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1.
Lawsonite-Omphacite-Bearing Metabasites of the Pam Peninsula, NE New Caledonia: Evidence for Disrupted Blueschist- to Eclogite-Facies Conditions 总被引:2,自引:0,他引:2
The Diahot terrane of NE New Caledonia contains an interbeddedsequence of Cretaceous to Eocene metasediments, felsic and maficmetavolcanics that experienced c. 40 Ma high-P/T metamorphism.Metabasaltic assemblages define two prograde events (M1 andM2) and a tectonically disrupted crustal profile that extendsfrom lawsoniteblueschist conditions in the SW to paragoniteeclogiteconditions in the NE. Weakly deformed metabasalts from lowest-gradeparts of the Diahot terrane contain M1 omphacite, chlorite,lawsonite and glaucophane-bearing assemblages that partiallypseudomorph igneous plagioclase and augite, and reflect P =0·71·0 GPa and T = 350400°C.M1 assemblages are enveloped by a steeply SW-dipping S2 foliationthat becomes progressively more intense towards the NE overa distance of c. 15 km. S2 assemblages are divided into fourzones: (1) lawsoniteomphacite; (2) lawsoniteclinozoisitespessartine;(3) clinozoisitehornblendealmandine; (4) almandineomphacite.S2 assemblages reflect a PT gradient that spans the exposed15 km of the Diahot terrane from P = 0·81·0GPa and T = 350400°C (Zone 1) to P = 1·61·7GPa and T = 550600°C (Zone 4). The systematic mineralogicalchanges reflect parts of a PT array between 1·0and 1·7 GPa that was extensively disrupted by tectonicthinning during exhumation. KEY WORDS: blueschist; eclogite; New Caledonia; CNFMASH; pseudosection 相似文献
2.
Experimental studies were carried out to evaluate phase relationsinvolving titaniteFAl-titanite solid solutionin the system CaSiO3Al2SiO5TiO2CaF2. Theexperiments were conducted at 9001000°C and 1·14·0GPa. The average F/Al ratio in titanite solid solution in theexperimental run products is 1·01 ± 0·06,and XAl ranges from 0·33 ± 0·02 to 0·91± 0·05, consistent with the substitution [TiO2+]1[AlF2+]1.Analysis of the phase relations indicates that titanite solidsolutions coexisting with rutile are always low in XAl, whereasthe maximum XAl of titanite solid solution occurs with fluoriteand either anorthite or Al2SiO5. Reaction displacement experimentswere performed by adding fluorite to the assemblage anorthite+ rutile = titanite + kyanite. The reaction shifts from 1·60GPa to 1·15 ± 0·05 GPa at 900°C, from1·79 GPa to 1·375 ± 0·025 GPa at1000°C, and from 1·98 GPa to 1·575 ±0·025 GPa at 1100°C. The data show that the activityof CaTiSiO4O is very close to the ideal molecular activity model(XTi) at 1100°C, but shows a negative deviation at 1000°Cand 900°C. The results constrain 相似文献
3.
An Experimentally Constrained Petrogenetic Grid in the Silica-Saturated Portion of the System KFMASH at High Temperatures and Pressures 总被引:4,自引:0,他引:4
Experiments in the quartz-saturated part of the system KFMASHunder fO2 conditions of the haematitemagnetite bufferand using bulk compositions with XMg of 0·81, 0·72,0·53 define the stability limits of several mineral assemblageswithin the PT field 912 kbar, 8501100°C.The stability limits of the mineral assemblages orthopyroxene+ spinel + cordierite ± sapphirine, orthopyroxene + garnet+ sapphirine, sapphirine + cordierite + orthopyroxene and garnet+ orthopyroxene + spinel have been delineated on the basis ofPT and TX pseudosections. Sapphirine did not appearin the bulk composition of XMg = 0·53. A partial petrogeneticgrid applicable to high MgAl granulites metamorphosedat high fO2, developed in our earlier work, was extended tohigher pressures. The experimental results were successfullyapplied to several high-grade terranes to estimate PTconditions and retrograde PT trajectories. KEY WORDS: KFMASH equilibria; experimental petrogenetic grid at high fO2 相似文献
4.
