A study of the seasonal migration of ITCZ and the quasi-periodic oscillations in a simple monsoon system using an energy balance model

Summary A zonally averaged global energy balance model with feedback mechanisms was constructed to simulate (i) the poleward limits of ITCZ over the continent and over the ocean and (ii) a simple monsoon system as a result of differential heating between the continent and the ocean. Three numerical experiments were performed with lower boundary as (1) global continent, (2) global ocean and (3) continent-ocean, with freezing latitudes near the poles. Over the continent, midlatitude deserts were found and the ITCZ migrates 25° north and south with seasons. Over a global swamp ocean results do not show migration of ITCZ with time but once the ocean currents are introduced the ITCZ migrates 5° north and south with seasons. It was found that the seasonal migration of ITCZ strongly depends on the meridional distribution of the surface temperature. It was also found that continent influences the location of the oceanic ITCZ. In the tropics northward progression of quasi-periodic oscillations called events are found during the pre- and post-monsoon periods with a period of 8 to 15 days. This result is consistent with the observed quasi-periodic oscillations in the tropical region. Northward propagation of the surface temperature perturbation appears to cause changes in the sensible heat flux which in turn causes perturbations in vertical velocity and latent heat flux fields.List of Symbols vertical average - ₀ zonal average - vertical mean of the zonal average - _0s zonal average at the surface - _0a zonal average at 500 mb level - latitude We now define the various symbols used in the model rate of atmospheric heating due to convective cloud formation (K/sec) - dp/dt (N/m²/sec) - density - potential temperature (K) - rate of rotation of the earth (rad/sec) - empirical constant - humidity mixing ratio - ^* saturated humidity mixing ratio - opacity of the atmosphere - ₁,₂ factors for downward and upward effective black body long wave radiation from the atmosphere - Stefan-Boltzmann constant - emissivity of the surface - _D subsurface temperature (K) - a specific volume - _0xs ,_0ys eastward and northward components of surface frictional stress - ^* vertical velocity at the top of the boundary layer (N/m²/sec) - P Thickness of the boundary layer (mb) - nondimensional function of pressure - P pressure - P _a pressure of the model atmosphere (N/m²) - P _s pressure at the surface (N/m²) - t time (sec) - U eastward wind speed (m/sec) - V northward wind speed (m/sec) - surface water availability - T absolute temperature (K) - heat addition due to water phase changes - g acceleration due to gravity (m²/sec) - a radius of the earth (m) - R gas constant for dry air (J/Kg/K) - C _p specific heat of air at constant pressure (J/Kg/K) - k R/C _p - L latent heat of condensation (J/Kg) - f coriolis parameter (rad/sec) - H _s H _0s ⁽¹⁾ +H _0s ⁽²⁾ +H _0s ⁽³⁾ +H _0s ⁽⁴⁾ +H _0s ⁽⁵⁾ (J/m²/Sec)=sum of the rates of vertical heat fluxes per unit surface area, directed toward the surface - H _a H _0a ⁽¹⁾ +H _0a ⁽²⁾ +H _0a ⁽³⁾ +H _0a ⁽⁴⁾ (J/m²/Sec)=sum of the rates of heat additions to the atmospheric column per unit horizontal area by all processes - H _0s ⁽¹⁾ ,H _0a ⁽¹⁾ heat flux due to short wave radiation - H _0s ⁽²⁾ ,H _0a ⁽²⁾ heat flux due to long wave radiation - H _0s ⁽³⁾ ,H _0a ⁽³⁾ heat flux due to small scale convection - H _0s ⁽⁴⁾ heat flux due to evaporation - H _0a ⁽⁴⁾ heat flux due to condensation - H _0s ⁽⁵⁾ heat flux due to subsurface conduction and convection - e ^* saturation vapor pressure - R solar constant (W/m²) - r _a albedo of the atmosphere - r _s albedo of the surface - b ₂ empirical constant (J/m²/sec) - c ₂ empirical constant (J/m²/sec) - e ₂ nondimensional empirical constant - f ₂ empirical constant (J/m₂/sec) - factor proportional to the conductive capacity of the surface medium - a _s constant used in Sellers model - b _s positive constant of proportionality used in the Sellers model (kg m²/J/sec²) - K _HT coefficient for eddy diffusivity of heat (m²/sec) - K _HE exchange coefficient for water vapor (m²/sec) - h depth of the water column (m) - z height (m) - V _0ws meridional component of surface current (m/sec) - n cloud amount - G _0,n long wave radiation form the atmosphere for cloud amount n (W/m²) - B ₀ long wave radiation from the surface (W/m²) - S _0,n short wave radiation from the atmosphere for cloud amount n (W/m²) - A _n albedo factor for a cloud amount n - R _f1 large scale rainfall (mm/day) - R _f2 small scale rainfall (mm/day) With 22 Figures     

