Electrochemical evaluation of dissolution characteristics of Al-based sacrificial anodes in seawater

The surface dissolution characteristics of Al-based sacrificial anodes in seawater have never been expressed numerically except in words such as uniform dissolution, non-uniform dissolution, serious localized dissolution, etc. An electrochemical method was developed in our laboratory to evaluate the above mentioned characteristics quantitatively. The Al anode samples are polarized to −1000 mv (vs. Ag/AgCl reference electrode) in seawater at 25±1°C, and anodic current-time curves are recorded simultaneously. Then the coulometric density was calculated with the aid of a planimeter. By comparing the coulometric densities of these samples, the surface dissolution characteristics of anodes can be evaluated quantitatively. Contribution No. 1447 from Institute of Oceanology, Academia Sinica     

贝塞尔曲线在虚拟森林景观单树几何模型构建中的应用

虚拟景观模型的生成,需要对实际景观进行抽象和简化。树几何模型和数字高程模型(DEM)是构成虚拟森林景观的两大要素。而树几何模型的构建又是林业GIS三维可视化的基础。在树几何建模中,树干及树枝形状的可视化表达具有突出意义。由于实际树种的复杂性,在计算机中建树模型,通常采用基于过程建模的方式,而这将面临用户如何对模型进行交互式控制的问题：参数太少,不足以描述树形态特征,而参数太多,则模型难以生成和理解。为了解决这个问题,我们引进贝塞尔(Bezier)曲线这种基于控制点的自由曲线来描述树木中的树干以及树枝形状,利用对曲线控制点的变动来控制曲线的形状,进而生成形态各异的树形状,对此,我们基于ActiveX技术生成Bezier曲线控件。结果表明,该方法能够表示多种形状的树干与树枝,具有操作简捷、计算速度快,可视化效果良好的优点。     

Study on Al-Zn-In Alloy as Sacrificial Anodes in Seawater Environment

Electrochemical properties including conventional electrochemical properties: open circuit potential, polarization potential, electrochemical capacity, morphology of surface dissolution, and the initial polarization properties of Al-Zn-In-Mg-Ti and Al-Zn-In-Si sacrificial anodes are investigated in the sea. The curves of anode output current and work potential with time, the impact of area ratio of cathode to anode on anode output current is discussed, and the initial polarization properties are investigated with cyclic voltammetry(CV) finally. The results show that for the two anodes, the current efficiency got in the sea environment is higher than the data of the 4-day-accelerated test in laboratory and the corrosion morphology is more uniform in the sea. With the same exposed area, the current efficiency of Al-Zn-In-Mg-Ti anode is higher than that of Al-Zn-In-Si in the sea. For both anodes, the current efficiency becomes larger with the increase of the area ratio of cathode to anode. The two anodes can output larger current in strong polarization state. The situation is consistent with the results that small area anode released higher current in the sea trial. The difference rests with that Al-Zn-In-Mg-Ti anode output far greater current than that of the Al-Zn-In-Si under the same polarization potential. The initial polarization property of the Al-Zn-In-Mg-Ti anode is better than Al-Zn-In-Si anode.     

Fracture analysis for torsion problems of a gravity platform column with cracks under wind load

Ocean platforms are subjected to a variety of environment loads, such as those from winds, waves, currents, etc. In this study, the torsion problems of a gravity platform column with cracks under wind load were investigated. The column was assumed to be a composite cylinder. Therefore the torsion fracture problem of a composite cylinder was considered, and new boundary integral equations for the Saint-Venant torsion problem of a composite cylinder with curvilinear cracks were derived. The problem was reduced to solving the boundary integral equations on every boundary. By using the new boundary element method, the torsion problem of the gravity platform column with a straight crack under various wind loads was calculated. The obtained results were compared with those obtained for a torsion problem of the same column without cracks to prove the applicability of the present method. The comparison showed that the detrimental effect of cracks in a column should be considered in marine engineering.     

