淡色花岗岩的岩石学和地球化学特征及其成因

淡色花岗岩(leucogranite)是一类高铝高硅碱的酸性侵入岩,主要地球化学特征是:SiO2≥72%,Al2O3≥14%,Na2O+K2O~8.5%,富Rb,亏损Th、Ba、Sr,稀土总量较一般花岗岩低(∑REE=(40~120)×10-6),且表现为中等分异的轻稀土弱富集型,一般具有Eu负异常;Sr-Nd-Pb-O同位素指示其岩浆明显的陆壳来源。淡色花岗岩主要发育于陆壳(俯冲)碰撞加厚带,由逆冲折返的俯冲板片变沉积岩部分经过脱水熔融产生。淡色花岗岩可划分为三种不同的岩石类型:(1)二云母型淡色花岗岩,由变泥质岩(或变硬砂岩)在中地壳水平经黑云母(和/或白云母)脱水熔融产生;(2)电气石型淡色花岗岩,由变泥质岩在较低温度下经白云母脱水熔融产生;(3)石榴子石型淡色花岗岩,由长英质下地壳经黑云母脱水熔融产生。源区残留独居石、磷灰石等富REE矿物是淡色花岗岩亏损REE、Th等元素的原因。源岩为变泥质岩及源区残留钾长石是淡色花岗岩亏损Sr、Ba的主要原因。     

藏南错那地区空布岗中新世淡色花岗岩的成因机制

空布岗位于特提斯喜马拉雅带东部、桑日-错那裂谷系内,发育二云母花岗岩、白云母淡色花岗岩、含石榴子石淡色花岗岩以及混合岩淡色体。LA-MC-ICP-MS锆石U-Pb定年显示,空布岗白云母淡色花岗岩结晶年龄为16.9±0.1Ma。全岩元素地球化学分析表明：二云母花岗岩为过铝质富钠花岗岩,具有较高的Sr（107×10^-6~141×10^-6）和Ba（230×10^-6~311×10^-6）,较低的Rb（108×10^-6~221×10^-6）和Rb/Sr比值（0.78~2.07）,Ba与Rb/Sr比值没有相关性,指示其为白云母含水部分熔融作用的产物。白云母淡色花岗岩为过铝质富钾花岗岩,具有较高的Rb（>270×10^-6）和Rb/Sr比值（5.2~9.5）,但是其Sr（< 58.5×10^-6）和Ba（< 167×10^-6）含量较低,Ba与Rb/Sr比值呈现明显的负相关关系,表明它是白云母脱水部分熔融作用的产物。含石榴子石淡色花岗岩具有显著的Ba、Th、Nb、Ta、P、Sr、Eu、Zr、Ti负异常和高度相关的微量元素变化,是花岗质熔体经历斜长石、锆石、云母等分离结晶作用的产物。混合岩淡色体具有较高的SiO₂、K₂O、TiO₂、Ba、Nb、Ta、Zr、Hf,部分样品富集轻稀土或重稀土,存在显著的正Eu异常,指示了淡色体形成过程中捕获了源岩中的锆石、独居石、石榴子石等副矿物以及转熔钾长石。结合错那地区已发表的数据,可以推断：空布岗中新世花岗岩与桑日-错那裂谷的开启相关,低喜马拉雅岩系变质脱水产生流体,流体通过裂谷系上升促使了高喜马拉雅结晶岩系发生白云母含水熔融,桑日-错那裂谷的开启时间应该不晚于22.5Ma。

     