A review of flux-profile relationships

Flux-profile relationships in the constant flux layer are reviewed. The preferred relationships are found to be those of Dyer and Hicks (1970), namely, _H = _W =(1–16(z/L))^–1/2, _M =(1–16(z/L))^–1/4 for the unstable region, and _H = _W = _M = 1+5(z/L) for the stable region.The carefully determined results of Businger et al. (1971) remain a difficulty which calls for considerable clarification.     

Analytical solutions for the Ekman layer

The PBL equation that governs the transition from the constant-stress surface layer to the geostrophic wind in a neutrally stratified atmosphere for which the eddy viscosityK(z) is assumed to vary smoothly from the surface-layer value U _*z (0.4,U _*=friction velocity,z=elevation) to the geostrophic asymptoteK _GU _*d forzd is solved through an expansion in fd/U _*1 (f=Coriolis parameter). The resulting solution is separated into Ekman's constant-K solution an inner component that reduces to the classical logarithmic form forzd and isO() relative to the Ekman component forzd. The approximationKU _*d is supported by the solution of Nee and Kovasznay's phenomenological transport equation forK(z), which yieldsK–U _*d exp(–z/d), where is an empirical constant for which observation implies, 1. The parametersA andB in Kazanskii and Monin's similarity relation forG/U _* (G=geostrophic velocity) are determined as functions of . The predicted values ofG/U _* and the turning angle are in agreement with the observed values for the Leipzig wind profile. The predicted value ofB based on the assumption of asymptotically constantK is 4.5, while that based on the Nee-Kovasznay model is 5.1; these compare with the observed value of 4.7 for the Leipzig profile. A thermal wind correction, an asymptotic solution for arbitraryK(z) and 1, and an exact (unrestricted ) solution forK(z)=U _*d[1–exp(–z/d)] are developed in appendices.     

Turbulence Reynolds number and the turbulent kinetic energy balance in the atmospheric surface layer

The relation between the turbulence Reynolds numberR and a Reynolds numberz* based on the friction velocity and height from the ground is established using direct measurements of the r.m.s. longitudinal velocity and turbulent energy dissipation in the atmospheric surface layer. Measurements of the relative magnitude of components of the turbulent kinetic energy budget in the stability range 0 >z/L 0.4 indicate that local balance between production and dissipation is maintained. Approximate expressions, in terms of readily measured micrometeorological quantities, are proposed for the Taylor microscale and the Kolmogorov length scale .     

