Non-recognition of continental tholeiites using the Ti-Y-Zr diagram

Continental tholeiites cannot be identified using the Ti-Y-Zr diagram. Two-hundred and thirteen analyses from 16 localities representing 7 continental tholeiitic provinces all plot outside the within-plate basalt field of this diagram.Analyses representing about 50% of the population plot in the ocean-floor basalt field, the rest plots in the calc-alkali basalt field. Therefore problems might arise when attempts are made to classify ancient tectonomagmatic environments using the Ti-Y-Zr diagram.     

The anthracite smokers of eastern pennsylvania: PS2 (g)P_{S_2 (g)} -T stability diagram by TL analysis

Coal seams and culm banks associated with mine fires in the anthracite region of eastern Pennsylvania have been burning for decades. Many of the fires may have ignited by spontaneous combustion or by the burning of trash. Minerals associated with the combustion of anthracite form by the condensation of gas exhaled through surficial gas vents or anthracite smokers. A Pressure-Temperature (P-T) stability diagram is constructed for the condensation of orthorhombic sulfur from anthracite gas using Thermodynamic Loop Analysis (TL analysis). This method of analyzing chemical systems incorporates Kirchhoff's Law into a four step procedure structured around a closed thermodynamic cycle or thermodynamic loop. The four steps, referred to us The Four S S of Thermodynamic Loop Analysis, include: (1) Set Up—graphical characterization of the problem. (2) Sum—the application of thermodynamic principles. (3) Substitute—the use of materials data available from the literature, and (4) Solve—computation of one or more variables. The example presented demonstrates that thermodynamic loops can incorporate any number of polymorphic phase transformations. In addition, thermodynamic loop analysis is applicable to any geologic process involving the condensation of minerals from a gas. The stability diagram derived by TL analysis may have applicability in monitoring the release of sulfur gas into the atmosphere.     

Principal components analysis of three-way tables

A three-mode principal components method allows visualization of the structural or taxonomic relationships within three-way data tables. The fundamental model includes three sets of eigenvectors and a core matrix relating the principal components of each mode. Formal relationships between the method and the usual principal components formulation allow calculation of loadings and scores for each mode; taken with the core matrix, these provide a number of points of view in graphical analysis of three-mode data. The model compares favorably with alternative formulations in terms of simplicity of computation, generality, and symmetry of operation among the modes. An organic geochemical example illustrates the method.     

Dam the rivers; damn the people: Hydroelectric development and resistance in Amazonian Brazil

This paper analyzes the history and consequences of two large scale hydroelectric projects in Amazonian Brazil. The argument makes three points. First, environmental impacts of such projects are inseparable from issues of human rights, regional economic development, and social justice. The implication of this view is that another development, something quite different from the industrial ideal of modernization, is necessary in Amazonia and elsewere.Second, analytical fragmentation of problems into specialist concerns with such topics as ecology (often only meaning wildlife), environment (often concerned only with soil erosion and regional climate), and human rights (sometimes only focusing on the rights of indigenous people, not small farmer migrants tempted to settle in such areas) is mirrored by a fragmented, and therefore weak, resistance to hydroelectric development. The paper traces the early signs of a more unified resistance movement capable of overcoming these special interests and fragmentation.Third, the paper provides data on an economic monstrosity. The Balbina dam was begun in 1981, had cost $ 700 million by 1988, will not be viable withoutanother $ 700 million of design correction, andeven then will not provide enough electricity for Manaus city: this is a monument to an apparent inability to learn from history.Funding provided by the Luce Program in Food, Resources, and International Policy of Hampshire College; The Peggy Howard Fund; Public Service/Social Change Program of Hampshire College; The Explorer's Club; Patrick T. Knight. Special Thanks to Dorothy and Egydio Schwade, Paulinho Paiakan Kaiapo. In Memory of Chico Mendes.     

