Solution of marble in the karst of the Pikikiruna range,Northwest Nelson,New Zealand

The paper reports the first research on karst solution processes and rates in New Zealand. The study area is an IHD representative basin in the northwest corner of the South Island in a mountain range consisting principally of Ordovician marble. The climate is sunny and warm (17°C) in summer and wet and cool (7°C) in winter. Average precipitation is 2,158 mm of which 525 mm evapotranspires, yielding a discharge of 51–75 l/s/km² in the river basin studied. Almost half of the catchment of 45.1 km² consists of karst which occurs mainly as a doline covered plateau at 600–900 m within which most drainage is subterranean. Water tracing is with fluorescein defined drainage patterns. Marble solution was established by estimating inputs, throughputs and outputs of water and dissolved calcium and magnesium in both autogenic and allogenic karst drainage systems. Particular attention was paid to estimating errors. Water samples for chemical analysis were taken irregularly for approximately one year, and a rating curve relating chemical load to discharge was established. The best estimate of solution loss from the basin yields a mean rate of 100 ±M24 m³/km²/a. Of this 80 per cent is derived from solution of marble by autogenic waters, mostly in the top 10–30 m of the marble outcrop. The remaining 20 per cent is accomplished by allogenic stream solution. Approximately 9.9 per cent of the dissolved calcium and magnesium load leaving the basin originates from non-karst rocks and 4.6 per cent is initially introduced by rainfall. River flows that are exceeded only 5 per cent of the time transport approximately 44 per cent of the annual dissolved load, while mean to low flows that occur for 75 per cent of the time transport 35 per cent of the annual solute load. This confirms the importance of low frequency-high magnitude events, but indicates also that in corrosion systems high frequency events of moderate to low magnitude can also accomplish significant work.     

The geochemistry of sulphur in a mixed allogenic–autogenic karst catchment,Castleton, Derbyshire,UK

Analyses are presented of anion chemistry and sulphur isotopic compositions of sulphate in sinking streams and groundwaters in a mixed allogenic–autogenic karst catchment. Using the sulphur isotopic data, sources of sulphate from agriculture and the effects of sulphate reduction arising from slurry application can be distinguished from natural rock weathering sources. Within the aquifer, sulphate in known autogenic waters has isotopic compositions distinct from allogenic waters, the autogenic waters being dominated by sulphate from rainfall and rock weathering in these low agricultural intensity catchments. On this basis, water rising at low flow from Whirlpool Rising, Speedwell Cavern, has been identified as dominantly autogenic. Groundwater flow between the sinks and risings in Speedwell Cavern is believed to be along conduits following mineralized faults (rakes). During transit SO42−/Cl− in the water increases. Isotopic mass balance shows that this must be due to addition of sulphate from the oxidation of ore minerals by groundwater. Mass balance considerations show that the present rate of sulphide oxidation must be the result of enhancement by lead mining operations on the rakes. Copyright © 2000 John Wiley & Sons, Ltd.     

Cosmogenic nuclide‐derived rates of diffusive and episodic erosion in the glacially sculpted upper Rhone Valley,Swiss Alps

Denudation rates of small tributary valleys in the upper Rhone valley of the Swiss Central Alps vary by more than an order of magnitude within a very small distance (tens of kilometers). Morphometric data indicate two distinct erosion processes operate in these steep mountain valleys. We determined the rates of these processes using cosmogenic beryllium‐10 (¹⁰Be) in pooled soil and stream sediment samples. Denudation in deep, glacially scoured valleys is characterized by rapid, non‐uniform processes, such as debris flows and rock falls. In these steep valleys denudation rates are 760–2100 mm kyr^?1. In those basins which show minimal previous glacial modification denudation rates are low with 60–560 mm kyr^?1. The denudation rate in each basin represents a binary mixture between the rapid, non‐uniform processes, and soil creep. The soil production rate measured with cosmogenic ¹⁰Be in soil samples averages at 60 mm kyr^?1. Mixing calculations suggest that the debris flows and rock falls are occurring at rates up to 3000–7000 mm kyr^?1. These very high rates occur in the absence of baselevel lowering, since the tributaries drain into the Rhone trunk stream up‐stream of a knickzone. The flux‐weighted spatial average of denudation rates for the upper Rhone valley is 1400 mm kyr^?1, which is similar to rock uplift rates determined in this area from leveling. The pace and location of erosion processes are determined by the oscillation between a glacial and a non‐glacial state, preventing the landscape from reaching equilibrium. Copyright © 2010 John Wiley & Sons, Ltd.     