Boninites are an important end-member supra-subductionzone magmatic suite as they have the highest H2O contents andrequire the most refractory of mantle wedge sources. The pressuretemperatureconditions of boninite origins in the mantle wedge are importantto understanding subduction zone initiation and subsequent evolution.Reaction experiments at 1·5 GPa (13501530°C),2 GPa (14001600°C) and 2·5 GPa (14501530°C)between a model primary high-Ca boninite magma composition anda refractory harzburgite under anhydrous and H2O-undersaturatedconditions (23 wt % H2O in the melt) have been completed.The boninite composition was modelled on melt inclusions occurringin the most magnesian olivine phenocrysts in high-Ca boninitesfrom the Northern Tongan forearc and the Upper Pillow Lavasof the Troodos ophiolite. Direct melting experiments on a modelrefractory lherzolite and a harzburgite composition at 1·5GPa under anhydrous conditions (14001600°C) havealso been completed. Experiments establish a P, T meltinggrid for refractory harzburgite at 1·5, 2 and2·5 GPa and in the presence of 23 wt % H2O. Theeffect of 23 wt % dissolved H2O produces a liquidus depressionin primary boninite of 相似文献
5.
RONALD FROST B.; FROST CAROL D.; HULSEBOSCH THOMAS P.; SWAPP SUSAN M. 《Journal of Petrology》2000,41(12):1759-1776
The 2·63 Ga Louis Lake batholith, a calc-alkalic plutonexposed in Wind River Range of western Wyoming, consists ofminor diorite, quartz diorite, granodiorite, and granite. Atshallow structural levels the batholith is pyroxene free, butat deeper levels, all units of the batholith contain pyroxenes.On its northern margin the batholith was emplaced at P = 56kbar, T = 775800°C, fO2 at FMQ (fayalitemagnetitequartz)+ 1·5 to FMQ + 1·8, and aH2O 相似文献
6.
A combined petrological and geochronological study was carriedout on mafic granulites and associated felsic gneisses fromthe McKaskle Hills, eastern Amery Ice Shelf, East Antarctica.Garnet-bearing mafic granulites exhibit reaction textures andexsolution textures that indicate two-stage metamorphic evolution.Thermobarometric estimates from matrix and symplectite assemblagesyield peak and retrograde PT conditions of 9·09·5kbar and 880950°C and 6·67·2kbar and 700750°C, respectively. Similar but slightlyscattered peak PT estimates of 7·910·1kbar and 820980°C are obtained from the core compositionsof minerals from felsic para- and orthogneisses. Evidence forthe prograde history is provided by muscovite inclusions ingarnet from a paragneiss. Sensitive high-resolution ion microprobeUPb zircon dating reveals an evolutionary history forthe granulites, including a mafic and felsic igneous intrusionat 11741019 Ma, sedimentation after 932916 Ma,and a high-grade metamorphism at 533529 Ma. In contrast,SmNd mineralwhole-rock dating mainly yields asingle age population at 500 Ma. This suggests that the McKaskleHills form part of the Prydz Belt, and that the relatively highpeak PT conditions and a decompression-dominated PTpath for the rocks resulted from a single Cambrian metamorphiccycle, rather than two distinct metamorphic events as formerlyinferred for the granulites from Prydz Bay. The age data alsoindicate that the Precambrian history of the McKaskle Hillsis not only distinct from that of the early Neoproterozoic terranein the northern Prince Charles Mountains, but also differentfrom that of other parts of the Prydz Belt. The existence ofmultiple basement terranes, together with considerable crustalthickening followed by tectonic uplift and unroofing indicatedby the clockwise PTt evolution, suggests thatthe Prydz Belt may represent a collisional orogen that resultedin the assembly of Gondwana during the Cambrian period. KEY WORDS: Mesoproterozoic basement; Cambrian metamorphism; PT path; Prydz Belt; East Antarctica 相似文献
7.