Space in geography

The concept of space is one of the most fundamental of geographical concepts. There is no work in geography that does not certain it. Nevertheless, geography has not as yet formulated an explicit and unambiguous definition of geographical space. This fact has had negative consequences for geographical theory, methodology and application. In the effort of contributing to its elimination we will try to outline the basic connotations of the concept.The concept of geographical space is a relational one. It acquires meaning and sense only when related to other concepts. The concept of space may be conceived as a supplement to things, i.e. substantively conceived objects. Space conceived in this way is the synonym of emptiness. The concept of space may be also conceived in relation ti individual landscape elements as their environments. Space conceived in this way has the character of a field of force. And, finally, space may be conceived also with respect to the totality of landscape elements, i.e. the system expressed by the term synergic. It is only this third variant of space which should be understood as the geographical space in the full menaing of the term. It is only this conception of geographical space as the space filled with qualities in relations and proportions that is considered as one of the basic prerequisites for the formulation of the theory of geography as science capable of prediction and thus also of practical utilization.     

Nature of the coordination polyhedra around M 2 cations in pigeonite

An understanding of the irregular coordination polyhedra exhibited by the M2 cations in clinopyroxenes is of prime importance in connection with the behaviour of solid solutions and polymorphism in pyroxenes.As shown by unfolding the silica chains in pigeonite, cations with octahedral stereochemistry like Mg⁺⁺and Fe⁺⁺ cause kinking of the silica chains, whereas larger cations like Ca⁺⁺and Na⁺have an opposite namely straightening effect. This is a probable factor causing immiscibility in the Mg⁺⁺-Ca⁺⁺ solid solutions in pyroxenes. In pyroxene structures with kinked silica chains the arrangement of oxygen atoms approaches close packing; consequently different stacking sequences will be energetically possible leading to polymorphism in pyroxenes.When Pauling's electrostatic valence rule is applied to clinopyroxenes, the charge balance will be exceedingly improved if effective coordination number of M2 cation is assigned and if the distortions of M 2 coordination polyhedron is considered.     

Möglichkeiten und Grenzen des Base Friction Konzepts

ZusammenfassungMöglichkeiten und Grenzen des Base Friction Konzepts Der vorliegende Beitrag befaßt sich mit einer von Goodman eingeführten neuen Technologie für zweidimensionale Modellversuche in der Felsmechanik. Bei diesen Modellen sollen die im Prototyp durch die Gravitation erzeugten Körperkräfte durch Reibungskräfte simuliert werden, die dieselbe Richtung wie die Erdbeschleunigung besitzen müssen und die entstehen, wenn das zweidimensionale Modell in einer horizontalen Ebene aufgebaut und zwischen dem Modell und der horizontalen Basis eine entsprechende Relativbewegung erzwungen wird.Nach einem kurzen Überblick über die einschlägige Literatur wird anhand eines Stabilitätsdiagramms für einen Einzelkörper an der Schiefen Ebene untersucht, ob die im geklüfteten Fels auftretenden Bruchmechanismen Gleiten, Kippen und Kippen bei gleichzeitigem Gleiten im Base Friction Modell exakt modellierbar sind.Aus dieser Untersuchung ergibt sich, daß in den Bereichen Kippen und Gleiten bezüglich der Kinetik mit Schwerkraftmodellen übereinstimmende Ergebnisse zu erzielen sind. Im Bereich Kippen bei gleichzeitigem Gleiten treten dagegen wesentliche Abweichungen auf, weil die Simulation der Schwerkraft durch Reibungskräfte nicht vollständig gelingt. Fälle, bei denen Aussagen über Geschwindigkeits-und Beschleunigungsverhältnisse im Prototyp gemacht werden sollen, können aus demselben Grund mit einem Base Friction Modell nicht untersucht werden.Nach einer ausführlichen Kritik wird dann der Schluß gezogen, daß das Base Friction Modell zwar als Entwurfshilfsmittel ungeeignet ist, daß es aber als Methode für die Grundlagenforschung in der Felsmechanik mit Aussicht auf Erfolg eingesetzt werden kann.

