Modified passive capillary samplers for collecting samples of snowmelt infiltration for stable isotope analysis in remote,seasonally inaccessible watersheds 1: laboratory evaluation

Snowmelt is the most significant source of runoff generation and recharge in many of the mountainous watersheds worldwide and this is especially true in the southwestern United States. Yet, the isotopic and geochemical composition of the soil–meltwater endmember remains poorly constrained. Using the isotopic compositions of snow and snowmelt runoff samples taken from the landscape surface as proxies for soil–meltwater endmembers is problematic since they are typically not representative of the actual composition of soil meltwater. Furthermore, the applicability of current methodologies to collect the isotopic composition of meltwater is limited because of the remote and often seasonally inaccessible nature of the terrain where snowpacks develop. Therefore, a robust methodology requiring little maintenance or monitoring is desirable. A lab experiment was conducted to determine the suitability of using a modified passive capillary sampler (M‐PCAPS) design to collect snowmelt infiltration for isotopic analysis. Passive capillary samplers are constructed from fiberglass wicks that can be installed in the soil to sample vadose‐zone waters under a wide range of matric potentials and require little maintenance. Results from this lab experiment indicate that the wicking process associated with M‐PCAPS does not fractionate water but certain precautions are necessary to prevent exchange between the wick and the atmosphere. In this experiment, M‐PCAPS effectively tracked the changing isotopic composition of a soil reservoir undergoing evaporation. Therefore, M‐PCAPS provide a robust methodology to sample the isotopic composition of snowmelt infiltration in remote watersheds and similar applications. Copyright © 2009 John Wiley & Sons, Ltd.     

Modified passive capillary samplers for collecting samples of snowmelt infiltration for stable isotope analysis in remote,seasonally inaccessible watersheds 2: field evaluation

Twelve modified passive capillary samplers (M‐PCAPS) were installed in remote locations within a large, alpine watershed located in the southern Rocky Mountains of Colorado to collect samples of infiltration during the snowmelt and summer rainfall seasons. These samples were collected in order to provide better constraints on the isotopic composition of soil‐water endmembers in the watershed. The seasonally integrated stable isotope composition (δ¹⁸O and δ²H) of soil‐meltwater collected with M‐PCAPS installed at shallow soil depths < 10 cm was similar to the seasonally integrated isotopic composition of bulk snow taken at the soil surface. However, meltwater which infiltrated to depths > 20 cm evolved along an isotopic enrichment line similar to the trendline described by the evolution of fresh snow to surface runoff from snowmelt in the watershed. Coincident changes in geochemistry were also observed at depth suggesting that the isotopic and geochemical composition of deep infiltration may be very different from that obtained by surface and/or shallow‐subsurface measurements. The M‐PCAPS design was also used to estimate downward fluxes of meltwater during the snowmelt season. Shallow and deep infiltration averaged 8·4 and 4·7 cm of event water or 54 and 33% of the measured snow water equivalent (SWE), respectively. Finally, dominant shallow‐subsurface runoff processes occurring during snowmelt could be identified using geochemical data obtained with the M‐PCAPS design. One soil regime was dominated by a combination of slow matrix flow in the shallow soil profile and fast preferential flow at depth through a layer of platy, volcanic rocks. The other soil regime lacked the rock layer and was dominated by slow matrix flow. Based on these results, the M‐PCAPS design appears to be a useful, robust methodology to quantify soil‐water fluxes during the snowmelt season and to sample the stable isotopic and geochemical composition of soil‐meltwater endmembers in remote watersheds. Copyright © 2009 John Wiley & Sons, Ltd.     

