Geochronology of Ailuropoda–Stegodon fauna and Gigantopithecus in Guangxi Province, southern China

Pleistocene faunas from south China are difficult to subdivide based on the long temporal ranges of many taxa and a reduced number of genera in comparison to faunas from temperate north China. In south China, the Ailuropoda–Stegodon fauna is a very general one and includes a relatively stable suite of genera that apparently persisted for long periods of time. These attributes have made constraining its time range difficult. Application of electron spin resonance (ESR) dating of tooth enamel constrains the ages well where uranium uptake was minor. Where uranium uptake into teeth was significant, an approach combining ESR and ²³⁰Th/²³⁴U isotopic analysis also yields excellent ages. Previous estimates of early, middle and late Pleistocene time ranges previously determined by biostratigraphic seriation for the Ailuropoda–Stegodon fauna are confirmed in all cases but are made more precise with our approach, including specific time ranges for certain archaic taxa. Absolute dating also yields an extended time range for Gigantopithecus blacki of 1200 to 310 ka.     

Cosmogenic nuclide constraints on glacial chronology in the source area of the Urumqi River,Tian Shan,China

Cosmogenic nuclide surface exposure dating of boulders and erratics provides new constraints for a glacial chronology in the source area of the Urumqi River, Tian Shan, China. ¹⁰Be exposure ages of 15.0 ± 1.3–17.1 ± 1.5 ka from the Upper Wangfeng (UWF) moraines agree well with their previous relative age assignments to marine isotope stage (MIS) 2, but are younger than published AMS ¹⁴C and electron spin resonance (ESR) ages (from 22.8 ± 0.6 to 37.4 ka). This difference may result from variations in techniques, or could reflect the impact of surface erosion and sediment/snow cover on surface exposure dating. ¹⁰Be ages from the Lower Wangfeng (LWF) moraines (18.7 ± 1.8 and 16.2 ± 1.5 ka) are indistinguishable from the UWF exposure ages, but are significantly younger than previously reported thermoluminescence (TL) and ESR ages (37.7 ± 2.6–184.7 ± 18 ka). Either these two groups were formed during the same period (MIS 2) and there are problems with TL and ESR ages, or the moraines were of very different ages and the similar exposure ages result from different degrees of degradation. Erratics on rock steps and a drumlin along >8 km of the main glacial valley above the UWF have internally consistent and slightly decreasing ¹⁰Be exposure ages indicating glacier retreat >2.5 m a^?1 after MIS 2 and before middle or late Holocene glacier re‐advances. This retreat rate is similar to rates observed from modern glaciers. Copyright © 2011 John Wiley & Sons, Ltd.     

Further evidence for a relatively high sea level during the penultimate interglacial: open-system U-series ages from La Marina (Alicante,East Spain)

The elevation and timing of high sea stands during Oxygen Isotope Stage (OIS) 7 are not as well constrained as those of OIS 5e. Conflicting values are reported from Mediterranean coastlines, and fossil dating is inaccurate because of ubiquitous open U-series systems. New morphostratigraphic data from La Marina (eastern Spain) supported by open-system U-series coral ages shed light on the maximum sea level during OIS 7. Fossil corals (Cladocora caespitosa) underlying an OIS 5e marine unit yielded U-series ages from 178 ± 10 to 208 ± 11 ka (±2s; n=7) with an outlier at 240 ± 18 ka. Mean open-system limit ages of 170 ± 10 (minimum age after correction for 234Th -230Th uptake) and 237 ± 20 ka (maximum age after correction for 238U - 234U uptake) were calculated to have a probable age closer to the minimum value, for an assignment of OIS 7a or 7c. The occurrence of a warm-water “Senegalese” fauna (Strombus bubonius) in OIS5e and OIS 7 marine units confirms the arrival of tropical species to the Mediterranean before the last interglacial period. Morpho-sedimentological and neotectonic studies suggest that the maximum paleo-sea level during OIS 7c or 7a was a few meters below that of OIS 5e.     

