High-Mg# andesitic lavas of the Shisheisky Complex,Northern Kamchatka: implications for primitive calc-alkaline magmatism

Primitive arc magmatism and mantle wedge processes are investigated through a petrologic and geochemical study of high-Mg# (Mg/Mg + Fe > 0.65) basalts, basaltic andesites and andesites from the Kurile-Kamchatka subduction system. Primitive andesitic samples are from the Shisheisky Complex, a field of Quaternary-age, monogenetic cones located in the Aleutian–Kamchatka junction, north of Shiveluch Volcano, the northernmost active composite volcano in Kamchatka. The Shisheisky lavas have Mg# of 0.66–0.73 at intermediate SiO₂ (54–58 wt%) with low CaO (<8.8%), CaO/Al₂O₃ (<0.54), and relatively high Na₂O (>3.0 wt%) and K₂O (>1.0 wt%). Olivine phenocryst core compositions of Fo90 appear to be in equilibrium with whole-rock ‘melts’, consistent with the sparsely phyric nature of the lavas. Compared to the Shisheisky andesites, primitive basalts from the region (Kuriles, Tolbachik, Kharchinsky) have higher CaO (>9.9 wt%) and CaO/Al₂O₃ (>0.60), and lower whole-rock Na₂O (<2.7 wt%) and K₂O (<1.1 wt%) at similar Mg# (0.66–0.70). Olivine phenocrysts in basalts have in general, higher CaO and Mn/Fe and lower Ni and Ni/Mg at Fo88 compared to the andesites. The absence of plagioclase phenocrysts from the primitive andesitic lavas contrasts the plagioclase-phyric basalts, indicating relatively high pre-eruptive water contents for the primitive andesitic magmas compared to basalts. Estimated temperature and water contents for primitive basaltic andesites and andesites are 984–1,143°C and 4–7 wt% H₂O. For primitive basalts they are 1,149–1,227°C and 2 wt% H₂O. Petrographic and mineral compositions suggest that the primitive andesitic lavas were liquids in equilibrium with mantle peridotite and were not produced by mixing between basalts and felsic crustal melts, contamination by xenocrystic olivine, or crystal fractionation of basalt. Key geochemical features of the Shisheisky primitive lavas (high Ni/MgO, Na₂O, Ni/Yb and Mg# at intermediate SiO₂) combined with the location of the volcanic field above the edge of the subducting Pacific Plate support a genetic model that involves melting of eclogite or pyroxenite at or near the surface of the subducting plate, followed by interaction of that melt with hotter peridotite in the over-lying mantle wedge. The strongly calc-alkaline igneous series at Shiveluch Volcano is interpreted to result from the emplacement and evolution of primitive andesitic magmas similar to those that are present in nearby monogenetic cones of the Shisheisky Complex.     

长江中下游中生代安山质火山岩记录的新元古代大洋板片-地幔相互作用

大陆弧安山岩的形成是大洋板片向大陆边缘之下俯冲的结果,但是在具体形成机制上存在很大争议.针对这个问题,对长江中下游地区中生代安山质火山岩及其伴生的玄武质和英安质火山岩进行了系统的岩石地球化学研究,结果对大陆弧安山质火成岩的成因提出了新的机制.分析表明,这些岩石形成于早白垩世,它们不仅表现出典型的岛弧型微量元素分布特征,而且具有高度富集的Sr-Nd-Hf同位素和高的放射成因Pb以及高的氧同位素组成.通过全岩和矿物地球化学成分变化检查发现,地壳混染和岩浆混合作用对其成分的富集特征贡献有限,而其岩浆源区含有丰富的俯冲地壳衍生物质才是其成分富集的根本原因.虽然这些火山岩的喷发年龄为中生代,但是其岩浆源区形成于新元古代早期的华夏洋壳俯冲对扬子克拉通边缘之下地幔楔的交代作用.大陆弧安山岩地幔源区中含有大量俯冲洋壳沉积物部分熔融产生的含水熔体,显著区别于大洋弧玄武岩的地幔源区,其中只含有少量俯冲洋壳来源的富水溶液和含水熔体.正是这些含水熔体交代上覆地幔楔橄榄岩,形成了不同程度富集的超镁铁质-镁铁质地幔源区.在早白垩纪时期,古太平洋俯冲过程的远弧后拉张导致中国东部岩石圈发生部分熔融,其中超镁铁质地幔源区熔融形成玄武质火山岩,镁铁质地幔源区则熔融形成安山质火山岩.因此,大陆弧安山岩成因与大洋弧玄武岩一样,可分为源区形成和源区熔融两个阶段,其中第一阶段对应于俯冲带壳幔相互作用.      