Magmatic Evolution of the La Pacana Caldera System, Central Andes, Chile: Compositional Variation of Two Cogenetic, Large-Volume Felsic Ignimbrites 总被引:10,自引:3,他引:10
LINDSAY J. M.; SCHMITT A. K.; TRUMBULL R. B.; DE SILVA S. L.; SIEBEL W.; EMMERMANN R. 《Journal of Petrology》2001,42(3):459-486
La Pacana is one of the largest known calderas on Earth, andis the source of at least two major ignimbrite eruptions witha combined volume of some 2700 km3. These ignimbrites have stronglycontrasting compositions, raising the question of whether theyare genetically related. The Toconao ignimbrite is crystal poor,and contains rhyolitic (7677 wt % SiO2) tube pumices.The overlying Atana ignimbrite is a homogeneous tuff whose pumiceis dacitic (6670 wt % SiO2), dense (4060% vesicularity)and crystal rich (3040 % crystals). Phase equilibriaindicate that the Atana magma equilibrated at temperatures of770790°C with melt water contents of 3·14·4wt %. The pre-eruptive Toconao magma was cooler (730750°C)and its melt more water rich (6·36·8 wt% H2O). A pressure of 200 MPa is inferred from mineral barometryfor the Atana magma chamber. Isotope compositions are variablebut overlapping for both units (87Sr/86Sri 0·70940·7131;143Nd/144Nd 0·512220·51230) and are consistentwith a dominantly crustal origin. Glass analyses from Atanapumices are similar in composition to those in Toconao tubepumices, demonstrating that the Toconao magma could representa differentiated melt of the Atana magma. Fractional crystallizationmodelling suggests that the Toconao magma can be produced by30% crystallization of the observed Atana mineral phases. Toconaomelt characteristics and intensive parameters are consistentwith a volatile oversaturation-driven eruption. However, thelow H2O content, high viscosity and high crystal content ofthe Atana magma imply an external eruption trigger. KEY WORDS: Central Andes; crystal-rich dacite; eruption trigger; high-silica rhyolite; zoned magma chamber 相似文献
8.
Intraplate basalts of the EoceneOligocene Monaro VolcanicProvince (MVP), in southeastern New South Wales, include lower-crustaland refractory to weakly metasomatized upper-mantle xenoliths.Lower-crustal-derived xenoliths appear to be all two-pyroxeneplagioclase granulites (CpxFe:Mg:Ca 0·170·56:0·630·77:0·280·89OpxFe:Mg:Ca 0·390·52:1·371·47:0·02An7286 and An4850) but may also include garnetpyroxenites at depth. Mantle-derived xenoliths are principallyspinel-bearing lherzolites (Fo89·890·6CpxFe:Mg:Ca 0·070·45:0·701·70:0·010·94OpxFe:Mg:Ca 0·160·19:1·621·75:0·010·10)but also include amphibole ± spinel-bearing lherzolite(Fo88·789·1 CpxFe:Mg:Ca 0·090·21:0·610·91:0·730·93OpxFe:Mg:Ca 0·090·31:0·701·54:0·030·91),spinel-bearing harzburgite (Fo90·590·7CpxFe:Mg:Ca 0·08:0·910·93:0·740·84OpxFe:Mg:Ca 0·160·18:1·731·79:0·000·02),wehrlite, pyroxenite (CpxFe:Mg:Ca 0·080·10:0·840·90:0·800·85OpxFe:Mg:Ca 0·160·33:1·511·73:0·020·03)and rare garnet pyroxenite (GtFe:Mg:Ca 0·830·95:1·601·70:0·450·48CpxFe:Mg:Ca 0·140·21:0·690·77:0·780·86Opx Fe:Mg:Ca 0·310·42:1·431·56:0·020·03)and amphiboleapatite composites. Xenolith textures aregenerally weakly to moderately foliated, a few are mosaic-porphyroblasticand rare samples are veined or highly strained. MVP xenolithsappear to have equilibrated under similar pressuretemperature(PT) conditions to other southeastern Australian xenolithsequivalent to the South Eastern Australia (SEA) palaeogeotherm.PT estimates for the MVP suite of xenoliths reveal aheterogeneous lower crust and upper mantle that is thickly underplatedto c. 1·8 GPa or c. 50 km depth. MVP xenolith PTdata are compared with those used to derive the SEA palaeogeotherm,which is shown to be in need of revision using more modern geothermometersand geobarometers and new xenolith coexisting mineral data. KEY WORDS: xenolith; petrography; texture; geotherm; Monaro; eastern Australia 相似文献
9.