Allogenic and autogenic effects on mangrove dynamics from the Ceará Mirim River,north‐eastern Brazil,during the middle and late Holocene

It is possible that climate changes and sea level fluctuations (allogenic processes) are and will cause major changes in mangrove dynamics. However, other driving forces may be significantly affecting this system. Distinguishing allogenic and autogenic influence on mangroves is a challenging question, because mechanisms related to the natural dynamics of depositional environments (autogenic processes) have strong influences on the establishment and degradation of mangroves. Thus, impacts on mangroves caused by autogenic processes may be erroneously attributed to allogenic mechanisms. Therefore, it is imperative to identify the ‘fingerprint’ of global changes in modern mangrove dynamics. In order to characterize the influence of these forces on mangroves, this work has used geomorphology and vegetation maps integrated with sedimentological and palynological data, radiocarbon dating, as well as δ¹³C, δ¹⁵N and C/N from sedimentary organic matter. The inter‐proxy analyses reveal an estuarine influence with mangrove development along the Ceará Mirim River, north‐eastern Brazil, since ~6920 cal yr bp , after the post‐glacial sea level rise. Relative sea level (RSL) has been stable during the middle and late Holocene. Mangrove establishment along this fluvial valley begins at about 6920 cal yr bp , caused by the sea‐level stabilization, an allogenic influence. However, after its establishment, wetland dynamics were mainly controlled by autogenic factors, related to channel migrations, instead of allogenic process. Some influence of sea‐level and climate changes on mangrove dynamics in this estuarine channel have been weakened by more intense tidal channels activities. Therefore, the expansion and contraction of mangrove areas along the estuary of the Ceará Mirim River since 6920 cal yr bp has been mainly influenced by channel dynamics that regulate the accretion and erosion of mangrove substrates. Copyright © 2018 John Wiley & Sons, Ltd.     

Late Holocene mangrove dynamics dominated by autogenic processes

Generally, palaeoenvironmental interpretations consider only allogenic processes, when autogenic factors may have a strong influence on proxies of stratigraphic sequences. For instance, the Holocene history of the vegetation along the southern littoral of the State of Bahia in north‐eastern Brazil is characterized by mangrove dynamics controlled by allogenic processes. However, over smaller timescales (~700 years), autogenic processes may have controlled vegetation dynamics and hence observed pollen distribution. This work proposes tidal channel dynamics as one of the main cause for changes in pollen assemblage along the studied stratigraphic profiles during the last centuries, based on sedimentology, pollen and elemental analysis (δ¹³C, δ¹⁵N and C/N) and radiocarbon dating of sedimentary organic matter from two cores sampled from an abandoned meander and a tidal flat at the mouth of the Jucuruçu River. One core was sampled from a mangrove formed during the past ~550 cal yr bp . Another core recorded sediments in a várzea forest (swamp seasonally and permanently inundated by freshwater) located ~2.7 km from the current shoreline, which displayed a maximum age of ~680 cal yr bp . Two facies associations were identified: tidal channel (A) and tidal flat/oxbow lake (B). This work proposes allogenic processes as the main driving forces controlling the wetlands dynamics at the studied site during the Holocene. However, our data also reveal that part of the changes in vegetation over the last ~700 years reflect tidal channels and tidal flats development, which represent autogenic processes. The change in timescale analysis from the Holocene to recent centuries may have weakened the influence of allogenic factors. However, this needs interpretation with reference to the spatial scale of the depositional environment as the larger the depositional system analyzed, the stronger the influence of autogenic processes on stratigraphic sequences over longer timescales. Copyright © 2017 John Wiley & Sons, Ltd.     