Geochronology and petrogeochemistry of Late Permian volcanic rocks in the B.Xiengnou area,Northwestern Laos: Petrogenesis and tectonic significance

The Nan Suture and Sukhothai Arc Terrane are products of the eastward subduction of the Paleotethyan Ocean during the Late Carboniferous to Triassic. However, their footprints in northwestern Laos are poorly constrained. New geochronological and geochemical data presented in this study demonstrate a Late Permian origin for the andesitic rocks in the B.Xiengnou area rather than Late Triassic. The breccia-bearing andesitic tuff in the B.On ultramafic complex yield a zircon U-Pb age of 260 ± 1.4 Ma, geochemically displaying a MORB-like signature. The andesitic tuff in the B.Kiophoulan-B.Houayhak belt gave the U-Pb age of 254 ± 1.3 Ma, with arc-like geochemical affinity. By combining geochronological and geochemical data from the Nan Suture and Sukhothai Arc Terrane, the authors suggest that the andesitic rocks in the B.On ultramafic complex formed in a back-arc basin background, which connected the Jinghong and Nan back-arc basin during the Permian; while the andesitic tuff in the B.Kiophoulan-B.Houayhak belt erupted in the Sukhothai continental arc setting.©2021 China Geology Editorial Office.     

Petrogenesis and tectonic setting of late Precambrian ensimatic volcanic rocks,central eastern desert of Egypt

Early stages in the geologic evolution of the central eastern desert of Egypt (CED) reflect an intense episode of ensimatic volcanic activity similar to modern magmatism of the ocean floors and island arcs. This paper reports results from studies of the petrology and petrogenesis, and interprets the significance of these Late Precambrian volcanic rocks.A three-fold stratigraphy is preserved in the basement of the CED. A basal section of oceanic crust includes ultramafics, gabbros and pillowed basalts. These older metavolcanics (OMV) are conformably succeeded by dominantly volcanogenic metasediments, which are in turn succeeded by a dominantly andesitic, calc-alkaline sequence of younger metavolcanics (YMV). The OMV and YMV are largely restricted to the CED in Egypt, but analogous terranes are found in northern Arabia. (40–400 ppm) and Ni (30–260 ppm). They are poor in K₂O (0.05–0.92%), Rb (0.3–5.0 ppm) and Ba (11–89 ppm). On Ti-Zr-Cr-V-Ni-P discriminant diagrams, the OMV plot in the field of modern abyssal tholeiites. High K/Rb (450–1800) and light REE depletions support this inference, although K/Ba (25–45) is lower than modern mid-ocean ridge basalts (MORB). The sum of OMV geochemical characteristics requires that these magmas were derived by the fractional fusion of the mantle. It is suggested that the OMV were generated by 20–25% fractional melting of previously depleted mantle at depths of less than 60 km. Relatively little fractionation accompanied ascent to the surface, where the OMV were erupted in a primitive crustal environment, either a small oceanic rift or a back-arc basin.Metamorphism of the YMV resulted in little elemental redistribution. These andesites have sub-alkaline clinopyroxenes and major-element geochemical characteristics indistinguishable from modern calc-alkaline andesites. YMV andesites in the central and western CED have K/Rb = 400–600, K/Ba = 20–40 and are light REE-enriched and heavy REE depleted. High concentrations of Cr (50–150 ppm) and Ni (20–100 ppm) and low initial ⁸⁷Sr/⁸⁶Sr ratios (0.7028–0.7030) indicate that these magmas were generated by melting in the mantle. Modelling studies and consideration of experimental data indicate that these andesites were formed by 2–10% fractional fusion of hydrous, undepleted, garnet therzolite at depths of 65 km or more in the mantle.The data show that an intense episode of instability, convection, and widespread melting occurred in the mantle beneath Afro-Arabia at the end of the Precambrian.     

Caribbean island-arc rifting and back-arc basin development in the Late Cretaceous: Geochemical, isotopic and geochronological evidence from Central Hispaniola

