内蒙古临河区地下水补径排特征及动态变化规律

查明地下水的补给、径流、排泄特征及动态变化规律,可为地下水资源开发与保护提供科学依据。通过长期观测内蒙古临河区地下水变化,综合研究前人资料,分析该区地下水补给、径流和排泄特征及动态变化规律。该区属于河套灌区,人类灌溉活动对地下水的补给占全部补给量的65.5%;人工开采及排干沟排泄等人为因素排泄占排泄总量的67.7%。通过分析该区年内地下水动态变化趋势,认为该区灌溉区地下水位动态与灌溉活动一致,城区地下水位动态主要受人工开采活动影响。     

山东省引黄灌区地下水赋存条件与开发潜力分析

在黄河断流时间遽增、来水量剧减的情况下,如何解决引黄灌区农田灌溉问题？本文通过对山东引黄灌区地下水赋存条件论述和开发利用潜力分析,提出地下水与黄河水互补乃是解决引黄灌区灌溉水源的根本途径。     

化隆—循化盆地不同类型含水层组高氟地下水的分布及形成过程

天然成因的高氟地下水是世界范围内备受关注的环境问题和饮用水安全问题。前人对高氟地下水的形成过程已开展了大量研究,但是对于高原盆地复杂水文地质条件下不同类型含水层组(第四系松散层含水层、基岩裂隙或岩溶含水层以及新生代古近纪以来的碎屑岩含水层)高氟地下水的分布和形成过程尚不明确。本文以化隆—循化盆地为研究区,通过采集、测试研究区内的各类地下水样品,分析研究区内不同类型含水层中地下水的化学特征及同位素特征。结果表明,高氟地下水(1.007.73 mg/L)主要分布在沿黄河的河谷区域和巴燕低山丘陵区域的泉水和潜水中以及深部的承压水中,在垂向上高氟地下水无明显分布规律。接受黄河水入渗补给的河谷潜水中氟离子浓度较低,补给黄河的河谷潜水中氟离子浓度较高。贫钙富钠的弱碱性苏打型水有利于地下水中氟的富集。泉水和潜水中氟主要来源于萤石的溶解,而承压水中氟除了来源于萤石外,还来源于其他含氟矿物。对于潜水和第四系松散层泉水,蒸发浓缩作用促进了地下水中氟的富集。另外,阴离子竞争吸附作用、阳离子交换吸附作用是泉水(第四系松散层泉水和基岩裂隙泉水)和潜水中氟元素富集的主要原因,而承压水中氟离子浓度受竞争吸附作用影响较大,阳离子交换吸附作用影响较小。研究成果可为化隆—循化盆地低氟地下水的勘查和开发提供科学依据。     

关于发展农业节水灌溉的建议

我国北方地区干旱缺水 ,农田灌溉用水量占总用水量 80 %以上。农业节水的主要潜力在河水灌区。要按农业用水量控制灌溉水量 ,要在河水灌区积极开发利用浅层地下水和微咸水。在河水灌区打井 ,发展井渠结合灌溉 ,地表水地下水联合运用 ,是优化利用水资源 ,防治灌区土壤盐碱化的根本途径。必须统一管理水资源并改革水价。     

河套平原中东部地下水的环境同位素特征分析

河套平原由大厚度第四系冲湖积地层组成,地下水水平径流滞缓,以垂向水交替为主。地下水D1、8O3、H同位素特征的分析表明,地下水开发利用和引黄河水灌溉对河套平原中东部地下水循环交替的影响主要是:在没有开采井的地域,灌溉水入渗补给对地下水的影响范围和深度十分有限;在开采井周围,灌溉入渗补给的影响深度、范围和强度明显增加,影响深度取决于主要开采层位,影响范围和强度取决于开采规模。     

