The investigation on particulate organic carbon fluxes with disequilibria between thorium-234 and uranium-238 in the Prydz Bay, the Southern Ocean

Dissolved and particulate thorium-234, particulate organic carbon in the upper 150 m of water columns from five stations in the Prydz Bay, the Southern Ocean were determined during the 22nd Chinese National Antarctic Research Expedition （from November 2005 to March 2006 ）. The disequilibria between thorium-234 and its parent uranium-238 in upper layer was used to derive the averaged residence time of thorium-234, which decreased along with the latitude to the south and a minimum value, 1 - 8 d for particulate thorium-234 and 29 - 48 d for dissolved thorium-234, appeared at the medium latitude station, and the export fluxes of thorium-234 were calculated too and ＇a maximum value, 0. 35 -0. 63 Bq/（m^3 · d） for the particulate thorium-234 and 0. 44 -0. 65 Bq/ （m^3 ·d） for the dissolved thorium-234, appeared at the same station. The export fluxes of particulate organic carbon at different water columns were derived by two methods with irreversible scavenging model, and the averaged values were 104. 7 mmol/ （ m2 · d ） （ E method） and 120. 6 mmol/（ m2·d ） （ B method ）, respectively, indicating that a relatively high new production would exist in summer in the Prydz Bay where it will play a potential significant role in sequestering the absorption CO2 to deeper ocean.     

Size-fractionated uranium isotopes in surface waters in the Jiulong Estuary in China

Surface water was collected from the Jiulong Estuary for determination of activity concentrations of uranium isotopes in different size fractions, namely, greater than 53, 10 -53, 2 - 10, 0.4 -2 μm, 10 000 u -0.4 μm and less than 10 000 u fractions by microfihration and cross-flow uhrafiltration technologies. Results indicated that most of the dissolved uranium （ 〈 0.4 μm） exis- ted in the low molecular mass fraction （ 〈 10 000 u）, and the colloidal uranium-238 （10 000 u -0.4 μm） only contributed less than 1% of the dissolved uranium-238. The fractions of colloidal uranium in the dissolved phases decreased with the increasing sa- linity. A positive linear relationship between uranium-238 activities and salinities was observed for the dissolved, colloidal and low molecular mass fractions, indicating a conservative behavior of uranium in the Jiulong Estuary. In the particulate phases （ 〉 0.4 μm）, the partitioning of uranium isotopes among different size fractions was controlled by the partitioning of particle concentrations. In the regions with salinities below 20, the partitioning of uranium-238 among different size fractions was as follows： 10 - 53 μm 〉 2 - 10 μm 〉 0.4 - 2 μm greater than above 53 μm. However, the order at the offshore station with salinities above 30 changed as follows ： 0.4 - 2 μm 〉 10 - 53 μm 〉 2 - 10 μm greater than above 53 μm. The fraction of the 0.4 - 2 μm particles increased at the offshore station, suggesting the increased contribution of the authigenic uranium. The activity ratio of uranium-234 to uranium-238 in the dissolved phases, including the low molecular mass fraction and the colloidal fraction, was larger than unity, showing the occurrence of excess uranium-234. In contrast, the activity ratio of uranium-234 to uranium-238 in all size fractions of the particulate phase was close to the equilibrium value （1.0）. The observed different values of the activity ratio of uranium-234 to uranium-238 in the dissolved phase and the partic     

Regional estimates of POC export flux derived from thorium-234 in the western Arctic Ocean

1Introduction CarboncyclingintheArcticOceanplaysanim- portantroletoglobalchange.Traditionally,marine productivityintheArcticOceanisthoughttobevery low,andthussomebiogeochemicalprocessessuchas particleexportandcyclingofnutrientsarenotsoac- tivebecauseofthembeingcoveredperenniallybyice, lowtemperatureandshorttimeofphotosynthesis (PlattandRao,1975).Afewpreviousestimatesof particulateorganiccarbon(POC)exportindicateda neglectablemagnitudeinthecentralArcticOcean (Baconetal.,1989).However,recen…     

Influence of particle composition on thorium scavenging in the marginal China seas

Thorium-234 and particle composition (organic matter, biogenic silica, carbonate and lithogenic component) were examined in the East China Sea (ECS) and the northern South China Sea (NSCS) in order to constrain the particle types scavenging thorium isotopes. Good positive correlations between particulate organic matter (POM) or carbonate and thorium-234 in suspended particulate matter (SPM) indicates that POM and carbonate are efficient to scavenge thorium-234. No relationship between biogenic silica and thorium-234 suggests that geochemical behavior of thorium-234 may be not influenced by biogenic silica. A simple model was used to evaluate the affinity of thorium-234 to different particle components. The results show that POM is the most efficient scavenger for thorium-234 in the ECS and the NSCS, followed by carbonate. The authors'' results lend support to the utility of thorium-234 as a proxy of POC and carbonate in the upper layer. However, the strong dependence of thorium scavenging on particle composition challenges thorium-230 as a constant flux proxy.     

