Studying seasonal variations in carbonaceous aerosol particles in the atmosphere over central Siberia

The results of 2-year (2010–2012) measurements of the concentrations of organic carbon (OC) and elemental carbon (EC), which were taken at the Zotino Tall Tower Observatory (ZOTTO) Siberian background station (61° N, 89° E), are given. Despite the fact that this station is located far from populated areas and industrial zones, the concentrations of OC and EC in the atmosphere over boreal forests in central Siberia significantly exceed their background values. In winter and fall, high concentrations of atmospheric carbonaceous aerosol particles are caused by the long-range transport (~1000 km) of air masses that accumulate pollutants from large cities located in both southern and southwestern regions of Siberia. In spring and summer, the pollution level is also high due to regional forest fires and agricultural burning in the steppe zone of western Siberia in the Russian–Kazakh border region. Background concentrations of carbonaceous aerosol particles were observed within relatively short time intervals whose total duration was no more than 20% of the entire observation period. In summer, variations in the background concentrations of OC closely correlated with air temperature, which implies that the biogenic sources of organic-particle formation are dominating.     

Total content of carbon monoxide in the atmosphere over Russian regions according to satellite data

Carbon monoxide (CO) total columns over European Russia (ER) and western Siberia (WS) have been analyzed using MOPITT (V5, TIR/NIR, L3) IR-radiometer data obtained in 2000–2014. High CO contents are revealed over large urban and industrial agglomerations and over regions of oil-and-gas production. A stable local CO maximum is observed over the Moscow agglomeration. Statistical characteristics of CO total columns observed in the atmosphere over ER and WS in 2000–2014 are presented. An analysis of long-term changes in CO content reveals nonlinear changes in the CO total column over northern Eurasia in 2000–2014. Results of a comparative analysis of annual variations in atmospheric CO contents over ER and WS are given. Based on Fourier analysis, empirical models of annual variations in total CO contents over ER and WS are proposed. Relations between regional CO contents and fire characteristics and between spatial CO distributions and features of large-scale atmospheric dynamics under conditions of weather and climate anomalies in the summers of 2010 in ER and 2012 in WS are analyzed. Data on total CO contents measured with a MOPITT satellite radiometer and a ground-based spectrometer operating at the Zvenigorod Scientific Station of the Obukhov Institute of Atmospheric Physics are compared.     

Identifying anthropogenic sources of nitrogen oxide emissions from calculations of Lagrangian trajectories and the observational data from a tall tower in Siberia during the spring-summer period of 2007

The task of identifying climatically significant regional anthropogenic emissions and estimating their contribution to the variability of nitrogen oxides observed at a monitoring station is considered on the basis of NO and NO₂ surface concentrations measured at the Zotino background observation station (60°26′ N, 89°24′ E, Krasnoyarsk Territory). The approach used is based on an estimation of the conditional probability of polluted air arriving from individual regions by using the results of calculating backward Lagrangian trajectories in the lower troposphere. It is established that the contribution of air masses supplied from industrial regions in the south of the Krasnoyarsk Territory to episodes of high concentrations of nitrogen oxides (>0.7 ppb) is larger than the contribution from cities and towns located in the south of Western Siberia. The results indicate that anthropogenic sources of pollution substantially affect the balance of minor gases in the lower troposphere on a regional scale and that this factor must be taken into account when observational data from the Zotino background station are analyzed and interpreted.     