青藏高原东缘湖相沉积和黄土高原黄土沉积磁化率与粒度相关性对比*

为探讨构造稳定地区(如黄土高原)和构造活跃地区(如青藏高原东缘)粉尘沉积物中磁化率(SUS)与粒度的相关性及其对环境事件的指示意义,本次研究分析了黄土高原蓝田剖面黄土—古土壤样品和青藏高原东缘湖相沉积样品的粒度和磁化率记录。黄土高原黄土—古土壤沉积SUS与2~10 μm粒度组分最强正相关,青藏高原东缘湖相沉积的SUS与2~10 μm粒度组分最强负相关,反映2~10 μm粒度组分为黄土高原和青藏高原乃至亚洲干旱—半干旱地区连续稳定敏感的背景沉积组分。黄土高原黄土—古土壤沉积的SUS与32~63 μm粒度组分最强负相关,青藏高原东缘湖相沉积的SUS与32~63 μm粒度组分最强正相关,反映32~63 μm粒度组分不仅是黄土高原尘暴事件沉积的敏感指标,也是青藏高原东缘湖相沉积记录的地震事件敏感指标。SUS与粒度组分的相关性在青藏高原东缘地区地震事件层开始部分高于结束部分,也较好地反映地震事件为研究区添加新鲜沉积物后随地形地貌恢复逐步减少的过程。SUS与粒度组分相关性也受当地物源的影响。     

青藏高原东缘湖相沉积和黄土高原黄土沉积磁化率与粒度相关性对比*

为探讨构造稳定地区(如黄土高原)和构造活跃地区(如青藏高原东缘)粉尘沉积物中磁化率(SUS)与粒度的相关性及其对环境事件的指示意义,本次研究分析了黄土高原蓝田剖面黄土—古土壤样品和青藏高原东缘湖相沉积样品的粒度和磁化率记录。黄土高原黄土—古土壤沉积SUS与2~10 μm粒度组分最强正相关,青藏高原东缘湖相沉积的SUS与2~10 μm粒度组分最强负相关,反映2~10 μm粒度组分为黄土高原和青藏高原乃至亚洲干旱—半干旱地区连续稳定敏感的背景沉积组分。黄土高原黄土—古土壤沉积的SUS与32~63 μm粒度组分最强负相关,青藏高原东缘湖相沉积的SUS与32~63 μm粒度组分最强正相关,反映32~63 μm粒度组分不仅是黄土高原尘暴事件沉积的敏感指标,也是青藏高原东缘湖相沉积记录的地震事件敏感指标。SUS与粒度组分的相关性在青藏高原东缘地区地震事件层开始部分高于结束部分,也较好地反映地震事件为研究区添加新鲜沉积物后随地形地貌恢复逐步减少的过程。SUS与粒度组分相关性也受当地物源的影响。     

银川盆地水体氢氧稳定同位素特征分析

中国西北部银川盆地干旱少雨,大量的黄河水用于灌溉,灌溉入渗水对地下水循环的参与程度、参与深度研究是进一步解决灌区水环境问题和确定地下水污染来源的关键,需要深入研究。笔者通过氢氧稳定同位素特征分析和氚同位素年龄分析,构建了银川盆地不同水体同位素特征分布关系。结果表明:银川盆地降水和流经的黄河水的氢氧稳定同位素丰度均值都分布在全球雨水线上,降水和黄河水符合全球大气降水来源;深层地下水、浅层地下水及由地下水排泄汇集的排水沟水的氢氧稳定同位素都分布在地下水拟合线上(δD=8.24δ18O+1.08)。这条地下水拟合线与全球雨水线近似平行分布。两线之间的差异指向2种不同水循环的主导过程,即蒸发-混合主导过程和水岩交互-混合主导过程。两种解释对应的灌溉循环量分别占地下水排泄量的44.07%和89.76%,初步认为水岩交互-混合是地下水拟合线分布于全球雨水线下方的主导过程。     

大型灌区陆地水循环模式的参数化方案:LWCMPS_ID

地表水系统、地下水系统和土壤植物大气连续体的强烈耦合作用是大型灌区水文过程的基本特点,这导致对大型灌区的陆地水循环和水资源进行评价必须采取综合的方法,然而目前还缺少适用的模拟工具。农业灌区的水文特征与天然流域存在显著差别,常规流域水文模型和陆面过程参数化方案用于大型灌区陆地水循环的分析还存在较大的困难。LWCMPS_ID是本文提出的一个适用于大型灌区陆地水循环模式的参数化方案,采用分块集中参数模型简明地实现了地表水、地下水和土壤水的动力学耦合分析,并且包含了一个土壤水冻结融化的简化模型。对处在黄河流域的内蒙古河套灌区,用LWCMPS_ID进行20 年水文动态的模拟,取得了较好的效果。     