西北冰洋表-底层碳动力学耦合作用的同位素(13C,234Th)指示

The coupling of upper ocean-benthic carbon dynamics in the ice-free western Arctic Ocean(the Chukchi Sea and the Canada Basin) was evaluated during the late July–early September 2003 using natural stable(13C) and radioactive(238U-234Th) isotope tracers. POC export flux estimated from 234Th/238 U disequilibria and dissolved CO2 concentration([CO2(aq)]) pointed out that the strengthened biological pump in the Chukchi Shelf have significantly lowered [CO2(aq)] and altered the magnitude of isotopic(12C/13C) fractionation during carbon fixation in the surface ocean. Further, d13 C signatures of surface sediments(d13Csed) are positively correlated to those of weighted d13 CPOC in upper ocean(d13Csed =13.64+1.56×d13CPOC, r2=0.73, p0.01), suggesting that the POC isotopic signals from upper ocean have been recorded in the sediments, partly due to the rapid export of particles as evidenced by low residence times of the highly particle-reactive 234 Th from the upper water column. It is suggested that there probably exists an upper ocean-benthic coupling of carbon dynamics, which likely assures the sedimentary d13 C record an indicator of paleo-CO2 in the western Arctic Ocean.     

Utilizing ~(234)Th/~(238)U disequilibrium to constrain particle dynamics in hydrothermal plumes in the Southwest Indian Ocean

Metal-enriched minerals have been widely observed near hydrothermal vent fields.However,the dynamics of particulate metals influenced by hydrothermal activities is poorly constrained.Here,radioactive ~(234)Th in both dissolved and particulate phases were used to examine the kinetics of particle-reactive metal adsorption,removal,and residence in a newly found hydrothermal plume over the Southwest Indian Ridge.The results showed a relatively low value on ~(234)Th/~(238)U ratios(i.e.,0.73-0.88) compared to the deep oceans,indicating an enhanced adsorption of particle-reactive metals onto particulate matter in the plume.Based on the ~(234)Th-~(238)U disequilibria,the adsorption and sinking rate constants of ~(234)Th averaged(0.009±0.001) d~(-1) and(0.113±0.024) d~(-1) in the hydrothermal plume,corresponding to the residence times of(115±19) d and(16±5) d for dissolved and particulate ~(234)Th,respectively.This timescale allows vent-discharged particle-reactive metals to disperse hundreds to thousands of miles away.Thus,hydrothermal activities might influence the metal distribution in deep ocean over a very large scope.Also,a high sinking flux of(36.2±5.4) B q/(m~2·d) for ~(234)Th was observed for the plume,suggesting an enrichment of metal in particles deposited close to the vent.The enhancement of particle sinking could also benefit the transport of organic carbon and nitrogen and fuel the benthic ecosystems under the plume regimes.Thus,hydrothermal plumes may have an impact on both the elemental geochemistry and/or ecosystem to the deep oceans interior than previous expectation.     

南大洋普里兹湾基于234Th/238U不平衡法的POC输出通量研究

中国第22次南极科学考察(2005年11月至2006年3月)期间,测定了南极普里兹湾海域5个站位的从表层至150 m水深的不同层位水样中溶解态和颗粒态234Th,238U的放射性比活度以及颗粒有机碳.利用234Th/238U在上层水体中的不平衡,计算了南极普里兹湾上层水体中234Th的平均停留时间和输出通量.结果显示,随着纬度的增加,上层水体中颗粒态和溶解态234Th的平均停留时间总体趋向减小,并在中纬度站位出现了最低值,分别为1~8和29~48 d,而颗粒态和溶解态234Th的输出通量则在中纬度站位出现了最大值,分别为21~38和26~39 dpm/(m3·d).运用箱型清除模式,利用两种不同的方法估算了各水柱中从真光层底部输出的POC通量,平均值分别达到104.7 mmol/(m2·d)(E法)和120.6 mmol/(m2·d)(B法),表明南极普里兹湾夏季存在很高的新生产力,它将会对该海域碳的生物泵过程产生重要作用.     