Advantages and challenges of using soil water isotopes to assess groundwater recharge dominated by snowmelt at a field study located in Canada

Seasonal signals of stable isotopes in precipitation, combined with measurements of isotope ratios in soil water, can be used for quantitative estimation of groundwater recharge rates. This study investigates the applicability of using the piston flow principle and the peak shift displacement method to estimate actual groundwater recharge rates in a humid Nordic region located in the province of Quebec, Canada. Two different sites with and without vegetation (C1 and C2) in an unconfined aquifer were tested by measuring soil water isotope ratios (¹⁸O/¹⁶O and ²H/¹H) and volumetric pore water content. Core samples were obtained along the vadose zone down to the groundwater table at the two sites (2.45 m for Site C1 and 4.15 m for Site C2). The peak shift method to estimate groundwater recharge rates was shown to be accurate only in certain specific conditions inherent to the soil properties and the topographical situation of the investigated sites. Indeed, at Site C2, recharge from the snowmelt could not be estimated because of heterogeneity in the lower part of the vadose zone. At this same site the later recharge after the snowmelt (in the period from late spring to early autumn) could be estimated accurately because the upper part of the vadose zone was homogeneous. Furthermore, at site C1, runoff/runon phenomena hampered calculations of actual infiltration and thus produced inaccurate results for recharge. These two different site effects (heterogeneity in the first site and runoff/runon in the other site) were identified as being limiting factors in the accurate assessment of actual recharge. This study therefore recommends the use of the peak shift method for (1) humid Nordic regions, (2) homogeneous and thick vadose zones, and (3) areas with few or limited site effects (runoff/runon).     

Evidence for climatic and hillslope‐aspect controls on vadose zone hydrology and implications for saprolite weathering

Through the delivery of water in snowmelt, climate should govern the rate and extent of saprolite formation in snow‐dominated mountain watersheds, yet the mechanisms by which water flows deeply into regolith are largely unexplored. In this study we link rainfall, snow depth, and water content data from both soil and shallow saprolite to document vadose zone dynamics in two montane catchments over 2 years. Measurements of snow pack thickness and soil moisture reveal strong contrasts between north‐ and south‐facing slopes in both the timing of meltwater delivery and the duration of significant soil wetting in the shallow vadose zone. Despite similar magnitudes of snowmelt recharge, north‐facing slopes have higher sustained soil moisture compared to south‐facing slopes. To help interpret these observations, we use a 2D numerical model of vadose zone dynamics to calculate the expected space–time moisture patterns on an idealized hillslope under two wetting scenarios: a single sustained recharge pulse versus a set of short pulses. The model predicts that the duration of the recharge event exerts a stronger control on the depth and residence time of water in the upper unsaturated zone than the magnitude of the recharge event. Model calculations also imply that water should move more slowly through the subsurface and downward water flux should be substantially reduced when water is applied in several pulses rather than in one sustained event. The results suggest that thicker soil and more deeply weathered rock on north‐facing slopes may reflect greater water supply to the deep subsurface. Copyright © 2015 John Wiley & Sons, Ltd.     

Controls on old and new water contributions to stream flow at some nested catchments in Vermont,USA

Factors controlling the partitioning of old and new water contributions to stream flow were investigated for three events in four catchments (three of which were nested) at Sleepers River Research Watershed in Danville, Vermont. In the 1993 snowmelt period, two‐component isotopic hydrograph separations showed that new water (meltwater) inputs to the stream ranged widely from 41 to 74%, and increased with catchment size (41 to 11 125 ha) (with one exception) and with open land cover (0–73%). Peak dissolved organic carbon concentrations and relative alkalinity dilution in stream water ranked in the same order among catchments as the new water fractions, suggesting that new water followed shallow flow paths. During the 1994 snowmelt, despite similar timing and magnitude of melt inputs, the new‐water contribution to stream flow ranged only from 30 to 36% in the four catchments. We conclude that the uncommonly high and variable new water fractions in streamwater during the 1993 melt were caused by direct runoff of meltwater over frozen ground, which was prevalent in open land areas during the 1993 winter. In a high‐intensity summer rainstorm in 1993, new water fractions were smaller relative to the 1993 snowmelt, ranging from 28 to 46%, but they ranked in the identical catchment order. Reconciliation of the contrasting patterns of new–old water partitioning in the three events appears to require an explanation that invokes multiple processes and effects, including:

• 1. topographically controlled increase in surface‐saturated area with increasing catchment size;
• 2. direct runoff over frozen ground;
• 3. low infiltration in agriculturally compacted soils;
• 4. differences in soil transmissivity, which may be more relevant under dry antecedent conditions.

