Testing the potential of a standardized growth curve approach for improving the applicability and performance of fading correction

Following a general trend in paleo-environmental research, a considerable and still growing number of luminescence dating studies have been focusing on sediment archives providing information on environmental conditions beyond the last glacial-interglacial cycle. This trend caused a revival of IRSL-based dating approaches using feldspar minerals. As a consequence, the long-known but still poorly understood problem of anomalous fading and various correction methods are gaining increasing importance. In order to cope with the challenge of fading, several new measurement protocols aiming at reducing or completely avoiding fading were proposed. However, these approaches are either still experimental (e.g., infrared radiofluorescence), have only been applied to a limited number of natural samples (e.g., infrared photoluminescence) or are the subject of ongoing scientific discussions (e.g., postIRIR-protocols).Anomalous fading therefore remains a severe problem for feldspar-based luminescence measurements, and fading correction will thus be of crucial importance for reliable age calculations. Some of the proposed correction methods require fully-constructed dose response curves (DRCs) to accurately constrain D₀-and saturation values, which is indispensable for mathematically accurate corrections. Recording such DRCs requires the consideration of high-dose points for a large number of aliquots, corresponding to long-lasting measurement times that pose challenges for resources in routine dating applications.The concept of standardized growth curves (SGC) might provide a promising solution for this problem. Here, we present results obtained from a comprehensive study assessing the potential of SGC-based approaches for improving the applicability and performance of fading correction procedures. In particular, our study is focusing on the fading correction model proposed by Kars et al. (2008), which is fundamentally based on the findings published by Huntley (2006). The applied performance test comprises various natural samples representing a variety of fading rates and covering different locations as well as sedimentary environments.     

Removal of Selenium by Adsorption onto Granular Activated Carbon (GAC) and Powdered Activated Carbon (PAC)

The present work involves the study of Se(IV) adsorption onto granular activated carbon (GAC) and powdered activated carbon (PAC). The adsorbents are coated with ferric chloride solution for the effective removal of selenium. The physico-chemical characterization of the adsorbents is carried out using standard methods, e. g., proximate analysis, scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FTIR), thermo-gravimetric (TGA) and differential thermal analysis (DTA), etc. The FTIR spectra of the GAC and PAC indicate the presence of various types of functional groups, e. g., free and hydrogen bonded OH groups, silanol groups (Si-OH), alkenes, and CO group stretching from aldehydes and ketones on the surface of adsorbents. Batch experiments are carried out to determine the effect of various factors such as adsorbent dose (w), initial pH, contact time (t), and temperature (T) on the adsorption process. The optimum GAC and PAC dosage is found to be 10 g/L and 8 g/L, respectively, for Se(IV) removal with C₀ = 100 mg/L. The percent removal of Se(IV) increases with increasing adsorbent concentration, while removal per unit weight of adsorbent increases with decreasing adsorbent concentration. Se(IV) adsorption onto both the GAC and PAC adsorbents is high at low pH values, and decreases with increased initial pH. The results obtained are analyzed by various kinetic models. The parameters of pseudo-first order, pseudo-second order kinetics, and Weber-Morris intra particle kinetics are determined. It is seen that the sorption kinetics of Se(IV) onto GAC and PAC can be best represented by the pseudo-second order kinetic model.     

A prototype upper-atmospheric data assimilation scheme based on optimal interpolation: 2. Numerical experiments

In Part 1 of this work (Akmaev, 1999), an overview of the theory of optimal interpolation (OI) (Gandin, 1963) and related techniques of data assimilation based on linear optimal estimation (Liebelt, 1967; Catlin, 1989; Mendel, 1995) is presented. The approach implies the use in data analysis of additional statistical information in the form of statistical moments, e.g., the mean and covariance (correlation). The a priori statistical characteristics, if available, make it possible to constrain expected errors and obtain optimal in some sense estimates of the true state from a set of observations in a given domain in space and/or time. The primary objective of OI is to provide estimates away from the observations, i.e., to fill in data voids in the domain under consideration. Additionally, OI performs smoothing suppressing the noise, i.e., the spectral components that are presumably not present in the true signal. Usually, the criterion of optimality is minimum variance of the expected errors and the whole approach may be considered constrained least squares or least squares with a priori information. Obviously, data assimilation techniques capable of incorporating any additional information are potentially superior to techniques that have no access to such information as, for example, the conventional least squares (e.g., Liebelt, 1967; Weisberg, 1985; Press et al., 1992; Mendel, 1995).     