We present new regional petrologic, geochemical, Sr–Nd isotopic, and U–Pb geochronological data on the Turonian–Campanian mafic igneous rocks of Central Hispaniola that provide important clues on the development of the Caribbean island-arc. Central Hispaniola is made up of three main tectonic blocks—Jicomé, Jarabacoa and Bonao—that include four broad geochemical groups of Late Cretaceous mafic igneous rocks: group I, tholeiitic to calc-alkaline basalts and andesites; group II, low-Ti high-Mg andesites and basalts; group III, tholeiitic basalts and gabbros/dolerites; and group IV, tholeiitic to transitional and alkalic basalts. These igneous rocks show significant differences in time and space, from arc-like to non-arc-like characteristics, suggesting that they were derived from different mantle sources. We interpret these groups as the record of Caribbean arc-rifting and back-arc basin development in the Late Cretaceous. The> 90 Ma group I volcanic rocks and associated cumulate complexes preserved in the Jicomé and Jarabacoa blocks represent the Albian to Cenomanian Caribbean island-arc material. The arc rift stage magmatism in these blocks took place during the deposition of the Restauración Formation from the Turonian–Coniacian transition (~ 90 Ma) to Santonian/Lower Campanian, particularly in its lower part with extrusion at 90–88 Ma of group II low-Ti, high-Mg andesites/basalts. During this time or slightly afterwards adakitic rhyolites erupted in the Jarabacoa block. Group III tholeiitic lavas represent the initiation of Coniacian–Lower Campanian back-arc spreading. In the Bonao block, this stage is represented by back-arc basin-like basalts, gabbros and dolerite/diorite dykes intruded into the Loma Caribe peridotite, as well as the Peralvillo Sur Formation basalts, capped by tuffs, shales and Campanian cherts. This dismembered ophiolitic stratigraphy indicates that the Bonao block is a fragment of an ensimatic back-arc basin. In the Jicomé and Jarabacoa blocks, the mainly Campanian group IV basalts of the Peña Blanca, Siete Cabezas and Pelona–Pico Duarte Formation, represent the subsequent stage of back-arc spreading and off-axis non-arc-like magmatism, caused by migration of the arc toward the northeast. These basalts have geochemical affinities with the mantle domain influenced by the Caribbean plume, suggesting that mantle was flowing toward the NE, beneath the extended Caribbean island-arc, in response to rollback of the subducting proto-Caribbean slab.     

Tectonic evolution of the southwestern margin of Pangea and its global implications: Evidence from the mid Permian–Triassic magmatism along the Chilean-Argentine border

The tectonic evolution of the southwestern margin of Pangea supercontinent is represented by the extensive late Paleozoic–Triassic magmatism along the southwestern margin of South America, including the Chilean Frontal Andes batholiths as part of the Choiyoi province. Several models have proposed cessation of subduction as the reason behind the vast amounts of felsic magmatism and apparent lack of typical arc magmas. Here, new U-Pb in zircon ages, and geochemical and isotope analyses (Rb-Sr, Sm-Nd, Re-Os) indicate that mid Permian–Triassic granitic magmatism originated in a subduction-related extensional setting (slab rollback). Subduction and anatexis of lower continental crust were the main magma-generation mechanisms, the latter caused by asthenospheric upwelling, decompression and subsequent accumulation of underplated basalts. A comparison with coeval igneous units along the Chilean-Argentine border allows extension of this model from at least 21° to 40°S. The key elements triggering slab rollback are low subduction plate velocities and convergence rates, which can be attributed to the assembly of Pangea supercontinent (mid Permian–Triassic). Therefore, subduction of the oceanic plate beneath South America has been a continuous process from early Paleozoic times onwards—rather than having a period without subduction before the onset of the Andean cycle as previous models have invoked. New geochronological constraints indicate that the peak of the voluminous crustal-derived magmatism and related explosive volcanism (Choiyoi province) was contemporaneous with the emplacement of the Emeishan and Siberian Traps LIPs, potentially conditioning the Earth system for the environmental collapse and biotic crises related to those LIPs. The observed tectonic changes, magmatism and related environmental implications could potentially be linked to the assembly of Pangea supercontinent.     

Geochemical characteristics of the Río Verde Complex,Central Hispaniola: Implications for the paleotectonic reconstruction of the Lower Cretaceous Caribbean island-arc

New geochronological, trace element and Sr–Nd isotope data for metabasalts, dolerites and amphibolites from the Río Verde Complex, Central Hispaniola, are integrated with existing geochemical data for mafic volcanic rocks and metamorphic derivatives from the Los Ranchos, Amina and Maimón Formations, giving new insights into magma petrogenesis and paleotectonic reconstruction of the Lower Cretaceous Caribbean island-arc–back arc system. U–Pb and ⁴⁰Ar/³⁹Ar age data show that the Río Verde Complex protoliths were in part coeval with volcanic rocks of the Los Ranchos Formation (Upper Aptian to Lower Albian). The geochemical data establish the existence of gradients in trace element parameters (Nb/Yb, Th/Yb, Zr/Yb, Zr/Ba, and normalized Ti, Sm, Y and Yb abundances) and Nd isotope compositions from throughout Hispaniola, which reflect differences in the degree of mantle wedge depletion and contributions from the subducting slab. The Río Verde Complex mafic rocks and some mafic sills and dykes intruding in the Loma Caribe Peridotite, have a transitional IAT to N-MORB geochemistry and a weak subduction-related signature, and are interpreted to form in a rifted arc or evolving back-arc basin setting. The Los Ranchos, Amina and Maimón Formations volcanic rocks have arc-like characteristics and represent magmatism in the volcanic front. Trace element and Nd isotope modeling reproduce observed data trends from arc to back-arc and suggest that the variations in several geochemical parameters observed in a SW direction across the Caribbean subduction system can be explained from the progressively lower subduction flux into a progressively less depleted mantle source. The low Nb contents and high (ε_Nd)_i values in both arc and back-arc mafic rocks imply, however, the absence of a significant Lower Cretaceous plume enriched component. In order to explain these observations, a model of proto-Caribbean oceanic lithosphere subducting to the SW at least in the 120–110 Ma interval, is proposed to cause the observed magmatic variations in the Lower Cretaceous Caribbean island-arc–back-arc system. In this context, arc rifting and initial sea-floor spreading to form the Río Verde Complex protoliths occurred in the back-arc setting of this primitive island-arc, built on the NE edge of the Caribbean plate.     