热带印度洋偶极子发生和演变机制的数值研究

对中国科学院大气物理研究所(IAP)大气科学和地球流体力学数值模拟国家重点实验室(LASG)发展的第三代海洋模式(L30T63 OGCM)进行了改进。分析了该模式1959年1月—1998年12月的40a积分结果，以此研究热带印度洋偶极子发生、发展和消亡的物理机制。对数值模拟结果的分析表明，赤道印度洋表面异常东风引起的异常环流结构是偶极子发生、发展的主要动力学原因，其表面异常东风转换为异常西风所引起的异常环流结构调整是偶极子消亡的主要动力学原因；海气界面热通量异常的交换对热带印度洋海表温度距平偶极子模态的形成和演变起着重要的作用；垂直输送作用是热带印度洋次表层海温偶极子模态发生和演变的主要物理机制。     

印度洋海底压强的季节和长期变化

利用2003—2015年的重力恢复和气候实验(Gravity Recovery and Climate Experiment, GRACE)卫星观测数据, 揭示了印度洋海底压强的变化特征, 并探讨了其变化机制。结果表明, 印度洋海底压强具有显著的季节变化特征, 北半球冬季在40°S以北(南), 海底压强呈负(正)异常, 夏季分布与冬季相反。印度洋区域的海底压强空间分布与Ekman输送空间分布有较好的对应关系。正压涡度方程诊断结果表明, 利用风场重构的海底压强能够较好地解释印度洋海底压强的季节和长期变化。此外, 海平面变化收支分析表明, 海底压强的变化在高纬度区域主导了海平面变化。     

太平洋-印度洋暖池次表层水温与南海夏季风爆发

为探索太平洋—印度洋热带海域次表层水温对南海季风的影响,用Argo剖面浮标等实测资料,分析了太平洋—印度洋暖池次表层水温异常对南海夏季风爆发的影响。结果表明：冬季,太—印暖池次表层水温偏暖（冷）时,翌年南海夏季风爆发时间偏早（晚）是主要现象。太—印暖池次表层水温偏暖,可能引起Walker环流加强,西太平洋副热带高压偏弱,中心位置偏北偏东,南海和西太平洋上空对流层下层有气旋性距平环流出现,有利于低空西到西南气流的加强,导致南海夏季风爆发偏早;太—印暖池次表层水温偏冷,可能引起Walker环流东移并减弱,西太平洋副热带高压偏强,中心位置偏南偏西,南海和西太平洋上空对流层下层有反旋性距平环流出现,不利于低空西到西南气流的加强,导致南海夏季风爆发偏晚。结论：冬季,太—印暖池次表层水温偏暖（冷）,翌年南海夏季风爆发时间偏早（晚）是主要现象。     

太平洋波高成份研究

利用Topex／Poseidon卫星高度计1992年10月到1998年12月连续75个月，230个重复周期的有效波高资料对南北太平洋的波高成份进行了分析，结果显示所有的月份，频数密度峰值对应的波高成份因子为1．4，以赤道太平洋海域最高为1．6，南北太平洋海域为1．2左右。7、8、9、10月份太平洋涌浪成份占频数密度累积率的比例大于95％，其余各月占90%左右，表明太平洋海域波高成份以涌浪为主。     

北冰洋与邻近海区海洋-海冰模式的试算与校验

本文将目前先进的大尺度海洋、海冰模式(NEMO3.6和LIM3)应用于北大西洋–北冰洋–北太平洋(简称NAPA),并进行了试验后报模拟。所建立的模式NAPA1/4和NAPA1/12的水平分辨率分别为(1/4)°和(1/12)°经、纬度,计算范围覆盖太平洋45°N以北海区、整个北冰洋及北大西洋;其中,NAPA1/4和NAPA1/12在北大西洋的边界分别为26°N和7°N。目前,已利用NAPA1/4完成了1993–2015年的后报模拟。本文基于观测数据和已发表文献对模拟结果中的北冰洋海冰变化、环流结构以及水文特征进行了校验。结果表明,NAPA1/4能够再现北冰洋的主要热力与动力过程,可以用来分析海冰、水团、大西洋/太平洋入/出流等的季节与年际变化规律。利用NAPA1/12进行了1993–1996年的模拟计算。初步结果分析表明,提高分辨率可更为精细地刻画北冰洋的海冰、水团和环流的结构。     

POC fluxes from euphotic zone estimated from 234Th deficiency in winter in the northwestern North Pacific Ocean