Kistufell: Primitive Melt from the Iceland Mantle Plume 总被引:5,自引:2,他引:5
This paper presents new geochemical data from Kistufell (64°48'N,17°13'W), a monogenetic table mountain situated directlyabove the inferred locus of the Iceland mantle plume. Kistufellis composed of the most primitive olivine tholeiitic glassesfound in central Iceland (MgO 10·56 wt %, olivine Fo89·7).The glasses are interpreted as near-primary, high-degree plumemelts derived from a heterogeneous mantle source. Mineral, glassand bulk-rock (glass + minerals) chemistry indicates a low averagemelting pressure (15 kbar), high initial crystallization pressuresand temperatures (1015 kbar and 1270°C), and eruptiontemperatures (1240°C) that are among the highest observedin Iceland. The glasses have trace element signatures (Lan/Ybn<1, Ban/Zrn 0·550·58) indicative ofa trace element depleted source, and the SrNdPbisotopic ratios (87Sr/86Sr 0·703040·70308,143Nd/144Nd 0·5130580·513099, 206Pb/204Pb18·34318·361) further suggest a long-termtrace element depletion relative to primordial mantle. HighHe isotopic ratios (15·316·8 R/Ra) combinedwith low 207Pb/204Pb (15·4215·43) suggestthat the mantle source of the magma is different from that ofNorth Atlantic mid-ocean ridge basalt. Negative Pb anomalies,and positive Nb and Ta anomalies indicate that the source includesa recycled, subducted oceanic crustal or mantle component. PositiveSr anomalies (Srn/Ndn = 1·391·50) furthersuggest that this recycled source component involves lower oceaniccrustal gabbros. The 相似文献
10.
Variation in Metamorphic Style along the Northern Margin of the Damara Orogen, Namibia 总被引:2,自引:0,他引:2
The northern margin of the Inland Branch of the Pan-AfricanDamara Orogen in Namibia shows dramatic along-strike variationin metamorphic character during convergence between the Congoand Kalahari Cratons (M3 metamorphic cycle). Low-P contact metamorphismwith anticlockwise PT paths dominates in the westerndomains (Ugab Zone and western Northern Zone), and high-P Barrovianmetamorphism with a clockwise PT path is documented fromthe easternmost domain (eastern Northern Zone). The sequenceof M3 mineral growth in contact aureoles shows early growthof cordierite porphyroblasts that were pseudomorphed to biotitechloritemuscoviteat the same time as an andalusitebiotitemuscovitetransposed foliation was developed in the matrix. The peak-Tmetamorphic assemblages and fabrics were overprinted by crenulationsand retrograde chloritemuscovite. The KFMASH PTpseudosection for metapelites in the Ugab Zone and western NorthernZone contact aureoles indicates tight anticlockwise PTloops through peak metamorphic conditions of 540570°Cand 2·53·2 kbar. These semi-quantitativePT loops are consistent with average PT calculationsusing THERMOCALC, which give a pooled mean of 556 ± 26°Cand 3·2 ± 0·6 kbar, indicating a high averagethermal gradient of 50°C/km. In contrast, the eastern NorthernZone experienced deep burial, high-P/moderate-T Barrovian M3metamorphism with an average thermal gradient of 21°C/kmand peak metamorphic conditions of c. 635°C and 8·7kbar. The calculated PT pseudosection and garnet compositionalisopleths in KFMASH, appropriate for the metapelite sample fromthis region, document a clockwise PT path. Early plagioclasekyanitebiotiteparageneses evolved by plagioclase consumption and the growthof garnet to increasing XFe, XMg and XCa and decreasing XMncompositions, indicating steep burial with heating. The developedkyanitegarnetbiotite peak metamorphic parageneseswere followed by the resorption of garnet and formation of plagioclasemoats, indicating decompression, which was followed by retrogressivecooling and chloritemuscovite growth. The clockwise PTloop is consistent with the foreland vergent foldthrustbelt geometry in this part of the northern margin. Earlier formed(580570 Ma) pervasive matrix foliations (M2) were overprintedby contact metamorphic parageneses (M3) in the aureoles of 530± 3 Ma granites in the Ugab Zone and 553514 Magranites in the western Northern Zone. Available geochronologicaldata suggest that convergence between the Congo and KalahariCratons was essentially coeval in all parts of the northernmargin, with similar ages of 535530 Ma for the main phaseof deformation in the eastern Northern Zone and Northern Platformand 538505 Ma high-grade metamorphism of the CentralZone immediately to the south. Consequently, NNESSW-directedconvergent deformation and associated M3 metamorphism of contrastingstyles are interpreted to be broadly contemporaneous along thelength of the northern margin of the Inland Branch. In the westheat transfer was dominated by conduction and externally drivenby granites, whereas in the east heat transfer was dominatedby advection and internally driven radiogenic heat production.The ultimate cause was along-orogen variation in crustal architecture,including thickness of the passive margin lithosphere and thicknessof the overlying sedimentary succession. KEY WORDS: Pan-African Orogeny; PT paths; pseudosections; low-P metamorphism; contact metamorphism; Barrovian metamorphism 相似文献
11.