Airflow above changes in surface heat flux,temperature and roughness; an extension to include the stable case

A numerical model of airflow above changes in surface roughness and thermal conditions is extended to include cases with stable thermal stratification within the internal boundary-layer. The model uses a mixing-length approach with empirical forms for M and H.Results are presented for some basic cases and an attempt is then made to compare results given by the model with the experimental results of Rider, Philip and Bradley. Tolerable agreement is achieved. The importance of roughness change and thermal stability effects in the diffusion of heat and moisture near a leading edge is emphasised.Notation A Refers to Taylor (1970) - B Businger-Dyer constant (= 16.0) in forms for _M and _H - C Constant in form for in stable case - c _p Specific heat at constant pressure - E Scaled absolute humidity - g Acceleration due to gravity - H Upward vertical heat flux - H ₀, H ₁ Surface heat fluxes for x <0, x0 - H _E Upward latent heat flux - k Von Kármán's constant (= 0.4) - K _H K _W Eddy transfer coefficients for heat and water vapour - L Monin-Obukhov length - L _H Latent heat of evaporation for water - m Ratio of roughness lengths ( = z ₁/z ₀) - RPB Refers to Rider et al. (1964) - RL* Non-dimensional parameter (see Equations (9), (20a), (22a), (24a)) - R* Net radiation less ground heat flux (see Equations (15), (16)) - T Scaled temperature - T ₁ Downstream scaled surface temperature - u ₀ u ₁(x) Surface friction velocities for x <0, x0 - U, W Horizontal and vertical mean velocities - x, z Horizontal and vertical co-ordinates - Z _i Local roughness length - z ₀, z _i Roughness lengths for x < 0, x 0 - Temperature - ₀, ₁ Surface temperatures for x<0, x0 - _E Non-dimensional absolute humidity gradient - _H Non-dimensional temperature gradient of heat flux - _M Non-dimensional wind shear - = _M = _H = _E an assumption used in stable conditions - Air density - Absolute humidity - _w Density of water - Kinematic shear stress - Logarithmic height scale (= ln(z+z ₁)/z ₁)     

Boundary-layer parameterizations for applied dispersion modeling over urban areas

Many applied dispersion models require the knowledge of boundary-layer parameters such as sensible heat flux,Q _H , friction velocity,u _*, and turbulent energy components, _w and _v . Formulas are suggested for calculating these parameters over a wide variety of types of ground surfaces, based on simple observations of wind speed near the ground and fractional cloud cover, and specification of constants such as roughness length, albedo, and soil moisture availability. Observations ofu _*,Q _H , _w , and _v during field experiments in St. Louis and Indianapolis are used to test the formulas for urban sites. Relative errors of about ±20% in the predictions are seen to occur whenu _*,Q _H , _w , and _v are large. However, when these quantities are small (e.g.,u _* < 0.2 m/s), the errors in the predictions are as large as the mean value of the quantity itself.In addition, it is concluded from studies of available field data and theories that the magnitude of _w is not well-known at elevations above about 100m during the late afternoon and night. Some simple parameterizations for _w . are suggested that are consistent with the observed steady decrease in ground-level concentration in the afternoon and the sudden increase in concentration that can occur a few hours after sunset due to wind shears associated with a low-level jet, for continuous plumes emitted from moderate to tall stacks.     

High resolution spectral features of a series of aromatic hydrocarbons and BrO: Potential interferences in atmospheric OH-measurements

Naphthalene (C₁₀H₈), several other hydrocarbons, mostly derivates of naphthalene, and bromine oxide (BrO) were analyzed for narrow band (0.01 nm) absorption lines in the wavelength range between 307.7 and 308.3 nm to study their potential impact on OH radical measurements by differential absorption spectroscopy.Only naphthalene showed narrow band absorption lines in this wavelength region. From nine naphthalene lines the differential absorption cross-section was determined.The strongest naphthalene line at 308.002 nm is close to the Q ₁(2) OH line, but about a factor of 200 weaker (=(65.2±15.3)×10^-20 cm²/molec). The corresponding detection limit for naphthalene is about 15 ppt. We re-evaluated some spectra of our OH measurement campaign in July 1987 with respect to naphthalene and obtained an upper limit of 30 ppt for its concentration.BrO was recorded in the larger wavelength interval between 307.7 and 308.7 nm. Structured absorptions were only observed at wavelengths above 308.2 nm and no significant structures were found in the vicinity of the Q ₁(2) and Q ₁(3) OH lines.     