Geochemical characterization of a Quaternary monogenetic volcano in Erciyes Volcanic Complex: Cora Maar (Central Anatolian Volcanic Province,Turkey)

Central Anatolian Volcanic Province (CAVP) is a fine example of Neogene-Quaternary post-collisional volcanism in the Alpine-Mediterranean region. Volcanism in the Alpine-Mediterranean region comprises tholeiitic, transitional, calc-alkaline, and shoshonitic types with an “orogenic” fingerprint. Following the orogenic volcanism, subordinate, within-plate alkali basalts (sl) showing little or no orogenic signature are generally reported in the region. CAVP is mainly characterized by widespread calc-alkaline andesitic-dacitic volcanism with orogenic trace element signature, reflecting enrichment of their source regions by subduction-related fluids. Cora Maar (CM) located within the Erciyes pull-apart basin, is an example to numerous Quaternary monogenetic volcanoes of the CAVP, generally considered to be alkaline. Major and trace element geochemical and geochronological data for the CM are presented in comparison with other CAVP monogenetic volcanoes. CM scoria is basaltic andesitic, transitional-calc-alkaline in nature, and characterized by negative Nb–Ta, Ba, P and Ti anomalies in mantle-normalized patterns. Unlike the “alkaline” basalts of the Mediterranean region, other late-stage basalts from the CAVP monogenetic volcanoes are classified as tholeiitic, transitional and mildly alkaline. They display the same negative anomalies and incompatible element ratios as CM samples. In this respect, CM is comparable to other CAVP monogenetic basalts (sl), but different from the Meditterranean intraplate alkali basalts. Several lines of evidence suggest derivation of CM and other CAVP monogenetic basalts from shallow depths within the lithospheric mantle, that is from a garnet-free source. In a wider regional context, CAVP basalts (sl) are comparable to Apuseni (Romania) and Big Pine (Western Great Basin, USA) volcanics, except the former have depleted Ba contents. This is a common feature for the CAVP volcanics and might be related to crustal contamination or source characteristics. Indeed, HFS and other incompatible element ratios suggest the role of crustal contamination in the genesis of the CAVP monogenetic basalts.     

The magmatic record in the Arghash region (northeast Iran) and tectonic implications

The area of Arghash in northeast Iran, prominent for its gold mineralization, was newly mapped on a scale of 1:20,000 with particular attention to the occurring generations of igneous rocks. In addition, geochronological and geochemical investigations were carried out. The oldest geological unit is a late Precambrian, hornblende-bearing diorite pluton with low-K composition and primitive isotope signatures. This diorite (U–Pb zircon age 554 ± 6 Ma) is most likely a remnant from a Peri-Gondwana island-arc or back-arc basin. About one-third of the map area is interpreted as an Upper Cretaceous magmatic arc consisting of a volcanic and a plutonic part. The plutonic part is represented by a suite of hornblende-bearing medium-K, I-type granitoids (minor diorite, mainly quartz–monzodiorite and granodiorite) dated at 92.8 ± 1.3 Ma (U–Pb zircon age). The volcanic part comprises medium-K andesite, dacite and tuffitic rocks and must be at least slightly older, because it is locally affected by contact metamorphism through the hornblende–granitoids. The Upper Cretaceous arc magmatism in the Arghash Massif is probably related to the northward subduction of the Sabzevar oceanic basin, which holds a back-arc position behind the main Neotethys subduction front. Small occurrences of pillow basalts and sediments (sandstone, conglomerate, limestone) tectonically intercalated in the older volcanic series may be relics of earlier Cretaceous or even pre-Cretaceous rocks. In the early Cenozoic, the Cretaceous magmatic arc was intruded by bodies of felsic, weakly peraluminous granite (U–Pb zircon age 55.4 ± 2.3 Ma). Another strong pulse of magmatism followed slightly later in the Eocene, producing large masses of andesitic to dacitic volcanic rocks. The geochemistry of this prominent Eocene volcanism is very distinct, with a high-K signature and trace element contents similar to shoshonitic series (high P, Zr, Cr, Sr and Ba). High Sr/Y ratios feature affinities to adakite magmas. The Eocene magmatism in the Arghash Massif is interpreted as related to thermal anomalies in crust and mantle that developed when the Sabzevar subduction system collapsed. The youngest magmatic activities in the Arghash Massif are lamprophyres and small intrusions of quartz–monzodiorite porphyries, which cut through all other rocks including an Oligocene–Miocene conglomerate cover series.     