Overview of Overland Satellite Rainfall Estimation for Hydro-Meteorological Applications

This paper reviews current techniques on rainfall estimation from satellite sensor observations. The sensors considered in this study are the Precipitation Radar (PR) and radiometer (TMI) onboard TRMM (Tropical Rainfall Measuring Missio) satellite, the Special Sensor Microwave/Imager (SSM/I) onboard Defense Meteorological Satellite Program (DMSP) platforms, and infrared (IR) sensors onboard geostationary satellites. We present the physical basis and mathematical formulation of a newly developed combined radar-radiometer (PR/TMI) retrieval for TRMM and its application for overland rain estimation. Subsequently we discuss the current state-of-the-art in overland passive microwave (TMI and SSM/I) rain estimation techniques, and outstanding issues associated with the inverse problem. The significance of lightning information in advancing high-frequency rainfall estimation from passive microwave-calibrated IR retrieval techniques is discussed on the basis of newly developed techniques. Finally, current approaches are presented on merging the infrequent passive microwave-based rainfall estimates with the high-frequency, but lower accuracy, rainfall fields derived from proxy parameters (e.g., lightning and IR). The paper provides useful insights on satellite rainfall estimation and discusses issues and applications.     

米仓山楔入冲断构造模型低温热年代学证据及其意义

基于低温热年代学特征的构造重建（或解译）与浅部地表过程模型在诠释盆-山结构与演化过程中受到越来越广泛的重视与应用.青藏高原东缘米仓山-川北前陆盆山系统楔入冲断构造模型与浅部地貌建造（非）耦合的检验校正为米仓山造山带构造变形及其动力学模型研究提供了契机.基于稳态楔入冲断构造低温热年代学模型研究表明,米仓山-川北前陆盆-山结构带盆山地貌的建造和低温热年代学（磷灰石裂变径迹和（U-Th）/He）特征具有明显的耦合性,二者统一于（盆地向）具~4°古地貌斜坡的楔入冲断构造模型.现今米仓山地区低温热年代学不具有明显的海拔高程和年龄线性关系,但当古地貌具有~4°坡度时低温热年代学与古地貌具有明显的线性相关性,揭示晚白垩世米仓山东西段具有一致（或相似）的稳态抬升剥露特征,东西段剥露速率分别为0.05 mm/a 和0.03 mm/a.古地貌坡度与古地温梯度具有较好的相关性（R²=95%~98%）,相关古地温梯度（25~35 ℃/km）符合米仓山稳态剥露地质结构特征.米仓山造山带楔入冲断构造模型的发育可能受控于多套滑脱层系（尤其是深部和浅部滑脱层系）和扬子板块能干性基底对造山带盆地向扩展变形过程的阻挡作用.     

Delineating and quantifying ground water discharge zones using streambed temperatures

Streambed temperature mapping, hydraulic testing using minipiezometers, and geochemical analyses of interstitial water of the streambed were used to delineate the pattern of ground water discharge in a sandy streambed and to develop a flux-based conceptual model for ground water/surface water interactions. A new and simple empirical method was used to relate fluxes obtained from minipiezometer data to streambed temperatures. The relationship allowed flux to be calculated at locations where only streambed temperature measurements were made. Slug testing and potentiomanometer measurements at 34 piezometers indicated ground water discharge ranged from 0.03 to 446 L/m2/day (and possibly as high as 7060 L/m2/day) along a 60 m long by 11 to 14 m wide reach of river. Complex but similar plan-view patterns of flux were calculated for both summer and winter using hundreds of streambed temperatures measured on a 1 by 2 m grid. The reach was dominated by ground water discharge and 5% to 7% of the area accounted for approximately 20% to 24% of the total discharge. < 12% of the total area consisted of recharge zones or no-discharge zones. A conceptual model for ground water/surface water interactions consisting of five different behaviors was developed based on the magnitude and direction of flux across the surface of the streambed. The behaviors include short-circuit discharge (e.g., high-flow springs), high discharge (e.g., preferential flowpaths), low to moderate discharge, no discharge (e.g., horizontal hyporheic or ground water flow), and recharge. Geological variations at depth played a key role in determining which type of flow behavior occurred in the streambed.     