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SummaryPossibilities and Limitations of the Base Friction Model The paper deals with a new technology for two-dimensional model tests in rock mechanics introduced by Goodman. In this model gravity is simulated by base friction forces. Their direction is to be that of gravity. The two-dimensional model is placed on a horizontal base. A movement of this base relative to the model produce frictional forces which model gravity.First a single model element placed on an inclined plane is analysed resulting in a stability diagram. The purpose of the subsequent analysis is to assess whether the mechanisms of failure being investigated, i. e. sliding, toppling, and toppling combined with sliding, are adequately reproduced by the base friction model.The specific mechanisms toppling and sliding produce kineticly valid results. Considerable errors are to be expected for toppling combined with sliding, because of the specific base friction feature. Mechanisms including velocity and acceleration cannot be modeled by base friction.Finally the limitations of the base friction model as a design tool and instrument for rock mechanics research are discussed.

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RésuméPossibilités et limites du base friction model Le présent article traite d'une nouvelle technologie des essais à deux dimensions, introduite par Goodman, sur la mécanique des roches. Par cette technologie les forces en prototype, produites par la gravitation, doivent être remplacées par des forces de frottement. Leur direction doit être la même que celle de la gravitation. Le modèle à deux dimensions est posé sur un plan horizontal. Le mouvement relatif du modèle contre la base horizontale produit des forces de frottement, qui modèlent la gravitation.A l'aide d'un diagramme de stabilité pour un élément isolé sur un plan incliné, on fait des analyses pour savoir si les états de mouvement aparaissant à la rupture de la roche, c'est-à-dire le fait de glisser, basculer, et basculer en même temps que glisser, peuvent être modelés exactement avec le base friction model.Les mécanismes glisser et basculer produisent des résultats qui sont cinétiquement réels. Des fautes remarquables doivent être attendues pour le fait de basculer en même temps que glisser à cause de la mécanique spécifique du modèle. A modeler des vitesses et des accélérations le modèle n'est pas propre.En conclusion on expose une critique détaillée pour savoir jusqu'à quel point cette méthode peut servir comme moyen de dimensionnement dans la pratique et comme instrument pour la recherche en mécanique des roches.

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Mit 9 Abbildungen     

Background,conceptual structure and organizational-administrative establishing of a “sustainable development strategy” for Coral Islands

Minitope coral islands represent one third of the islands located in the tropical Indo-Pacific. Subsistence farming and extensive agriculture dominate the traditional structure of income. As the lack of natural resources, infrastructure and capital restrict the developmental changes, the islands' natural environment has been utilized as economic potential. Planning and realization of land use systems introduced have, however, often been based on an insufficient data basis and have often inadequately considered the consequences of human impacts on the natural environment and its controlling factors. The result was environmental degradation and ecological destruction, affecting also the population's socioeconomic situation and in some cases rendering alternative land use impossible. Therefore, the long-term utilization of coral islands and, hence, the economic development of those countries require a specific development strategy. Based on the environmental and socioeconomic consequences of touristic utilization of coral islands in the Maldivian Archipelago, the model for a sustainable development strategy and its aims are derived, and the objectives, the conceptual structure, and the way of establishing them organizationally and administratively are presented.     

Petrogenesis of the Bosworgey granitic cusp in the SW England tin province and its implications for ore mineral genesis

The Bosworgey granite cusp forms an apical portion of the concealed northern extension of the Tregonning-Godolphin granite ridge. It is characterised by unusually high values of B, P, Mn, Fe, As, Cu, Nb, Ta, Bi, Sn, W, U and S which are present largely as tourmaline, apatite, pyrite, arsenopyrite, chalcopyrite, bismuth, columbite, cassiterite, wolframite and uraninite; and low levels of Zr, Hf, Ti and REE present in zircon, ilmenite and monazite. The granite is classified as Sn and W specialised (Tischendorf, 1974) and it belongs to the ilmenite series of Japanese workers. The classification of Chappell and White (1974) (S and I type granites) is shown to be inapplicable to Cornubian rocks although the Bosworgey samples show characteristics of S type granites. The accessory mineral assemblages are typical of high temperature lodes (cassiterite, wolframite, arsenopyrite, chalcopyrite) and the assamblage is concluded to be the cusp analogue of hypothermal lodes produced by extreme differentiation and concentration of volatiles. It is speculated that such granites could provide the parent material for the mesothermal crosscourse mineralisation (pitchblende, bismuth, pyrite, galena, sphalerite).     