A method for coupled ESR/U-series dating of teeth showing post-depositional U-loss

An additional method of coupled ESR/U-series dating is developed for teeth showing post-depositional U-loss. The fundamental parameter for the dose rate calculation is the present-day ²³⁰Th-activity because of the geochemical immobility of thorium. Uranium and thorium concentrations are measured by thermal ionization mass spectrometry (TIMS). Due to the unknown uranium history an average saturation uptake of uranium is assumed leading to an average development of U-series activities. Therewith an internal dose rate and the age T can be calculated on condition that the modelled ²³⁰Th-activity at time T corresponds with the measured value. Using this new method, teeth, found in archaeological sites in France (Gramat, Bramefond), could be dated even though they show U-loss after U-uptake. Two teeth from Gramat could be dated to 128.3±8.6 and 130.5±10 ka. Two teeth from Bramefond have ages of 104.4±8.4 and 115.1±10.2 ka. Both sites can be ascribed to oxygen isotope stage 5.     

ESR dating of level L 2/3 at La Micoque (Dordogne), France: Excavations of Debénath and Rigaud

Electron spin resonance (ESR) dates have been obtained on enamel from horse teeth found in Layer L 2/3 of the lower Paleolithic archaeological site of La Micoque. the age given by six of the seven samples analyzed is between 241 ± 15 and 288 ± 10 ka, the ages given by models that postulate early or continuous (linear) uptake of uranium by the tooth, respectively.     

Amino acid racemization in mammalian bones and teeth from La Chaise-de-Vouthon (Charente), France

A controlled test of the amino acid dating method as it is currently being applied to bones and teeth was attempted for the time range 100-250 ka, beyond that of ¹⁴C, at the archeological site of La Chaise-de-Vouthon (Charente, France). In Bourgeois-Delaunay, mammal fossils associated with Paleolithic artifacts were collected from layers dated at 101 ± 12 to 114 ± 7 ka by ²³⁰Th/²³⁰ dating of the over- and underlying stalagmitic floors. Racemization ratios for most amino acids were significantly lower than for comparably aged materials from other European sites. Regardless of the rate constants used, most amino acid dates were incorrect. Large associated errors spanned the late Pleistocene, making the dates useless for discriminating archaeological or geological events. Stratigraphic correlations using any tissue were also problematic. Relative interacid ratios varied with age, indicating that diagenetic alteration had affected racemization. Therefore, amino acid relative and absolute dating cannot be accurately applied to mid-Pleistocene bones or teeth.     

On the limits of using combined U-series/ESR method to date fossil teeth from two Early Pleistocene archaeological sites of the Orce area (Guadix-Baza basin,Spain)

The combined U-series/electron spin resonance (ESR) dating method was applied to nine teeth from two Early Pleistocene archaeological sites located in the Orce area (Guadix-Baza Basin, Southern Spain): Fuente Nueva-3 (FN-3) and Barranco León (BL). The combination of biostratigraphy and magnetostratigraphy places both sites between the Olduvai and Jaramillo subchrons (1.78–1.07 Ma).Our results highlight the difficulty of dating such old sites and point out the limits of the combined U-series/ESR dating method based on the US model. We identified several sources of uncertainties that may lead to inaccurate age estimates. Seven samples could not be dated because the dental tissues had (²³⁰Th/²³⁴U) activity ratios higher than equilibrium, indicating that uranium had probably leached from these tissues. It was however possible to calculate numerical estimates for two of the teeth, both from FN-3. One yielded a Middle Pleistocene age that seems to be strongly underestimated; the other provided an age of 1.19 ± 0.21 Ma, in agreement with data obtained from independent methods. The latter result gives encouragement that there are samples that can be used for routine dating of old sites.     

U‐Th Zircon Dating by Laser Ablation Single Collector Inductively Coupled Plasma‐Mass Spectrometry (LA‐ICP‐MS)