Changes in climatic characteristics of Northern Hemisphere extratropical land in the 21st century: Assessments with the IAP RAS climate model

Assessments of future changes in the climate of Northern Hemisphere extratropical land regions have been made with the IAP RAS climate model (CM) of intermediate complexity (which includes a detailed scheme of thermo- and hydrophysical soil processes) under prescribed greenhouse and sulfate anthropogenic forcing from observational data for the 19th and 20th centuries and from the SRES B1, A1B, and A2 scenarios for the 21st century. The annual mean warming of the extratropical land surface has been found to reach 2–5 K (3–10 K) by the middle (end) of the 21st century relative to 1961–1990, depending on the anthropogenic forcing scenario, with larger values in North America than in Europe. Winter warming is greater than summer warming. This is expressed in a decrease of 1–4 K (or more) in the amplitude of the annual harmonic of soil-surface temperature in the middle and high latitudes of Eurasia and North America. The total area extent of perennially frozen ground S _p in the IAP RAS CM changes only slightly until the late 20th century, reaching about 21 million km², and then decreases to 11–12 million km² in 2036–2065 and 4–8 million km² in 2071–2100. In the late 21st century, near-surface permafrost is expected to remain only in Tibet and in central and eastern Siberia. In these regions, depths of seasonal thaw exceed 1 m (2 m) under the SRES B1 (A1B or A2) scenario. The total land area with seasonal thaw or cooling is expected to decrease from the current value of 54–55 million km² to 38–42 in the late 21st century. The area of Northern Hemisphere snow cover in February is also reduced from the current value of 45–49 million km² to 31–37 million km². For the basins of major rivers in the extratropical latitudes of the Northern Hemisphere, runoff is expected to increase in central and eastern Siberia. In European Russia and in southern Europe, runoff is projected to decrease. In western Siberia (the Ob watershed), runoff would increase under the SRES A1B and A2 scenarios until the 2050s–2070s, then it would decrease to values close to present-day ones; under the anthropogenic forcing scenario SRES B1, the increase in runoff will continue up to the late 21st century. Total runoff from Eurasian rivers into the Arctic Ocean in the IAP RAS CM in the 21st century will increase by 8–9% depending on the scenario. Runoff from the North American rivers into the Arctic Ocean has not changed much throughout numerical experiments with the IAP RAS CM.     

Analysis of historical trend of pollution sources of lead in Tokyo Bay based on lead isotope ratios in sediment core

The historical trend of pollution sources of Pb in Tokyo Bay, Japan was investigated on the basis of Pb isotope ratios in a sediment core. The isotope ratios of anthropogenic Pb decreased gradually with increasing Pb concentration in the 1900s–1970s, suggesting a combination of Pb sources with various isotope ratios. In contrast, the isotope ratios of anthropogenic Pb in the 1980s–2000s showed no significant trend, and corresponded to the Pb isotope ratios in the three principal rivers flowing into the bay. It is probable that river bottom sediments contaminated with Pb are principal sources of anthropogenic Pb in Tokyo Bay.     

Time variations of the total CO content in the atmosphere near St. Petersburg

We analyzed measurements of the total carbon monoxide (CO) content in the atmosphere in the region of St. Petersburg (59.88°N, 29.83° E; 20 m above sea level) in the period from 1995 to 2009. The average annual behavior for the entire measurement period has a maximum in February–March and a minimum in July with an amplitude of ～20%. In the absence of strong forest fires in the European part of the Russian Federation and Siberia, the annual minimum of the total CO content is usually recorded in August–September. In winter 1995–2009 (November–January), there was a decrease in the total CO content with a gradual shift in the maximum of the annual behavior from January (1995–1999) to February (2000–2004) and March (2005–2009). The total CO content in January–February 2009 was ～20% lower than the multiyear average level. Estimates of the linear trend for the maximum, minimum, and average values for the period of 1996–2009 showed an absence of statistically significant long-term changes in the total CO content. A spectral analysis of data showed that the spectral components with periods of 12, 14, 17, 24, and 46 months are extracted with 80% confidence. It is shown that the irregular component of the time series of the total CO content (calculated for the period from May to September) agrees well with data on the areas of the forest fires and on the volume of the burnt forest and that 1999, 2001, 2005, 2007, and 2009 can be considered “background” years with the least numbers of forest fires.     