藏南吉隆淡色花岗岩地球化学特征、成因机制及其构造动力学意义

藏南吉隆淡色花岗岩体位于大喜马拉雅淡色花岗岩带的中部,是吉隆地区藏南拆离系剪切带上部的重要组成部分。地球化学特征显示,岩石具有高SiO_2(72.09%~74.02%)、Al_2O_3(14.54%~15.59%)和K_2O(4.55%~5.59%)含量,高K_2O/Na_2O比值(1.12~1.55)和A/CNK值(1.14~1.18),属于高钾钙碱性过铝质S型花岗岩。富集大离子亲石元素Rb和放射性生热元素U,亏损Ba、Nb、Sr和Zr等元素,具有明显的轻重稀土元素分异和Eu负异常(δEu=0.37~0.54)。具有高的Rb/Sr比值(3.6~9.7)和低的CaO/Na_2O比值(0.15~0.25),指示源区为泥质岩区;(~(87)Sr/~(86)Sr)_i和ε_(Nd)(t)变化范围分别为0.7548~0.7586和-14.0~-13.1,与大喜马拉雅变泥质岩的Sr-Nd同位素组成一致;锆石边部的ε_(Hf)(t)介于-16.0~-8.5之间,位于大喜马拉雅变泥质岩中碎屑锆石的演化线上,表明淡色花岗岩的源岩为大喜马拉雅变泥质岩。岩石(~(87)Sr/~(86)Sr)_i较高而Sr浓度较低,且随着Ba浓度的增加,Rb/Sr比值降低,表明淡色花岗岩是无水条件下白云母脱水熔融形成的,部分熔融可能与藏南拆离系(STDS)伸展拆离导致的深部构造减压密切相关。吉隆淡色花岗岩的形成反映了地壳伸展减薄背景下,构造减压导致的深部地壳物质中含水矿物(白云母)脱水熔融并沿向北伸展的STDS侵位的构造动力学过程。     

藏南东部麻玛沟地区早古生代与中新世岩浆作用及其意义

喜马拉雅造山带东部错那县麻玛沟地区发育多种类型的花岗片麻岩和淡色花岗岩。锆石SHRIMP U-Pb地质年代学研究结果表明：花岗片麻岩(MM15)原岩结晶年龄为500.7±4.5Ma,含石榴子石淡色花岗岩中携带的继承性核部锆石年龄为498.6±3.4Ma,表明该地区经历了早古生代的岩浆作用事件。淡色花岗岩的结晶年龄区间为15.7~25.1Ma之间,为白云母脱水熔融的产物,可能是晚元古代-早古生代花岗质岩石发生低程度部分熔融的结果。锆石形态学表明该区的花岗片麻岩和淡色花岗岩均为过铝质花岗岩,并相对富集Cs、Rb、U、Pb,亏损Zr、Hf和低Nb/Ta比值,属于造山型花岗岩,支持该区域古生代岩浆作用事件与俯冲-碰撞造山作用相关,不是被动大陆边缘构造背景。结合前人数据推断：(1)从晚元古代末期开始,原特提斯洋向印度大陆的初始俯冲为自东向西的俯冲扩展模式;和(2)喜马拉雅造山带中新世淡色花岗岩为白云母脱水熔融和水致白云母熔融共同作用的结果,岩浆活动至少存在五个相。

     

喜马拉雅碰撞造山带新生代地壳深熔作用与淡色花岗岩

自从印度-欧亚大陆碰撞以来,伴随着构造演化和温度-压力-成分(P-T-X)的变化,喜马拉雅造山带中下地壳变质岩发生不同类型的部分熔融反应,形成性质各异的过铝质花岗岩。这些花岗岩在形成时代、矿物组成、全岩元素和放射性同位素地球化学特征上都表现出巨大的差异性。始新世构造岩浆作用形成高Sr/Y二云母花岗岩和演化程度较高的淡色花岗岩和淡色花岗玢岩,它们具有相似的Sr-Nd同位素组成,是碰撞早期增厚下地壳部分熔融的产物。渐新世淡色花岗岩主要为演化程度较高的淡色花岗岩,可能指示了喜马拉雅造山带的快速剥露作用起始于渐新世。早中新世以来的淡色花岗岩是喜马拉雅造山带淡色花岗岩的主体,是变泥质岩部分熔融的产物,包含两类部分熔融作用——水致白云母部分熔融作用(A类)和白云母脱水熔融作用(B类)。这两类部分熔融作用形成的花岗质熔体在元素和同位素地球化学特征上都表现出明显的差异性,主要受控于两类部分熔融作用过程中主要造岩矿物和副矿物的溶解行为。这些不同期次的地壳深熔作用都伴随着高分异淡色花岗岩,伴随着关键金属元素(Nb、Ta、Sn、Be等)的富集,是未来矿产勘探的重要靶区。新的观测结果表明:在碰撞造山带中,花岗岩岩石学和地球化学性质的变化是深部地壳物质对构造过程响应的结果,是深入理解碰撞造山带深部地壳物理和化学行为的重要岩石探针。     