西太平洋雅浦海沟地幔演化与岩浆作用研究进展

俯冲带地幔演化与岩浆作用是地球各固体圈层之间发生物质和能量交换的重要地质过程.西太平洋雅浦海沟因其极短的沟-弧距离和洋脊碰撞等独特的地质构造特征成为研究复杂条件下俯冲带演化的理想场所.为了探究雅浦海沟地幔演化与岩浆作用,本文将前人对雅浦海沟火成岩的研究数据进行整合,分析了雅浦海沟火成岩的成因,并根据火成岩形成的制约条件,对卡罗琳板块俯冲到菲律宾海板块的地幔演化与岩浆作用过程进行了讨论.结果显示雅浦海沟火成岩均具有与俯冲相关火成岩的典型特征.橄榄岩地球化学特征指示雅浦海沟地幔熔融程度为20%~25%,地幔在部分熔融过程中受到了流体与熔体的双重交代作用.Re-Os同位素特征指示雅浦海沟地幔中存在约1.16 Ga非常古老的残余地幔,表明地幔可能经历过多期熔融事件,从而导致雅浦海沟地幔非常亏损.雅浦岛弧成因至今仍存争议,主要包括:(1)现今雅浦岛弧为帕里希维拉海盆洋壳的一部分,在中新世因卡罗琳洋脊的碰撞导致帕里希维拉海盆洋壳逆冲到原雅浦岛弧之上.(2)雅浦岛弧在不同构造时期经历过多期岛弧岩浆作用,包括俯冲初始阶段(~52 Ma)的弧前玄武岩、俯冲开始后的岛弧玄武岩(~25 Ma)、与卡罗琳洋脊碰撞(21 Ma)后的岛弧拉斑玄武岩(7~11 Ma).其中7~11 Ma的岛弧拉斑玄武岩指示雅浦岛弧岩浆活动并未因卡罗琳洋脊的碰撞完全停止,很有可能在晚中新世短暂恢复活动.      

Calc-alkaline, Shoshonitic, and Primitive Tholeiitic Lavas from Monogenetic Volcanoes near Crater Lake, Oregon

Quaternary monogenetic volcanism in the High Cascades of Oregonis manifested by cinder cones, lava fields, and small shields.Near Crater Lake caldera, monogenetic lava compositions include:low-K (as low as 0?09% K₂O) high-alumina olivine tholeiite (HAOT);medium-K. calc-alkaline basalt, basaltic andesite, and andesite;and shoshonitic basaltic andesite (2?1% K₂O, 1750 ppm Sr at54% SiO₂). Tholeiites have MORB-like trace element abundancesexcept for elevated Sr, Ba, and Th and low high field strengthelements (HFSE), and they represent near-primary liquids. Theyare similar to HAOTs from the Cascades and adjacent Basin andRange, and to many primitive basalts from intraoceanic arcs.Calc-alkaline lavas show a well-developed arc signature of highlarge-ion lithophile elements (LILE) and low HFSE. Their Zrand Hf concentrations are at least partly decoupled from thoseof Nb and Ta; HREE are low relative to HAOT. Incompatible elementabundances and ratios vary widely among basaltic andesites.Some calc-alkaline lavas vented near Mount Mazama contain abundantgabbroic microxcnoliths, and are basaltic andesitic magmas contaminatedwith olivine gabbro. A calc-alkaline basalt and a few basaltic andesites have MgOand compatible trace element contents that suggest only minorfractionation. There appears to be a compositional continuumbetween primitive tholeiitic and calc-alkaline lavas. Compositionalvariation within suites of comagmatic primitive lavas, boththoleiitic and calc-alkaline, mainly results from differentdegrees of partial melting. Sources of calc-alkaline primarymagmas were enriched in LILE and LREE by a subduction componentand contained residual garnet, whereas sources of HAOTs hadlower LILE and LREE concentrations and contained residual clinopyroxene.High and variable LILE and LREE contents of calc-alkaline lavasreflect variations in fluid-transported subduction componentadded to the mantle wedge, degree of partial melting, and possiblyalso interaction with rocks or partial melts in the lower crust. Andesites were derived from calc-alkaline basaltic andesitesby fractionation of plagioclase+augite+magnetite+apatite ? orthopyroxeneor olivine, commonly accompanied by assimilation. Many andesitesare mixtures of andesitic or dacitic magma and a basaltic orbasaltic andesitic component, or are contaminated with gabbroicmaterial. Mingled basalt, andesite, and dacite of Williams Craterformed by multi-component, multi-stage mixing of basaltic andesiticmagma, gabbro, and dacitic magma. The wide range of compositionsvented from monogenetic volcanoes near Crater Lake is a resultof the thick crust coupled with mild tectonic extension superimposedon a subduction-related magmatic arc.     