Electron transfer from sulfate-reducing becteria biofilm promoted by reduced graphene sheets

Reduced graphene sheets (RGSs) mediate electron transfer between sulfate-reducing bacteria (SRB) and solid electrodes, and promote the development of microbial fuel cells (MFC). We have investigated RSG-promoted electron transfer between SRB and a glassy carbon (GC) electrode. The RGSs were produced at high yield by a chemical sequence involving graphite oxidation, ultrasonic exfoliation of nanosheets, and N2H4 reduction. Cyclic voltammetric testing showed that the characteristic anodic peaks (around 0.3 V) might arise from the combination of bacterial membrane surface cytochrome c3 and the metabolic products of SRB. After 6 d, another anodic wave gradually increased to a maximum current peak and a third anodic signal became visible at around 0 V. The enhancements of two characteristic anodic peaks suggest that RSGs mediate electron-transfer kinetics between bacteria and the solid electrode. Manipulation of these recently-discovered electron-transport mechanisms will lead to significant advances in MFC engineering.     

Predicting size effect on diffusion-limited current density of oxygen reduction by copper wire

The size effect of copper wire radius (0.04–0.82 mm) on the diffusion-limited current density of an oxygen reduction reaction in stagnant simulated seawater (naturally aerated 0.5 mol/L NaCl) is investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) and compared with the results obtained in 0.5 mol/L H2SO4. In the oxygen diffusion-limited range, size effect is found to occur independent of electrolytes, which is attributed to non-linear diffusion. Additionally, to satisfy application in a marine setting, an empirical equation correlating oxygen diffusion-limited current density to copper wire radius is proposed by fitting experimental data.     

不同结构网囊特性的初步研究

为了测定不同拖网网囊结构对网囊的几何形状、同目张开、网目形状和拖网阻力的影响,设计和制作了4种网囊,一种是传统的菱形同目（DM）网囊,另三种是新型网囊：方形同目（SM）网囊,菱、方形网目混合二片式（DSM2）网囊和菱、方形同目混合四片式（DSM4）网囊。于1996年9月11～12日在中山大学试验水槽进行了同模试验,结果表明：1）各网囊阻力相差不大,且随拖速和渔获的增加而增大。2）新型网囊的几何形状和同目的张开及其形状均优于传统菱形网目网囊。3）空网时,各种网囊均呈圆筒状。当网囊中有了渔获后,传统菱形同目网囊的端部变为球状,除了球状部分的网目有较大张开外,其余同目张开很小,网囊使用直径也小,而新型网囊始终保持筒状,且网目充分张开,网囊使用直径也大。4）新型例翼的几何形状及使用直径和网目的张开及形状几乎不受拖速大小、有无渔获和渔获多少的影响。     

Optimization of stocking density for the sea cucumber, Apostichopus japonicus Selenka, under feed-supplement and non-feed-supplement regimes in pond culture

Optimal stocking densities were investigated for the sea cucumber Apostichopus japonicus Selenka under feed-supplement and non-feed-supplement regimes in net enclosures for 333 d. Substantial weight loss occurred during the aestivation phase (AE). Decreased growth rates were also observed during the winter phase (WT). In contrast, sea cucumbers showed rapid growth during the spring (SP) and autumn (AU) phases. Feeding regimes considerably influenced the growth performance, i.e., sea cucumbers grew faster under feed-supplement regime than under non-feed-supplement regime (P < 0.05). The average survival rates of sea cucumbers under feed-supplement regime were higher than those under non-feed-supplement regime for both the autumn phase and spring phase, but the differences were only significant for the latter phase (P < 0.05). The fitted B-N curves showed that the optimal stocking densities, in terms of net production, were 22.3 ind. m-2 for feed-supplement regime and 14.1 ind. m-2 for non-feed-supplement regime.     

Comparative study of two carbon fiber cathodes and theoretical analysis in microbial fuel cells on ocean floor

Cathode activity plays an important role in the improvement of the microbial fuel cells on ocean floor(BMFCs). A comparison study between Rayon-based(CF-R) and PAN-based carbon fiber(CF-P) cathodes is conducted in the paper. The two carbon fibers were heat treated to improve cell performance(CF-R-H CF-P-H), and were used to build a new BMFCs structure with a foamy carbon anode. The maximum power density was 112.42 mW m-for CF-R-H, followed by 66.6 mW m-2 for CF-R, 49.7 mW m-2 for CF-P-H and 21.6 mW m-2 for CF-P respectively. The higher specific area and deep groove make CF-R have a better power output than with CF-P. Meanwhile, heat treatment of carbon fiber can improve cell power, nearly two-fold higher than heat treatment of plain fiber. This improvement may be due to the quinones group formation to accelerate the reduction of oxygen and electron transfer on the fiber surface in the three phase boundary after heat treatment. Compared to PAN-based carbon fiber, Rayon-based carbon fiber would be preferentially selected as cathode in novel BMFCs design due to its high surface area, low cost and higher power. The comparison research is significant for cathode material selection and cell design.     