These data highlight some of the difficulties faced by catchment hydrologists in formulating a theory of runoff generation at varying basin scales. Copyright © 2002 John Wiley & Sons, Ltd.     

Hydrologic connectivity at the hillslope scale through intra-snowpack flow paths during snowmelt

The seasonal snowmelt period is a critical component of the hydrologic cycle for many mountainous areas. Changes in the timing and rate of snowmelt as a result of physical hydrologic flow paths, such as longitudinal intra-snowpack flow paths, can have strong implications on the partitioning of meltwater amongst streamflow, groundwater recharge, and soil moisture storage. However, intra-snowpack flow paths are highly spatially and temporally variable and thus difficult to observe. This study utilizes new methods to non-destructively observe spatio-temporal changes in the liquid water content of snow in combination with plot experiments to address the research question: What is the scale of influence that intra-snowpack flow paths have on the downslope movement of liquid water during snowmelt across an elevational gradient? This research took place in northern Colorado with study plots spanning from the rain-snow transition zone up to the high alpine. Results indicate an increasing scale of influence from intra-snowpack flow paths with elevation, showing higher hillslope connectivity producing larger intra-snowpack contributing areas for meltwater accumulation, quantified as the upslope contributing area required to produce observed changes in liquid water content from melt rate estimates. The total effective intra-snowpack contributing area of accumulating liquid water was found to be 17, 6, and 0 m² for the above tree line, near tree line, and below tree line plots, respectively. Dye tracer experiments show capillary and permeability barriers result in increased number and thickness of intra-snowpack flow paths at higher elevations. We additionally utilized aerial photogrammetry in combination with ground penetrating radar surveys to investigate the role of this hydrologic process at the small watershed scale. Results here indicate that intra-snowpack flow paths have influence beyond the plot scale, impacting the storage and transmission of liquid water within the snowpack at the small watershed scale.     

Land cover controls on depression‐focused recharge on the Oak Ridges Moraine,southern Ontario,Canada

The Oak Ridges Moraine (ORM) is a key hydrogeologic feature in southern Ontario. Previous research has emphasized the importance of depression‐focused recharge (DFR) for the timing and location of water recharge to the ORM's aquifers. However, the significance of DFR has not been empirically demonstrated, and the ORM's permeable surficial deposits imply that rainfall and snowmelt will largely recharge vertically rather than move laterally to topographic depressions. The exception may be during winter and spring, when concrete soil frost limits infiltration and encourages overland flow. The potential for DFR was examined for closed depressions under forest and agricultural land covers with similar soils and surficial geology. Air temperatures, precipitation, snow depth and water equivalent, soil water contents, soil freezing, and depression surface‐water levels were monitored during the winter and spring of 2012–2013 and 2013–2014. Recharge (R) was estimated at the crest and base of each depression using a 1‐dimensional water balance approach and surface‐applied Br^? tracing. Both forest and agricultural land covers experienced soil freezing; however, forest soils did not develop concrete frost. Conversely, agricultural fields saw concrete frost, overland flow, episodic ponding, and subsequent drainage of rain‐on‐snow and snowmelt inputs in open depressions. Recharge at the base of open depressions exceeded that in surrounding areas by an order of magnitude, suggesting that DFR is a significant hydrologic process during winter and spring under agricultural land cover on the ORM. Closed topographic depressions under agricultural land cover on the ORM crest may serve as critical recharge “hot spots” during winter and spring, and the ability of the unsaturated zone beneath these depressions to modify the chemistry of recharging water deserves further attention.     