The influence of surface cover and climate on energy partitioning and evaporation in a subarctic wetland

Energy partitioning and evaporation were measured over three wetland surfaces in a subarctic coastal marsh during pre-growing and growing periods. These surfaces included an alder/willow woodland, a sedge marsh and a raised backshore sedge meadow. A combination model analysis was used to assess the relative importance of surface resistance and meteorological conditions on the magnitude of the Bowen ratio, , during the growing period.Overall, the three surfaces experienced important site-to-site and seasonal differences in and evaporation, Q _E. During the non-foliated period, Q _E was largest and was smallest for the open water marsh, while the dry backshore site experienced the smallest Q _E and largest . The non-foliated woodland assumed intermediate values of and Q _E. After the vegetation covers were established, the woodland assumed the smallest and largest Q _E flux. It was also found that at the marsh site increased with the presence of a vegetation cover.Wind direction was always an important factor in determining Q _E and at all sites. was substantially larger and Q _E was smaller for onshore winds (i.e., originating from James Bay) than for offshore winds. The combination model analysis showed that canopy resistance at all sites was largest during warm offshore winds, which were associated with large saturation deficits. However, the effect of increased canopy resistance on during offshore winds was offset by a large climatological resistance, resulting in small values and large Q _E. When winds originated from James Bay, canopy resistance was smaller than for offshore winds, but the climatological resistance also was much smaller, resulting in larger and small Q _E. The results have important implications for changes in land cover and climate on the regional water balance.     

Reactions of alkoxy radicals under atmospheric conditions: The relative importance of decomposition versus reaction with O2

The reactions of alkoxy radicals determine to a large extent the products formed during the atmospheric degradations of emitted organic compounds. Experimental data concerning the decompositions, 1,5-H shift isomerizations and reactions with O₂ of several classes of alkoxy radicals are inconsistent with literature estimations of their absolute or relative rate constants. An alternative, although empirical, method for assessing the relative importance under atmospheric conditions of the reactions of alkoxy radicals with O₂ versus decomposition was derived. This estimation method utilizes the differences in the heats of reaction, (H)=(H_{decomposition}–H_{O 2 reaction}), between these two reactions pathways. For (H)[22–0.5(H_{O 2 reaction})], alkoxy radical decomposition dominates over the reaction with O₂ at room temperature and atmospheric pressure of air, while for (H)[25-0.5(H_{O 2 reaction})], the O₂ reaction dominates over decomposition (where the units of H are in kcal mol^–1). The utility and shortcomings of this approach are discussed. It is concluded that further studies concerning the reactions of alkoxy radicals are needed.     

Experimental investigations into variations of ground-based inversions and comparisons with results of simple boundary-layer models

Meteorological data obtained from sensors mounted on a 300-m antenna mast, including wind components and temperature fluctuations together with high resolution profile measurements, were used to calculate quantities which describe the most important processes during the development and decay of ground-based inversions. The vertical distribution of air temperature during the developing phase of radiation inversions has been measured continuously and compared with an existing simple prognostic model. Free and forced convection conditions have been investigated for the inversion lifting phase by measuring the heat fluxes at the surface (H _s) and at the inversion base (H _i), the heating rate of the mixed layer (/z) _m , the friction velocity (u _*) and the entrainment rate (dh/dt). Comparisons between the directly measured entrainment rates and those calculated by models show good agreement. For nearly free convection conditions, the entrainment parameter (k = -H _i/H_s) has been determined to be about 0.25.     