Combined action of uniform flow and oscillating flow around marine riser at low Keulegan-Carpenter number

With the increase of petroleum and gas production in deep ocean, marine risers of circular cylinder shape are widely used in the offshore oil and gas platform. In order to research the hydrodynamic performance of marine risers, the dynamic mesh technique and User-Defined Function （UDF） are used to simulate the circular cylinder motion. The motion of a transversely oscillat-ing circular cylinder in combination of uniform flow and oscillating flow is simulated. The uniform flow and oscillating flow both are in x direction. SIMPLE algorithm is used to solve the Navier-Stokes equations. The User-Defined Function is used to control the cylinder transverse vibration and the inlet flow. The lift and drag coefficient changing with time and the map of vorticity isolines at different phase angle are obtained. Force time histories are shown for uniform flow at Reynolds number （Re） of 200 and for the com-bination of uniform and oscillating flows. With the increase of amplitude of oscillating flow in combined flow, the change of lift am-plitude is not sensitive to the the change of cylinder oscillating frequency. Lift amplitude increases with the increase of oscillating flow amplitude in the combined flow, but there is no definite periodicity of the lift coefficient. The drag and inertia force coefficients change when the maximum velocity of the oscillating flow increases in the combined flow. The vortex shedding near the circular cylinder shows different characteristics.     

Humic Acid and Iron Chelation Modified Anode Improves the Electrochemical Performance of Marine Sediment Microbial Fuel Cell

Marine sediment microbial fuel cell(MSMFCs)can be utilized as a long lasting power source to drive small instruments to work for long time on ocean floor and its higher power has a significant meaning for practical application.Anode modification can greatly improve the performance of MSMFCs.Herein,humic acid(HA)and humic acid-iron ion complex(HA-Fe)were used to modify the anode for constructing a better MSMFCs.The results indicated that HA-Fe modified anode,better than HA modification,significantly improved the MSMFCs cell power output.The maximum power density of HA-Fe modified MSMFCs is 165.3 mW m?2,which are 6.5-folds of blank MSMFCs.The number of microorganisms on anode,redox activity,and relative kinetic activity were 1.8-,6.1-,and 13.1-folds of blank MSMFCs,respectively.The MSMFCs improvement would be attributed to the electron transfer media of HA and the valence conversion of Fe ions.A synergistic interaction between the naturally occurring HA and Fe ions on the anodic surface in marine sediments would make the modified anodes have‘renewable’characteristics,which is beneficial for the MSMFCs to maintain its long-term higher power.     

林木多样性模型及生长模拟

林木生存环境复杂多变,导致林木形态千差万别,为了准确描述林木的形态多样性特征,提出了一种基于模型分解的林木生长模拟方法。首先构建多样性林木三维模型,使用林木形态的实际测量数据,基于B样条函数约束树干、树冠形态,依据削度方程模拟树干直径的变化趋势,利用Direct3D实现林木形态的三维建模;其次,按林木形态特征进行林木模型分解,将林木模型分为9个子模型;最后,使用场景节点按照拓扑结构关系对子模型进行动态组织,基于胸径、树高、枝下高、冠高和冠幅生长模型,使用多核CPU多线程并行的计算方式,获得各年龄阶段林木东、南、西、北方向形态参数,从而对子模型生长状态进行控制,实现林木不同方向生长变化的可视化模拟。结果表明：该方法可将林木三维模型与生长模型紧密结合起来,林木各方向的枝下高、冠高和冠幅严格按照生长模型进行生长,可有效模拟出林木各方向生长状态的多样性;三维场景渲染帧率（FPS）保持在25以上,平均FPS可以达到50,实现林木生长的方向异质性模拟。     