Zircon crystals in the age range of ca. 10–300 ka can be dated by ²³⁰Th/²³⁸U (U‐Th) disequilibrium methods because of the strong fractionation between Th and U during crystallisation of zircon from melts. Laser ablation inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) analysis of nine commonly used reference zircons (at secular equilibrium) and a synthetic zircon indicates that corrections for abundance sensitivity and dizirconium trioxide molecular ions (Zr₂O₃⁺) are critical for reliable determination of ²³⁰Th abundances in zircon. When corrected for abundance sensitivity and interferences, mean activity ratios of (²³⁰Th)/(²³⁸U) for nine reference zircons analysed on five different days averaged 0.995 ± 0.023 (95% confidence weighted by data‐point uncertainty only, MSWD = 1.6; n = 9), consistent with their U‐Pb ages > 4 Ma that imply equilibrium for all intermediate daughter isotopes (including ²³⁰Th) within the ²³⁸U decay chain. U‐Th zircon ages generated by LA‐ICP‐MS without mitigating (e.g., by high mass resolution) or correcting for abundance sensitivity and molecular interferences on ²³⁰Th are potentially unreliable. To validate the applicability of LA‐ICP‐MS to this dating method, we acquired data from three late Quaternary volcanic units: the 41 ka Campanian Ignimbrite (plutonic clasts), the 161 ka Kos Plateau Tuff (juvenile clasts) and the 12 ka Puy de Dôme trachyte lava (all eruption ages by Ar/Ar, with zircon U‐Th ages being of equal or slightly older). A comparison of the corrected LA‐ICP‐MS results with previously published secondary ion mass spectrometry (SIMS) data for these rocks shows comparable ages with equivalent precision for LA‐ICP‐MS and SIMS, but much shorter analysis durations (~ 2 min vs. ~ 15 min) per spot with LA‐ICP‐MS and much simpler sample preparation. Previously undated zircons from the Yali eruption (Kos‐Nisyros volcanic centre, Greece) were analysed using this method. This yielded a large age spread (~ 45 to > 300 ka), suggesting significant antecryst recycling. The youngest zircon age (~ 45 ± 10 ka) provides a reasonable maximum estimate for the eruption age, in agreement with the previously published age using oxygen isotope stratigraphy (~ 31 ka).     

The challenge of dating early pleistocene fossil teeth by the combined uranium series–electron spin resonance method: the Venta Micena palaeontological site (Orce,Spain)

The palaeontological site of Venta Micena (Orce, Andalusia, Spain) lies in the eastern sector of the Guadix–Baza basin, one of the best documented areas in Europe for Plio‐Pleistocene biostratigraphy. The combination of biochronological and palaeomagnetic results, combined with the radiometric data obtained for Atapuerca Sima del Elefante, indicated that the Venta Micena stratum was formed between the Jaramillo and Olduvai palaeomagnetic events, most likely between 1.22 and 1.77 Ma. Five fossil teeth from two outcrops (sites A and B) were selected to assess the potential of combined uranium series–electron spin resonance (US‐ESR) dating of Early Pleistocene sites. Although the US‐ESR results of the first outcrop showed a large scatter between the three teeth, the mean age of 1.37 ± 0.24 Ma can be considered a reasonable age estimate for Venta Micena. The mean ESR age of 0.62 ± 0.03 Ma obtained for site B seems to be a severe underestimation when compared with the independent age control. This underestimation is attributed to a relative recent U‐mobilization event that led to some U‐leaching. The results show that any ESR age calculations of old samples are extremely sensitive to variations in the measured ²³⁰Th/²³⁴U ratios in dental tissues. Although the results demonstrate that ESR can in principle be applied to Early Pleistocene sites, they also reveal the complexity of dating such old teeth. It is necessary to continue research in several directions, such as study of the behaviour of ESR signals in old teeth and understanding recent U‐mobilization processes, to improve the reliability of the combined US‐ESR dating method applied to Early Pleistocene times, a period for which the number of available numerical dating techniques is very limited. Copyright © 2011 John Wiley & Sons, Ltd.     

Uranium-series dating of pedogenic silica and carbonate, Crater Flat, Nevada

A ²³⁰Th-²³⁴U-²³⁸U dating study on pedogenic silica-carbonate clast rinds and matrix laminae from alluvium in Crater Flat, Nevada was conducted using small-sample thermal-ionization mass spectrometry (TIMS) analyses on a large suite of samples. Though the ²³²Th content of these soils is not particularly low (mostly 0.1-9 ppm), the high U content of the silica component (mostly 4-26 ppm) makes them particularly suitable for ²³⁰Th/U dating on single, 10 to 200 mg totally-digested samples using TIMS. We observed that (1) both micro- (within-rind) and macro-stratigraphic (mappable deposit) order of the ²³⁰Th/U ages were preserved in all cases; (2) back-calculated initial ²³⁴U/²³⁸U fall in a restricted range (typically 1.67±0.19), so that ²³⁴U/²³⁸U ages with errors of about 100 kyr (2σ) could be reliably determined for the oldest, 400 to 1000 ka rinds; and (3) though 13 of the samples were >350 ka, only three showed evidence for an open-system history, even though the sensitivity of such old samples to isotopic disruption is very high. An attempt to use leach-residue techniques to separate pedogenic from detrital U and Th failed, yielding corrupt ²³⁰Th/U ages. We conclude that ²³⁰Th/U ages determined from totally dissolved, multiple sub-mm size subsamples provide more reliable estimates of soil chronology than methods employing larger samples, chemical enhancement of ²³⁸U/²³²Th, or isochrons.     