Pressure-Temperature Path Recorded in the Yangkou Garnet Peridotite, in Su-Lu Ultrahigh-pressure Metamorphic Belt, Eastern China 总被引:2,自引:0,他引:2
Chemical variations along with changes in microstructure ofthe principal constituent minerals make it possible to identifyat least four equilibrium stages in the evolution of the Yangkougarnet peridotite in the Su-Lu ultrahigh-pressure metamorphicbelt, eastern China: Stage Ia primary garnet lherzolitestage represented by coarse-grained (a few millimeters size)porphyroclastic aluminous pyroxenes + chromian spinel ±garnet; Stage IIan ultrahigh-pressure (UHP) stage definedby fine-grained matrix phases (0·10·3 mmsize) of garnet + extremely low-Al orthopyroxene + high-Na clinopyroxene+ chromite; Stage IIIa medium-pressure stage definedby fine-grained mineral aggregates (<0·10·2mm size) mainly composed of aluminous spinel + high-Al orthopyroxenein the matrix; Stage IVan amphibolite- to greenschist-faciesstage defined by poikiloblastic amphibole. Orthopyroxeneclinopyroxenethermometry and an empirical spinel barometer give temperaturesof around 800830°C and pressures of 1·22·9GPa for porphyroclasts of Stage I. Garnetorthopyroxene,garnetclinopyroxene and empirical spinel geothermobarometersgive relatively uniform PT conditions for the matrixgarnetorthopyroxeneclinopyroxenechromiteassemblage of Stage II ( 相似文献
12.
The results of a laser ablation microprobeinductivelycoupled plasma mass spectrometry LuHf isotope study ofzircons in 0·931·67 Ga rocks from southNorway indicate that early Proterozoic protoliths of the BalticShield have present-day 176Hf/177Hf 相似文献
13.