The behaviour of aerosol optical depth during clear summer days in Athens,Greece

Summary The integral aerosol optical depths (k ) at the hour of 08:20 Local Standard Time (LST), are compared with those calculated previously at 11:20 and 14:20 LST, for clear days during summer in Athens over the period 1962–1988. The mean values at 08:20 LST were consistently lower than the values at 11:20 and 14:20 LST. The influence of the vertical wind profile on the values ofk was also investigated. A comparison was made of the wind profiles at 02:00 and 14:00 LST, for days in which the 11:20 and 14:20 LST values ofk were 0.200 andk 0.350, respectively. The corresponding bulk wind shear s was also found for the period 1980–1988. The most significant results occurred with the first category of days. The resultant wind velocities from the surface to the 900 hPa level, in each hour were higher by 2–4 m·s^–1 with respect to the corresponding values for the second category. At 02:00 LST the bulk wind shear showed a considerable difference (1.8) between the two categories of days in the surface to 700 hPa layer at 02:00 LST. Finally, the associated weather conditions that appear to initiate a period of low values ofk (k 0.200) at 11:20 and 14:20 LST were examined for the period 1980–1988. Fifteen such cases were identified and it was found that they all occurred after the passage of weak cold fronts.With 6 Figures     

Estimation of the Monin-Obukhov similarity functions from a spectral model

From measured one-dimensional spectra of velocity and temperature variance, the universal functions of the Monin-Obukhov similarity theory are calculated for the range –2 z/L + 2. The calculations show good agreement with observations with the exception of a range –1 z/L 0 in which the function _m , i.e., the nondimensional mean shear, is overestimated. This overestimation is shown to be caused by neglecting the spectral divergence of a vertical transport of turbulent kinetic energy. The integral of the spectral divergence over the entire wave number space is suggested to be negligibly small in comparison with production and dissipation of turbulent kinetic energy.Notation a,b,c contants (see Equations (–4)) - C_i constants i=u, v, w, (see Equation (5) - k_me,k_mT peak wave numbers of 3-d moel spectra of turbulent kinetic energy and of temperature variance, respectively - k_mi peak wave numbers of 1-d spectra of velocity components i=u, v, w and of temperature fluctuations i= - k_sb, k_c characteristics wave numbers of energy-feeding by mechanical effects being modified by mean buoyancy, and of convective energy feeding, respectively - L Monin-Obukhov length - % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiiYdd9qrFfea0dXdf9vqai-hEir8Ve% ea0de9qq-hbrpepeea0db9q8as0-LqLs-Jirpepeea0-as0Fb9pgea% 0lrP0xe9Fve9Fve9qapdbaqaaeGacaGaaiaabeqaamaabaabcaGcba% Gabeivayaaraaaaa!3C5B!\[{\rm{\bar T}}\] difference of mean temperature and mean potential temperature - T* Monin-Obukhov temperature scale - velocity of mean flow in positive x-direction - u* friction velocity - u, v, w components of velocity fluctuations - z height above ground - von Kármanán constant - temperature fluctuation - _m nondimensional mean shear - _H nondimensional mean temperature gradient - nondimensional rate of lolecular dissipation of turbulent kinetic energy - _D nondimensional divergence of vertical transports of turbulent linetic energy     

Spectral Characteristics and Correction of Long-Term Eddy-Covariance Measurements Over Two Mixed Hardwood Forests in Non-Flat Terrain