Geochronology,geochemistry and tectonic implications of a new ophiolitic mélange in the northern West Junggar,NW China

The West Junggar, located in the southernmost part of the Central Asian Orogenic Belt (CAOB), is a key region for understanding the Paleozoic evolution of the CAOB. Issues of the timing of initial subduction and tectonic unit connections in northern West Junggar still remain controversial. In this study, we report a new ophiolitic mélange named the E'min ophiolitic mélange in northern West Junggar. The tectonic blocks in the E'min ophiolitic mélange are mainly composed of serpentinized peridotite, serpentinite, gabbros, pillow basalts, and cherts, with a matrix consisting of highly deformed serpentinites. A gabbro exhibits a zircon SHRIMP U-Pb age of 476 ± 2 Ma, and the zircon grains have δ¹⁸O values similar to those of mantle zircons. Those basalt samples display depletions of light rare earth element (REE) relative to heavy REEs. They exhibit weak enrichment of Ba and Th, and moderate depletion of Nb and Ta. The basalts display similar geochemical characteristics to that of fore–arc basalts in the present-day fore–arc setting. The gabbros exhibit high MgO and compatible element contents, but low TiO₂, total REE and high field strength element (HFSE) contents. They exhibit light REE depletion, enrichment in large-ion lithophile elements, and depletion of HFSEs. The boninite-like geochemical patterns of the gabbros indicate that they were formed in a subduction-related environment, and were derived from an extremely depleted mantle source infiltrated by subduction-derived fluids and/or melts. The E'min ophiolitic mélange has a geochemical make-up similar to those of suprasubduction-zone (SSZ)-type ophiolites formed in a forearc setting. Hence, we propose that the E'min ophiolitic mélange formed in a forearc setting and may represent the initial subduction in northern West Junggar. Based on geochronological data, we propose that the E'min ophiolite, together with the Kujibai, Hoboksar and Hongguleleng ophiolites, formed during a similar period and comprise a huge E–W trending ophiolitic belt.     

Zircon SHRIMP U–Pb age of Late Jurassic OIB-type volcanic rocks from the Tethyan Himalaya: constraints on the initial activity time of the Kerguelen mantle plume

This work presents zircon U–Pb age and whole-rock geochemical data for the volcanic rocks from the Lakang Formation in the southeastern Tethyan Himalaya and represents the initial activity of the Kerguelen mantle plume. SHRIMP U–Pb dating of zircons from the volcanic rocks yielded a ²⁰⁶Pb/²³⁸U age of 147 ± 2 Ma that reflects the time of Late Jurassic magmatism. Whole rock analyses of major and trace elements show that the volcanic rocks are characterized by high content of TiO₂ (2.62 wt%–4.25 wt%) and P₂O₅ (0.38 wt%–0.68 wt%), highly fractionated in LREE/HREE [(La/Yb)_N = 5.35–8.31] with no obvious anomaly of Eu, and HFSE enrichment with no obvious anomaly of Nb and Ta, which are similar to those of ocean island basalts and tholeiitic basaltic andesites indicating a mantle plume origin. The Kerguelen mantle plume produced a massive amount of magmatic rocks from Early Cretaceous to the present, which widely dispersed from their original localities of emplacement due to the changing motions of the Antarctic, Australian, and Indian plates. However, our new geochronological and geochemical results indicate that the Kerguelen mantle plume started from the Late Jurassic. Furthermore, we suggest that the Kerguelen mantle plume may played a significant role in the breakup of eastern Gondwanaland according to the available geochronological, geochemical and paleomagnetic data.     

Protoliths of the metamorphic rocks of the Fedorov Complex, Aldan shield: Character, age, and geodynamic environments of origin

Geochemical data indicate that the protoliths of the overwhelming majority of the metamorphic rocks composing the Fedorov Complex in the Aldan granulite megacomplex were volcanic rocks of three groups, which occur in different proportions in the complex: (i) volumetrically predominant (no less than 90%) continuous differentiated island-arc basalt-andesite-dacite-rhyolite series, (ii) within-plate basalts, whose composition was similar to that of low-Ti traps, and (iii) basalts of composition similar to that of continentalrift basalts. The U-Pb zircon crystallization age of the metamorphosed basaltic andesites of the Fedorov Complex was estimated at 2006 ± 3 Ma, which testifies, when considered together with preexisting geochronological data, that the complex was produced during a time span of no longer than 25 m.y. A model is proposed according to which the complex was produced within the geodynamic system of the active continental margin of the Olekma-Aldan continental microplate and the Fedorov island arc.     