Parameters of thunderstorm activity and lightning discharges in Central Yakutia from 2009 to 2012

The results of integrated instrumental observations of thunderstorm activity around Yakutsk at a radius of 400 and 30 km are presented. The seasonal course of thunderstorm activity was found to contain characteristic peaks in the first 10 days of June and the last 10 days of July or early August. The fraction of cloud-to-ground discharges in Central Yakutia is 40–60%, which is consistent with observations in Western Siberia (40–50%). The number of positive discharges to the ground was 8–15% of all cases of discharges to the ground, which is consistent with observations in Germany (17%) and slightly exceeds the observed number in the Caucasus (2.2–8.2%) and United States (4.5%). The thunderstorm activity in Yakutsk is three times higher than in the area around Yakutsk with a radius of 400 km, which can be explained by the fact that the city is a heat island.     

Geochemical investigation of selected elements in coastal and riverine sediments from Ube, Kasado, and Suo-Oshima Bays in the western Seto Inland Sea, Southwest Japan

This paper presents the geochemical study of sediments along Ube, Suo-Oshima, and Kasado Bays in the Seto Inland Sea of Japan. We examined the distribution and abundances of 13 elements (As, Pb, Zn, Cu, Ni, Cr, Sr, Ca, Fe, Ti, P, Mn, and total S) in 40 coastal and river sediment samples, to evaluate the factors controlling their abundances, possible sources, and environmental implications. Average concentrations of As, Pb, Zn, Cu, Ni, and Cr at Ube were 12, 26, 86, 16, 43, and 92?mg/kg, 6, 25, 31, 8, 9, and 29?mg/kg at Kasado, and 5, 20, 28, 3, 5, and 18?mg/kg at Suo-Oshima, respectively. Average As, Pb, Zn, and Cr concentrations at Ube were comparable or enriched relative to those of the upper continental crust and Japan upper crust, whereas most major elements, Cu, and Ni were depleted at Kasado and Suo-Oshima. Enrichment factor values show low to moderate enrichment of Zn, Ni, and Cr, whereas As and Pb show significant contamination at some sites, suggesting contributions from anthropogenic sources. Anthropogenic contributions of most metals mainly originate from natural processes; however, As and Pb ranges of 73–79 and 66–81?%, respectively, confirm their anthropogenic contribution. Factor analysis and correlation matrices suggest that elevated metal concentrations at Ube, especially in samples located in the river basin, may be controlled by Fe–Mn oxy-hydroxides. Deposition of metals at Kasado and Suo-Oshima might be controlled by non-ferrous metal (i.e., aluminosilicates), sediment grain size, or source rock composition (granite and gneiss).     

Background component of carbon oxide concentrations in the surface air (Obninsk monitoring station)

Data on the volume concentration of carbon oxide (CO) in surface-air samples taken in European Russia, which were obtained using the Fourier transform spectroscopy method, are given. Over 16 years of measurements, this concentration decreased by 28%. These measured concentrations of CO are separated into its regional natural background and anthropogenic components. Seasonal variations in the concentration of CO are separated from its background concentration. Their extreme intra-annual values and mean amplitudes are determined. An empirical model of time variations in the concentration of CO is proposed. The atmospheric concentration of the CO anthropogenic component decreased by ~61 ppb over the measurement period.     

Holocene Faunal Trends in West Siberia and Their Causes

Based on an analysis of the transformation of vertebrate and invertebrate fauna of West Siberia in the Holocene, the classification and periodization of the main faunal trends are presented. Against the background of changing environmental conditions, the key regularities of the faunal dynamics, and the ways some species penetrate into the territory of the region and others disappear from the beginning of the Holocene to the present time have been indicated. Three global and four fluctuating trends are identified. The anthropogenic trend is ascertained separately. A conclusion is made about the prevailing causes of these changes, associated primarily with periodic climatic processes of different levels, determined by planetary geological and cosmic cycles. It is emphasized that, in the historical period, anthropogenic factors play a significant role in the regional faunal dynamics.     