Coupling of anatectic reactions and dissolution of accessory phases and the Sr and Nd isotope systematics of anatectic melts from a metasedimentary source

Advances in field observations and experimental petrology on anatectic products have motivated us to investigate the geochemical consequences of accessory mineral dissolution and nonmodal partial melting processes. Incorporation of apatite and monazite dissolution into a muscovite dehydration melting model allows us to examine the coupling of the Rb-Sr and Sm-Nd isotope systems in anatectic melts from a muscovite-bearing metasedimentary source. Modeling results show that (1) the Sm/Nd ratios and Nd isotopic compositions of the melts depend on the amount of apatite and monazite dissolved into the melt, and (2) the relative proportion of micas (muscovite and biotite) and feldspars (plagioclase and K-feldspar) that enter the melt is a key parameter determining the Rb/Sr and ⁸⁷Sr/⁸⁶Sr ratios of the melt. Furthermore, these two factors are not, in practice, independent. In general, nonmodal partial melting of a pelitic source results in melts following one of two paths in ε_Nd-⁸⁷Sr/⁸⁶Sr ratio space. A higher temperature, fluid-absent path (Path 1) represents those partial melting reactions in which muscovite/biotite dehydration and apatite but not monazite dissolution play a significant role; the melt will have elevated Rb/Sr, ⁸⁷Sr/⁸⁶Sr, Sm/Nd, and ε_Nd values. In contrast, a lower temperature, fluid-fluxed path (Path 2) represents those partial melting reactions in which muscovite/biotite dehydration plays an insignificant role and apatite but not monazite stays in the residue; the melt will have lower Rb/Sr, ⁸⁷Sr/⁸⁶Sr, Sm/Nd, and ε_Nd values than its source. The master variables controlling both accessory phase dissolution (and hence the Sm-Nd system), and melting reaction (and hence the Rb-Sr systematics) are temperature and water content. The complexity in Sr-Nd isotope systematics in metasediment-derived melts, as suggested in this study, will help us to better understand the petrogenesis for those granitic plutons that have a significant crustal source component.     

Trace element modelling of pelite-derived granites

The presence or absence of a vapour phase during incongruent-melt reactions of muscovite and biotite together with the composition of the protolith determines the trace-element characteristics of the resulting melt, provided that equilibrium melting occurs for those phases that host the tracc elements of interest. For granitic melts, Rb, Sr and Ba provide critical constraints on the conditions that prevailed during melting, whereas REE are primarily controlled by accessory phase behaviour. Mass-balance constraints for eutectic granites that are formed by the incongruent melting of muscovite in pelites indicate that melting in the presence of a vapour phase will result in a large melt fraction, and deplete the restite in feldspar. Hence the melt will be characterized by low Rb/Sr and high Sr/Ba ratios. In contrast, vapour-absent melting will result in a smaller melt fraction, and an increase in the restitic feldspar. Consequently high Rb/Sr and low Sr/Ba ratios are predicted. Vapour-absent melting will also enhance the negative Eu anomaly in the melt. Granites that result from the incongruent melting of biotite in the source will be characterized by higher Rb concentrations than those that result from the incongruent melting of muscovite. The Himalayan leucogranites provide an example of unfractionated, crustally derived eutectic melts that are enriched in Rb but depleted in Sr and Ba relative to their metasedimentary protoliths. These compositions may be generated by the incongruent melting of muscovite as a low melt fraction (F0.1) from a pelitic source under vapour-absent conditions.     

Late Neoproterozoic strongly peraluminous leucogranites, South Eastern Desert, Egypt – petrogenesis and geodynamic significance