We present turbulence spectra and cospectra derived from long-term eddy-covariancemeasurements (nearly 40,000 hourly data over three to four years) and the transferfunctions of closed-path infrared gas analyzers over two mixed hardwood forests inthe mid-western U.S.A. The measurement heights ranged from 1.3 to 2.1 times themean tree height, and peak vegetation area index (VAI) was 3.5 to 4.7; the topographyat both sites deviates from ideal flat terrain. The analysis follows the approach ofKaimal et al. (Quart. J. Roy. Meteorol. Soc. 98, 563–589, 1972) whose results were based upon 15 hours of measurements atthree heights in the Kansas experiment over flatter and smoother terrain. Both thespectral and cospectral constants and stability functions for normalizing and collapsingspectra and cospectra in the inertial subrange were found to be different from those ofKaimal et al. In unstable conditions, we found that an appropriate stabilityfunction for the non-dimensional dissipation of turbulent kinetic energy is of the form ₍₎ = (1 - b^-)^-1/4 - c^-, where representsthe non-dimensional stability parameter. In stable conditions, a non-linear functionG_xy() = 1 + b_xy^c _xy (c_xy < 1) was found to benecessary to collapse cospectra in the inertial subrange. The empirical cospectralmodels of Kaimal et al. were modified to fit the somewhat more (neutraland unstable) or less (stable) sharply peaked scalar cospectra observed over forestsusing the appropriate cospectral constants and non-linear stability functions. Theempirical coefficients in the stability functions and in the cospectral models varywith measurement height and seasonal changes in VAI. The seasonal differencesare generally larger at the Morgan Monroe State Forest site (greater peak VAI) andcloser to the canopy.The characteristics of transfer functions of the closed-path infrared gas analysersthrough long-tubes for CO₂ and water vapour fluxes were studied empirically. This was done by fitting the ratio between normalized cospectra of CO₂ or watervapour fluxes and those of sensible heat to the transfer function of a first-order sensor.The characteristic time constant for CO₂ is much smaller than that for water vapour. The time constant for water vapour increases greatly with aging tubes. Three methods were used to estimate the flux attenuations and corrections; from June through August, the attenuations of CO₂ fluxes are about 3–4% during the daytime and 6–10% at night on average. For the daytime latent heat flux (Q_E), the attenuations are foundto vary from less than 10% for newer tubes to over 20% for aged tubes. Correctionsto Q_E led to increases in the ratio (Q_H + Q_E)/(Q^* - Q_G) by about 0.05 to0.19 (Q_H is sensible heat flux, Q^* is net radiation and Q_G is soil heat flux),and thus are expected to have an important impact on the assessment of energy balanceclosure.     

A coupled ocean-atmosphere climate model: temperature versus salinity effects on the thermohaline circulation

A simple nonlinear three-box ocean model of the North Atlantic Ocean including the rudiments of eddy mixing, vertical stratification and thermohaline circulation is first presented. It is subject to uniform latitudinal differential heating, q, and net evaporation m _e , and includes a linear equation of state. Two quite different limiting steady-state solutions exist. The first has a warm saline surface water and a cold, low-salinity deep ocean; deep water is primarily formed in higher latitudes by the prevalence of differential heating. A second limiting solution consists of a warm saline deep ocean underlying a cool, low-salinity surface ocean; deep water is formed primarily in lower latitudes as a consequence of large differential evaporation. A coupled ocean-atmosphere model, in which the oceanic surface heat fluxes are determined internally but with differential evaporation at the ocean surface m _e remaining an external parameter, is next presented. The atmosphere component is a simple energy balance model that emphasizes the vertical fluxes of radiative, sensible and latent heat fluxes but does not include temperature-albedo feedback. Model response depends on the external parameters m _e and , controlling the magnitude of the thermohaline-driven circulation, and on the magnitudes of the eddy mixing coefficients and the solar constant. For small m _e , a steady-state solution corresponding to a cold fresh deep ocean is found, qualitatively similar to the modern ocean. For large m _e , a steady-state solution with a warm saline deep ocean occurs; this solution resembles conceptual models that have been proposed for the warm saline Cretaceous ocean. There exists an intermediate region of values of m _e for which the solutions are more complex. On the lower end of this region, both the cold fresh deep-ocean and warm saline deep-ocean circulations coexist as stable equilibria. On the upper end, the cold-deep ocean becomes unstable, manifesting oscillations with growing amplitude, and ultimately reaches the warm saline deep-ocean solution. In the neighborhood of a cusp on the , m _e plane, that is, for relatively small , more complex behaviour occurs, which has not yet been fully analyzed. The model response in the region of complexity is not sensitive to changes in the solar constant but is sensitive to the eddy mixing coefficients.     