Methane cycle in the INM RAS climate model

The atmosphere-ocean general circulation model with the carbon cycle is coupled to a model of methane evolution, in which methane sources in the soil of wetlands and methane evolution in the atmosphere are calculated. A numerical experiment on the simulation of climate and methane-cycle changes in 1860–2100 has been conducted with the model forced by methane emissions prescribed from scenario A1B. The distribution of the sources of methane from soil agrees with the available estimates and amounts to about 240 Mt/year in the 20th century. The methane flux from soil increases to 340 Mt/year by the end of the 21st century. The model adequately reproduces an increase in the atmospheric methane concentration from 800 ppb in 1860 to about 1800 ppb in 2000, but does not produce the observed stabilization of methane concentration in the early 21st century. By 2060, the methane concentration in the model attains 2700 ppb. The increase in atmospheric methane concentration is due mainly to anthropogenic emissions. A similar numerical experiment with fixed sources of methane from soil at the 1860–1900 level suggests that the maximum methane concentration in the model in this case could amount to 2400 ppb. A temperature increase at the end of the 21st century relative to the 19th century is 3.5° for a simulated change in the methane flux from soil and 0.25° less for a fixed methane flux.     

Variations in the total column amounts of carbon monoxide and methane in the Antarctic atmosphere

The results of measuring the total contents of carbon monoxide and methane via the method of solar-absorption spectroscopy are presented. The measurements were performed at the Molodezhnaya Station in 1977–1978, at the Mirny Observatory from 1982 to 1992, and at the Novolazarevskaya Station from 2003 to 2006. The character of seasonal variations in the contents of these gases in the Antarctic atmosphere is described and compared to the intra-annual variation of their surface concentrations measured at the Syowa Station (Japan). Synchronous intra-annual variations in the contents of carbon monoxide in the atmospheric column and in its surface concentrations are observed, while the spring maximum content of methane is observed three months after the maximum of its surface concentration. Synchronous seasonal variations in the total content of methane and ozone are observed, which makes it possible to suggest that the Antarctic circumpolar vortex has a significant influence on the characteristics of the vertical distribution of methane during Antarctic spring. Quantitative estimates of the parameters of multiyear variations in the contents of CO and CH₄ are given. The content of methane was increasing (although with different rates) during the entire observation period 1977–2006. The content of CO was observed to increase until 1992 and to decrease during 2003–2006.     

渤海莱州湾表层沉积物中金属元素分布及环境质量

利用X-射线荧光光谱仪、等离子质谱仪或原子荧光光度计测定了莱州湾表层沉积物中金属元素的含量,探讨了它们的分布特征、来源及污染程度,结果表明,沉积物中铜、锌、铅、镉、砷、镍、铬、钴、钒、钪、铁、锰的含量由近岸向湾内递减,莱州湾北部海域的含量大于南部的。银含量高的沉积物主要分布在莱州湾中部偏西南的环流中心区。沉积物中砷和镍含量超过ERL值,潜在生态风险较高。富集系数和主成分分析显示,沉积物中铁、铜、锌、镉、砷、铬、镍、钴、锰、钒和钪为无富集,砷为轻度富集,铅和银为中度富集。铁、铜、锌、镉、铬、镍、钴、锰、钒、砷和钪主要来源于自然源,铅既有岩石和土壤风化产物硅酸盐矿物等自然源的贡献,又受到了人为活动的影响,银主要受人为活动的影响。聚类分析表明,可把莱州湾沉积物分为4类,其中黄河口西北缘沉积物中砷和镍污染生态风险最高,其次是莱州湾中部和北部。     

Heavy Metals in the Atmosphere over the Northern Coast of Eurasia: Interannual Variations in Winter and Summer