Erosion rates in the southern oregon coast range: Evidence for an equilibrium between hillslope erosion and sediment yield

The relationship of hillslope erosion rates and sediment yield is often poorly defined because of short periods of measurement and inherent spatial and temporal variability in erosion processes. In landscapes containing hillslopes crenulated by alternating topographic noses and hollows, estimates of local hillslope erosion rates averaged over long time periods can be obtained by analysing colluvial deposits in the hollows. Hollows act as local traps for a portion of the colluvium transported down hillslopes, and erosion rates can be calculated using the age and size of the deposits and the size of the contributing source area. Analysis of colluvial deposits in nine Oregon Coast Range hollows has yielded average colluvial transport rates into the hollows of about 35cm³cm^?1yr^?1 and average bedrock lowering rates of about 0.07 mm yr^?1 for the last 4000 to 15000 yr. These rates are consistent with maximum bedrock exfoliation rates of about 0.09 mm yr^?1 calculated from six of the hollows, supporting the interpretation that exfoliation rates limit erosion rates on these slopes. Sediment yield measurements from nine Coast Range streams provide similar basin-wide denudation rates of between 0.05 and 0.08mm yr^?1, suggesting an approximate steady-state between sediment production on hillslopes and sediment yield. In addition, modern sediment yields are similar in basins varying in size from 1 to 1500 km², suggesting that erosion rates are spatially uniform and providing additional evidence for an approximate equilibrium in the landscape.     

Erosion rates and mechanisms of knickzone retreat inferred from 10Be measured across strong climate gradients on the northern and central Andes Western Escarpment

A steep escarpment edge, deep gorges and distinct knickzones in river profiles characterize the landscape on the Western Escarpment of the Andes between ~5°S and ~18°S (northern Peru to northern Chile). Strong north–south and east–west precipitation gradients are exploited in order to determine how climate affects denudation rates in three river basins spanning an otherwise relatively uniform geologic and geomorphologic setting. Late Miocene tectonics uplifted the Meseta/Altiplano plateau (~3000 m a.s.l.), which is underlain by a series of Tertiary volcanic‐volcanoclastic rocks. Streams on this plateau remain graded to the Late Miocene base level. Below the rim of the Meseta, streams have responded to this ramp uplift by incising deeply into fractured Mesozoic rocks via a series of steep, headward retreating knickzones that grade to the present‐day base level defined by the Pacific Ocean. It is found that the Tertiary units on the plateau function as cap‐rocks, which aid in the parallel retreat of the sharp escarpment edge and upper knickzone tips. ¹⁰Be‐derived catchment denudation rates of the Rio Piura (5°S), Rio Pisco (13°S) and Rio Lluta (18°S) average ~10 mm ky^?1 on the Meseta/Altiplano, irrespective of precipitation rates; whereas, downstream of the escarpment edge, denudation rates range from 10 mm ky^?1 to 250 mm ky^?1 and correlate positively with precipitation rates, but show no strong correlation with hillslope angles or channel steepness. These relationships are explained by the presence of a cap‐rock and climate‐driven fluvial incision that steepens hillslopes to near‐threshold conditions. Since escarpment retreat and the precipitation pattern were established at least in the Miocene, it is speculated that the present‐day distribution of morphology and denudation rates has probably remained largely unchanged during the past several millions of years as the knickzones have propagated headward into the plateau. Copyright © 2011 John Wiley & Sons, Ltd.     