Scapolite and other halogen-rich minerals (phlogopite, amphibole,apatite, titanite and clinohumite) occur in some high-pressureamphibolite facies calc-silicates and orthopyroxene-bearingrocks at Sare Sang (Sar e Sang or Sar-e-Sang), NE Afghanistan.The calc-silicates are subdivided into two groups: garnet-bearingand garnet-free, phlogopite-bearing. Besides garnet and/or phlogopite,the amphibolite facies mineral assemblages in the calc-silicatesinclude clinopyroxene, calcite, quartz and one or more of theminerals scapolite, plagioclase, K-feldspar, titanite, apatiteand rarely olivine. Orthopyroxene-bearing rocks consist of clinopyroxene,garnet, plagioclase, scapolite, amphibole, quartz, calcite andaccessory dolomite and alumosilicate (kyanite?). Retrogradephases in the rocks are plagioclase, scapolite, calcite, amphibole,sodalite, haüyne, lazurite, biotite, apatite and dolomite.The clinopyroxene is mostly diopside and rarely also hedenbergite.Aegirine and omphacite with a maximum jadeite content of 29mol % were also found. Garnet from the calc-silicates is Grs4595Py02and from the orthopyroxene-bearing rocks is Grs1015Py3643.Peak PT metamorphic conditions, calculated using availableexchange thermobarometers and the TWQ program, are 750°Cand 1·31·4 GPa. Depending on the rock type,the scapolite exhibits a wide range of composition (from EqAn= 0·07, XCl =0·99 to EqAn = 0·61, XCl =0·07).Equilibria calculated for scapolite and coexisting phases atpeak metamorphic conditions yield XCO2 = 0·030·15.XNaCl (fluid), obtained for scapolite, ranges between 0·04and 0·99. Partitioning of F and Cl between coexistingphases was calculated for apatitebiotite and amphibolebiotite.Fluorapatite is present in calc-silicates, but orthopyroxene-bearingrocks contain chlorapatite. Cl preferentially partitions intoamphibole with respect to biotite. All these rocks have sufferedvarious degrees of retrogression, which resulted in removalof halogens, CO2 and S. Halogen- and S-bearing minerals formedduring retrogression and metasomatism are fluorapatite, sodalite,amphibole, scapolite, clinohumite, haüyne, pyrite, andlazurite, which either form veins or replace earlier formedphases. KEY WORDS: scapolite; fluid composition; high-pressure; amphibolite facies; Western Hindukush; Afghanistan 相似文献
14.
Empirical Garnet-Biotite-Plagioclase-Quartz (GBPQ) Geobarometry in Medium- to High-Grade Metapelites 总被引:23,自引:0,他引:23
On the basis of the net transfer reactions among garnet, biotite,plagioclase and quartz (for both Mg and Fe end-member models),the garnetbiotiteplagioclasequartz (GBPQ)geobarometer was empirically calibrated under physical conditionsof P = 1·011·4 kbar and T = 515878°C,based on the input garnetbiotite temperatures and garnetaluminosilicateplagioclasequartz(GASP) pressures of 224 natural aluminosilicate-bearing metapeliticsamples collated from the literature. The calibrations are internallyconsistent with the asymmetric quaternary solid solution modelof garnet, the symmetric quaternary solid solution model ofbiotite, and the Al-avoidance ternary solid solution model ofplagioclase in calibrating the garnetbiotite geothermometerand the GASP geobarometer. The resulting two GBPQ barometerformulae reproduce the input GASP pressures well within ±1·0kbar (mostly within ±0·5 kbar). For both aluminosilicate-bearingand aluminosilicate-absent metapelites, the two GBPQ barometryformulae yielded identical pressures, whether the sample wasincluded or not included in calibrating the GBPQ barometry.The random error of the GBPQ barometry may be expected as ±1·2kbar. The dP/dT slopes of these two GBPQ formulae are closeto that of the GASP barometer in PT space. Applicationsof the GBPQ barometry of aluminosilicate-absent metapelitesto the rocks within a thermal contact aureole, or rocks withina limited geographical area without post-metamorphic structuraldiscontinuity, show no obvious pressure change. It may be concludedthat the two GBPQ barometry formulae derived in this study maybe used as practical tools for metamorphic pelites under theconditions of 515878°C and 1·011·4kbar, in the composition range of Xgros >3% in garnet, Xan>17% in plagioclase, and 相似文献
15.
Late Devonian Diamondiferous Kimberlite and Alkaline Picrite (Proto-kimberlite?) Magmatism in the Arkhangelsk Region, NW Russia 总被引:7,自引:4,他引:3
MAHOTKIN I. L.; GIBSON S. A.; THOMPSON R. N.; ZHURAVLEV D. Z.; ZHERDEV P. U. 《Journal of Petrology》2000,41(2):201-227
Widespread penecontemporaneous igneous activity affected NWRussia (the Kola Peninsula and adjoining areas to the SE aroundArkhangelsk) during the Late Devonian (360380 Ma). Magmatismvaries from tholeiitic basalts, erupted in the axial regionsof former Middle Proterozoic (Riphean) rifts, to strongly alkalinerock-types on and marginal to Archaean cratons. NNE of Arkhangelskkimberlites, olivine lamproites and alkaline picrites were emplaced;all these rock-types are diamondiferous to varying extents.Higher TiO2 (and also total Fe) distinguish predominantly mica-poorEastern Group kimberlites (TiO2 = 2·43·1wt %) and spatially associated alkaline picrites (TiO2 = 3·23·7wt %) from nearby micaceous Western Group kimberlites (TiO2= 0·81·1 wt %). Each rock-type also hasdistinctive rare earth element (REE) patterns, and 相似文献
16.