Summary Late Neoproterozoic garnet-bearing leucogranites are developed locally along thrust faults in the South Eastern Desert, Egypt. This work presents field observations, whole rock major and trace element abundances, Rb–Sr isotope data and mineral chemistry for three occurrences in the Sikait-Nugrus area. Field observations show that the leucogranites cut the faults and their contact with the country rocks is sharp with no indication of contact metamorphism. They were intruded into a low-grade metamorphosed ophiolitic melange and a high-grade metamorphosed metasedimentary succession of biotite schist composition. Numerous biotite schist enclaves, having irregular and diffuse contacts, are recorded within the leucogranites. Whole rock Rb–Sr ages of the leucogranites from two different localities are 610±20 and 594±12Ma respectively; they are interpreted as emplacement ages. The leucogranites contain more than 70% SiO₂, and they are strongly peraluminous (A/CNK>1.1) with low TiO₂, Fe₂O₃*, MgO, CaO, Ba, Sr, LREE, Eu/Eu* and Sr/Ba and high Rb, Rb/Zr, Rb/Sr and Rb/Ba. These geochemical parameters and the low initial ⁸⁷Sr/⁸⁶Sr ratios (0.703) indicate crustal derivation by dehydration partial melting from a juvenile protolith similar to the exposed biotite-rich metasediments. Models for the tectonic setting of these leucogranites suggest their emplacement during an extensional tectonic stage that follows continental collision. It is proposed that crustal heating, caused by decompression along shear zones, is responsible for the production of these granitic melts. The results support previous hypotheses and further document a regional late Neoproterozoic extensional tectonic event, which is probably related to the initial break-up of Gondwana.     

Behavior of apatite in granitic melts derived from partial melting of muscovite in metasedimentary sources

Fluid-absent and fluid-fluxed melting of muscovite in metasedimentary sources are two types of crustal anatexis to produce the Himalaya Cenozoic leucogranites. Apatite grains separated from melts derived from the two types of parting melting have different geochemical compositions. The leucogranites derived from fluid-fluxed melting have relict apatite grains and magmatic crystallized apatite grains, by contrast, there are only crystallized apatite grains in the leucogranites derived from fluid-absent melting. Moreover, apatite grains crystallized from fluid-fluxed melting of muscovite contain higher Sr, but lower Th and LREE than those from fluid-absent melting of muscovite, which could be controlled by the distribution of partitioning coefficient (D_Ap/Melt) between apatite and leucogranite. D_Ap/Melt in granites derived from fluid-absent melting is higher than those from fluid-fluxed melting. So, not only SiO₂ and A/CNK, but also types of crustal anatexis are sensitive to trace element partition coefficients for apatite. In addition, due to being not susceptible to alteration, apatite has a high potential to yield information about petrogenetic processes that are invisible at the whole-rock scale and thus is a useful tool as a petrogenetic indicator.©2021 China Geology Editorial Office.     

东天山哈尔里克地区晚石炭世淡色花岗岩成因及其地质意义

淡色花岗岩对深入理解造山带构造演化具有重要意义.哈尔里克山南麓小铺地区出露多种类型的淡色花岗岩脉,包括黑云母花岗岩、二云母花岗岩、含电气石花岗岩以及含石榴石花岗岩.岩石地球化学研究显示这些淡色花岗岩整体具有高硅（SiO₂=73.22%~75.12%）、铝（Al₂O₃=13.59%~14.49%）、碱（ALK=7.11%~9.67%）,低钛（TiO₂=0.01%~0.14%）、铁（TFeO=0.26%~1.37%）、镁（MgO=0.09%~0.46%）、钙（CaO=0.46%~1.92%）的特点,属于弱过铝质钙碱性-钾玄岩系列岩石.其中黑云母花岗岩具有较高的CaO/Na₂O比值（0.46~0.47）和低的Rb/Sr比值（0.31~0.33）,指示其为砂质源岩经黑云母脱水熔融形成;二云母花岗岩和含电气石花岗岩具有较低的CaO/Na₂O比值（0.11~0.31）和高的Rb/Sr比值（1.41~3.75）,为泥质源岩经白云母脱水熔融形成;含石榴石花岗岩具有强烈的Eu负异常以及"海鸥状"稀土配分模式,为高分异型花岗岩.小铺淡色花岗岩初始岩浆温度较低（T=637~744℃）,结合其野外地质特征,认为其形成可能与深部物质的折返、造山带的伸展垮塌有关.利用LA-ICP-MS微区原位锆石U-Pb定年获得黑云母花岗岩的形成时代为308.5±2.2 Ma,含电气石花岗岩的形成时代为307.8±2.3 Ma,二者在误差范围内近乎一致,指示哈尔里克地区在晚石炭世末处于伸展构造背景.      