内蒙古二连盆地白音查干凹陷下白垩统腾格尔组热水沉积过程中矿物沉淀顺序及其控制因素*

基于岩心、岩石薄片及元素分析等资料,通过偏光显微镜、定量矿物扫描(QemScan)、电子探针、能谱和流体包裹体分析等技术手段,探讨了二连盆地白音查干凹陷下白垩统腾格尔组热水沉积岩中热水沉积矿物的沉淀顺序。研究区热水沉积矿物主要为铝硅酸盐和碳酸盐,含少量黄铁矿、重晶石、萤石等矿物。这些矿物在空间上具有特定的先后关系或位置关系: (1)在纹层状岩层中,由下到上从铝硅酸盐过渡为碳酸盐。在铝硅酸盐矿物组合中,首先出现的是方沸石,其次是钠沸石,再次为钠长石;在碳酸盐矿物中,首先出现的是菱镁矿,其次是菱铁矿,再次为铁白云石,有时还可见到方解石,但其含量很低。(2)在凝絮状团块中,团块中心为黄铁矿,从中心向外依次过渡为方沸石、钠沸石、菱镁矿、菱铁矿,最外层为铁白云石。在纹层状岩层和凝絮状团块中,有时还能见到上述顺序的逆顺序。(3)在后期充填的裂缝中,边部为沸石或绿泥石等铝硅酸盐矿物,向中心逐渐过渡为铁白云石碳酸盐。综合研究区所有的矿物序列来看,最完整的序列应为黄铁矿—钾长石—方沸石—钠沸石—钠长石—菱镁矿—菱铁矿—白云石—方解石,但是这种完整的序列是不常见的,通常仅为其中某几种矿物的组合,然而不管是哪些矿物进行组合,其出现的顺序都不变。推测该矿物序列的类型受热液喷流和溢流阶段、时间、温度和热水化学性质控制,早期高温、高盐度条件下出现的铝硅酸盐矿物序列较多,而晚期主要形成碳酸盐矿物序列。     

The influence of irrigation and Wuliangsuhai Lake on groundwater quality in eastern Hetao Basin,Inner Mongolia,China

Geochemical and isotopic characterization of groundwater and lake-water samples were combined with water and total dissolved solids balances to evaluate sources of groundwater quality deterioration in eastern Hetao Basin, Inner Mongolia, China. Groundwater quality is poor; 11 of 13 wells exceed drinking-water guidelines for at least one health-based parameter and all wells exceed aesthetic guidelines. The well water is largely derived from Yellow River irrigation water. Notably high uranium concentrations in the Yellow River, relative to world rivers, suggest groundwater uranium and other trace elements may originate in the river-derived irrigation water. Complex hydrostratigraphy and spatial variation in groundwater recharge result in spatially complex groundwater flow and geochemistry. Evapotranspiration of irrigation water causes chloride concentration increases of up to two orders of magnitude in the basin, notably in shallow groundwater around Wuliangsuhai Lake. In addition to evapotranspiration, groundwater quality is affected by mineral precipitation and dissolution, silicate weathering, and redox processes. The lake-water and TDS balances suggest that a small amount of discharge to groundwater (but associated with very high solute concentrations) contributes to groundwater salinization in this region. Increasing salinity in the groundwater and Wuliangsuhai Lake will continue to deteriorate water quality unless irrigation management practices improve.     

