湖南石门雄黄矿床流体包裹体地球化学特征

石门超大型雄黄矿床流体包裹体丰富。包裹体液相成分中富Ｎａ＋、Ｃｌ－和Ｋ＋、ＳＯ２－４，气相成分中Ｈ２Ｏ占绝对优势，少量ＣＯ２，成矿流体化学类型属Ｃｌ ＳＯ４ Ｎａ Ｋ型水。雄黄、雌黄形成于低温（１８０～９０℃）、低压（２０～５ＭＰａ）、浅成（１７５～７００ｍ）、弱酸性（ｐＨ：４．６７、４．４３）和弱还原（Ｅｈ：－０．２６５Ｖ）条件。流体包裹体氢氧同位素研究表明，成矿流体主要为古大气降水，并混有盆地建造水，大气降水下渗、循环、加热、淋滤形成了中－低盐度［ｗ（ＮａＣｌ）：１６．０３％～４．２７％］，中等密度（０．８６３～１．０６５ｇ／ｃｍ３），含矿地下热水。     

川东南脉状萤石－重晶石矿床流体包裹体研究

川东南脉状萤石──重晶石矿床主要产于下奥陶统碳酸盐岩中，其成矿与岩浆活动无明显联系．成矿温度较低，成矿流体富含ＮａＣｌ和Ｈ＿２Ｏ，ＣＯ＿２和ＣＨ＿４的含量较低，Ｎ＿２，Ｏ＿２及Ｈ＿２的含量甚微。成矿介质水主要来源于地层水（如封存的海水、盆地压实脱水等）及大气降水，成矿温度、δ￣Ｄ值、盐度、Ｎａ￣＋／Ｋ￣＋比值以及矿石中有机包裹体的在在均表明本区萤石和重晶石的成矿流体类似于密西西比河谷型矿床的成矿热卤水，其形成与介质水溶滤本区寒武系蒸发岩有关。     

钱塘江流域的地球化学质量平衡研究

从地球化学角度出发，对钱塘江流域的物质平衡关系及起控制作用的化学风化反应进行了探讨和计算。结果表明，降雨提供了河水中大部分的Ｋ~＋、Ｎａ~＋和ＳＯ~２－＿４。另外，灰岩地区碳酸钙的溶解反应提供了河水中大部分的Ｃａ~２＋和ＨＣＯ~－＿３，硅酸盐岩地区钠长石和黑云母生成高岭石的风化反应提供了剩余的Ｋ~＋、Ｎａ~＋、Ｈ＿４ＳｉＯ＿４和大部分的Ｍｇ~２＋及少量的ＨＣＯ~－＿３。石膏和白云石的风化反应控制了ＳＯ~２－＿４和Ｍｇ~２＋的平衡，其中碳酸钙的溶解反应占主导地位。流域的化学侵蚀率和机械剥蚀率分别为０．０２２和０．０７１（ｋｇ·ｍ－２·ａ－１），碳酸盐岩区的物质流出量是硅酸盐岩区的２倍。     

花岗岩－KBF＿4－Na＿2MoO＿4体系的实验结果

花岗岩－ＫＢＦ＿４－Ｎａ＿２ＭｏＯ＿４体系的实验结果朱永峰（北京大学地质学系，１００８７１）常压下花岗岩－ＫＢＦ＿４－Ｎａ＿２ＭｏＯ＿４体系在１２５０℃条件下呈均匀熔体状态，成矿元素Ｍｏ及其它元素（如Ｆ，Ｃｌ，Ｈ＿２Ｏ及变网离子Ｃａ，Ｎａ，Ｋ，Ｍｇ等...     

色层分离－端视电感耦合等离子体发射光谱法测定高纯氧化铕中稀土杂质元素

对Ｐ５０７萃淋树脂分离稀土元素的条件进行了实验，拟定了以Ｐ５０７萃淋树脂为固定相，ＨＣｌ为流动相分离４Ｎ级荧光材料Ｅｕ＿２Ｏ＿３中１４种稀土杂质元素的流程，使被测杂质与基体Ｅｕ＿２Ｏ＿３达到了较好的分离；再用阳离子交换树脂分离被测液中非稀土杂质元素。选择了端视ＩＣＰ－ＡＥＳ测量稀土杂质元素的最佳条件。称样量５０ｍｇ时各杂质组分的测定下限（ｕｇ／ｇ）为：ＣｅＯ＿２、Ｐｒ＿６Ｏ＿（１１）、Ｎｄ＿２Ｏ＿３、Ｓｍ＿２Ｏ＿３、Ｔｂ＿４Ｏ＿７、Ｈｏ＿２Ｏ＿３、Ｅｒ＿２Ｏ＿３，Ｔｍ＿２Ｏ＿３、Ｌｕ＿２Ｏ＿３０．４，Ｌａ＿２Ｏ＿３、Ｇｄ＿２Ｏ＿３、０．２，Ｄｙ＿２Ｏ＿３、Ｙ＿２Ｏ＿３０．０４，Ｙｂ＿２Ｏ＿３０．０２。６次取样分析，各杂质组分加入量为１０ｕｇ／ｇ（ＣｅＯ＿２为２ｕｇ／ｇ），加入回收率在８４％～１１２％；ＲＳＤ＜１３％。方法可用于纯度在９９．９９％～９９．９９９５％Ｅｕ＿２Ｏ＿３中１４种稀土杂质元素的测定。     