Contemporary rates of chemical denudation and atmospheric CO2 sequestration in glacier basins: an Arctic perspective

This paper presents new estimates of solute fluxes from five high Arctic glacier basins in Svalbard. These estimates are combined with data from two other glacier basins to assess the effectiveness of chemical denudation on Svalbard and to estimate rates of temporary (or transient) CO₂ drawdown. We use a solute provenance model to partition solutes into marine, aerosol, atmospheric and crustal components and to estimate their annual fluxes. Crustally derived solute fluxes are equivalent to a mean chemical denudation rate of 350 Σmeq⁺ m⁻² a⁻¹ for Svalbard (range: 160–560 Σmeq⁺ m⁻² a⁻¹), which lies within the global range of 94–4200 Σmeq⁺ m⁻² a⁻¹ for 21 glacier basins in the northern hemisphere, and is close to the continental average of 390 Σmeq⁺ m⁻² a⁻¹. Specific annual discharge is the most significant control upon chemical denudation in the glacierized basins, and basin lithology is an important secondary control, with carbonate‐rich and basaltic lithologies currently showing the greatest chemical denudation rates. Estimates of transient CO₂ drawdown are also directly associated with specific annual discharge and rock type. On Svalbard transient CO₂ drawdown lies in the range 110–3000 kg C km⁻² a⁻¹, whilst the range is 110–13000 kg C km⁻² a⁻¹ for the northern hemisphere glacial data set. Transient CO₂ drawdown is therefore usually low in the Svalbard basins unless carbonate or basalt rocks are abundant. The analysis shows that a large area of uncertainty in the transient CO₂ drawdown estimates exists due to the non‐stoichiometric release of solute during silicate hydrolysis. Silicate hydrolysis is particularly non‐stoichiometric in basins where the extent of glacierization is high, which is most probably an artefact of high flushing rates through ice‐marginal and subglacial environments where K‐feldspars are undergoing mechanical comminution. Copyright © 2000 John Wiley & Sons, Ltd.     

Hydraulic modeling of flood pulses in the Middle Bussento Karst System (MBSKS), UNESCO Cilento Global Geopark,southern Italy

Karst systems provide water for domestic and industrial uses and for generating hydropower, but they can also create fluvial hazards, such as upstream back‐flooding and downstream karst flash‐flood events. However, these hazards are difficult to foresee due to the complex recharge‐discharge processes as well as the lack of information on the inside of the system, which has often not been completely surveyed by speleologists or explored by boreholes. To overcome these difficulties, hydro‐chemical data from the monitoring system in the Middle Bussento Karst System (MBSKS), one of the first Experimental Karst Systems in southern Italy, were recorded and previously discussed. Based on shared background in flood karst hydraulic modeling, this paper describes the conceptual premises and rationale of a general‐purpose hydraulic model that is suitable both for the MBSKS and for other Mediterranean, multi‐recharge, mature, conduit‐dominated karst systems. To test the reliability of the model, simulations of time–space behavior and response are performed using natural and artificial flood pulses “as tracers”, considering a “pulse” as a significant variation in water quantity and/or quality. The results of the model explain the interactions between allogenic, autogenic, and anthropogenic recharges from differentiated sources and phreatic conduit systems. These results also clarify the overall response of karst springs at typical time scales of flood pulses. Table acronym name     

Mapping of erosion rates in marly badlands based on a coupling of anatomical changes in exposed roots with slope maps derived from LiDAR data