Influences of groundwater extraction on flow dynamics and arsenic levels in the western Hetao Basin,Inner Mongolia,China

Data on spatiotemporal variations in groundwater levels are crucial for understanding arsenic (As) behavior and dynamics in groundwater systems. Little is known about the influences of groundwater extraction on the transport and mobilization of As in the Hetao Basin, Inner Mongolia (China), so groundwater levels were recorded in five monitoring wells from 2011 to 2016 and in 57 irrigation wells and two multilevel wells in 2016. Results showed that groundwater level in the groundwater irrigation area had two troughs each year, induced by extensive groundwater extraction, while groundwater levels in the river-diverted (Yellow River) water irrigation area had two peaks each year, resulting from surface-water irrigation. From 2011 to 2016, groundwater levels in the groundwater irrigation area presented a decreasing trend due to the overextraction. Groundwater samples were taken for geochemical analysis each year in July from 2011 to 2016. Increasing trends were observed in groundwater total dissolved solids (TDS) and As. Owing to the reverse groundwater flow direction, the Shahai Lake acts as a new groundwater recharge source. Lake water had flushed the near-surface sediments, which contain abundant soluble components, and increased groundwater salinity. In addition, groundwater extraction induced strong downward hydraulic gradients, which led to leakage recharge from shallow high-TDS groundwater to the deep semiconfined aquifer. The most plausible explanation for similar variations among As, Fe(II) and total organic carbon (TOC) concentrations is the expected dissimilatory reduction of Fe(III) oxyhydroxides.     

Suitability assessment of shallow and deep groundwaters for drinking and irrigation use in the El Khairat aquifer (Enfidha, Tunisian Sahel)

The El Khairat aquifer is an important groundwater aquiferous system, which is considered a major source for drinking and irrigation water in Enfidha in Tunisian Sahel. The analysis of groundwater chemical characteristics provides much important information useful in water resources management. Assessing the water quality status for special use is the main objective of any water monitoring studies. An attempt has been made for the first time in this region to appreciate the quality and/or the suitability of shallow and deep groundwater for drinking and irrigation. In order to attend this objective, a total of 35 representative water samples were collected during February 2007 from both boreholes (17) and wells (18); and analyzed for the major cations (sodium, calcium, magnesium and potassium) and anions (chloride, sulphate, bicarbonate, and nitrate) along with various physical and chemical parameters (temperature, pH, total dissolved salts, and electrical conductivity). Based on the physico-chemical analyses, irrigation quality parameters like sodium absorption ratio (SAR), residual sodium carbonate (RSC), percentage of sodium (Na%), and permeability index (PI) were calculated. In addition to this, iso-concentration maps were constructed using the geographic information system to delineate spatial variation of qualitative parameters of groundwater samples. The correlation of the analytical data has been attempted by plotting different graphical representations such as Piper, Wilcox, and US Salinity Laboratory for the classification of water. The suitability of the water from the groundwater sources for drinking and irrigation purposes was evaluated by comparing the values of different water quality parameters with World Health Organization guideline values for drinking water. A preliminary hydrochemical characterization shows that most of the groundwater samples fall in the field of calcium–magnesium–chloride–sulphate type of water. Majority of the samples are not suitable for drinking purposes and far from drinking water standards. The high EC value and the percentage of Na in most of the groundwater render it unsuitable for irrigation. Wilcox classification suggested that around 50% of both deep and shallow groundwater samples are unsuitable for irrigation. According to the US Salinity Classification, most of the groundwater is unsuitable for irrigation unless special measures are adopted.     

Hydrochemical investigation and quality assessment of ground water in rural areas of Delhi,India

The suitability of groundwater quality for drinking and agricultural purposes was assessed in the rural areas of Delhi based on the various water quality parameters. A total of 50 ground water samples were collected randomly from different sources viz. hand pump, tube well, boring and analyzed for major ion chemistry to understand the operating mechanism of geochemical processes for ground water quality. The quality analysis is performed through the estimation of pH, EC, TDS, total hardness, total alkalinity, Na, K, Cl, NO₃, SO₄, DO, BOD, Cu, Cr, Cd, Ni, Zn and Pb. Hydrochemical facies were identified using Piper, Durov and Chadha diagram. Chemical data were also used for mathematical calculations (SAR, %Na, RSC, PI, KI, and chloroalkaline indices) for better understanding the suitability of ground water for irrigation purposes. The results of saturation index shows that all the water samples were supersaturated to undersaturated with respect to carbonate minerals and undersaturated with respect to sulphate and chloride minerals. According to USSL diagram, most of the samples fall in the field of C₃S₁, indicating medium salinity and low sodium water which can be used for almost all types of soil with little danger of exchangeable sodium. Assessment of water samples from various methods indicated that majority of the ground water in the study area is chemically suitable for drinking and agricultural uses.     