Applicability of isotopic hydrograph separation in a suburban basin during snowmelt

C. H. TAYLOR Methodological issues associated with isotopic hydrograph separations (IHSs) in built-up environments are explored using results from the 1990 spring melt in a suburban basin in Peterborough, Ontario, Canada. The hetrogeneous nature of suburban environments complicates the selection of appropriate isotopic signatures for event and pre-event waters. Near-stream groundwater δ¹⁸O sampled from wells was poorly mixed, such that the pre-event water signature was best characterized by δ¹⁸O in pre-melt baseflow or discharge from a headwater spring. The event water signature during snowmelt can be characterized using δ¹⁸O in the pre-melt snowpack, surface runoff samples or meltwater from lysimeters. However, the use of snowpack δ¹⁸O may be inappropriate in suburban basins where meltwater from thin snowcover may exhibit pronounced responses to δ¹⁸O in rainfall contributions. Intensive sampling of the spatial variability of runoff or meltwater δ¹⁸O may be required to characterize the average event water signature adequately. Rainfall δ¹⁸O provided an appropriate event water signal during a large rain on snow event, and differences between this IHS and one generated using an event water signature that included meltwater contributions from snow-covered surfaces were within the uncertainty attributable to the analytical error in δ¹⁸O values. Event water supplied 55-63% of the peak discharge and 48-58% of total runoff from the basin during the melt, which is consistent with the fraction of the basin that has been developed. These results contrast with IHSs conducted in forested basins that suggest that stormflow is dominated by pre-event water contributions.     

Soil partitioning and surface store controls on spring runoff from a boreal forest peatland basin in north‐central Manitoba,Canada

The mid‐ to high‐boreal forest in Canada occupies the discontinuous permafrost zone, and is often underlain by glaciolacustrine sediments mantled by a highly porous organic mat. The result is a poorly drained landscape dominated by wetlands. Frost‐table dynamics and surface storage conditions help to control runoff contributions from various landscape elements, hydrological linkages between these elements, and basin streamflow during spring snowmelt. Runoff components and pathways in a forested peatland basin were assessed during two spring snowmelts with contrasting input and basin conditions. Runoff from relatively intense melt (up to 16 mm day^?1) on slopes with limited soil thawing combined with large pre‐melt storage in surface depressions to produce high flows composed primarily of meltwater (78% of the 0·29 m³ s^?1 peak discharge) routed over wetland surfaces and through permeable upper peat layers. Melt intensity was less in the subsequent year (maximum of 10 mm day^?1) and active layer development was relatively greater (0·2 m deeper at the end of spring melt), resulting in less slope runoff. Coupling of reduced slope contributions with lower storage levels in basin wetlands led to relatively subdued streamflows dominated by older water (73% of the 0·09 m³ s^?1 peak discharge) routed through less‐permeable deeper peat layers and mineral soil. Interannual differences in runoff conditions provide important insight for the development of distributed hydrological models for boreal forest basins and into potential influences on biogeochemical cycling in this landscape under a warming climate. Copyright © 2001 John Wiley & Sons, Ltd.     

Soil profile evolution following land‐use change: implications for groundwater quantity and quality

Soil and vadose zone profiles are used as an archive of changes in groundwater recharge and water quality following changes in land use in an area of the Loess Plateau of China. A typical rain‐fed loess‐terrace agriculture region in Hequan, Guyuan, is taken as an example, and multiple tracers (chloride mass balance, stable isotopes, tritium and water chemistry) are used to examine groundwater recharge mechanisms and to evaluate soil water chloride as an archive for recharge rate and water quality. Results show that groundwater recharge beneath natural uncultivated grassland, used as a baseline, is about 94–100 mm year^?1 and that the time it takes for annual precipitation to reach water table through the thick unsaturated zone is from decades to hundreds of years (tritium free). This recharge rate is 2–3 orders of magnitude more than in the other semiarid areas with similar annual rainfall but with deep‐rooted vegetation and relatively high temperature. Most of the water that eventually becomes recharge originally infiltrated in the summer months. The conversion from native grassland to winter wheat has reduced groundwater recharge by 42–50% (50–55 mm year^?1 for recharge), and the conversion from winter wheat to alfalfa resulted in a significant chloride accumulation in the upper soil zone, which terminated deep drainage. The paper also evaluates the time lag between potential recharge and actual recharge to aquifer and between increase in solute concentration in soil moisture and that in the aquifer following land‐use change due to the deep unsaturated zone. Copyright © 2012 John Wiley & Sons, Ltd.     