Radiometrically determined skin temperature and scalar roughness to estimate surface heat flux part II: Performance of parameterized scalar roughness for the determination of sensible heat

Several formulations and proposals to determine the value of the radiometric scalar roughness for sensible heatz _0h,r are tested with respect to their performance in the estimation of the sensible heat flux by means of the profile equations derived from Monin-Obukhov similarity theory. The equations are applied to the data set of spatially averaged surface skin temperature and profiles of wind speed and temperature observed in a pasture field during a growing season. The use of a physical model developed for a dense canopy to estimate scalar roughness for sensible heatz _0h,r produced sensible heat fluxH with a correlation coefficientr=0.884, the ratio of means being H _s /H=1.19 in a comparison with reference values ofH _s . In comparison, a proposal for a fixed value ofz _0h yieldedr=0.887, H _s /H=0.879. In both cases, the validity ofz _0h =z _0h,r was assumed. All expressions derived to estimatez _0h,r from a multiple linear regression with such predictors as leaf area index, solar radiation and the ratio of solar radiation to extraterrestrial radiation, were found to produce a better result, withr better than 0.90 and H _s /H around 1.0. However, when the constantsc andf of a linear regression equationHs=cH+f are used to evaluate the equations, a marked difference in performance of each formulation appeared. In general, equations with smaller numbers of predictors tend to produce a biased result, i.e., an overestimation ofH at largeH _s . These values ofH are used in conjunction with the energy balance equation to derive values of the latent heat fluxLE, which are shown to be in good agreement with the reference valuesLE _s , withr greater than 0.97.     

Effect of finite sampling on atmospheric spectra

The effect of a finite averaging time on variances is well known, but its effect on power spectra is less clearly understood. We present numerical solutions for the spectral distortion arising from sampling over a finite time interval T and show that the commonly used filter function (1 – sinc²f T), valid for variances, is a reasonable approximation for power spectra only when T 10 _m , where f is the cyclic frequency, and _m is the dominant time scale of the process. Our results exhibit an increasingly steeper low-frequency roll-off as T decreases relative to _m , indicating that the measured spectrum is subject to a greater suppression of the lower frequencies (f > 1/T) than predicted by (1 – sinc²f T). This suppression is, in a sense, compensated by an overestimation of spectral estimates in the frequency range f 1/T.     

Numerical modeling of the nocturnal urban boundary layer

A numerical case study with a second-order turbulence closure model is proposed to study the role of urban canopy layer (UCL) for the formation of the nocturnal urban boundary layer (UBL). The turbulent diffusion coefficient was determined from an algebraic stress model. The concept of urban building surface area density is proposed to represent the UCL. Calculated results were also compared with field observation data. The height of the elevated inversion above an urban center was simulated and found to be approximately twice the average building height. The turbulent kinetic energy k, energy dissipation rate , and turbulence intensities u ² and w ² increase rapidly at the upwind edge of the urban area. The Reynolds stress uw displayed a nearly uniform profile inside the UBL, and the vertical sensible heat flux w had a negative value at the inversion base height. This indicates that the downward transport of sensible heat from the inversion base may play an important role in the formation of the nocturnal UBL.     

Trace gas exchange at the air/water interface: Measurements of mass accommodation coefficients

A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO₃ (0.01), N₂O₅ (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.     