Hydrogeochemical parameters for assessment of groundwater quality in the upper Gunjanaeru River basin,Cuddapah District,Andhra Pradesh,South India

In the management of water resources, quality of water is just as important as its quantity. In order to know the quality and/or suitability of groundwater for domestic and irrigation in upper Gunjanaeru River basin, 51 water samples in post-monsoon and 46 in pre-monsoon seasons were collected and analyzed for various parameters. Geological units are alluvium, shale and quartzite. Based on the analytical results, chemical indices like percent sodium, sodium adsorption ratio, residual sodium carbonate, permeability index (PI) and chloroalkaline indices were calculated. The pre-monsoon waters have low sodium hazard as compared to post-monsoon season. Residual sodium carbonate values revealed that one sample is not suitable in both the seasons for irrigation purposes due the occurrence of alkaline white patches and low permeability of the soil. PI values of both seasons revealed that the ground waters are generally suitable for irrigation. The positive values of Chloroalkaline indices in post-monsoon (80%) and in pre-monsoon (59%) water samples indicate absence of base-exchange reaction (chloroalkaline disequilibrium), and remaining samples of negative values of the ratios indicate base-exchange reaction (chloroalkaline equilibrium). Chadha rectangular diagram for geochemical classification and hydrochemical processes of groundwater for both seasons indicates that most of waters are Ca–Mg–HCO₃ type. Assessment of water samples from various methods indicated that majority of the water samples in both seasons are suitable for different purposes except at Yanadipalle (sample no. 8) that requires precautionary measures. The overall quality of groundwater in post-monsoon season in all chemical constituents is on the higher side due to dissolution of surface pollutants during the infiltration and percolation of rainwater and at few places due to agricultural and domestic activities.     

A geochemical assessment of coastal groundwater quality in the Varahi river basin, Udupi District, Karnataka State, India

The Varahi Irrigation project site is located at 13°39′15″N (latitude) and 74°57′E (longitude) in Hole Shankaranarayana village, approximately 6 km from Siddapura, Kundapura taluk, Udupi district. A total of 59 groundwater samples were collected from dug and tube wells in November 2008 to evaluate hydrochemistry and suitability for drinking and irrigation purposes. The physico-chemical parameters estimated include pH, electrical conductivity (EC), total dissolved solids (TDS), redox potential (Eh), total hardness (TH), total alkalinity (TA), temperature, major cations and anions, besides irrigation quality parameters like boron, sodium absorption ratio (SAR), % Na, residual sodium carbonate (RSC), residual sodium bicarbonate (RSBC), chlorinity index, soluble sodium percentage (SSP), exchangeable sodium ratio (ESR), non-carbonate hardness, potential salinity (PS), permeability index (PI), Kelly index (KI), magnesium hazard (MH), magnesium ratio (MR), index of base exchange. Chloride, sulphate and bicarbonate concentrations classified the groundwater samples into normal chloride, normal sulphate and normal bicarbonate water types, respectively. The Salinity (Class I; 98.3%), Chlorinity (Class I; 100%) and Sodicity (Class 0; 96.6%) indices suggest the suitability of groundwater for irrigation. The Wilcox diagram illustrates that 96.6% of the samples belongs to excellent to good category, while the US Salinity Laboratory (USSL) diagram indicates the low salinity/low sodium content in 86.44% of samples (C1S1). Positive index of base exchange in majority of the samples (91.52%) indicates direct base exchange reaction or chloro-alkaline equilibrium in the study area. The positive value of RSC in majority of samples signifying higher concentrations of HCO₃ over alkaline earths indicates that groundwater are base exchange-softened water as there is an exchange of alkaline earths for Na⁺ ions. Majority of water samples fall in the precipitation dominance field based on Gibbs’ ratio.     