内蒙古迪彦庙蛇绿岩带达哈特前弧玄武岩的发现及其地质意义

内蒙古SSZ型迪彦庙蛇绿岩位于兴蒙造山带北部的二连浩特-贺根山蛇绿岩带。笔者最近在迪彦庙蛇绿岩带西侧达哈特一带新发现前弧枕状玄武岩。该玄武岩岩性为低钾拉斑玄武岩,发育球颗结构和枕状构造。通过LA-ICP-MS U-Pb测年,获得玄武岩中锆石的206Pb/238U加权平均年龄为333.4±8.5Ma。岩石SiO_2 42.97%~50.9%,较低的TiO_2 0.59%~0.94%,富Na_2O(1.58%~4.26%)而贫K_2O(0.04%~0.44%),Na_2O/K_2O为9.59~47.3;岩石具有亏损型稀土配分模式,类似N-MORB,但高场强元素(HFSE)Nb、Ta和Ti等比N-MORB稍低,相容元素Cr、Ni和大离子亲石元素(LILE)K、Rb、Ba、U比N-MORB稍高,与弧拉斑玄武岩相似。地球化学特征指示达哈特枕状玄武岩兼有洋中脊与岛弧双重特性,而更像洋中脊,与马里亚纳前弧玄武岩(FAB)相一致。这一发现为明确二连-贺根山蛇绿岩带早石炭世存在前弧玄武岩提供了岩石学、年代学和地球化学佐证,表明二连-贺根山洋早石炭世发生了洋内初始俯冲和洋陆转化岩浆作用。     

Geochemical variations in Andean basaltic and silicic lavas from the Villarrica-Lanin volcanic chain (39.5° S): an evaluation of source heterogeneity,fractional crystallization and crustal assimilation

At 39.5° S in the southern volcanic zone of the Andes three Pleistocene-recent stratovolcanoes, Villarrica, Quetrupillan and Lanin, form a trend perpendicular to the strike of the Andes, 275 to 325 km from the Peru-Chile trench. Basalts from Villarrica and Lanin are geochemically distinct; the latter have higher incompatible element abundances and La/Sm but lower Ba/La and alkali metal/La ratios. These differences are consistent with our previously proposed models involving: a) a west to east decrease in an alkali metal-rich, high Ba/La slab-derived component which causes an across strike decrease in degree of melting; or b) a west to east increase in the contamination of subduction-related magma by enriched subcontinental lithospheric mantle. Silicic and mafic lavas from the stratovolcanoes have overlapping Sr, Nd and O isotopic ratios. Silicic lavas also have geochemical differences that parallel those of their associated basalts, e.g., rhyolite from Villarrica has lower La/Sm and incompatible element contents than high-SiO₂ andesite from Lanin. At each volcano the most silicic lavas can be modelled by closed system fractional crystallization while andesites are best explained by magma mixing. Apparently crustal contamination was not an important process in deriving the evolved lavas. Basaltic flows from small scoria cones, 20–35 km from Villarrica volcano have high incompatible element contents and low Ba/La, like Lanin basalts, but trend to higher K/Rb (356–855) and lower ⁸⁷Sr/ ⁸⁶Sr (0.70361–0.70400) than basalts from either stratovolcano. However all basalts have similar Nd, Pb and O isotope ratios. The best explanation for the unique features of the cones is that the sources of SVZ magmas, e.g., slab-derived fluids or melts of the subcontinental lithospheric mantle, have varying alkali metal and radiogenic Sr contents. These heterogeneities are not manifested in stratovolcano basalts because of extensive subcrustal pooling and mixing. This model is preferable to one involving crustal contamination because it can account for variable Sr isotope ratios and uniform Nd and Pb isotope ratios among the basalts, and the divergence of the cones from across-strike geochemical trends defined by the stratovolcanoes.     

Role of backarc processes in the origin of across-arc geochemical zoning in volcanics of early evolutionary stages in Kunashir Island

Geochemical data obtained on volcanic rocks produced during the early evolutionary stages in Kunashir Island provide insight into certain important aspect of the evolution of the subduction system. The mafic lavas of all age intervals exhibit clearly pronounced across-arc geochemical zoning, which implies that these rocks were produced in the environment of a subducted oceanic slab. The high Ba/Th and U/Th ratios of basalts from the frontal zones suggest that an important role in magma generation was played by a low-temperature aqueous fluid. The arc lavas of the Early Miocene, Pliocene, and Pliocene-Pleistocene episodes in the evolution of the island arc system provide evidence of the melting of subducted sediments, which testifies, when considered together with the calculated P-T conditions under which the high-Mg basalts were derived, that backarc tectono-magmatic processes affected subduction-related magmatic generation. Active mantle diapirism and volcanic activity in the opening Kurile Basin resulted in the heating of the suprasubduction mantle in the rear zone, the involvement of the upper sedimentary layer of the oceanic slab in the process of melting, and the eventual generation of basaltic magmas with unusual geochemical characteristics.     

