derived from terranes north and/or south of the WINB. WINB detrital zircon age spectra can be reconciled by an Avalonian or combined Avalonian–Laurentian provenance for WINB sedimentary strata. Further research is required in order to distinguish between these two possibilities. Copyright © 2011 John Wiley & Sons, Ltd.     

Detrital Zircon U‐Pb Dating of Nanshuangyashan Formation in the Jiamusi Massif,NE China and its Tectonic Implications

A suite of the fossil-rich marine-land interbedded strata(Nanshuangyashan Formation) is distributed at the eastern margin of the Jiamusi massif in the eastern Heilongjiang Province, NE China. The authors had recently discovered a suite of arkose beneath the marine-land interbedded strata, which overlays unconformably on the Permain granite in the eastern margin of the Jiamusi massif. The LA-ICP-MS zircon U-Pb dating indicate that all detrital zircons from the analysed four arkose samples show the four population ages of 800 Ma, 538–481 Ma, 269–250 Ma and 223–215 Ma. The former three population ages are widely recorded in the Jiamusi-Khanka massif and the Songnen massif. The later group is the minimal age population in the analyzed samples, limiting the sedimentation time of the arkoses occurred after the Late Triassic. At present, the minimal age population is not recorded in the Jiamusi massif, but the granites with the ages of 228–210 Ma are widely distributed in the Songnen-Zhangguangcai Range massif and the Khanka massif. The predominantly Permian zircons are characterized by oscillatory zoning and euhedral shapes, with variable zircon ε_(Hf)(t) values(-5.5 to +11.2), indicating that they were derived from mixture sources, possibly mixed with components of the Songnen-Zhangguangcai Range massif and the Jiamusi-Khanka massif. These results, combined with regional analyses, indicate that the closing of Mudanjiang ocean and Panthalassa ocean possibly existed from Early Permian to Late Triassic.     

Community‐Derived Standards for LA‐ICP‐MS U‐(Th‐)Pb Geochronology – Uncertainty Propagation,Age Interpretation and Data Reporting

The LA‐ICP‐MS U‐(Th‐)Pb geochronology international community has defined new standards for the determination of U‐(Th‐)Pb ages. A new workflow defines the appropriate propagation of uncertainties for these data, identifying random and systematic components. Only data with uncertainties relating to random error should be used in weighted mean calculations of population ages; uncertainty components for systematic errors are propagated after this stage, preventing their erroneous reduction. Following this improved uncertainty propagation protocol, data can be compared at different uncertainty levels to better resolve age differences. New reference values for commonly used zircon, monazite and titanite reference materials are defined (based on ID‐TIMS) after removing corrections for common lead and the effects of excess ²³⁰Th. These values more accurately reflect the material sampled during the determination of calibration factors by LA‐ICP‐MS analysis. Recommendations are made to graphically represent data only with uncertainty ellipses at 2s and to submit or cite validation data with sample data when submitting data for publication. New data‐reporting standards are defined to help improve the peer‐review process. With these improvements, LA‐ICP‐MS U‐(Th‐)Pb data can be considered more robust, accurate, better documented and quantified, directly contributing to their improved scientific interpretation.     

A New Appraisal of Sri Lankan BB Zircon as a Reference Material for LA‐ICP‐MS U‐Pb Geochronology and Lu‐Hf Isotope Tracing

A potential zircon reference material (BB zircon) for laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) U‐Pb geochronology and Hf isotope geochemistry is described. A batch of twenty zircon megacrysts (0.5–1.5 cm³) from Sri Lanka was studied. Within‐grain rare earth element (REE) compositions are largely homogeneous, albeit with some variation seen between fractured and homogeneous domains. Excluding fractured cathodoluminescence bright domains, the variation in U content for all analysed crystals ranged from 227 to 368 μg g^?1 and the average Th/U ratios were between 0.20 and 0.47. The Hf isotope composition (0.56–0.84 g/100 g Hf) is homogeneous within and between the grains – mean ¹⁷⁶Hf/¹⁷⁷Hf of 0.281674 ± 0.000018 (2s). The calculated alpha dose of 0.59 × 10¹⁸ g^?1 for a number of BB grains falls within the trend of previously studied, untreated zircon samples from Sri Lanka. Aliquots of the same crystal (analysed by ID‐TIMS in four different laboratories) gave consistent U‐Pb ages with excellent measurement reproducibility (0.1–0.4% RSD). Interlaboratory assessment (by LA‐ICP‐MS) from individual crystals returned results that are within uncertainty equivalent to the TIMS ages. Finally, we report on within‐ and between‐grain homogeneity of the oxygen isotope systematic of four BB crystals (13.16‰ VSMOW).