内蒙古河套平原塔尔湖地区湖泊成因

内蒙古五原县塔尔湖地区发育一系列湖泊,与当地干旱气候形成鲜明的对比,湖泊成因机制对河套地区第四纪水文地质、气候环境研究具有重要意义。对色尔腾山山前—塔尔湖湖泊—黄河沿线不同水体样品进行水化学测试后,利用Gibbs模型投影显示湖泊采样点主要落在蒸发-浓缩端元和岩石风化端元的过渡带,而远离大气降水作用带,地下水更靠近岩石风化端元,说明湖泊接受地下水补给,蒸发强烈;Piper三线图显示山前泉水以HCO3—Ca型为主,河套平原地下水以HCO3—Na、Cl—Na型为主,黄河水为HCO3—Na型,湖泊以Cl—Na型为主,说明塔尔湖地区地下水与湖泊存在水力联系,HCO3—Na型地下水经过蒸发浓缩作用转变成了盐度更高的Cl—Na型湖泊,导致盐分的聚集;地下水可溶性固体总量(TDS)自北向南由262 mg/l快速增加至2 296 mg/l,而湖泊TDS先升后降,最后小于地下水TDS,最大值在塔尔湖地区北部,为1 213 mg/l,说明湖泊还受现代黄河补给,地下水TDS变化满足山前—盆地的水文地质模型。塔尔湖地区的湖泊既可以发育于古河床亚相也可以发育于堤坝亚相,且湖泊呈零星分布,与古河道形成的牛轭湖特征不吻合,从而基本排除湖泊为古黄河残留的可能;潜水面之上的河流相沉积物由于风蚀作用被切穿,导致地下水出露,补给湖泊,从而推断塔尔湖地区湖泊主要为风蚀湖。     

Evaluation of hydrogeochemical characteristics of groundwater in parts of the lower Benue Trough, Nigeria

The aim of this work is to evaluate the hydrogeochemical characteristics of groundwater in parts of the lower Benue Through in Nigeria as well as to evaluate the variation in groundwater chemistry data and the suitability of the groundwater for drinking and other domestic purposes. This was based on chemical analyses of 44 water samples from existing wells and boreholes in the study area. From the statistical analysis (wide ranges, median and standard deviation), it is obvious that there are significant variations in the quality/composition of groundwater in the period of sampling. The calculated SAR, Na% and RSC values indicated that the water is of excellent to good quality and is suitable for irrigation. Na and HCO₃ are dominant with respect to the chemical composition of the groundwater. On the basis of water chemistry, hydrochemical indices and factor analysis the dominant controls or processes affecting the distribution of geochemical variables in the study area have been shown to be water/rock interaction which is mainly controlled by carbonate and silicate dissolution as well as anthropogenic influence to a lesser extent. Additional processes include cation exchange reactions and reverse ion exchange to a minor extent.     

Major ion chemistry,weathering processes and water quality assessment in upper catchment of Damodar River basin,India

The chemical characteristics of surface, groundwater and mine water of the upper catchment of the Damodar River basin were studied to evaluate the major ion chemistry, geochemical processes controlling water composition and suitability of water for domestic, industrial and irrigation uses. Water samples from ponds, lakes, rivers, reservoirs and groundwater were collected and analysed for pH, EC, TDS, F, Cl, HCO₃, SO₄, NO_3, Ca, Mg, Na and K. In general, Ca, Na, Mg, HCO₃ and Cl dominate, except in samples from mining areas which have higher concentration of SO₄. Water chemistry of the area reflects continental weathering, aided by mining and other anthropogenic impacts. Limiting groundwater use for domestic purposes are contents of TDS, F, Cl, SO₄, NO₃ and TH that exceed the desirable limits in water collected from mining and urban areas. The calculated values of SAR, RSC and %Na indicate good to permissible use of water for irrigation. High salinity, %Na, Mg-hazard and RSC values at some sites limit use for agricultural purposes.