Precise two chronometer dating of Pleistocene travertine: The Th/U and Raex/Ra(0) approach

In order to determine the geochemical evolution of a freshwater limestone cave system located in central Switzerland (Hell Grottoes at Baar/Zug,) young postglacial tufaceous limestone and travertine precipitates were investigated using the ²³⁰Th/²³⁴U ingrowth system. Additional analyses of further radionuclides within the ²³⁸U decay chain, i.e. ²²⁶Ra and ²¹⁰Pb, showed that the Th/U chronometer started with insignificant inherited ²³⁰Th over the entire formation period of the travertine setting (i.e. ²³⁰Th(0)=0). A contribution from detrital impurities with ²³⁰Th/²³⁴U in secular equilibrium could be precisely subtracted by applying isochron dating of cogenetic phases and recently formed travertine. The resulting precise ²³⁰Th/²³⁴U formation ages were found to be consistent with the geological stratigraphy and were furthermore used to demonstrate the applicability of the next geologically important chronometer in the ²³⁸U-decay series, based on decay of excess ²²⁶Ra normalized to the initial, i.e.²²⁶Ra_ex/²²⁶Ra(0). This system is suitable for dating phases younger than 7000 yr when the correction of a detritus component increasingly limits the precision of the ²³⁰Th/²³⁴U chronometer. Analytical solutions of the coupled ²³⁴U/²³⁰Th/²²⁶Ra radionuclide system predicted that the ²²⁶Ra_ex/²²⁶Ra(0) chronometer is independent of the actual ²³⁰Th activity build up from decay of ²³⁴U, if the systems starts with zero inherited ²³⁰Th(0). The data set confirmed this hypothesis and showed furthermore that the initially incorporated ²²⁶Ra excess must have remained almost uniform in all limestone over a period of at least 7000 yr, i.e. 4–5 half-lives of ²²⁶Ra. This is concluded because (i) the ²²⁶Ra_ex/²²⁶Ra(0) ages agreed well with those derived from ²³⁰Th/²³⁴U, (ii) all data plot within uncertainty on the ²²⁶Ra_ex/²²⁶Ra(0) decay curve and (iii) the atomic Ba/Ca ratio was found to be constant in the travertine material independent of the sample ages. Provided that such boundary conditions hold, ²²⁶Ra_ex/²²⁶Ra(0) should be applicable to materials which are suitable for ²³⁰Th/²³⁴U dating in sedimentology and oceanography, i.e. travertine, corals, phosphorites, etc., and should strongly support ²³⁰Th/²³⁴U for samples that have been formed a few thousand years ago.     

Pleistocene climatic change in Southern Australia and its effect on speleothem deposition in some Nullarbor caves

Activity ratios of ²³⁴U/²³⁸U, ²³⁰Th/²³⁴U, and ²³⁰Th/²³²Th have been determined for calcite, gypsum and halite speleothems from caves of the Nullarbor Plain, mostly in the area N and NW of Mundrabilla Station, for the purpose of U-series dating. All calcite speleothems contain adequate amounts of uranium for dating, but some show an excess of ²³⁰Th. Stratigraphic relationships indicate that there were at least three phases of calcium carbonate deposition in the Nullarbor caves. The calcite samples, with one possible exception, have ages in excess of ca. 400000 yrs BP. This suggests that no significant amounts of calcium carbonate deposition have taken place during the last 400ka. At present, active deposition of speleothems is restricted almost entirely to gypsum and halite. The only gypsum speleothem dated was found to have a finite age of ca. 185 ka. Six dates on a small halite speleothem containing insect and arachnid remains indicate that it formed rapidly during Holocene time.     

