Zircon U‐Pb Ages and Geochemistry of Permo‐Carboniferous Mafic Intrusions in the Xilinhot Area,Inner Mongolia: Constraints on the Northward Subduction of the Paleo‐Asian Ocean

The Central Asian Orogenic Belt(CAOB) resulted from accretion during the Paleozoic subduction of the PaleoAsian Ocean. The Xilinhot area in Inner Mongolia is located in the northern subduction zone of the central-eastern CAOB and outcropped a large number of late Paleozoic mafic intrusions. The characteristics of magma source and tectonic setting of the mafic intrusions and their response to the closure process of the Paleo-Asian Ocean are still controversial. This study presents LA-ICPMS zircon U-Pb ages and geochemical features of mafic intrusions in the Xilinhot area to constrain the northward subduction of the Paleo-Asian Ocean. The mafic intrusions consist of gabbro, hornblende gabbro, and diabase. Their intrusion times can be divided into three stages of 326–321 Ma, 276 Ma and 254 Ma by zircon U-Pb ages. The first two stages of the 326–276 Ma intrusions mostly originated from subduction-modified continental lithospheric mantle sources that underwent a variable degree partial melting(5–30%), recording the subduction of oceanic crust. The third stage of the 254 Ma mafic rocks also show arc-related features. The primary magma compositions calculated by PRIMELT2 modeling on three samples of ～326 Ma and two samples of ～254 Ma show that these mafic samples are characterized by a variable range in SiO_2(47.51–51.47 wt%), Al_2O_3(11.46–15.55 wt%), ΣFeO(8.27–9.61 wt%), MgO(13.01–15.18 wt%) and CaO(9.13–11.67 wt%), consisting with the features between enriched mantle and lower continental crust. The source mantle melting of mafic intrusions occurred under temperatures of 1302–1351°C and pressures of 0.92–1.30 GPa. The magmatic processes occurred near the crust-mantle boundary at about 33–45 km underground. Combined with previous studies, it is concluded that Carboniferous to early Permian(～326–275 Ma) northward subduction of the Paleo-Asian oceanic crust led to the formation of the mafic magmatism in the Baolidao arc zone. The whole region had entered the collision environment at ～254 Ma, but with subduction-related environments locally. The final collision between the North China craton and the South Mongolian microcontinent may have lasted until ca. 230 Ma.     

An Overview on the Composition and Age of Upper Crust of Proto-Tethyan Lajishan Intra-oceanic Arc, NE Tibet Plateau

Identification and anatomy of oceanic arcs within ancient orogenic belt are significant for better understanding the tectonic framework and closure process of paleo-ocean basin. This article summarizes the geological, geochemical, and geochronological characteristics of upper crust of Proto-Tethyan Lajishan intra-oceanic arc and provides new data to constrain the subduction evolution of the South Qilian Ocean. The intra-oceanic arc volcanic rocks, including intermediate–mafic lava, breccia, tuff, and minor felsic rocks, are distributed along southern part of the Lajishan ophiolite belt. Geochemical and isotopic compositions indicate that the intermediate–mafic lava were originated from depleted mantle contaminated by sediment melts or hydrous fluids, whereas the felsic rocks were likely generated by partial melting of juvenile mafic crust in intra-oceanic arc setting. Zircons from felsic rocks yield consistent and concordant ages ranging from 506 to 523 Ma, suggesting these volcanic rocks represent the relicts of upper crust of the Cambrian intra-oceanic arc. Combined with the Cambrian forearc ophiolite and accretionary complex, we suggest that the Cambrian intra-oceanic arc in the Lajishan ophiolite belt is belonging to the intra-oceanic arc system which was generated by south-directed subduction in the South Qilian Ocean at a relatively short interval between approximately 530 and 480 Ma.     

U–Pb Zircon Geochronology and Geochemistry of the Neoproterozoic Liujiaping Group Volcanics in the Northwest Margin of the Yangtze Block:Implications For the Breakup of the Rodinia Supercontinent

Investigation of the petrogenesis and the origin of zircons from the volcanic rocks of the Liujiaping Group of the back-Longmenshan tectonic belt in the northwest margin of the Yangtze Block is conducted by analysis of U–Pb geochronology and geochemistry. Results show that selected zircons are characterized by internal oscillatory zonings and high Th/U ratios(0.43–1.18), indicating an igneous origin. Geochronological results of LA–ICP–MS U–Pb dating of the Liujiaping Group zircons yield an age of 809 ± 11 Ma(MSWD = 2.2), implying that the volcanic rocks were formed in the Late Neoproterozoic. Geochemical analysis shows that the rocks are calc-alkaline, supersaturated in Al, and metaluminous to weakly peraluminous. Rare-earth elements are present at high concentrations(96.04–265.48 ppm) and show a rightward incline and a moderately negative Eu anomaly, similar to that of continental rift rhyolite. Trace element geochemistry is characterized by evident negative anomalies of Nb, Ta, P, Th, Ti, inter alia, and strong negative anomalies of K, Rb, Sr, et al. We conclude that the Liujiaping Group volcanic rocks resulted from typical continental crust source petrogenesis and were formed in a continental margin setting, which had no relation to subduction, and thus, were the products of partial melting of the lower crust due to crustal thickening caused by active continental margin subduction and arc–continent collision orogeny in the northwestern Yangtze Block and were triggered by the breakup of the Rodinia supercontinent during the Neoproterozoic.     