Size-Resolved Characterisation of Soluble Ions in the Particles in the Tropospheric Plume of Masaya Volcano, Nicaragua: Origins and Plume Processing

We present the first application of a multi-stage impactor to study volcanic particle emissions to the troposphere from Masaya volcano, Nicaragua. Concentrations of soluble SO₄ ^2–,Cl^–, F^–, NO₃ ^–, K⁺, Na⁺,NH₄ ⁺, Ca²⁺ and Mg²⁺ were determined in 11 size bins from 0.07 m to >25.5 m. The near-source size distributions showed major modes at 0.5m (SO₄ ^2–, H⁺,NH₄ ⁺); 0.2 m and 5.0 m (Cl^–) and 2.0–5.0 m(F^–). K⁺ and Na⁺ mirrored the SO₄ ^2– size-resolvedconcentrations closely, suggesting that these were transported primarily asK₂SO₄ and Na₂SO₄ in acidic solution, while Mg²⁺ andCa²⁺ presented modes in both <1 m and >1 m particles. Changes in relative humidity were studied by comparing daytime (transparent plume) and night-time (condensed plume) results. Enhanced particle growth rates were observed in the night-time plume as well as preferential scavenging of soluble gases, such as HCl, by condensed water. Neutralisation of the acidic aerosol by background ammonia was observed at the crater rim and to a greater extent approximately 15 km downwind of the active crater. We report measurements of re-suspended near-source volcanic dust, which may form a component of the plume downwind. Elevated levels ofSO₄ ^2–, Cl^–, F^–,H⁺, Na⁺, K⁺ and Mg²⁺ were observed around the 10 m particle diameter in this dust. The volcanic SO₄ ^2– flux leaving the craterwas 0.07 kg s^–1.     

Energy flux partitioning over the Amazon forest

The present study involved determination of the experimental energy receipt partitioning over the tropical Amazon forest. Diurnal variation of net radiation (Q ^*), sensible heat flux (Q _H) and latent heat flux (Q _E) is presented. The daytimeQ _E is in phase withQ ^* and it is always an important term in the energy balance. The daily averagedQ _E is 59 to 100% of the dailyQ ^* whereasQ _H is 5 to 28% at the Amazon forest site (2° 57 S; 59° 57 W) for the sample periods. The results present evidence thatQ _E over the Amazon forest is greater thanQ ^* in the afternoon hours. The role of sensible heat advection in maintaining largeQ _E over the forest surface is discussed. Hourly Bowen ratio () values for two campaigns of the Amazon forest micrometeorological experiment are presented. During daylight hours, the differences in are not significant, and exhibit a systematic pattern. The only time that the variation in Bowen ratio increased significantly was at sunrise and sunset when the thermal structure of the air was changing from a strong inversion to lapse and vice versa. The diurnal values changed from –3.50 to 0.85. The mean hourly calculated from values from 07.00 to 16.00 h, varied from 0.05 to 0.85.Diese Studie beschäftigt sich mit der Aufteilung der empfangenen Energie über dem tropischen Amazonasurwald. Es wird der Tagesgang der Strahlungsbilanz (Q ^*), des fühlbaren (Q _H) und des latenten Wärmestromes (Q _E) vorgestellt. Während der Tagesstunden istQ _E in Phase mitQ ^* und ist immer ein wichtiger Term der Energiebilanz. Das Tagesmittel vonQ _E beträgt 59 bis 100%,Q _H 5 bis 28% des täglichenQ ^* an den Meßtagen bei der Amazonasurwaldstation (2° 57 S; 59° 57 W). Die Ergebnisse legen nahe, daß in den NachmittagsstundenQ _E über dem Amazonasurwald größer ist alsQ ^*. Die Rolle der Advektion von fühlbarer Wärme zur Aufrechterhaltung des großenQ _E über der Waldoberfläche wird diskutiert. Für zwei Meßkampagnen wurden die stündlichen Bowenverhältnisse () vorgestellt. Während der Tagesstunden ergaben sich keine signifikanten Änderungen von, während bei Sonnenaufgang und -untergang, wenn der thermische Aufbau der Luft von einer starken Inversion zu neutral und umgekehrt wechselt, die Unterschiede deutlich anstiegen. Die Tageswerte von lagen zwischen –3.50 und 0.85. Die Stundenmittel von 7.00 bis 16.00 Uhr schwankten zwischen 0.05 und 0.85.

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With 3 Figures