High resolution analysis of uranium and thorium concentration as well as U-series isotope distributions in a Neanderthal tooth from Payre (Ardèche, France) using laser ablation ICP-MS

We have mapped U (²³⁸U) and Th (²³²Th) elemental concentrations as well as U-series isotope distributions in a Neanderthal tooth from the Middle Palaeolithic site of Payre using laser ablation ICP-MS. The U-concentrations in an enamel section varied between 1 and 1500 ppb. The U-concentration maps show that U-migration through the external enamel surface is minute, the bulk of the uranium having migrated internally via the dentine into the enamel. The uranium migration and uptake is critically dependent on the mineralogical structure of the enamel. Increased U-concentrations are observed along lineaments, some of which are associated with cracks, and others may be related to intra-prismatic zones or structural weaknesses reaching from the dentine into the enamel. The uranium concentrations in the dentine vary between about 25,000 and 45,000 ppb. Our systematic mapping of U-concentration and U-series isotopes provides insight into the time domain of U-accumulation. Most of the uranium was accumulated in an early stage of burial, with some much later overprints. None of the uranium concentration and U-series profiles across the root of the tooth complied with a single stage diffusion-adsorption (D-A) model that is used for quality control in U-series dating of bones and teeth. Nevertheless, in the domains that yielded the oldest apparent U-series age estimates, U-leaching could be excluded. This means that the oldest apparent U-series ages of around 200 ka represent a minimum age for this Neanderthal specimen. This is in good agreement with independent age assessments (200-230 ka) for the archaeological layer, in which it was found.The Th elemental concentrations in the dental tissues were generally low (between about 1 and 20 ppb), and show little relationship with the nature of the tissue.     

ESR dating of tooth enamel in Mousterian layer 20, El Castillo,Spain

Nine faunal teeth from layer 20 of El Castillo cave in Cantabrian Spain were dated using electron spin resonance (ESR). Two teeth were rejected due to inconsistent subsample ages, while the remaining teeth yielded a mean age that is consistent with the stratigraphic expectations: 42.7±3.5. Uncertainty in the external γ dose rate results in a potential systematic uncertainty of±6.4ka that should affect all samples equally. The results provide independent confirmation of previously reported ¹⁴C ages for layer 20. © 2010 Wiley Periodicals, Inc.     

ESR and Th/U dating of speleothems from Aladağlar Mountain Range (AMR) in Turkey

Electron spin resonance (ESR) and ²³⁰Th/²³⁴U ages of speleothem samples collected from karstic caves located around 3000 m elevation in the Alada?lar Mountain Range (AMR), south-central Turkey, were determined in order to provide new insight and information regarding late Pleistocene climate. ESR ages were validated with the ²³⁰Th/²³⁴U ages of test samples. The ESR ages of 21 different layers of six speleothem samples were found to range mostly between about 59 and 4 ka, which cover the Marine Oxygen Isotope Stages (MIS) MIS 3 to MIS 1. Among all, only six layers appear to have deposited during MIS 8 and 5. Most of the samples dated were deposited during the late glacial stage (MIS 2). It appears that a cooler climate with a perennial and steady recharge was more conducive to speleothem development rather than a warmer climate with seasonal recharge in the AMR during the late Quaternary. This argument supports previous findings that suggest a two -fold increase in last glacial maximum mean precipitation in Turkey with respect to the present value.     

Th/U/U and Pa/U ages from a single fossil coral fragment by multi-collector magnetic-sector inductively coupled plasma mass spectrometry