SCHMITT A. K.; EMMERMANN R.; TRUMBULL R. B.; BUHN B.; HENJES-KUNST F. 《Journal of Petrology》2000,41(8):1207-1239
Anorogenic granites of the Brandberg igneous complex in NW Namibiaformed during early Cretaceous rifting and continental break-upof Gondwana. A metaluminous series [SiO2 = 6277 wt %,molar (Na + K)/Al = 0·80·95] includes anearly monzonite body, major biotitehornblende granite,late biotite granite segregations and peripheral dykes of trachydacite.Volumetrically minor peralkaline granites of the Amis complex[SiO2 = 7277 wt %, (Na + K)/Al = 1·01·5]intrude the main granite and adjacent country rocks. Comparedwith the metaluminous main granite, these are in part highlyenriched in Zr, Nb, Y, U and Th. Initial Nd and Sr isotope ratiosof the metaluminous suite are 相似文献
17.
The early augite syenite unit in the 1·13-Ga-old Ilímaussaqintrusive complex, South Greenland, consists of a magmatic assemblageof ternary alkali feldspar + fayalitic olivine + augite + titanomagnetite+ apatite + baddeleyite ± nepheline ± quartz ±ilmenite ± zircon. Feldspar, nepheline and QUILF thermometryyield T = 1000700°C, at P = 1 kbar, which is derivedfrom fluid inclusion data from other parts of the complex. Ternaryfeldspar was the first major liquidus phase. It crystallizedat temperatures between 950 and 1000°C from a homogeneousmagma with aSiO2 = 0·8 and fO2 about 1·52log units below the fayalitemagnetitequartz (FMQ)buffer. Later, closed system fractionation produced nepheline-bearingassemblages with aSiO2 = 0·4 and log fO2 = FMQ 3 to FMQ 5. Assimilation of wall rocks produced localvariations of melt composition. Four traverses through the unitwere sampled parallel to the assumed direction of crystallization.They exhibit significant differences in their mineral assemblagesand compositions. The chemical zoning and calculated intensiveparameters of four sample suites reflect both closed systemfractional crystallization and local assimilation of wall rocks. KEY WORDS: alkaline magmatism; assimilation; fractionation; redox equilibria; QUILF 相似文献
18.
Polymetamorphism in the NE Shackleton Range, Antarctica: Constraints from Petrology and U-Pb, Sm-Nd, Rb-Sr TIMS and in situ U-Pb LA-PIMMS Dating 总被引:1,自引:0,他引:1
Metapelitic rock samples from the NE Shackleton Range, Antarctica,include garnet with contrasting zonation patterns and two agespectra. Garnet porphyroblasts in K-rich kyanitesillimanitestaurolitegarnetmuscovitebiotite schistsfrom Lord Nunatak show prograde growth zonation, and give SmNdgarnet, UPb monazite and RbSr muscovite ages of518 ± 5, 514 ± 1 and 499 ± 12 Ma, respectively.Geothermobarometry and PT pseudo-section calculationsin the model system CaONa2OK2O TiO2MnOFeOMgOAl2O3SiO2H2Oare consistent with garnet growth during prograde heating from540°C/7 kbar to 650°C/7·5 kbar, and partial resorptionduring a subsequent PT decrease to <650°C at <6kbar. All data indicate that rocks from Lord Nunatak were affectedby a single orogenic cycle. In contrast, garnet porphyroblastsin K-poor kyanitesillimanite staurolitegarnetcordieritebiotite-schistsfrom Meade Nunatak show two growth stages and diffusion-controlledzonation. Two distinct age groups were obtained. Laser ablationplasma ionization multicollector mass spectrometry in situ analysesof monazite, completely enclosed by a first garnet generation,yield ages of c. 1700 Ma, whereas monazite grains in open garnetfractures and in most matrix domains give c. 500 Ma. Both agegroups are also obtained by UPb thermal ionization massspectrometry analyses of matrix monazite and zircon, which fallon a discordia with lower and upper intercepts at 502 ±1 and 1686 ± 2 Ma, respectively. SmNd garnet datingyields an age of 1571 ± 40 Ma and RbSr biotiteanalyses give an age of 504 ± 1 Ma. Integrated geochronologicaland petrological data provide evidence that rocks from MeadeNunatak underwent a polymetamorphic Barrovian-type metamorphism:(1) garnet 1 growth and subsequent diffusive garnet annealingbetween 1700 and 1570 Ma; (2) garnet 2 growth during the RossOrogeny at c. 500 Ma. During the final orogenic event the rocksexperienced peak PT conditions of about 650°C/7·0kbar and a retrograde stage at c. 575°C/4·0 kbar. KEY WORDS: garnet microtexture; PT pseudosection; geochronology; polymetamorphism; Shackleton Range; Antarctica 相似文献
19.