The US army in operations other than War: A time to revive military geography

This paper revisits and interrelates the scope of military geography and the changing role of the military, two themes previously addressed in the 1993 and 1994 special editions ofGeoJournal. I begin by tracing the evolution of military geography in the US from World War I through the end of the Gulf War to reveal the demise of the subfield within American academic geography. Within the context of the post-Cold War era, I describe the military's reorientation and emphasize the need and opportunity to broaden the scope of military geography accordingly. The military's current operating environment is best characterized by operations other than war, undertaken on an unprecedented scale. Military geographers and regional, systematic, and technical experts throughout the discipline now have an unparalleled opportunity to contribute to the success of peacekeeping, humanitarian, and disaster assistance missions with which the military is currently preoccupied. Initiatives by academic geographers would not only enhance mission accomplishment from the military and federal government's perspective, but might also help to revive military geography as a legitimate subfield by demonstrating that military geographic endeavors can be both socially responsible and politically correct, particularly within operations other than war.     

Geochemistry of the Grenville Dyke Swarm: role of plume-source mantle in magma genesis

Major and trace element data of samples from the approximately 590 Ma Grenville dyke swarm, in the southeastern parts of the Canadian Shield, were used to evaluate the extent of crustal contamination of the dyke magma and to model its probable mantle source. The dyke rocks are mostly saturated, quartz tholeiites. A few samples represent transitional basalts. Their overall chemistries are similar to those of continental flood basalts. Their compositions resemble those of liquids initially produced in the garnet peridotite mantle zone and then subjected to polybaric fractionation. However, fractionation models fail to mass-balance Ti, Fe, K, and P. Geochemical and isotopic criteria indicate that crustal contamination was minimal. The incompatible elements Zr, Y, K, Rb, Nb, V, Ta, Hf, and Th show hyperbolic elemental ratio-ratio distributions indicative of mixing between two end-members. One end-member has elemental ratios similar to those of a depleted N-MORB source and the second of a P-MORB i.e. ertile or plume MORB source. The more enriched dyke compositions can be successfully reproduced by mixing models in the ratio of 6:1 between the most depleted MORB-like dyke magma and a liquid composition similar to metasomatic glass veinlets coexisting with mica peridotite mantle xenoliths, and subsequent crystal fractionation. The Grenville dykes are probably a synrift swarm that was emplaced along a rift arm related to an Iapetan rrr triple junction that is thought to have formed over a mantle plume. The chemistry of the dyke swarm is consistent with its derivation from a plume head, in that the minor enriched source can be identified with plume-source mantle and the major depleted source with entrained mantle. The magma probably originated in the upper cooler parts of the plume head.     

Islands and oil — locality and structure

This paper analyses the meeting between the international petroleum industry and two local communities. The building of an oil terminal in a local community is both a major event, and a generator of processes on the local level. Three different angles is used to enlighten these processes; categorised as as place, people and mind. The place analysis consentrates on the effects on population and workforce development, the people analysis look at the institutional and planning processes, and the mind analysis the effects on the feeling of local identification. The paper demonstrates that local factors are of crucial importance even for the international petroleum industry.     