The ²³⁰Th/²³⁴U/²³⁸U age dating of corals via alpha counting or mass spectrometry has significantly contributed to our understanding of sea level, radiocarbon calibration, rates of ocean and climate change, and timing of El Nino, among many applications. Age dating of corals by mass spectrometry is remarkably precise, but many samples exposed to freshwater yield inaccurate ages. The first indication of open-system ²³⁰Th/²³⁴U/²³⁸U ages is elevated ²³⁴U/²³⁸U_initial values, very common in samples older than 100,000 yr. For samples younger than 100,000 yr that have ²³⁴U/²³⁸U_initial values close to seawater, there is a need for age validation. Redundant ²³⁰Th/²³⁴U/²³⁸U and ²³¹Pa/²³⁵U ages in a single fossil coral fragment are possible by Multi-Collector Magnetic Sector Inductively Coupled Plasma Mass Spectrometry (MC-MS-ICPMS) and standard anion exchange column chemistry, modified to permit the separation of uranium, thorium, and protactinium isotopes from a single solution. A high-efficiency nebulizer employed for sample introduction permits the determination of both ²³⁰Th/²³⁴U/²³⁸U and ²³¹Pa/²³⁵U ages in fragments as small as 500 mg. We have obtained excellent agreement between ²³⁰Th/²³⁴U/²³⁸U and ²³¹Pa/²³⁵U ages in Barbados corals (30 ka) and suggest that the methods described in this paper can be used to test the ²³⁰Th/²³⁴U/²³⁸U age accuracy.Separate fractions of U, Th, and Pa are measured by employing a multi-dynamic procedure, whereby ²³⁸U is measured on a Faraday cup simultaneously with all minor isotopes measured with a Daly ion counting detector. The multi-dynamic procedure also permits correcting for both the Daly to Faraday gain and for mass discrimination during sample analyses. The analytical precision of ²³⁰Th/²³⁴U/²³⁸U and ²³¹Pa/²³⁵U dates is generally better than ±0.3% and ±1.5%, respectively (2 Relative Standard deviation [RSD]). Additional errors resulting from uncertainties in the decay constant for ²³¹Pa and from undetermined sources currently limit the ²³¹Pa/²³⁵U age uncertainty to about ±2.5%. U isotope data and ²³⁰Th/²³⁴U/²³⁸U ages agree with National Institute of Standards and Technology (NIST) reference materials and with measurements made by Thermal Ionization Mass Spectrometry (TIMS) in our laboratory.     

An assessment and comparison of 230Th and AMS 14C ages for lacustrine sediments from Qarhan Salt Lake area in arid western China

The age framework of Qarhan Salt Lake in arid western China is still controversial due in part to (1) age discrepancy between conventional ¹⁴C and ²³⁰Th dating results, and (2) no AMS ¹⁴C ages of organic carbon from drilling cores in Qarhan Salt Lake were reported until now. In order to discuss these chronological problems, upper 54.50 m lacustrine sediments from a drilling core (ISL1A) recovered from Qarhan Salt Lake were dated based on ²³⁰Th and AMS ¹⁴C dating techniques. Results show that (1) AMS ¹⁴C ages of total organic carbon (TOC) from 4.65 to 30.29 m are almost in stratigraphic order and consistent with ²³⁰Th ages of halite in the corresponding layers; (2) AMS ¹⁴C ages of TOC from 30.29 to 54.50 m are younger with increasing depth. This phenomenon was also found in Shell Bar in the study area, suggesting that AMS ¹⁴C ages from upper 30.29 m are more reliable while those from lower 24.21 m in ISL1A may be underestimated; (3) ²³⁰Th ages of halite from lower 24 m lacustrine sediments are obviously older than AMS ¹⁴C ages of TOC in the corresponding layers, which results into different age framework of salt lake sediments in Qarhan Salt Lake; (4) if extrapolating these reliable AMS ¹⁴C ages in ISL1A, similar age framework with ²³⁰Th ages in this core confirms that ²³⁰Th ages are much close to the true ages of these sediments, which suggests that the forming timing of the bottom salt layer is ~50 ka.     

Introduction

Manisa Fault is a geomorphologically distinct normal dip-slip fault, which oversees the southern edge of the Manisa Graben that is a continuum of the Gediz Graben towards the west. This study aims to determine the neotectonic activity of the Manisa Fault and the most recent time of the change in its stress condition through age-dating data obtained by using ²³⁰Th/²³⁴U dating methodology applied on the calcite coating that develops over hanging-wall of the Manisa Fault and the calcite veins that occur as fracture fillings. The age of the calcite precipitations associated with the Manisa Fault was determined to be between 307?±?203 and 444?±?101?ka by using the ²³⁰Th/²³⁴U dating method. Evaluation of the carbonate precipitations on the Manisa Fault along with the age data and the kinematic indicators ascertained that the Manisa Fault switched to a dip-slip normal faulting character from Middle Pleistocene onwards and that the region was under the effect of a NE–SW directional extensional regime. In addition, the opening rate was attempted to be determined using the roll-over anticline structure that advanced depending upon the movement of the fault on the upper horizontal strata of colluviums, which developed in association with the Manisa Fault. Along with the evaluation of the rise in the horizontal stratification in colluvium and the obtained age data, opening rate of the Manisa Fault was determined as 0.01?mm?y^?1.     