福建沿海中生代变质带中花岗质岩石的地球化学

福建东南沿海中生代变质带的花岗质岩石分布于东山、晋江和莆田等广大地区。花岗岩中常包含黑云母、石榴子石或白云母。但地球化学研究表明，这些花岗岩属于钙碱性或高钾钙碱性，以低Rb、Zr、Hf、Nb、Y、Ga含量和Rb/Sr比值，以及高Ba、Sr丰度为特征，属于典型的Ⅰ型花岗岩。它们的稀土总量普遍较低，具有轻稀土富集、铕中等亏损的稀土分布模式。本带三个地区花岗岩的微量元素组成存在一定差异，但具有相似的Sr、Nd同位素组成，以高εNd(t)(-4.49～-3.15)和低ISr(0.7055-0.7074)、tDM(1.19-1.29Ga)为特征。地球化学研究显示本带花岗岩形成于相同的构造背景－大型边缘火山弧环境。其母岩浆是由类似于麻源群的古老火成变质岩部分熔融产生的熔融体与同期的幔源玄武质岩浆发生一定程度混合而成。不同地区或同一地区花岗岩地球化学组成上的差异是不同程度的部分熔融和结晶分异的结果。     

华北克拉通北缘显生宙含石榴石淡色花岗岩:特征、时代及成因初探

淡色花岗岩是一种特殊的花岗岩类型,其暗色矿物含量低,且多含有白云母、电气石或石榴石等富铝矿物。通常认为,淡色花岗岩是大陆碰撞造山带最具标志性的岩石类型,主要来自于地壳内沉积物的部分熔融,虽然一些最新研究强调它只是岩浆高度分异与演化的产物。显生宙时期,华北克拉通北缘花岗质岩浆作用强烈,然而对于区域存在的少量具有淡色花岗岩特征的岩体却关注较少。本文在对冀东麻地含石榴石白云母二长花岗岩详细研究的基础上,对华北北缘显生宙含石榴石淡色花岗岩的特征、时代进行了总结与对比,并对其成因进行了初步探讨。结果表明,这些岩石具有淡色花岗岩的典型矿物组成与地球化学特征,但已有数据还不足以充分论证其是否由变沉积岩部分熔融形成。与此同时,稀土元素四分组效应与Nb/Ta、Zr/Hf、Y/Ho、K/Rb、Rb/Sr等比值以及CaO、Ba、Sr等元素含量的差异性指示,这些花岗岩经历了不同程度的岩浆分异作用,部分岩石受到了岩浆演化晚期熔-流体相互作用的影响。岩浆分异程度的不同,是导致这些淡色花岗岩具有不同稀有金属成矿潜力的重要因素,高度分异演化有利于成矿元素的富集。由于仅部分淡色花岗岩经历了较高程度的分异,因此岩浆分异可能并非淡色花岗岩形成的必要机制。华北北缘含石榴石淡色花岗岩集中出现在中-晚二叠世、中-晚侏罗世。前者的形成,与古亚洲洋闭合时的碰撞造山有关;后者与东北、华南等中国东部相似岩石同时代产出,形成于古太平洋俯冲的大地构造背景下,其地球动力学内涵值得进一步探讨。     

Petrogenesis of synorogenic high-temperature leucogranites (Damara orogen,Namibia): Constraints from U–Pb monazite ages and Nd,Sr and Pb isotopes

Two suites of leucogranites were emplaced at 508 ± 5.9 Ma in the Okombahe District of the Damara belt (Namibia) synchronous with the peak of regional high-temperature metamorphism. The Sr (⁸⁷Sr/⁸⁶Sr_init: 0.707 to 0.711), Nd (εNd_init: − 4.5 to − 6.6), and Pb isotopic (²⁰⁶Pb/²⁰⁴Pb: 18.51–19.13; ²⁰⁷Pb/²⁰⁴Pb: 15.63–15.69; ²⁰⁸Pb/²⁰⁴Pb: 38.08–38.66) compositions indicate that these peraluminous S-type granites were derived from mid- to lower-crustal rocks, which are slightly different to the metapelitic rocks into which they intruded. Since the leucogranites are unfractionated and show no evidence for assimilation or contamination, they constrain the temperature and pressure conditions of their formation. Calculated Zr and LREE saturation temperatures of ca. 850 °C indicate high-temperature crustal melts. High Rb/Sr and low Sr/Ba ratios are consistent with biotite dehydration melting of pelitic source rocks. Qz–Ab–Or systematics reveal that melting and segregation for the least fractionated samples occurred at ca. 7 kbar corresponding to a mid-crustal level of ca. 26 km. However, there is no evidence for a mantle component that could have served as a local heat source for crustal melting. Therefore, the hot felsic magmas that formed close to the time of peak metamorphism are the result of long-lasting high temperature regional metamorphic conditions and intra-crustal collision.     