Black marls form very extensive outcrops in the Alps and constitute some of the most eroded terrains, thus causing major problems of sedimentation in artificial storage systems (e.g. reservoirs) and river systems. In the experimental catchments near Draix (France), soil erosion rates have been measured in the past at the plot scale through a detailed monitoring of surface elevation changes and at the catchment scale through continuous monitoring of sediment yield in traps at basin outlets. More recently, erosion rates have been determined by means of dendrogeomorphic techniques in three monitored catchments of the Draix basin. A total of 48 exposed roots of Scots pine have been sampled and anatomical variations in annual growth rings resulting from denudation analysed. At the plot scale, average medium‐term soil erosion rates derived from exposed roots vary between 1·8 and 13·8 mm yr^?1 (average: 5·9 mm yr^?1) and values are significantly correlated with slope angle. The dendrogeomorphic record of point‐scale soil erosion rates matches very well with soil erosion rates measured in the Draix basins. Based on the point‐scale measurements and dendrogeomorphic results obtained at the point scale, a linear regression model involving slope angle was derived and coupled to high‐resolution slope maps obtained from a LiDAR‐generated digital elevation model so as to generate high‐resolution soil erosion maps. The resulting regression model is statistically significant and average soil erosion rates obtained from the areal erosion map (5·8, 5·2 and 6·2 mm yr^?1 for the Roubine, Moulin and Laval catchments, respectively) prove to be well in concert with average annual erosion rates measured in traps at the outlet of these catchments since 1985 (6·3, 4·1 and 6·4 mm yr^?1). This contribution demonstrates that dendrogeomorphic analyses of roots clearly have significant potential and that they are a powerful tool for the quantification and mapping of soil erosion rates in areas where measurements of past erosion is lacking. Copyright © 2011 John Wiley & Sons, Ltd.     

Climate and relief-induced controls on the temporal variability of denudation rates in a granitic upland

How soil erosion rates evolved over the last about 100 ka and how they relate to environmental and climate variability is largely unknown. This is due to a lack of suitable archives that help to trace this evolution. We determined in situ cosmogenic beryllium-10 (¹⁰Be) along vertical landforms (tors, boulders and scarps) on the Sila Massif to unravel their local exhumation patterns to develop a surface denudation model over millennia. Due to the physical resistance of tors, their rate of exhumation may be used to derive surface and, thus, soil denudation rates over time. We derived soil denudation rates that varied in the range 0–0.40 mm yr^-1. The investigated boulders, however, appear to have experienced repositioning processes about ~20–25 ka bp and were therefore a less reliable archive. The scarps of the Sila upland showed a rapid bedrock exposure within the last 8–15 ka. Overall, the denudation rates increased steadily after 75 ka bp but remained low until about 17 ka bp . The exhumation rates indicate a denudation pulse that occurred about 17–5 ka bp . Since then the rates have continuously decreased. We identify three key factors for these developments – climate, topography and vegetation. Between 75 and 17 ka bp , climate was colder and drier than today. The rapid changes towards warmer and humid conditions at the Pleistocene–Holocene transition apparently increased denudation rates. A denser vegetation cover with time counteracted denudation. Topography also determined the extent of denudation rates in the upland regime. On slopes, denudation rates were generally higher than on planar surfaces. By determining the exhumation rates of tors and scarps, soil erosion rates could be determined over long timescales and be related to topography and particularly to climate. This is key for understanding geomorphic dynamics under current environmental settings and future climate change. © 2019 John Wiley & Sons, Ltd. © 2019 John Wiley & Sons, Ltd.     

Simulation of spring flows from a karst aquifer with an artificial neural network

In China, 9·5% of the landmass is karst terrain and of that 47,000 km² is located in semiarid regions. In these regions the karst aquifers feed many large karst springs within basins of thousands of square kilometres. Spring discharges reflect the fluctuation of ground water level and variability of ground water storage in the basins. However, karst aquifers are highly heterogeneous and monitoring data are sparse in these regions. Therefore, for sustainable utilization and conservation of karst ground water it is necessary to simulate the spring flows to acquire better understanding of karst hydrological processes. The purpose of this study is to develop a parsimonious model that accurately simulates spring discharges using an artificial neural network (ANN) model. The karst spring aquifer was treated as a non‐linear input/output system to simulate the response of karst spring flow to precipitation and applied the model to the Niangziguan Springs, located in the east of Shanxi Province, China and a representative of karst springs in a semiarid area. Moreover, the ANN model was compared with a previous time‐lag linear model and it was found that the ANN model performed better. Copyright © 2007 John Wiley & Sons, Ltd.     