Strontium isotopic equilibration during metamorphism of tillites from the Ogcheon Belt,South Korea

The NE/SW trending Ogcheon Belt formed during the Mesozoic by deformation and metamorphism of a sedimentary sequence which includes tillite formations of late Precambrian or Lower Palaeozoic age. In this study Rb-Sr isotopic data are reported from cm-scale sampling of clasts and matrix in these tillites, which underwent metamorphism at grades ranging from the biotite zone to the kyanite zone. Sr-isotopic disequilibrium between clasts and matrix persists up to the highest grade but in four out of five rocks the matrix samples approximate to isochrons (MSWD's<12). The mechanism for this selective isotopic equilibration is considered to be related to the metamorphic reactions in the matrix, which were probably accompanied by a substantial fluid flow. The matrix isochrons for three of the rocks, together with separated white micas from associated schists, suggest that metamorphism took place in the Trias, approximately 200 Myr ago. Metamorphism was followed by slow cooling and biotite closure temperatures were not reached until 190-150 Myr. — These results suggest that where high fluid/rock ratios can be demonstrated on independent petrological grounds, the analysis of small-scale whole-rock samples may allow effective Rb/Sr dating of metamorphism.     

The alteration of olivine in basaltic and associated lavas

Olivines which cool under oxidizing conditions exsolve iron oxides at high temperature, and at low temperatures break down to essentially chloritic materials. Olivines which cool under non-oxidizing conditions alter at intermediate temperatures to complex assemblages of chlorite and interstratified phyllosilicates containing a smectite. Alteration under oxidizing conditions at low temperature, probably below 140° C, produces iddingsite, an orientated assemblage of goethite and interstratified phyllosilicates also containing a smectite.Post-deuteric alteration extends or initiates the breakdown of olivine to phyllosilicate mixtures often resulting in widespread movement of materials through the flow. Post-deuteric alteration of iddingsite produces strongly pleochroic, highly ordered varieties which eventually break down to green phyllosilicate assemblages.Weathering of olivine may produce orientated assemblages similar to deuteric forms of iddingsite. Weathering of green alteration products results in oxidation and the liberation of discrete iron hydroxides.Alteration in all cases requires exchange of material between interstitial components and olivine. During deuteric alteration, plagioclase and pyroxene are usually unaffected.     

The high-pressure assemblages at Milos,Greece

Metamorphic rocks at Milos are known in small outcrops beneath the volcanic formations, as xenoliths in the Traphores volcanic breccia and as pebbles in the Paleochora Quaternary deposits. These rocks seem to belong to three different metamorphic units which probably have intricate relationships in the basement: — the eclogites unit shows garnetjadeite or garnet-omphacite primary associations, with apparently late crystallization of lawsonite phenoblasts an recrystallization features at relatively low temperatures; — the glaucophane schist unit exhibits Jadeite+quartz or glaucophane+lawsonite primary mineralogy; — the greenschist facies unit shows low-pressure main assemblages, most generally developed after high-pressure events. The two former units involve tholeiitic meta-igneous rocks, having been spilitized before metamorphism; they generally suffered more or less advanced recrystallization features in the low-pressure field of the greenschist facies. The third unit shows only meta-sedimentary rocks, with the sole exception of one single meta-doleritic pebble having calk-alkaline affinities.Petrological and mineralogical studies, based upon 15 bulk-rock compositions and 178 probe-analysed data points, lead to suspect at least 2, perhaps 3, different metamorphic events rather than one single metamorphic evolution, to account for the 3 U distinguished. From the observation of the mineralogical assemblages and their evolution, the former events (stages 1 and 2) could be related to rapid subduction of ocean-floor or back-arc basalts, whereas, during the latter event (stage 3), the rocks experienced crystallization conditions involving both decreasing pressures and increasing temperatures.     

Mineralized hydrothermal solution cavities in the Co-As Aït Ahmane mine (Bou Azzer,Morocco)

In the F53 Aït Ahmane Cobalt-deposit (Bou Azzer, Anti-Atlas, Morocco) a new type of contact mineralization is described. It is carbonate hosted but displays similar depositional sequence and fluid inclusion patterns to the well-known vein mineralization from the same mine. Field studies suggest that such a contact mineralization formed early by infilling solution cavities in formerly calcified serpentinite.     