Petrogenesis of peraluminous magmas from the Akum-Bamenda Massif,Pan-African Fold Belt,Cameroon

Peraluminous intrusives of the Akum-Bamenda Massif, Pan-African Belt, Central Cameroon, were synkinematically emplaced in a Pan-African sinistral strike-slip shear zone. The rock sequences consist of medium-grained leucogranites, fine-grained leucogranites, and orthogneisses of biotite granite composition; in aggregate, they cover a range from about 65 to 74 wt.% SiO₂, defining a continuous chemical evolutionary trend and displaying characteristics of the high-K and medium calc-alkaline series. Leucogranites are strongly peraluminous (A/CNK > 1.1) and plot in the field of S-type granites, whereas orthogneisses are metaluminous and plot in the field of I-type granitoids. Major and trace element compositions and the Rb/Sr isotopes of the leucogranites indicate crustal derivation by remelting of a composite metapelite?+?metagreywacke protolith similar to the metasedimentary rocks of the central domain of the Cameroon Pan-African North-Equatorial fold belt.     

Petrology and geochemistry of Pan-African granitoids, Kab Amiri area, Egypt – implications for tectonomagmatic stages in the Nubian Shield evolution

Summary Three distinctive metaluminous granitic suites have been identified from the Pan-African belt of the Kab Amiri area, Eastern Desert, Egypt. These are: 1) a trondhjemite-tonalite suite, 2) a calc-alkaline granodiorite suite, and 3) an alkali leucogranite suite. The trondhjemite-tonalite and the granodiorite suites resemble I-type granitoids whereas the alkali leucogranites display A-type characteristics. Geochemical attributes and field aspects indicate that three independent magmas, at different tectonic stages of the Pan-African crustal growth, are required to explain the origin of these granitoid suites. Rocks of the trondhjemite-tonalite suite correspond to granites of the arc stage and possess a narrow range of SiO₂ with low K₂O, Sr, Rb, Ba, Nb and Zr. Its composition is consistent with 20–30% partial melting of a primitive low-K tholeiitic source, similar to the early formed tholeiitic metavolcanics of the Egyptian basement. The granodiorite suite belongs to the collision stage and displays higher K₂O, Rb, Ba, and Sr. Its magma was derived by 30–40% partial melting of LILE-enriched mafic island arc crust. The presence of abundant microdiorite enclaves in the trondhjemite-tonalite and the granodiorite suites suggests that mantle-derived mafic magma played an important role in their petrogenesis, acting as a heat source for melting via underplating and/or intrusion. The A-type leucogranites are post-collision highly fractionated granites. They exhibit low Al₂O₃, MgO, CaO, TiO₂, Sr, and Ba and high Rb, Nb, Y. The wide chemical variations within this suite are consistent with its evolution by fractional crystallization of plagioclase, K-feldspar, amphibole, Fe–Ti oxides, and apatite from a mafic magma. The parent magma was originated in the upper mantle due to crustal attenuation associated with extension in the late stage of the Pan-African crustal evolution. Received September 13, 2000; revised version accepted May 4, 2001     