Submarine pillow basalts (34 Ma) recovered from the NorthernKerguelen Plateau at ODP Site 1140 contain abundant unalteredglass, providing the first opportunity to measure the volatilecontents of tholeiitic basaltic magmas related to the Kerguelenmantle plume. The glasses have La/Sm and Nb/Zr ratios that varyfrom values similar to Southeast Indian Ridge (SEIR) MORB (Unit1), to slightly more enriched (Unit 6), to values transitionalbetween SEIR MORB and basaltic magmas formed by melting of theKerguelen plume (Units 2 and 3). Volatile contents for glassesin Units 1 and 6 are similar to depleted mid-ocean ridge basalt(MORB) values (0·250·27 wt % H2O, 12401450ppm S, 4254 ppm Cl). In contrast, H2O contents are higherfor the enriched glasses (Unit 2, 0·44 wt % H2O; Unit3, 0·69 wt %), as are S (1500 ppm) and Cl (146206ppm). Cl/K ratios for all glasses are relatively low (0·030·04),indicating that assimilation of hydrothermally altered materialdid not occur during shallow-level crystallization. H2O/Ce forthe enriched glasses (Units 2 and 3) is significantly lowerthan Pacific and South Atlantic MORB values, suggesting thatlow H2O/Ce may be an inherent characteristic of the Kerguelenplume source. Vapor saturation pressures calculated using theH2O and CO2 contents of the glasses indicate that 相似文献
20.
The magmatic processes leading to porphyry-Cu mineralizationat Santa Rita are reconstructed on the basis of petrographicstudies, thermobarometry, and laser-ablation inductively-coupled-plasmamass-spectrometry analyses of silicate melt and sulfide inclusionsfrom dikes ranging from basaltic andesite to rhyodacite. Combinedresults suggest that magma evolution at Santa Rita is similarto that of sulfur-rich volcanoes situated above subduction zones,being characterized by repeated injection of hot, mafic magmainto an anhydrite-bearing magma chamber of rhyodacitic composition.The most mafic end-member identified at Santa Rita is a shoshoniticbasaltic andesite that crystallized at 10001050°C,13 kbar and log fO2 = NNO + 0·7 to NNO + 1·0,whereas the rhyodacite crystallized at 730760°C andlog fO2 = NNO + 1·3 to NNO + 1·9. Mixing betweenthe two magmas caused precipitation of 0·10·2wt % magmatic sulfides and an associated decrease in the Cucontent of the silicate melt from 300500 ppm to lessthan 20 ppm. Quantitative modeling suggests that temporal storageof ore-metals in magmatic sulfides does not significantly enhancethe amount of copper ultimately available to ore-forming hydrothermalfluids. Magmatic sulfides are therefore not vital to the formationof porphyry-Cu deposits, unless a mechanism is required thatholds back ore-forming metals until late in the evolution ofthe volcanicplutonic system. KEY WORDS: porphyry-Cu; sulfur; sulfides; magma mixing; LA-ICP-MS 相似文献