Daytime precipitation identification scheme based on multiple cloud parameters retrieved from visible and infrared measurements

Visible and infrared (VIR) measurements and the retrieved cloud parameters are commonly used in precipitation identification algorithms, since the VIR observations from satellites, especially geostationary satellites, have high spatial and temporal resolutions. Combined measurements from visible/infrared scanner (VIRS) and precipitation radar (PR) aboard the Tropical Rainfall Measuring Mission (TRMM) satellite are analyzed, and three cloud parameters, i.e., cloud optical thickness (COT), effective radius (Re), and brightness temperature of VIRS channel 4 (BT4), are particularly considered to characterize the cloud status. By associating the information from VIRS-derived cloud parameters with those from precipitation detected by PR, we propose a new method for discriminating precipitation in daytime called Precipitation Identification Scheme from Cloud Parameters information (PISCP). It is essentially a lookup table (LUT) approach that is deduced from the optimal equitable threat score (ETS) statistics within 3-dimensional space of the chosen cloud parameters. South and East China is selected as a typical area representing land surface, and the East China Sea and Yellow Sea is selected as typical oceanic area to assess the performance of the new scheme. It is proved that PISCP performs well in discriminating precipitation over both land and oceanic areas. Especially, over ocean, precipitating clouds (PCs) and non-precipitating clouds (N-PCs) are well distinguished by PISCP, with the probability of detection (POD) near 0.80, the probability of false detection (POFD) about 0.07, and the ETS higher than 0.43. The overall spatial distribution of PCs fraction estimated by PISCP is consistent with that by PR, implying that the precipitation data produced by PISCP have great potentials in relevant applications where radar data are unavailable.     

Exploring landscape and geologic controls on spatial patterning of streambank groundwater discharge in a mixed land use watershed

Preferential groundwater discharge features along stream corridors are ecologically important at local and stream network scales, yet we lack quantification of the multiscale controls on the spatial patterning of groundwater discharge. Here we identify physical attributes that best explain variation in the presence and lateral extent of preferential groundwater discharges along two 5th order streams, the Housatonic and Farmington Rivers, and 32 1st to 4th order reaches across the Farmington River network. We mapped locations of preferential groundwater discharge exposed along streambanks using handheld thermal infrared cameras paired with high-resolution topographic and land use land cover datasets, surficial soil characteristic maps, and depth-to-bedrock geophysical measurements. The unconfined Housatonic River, MA, USA (12 km) had fewer discharge locations and less lateral extent (41 discharge locations with 38 m of active discharge/km of river) compared to the partially confined Farmington River, CT, USA (26 km; 169 discharge locations with 129 m of active discharge/km of river). Using a moving window analysis, we found along both rivers that discharge was more likely to occur where bank slopes were steeper, floodplain extent was narrower, and degree of confinement was higher. Along the Farmington River, groundwater discharge was more likely to occur where saturated hydraulic conductivity was higher and depth-to-bedrock was shallower. Among the 32 stream reaches surveyed (33.2 km of total stream length) within the Farmington River watershed, preferential discharge was observed in all but two stream reaches, varied from 0 to 25% of lateral extent along stream banks (mean = 6%), and was more likely to occur where stream reach slopes were steep, saturated hydraulic conductivity was high, and watershed urbanization was low. Our results show that, though both surface (e.g., topographic, land use land cover) and subsurface (e.g., soil characteristics, bedrock depth) factors control the prevalence of streambank preferential groundwater discharge, the dominant controls vary across valley settings and stream sizes.     