Influence of melt‐freeze‐cycles on the radionuclide transport in homogeneous laboratory snowpack

Radionuclides released to the environment and deposited with or onto snow can be stored over long time periods if ambient temperature stays low, particularly in glaciated areas or high alpine sites. The radionuclides will be accumulated in the snowpack during the winter unless meltwater runoff at the snow base occurs. They will be released to surface waters within short time during snowmelt in spring. In two experiments under controlled melting conditions of snow in the laboratory, radionuclide migration and runoff during melt‐freeze‐cycles were examined. The distribution of Cs‐134 and Sr‐85 tracers in homogeneous snow columns and their fractionation and potential preferential elution in the first meltwater portions were determined. Transport was associated with the percolation of meltwater at ambient temperatures above 0 °C after the snowpack became ripe. Mean migration velocities in the pack were examined for both nuclides to about 0.5 cm hr^?1 after one diurnal melt‐freeze‐cycle at ambient temperatures of ?2 to 4 °C. Meltwater fluxes were calculated with a median of 1.68 cm hr^?1. Highly contaminated portions of meltwater with concentration factors between 5 and 10 against initial bulk concentrations in the snowpack were released as ionic pulse with the first meltwater. Neither for caesium nor strontium preferential elution was observed. After recurrent simulated day‐night‐cycles (?2 to 4 °C), 80% of both radionuclides was released with the first 20% of snowmelt within 4 days. 50% of Cs‐134 and Sr‐85 were already set free after 24 hr. Snowmelt contained highest specific activities when the melt rate was lowest during the freeze‐cycles due to concentration processes in remaining liquids, enhanced by the melt‐freeze‐cycling. This implies for natural snowpack after significant radionuclide releases, that long‐time accumulation of radionuclides in the snow during frost periods, followed by an onset of steady meltwater runoff at low melt rates, will cause the most pronounced removal of the contaminants from the snow cover. This scenario represents the worst case of impact on water quality and radiation exposure in aquatic environments.     

Using stable isotopes to estimate travel times in a data‐sparse Arctic catchment: Challenges and possible solutions

Use of isotopes to quantify the temporal dynamics of the transformation of precipitation into run‐off has revealed fundamental new insights into catchment flow paths and mixing processes that influence biogeochemical transport. However, catchments underlain by permafrost have received little attention in isotope‐based studies, despite their global importance in terms of rapid environmental change. These high‐latitude regions offer limited access for data collection during critical periods (e.g., early phases of snowmelt). Additionally, spatio‐temporal variable freeze–thaw cycles, together with the development of an active layer, have a time variant influence on catchment hydrology. All of these characteristics make the application of traditional transit time estimation approaches challenging. We describe an isotope‐based study undertaken to provide a preliminary assessment of travel times at Siksik Creek in the western Canadian Arctic. We adopted a model–data fusion approach to estimate the volumes and isotopic characteristics of snowpack and meltwater. Using samples collected in the spring/summer, we characterize the isotopic composition of summer rainfall, melt from snow, soil water, and stream water. In addition, soil moisture dynamics and the temporal evolution of the active layer profile were monitored. First approximations of transit times were estimated for soil and streamwater compositions using lumped convolution integral models and temporally variable inputs including snowmelt, ice thaw, and summer rainfall. Comparing transit time estimates using a variety of inputs revealed that transit time was best estimated using all available inflows (i.e., snowmelt, soil ice thaw, and rainfall). Early spring transit times were short, dominated by snowmelt and soil ice thaw and limited catchment storage when soils are predominantly frozen. However, significant and increasing mixing with water in the active layer during the summer resulted in more damped steam water variation and longer mean travel times (~1.5 years). The study has also highlighted key data needs to better constrain travel time estimates in permafrost catchments.     