Gangbildung und Tektonik im Gebiet der Spateisensteingrube “Neue Haardt” bei Weidenau/Sieg

Zusammenfassung Die Bildung des Spateisensteinganges von Grube Neue Haardt schließt an die Hauptfaltung an. Der Gang ist aus einer Abschiebung entstanden und wird von der Geisweider Überschiebung abgeschnitten.Es wird nachgewiesen, daß auf dieser Überschiebung nach Zeit und Richtung unterschiedliche Bewegungen stattgefunden haben.     

Sakmarian geography

The known palaeontological and stratigraphical evidence is used as a basis for the construction of maps of the continents showing the extent of their inundation by the sea in Sakmarian time in the Upper Palaeozoic. In the northern hemisphere apart from India the evidence is sufficiently reliable to give reasonable maps, and the great extent of the inundations suggests that the climate would be considerably modified from that of today; no undoubted Sakmarian glacials occur there. In Southern continents and India, the Gondwana biogeographical province has made correlation with the northern continents controversial, but reasons are given for assuming that Gondwana glacial deposits were at least in part Sakmarian; the resultant maps show that the Gondwana land surfaces were but little reduced in area, and that the main glacials (except for India) lie within a belt between 40 S and 20 S. Present lack of knowledge of Sakmarian conditions in Antarctica makes reconstructions of climatic belts too hazardous for possible use in enunciating or checking hypotheses of continental drift and polar wandering.     

Autoassociation, a new geological tool

Autoassociation is a computer method of comparing a sequence of nonnumeric elements, e.g., of rock types. The sequence is slid past a replicate of itself. At each position of overlap the number of matching elements is noted and statistics of goodness-of-match are computed. The method allows several properties to be coded at each position in the sequence. It also allows unknown, missing, or not applicable elements. Reverse matches also are performed, i.e., with the duplicate sequences reversed in direction. Autoassociation is used to detect partial repetitions in stratigraphic sequences and to compare regressive and transgressive phases of cyclothems.     

Contact strain and folding instability of a multilayered body under compression

The contact strain which develops in a host rock during compression-folding of a more competent layer is treated mathematically and demonstrated by tests on composite models of rubber sheets and blocks with different rigidities.The contact strain is found to be negligible outside a zone about one initial wavelength wide on either side of the folded sheet. This theoretical conclusion based upon the contact deformation resulting from the initial small-amplitude buckles is also, according to the experimental tests, valid for rather strong buckling.Second-order folding of a thin competent layer laying within the contact zone of a thicker buckled competent layer is demonstrated by experimental tests.Considerations of the stresses connected with the contact strain and the stress distribution in the buckling competent layer itself give a simple expression for the initial stable wavelength which develops in response to compression parallel to the layering.The strain distribution in folded multilayers consisting of a set of thin competent sheets evenly spaced in an uniform less competent body is considered theoretically.In such multilayers the stable initial wavelength as developed during compression will, according to the theory, increase somewhat with decreasing spacing between the competent layers if all other conditions are equal. If the spacing is close enough (the limit depends upon the relative mechanical properties of the two substances) the multilayer will buckle as an unit in the sense that one half-wave covers the whole length of the body. This agrees with compression tests on multilayered rubber blocks.In the last two sections of the paper a theory of viscous buckling of thick layers is developed both for the case of a single layer enclosed in a large uniform body and for the case of a multilayer of alternating competent and incompetent layers. In this theory shear parallel to layering plays an important part. For a single embedded layer the thick-layer model gives a little smaller wavelength/thickness ratio than the simple but less realistic thin-layer model. For multilayers strain parallel to layering becomes very significant, particularly when the spacing between the competent layers is small, and the thick-layer model differs considerably from the simpler thin-layer model.A theory of buckling of a multilayer withn alternating competent-incompetent layers sandwiched between two very thick uniform bodies is also developed.