藏南也拉香波早渐新世富钠过铝质淡色花岗岩的成因机制及其构造动力学意义

藏南也拉香波穹隆位于近东西向展布的北喜马拉雅片麻岩穹隆(NHGD)最东端,主要由石榴角闪岩、石榴石云母片麻岩、二云母花岗岩和淡色花岗岩组成.SHRIMP锆石U/Pb定年结果表明也拉淡色花岗岩的结晶年龄为35.3±1.1Ma,明显老于位于该穹隆以西类似的淡色花岗岩(年龄普遍<25Ma).全岩元素和Sr-Nd同位素测试结果揭示：(1)也拉香波淡色花岗岩为过铝质富钠花岗岩;(2)与片麻岩相似,也拉香波淡色花岗岩富集大离子亲石元素(LILE,如K,Sr,Rb和Ba),但亏损Ti,Y,Yb,Sc和Cr;(3)和片麻岩或角闪岩相比,也拉香波淡色花岗岩同时亏损LREE和HREE,但与HREE相比,LREE相对富集;(4)在Sr-Nd同位素系统特征上.淡色花岗岩初始Sr同位素比值与角闪岩的相当,在0.711949～0.719344之间;但远小于片麻岩.而Nd同位素组成在片麻岩和角闪岩之间,在-8.9～-15.0之间.以石榴角闪岩和片麻岩为端元,简单混合计算表明：由石榴角闪岩为主和片麻岩为辅组成的混合源区发生部分熔融作用,各自产生的熔体进行不同程度的混合,可形成类似于也拉香波淡色花岗岩成分的岩浆,其中角闪岩的部分熔融起主要作用.使用Zr在岩浆中的饱和浓度温度计得出岩浆的平均温度为673℃,在此温度下,变泥质片麻岩在高压(～10kbar)条件下的水致部分熔融和角闪岩部分熔融都可形成也拉过铝质富钠淡色花岗岩,但角闪岩的脱水部分熔融起主导作用.在地壳增厚条件下,下地壳角闪岩的部分熔融可能是导致喜玛拉雅造山带从缩短增厚向伸展垮塌转换的主要因素之一.     

Formation and evolution of high-pressure leucogranulites: Experimental constraints and unresolved issues

High-pressure (HP) leucogranulites of the Bohemian Massif are interpreted as the metamorphosed equivalents of HP leucogranites produced by deep crustal melting. This is supported by their preserved mineral assemblages (Grt-Ky-mesoperthite), bulk rock chemistry, P-T estimates, and garnet and accessory phase trace element abundances. Following melting and peak metamorphism, the leucogranulites have been exhumed from lower crustal depths to their present position at the highest structural level of the Gföhl Nappe. The nearisothermal decompression (ITD) P-T path and available geochronological data imply high exhumation rates.The dry character of the leucogranulites reflects the water-undersaturated conditions that prevailed during formation of the precursor leucogranitic melts and their subsequent recrystallization in the middle and lower crust. Compositions of the leucogranulites are displaced towards the Qz-Or join in the Qz-Ab-Or ternary diagram, which corresponds to experimental results for water undersaturated melting. Trace element and REE abundances in whole rocks, garnets and accessory phases are consistent with muscovite and biotite dehydration melting coupled with K-feldspar fractionation or separation as the principal controls on the chemical evolution of the rocks. The melting reactions and protoliths potentially involved in the generation of these HP leucogranite melts are evaluated in the light of available experimental data for water-saturated and dry melting of crustal rocks.     

Muscovite dehydration melting: Reaction mechanisms,microstructures, and implications for anatexis

Dehydration melting of muscovite in metasedimentary sequences is the initially dominant mechanism of granitic melt generation in orogenic hinterlands. In dry (vapour-absent) crust, muscovite reacts with quartz to produce K-feldspar, sillimanite, and monzogranitic melt. When water vapour is present in excess, sillimanite and melt are the primary products of muscovite breakdown, and any K-feldspar produced is due to melt crystallization. Here we document the reaction mechanisms that control nucleation and growth of K-feldspar, sillimanite, and silicate melt in the metamorphic core of the Himalaya, and outline the microstructural criteria used to distinguish peritectic K-feldspar from K-feldspar grains formed during melt crystallization. We have characterized four stages of microstructural evolution in selected psammitic and pelitic samples from the Langtang and Everest regions: (a) K-feldspar nucleates epitaxially on plagioclase while intergrowths of fibrolitic sillimanite and the remaining hydrous melt components replace muscovite. (b) In quartzofeldspathic domains, K-feldspar replaces plagioclase by K⁺–Na⁺ cation exchange, while melt and intergrowths of sillimanite+quartz form in the aluminous domains. (c) At 7–8 vol.% melt generation, the system evolves from a closed to open system and all phases coarsen by up to two orders of magnitude, resulting in large K-feldspar porphyroblasts. (d) Preferential crystallization of residual melt on K-feldspar porphyroblasts and coarsened quartz forms an augen gneiss texture with a monzogranitic-tonalitic matrix that contains intergrowths of sillimanite+tourmaline+muscovite+apatite. Initial poikiloblasts of peritectic K-feldspar trap fine-grained inclusions of quartz and biotite by replacement growth of matrix plagioclase. During subsequent coarsening, peritectic K-feldspar grains overgrow and trap fabric-aligned biotite, resulting in a core to rim coarsening of inclusion size. These microstructural criteria enable a mass balance of peritectic K-feldspar and sillimanite to constrain the amount of free H₂O present during muscovite dehydration. The resulting modal proportion of K-feldspar in the Himalayan metamorphic core requires vapour-absent conditions during muscovite dehydration melting and leucogranite formation, indicating that the generation of large volumes of granitic melts in orogenic belts is not necessarily contingent on an external source of fluids.     

