Thermochemical mantle plumes

Doklady Earth Sciences -     

地幔不均一性与地幔循环的多维表征和原因思考

地幔早先经核- 幔- 壳分异形成,后受不同尺度对流和循环的影响,因而具有不均一性特征。近三十年来,地幔化学通过研究大洋玄武岩发现了多样地幔端元和非放射性同位素证据并证明了地幔不均一性,逐渐建全了地幔地球化学体系。然而,地幔不均一性如何对应于时空尺度的地幔循环,以及地球演化如何影响地幔不均一性等,仍不清楚。此外,地球物理研究显示,岩石圈厚度差异、中下地幔的波速异常体以及俯冲板片形态的观测为纵横向对流系统提供了空间不均一性证据支持。联合地球化学和地球物理手段对研究地幔不均一性至关重要,用好透视地幔成分与结构的“双目镜”已成为共识。本文从地幔不均一性结合地球化学场、地球物理的不同表现形式,以及现今及历史时期的洋陆格局的对比,多维度联系地幔循环和演化,思考了超大陆旋回与地幔不均一化的内在逻辑。强调了从全球演化角度看地幔不均一性的重要性和提出多手段联合建立地幔循环驱动模型的展望。     

Ferropericlase—a lower mantle phase in the upper mantle

Experiments on compositions along the join MgO–NaA³⁺Si₂O₆ (A=Al, Cr, Fe³⁺) show that sodium can be incorporated into ferropericlase at upper mantle pressures in amounts commonly found in natural diamond inclusions. These results, combined with the observed mineral parageneses of several diamond inclusion suites, establish firmly that ferropericlase exists in the upper mantle in regions with low silica activity. Such regions may be carbonated dunite or stalled and degassed carbonatitic melts. Ferropericlase as an inclusion in diamond on its own is not indicative of a lower mantle origin or of a deep mantle plume. Coexisting phases have to be taken into consideration to decide on the depth of origin. The composition of olivine will indicate an origin from the upper mantle or border of the transition zone to the lower mantle and whether it coexisted with ferropericlase in the upper mantle or as ringwoodite. The narrow and flat three phase loop at the border transition zone—lower mantle together with hybrid peridotite plus eclogite/sediments provides an explanation for the varying and Fe-rich nature of the diamond inclusion suite from Sao Luiz, Brazil.     

A possible new Sr-Nd-Pb mantle array and consequences for mantle mixing

A number of oceanic island basalts display isotopic characteristics which fall below the so-called Nd-Sr mantle array. The most extreme (lowest Nd) samples from each suite form a linear alignment in Sr-Nd-Pb-space; this low Nd array, termed here the LoNd array, is defined by basalts from Tubuaii, St. Helena, New England Seamounts, Comores, San Felix and Walvis Ridge. Intra-island isotopic variations for these suites are not colinear with the array but initiate on the array and trend towards the “mantle plane” of Zindler et al. (1982) at high angles. This suggests that mixing between the two mantle reservoirs which are endmembers of the LoNd array (Tubuaii-Walvis) precedes the mixing with reservoirs closer to the “mantle plane” that produces the intra-island variations. Full elucidation of such a mantle mixing “chronology” can provide essential constraints on the location of various mantle reservoirs. If further study substantiates the LoNd array, we argue that the endmember reservoirs of this array are most probably sited in the subcontinental lithosphere, and are introduced into the oceanic mantle circulation by delamination of this lithosphere.     

Cratonic mantle roots, remnants of a more chondritic Archean mantle?