Interannual variations in the level of anthropogenic contamination of the surface air in the northern areas of Russia are studied, which are related to a change in the direction of air mass transport. The transport of air and heavy metals to four sites located on territories of nature reserves on the coast of the Arctic Ocean (from the Kola Peninsula to a delta of the Lena River) in winter (January) and summer (July) is analyzed for 2000–2013. Indices of atmospheric circulation and data on the emission of pollutants into the atmosphere in cities and regions of Russia are involved in the analysis. Concentrations of seven heavy metals in the surface air are evaluated in the Arctic regions under study and their interannual, spatial, and seasonal variations are discussed. A strong interannual variability of atmospheric circulation differently influences the variations in the atmosphere contamination with different anthropogenic heavy metals in various areas of the north of Russia. The concentration ratios of heavy metals under study are different for each site in different years. The interannual and seasonal variations in the contamination level have maximum values for heavy metals arriving from most distant sources. Thus, the results of measuring the content of anthropogenic contaminants in the air of reference areas during one season or even one year should not serve a basis for longterm conclusions and forecasts. It would be also unjustified to make general conclusions on the contamination level of the environment from observation results for only one contaminant and/or only at a single site.     

Dispersal of natural and anthropogenic lead through submarine canyons at the Portuguese margin

Submarine canyons represent natural conduits for preferential transport of particulate material, including anthropogenic contaminants, from coastal zones directly to the deep sea. To assess related dispersal of natural and anthropogenic lead (Pb), we analyzed Pb concentrations and stable isotope ratios in surface sediments and sediment trap particulate material from the Portuguese margin Nazaré and Setúbal/Lisbon canyons. Geochemical data are integrated with previously obtained data on near-bottom hydrodynamics and processes and pathways of sediment transport. The two canyon systems are located in close geographic proximity to each other, but represent contrasting settings in terms of sediment input and down-canyon sediment transport processes.Concentration–isotope diagrams and three-isotope plots (²⁰⁶Pb/²⁰⁷Pb vs. ²⁰⁸Pb/²⁰⁶Pb) suggest binary mixing between natural and anthropogenic end members. The inferred isotopic signature of pollutant Pb (²⁰⁶Pb/²⁰⁷Pb=1.143 [1.134–1.149, 95% confidence interval]) is most consistent with industrial Pb; ongoing influence from gasoline Pb additives is at most of minor importance. Two proposed natural end members most likely bracket the isotopic signature of natural Pb. Accordingly, binary mixing calculations indicate that on average 20–45% vs. 35–55% of total Pb is derived from anthropogenic sources in the Nazaré and Setúbal–Lisbon canyon systems, respectively. Enhanced anthropogenic influence in the latter area is consistent with its proximity to heavily populated and industrialized areas and with sediment input from the Tagus and Sado rivers, potential major carriers of pollutant particles. In both canyon systems, the anthropogenic component generally decreases with increasing water depth.Isotopic signatures of sediment trap particulate material are generally consistent with surface sediment data at similar water depth, but show large variability in the upper Nazaré canyon and major deviations from surface sediments in the lower canyon. In the lower canyon, Pb isotopic ratios of sediment trap particulate material mostly reflect low pelagic fluxes from the overlying water column, whereas surface sediment signatures are dominated by episodic down-canyon mass transport events. Such gravity flows appear to incorporate older (pre-industrial) material masking the isotopic signature of pollutant Pb. Large variability in the upper canyon reflects continuous sediment resuspension by bottom currents. Stronger average bottom currents are associated with higher ²⁰⁶Pb/²⁰⁷Pb ratios of sediment trap particulate material and hence decreased influence of pollutant Pb. This may reflect preferential resuspension of natural Pb at the canyon floor and/or additional remobilization of older, less-polluted sediment in adjacent areas such as the canyon walls.     