Geochemical Constraints on Leucogranite Magmatism in the Langtang Valley, Nepal Himalaya

A complex of crustally derived leucogranitic sills emplacedinto sillimanite-grade psammites in the upper Langtang Valleyof northern Nepal forms part of the Miocene High Himalayan graniteassociation. A series of post-tectonic, subvertical leucograniticdykes intrude the underlying migmatites, providing possiblefeeders to the main granite sills. The leucogranite is peraluminous and alkali-rich, and can besubdivided into a muscovite–biotite and a tourmaline–muscovitefacies. Phase relations suggest that the tourmaline leucogranitescrystallized from a water-undersaturated magma of minimum-meltcomposition at pressures around 3–4 kbar. Potential metasedimentaryprotoliths include a substantial anatectic migmatite complexand a lower-grade mica schist sequence. Isotopic constraintspreclude the migmatites as a source of the granitic melts, whereastrace-element modelling of LILEs (Rb, Sr, and Ba), togetherwith the Nd and Sr isotopic signatures of potential protoliths,strongly suggest that the tourmaline-bearing leucogranites havebeen generated by fluid-absent partial melting of the muscovite-richschists. However, REE and HFSE distributions cannot be reconciledwith equilibrium melting from such a source. Systematic covariationsbetween Rb, Sr, and Ba can be explained by variations in protolithmineralogy and P–T–a_H2O. Tourmaline leucogranites with high Rb/Sr ratios represent low-fraction-melts(F{small tilde} 12%) efficiently extracted from their protolithsunder conditions of low water activity, whereas the heterogeneoustwo-mica granites may result from melting under somewhat highera_H2O conditions. The segregation of low-degree melts from sourcewas probably by deformation-enhanced intergranular flow andmagma fracturing, with the mechanisms of migration and emplacementcontrolled by variations in the uppercrustal stress regime duringlate–orogenic extensional collapse of the thickened crust.     

The petrogenesis of leucogranitic dykes intruding the northern Semail ophiolite, United Arab Emirates: field relationships, geochemistry and Sr/Nd isotope systematics

The Khawr Fakkan block of the Semail ophiolite (United Arab Emirates) exhibits a suite of 10–100 m scale metaluminous to peraluminous granitic intrusions, ranging from cordierite-andalusite-biotite monzogranites to garnet-tourmaline leucogranites, which intrude mantle sequence harzburgites and lower crustal sequence cumulate gabbros. Structural constraints suggest that the subduction of continental sedimentary material beneath the hot proto-ophiolite in an intra-oceanic arc environment led to granulite facies metamorphism at the subduction front and the generation of granitic melts which were emplaced up to the level of the ophiolite Moho. Compositions indicate the analysed granitoids were largely minimum melts that crystallised at variable a _H2O and pressures of 3 to 5 kbar. The LILE (Sr, Rb and Ba) covariation modelling suggests that the granitoids formed largely by the dehydration melting of muscovite rich metasediments. Initial ⁸⁷Sr/⁸⁶Sr ratios of analysed dykes vary between 0.710 and 0.706 at initial ɛ_Nd values of between −6.3 and −0.5. Cogenetic units of a composite sill from Ra's Dadnah yield a Sm-Nd isochron age of 98.8 ± 9.5 Ma (MSWD = 1.18). Geochemical and isotopic characteristics of the analysed granitic intrusions indicate that the subducted continental material was derived from oceanic trench fill (Haybi complex) sediments, preserved as greenschist (Asimah area) to granulite facies (Bani Hamid area) ophiolitic metamorphic sole terranes. The Sr-Nd isotope systematics suggest that hybrid granitic melts were derived from pre-magmatic mixing of two contrasting subduction zone sources. Received: 17 December 1998 / Accepted: 19 July 1999