The Earth's continents are cored by Archean cratons underlain by seismically fast mantle roots descending to depths of 200⁺ km that appear to be both more refractory and colder than the surrounding asthenospheric mantle. Low-temperature mantle xenoliths from kimberlite pipes indicate that the shallow parts of these cratonic mantle roots are dominated by refractory harzburgites that are very old (3⁺ Ga). A fundamental mass balance problem arises, however, when attempts are made to relate Archean high-Mg lavas to a refractory restite equivalent to the refractory lithospheric mantle roots beneath Archean cratons. The majority of high-Mg Archean magmas are too low in Al and high in Si to leave behind a refractory residue with the composition of the harzburgite xenoliths that constitute the Archean mantle roots beneath continental cratons, if a Pyrolitic primitive mantle source is assumed. The problem is particularly acute for 3⁺ Ga Al-depleted komatiites and the Si-rich harzburgites of the Kaapvaal and Slave cratons, but remains for cratonic harzburgites that are not anomalously rich in orthopyroxene and many Al-undepleted komatiites. This problem would disappear if fertile Archean mantle was richer in Fe and Si, more similar in composition to chondritic meteorites than the present Pyrolitic upper mantle of the Earth. Accepting the possibility that the Earth's convecting upper mantle has become poorer in Fe and Si over geologic time not only provides a simpler way of relating Archean high-Mg lavas to the lithospheric mantle roots that underlie Archean cratons, but could lead to new models for the nature Archean magmatism and the lower mantle sources of modern hot-spot volcanism.     

Large cold anomalies in the deep mantle and mantle instability in the Cretaceous

Two large cold masses in the deep mantle have been delineated by using long-wavelength seismic tomographic models in conjunction with mineralogical experimental data at high pressure. These cold anomalies are found under the western Pacific and the Americas with temperatures more than 1000 degrees below the ambient mantle temperature. These strong cold anomalies existing in the lower mantle today would suggest that there might have existed not too long ago a substantial temperature jump across a thermal boundary layer between the upper and lower mantle. Numerical simulations in an axisymmetric spherical-shell model incorporating the two major phase transitions have shown that very large pools of cold material with temperatures of around 1500 K can be flushed down to the core–mantle boundary during this tumultuous gravitational instability. A correlation is found between the current locations of these very cold masses and regions of past subduction since the Cretaceous. Correlation analysis shows that the slab mass-flux into the lower mantle does not behave in a steady-state fashion. These findings may support the idea of a strong gravitational instability with origins in the transition zone, as suggested by numerical models of mantle convection.     

The persistent mantle plume myth

Seismology, thermodynamics and classical physics—the physics associated with the names of Fourier, Debye, Born, Grüneisen, Kelvin, Rayleigh, Rutherford, Ramberg and Birch—show that ambient shallow mantle under large long-lived plates is hundreds of degrees hotter than in the passive upwellings that fuel the global spreading ridge system, that potential temperatures in mantle below about 200 km generally decrease with depth and that deep mantle low shear wave-speed features are broad, sluggish and dome-like rather than narrow and mantle-plume-like. The surface boundary layer of the mantle is more voluminous and potentially hotter than regions usually considered as sources for intraplate volcanoes. This means that the ‘mantle plume’ explanation for Hawaii and large igneous provinces is unnecessary. In isolated systems, heated from within and cooled from above, upwellings are passive and large, which suggests that tomographic features, and upwellings, are responses to plate tectonics, spreading and subduction, at least until melting introduces a small intrinsic buoyancy at shallow depths. Melting anomalies, or ‘hotspots,’ are side-effects of plate tectonics and are fed primarily by shear-driven processes in the boundary layer (BL), not by deep buoyant upwellings. A dense basal melange (BAM) component further stabilises the lower boundary layer of the mantle. Mid-ocean ridges and associated broad passive depleted mantle (DM) upwellings probably originate in the transition region. Deeper mantle upwellings are broad domes that stay in the lower mantle.     