Seepage response along an alluvial valley in a semi‐arid catchment in north‐central California

Over a period of 12 months, soil moisture content and potential was monitored in an annual‐grass‐dominated 20 ha catchment in order to determine flow paths leading to exfiltration at the catchment outlet. Water was found to enter the catchment valley either through flow originating in the slopes or through surface infiltration during rainfall events. Although subsurface flow from the slopes to the catchment outlet occurred throughout the year, surface recharge was restricted to a few events during the wet season. In the deeper saturated profile of the valley, flow was directed upwards along the valley edges and gradually became horizontal towards the central axis of the valley. During the peak of the rainfall season, horizontal flow close to the catchment outlet intercepted the gradually sloping surface, resulting in exfiltration. Plants influenced the hydrology of the catchment by removing moisture from the root zone during spring and early summer, resulting in evapotranspiration losses from the vadose zone. Heterogeneities within the valley soil were evident as variable‐permeability layers that resulted in a seasonally confined water table within the valley. This investigation shows that the vadose zone plays an important role in redistributing surface recharge and emphasizes the importance of accounting for effective moisture in low‐yielding catchments with ephemeral surface runoff. Copyright © 2002 John Wiley & Sons, Ltd.     

Water source dynamics of high Arctic river basins

Arctic river basins are amongst the most vulnerable to climate change. However, there is currently limited knowledge of the hydrological processes that govern flow dynamics in Arctic river basins. We address this research gap using natural hydrochemical and isotopic tracers to identify water sources that contributed to runoff in river basins spanning a gradient of glacierization (0–61%) in Svalbard during summer 2010 and 2011. Spatially distinct hydrological processes operating over diurnal, weekly and seasonal timescales were characterized by river hydrochemistry and isotopic composition. Two conceptual water sources (‘meltwater’ and ‘groundwater’) were identified and used as a basis for end‐member mixing analyses to assess seasonal and year‐to‐year variability in water source dynamics. In glacier‐fed rivers, meltwater dominated flows at all sites (typically >80%) with the highest contributions observed at the beginning of each study period in early July when snow cover was most extensive. Rivers in non‐glacierized basins were sourced initially from snowmelt but became increasingly dependent on groundwater inputs (up to 100% of total flow volume) by late summer. These hydrological changes were attributed to the depletion of snowpacks and enhanced soil water storage capacity as the active layer expanded throughout each melt season. These findings provide insight into the processes that underpin water source dynamics in Arctic river systems and potential future changes in Arctic hydrology that might be expected under a changing climate. Copyright © 2013 John Wiley & Sons, Ltd.     

Evidence for seasonal subglacial outburst events at a polythermal glacier,Finsterwalderbreen, Svalbard

Bulk runoff and meteorological data suggest the occurrence of two meltwater outburst events at Finsterwalderbreen, Svalbard, during the 1995 and 1999 melt seasons. Increased bulk meltwater concentrations of Cl^? during the outbursts indicate the release of snowmelt from storage. Bulk meltwater hydrochemical data and suspended sediment concentrations suggest that this snowmelt accessed a chemical weathering environment characterized by high rock:water ratios and long rock–water contact times. This is consistent with a subglacial origin. The trigger for both the 1995 and 1999 outbursts is believed to be high rates of surface meltwater production and the oversupply of meltwater to areas of the glacier bed that were at the pressure melting point, but which were unconnected to the main subglacial drainage network. An increase in subglacial water pressure to above the overburden pressure lead to the forcing of a hydrological connection between the expanding subglacial reservoir and the ice‐marginal channelized system. The purging of ice blocks from the glacier during the outbursts may indicate the breach of an ice dam during connection. Although subglacial meltwater issued continually from the glacier terminus via a subglacial upwelling during both melt seasons, field observations showed outburst meltwaters were released solely via an ice‐marginal channel. It is possible that outburst events are a seasonal phenomenon at this glacier and reflect the periodic drainage of meltwaters from the same subglacial reservoir from year to year. However, the location of this reservoir is uncertain. A 100 m high bedrock ridge traverses the glacier 6·5 km from its terminus. The overdeepened area up‐glacier from this is the most probable site for subglacial meltwater accumulation. Copyright © 2001 John Wiley & Sons, Ltd.     