Basinga: A cell-by-cell GIS toolbox for computing basin average scaling factors,cosmogenic production rates and denudation rates

The calculation of denudation rates from the measured cosmogenic nuclide concentrations in river sediments requires assumptions and approximations. Several different approaches and numerical tools are available in the literature. A widely used analytical approach represents the muogenic production with one or two exponentials, assumes the attenuation length of muons to be constant and also neglects temporal variations in the Earth's magnetic field. The denudation rates are then calculated directly and analytically from the measured concentrations. A second numerical and iterative approach was more recently proposed and considers a more rigorous muogenic production law based on pre-calculated variable attenuation length of muons and accounts for temporal changes of the magnetic field. It also assumes a specific distribution of denudation rates throughout the basin and uses an iterative approach to calculate the basin average denudation rates. We tested the two approaches across several natural basins and found that both approaches provide similar denudation results. Hence, assuming exponential muogenic production and constant attenuation length of muons in the rock has little impact on the derived denudation rates. Therefore, unless a priori known distributions of denudation rates are to be tested, there does not appear to be any particular gain from using the second iterative method which is computationally less effective. Based on these findings, we developed and describe here Basinga , a new ArcGIS® and QGIS toolbox which computes the basin average scaling factors, cosmogenic production rates and denudation rates for several tens of drainage basins together. Basinga follows either the Lal/Stone or the Lifton/Sato/Dunai scaling schemes and includes several optional tools for correcting for topographic shielding, ice cover and lithology. We have also developed an original method for correcting the cosmogenic production rates for past variations in the Earth's magnetic field. © 2019 John Wiley & Sons, Ltd.     

The influence of bedrock orientation on the landscape evolution,surface morphology and denudation (10Be) at the Niesen,Switzerland

Landscape evolution and surface morphology in mountainous settings are a function of the relative importance between sediment transport processes acting on hillslopes and in channels, modulated by climate variables. The Niesen nappe in the Swiss Penninic Prealps presents a unique setting in which opposite facing flanks host basins underlain by identical lithologies, but contrasting litho‐tectonic architectures where lithologies either dip parallel to the topographic slope or in the opposite direction (i.e. dip slope and non‐dip slope). The north‐western facing Diemtigen flank represents such a dip slope situation and is characterized by a gentle topography, low hillslope gradients, poorly dissected channels, and it hosts large landslides. In contrast, the south‐eastern facing Frutigen side can be described as non‐dip slope flank with deeply incised bedrock channels, high mean hillslope gradients and high relief topography. Results from morphometric analysis reveal that noticeable differences in morphometric parameters can be related to the contrasts in the relative importance of the internal hillslope‐channel system between both valley flanks. While the contrasting dip‐orientations of the underlying flysch bedrock has promoted hillslope and channelized processes to contrasting extents and particularly the occurrence of large landslides on the dip slope flank, the flank averaged beryllium‐10 (¹⁰Be)‐derived denudation rates are very similar and range between 0.20 and 0.26 mm yr^?1. In addition, our denudation rates offer no direct relationship to basin's slope, area, steepness or concavity index, but reveal a positive correlation to mean basin elevation that we interpret as having been controlled by climatically driven factors such as frost‐induced processes and orographic precipitation. Our findings illustrate that while the landscape properties in this part of the northern Alpine border can mainly be related to the tectonic architecture of the underlying bedrock, the denudation rates have a strong orographic control through elevation dependent mean annual temperature and precipitation. Copyright © 2013 John Wiley & Sons, Ltd.     