Manganese thermometer for mantle peridotites

The temperature dependence of the Mn-Mg distribution between garnet and clinopyroxene, originally proposed by Carswell, was confirmed by Shimizu and Allègre (1978) using ion microprobe and electron microprobe data. High precision electron microprobe analyses of a larger set of 52 Iherzolites from S. Africa and Malaita, Solomon Islands show considerable scatter in the temperature dependence of this distribution, and correlation with the CaO content of the garnet is indicated. A new distribution coefficient is based on the reaction: $$\begin{gathered} \operatorname{Mn} _{\text{2}} \operatorname{Si} _2 \operatorname{O} _6 {\text{ + }}\operatorname{CaAl} _{2/3} \operatorname{SiO} _4 {\text{ + }}\operatorname{MgAl} _{2/3} \operatorname{SiO} _4 \hfill \\ {\text{Mn - pyroxene grossular pyrope}} \hfill \\ {\text{ }} \rightleftharpoons \operatorname{CaMgSi} _2 \operatorname{O} _6 {\text{ + }}2\operatorname{MnAl} _{2/3} \operatorname{SiO} _4 \hfill \\ {\text{ diopside spessartine}} \hfill \\ \end{gathered} $$ It was calibrated against temperature determined from two independent thermometers (Wells pyroxene and O'Neill-Wood garnet-olivine) for Iherzolitic assemblages, and shown to to be sensitive to within + 50 °C for most specimens in the range 900 °– 1,300 ° C. This distribution coefficient appears independent of pressure within the uncertainty of the available data, and has the potential to be a third independent thermometer for use in garnet Iherzolites and possibly eclogites.     

Fluid inclusions in mantle xenoliths

Fluid inclusions in olivine and pyroxene in mantle-derived ultramafic xenoliths in volcanic rocks contain abundant CO₂-rich fluid inclusions, as well as inclusions of silicate glass, solidified metal sulphide melt and carbonates. Such inclusions represent accidentally trapped samples of fluid- and melt phases present in the upper mantle, and are as such of unique importance for the understanding of mineral–fluid–melt interaction processes in the mantle. Minor volatile species in CO₂-rich fluid inclusions include N₂, CO, SO₂, H₂O and noble gases. In some xenoliths sampled from hydrated mantle-wedges above active subduction zones, water may actually be a dominant fluid species. The distribution of minor volatile species in inclusion fluids can provide information on the oxidation state of the upper mantle, on mantle degassing processes and on recycling of subducted material to the mantle. Melt inclusions in ultramafic xenoliths give information on silicate–sulphide–carbonatite immiscibility relationships within the upper mantle. Recent melt-inclusion studies have indicated that highly silicic melts can coexist with mantle peridotite mineral assemblages. Although trapping-pressures up to 1.4 GPa can be derived from fluid inclusion data, few CO₂-rich fluid inclusions preserve a density representing their initial trapping in the upper mantle, because of leakage or stretching during transport to the surface. However, the distribution of fluid density in populations of modified inclusions may preserve information on volcanic plumbing systems not easily available from their host minerals. As fluid and melt inclusions are integral parts of the phase assemblages of their host xenoliths, and thus of the upper mantle itself, the authors of this review strongly recommend that their study is included in any research project relating to mantle xenoliths.     

大陆岩石圈地幔定年

大陆岩石圈地幔是伴随地壳熔体抽取而形成的低密度地幔残留,是联系软流圈与地壳的重要纽带。虽然大陆岩石圈地幔一直是固体地球科学研究的重要内容,但对其形成时代的准确厘定则是当前研究的难点。传统方法是采用岩石圈地幔中橄榄岩主要元素的贫瘠程度来对岩石圈进行定年,即古老的岩石圈地幔Al2O3和CaO含量低,而MgO含量高(同时导致橄榄石高Fo值),而年轻岩石圈地幔的特征正好相反。显然,这种间接的方法不能给出确切的年龄信息。尽管Sr-Nd和锆石U-Pb等同位素方法也被用来进行地幔橄榄岩定年,但岩石圈地幔通常具有的较高温度使上述同位素体系不能保持封闭,因而给出的年龄大多与岩石圈地幔的形成时代无关。近几年发展起来的Re-Os同位素技术是目前进行岩石圈地幔定年的最理想工具,但也存在一系列需要研究的问题。文中对这一方法的基本原理、发展现状和存在的问题进行了全面的介绍。同时,根据目前获得的Os同位素资料,对中国东部岩石圈地幔的时代进行了讨论,并简要论述所获得的资料对岩石圈减薄研究的启示。     