Hydrology and nitrogen balance of a seasonally inundated Danish floodplain wetland

This paper characterizes a seasonally inundated Danish floodplain wetland in a state close to naturalness and includes an analysis of the major controls on the wetland water and nitrogen balances. The main inputs of water are precipitation and percolation during ponding and unsaturated conditions. Lateral saturated subsurface flow is low. The studied floodplain owes its wetland status to the hydraulic properties of its sediments: the low hydraulic conductivity of a silt–clay deposit on top of the floodplain maintains ponded water during winter, and parts of autumn and spring. A capillary fringe extends to the soil surface, and capillary rise from groundwater during summer maintains near‐saturated conditions in the root zone, and allows a permanently very high evapotranspiration rate. The average for the growing season of 1999 is 3·6 mm day^?1 and peak rate is 5·6 mm day^?1. In summer, the evapotranspiration is to a large degree supplied by subsurface storage in a confined peat layer underlying the silt–clay. The floodplain sediments are in a very reduced state as indicated by low sulphate concentrations. All nitrate transported into the wetland is thus denitrified. However, owing to modest water exchange with surrounding groundwater and surface water, denitrification is low; 71 kg NO₃–N ha^?1 during the study period of 1999. Reduction of nitrate diffusing into the sediments during water ponding accounts for 75% of nitrate removal. Biomass production and nitrogen uptake in above‐ground vegetation is high—8·56 t dry matter ha^?1 year^?1 and 103 kg N ha^?1 year^?1. Subsurface ammonium concentrations are high, and convective upward transport into the root zone driven by evapotranspiration amounted to 12·8 kg N ha^?1year^?1. The floodplain wetland sediments have a high nitrogen content, and conditions are very favourable for mineralization. Mineralization thus constitutes 72% of above‐ground plant uptake. The study demonstrates the necessity of identifying controlling factors, and to combine surface flow with vadose and groundwater flow processes in order to fully comprehend the flow and nitrogen dynamics of this type of wetland. Copyright © 2004 John Wiley & Sons, Ltd.     

ROAD SALT ACCUMULATION IN HIGHWAY SNOW BANKS AND TRANSPORT THROUGH THE UNSATURATED ZONE OF THE OAK RIDGES MORAINE,SOUTHERN ONTARIO

Pathways and fate of road deicing salt (NaCl) applied during the 1994–1995 winter were studied for a 14-km section of a major highway that crosses the Oak Ridges Moraine in southern Ontario. Total salt applications over the winter ranged from 29 to 74 kg m⁻¹ of highway, and NaCl concentrations in snow banks adjacent to the roadway reached 9400 mg l⁻¹ during the later stages of snow cover development. This salt was released to the ground surface during snowmelt. Sodium chloride (NaCl) loadings to soil from snow cover during the final melt phase were relatively uniform along the study section (3–5 kg NaCl m⁻¹ of highway). However, the snowpack at all transects retained <50% of applied NaCl, and this shortfall probably reflected direct runoff and infiltration of saline meltwater from the road surface into the adjacent shoulder and right-of-way. Cation exchange with Ca²⁺ in near-surface soils most likely resulted in preferential retention of Na⁺ relative to Cl⁻, although total storage of NaCl in upper soil horizons by winter's end was <15% of deicing salt applications. An environmental tracer (¹⁸O) was used to trace movement of saline meltwater through the unsaturated zone underlying the highway. Average meltwater particle velocities at a site underlain by loam soils were 0.02 m d⁻¹, and ca. 280 mm of water was displaced below a depth of 1.86 m over a 78-day period in the spring and summer of 1995. Sodium ion and chloride ion concentrations in water sampled in late summer 1995 at depths >2 m exceeded 500 mg l⁻¹ and 1000 mg l⁻¹, respectively. Approximately 75% of the net flux of NaCl below the upper soil was retained in the 0–2.8 m depth interval at this site, and results from more permeable soils traversed by the highway indicate an even greater penetration of the annual NaCl application into the unsaturated zone along the moraine. This saline water likely recharges groundwater in this portion of the Oak Ridges Moraine.     