Carbon sequestration in forest vegetation of Beijing at sublot level

Based on forest inventory data (FID) at sublot level,we estimated the carbon sequestration in forest vegetation of Beijing,China in 2009.In this study,the carbon sequestration in forest vegetation at sublot level was calculated based on net biomass production (ΔB) which was estimated with biomass of each sublot and function relationships between ΔB and biomass.The biomass of forested land was calculated with biomass expansion factors (BEFs) method,while those of shrub land and other forest land types were estimated with biomass,coverage and height of referred shrubs and shrub coverage and height of each sublot.As one of special forested land types,the biomass of economic tree land was calculated with biomass per tree and tree number.The variation of carbon sequestration in forest vegetation with altitude,species and stand age was also investigated in this study.The results indicate that the carbon sequestration in forest vegetation in Beijing is 4.12 × 106 tC/yr,with the average rate of 3.94 tC/(ha·yr).About 56.91% of the total carbon sequestration in forest vegetation is supported by the forest in the plain with an altitude of < 60 m and the low mountainous areas with an altitude from 400 m to 800 m.The carbon sequestration rate in forest vegetation is the highest in the plain area with an altitude of < 60 m and decreased significantly in the transitional area from the low plain to the low mountainous area with an altitude ranging from 200 m to 400 m due to intensive human disturbance.The carbon sequestration of Populus spp.forest and Quercus spp.forest are relatively higher than those of other plant species,accounting for 25.33% of the total.The carbon sequestration in vegetation by the forest of < 40 years amounts to 45.38% of the total.The carbon sequestration rate in forest vegetation peaks at the stand age of 30–40 years.Therefore,it would be crucial for enhancing the capability of carbon sequestration in forest vegetation to protect the forest in Beijing,to limit human disturbance in the transitional area from the plain to the low mountain area,and to foster the newly established open forest.     

Factorial analysis of annual erosion-accretion cycles of tidal flats in the front area of the southern Changjiang river delta

Based on surveyed data from seven coastal sections and the collected data of wind, sea level, tide, nearshore suspended sediment concentration and river flux from adjacent stations, this paper deals with regressive correlation between monthly average flat elevation and monthly average figures of the influential factors. All sections except one which is located within the river mouth showed negative correlation between flat elevation and sea level and between flat elevation and tidal range, with correlation coefficients being −0.53 – −0.91 (−0.77 on the average) in the former condition and −0.56 – −0.97 (−0.80 on the average) under the latter. Each of the sections with available suspended sediment concentration (SSC) data shows a positive correlation between flat elevation and SSC, with correlative coefficients being 0.35 – 0.97 (0.66 on the average). Only two sections (one in the Changjiang River Estuary and the other in the Hangzhou Bay) which are similar to beaches in sediment grain-size and slope gradient showed a negative correlation between flat elevation and onshore wind frequency and between flat elevation and average wind velocity, with correlative coefficients being respectively −0.57 and −0.69 (−0.63 on the average) in the former situation and −0.61 and −0.75 (−0.68 on the average) in the latter. Other sections did not show uniform relationship between flat elevation and wind conditions. Due to local marine factors the nearshore SSC in the studied area is negatively correlated with the Changjiang River sediment flux (r=−0.78), which results in false negative correlation between flat elevation and river sediment flux. The paper also gives sediment dynamic and morphodynamic explanation for the above correlations. Sea level rise results in the spread of breaker zone from subtidal area to intertidal area and then increases the intertidal water energy. The larger the tidal range, the stronger the tide currents and the easier for the flat to be eroded. The higher the SSC of flood water, the easier for the sediment to deposit down. Because of correlations among the influential factors, it is difficult to give the prime one which dominates the erosion and accretion processes in tidal flats.     

Environmental Impact of Artificial Harbors in Tropic Pacific Oceanic Islands

1　Introduction　Oceanicislandsfallintoseveraldifferenttypes .Thecommontypesarevolcanicislands ,atollsandemer gentlimestoneislands (ScottandRotondo ,1 983;Woodroffe ,1 992 ) .Avolcanicislandinthetropicshasfringingor andbarrierreefs .Anatollhasaring shaped…     

Ecological distribution of soil animals in broad-leaved pine forests in southern slope of Xiao Hinggan Mountains

Broad leaved pine forests are the typical zonal vegetation and its central distribution zone is in the Changbai Mountains in northeast China. However, because of man's disturbance and destruction, primitive broad leaved pine forests exist now only in a few areas such as the Changbai Mountains of Jilin Province and Wuying, Liangshui Natural Reserves of Heilongjiang Province, and the forests in other places are substituted by natural secondary forests (WANG, 1994). Broad leaved pine …     

Interactions between a cyanobacterial bloom (<Emphasis Type="Italic">Microcystis</Emphasis>) and the submerged aquatic plant <Emphasis Type="Italic">Ceratophyllum oryzetorum</Emphasis> Kom.