Estimating the efficiency of mitigating and preventing global warming with scenarios of controlled aerosol emissions into the stratosphere

Ensemble numerical experiments with the climate model of intermediate complexity developed at the A.M. Obukhov Institute of Atmospheric Physics of the Russian Academy of Sciences (IAP RAS CM) are conducted to estimate the efficiency of controlled climate forcing (geoengineering) due to stratospheric sulfate aerosol (SSA) emissions in order to compensate for global warming under the SRES A1B anthropogenic emission scenario. Full (or even excessive) compensation for the expected anthropogenic warming in the model is possible with sufficiently intense geoengineering. For ensemble members with values of the governing parameters corresponding to those obtained for the Mt. Pinatubo eruption, global warming is reduced by no more than 0.46 K in the second half of the 21st century, with a residual rise in the global surface temperature T _g comparative to 1961–1990 of 1.0–1.2 K by 2050 and 1.9–2.2 K by 2100. The largest reduction in global warming (with the other parameters of the numerical experiment being equal) is found not for a meridional distribution of SSA concentration peaked at low latitudes (despite the largest (in magnitude) global compensation instantaneous radiative forcing), but for a uniform horizontal aerosol distribution and for a distribution with the SSA concentration maximum in the middle and subpolar latitudes of the Northern Hemisphere. The efficiency of geoengineering in terms of T _g in the second half of the 21st century between the most efficient and the least efficient meridional distributions of stratospheric aerosols differs by as much as one-third, depending on the values of other governing parameters. For meridional distributions of SSA concentration, which produce the largest deceleration of global warming, such a deceleration is regionally most pronounced over high- and subpolarlatitude land areas and in the Arctic. In particular, this is expressed in the smallest reduction in the sea-ice extent and permafrost area under climate warming in the model. The compensation forcing also decelerates a general increase in global annual precipitation P _g during warming. The relative deceleration in precipitation increase is most pronounced in land regions outside the tropics, where a significant deficit in precipitation is currently observed. After the theoretical completion of geoengineering in the first or second decade, its temperature effect vanishes with an abrupt acceleration of global and regional surface warming. For individual members of the ensemble experiment, the global temperature change in this period is five times as large as that in the experiment without geoengineering and ten times as large regionally (in northeastern Siberia).     

Relationships between interannual variations in stratospheric warmings, tropospheric circulation, and sea surface temperature in the Northern Hemisphere

The leading modes of interannual and long-term variations in the stratospheric and tropospheric circulation and total ozone (TOMS data) and their relations to Northern Hemisphere sea surface temperature (SST) anomalies are investigated using the monthly mean NCEP/NCAR reanalysis data for the winter months of 1958–2003. Strong correlations are indicated between the interannual total ozone variations over Labrador and the North Atlantic and changes in the stratospheric polar vortex. The onset of major stratospheric warmings is connected not only with the strengthening of westerlies at the 500-hPa level in the midlatitude Atlantic, but also with the weakening of tropospheric winds over the north of eastern Siberia and strengthening over the Far East. In years with major stratospheric warmings, abnormally cold winters are observed in Eurasia, especially in eastern Siberia and northeastern China. The calculated simultaneous (with no time lags) correlations of the stratospheric circulation changes with El Niño/La Niña events give evidence of low correlations between the tropical Pacific SST anomalies and the stratospheric dynamics in the Arctic. However, there are high correlations of the extratropical Pacific and Atlantic SST anomalies with interannual tropospheric and stratospheric circulation variations, the stratospheric dynamics being more strongly connected with Pacific SST than with Atlantic SST anomalies. The interannual changes in tropospheric circulation are coupled to SST anomalies in both the Pacific and the Atlantic. Mechanisms of long-term changes in the interactive ocean-atmosphere-ozone layer system are discussed.     