浅议临澧县白土坡玻屑凝灰岩的岩石学特征

临澧县白土坡玻屑凝灰岩（或半固结火山灰）赋存在第四系下更新统，层状或似层状，岩石松散，镜下具典型的玻屑凝灰结构。主要由流纹质火山玻屑，少量斜长石、石英及黑云母晶屑以及粘上矿物等组成。流纹质火山玻璃的电子探针分析平均值（％）：ＳｉＯ＿２７４．９７、Ａｌ＿２Ｏ＿３１４．０４６、ＣａＯ０．３２６、ＫｚＯ６．９３３、Ｎａ＿２Ｏ２．５３６、ＦｅＯ０．５１，总量９９．５２。     

锇粉中杂质元素分析方法研究

利用ＩＣＰ＿ＭＳ技术建立了锇粉中痕量杂质元素的分析方法。在浓ＨＮＯ３介质中，锇以ＯｓＯ４形式挥发除去，分离锇基体后，可直接测定的痕量元素达５０余种。取样量０．１ｇ，测定限为０．２～２４６ｎｇ／ｇ，可实现质量分数ｗ（Ｏｓ）为９９．９９９９％锇粉中杂质元素测定。结合ＩＣＰ＿ＡＥＳ测定Ｋ、Ｎａ、Ｃａ、Ｍｇ、Ａｌ、Ｆｅ、Ｓｉ和Ｐ，可实现锇粉原料及产品的纯度分析。     

吉林小西南岔金铜矿床流体包裹体及成矿作用研究

该矿床流体包裹体丰富，为２相气液、１相液体、少数含子晶多相和含液态ＣＯ＿２三相包裹体。包裹体液相中富Ｎａ￣＋、Ｃｌ￣－和ＳＯ，气相中Ｈ＿２Ｏ占优势，ＣＯ＿２次之。属ＮａＣｌ－Ｈ＿２Ｏ体系。包裹体同位素分析表明，成矿流体为岩浆水和大气降水的混合流体。在温度高于３６０～４００℃的中性—弱酸性热流体中，Ａｕ和Ｃｕ的络合物呈迁移状态，在温度低的弱酸—酸性的较还原环境下，围岩产生广泛的石英－绢云母化，导致Ａｕ、Ｃｕ络合物分解，沉淀出大量Ａｕ和Ｃｕ。     

镍与邻羧基苯基重氮氨基偶氮苯的显色反应及其应用

在乳化剂ＯＰ存在下，于ｐＨ９．７～１０．０的Ｎａ＿２Ｂ＿４Ｏ＿７－ＮａＯＨ缓冲介质中，Ｎｉ￣（２＋）与邻羧基苯基重氮氨基偶氮苯（ＣＤＡＡ）形成组成比为１：２的稳定的红色配合物，其吸收峰波长在５４０ｎｍ，对比度△λ＝１２６ｎｍ，表观摩尔吸光系数为１．９９×１０￣５Ｌ·ｍｏｌ￣（－１）·ｃｍ￣（－１），室温下２０ｍｉｎ内显色反应完全，有色配合物至少稳定１２ｈ。方法线性范围是０～０．２０μｇ／ｍｌＮｉ，检测限为０．０００４μｇ／ｍｌ。在掩蔽剂存在下，方法用于矿样和低合金钢的分析，结果与标准值相符，其ＲＳＤ（ｎ＝６）分别为１．８％和３．１％，标准加入回收率为９５．０％～１０１．２％。     

新矿物硒锑矿形成的地质地球化学环境

在我国贵州某低中温热卤水改造层控铀－汞矿床和湖南某古岩溶热造铀矿床中几乎同时发现了新矿物─—硒锑矿（Ｓｂ＿２Ｓｅ＿３）．该矿物的单晶呈细板条状、针状，集合体呈放射状、禾束状。确定硒锑矿形成于１３０─１６０℃富含Ｃａ￣（２＋），Ｎａ￣＋，Ｍｇ￣（２＋），ＳＯ＿４￣２－，ＨＣＯ＿３￣－的弱酸性─弱碱性热液，伴生一套典型的低中温热液矿物组合和围岩蚀变。硒锑矿是低中温热液标型矿物     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Quaternary stresses revealed by calcite twinning inversion: insights from observations in the Savonnières underground quarry (eastern France)

Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ₁ roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).     

HYDROGEOLOGY

正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level     

METAMORPHIC PETROLOGY

正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),     

SERIALS

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GEOPHYSICAL EXPLORATION

正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-     

QUATERNARY GEOLOGY & GEOMORPHOLOGY

正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-     

PETROLEUM GEOLOGY

正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)     

GEOCHEMISTRY

正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861