Minimizing the impacts of contaminant intrusion in small water distribution networks through booster chlorination optimization

Contaminant intrusion in a water distribution network (DN) has three basic pre-conditions: source of contaminant (e.g., leaky sewer), a pathway (e.g., water main leaks), and a driving force (e.g., negative pressure). The impact of intrusion can be catastrophic if residual disinfectant (chlorine) is not present. To avoid microbiological water quality failure, higher levels of secondary chlorination doses can be a possible solution, but they can produce disinfectant by-products which lead to taste and odour complaints. This study presents a methodology to identify potential intrusion points in a DN and optimize booster chlorination based on trade-offs among microbiological risk, chemical risk and life-cycle cost for booster chlorination. A point-scoring scheme was developed to identify the potential intrusion points within a DN. It utilized factors such as pollutant source (e.g., sewer characteristics), pollution pathway (water main diameter, length, age, and surrounding soil properties, etc.), consequence of contamination (e.g., population, and land use), and operational factors (e.g., water pressure) integrated through a geographical information system using advanced ArcMap 10 operations. The contaminant intrusion was modelled for E. Coli O156: H7 (a microbiological indicator) using the EPANET-MSX programmer’s toolkit. The quantitative microbial risk assessment and chemical (human health) risk assessment frameworks were adapted to estimate risk potentials. Booster chlorination locations and dosages were selected using a multi-objective genetic algorithm. The methodology was illustrated through a case study on a portion of a municipal DN.     

Bleachability of pIRIR signal from single-grain K-feldspar

The high-temperature (e.g., >200 °C) post-infrared infrared (pIRIR) stimulated luminescence of feldspar has been widely used for dating, because it usually suffers negligibly from anomalous fading. However, compared to the quartz optically stimulated luminescence (OSL) or low-temperature (e.g., 50 °C) IR stimulated luminescence (IRSL) from feldspars, the high-temperature pIRIR signals have been shown to bleach more slowly and usually have high residual does of a few Gys or more, which limits its application to date relatively young samples and may cause problems for correcting residual dose/signal. In this study, we investigated the bleachability of K-feldspar pIRIR signals for individual grains. A significant variation in the bleachability of the pIRIR signal was observed among different K-feldspar grains from the same sample. Experiments show that such a variability may result in different residual doses for different grains and, consequently, additional scatter in D_e values. We present a method for quickly testing the bleachability of individual grains. Our result suggests that selecting the easy-to-bleach grains for D_e determination provides an efficient way to date young samples using high-temperature pIRIR signals, which avoids the compromise of using low-temperature pIRIR signals that may suffer from anomalous fading.     

Transport of moderately sorted gravel at low bed shear stresses: The role of fine sediment infiltration

A reliable estimation of sediment transport in gravel‐bed streams is important for various practical engineering and biological studies (e.g., channel stability design, bed degradation/aggradation, restoration of spawning habitat). In the present work, we report original laboratory experiments investigating the transport of gravel particles at low bed shear stresses. The laboratory tests were conducted under unsteady flow conditions inducing low bed shear stresses, with detailed monitoring of the bed topography using a laser scanner. Effects of bed surface arrangements were documented by testing loose and packed bed configurations. Effects of fine sediments were examined by testing beds with sand, artificial fine sand or cohesive silt infiltrated in the gravel matrix. Analysis of the experimental data revealed that the transport of gravel particles depends upon the bed arrangement, the bed material properties (e.g., size and shape, consolidation index, permeability) and the concentration of fine sediments within the surface layer of moving grains. This concentration is directly related to the distribution of fine particles within the gravel matrix (i.e., bottom‐up infiltration or bridging) and their transport mode (i.e., bedload or suspended load). Compared to loose beds, the mobility of gravel is reduced for packed beds and for beds clogged from the bottom up with cohesive fine sediments; in both cases, the bed shear stress for gravel entrainment increases by about 12%. On the other hand, the mobility of gravel increases significantly (bed shear stress for particle motion decreasing up to 40%) for beds clogged at the surface by non‐cohesive sand particles. Copyright © 2017 John Wiley & Sons, Ltd.     