1IntroductionThefluxesofcarbon,nutrients,andassoci-atedelementsinvolvedinthebiogeochemicalcyclesoutoftheeuphoticzoneareimportantinthestudyofglobalCO2 change.Someworkershaveproposedthatatthesteadystatethefluxofparticulateorganiccarbonoutoftheeuphoticzoneequalsthenewproduction(EppleyandPe-terson,1979;Eppley,1989).Generallytwometh-odscanbeemployedtoobtainthefluxdata.Oneistousesedimenttrapsintheupperocean(<200m)orfloatingsedimenttraps.Thoughthesedimenttraptechnologyhasshowntobeuse-fulfortimeser…     

全球大洋潮汐模式在北印度洋潮汐预报准确性的评估

为评估DTU10、TPXO8、GOT00.2和NAO.99b 4个全球大洋潮汐模式对北印度洋潮汐的预报能力,采用英国海洋资料中心提供的海区中部和沿岸站潮汐调和常数资料,检验了这些模式4个主要分潮(M_2、S_2、K_1、O_1)的准确度。它们的各分潮调和常数资料准确度都比较高,振幅绝均差的最大值仅5.61 cm,迟角绝均差的最大值仅9.13°。这些模式的调和常数给出潮波传播特征差别不大。基于这些模式提供的调和常数,分别建立了北印度洋4、8和16分潮潮汐预报模型,将预报结果与中国海事服务网提供的沿岸24个站潮汐表资料进行对比。各模式的8分潮(M_2、S_2、N_2、K_2、K_1、O_1、P_1、Q_1)潮汐预报模型均优于4分潮(M_2、S_2、K_1、O_1)潮汐预报模型,NAO.99b模式可以提供16分潮(M_2、S_2、N_2、K_2、K_1、O_1、P_1、Q_1、MU_2、NU_2、T_2、L_2、2N_2、J_1、M1、OO_1)潮汐预报模型,但是对预报结果改善不明显;在各模式中,GOT00.2模式的8分潮潮汐预报模型对北印度洋沿岸的预报效果最好,平均绝均差为14.97 cm。     

Comparison of Grid Averaged Altimeter and Buoy Significant Wave Heights in the Northern Indian Ocean

A quantitative comparison of the collocated inter-annual significant wave height (SWH) data collected between 2006 and 2009 from buoys and altimeters at nine buoy locations (total n = 2241) in the Northern Indian Ocean is attempted for assessing the validity of daily averaged gridded altimeter significant wave height (ASWH) provided by AVISO for operational use. ASWH is underestimated by 0.20 m, the root-mean-square error (RMSE) is less than 0.30 m, the Scatter Index is less than 20%, and the correlation coefficient is greater than 0.90. Further, at three locations, the examination of the above statistics showed that the bias and RMSE is high during the southwest monsoon season compared with the Northeast monsoon. Scatter Index showed only slight variation (14–18%) for different ranges of SWH. The response of the daily average gridded ASWH data during extreme conditions (cyclones) in the vicinity of the buoy locations is poor at all compared buoy locations. The gridded ASWH from different satellite missions provided by AVISO can be used for basin scale validation experiments of the wave model and for climatological studies in the Indian Ocean, except during cyclone conditions.     

On the history of meridional overturning circulation schematic diagrams

Recent global warming caused by humans and the prediction of a reduced Atlantic Ocean meridional overturning circulation in the future has increased interest in the role of the overturning circulation in climate change. A schematic diagram of the overturning circulation called the “Great Ocean Conveyor Belt,” published by Wallace Broecker in 1987, has become a popular image that emphasizes the inter-connected ocean circulation and the northward flux of heat in the Atlantic. This seems a good time to review the development of the conveyor belt concept and summarize the history of overturning circulation schematics.In the 19th century it was thought that symmetric overturning circulation cells were located on either side of the equator in the Atlantic. As new hydrographic measurements were obtained, circulation schematics in the early 20th century began to show the inter-hemispheric overturning circulation in the Atlantic. In the second half of the 20th century schematics showed the global ocean overturning circulation including connections between the Atlantic and the Pacific and Indian Oceans. Some recent schematics of the overturning circulation show its complexities, but as more information is included these schematics have also become complex and not as easy to understand as the simple Broecker 1987 version. However, these complex schematics, especially the quantitative ones, represent valuable syntheses of our developing knowledge of the overturning circulation.     