Convection in the earth's mantle

According to the hypothesis of global plate tectonics the surface motions of the earth are now known in considerable detail, but very little is known about the three-dimensional flow in the earth and about the forces which maintain the motions. The motions at depth are difficult to study because they produce few surface effects. For instance, there is now no reason to believe that ridges are the surface evidence for rising convection currents at depth. Only the plate motions themselves and the gravity field observed by satellites must be consequences of three-dimensional flow beneath the plates. Other observations, such as the high heat flow near ridges or deep earthquakes beneath trenches, now appear to be explained by the production and destruction of plates.     

Omphacite paradox in mantle peridotites

Omphacite is a typomorphic mineral of eclogites, which is inappropriate to mineral assemblages of peridotites. Nevertheless, findings of this mineral in inclusions in peridotitic diamonds can be considered as indirect evidence for the existence of this paradoxical mineral assemblage.In this paper we present experimental results on the interaction between carbonate-bearing amphibolite and olivine that model processes operated at the crust–mantle boundary in subduction zones. The experiments demonstrate growth of omphacite at the interface between acid melt and peridotite media at 2.9 GPa and 850–900 °C; the omphacite coexists either with garnet and orthopyroxene or with phlogopite. The synthetic omphacite is exclusively of reactive-magmatic origin and does not form in metasomatic way. Findings of omphacite inclusions in peridotitic diamonds and in some pyroxenites from kimberlites are discussed in scope of the obtained experimental data.     

Energy sources for mantle plumes

Mantle plumes are the consequence of a focussed transfer of mass from mantle to core and are agents of outgassing from the mantle. The energy of propagation is derived from released energy of their formation, decreases in density, and partial fluidization. This energy is dissipated during distension and rupture of the overlying crust.

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Zusammenfassung Mantelplumes haben ihren Ursprung in einer gezielten Massenverfrachtung vom Mantel zum Kern und führen zur Mantelentgasung. Die Fortpflanzungsenergie entsteht aus frei werdender Bildungsenergie, Dichteverminderung und teilweiser Verflüssigung. Die Energie verflüchtigt sich bei Ausdehnung und Rißbildung der überlagernden Kruste.

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Résumé Plumes en le manteau sont derivées d'un transfert de masse dès le manteau au noyau. Elles sont agents de la dégassification du manteau. L'énergie de la propagation est derivée de l'énergie de la formation liberée, des décroissements de la densité, et de la fluidification partielle. Cette énergie est dissipée pendant la dilatation et la rupture de la croûte s'étendante là-dessus.

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Plumes , . : , . .

     

Mica in the upper mantle

Despite several lines of indirect evidence, there has hitherto been little unambiguous evidence of a volatile bearing phase in the upper mantle. Mica has been found as a primary phase in several specimens of peridotite and one specimen of garnet lherzolite from the Lashaine volcano, northern Tanzania.     

Deep subduction and mantle heterogeneities

The globe-encircling isotopic anomaly centred on latitude 30°S defined from the geochemistry of mid-ocean ridge and particularly intraplate basalts has been previously shown to be correlative with degree-2 features of the Earth's geoid. The same region appears to show a correlation with zones of low seismic velocities, perhaps indicative of heated rocks, which persist to at least the transition zone between the upper and lower mantle. That the basalts in this anomalous region are derived by diapiric uprise from a mantle reservoir of old deeply subducted materials is favourably demonstrated by olivine and clinopyroxene-controlled partial melting trends on geochemical discrimination diagrams.     