Integrating toxicology and ecology: putting the "eco" into ecotoxicology

Environmental toxicology has been and continues to be an important discipline (e.g., single-species testing for screening purposes). However, ecological toxicology (ecotoxicology--more realism in tests, test species and exposures) is required for predicting real world effects and for site-specific assessments. Ecotoxicology and ecology have shown similar developmental patterns over time; closer cooperation between ecologists and toxicologists would benefit both disciplines. Ecology can be incorporated into toxicology either extrinsically (separately, e.g., providing information on pre-selected test species) or intrinsically (e.g., as part of test species selection)--the latter is preferable. General guidelines for acute and chronic testing and criteria for species selection differ for ecotoxicology and environmental toxicology, and are outlined. An overall framework is proposed based on ecological risk assessment (ERA), for combining ecology and toxicology (environmental and ecological) for decision-making. Increased emphasis on ecotoxicology represents a shift from reductionist to holistic approaches.     

Determination of Polar Organic Pollutants in Aqueous Samples of Former Ammunition Sites in Lower Saxony by Means of HPLC/Photodiode Array Detection (HPLC/PDA) and Proton Nuclear Magnetic Resonance Spectroscopy ( 1H-NMR)

Leachate, ground-, and surface water from former ammunition sites and areas which are known to be contaminated by nitroaromatic compounds in Lower Saxony (Germany) were investigated in order to identify and quantify acidic nitroaromatic compounds (e.g., nitrobenzoic acids, aminonitrobenzoic acids, nitrophenols, and nitrocresols). Acidic and neutral nitroaromatic compounds were enriched by solid-phase extraction (SPE) on a polystyrenedivinylbenzene copolymer and routinely screened for acidic compounds by means of HPLC/photodiode array detection (HPLC/PDA). Qualitative and quantitative results obtained in this way were corroborated by proton nuclear magnetic resonance spectroscopy (¹H-NMR). Validation data for the quantification procedure using this technique are given. The results show that all samples contaminated with 2,4,6-trinitrotoluene (TNT) and related compounds are also contaminated by acidic nitroaromatic compounds (e.g., 2,4-dinitrobenzoic acid, 3,5-dinitrophenol, and especially with 2-amino-4,6-dinitrobenzoic acid) in the μg/L range. This current work shows that 1 H-NMR allows the quantitative determination of protoncarrying analytes in mixtures after solid-phase extraction down to the upper ng/L range after addition of an internal standard to the SPE extract. This is even possible when reference compounds are not commercially available.     

Aquifer Storage and Recovery Using Saline Aquifers: Hydrogeological Controls and Opportunities

Aquifer storage and recovery (ASR) is a valuable tool for managing variations in the supply and demand of freshwater, but system performance is highly dependent upon system-specific hydrogeological conditions including the salinity of the storage-zone native groundwater. ASR systems using storage zones containing saline (>10,000 mg/L of total dissolved solids) groundwater tend to have relatively low recovery efficiencies (REs). However, the drawbacks of low REs may be offset by lesser treatment requirements and may be of secondary importance where the stored water (e.g., excess reclaimed, surface, and storm waters) would otherwise go to waste and pose disposal costs. Density-dependent, solute-transport modeling results demonstrate that the RE of ASR systems using a saline storage zone is most strongly controlled by parameters controlling free convection (e.g., horizontal hydraulic conductivity) and mixing of recharged and native groundwater (e.g., dispersivity and aquifer heterogeneity). Preferred storage zone conditions are moderate hydraulic conductivities (5 to 20 m/d), low degrees of aquifer heterogeneity, and primary porosity-dominated siliclastic and limestones lithologies with effective porosities greater than 5%. Where hydrogeological conditions are less favorable, operational options are available to improve RE, such as preferential recovery from the top of the storage zone. Injection of large volumes of excess water currently not needed into saline aquifers could create valuable water resources that could be tapped in the future during times of greater need.     

Characterization of ocean surface current properties from single site HF/VHF radar

Surface current mapping from HF/VHF coastal radars traditionally requires at least two distant sites. Vector velocities are estimated by combining the radial velocity components measured by the radars. In many circumstances (e.g., failures, interferences, logistics constraints), such a combination is not possible by lack of data from one station. Two methods are evaluated to get information on surface circulation from a single site radar: the Vectorial Reconstruction Method (VRM) for current vector mapping and the Vortex Identification Method (VIM) for detecting eddy-like structures. The VRM assumes a non-divergent horizontal surface current, and the VIM analyzes radial velocities and their radial and orthoradial gradients. These two methods are tested on modeled and measured data sets in the Northwestern Mediterranean Sea where both high-resolution ocean circulation model and radar campaigns are available. The VRM performance is strongly limited by the divergence-free hypothesis which was not satisfied in our real data. The VIM succeeded in detection of vortex in the Gulf of Lions and from an operating single site radar located on the Provence coasts in summer.     