西藏雄梅地区晚白垩世江巴组火山岩岩石成因及对加厚地壳减薄的指示

江巴组火山岩是西藏雄梅地区近年来发现的火山岩,但其岩石成因尚不明确.通过开展系统的岩相学、地球化学、同位素定年示踪研究,结果表明英安质火山岩锆石U-Pb年龄为85.1±1.0 Ma,为晚白垩世.安山质和英安质火山岩显示出明显的埃达克质岩特征,主量元素显示出较高的SiO₂和Al₂O₃含量及Mg#值;稀土元素整体呈轻稀土元素富集,重稀土元素强烈亏损,轻重稀土元素分异明显,（La/Yb）_N值较高,无明显Eu异常;微量元素具有明显的高Sr,低Y、Yb和高Sr/Y值,相对富集Th、Zr和Hf,亏损Nb、Ta和Ti的特点;英安质火山岩锆石ε_Hf（t）值均为正值,在+2.7~+7.1之间,指示有亏损地幔物质参与成岩作用;以上表明安山质和英安质火山岩可能形成于加厚新生下地壳拆沉的部分熔融并有亏损地幔物质的加入.流纹质火山岩具相对低的MgO、TiO₂含量;LREEs富集、HREEs亏损,但轻重稀土元素分馏明显较安山质和英安质火山岩弱,微量元素富集Rb、Th和K,强烈亏损Eu,Sr,Ba,P和Ti,明显的负Eu异常,表明流纹质火山岩为地壳发生深熔而形成.综合对比江巴组火山岩的地球化学性质,表明班公湖-怒江缝合带中段昂龙岗日-班戈弧地区在晚白垩世期间存在一期板内加厚下地壳拆沉减薄事件.      

Evidence for the Jurassic arc volcanism of the Lolotoi complex,Timor: Tectonic implications

We report the first sensitive high-resolution ion microprobe (SHRIMP) U–Pb zircon ages with geochemical data from metavolcanic rocks in the Lolotoi complex, Timor. The zircon U–Pb ages of two andesitic metavolcanic rocks yield a permissible range of the Middle Jurassic extrusion from 177 Ma to 174 Ma. The geochemical data indicate that the origins of the basaltic and andesitic metavolcanic rocks are products of prolonged oceanic crust and arc magmatism, respectively. They are originated from partial melting of lherzolites, providing an insight into the tectonic evolution of the forearc basements of the Banda volcanic arc. Thus, parts of the Banda forearc basement are pieces of allochthonous oceanic basalts and Jurassic arc-related andesites accreted to the Sundaland during the closure of Mesotethys, and are incorporated later into the Great Indonesian Volcanic Arc system along the southeastern margin of the Sundaland.     

<Superscript>10</Superscript>Be, <Superscript>18</Superscript>O and radiogenic isotopic constraints on the origin of adakitic signatures: a case study from Solander and Little Solander Islands,New Zealand

Subduction-related Quaternary volcanic rocks from Solander and Little Solander Islands, south of mainland New Zealand, are porphyritic trachyandesites and andesites (58.20–62.19 wt% SiO₂) with phenocrysts of amphibole, plagioclase and biotite. The Solander and Little Solander rocks are incompatible element enriched (e.g. Sr ~931–2,270 ppm, Ba ~619–798 ppm, Th ~8.7–21.4 ppm and La ~24.3–97.2 ppm) with MORB-like Sr and Nd isotopic signatures. Isotopically similar quench-textured enclaves reflect mixing with intermediate (basaltic-andesite) magmas. The Solander rocks have geochemical affinities with adakites (e.g. high Sr/Y and low Y), whose origin is often attributed to partial melting of subducted oceanic crust. Solander sits on isotopically distinct continental crust, thus excluding partial melting of the lower crust in the genesis of the magmas. Furthermore, the incompatible element enrichments of the Solander rocks are inconsistent with partial melting of newly underplated mafic lower crust; reproduction of their major element compositions would require unrealistically high degrees of partial melting. A similar argument precludes partial melting of the subducting oceanic crust and the inability to match the observed trace element patterns in the presence of residual garnet or plagioclase. Alternatively, an enriched end member of depleted MORB mantle source is inferred from Sr, Nd and Pb isotopic compositions, trace element enrichments and εHf ? 0 CHUR in detrital zircons, sourced from the volcanics. ¹⁰Be and Sr, Nd and Pb isotopic systematics are inconsistent with significant sediment involvement in the source region. The trace element enrichments and MORB-like Sr and Nd isotopic characteristics of the Solander rocks require a strong fractionation mechanism to impart the high incompatible element concentrations and subduction-related (e.g. high LILE/HFSE) geochemical signatures of the Solander magmas. Trace element modelling shows that this can be achieved by very low degrees of melting of a peridotitic source enriched by the addition of a slab-derived melt. Subsequent open-system fractionation, involving a key role for mafic magma recharge, resulted in the evolved andesitic adakites.