Hydrological and hydrochemical response of a small canadian shield catchment to late winter rain-on-snow events

A study was undertaken during the winter of 1990–1991 in a small (3.7 ha) Canadian Shield catchment to examine the hydrological and hydrochemical response during rain-on-snow events. The results are presented of two large (37.9 and 34.6 mm) rain-on-snow events occurring in early and late March 1991. Peak and total runoff and the groundwater response from the two events are significantly different. Hydrological data indicate that these differences can be attributed to a combination of meteorological (temperature) and physical conditions (antecedent snowpack ripeness, soil moisture and groundwater levels). An immature snowpack (low temperature and density) combined with low antecedent soil moisture conditions significantly reduced the magnitude of the net hydrological input and runoff from the catchment during the early March event, whereas a more mature snowpack and high antecedent soil moisture conditions led to a large runoff event during late March. During both rain-on-snow events a significant portion of the pre-event snowpack chemical load was lost. Based on the maximum snowpack chemical load measured before the events, the two large rain-on-snow events and a brief mid-March warm period during which there were two much smaller rain-on-snow events removed 78% of the hydrogen ion and 63% of the sulphate and nitrate load from the snowpack, while only reducing snowpack water equivalence by 7%. A two-component (rain and snowmelt) isotopic (δ¹⁸O SMOW %₀) separation of snowmelt lysimeter water during the two events indicated that snowmelt was an important (50 and 65%, respectively) water source available for infiltration and runoff at the snow-soil interface. Considering the high hydrogen ion loadings to the catchment during these two events (3.3 and 3.0 mequiv.m^?2, respectively) streamflow pH was not significantly reduced due to an increase in the discharge of well-buffered groundwater. A two-component isotopic hydrograph separation of peak stream discharge during the 2–3 March event indicated that 75% of the total flow was groundwater. In mid-latitude acid-sensitive catchments, winter rain-on-snow events are an important hydrological occurrence due to their ability to elute much of the chemical load (H⁺, SO₄, NO₃) from the snowpack before the onset of spring melt when the maximum annual hydrological input typically occurs.     

Characteristics of soil moisture in permafrost observed in East Siberian taiga with stable isotopes of water

Soil moisture and its isotopic composition were observed at Spasskaya Pad experimental forest near Yakutsk, Russia, during summer in 1998, 1999, and 2000. The amount of soil water (plus ice) was estimated from volumetric soil water content obtained with time domain reflectometry. Soil moisture and its δ¹⁸O showed large interannual variation depending on the amount of summer rainfall. The soil water δ¹⁸O decreased with soil moisture during a dry summer (1998), indicating that ice meltwater from a deeper soil layer was transported upward. On the other hand, during a wet summer (1999), the δ¹⁸O of soil water increased due to percolation of summer rain with high δ¹⁸O values. Infiltration after spring snowmelt can be traced down to 15 cm by the increase in the amount of soil water and decrease in the δ¹⁸O because of the low δ¹⁸O of deposited snow. About half of the snow water equivalent (about 50 mm) recharged the surface soil. The pulse of the snow meltwater was, however, less important than the amount of summer rainfall for intra‐annual variation of soil moisture. Excess water at the time just before soil freezing, which is controlled by the amount of summer rainfall, was stored as ice during winter. This water storage stabilizes the rate of evapotranspiration. Soil water stored in the upper part of the active layer (surface to about 120 cm) can be a water source for transpiration in the following summer. On the other hand, once water was stored in the lower part of the active layer (deeper than about 120 cm), it would not be used by plants in the following summer, because the lower part of the active layer thaws in late summer after the plant growing season is over. Copyright © 2002 John Wiley & Sons, Ltd.