Trophic functioning of macrobenthic fauna in a tropical acidified Bornean estuary (Southeast Asia)

The trophic structure of a community is used to infer ecosystem functioning(e.g. energy transfer and nutrient cycling). Here the trophic structure of the benthic infaunal and epifaunal communities in the Brunei Estuary are characterized, and their distribution along an estuarine pH gradient is analyzed using univariate and multivariate techniques. This analysis revealed that surface deposit feeders(e.g., polychaetes) were numerically dominant within the infaunal communities whereas in the epifaunal communities filter feeders(e.g., bivalves) were highly abundant. Species richness for almost all trophic groups increased toward the lower estuary, except for omnivores in the epifaunal communities, which decreased markedly. Both Analysis of Variance(ANOVA) and Analysis of Similarities(ANOSIM) detected significant differences in the density of respective trophic groups among stations. Within infaunal communities, both Biological and Environmental procedure(BIO-ENV) and Canonical Correspondence Analysis(CCA) showed that trophic shifts were associated with environmental gradients. Surface-deposit feeders and omnivores were the most abundant macrobenthos of the upper estuary characterized by low salinity, low pH, and a higher percentage of mud particles. The proportion of filter feeders and carnivores increased with salinity/pH and sand. A more uniform distribution of trophic structure was found in the lower estuary, with high salinity and pH over sandy habitat. In contrast, within epifaunal trophic groups,the percentage of surface deposit feeders and omnivores declined, but filter feeders remarkably increased toward the sea. The proportion of carnivores remained similar at all stations. Non-Metric Multidimensional Scaling(nMDS) ordination for epifaunal trophic groups clearly demarcated higher salinity/pH stations from lower salinity/pH stations, suggesting different trophic compositions along the estuarine pH gradient.     

北京密云水库表层沉积物磁性矿物的鉴别

本文对密云水库表层沉积物中的磁性矿物进行了岩石磁学和透射电子显微学的综合研究.本实验建立的磁选方法实现将70%~85%左右的磁性矿物从沉积物中分离出来.岩石磁学研究表明,密云水库沉积物中的磁性矿物以多畴和单畴磁铁矿为主,还含有少量高矫顽力弱磁性载磁矿物(可能为赤铁矿).对磁选矿物的透射电镜观测表明,样品中部分单畴磁铁矿具有纳米尺寸和化学纯度高等特点,为拉长的立方-八面体磁铁矿,是趋磁细菌产生的化石磁小体;多畴磁铁矿多数具有微米尺寸,形状不规则,为碎屑成因;超顺磁磁铁矿粒径约为5~20nm,且含硅、铝等元素,可能为自生成因.研究结果表明,岩石磁学和透射电子显微学的综合应用可以更全面、准确地分析沉积物中磁性矿物的成分、含量、粒径和化学成分等信息,为环境磁学、生物地磁学和古地磁学研究提供依据.     

A Multilevel Ground Water Monitoring System for Casing Advance and Bedrock Drilling Methods

A single-hole multilevel sampling piezometer system (MLSPS) has been designed by the Geological Survey of Canada (GSC) to be installed using drilling systems that continuously core (e.g., Rotosonic) or continuously sample (e.g., hollow-stem auger, Becker hammer) overburden and that have the flexibility of allowing additional coring (diamond drilling) or sampling (hammer drilling) of bedrock. The GSC-MLSPS (under license to Solinst Canada Ltd.) uses a patented GSC dry injection system for accurate emplacement of filter packs and seals. This system permits (a) the use of variable screen lengths; (b) the complete evacuation of piezometers before introduction of new ground water (no bailing); (c) the use of a number of types of hydraulic tests (e.g., slug, withdrawal/recovery, vacuum, pressure-pulse); (d) ground water sampling under a nitrogen atmosphere; (e) dissolved gas sampling; (f) a great deal of flexibility in the use of design materials; and (g) the elimination of bridging and collapse of filter packs and seals.