In aquatic ecosystems, macrophytes and phytoplankton are main primary producers, in which macrophyte plays an important role in maintaining clear water state, while phytoplankton often dominates in turbid waterbodies. In the present study, the growth and photosynthetic activity of the submerged aquatic plant Ceratophyllum oryzetorum Kom. in different cell densities of cyanobacterial bloom are studied. The results show that the plant length and fresh mass of C. oryzetorum are promoted by low cyanobacterial cell densities. Medium and high cyanobacterial cell densities, on the contrary, act as inhibitory. Furthermore, the photosynthetic activity of C. oryzetorum is strongly inhibited by high cyanobacterial cell densities. To a certain extent, the growth of cyanobacteria is inhibited by C. oryzetorum, but no significant effect is found in this study. Supported by the Innovation Project of CAS (No.KZCX2-YW-426), a Provincial Project of Hubei (No. 2006AA305A0402) and the National Basic Research Program of China (973 Program, No. 2002CB 412306)     

Effects of environmental factors on tree seedling regeneration in a pine-oak mixed forest in the Qinling Mountains, China

Natural seedling regeneration and tree establishment are affected by various environmental factors.In this study,we established eight,eight,six,and four independent forest stands(each stand was further divided into five subplots) respectively based on the altitudinal gradient,stand density,slope location,and slope aspect to investigate the effects of environmental factors on tree seedling regeneration in a pine-oak mixed forest.The results indicated that the seedling density was significantly higher at altitudes of 1,283 m to 1,665 m,whereas the sapling density did not differ with altitudes.The seedling and sapling density decreased significantly at 1,835 m.The seedling densities on the upper slopes were much higher than those on the middle and lower slopes,whereas the sapling density had no difference.The sapling density decreased gradually from the southwest(20°-75°) whereas it increased on the shady slopes to the northeast(40°).The seedling density increased from southwest(20°) to northeast(40°).The seedling and sapling densities increased with the stand density(850 trees ha-1to 1,525 trees ha-1) whereas the sapling density was significantly lower in stands(1,900 trees ha-1).Principal components analysis showed that the slope aspect and stand density had more important roles in tree regeneration in this study region compared with the other two factors.Therefore,our findings suggest that it will be beneficial to keep stands at a moderate density on shady slopes.Appropriate thinning of higher density stands is also expected to promote the natural regeneration of pine-oak mixed forest.     

Cathodic protection of A1 hull ship

Heavy paint coating loss and localized corrosion of the Al alloy hull occur red after less than a year's service of a ship at sea. Examination and analysis showed that the Mg-basic sacrificial anodes originally used for cathodic protection were not suitable as the resulting −1.3V-plus (vs Ag/AgCl) protection potential for the hull was too negative for the purpose. A new protection system was designed in which the protection current densities were 15mA/m² for the hull and 350mA/m² for the propeller. The hull protection potential under actual condition at sea was between −920mV and −1100mV (Ag/AgCl) and the protection efficiency was over 90%. The protection areas were calculated by using the formulas A=1.8×LBP×D+BC×LB×B for the hull and A_s=2Aa_s for the propeller. Contribution No. 1640 from the Institute of Oceanology, Academia Sinica.     

基于DEM和地统计的森林资源空间格局分析--以武夷山山区为例

鉴于森林资源空间分布与地形的紧密相关,本文采用DEN与地统计学方法探讨武夷山森林主要树种蓄积量的空间格局。研究结果表明,地带性植被阔叶树由于受人为干扰趋向分布于高海拔、坡度陡的山地:杉木林在长年人工经营的过程中,逐渐占据林分的首要地位,因此主要分布在500m以下的低山丘陵:马尾松适生性较广,且明显倾向分布于(半)阳坡。地统计的分析发现各向同性的块金方差与基台值之比为0.5,即随机因素和空间自相关引起的空间异质性均各占一半,变程约24kin。在各向异性的变异中,0°和45°方向的曲线变化规律一致,随着空间距离的增加,半变异函数上升,达到基台值附近趋平,但90°和135°方向上,曲线的斜率则急剧上升。结果表明,虽然武夷山林区本身优越的地带性自然条件带来丰富多样的森林资源,地形也深刻影响着树木的天然分布,但是源于森林经营和管理的人为选择,较大程度地改变了武夷山林区森林天然的空间分布格局,森林蓄积量的空间异质性并不十分明显。由此可推断,随着城镇和经济的不断发展,该区域植被的水平地带性特征将愈加模糊,森林资源的异质性也将日渐减少。