The Ganges and Brahmaputra rivers in Bangladesh: basin denudation and sedimentation

Every year the Ganges and Brahmaputra rivers in Bangladesh transport 316 and 721 million tonnes of sediment, respectively. These high loads of suspended sediment reflect the very high rate of denudation in their drainage basins. The average mechanical denudation rate for the Ganges and Brahmaputra basins together is 365 mm 10³ yr⁻¹. However, the rate is higher in the Brahmaputra Basin than that in the Ganges Basin. Several factors, including mean trunk channel gradient, relief ratio, runoff, basin lithology and recurring earthquakes are responsible for these high denudation rates. Of the total suspended sediment load (i.e. 1037 million tonnes) transported by these rivers, only 525 million tonnes (c. 51% of the total load) are delivered to the coastal area of Bangladesh and the remaining 512 million tonnes are deposited within the lower basin, offsetting the subsidence. Of the deposited load, about 289 million tonnes (about 28% of the total load) are deposited on the floodplains of these rivers. The remaining 223 million tonnes (about 21% of the total load) are deposited within the river channels, resulting in aggradation of the channel bed at an average rate of about 3·9 cm yr⁻¹. Although the Brahmaputra transports a higher sediment load than the Ganges, the channel bed aggradation rate is much higher for the Ganges. This study also documents a wide range of interannual, seasonal and daily variation in suspended sediment transport and water discharge. Interannual variation in sediment deposition within the basin is also suggested. Copyright © 1999 John Wiley & Sons, Ltd.     

Constraining landscape development of the Sri Lankan escarpment with cosmogenic nuclides in river sediment

Escarpments are prominent morphological features along high-elevation passive margins. Recent studies integrating geomorphology, thermochronology, and cosmogenic nuclide-based denudation rate estimates suggest a rapid phase of denudation immediately after the earliest stages of seafloor spreading, and subsequent slow denudation rates since. To constrain the geomorphic evolution of passive margins, we have examined the development of the Sri Lankan escarpment. Cosmogenic nuclide data on river sediment along a north–south transect across the southern escarpment reveal that the landscape is eroding ten times more rapidly in the escarpment zone (26 to 71 mm kyr^− 1) than in the high-elevation plateau above it and in the lowland plain beneath it (2.6 to 6.2 mm kyr^− 1). Unlike these low denudation rate areas, the escarpment denudation is strongly and linearly hill slope-dependent. This shows that denudation and retreat are tightly interlinked within the escarpment, which suggests that the escarpment is evolving by rift-parallel retreat, rather than by escarpment downwearing. Supporting evidence is provided by the morphology of rivers draining the escarpment zone. These have steep bedrock channels which show sharp and prominent knickpoints along their longitudinal profiles. It appears that fluvial processes are driving escarpment retreat, as rivers migrate headwards were they incise into the high-elevation plateau. However, the average catchment-wide denudation rates of the escarpment zone are low compared to the denudation rates that are estimated for constant escarpment retreat since rifting. In common with other escarpments worldwide, causes for this slow down can be tectonic change related to flexural bending of the lithosphere, climate change that would vary the degree of precipitation focused into the escarpment, or the decrease in the contributing catchment area, which would reduce the stream power available for fluvial erosion.     

Chemical erosion of the Lilburn Cave system, Kings Canyon National Park, California

Multi-year instrumental records for input, throughflow and output waters of the Lilburn Cave system provide control on denudation rates as they respond to seasonal and spatial variability. Data suggest that maximum denudation is in the late fall and early winter. This is when non-snowmelt discharge is at its maximum. At lower discharge rates the volume of water moving through the cave system is the limiting control on the volume of denudation. During periods of snowmelt the limiting control is the rate at which the calcite dissolves. This is probably the result of water flowing through wider channels during these times. Based on instrumental measurements, there is considerable variation in terms of where denudation occurs inside the cave. The loci of dissolution change from year to year. This is to be expected in the dynamic environment of the cave where materials shift routinely. This variability should be studied over longer periods of time in order to more fully understand its extent. The relatively small area of carbonate exposure relative to the area of the drainage basin gives rise to relatively high denudation rates. The carbonate is being removed at a rate of about 5000 metric tons per year, or at about 830 mm/y. This is about five times the rate reported in the humid karst regions of Malaysia. This information indicates that the relative proportion of carbonate in the drainage basin needs to be considered when trying to estimate denudation in other areas.     