Thermoluminescence dating of St. Croix ceramics: Chronology building in Southwestern Nova Scotia

Using the classic thermoluminescence (TL) dating technique for fired ceramic materials, we have obtained the first direct ages for five ceramic artifacts recovered from BfDa-1, a prehistoric archaeological site located in St. Croix, southcentral Nova Scotia. BfDa-1 is the only archaeological site in Nova Scotia to produce the full range of ceramic styles associated with the Woodland or Ceramic Period (c. 1050 B.C. to A.D. 1500); thus our new chronology can be used to revise the current local and regional ceramic chronologies. The five sherds from the St. Croix site yielded absolute gas of 1.15 ± 0.15 ka to 2.62 ± 0.29 ka (1 ka = 1000 years). The oldest of these TL ages was obtained on a sherd decorated with a pseudoscallop shell design and is in excellent agreement with a ¹⁴C date of 2500 ± 120 B.P. associated with Early Ceramic artifacts at this site. The other TL ages are in agreement with the relative ceramic chronology deduced from their decorative attributes. All five TL dates are in the correct depth-age order. This demonstrates that the recent excavations explored a part of the site which remained undisturbed in spite of extensive agricultural and horticultural activities in the vicinity in recent centuries. The dates also indicate a high degree of compression for the cultural remains at the site. They suggest a sediment deposition rate of 1.3 cm/100 yr during the early stages of the occupation period (2000–2600 yr B.P.), and a decrease in the deposition rate to 0.5 cm/100 yr during the last 2000 years. These dates provide the first successful application of TL dating to ceramics of the Minas Basin area. They confirm an initial hypothesis based on the stylistic attributes of ceramics recovered from BfDa-1, that human occupation at the site must have been of long duration. The excellent quality of the analytical data indicates that the TL dating technique should be well suited to the study of ceramic technology in other parts of the province, and that local mineralogy is suitable for optical dating of sediments at the site and elsewhere in Nova Scotia. © 1997 John Wiley & Sons, Inc.     

Can 234U–230Th dating be used to date large semi‐arid tufas? Challenges from a study in the Naukluft Mountains,Namibia

The large, extensive tufa deposits of the semi‐arid Naukluft Mountains, Namibia are potentially important palaeoenvironmental indicators in an area with few proxy records. Tufas are reliable indicators of increased moisture availability, and have been shown to be amenable to ²³⁴U–²³⁰Th dating, although two challenges are detrital contamination and open‐system behaviour. Densely cemented tufa facies are good candidates for dating, minimising these problems. We report attempts to date five densely‐cemented units, which are only found rarely within the Naukluft deposits. We applied a detailed methodology using multiple subsample analysis, measurement of insoluble residues, application of ‘isochron’ mixing lines, and attempted open‐systems modelling, alongside observations of micromorphology and cathodoluminescence in order to assess the validity of any obtained dates. Surprisingly, densely cemented tufas were found not always to be suitable for dating. Two units contained detrital contamination, which could not be corrected for using a single leachate correction or ‘isochron’ methods. Two units contained ‘excess ²³⁰Th’. This could result under a closed‐system if initial (²³⁴U/²³⁸U) was sufficiently high. Alternatively this may be the result of open‐system behaviour, and loss of uranium, or incorporation of initial unsupported ²³⁰Th, which render samples unsuitable for ²³⁴U–²³⁰Th dating. Micromorphological appearance and cathodoluminescence behaviour are used to explore these possibilities. This study exemplifies the need for careful sample selection, and highlights the importance of analysing multiple subsamples from any tufa sample. The detailed methodology applied proves to be a powerful tool for identifying the range of problems that can be encountered when selecting suitable candidate samples for successful dating. It also shows that semi‐arid tufa sequences may contain very little material suitable for dating. A reliable age of c 80 ka was obtained for a banded unit within a large fluvial barrage, with less reliable dates suggesting tufa deposition during times since >350 ka through to the late Holocene. Copyright © 2010 John Wiley & Sons, Ltd.