Contributions of shortwave radiation to the formation of temperature inversions in the Bay of Bengal and eastern equatorial Indian Ocean: A modeling approach

Variations in incoming shortwave radiation influence the net surface heat flux, contributing to the formation of a temperature inversion. The effects of shortwave radiation on the temperature inversions in the Bay of Bengal and eastern equatorial Indian Ocean have never been investigated. Thus, a high-resolution (horizontal resolution of 0.07°×0.07° with 50 vertical layers) Regional Ocean Modeling System (ROMS) model is utilized to quantify the contributions of shortwave radiation to the temperature inversions in the study domain. Analyses of the mixed layer heat and salt budgets are performed, and different model simulations are compared. The model results suggest that a 30% change in shortwave radiation can change approximately 3% of the temperature inversion area in the Bay of Bengal. Low shortwave radiation reduces the net surface heat flux and cools the mixed layer substantially; it also reduces the evaporation rate, causing less evaporative water vapor losses from the ocean than the typical situation, and ultimately enhances haline stratification. Thus, the rudimentary outcome of this research is that a decrease in shortwave radiation produces more temperature inversion in the study region, which is primarily driven by the net surface cooling and supported by the intensive haline stratification. Moreover, low shortwave radiation eventually intensifies the temperature inversion layer by thickening the barrier layer. This study could be an important reference for predicting how the Indian Ocean climate will respond to future changes in shortwave radiation.     

The POC / Th ratio of settling particles isolated using split flow-thin cell fractionation (SPLITT)

The common assumption that the ratio between particulate organic carbon (POC) and particulate ²³⁴Th obtained from shallow sediment traps and filterable particles are representative of the ratio in the total particle settling flux should be treated with caution in view of well-known biases associated with tethered shallow sediment traps and the decoupling between size and settling velocity of many natural particle regimes. To make progress toward reliably constraining the POC / ²³⁴Th ratio on truly settling particles, we have tested here a settling collection technique designed to remove any hydrodynamic bias; split flow-thin cell fractionation (SPLITT). These first results from a North Sea fjord and an open Baltic Sea time-series station indicates that the POC / ²³⁴Th ratio on the more complete particle-settling spectrum, isolated with SPLITT, was higher than the POC / ²³⁴Th ratio obtained simultaneously from tethered shallow sediment traps in seven out of seven parallel deployments with an average factor of 210%. The POC / ²³⁴Th ratio from the SPLITT was either in the same range or higher than that obtained on filtered “bulk” particles. To explain this novel data we hypothesize that the slowest settling fraction is organic-matter rich and does not strongly complex ²³⁴Th (i.e., high POC / ²³⁴Th). We suggest that this ultra-slow sinking fraction is better collected by SPLITT than with tethered sediment traps because of minimized hydrodynamic bias.This was tested using the ratio of POC / Al as a tracer of detrital mineral-ballast influenced settling velocity. The higher POC / Al ratios in SPLITT samples relative to in traps is consistent with the hypothesis that SPLITT is better suited for collecting also the slow-settling component of sinking particles. This important slow-settling component appears to here consist primarily of non-APS/TEP components of plankton exudates or other less-strongly ²³⁴Th-complexing organic matter. Further applications of the SPLITT technique are likely to return increasingly new insights on the composition (including “truly settling” POC / ²³⁴Th) of the total spectrum of particles settling out of the upper ocean.     

Dynamics of seasonal and interannual variability of the ocean bottom pressure in the Southern Ocean

Seasonal and interannual variability of ocean bottom pressure(OBP) in the Southern Ocean was investigated using Gravity Recovery and Climate Experiment(GRACE) data and a Pressure Coordinate Ocean Model(PCOM)based on mass conservation. By comparing OBP, steric sea level, and sea level, it is found that at high latitudes the OBP variability dominates the sea level variability at seasonal-to-decadal time scales. The diagnostic OBP based on barotropic vorticity equation has a good correlation with t...     

海洋激光荧光雷达海面油膜种类鉴别研究

海洋激光雷达在探测海面油荧光方面的应用 ,受到广泛重视。海洋激光荧光雷达是以物质荧光谱理论为基础 ,将荧光技术应用于海面油膜检测领域。本文介绍了激光荧光原理 ,青岛海洋大学海洋激光雷达的基本结构和工作过程 ,以及该套系统进行海面油膜种类鉴别的使用方法和适用范围。通过实验证明 ,该套系统性能可靠 ,测量值稳定 ,能够进行一定程度上的油荧光测量。提出采用荧光强度 4 35 / 380 ,4 35 / 5 0 0 ,4 35 / 5 5 0 ,3个比值作为油样荧光特性的描述值进行油种鉴别。相对其他的鉴别方法 ,三比值法无须配置溶液 ,适于现场测量。根据系统响应情况提取的特征值不但更有针对性 ,而且由于特征值数量多 ,对荧光谱分布曲线的描述更加准确。