Some Uncertainties in the Derivation of Rates of Denudation from Thermochronologic Data

Low-temperature thermochronology, such as that provided by apatite fission-track analysis, provides a valuable means of establishing the timing of major denudational events and associated rates of denudation over geological time-scales of 10⁶–10⁸ Ma. Care must be taken, however, in deriving denudation rates from the crustal cooling histories documented by thermochronologic techniques, especially in rapidly eroding terrains, since, in such cases, apparent denudation rates derived from thermochronologic data will usually overestimate true rates if the advective effect of denudation is not included. This is likely to be resolvable where the rate of denudation exceeds 300 m Ma⁻¹ and when the depth of denudation occurring at these rates exceeds several kilometres prior to the sample cooling below the appropriate closure temperature. Because the time at which a sample cools below a particular closure temperature is relatively insensitive to advection, the initiation of denudation can be accurately established, even given uncertainties in the estimation of depths and rates of denudation. Where thermal events originate from a source within or below the lower crust, the cooling through denudation will dominate the low-temperature history of the shallow crust if denudation occurs coevally with the subsurface heating. © 1997 by John Wiley & Sons, Ltd.     

Determination of both exposure time and denudation rate from an in situ-produced 10Be depth profile: A mathematical proof of uniqueness. Model sensitivity and applications to natural cases

Measurements of radioactive in situ-produced cosmogenic nuclide concentrations in surficial material exposed to cosmic rays allow either determining the long-term denudation rate assuming that the surface studied has reached steady-state (where production and losses by denudation and radioactive decay are in equilibrium) (infinite exposure time), or dating the initiation of exposure to cosmic rays, assuming that the denudation and post-depositional processes are negligible. Criteria for determining whether a surface is eroding or undergoing burial as well as quantitative information on denudation or burial rates may be obtained from cosmogenic nuclide depth profiles. With the refinement of the physical parameters involved in the production of in situ-produced cosmogenic nuclides, a unique well-constrained depth profile now permits determination of both the exposure time and the denudation rate affecting a surface. In this paper, we first mathematically demonstrate that the exponential decrease of the in situ-produced ¹⁰Be concentrations observed along a depth profile constrains a unique exposure time and denudation rate when considering both neutrons and muons. In the second part, an improved chi-square inversion model is described and tested in the third part with actual measured profiles.     

Mass transport triggered by heavy rainfall: the role of endorheic basins and epikarst in a regional karst aquifer

This study aims at recognizing the mechanisms of mass transport between the karst surface and the saturated zone in a morphostructural relief of the Mesozoic karst carbonate platform of Murgia (Puglia, Southern Italy). The large dimension of the karst aquifer, the regional scale of the flow system, the boundary condition constituted by the sea, and the lack of freshwater springs constrain to the use of wells as monitoring points and limit the study area to the recharge area comprising 986 endorheic basins. The concentrations of non‐reactive tracers (nitrates) in the waters of autogenic recharge (from endorheic basins) have been modeled through the evaluation of effective infiltration, land use, and nitrogen surplus, with reference to a time window, which includes a low precipitation period followed by significant rainfall events. The comparison between the modeled nitrate concentrations and the nitrate concentrations measured in ground waters, coupled with the analysis of groundwater chemograms and records of hydraulic heads (all referred to the same time window), allows inferring the mechanism of mass transport between the karst surface and the groundwater table. The mass transport conceptual model requires the presence of the epikarst. The infiltration of significant rainfall in the endorheic basins after a low precipitation period displaces waters stored in the epikarst toward the saturated zone. Ground waters in the post‐event period show higher concentrations of nitrates, lower concentrations of total organic carbon, and higher Mg/Ca ratios than both those of the pre‐event period and the autumn‐winter recharge period. The post‐event recharge from epikarst storage determines a transient hazard of groundwater pollution with a time lag from the occurrence of the heavy rainfall.