Sublithospheric flows in the mantle

The estimated rates of upper mantle sublithospheric flows in the Hawaii–Emperor Range and Ethiopia–Arabia–Caucasus systems are reported. In the Hawaii–Emperor Range system, calculation is based on motion of the asthenospheric flow and the plate moved by it over the branch of the Central Pacific plume. The travel rate has been determined based on the position of variably aged volcanoes (up to 76 Ma) with respect to the active Kilauea Volcano. As for the Ethiopia–Arabia–Caucasus system, the age of volcanic eruptions (55–2.8 Ma) has been used to estimate the asthenospheric flow from the Ethiopian–Afar superplume in the northern bearing lines. Both systems are characterized by variations in a rate of the upper mantle flows in different epochs from 4 to 12 cm/yr, about 8 cm/yr on average. Analysis of the global seismic tomographic data has made it possible to reveal rock volumes with higher seismic wave velocities under ancient cratons; rocks reach a depth of more than 2000 km and are interpreted as detached fragments of the thickened continental lithosphere. Such volumes on both sides of the Atlantic Ocean were submerged at an average velocity of 0.9–1.0 cm/yr along with its opening. The estimated rates of the mantle flows clarify the deformation properties of the mantle and regulate the numerical models of mantle convection.     

Metasomatism of the Pan-African lithospheric mantle beneath the Damara Belt,Namibia, by the Tristan mantle plume: geochemical evidence from mantle xenoliths

In situ trace element analyses of constituent minerals in mantle xenoliths occurring in an alnöite diatreme and in nephelinite plugs emplaced within the central zone of the Damara Belt have been determined by laser ablation ICP-MS. Primitive mantle-normalized trace element patterns of clinopyroxene and amphibole indicate the presence of both depleted MORB-like mantle and variably enriched mantle beneath this region. Clinopyroxenes showing geochemical depletion have low La/Sm_n ratios (0.02–0.2), whereas those showing variable enrichment have La/Sm_n ranging up to 3.8 and La/Yb_n to 9.1. The most enriched clinopyroxenes coexist with amphibole showing similar REE patterns (La/Sm_n = 1.3–4.1; La/Yb_n = 4.5–9). Primitive mantle-normalized trace element patterns allow further groups to be distinguished amongst the variably enriched clinopyroxenes: one having strong relative depletion in Rb–Ba, Ta–Nb and relative enrichment in Th–U; another with similar characteristics but with additional strong relative depletion in Zr–Hf; and one showing no significant anomalies. Amphiboles show similar normalized trace element patterns to co-existing clinopyroxene. Clinopyroxene and amphiboles showing LREE_N enrichment have high Sr and low Nd isotope ratios compared to clinopyroxene with LREE-depleted patterns. Numerical simulation of melt percolation through the mantle via reactive porous flow is used to show that the chromatographic affect associated with such a melt migration process is able to account for the fractionation seen in La–Ce–Nd in cryptically metasomatized clinopyroxenes in Type 1 xenoliths, where melt–matrix interactions occur near the percolation front, whereas REE patterns in clinopyroxenes proximal to the source of metasomatic melt/fluid match those found in modally metasomatized Type 2 xenoliths. The strong fractionation between Rb–Ba, Th–U and Ta–Nb shown by some cryptically metasomatized xenoliths can be also accounted for by reactive porous flow, provided amphibole crystallizes from the percolating melt/fluid close to its source. The presence of amphibole in vein-like structures in some xenoliths is consistent with this interpretation. The strong depletion in Zr–Hf in clinopyroxene and amphibole in some xenoliths cannot be accounted for by melt migration processes and requires metasomatism by a separate carbonate-rich melt/fluid. When taken together with published isotope data on these same xenoliths, the source of metasomatic enrichment of the previously depleted (MORB-like) sub-Damaran lithospheric mantle is attributed to the upwelling Tristan plume head at the time of continental breakup.