Oceanic iron fertilization: one of strategies for sequestration atmospheric CO2

Carbon cycle is connected with the most important environmental issue of Global Change.As one of the major carbon reservoirs, oceans play an important part in the carbon cycle. In recent years, iron seems to give us a good news that oceanic iron fertilization could stimulate biological productivity as CO2 sink of human-produced CO2. Oceanic iron fertilization experiments have verified that adding iron into high nutrient low chlorophyll (HNLC) seawaters can increase phytoplankton production and export organic carbon, and hence increase carbon sink of anthropogenic CO2, to reduce global warming. In sixty days, the export organic carbon could reach 10 000 times for adding iron by model prediction and in situ experiment, i.e. the atmospheric CO2 uptake and inorganic carbon drawdown in upper seawaters also have the same magnitude. Therefore, oceanic iron fertilization is one of the strategies for increasing carbon sink of anthropogenic CO2. The paper is focused on the iron fertilization, especially in situ o     

Variations of the total content of carbon monoxide over Moscow megapolis

The results of the carbon monoxide total content measurements over Moscow and Zvenigorod for 2005–2008 are compared with the same data sets for Moscow 1986–2005 and Beijing, 1992–2007. Two identical medium resolution diffraction spectrometers (resolution 0.2 cm^?1) with solar tracking system were used. The CO total content measured simultaneously over the city and over Zvenigorod Scientific Station (ZSS) of the Obukhov Institute of Atmospheric Physics, Russian Academy of Sciences (60 km west from Moscow). This method allows to isolate an urban part of CO content. The acoustic locator SODAR LATAN-3 measurements permitted us to study the influence of the carbon monoxide ventilation conditions upon level of pollution. Correlation coefficients between the urban part of CO content and average wind speed for cold and warm seasons were obtained. The data sets analysis showed a preeminent effect of the wind within boundary layer (up to 300 m) over the CO ventilation. The urban part of the CO content hasn’t increased in spite of more than quintuple increase of the motor-vehicles number in Moscow. An increase of the rural CO total column for the 1970–1985 has transformed into its virtually stable amount in between of 1986 to 2000, changed then to a decrease for 2001–2008. We noted the 2008 as “the year of the CO total column minimum” over the past decade. The effect of urban CO sources influence on the CO total column in rural area is small, i.e. on a level of 3% of the total number of measurements. The number of extremal daily values for Moscow is estimated as 5%, and 20% for Beijing.     

Spatial and temporal changes in reef fish assemblages on disturbed coral reefs,north Pacific coast of Costa Rica

Benthic structure of coral reefs determines the availability of refuges and food sources. Therefore, structural changes caused by natural and anthropogenic disturbances can have negative impacts on reef‐associated communities. During the 1990s, coral reefs from Bahía Culebra were considered among the most diverse ecosystems along the Pacific coast of Costa Rica; however, recently they have undergone severe deterioration as consequence of chronic stressors such as El Niño‐Southern Oscillation and harmful algal blooms. Reef fish populations in this area have also been intensely exploited. This study compared reef fish assemblages during two periods (1995–1996 and 2014–2016), to determine whether they have experienced changes as a result of natural and anthropogenic disturbances. For both periods, benthic composition and reef fish abundance were recorded using underwater visual censuses. Live coral cover (LCC) decreased from 43.09 ± 18.65% in 1995–1996 to 1.25 ± 2.42% in 2014–2016 (U = 36, p < 0.05). Macroalgal cover (%) in 2014–2016 was sixfold higher than mean values reported for the Eastern Tropical Pacific region. Mean (±SD) fish species richness in 1995–1996 (36.67 ± 14.20) was higher than in 2014–2016 (23.00 ± 9.14; U = 20, p < 0.05). Over 40% of reef fish orders observed in 1995–1996 were not detected in the 2014–2016 surveys, including large‐bodied predators. Reduction in abundance of fish predators such as sharks, grunts, and snappers is likely attributed to changes in habitat structure. Herbivorous such as parrotfishes and pufferfishes increased their abundance at sites with low LCC, probably in response to predators decline and increased algal cover. These findings revealed significant degradation and drastic loss of structural complexity in coral reefs from Bahía Culebra, which now are dominated by macroalgae. The large reduction in structural complexity of coral reefs has resulted in the loss of diversity and key ecological roles (e.g., predation and herbivory), thus potentially reducing the resilience of the entire ecosystem.