U–Pb Zircon Geochronology and Geochemistry of the Neoproterozoic Liujiaping Group Volcanics in the Northwest Margin of the Yangtze Block: Implications For the Breakup of the Rodinia Supercontinent

Investigation of the petrogenesis and the origin of zircons from the volcanic rocks of the Liujiaping Group of the back-Longmenshan tectonic belt in the northwest margin of the Yangtze Block is conducted by analysis of U–Pb geochronology and geochemistry. Results show that selected zircons are characterized by internal oscillatory zonings and high Th/U ratios (0.43–1.18), indicating an igneous origin. Geochronological results of LA–ICP–MS U–Pb dating of the Liujiaping Group zircons yield an age of 809 ± 11 Ma (MSWD = 2.2), implying that the volcanic rocks were formed in the Late Neoproterozoic. Geochemical analysis shows that the rocks are calc-alkaline, supersaturated in Al, and metaluminous to weakly peraluminous. Rare-earth elements are present at high concentrations (96.04–265.48 ppm) and show a rightward incline and a moderately negative Eu anomaly, similar to that of continental rift rhyolite. Trace element geochemistry is characterized by evident negative anomalies of Nb, Ta, P, Th, Ti, inter alia, and strong negative anomalies of K, Rb, Sr, et al. We conclude that the Liujiaping Group volcanic rocks resulted from typical continental crust source petrogenesis and were formed in a continental margin setting, which had no relation to subduction, and thus, were the products of partial melting of the lower crust due to crustal thickening caused by active continental margin subduction and arc–continent collision orogeny in the northwestern Yangtze Block and were triggered by the breakup of the Rodinia supercontinent during the Neoproterozoic.     

Provenance of the Early–Middle Devonian Shugouzi Formation in the Quruqtagh, Northeastern Xinjiang: Constraints from Sandstone Geochemistry and Heavy Mineral Analysis

The Early-Middle Devonian Shugouzi Formation in the Quruqtagh block consists mainly of clastic rocks.However,their provenance has been scarcely studied since it was named.Geochemistry of clastic rocks was commonly used to interpret the provenance.Detrital heavy mineral analyses help frame the U-Pb age from zircon grains,integrated with geochemical data from detrital tourmaline and spinels.These techniques were used to characterize components of the sediment flux and define erosion areas in the Qurugtagh block,further providing evidence about the tectonic evolution of the South Tianshan and Tarim plate.The maximum depositional age constrained by detrital zircon dating was Early-Middle Devonian.Multiple diagrams for sedimentary provenance using major and trace elements indicate that continental island arc-related felsic rocks were the major source rocks for the Shugouzi Formation.Detrital tourmalines are dravite and schorl.The results of detrital tourmaline electron probe microanalysis(EPMA)show that the source rocks are mainly metasedimentary rocks and granitoids.The detrital chromian spinels within the sediments are characterized by high chroumium(Cr^#)and varying magnesium(Mg^#).The discrimination plots reveal that these spinels were sourced from island arc magmatic rocks.The laser ablation inductively-coupled plasma mass spectrometry(LA-ICP-MS)U-Pb chronology of detrital zircons suggests that the sediments were derived mainly from 414-491 Ma and 744-996 Ma magmatic rocks.Paleocurrent restoration,sandstone geochemistry,EPMA,and detrital zircon geochronology indicate that the source rocks were predominantly derived from Late Ordovician and Devonian magmatic rocks and subordinately from recycled Neoproterozoic magmatic rocks.Comprehensive analyses of the source areas suggest that a remnant arc still existed in the Early Devonian and the Shugouzi Formation was deposited in a passive continental margin.     

Episodic Paleozoic Adakitic Magmatism in the Eastern Tianshan, Southern Altaids: Implications for Petrogenesis and Geodynamics

The adakites rocks are typically considered as direct diagnostic evidence for subduction and continental growth, as well as the important evidence to determine the location of the major oceanic basin and evolution history of lost oceanic basins, which are longstanding conundrums for understanding the tectonics of the Paleo-Asian Ocean (PAO). As the processor of the Altaids, the PAO was a long-lived ocean, and its multiple subductions led to substantial continental growth in the Central Asian continent. Here we report our newly discovered Paleozoic adakitic rocks (granite and dacite) developed in Jijitaizi in the Eastern Tianshan of the southern Altaids to address the above issues. The Jijitaizi granite and dacite contain high concentrations of Sr (203–343 ppm) and low concentrations of Y (3.00–6.36 ppm) and Yb (0.23–0.62 ppm), indicative of the adakitic affinity. Zircon U-Pb dating results show that the adakitic rocks were formed in three episodes at 372.26 ± 1.51 Ma, 356.02 ± 1.11 Ma and 334.51 ± 0.68 Ma from the Late Devonian to Carboniferous. The rocks are depleted in Nb, P and Ti, and possess variable Mg# values (28.51–57.22), high Na2O/K2O ratios (1.39–4.94), as well as relatively depleted Hf isotopic compositions, all of which point to a subduction origin from slab melting. Our new finding with the date from the Jijitaizi complex (ca. 321 Ma) suggests continuing subduction of the Paleo-Asian oceanic slab beneath the Central Tianshan from the Late Devonian to Carboniferous. Our work provides a solid line of key evidence demonstrating that continuous oceanic subduction of the major PAO evolved into its mature stage following subducting beneath the Central Tianshan from ca. 372 to 321 Ma.     

Tectonic Setting and Nature of the Provenance of Sedimentary Rocks in Lanping Mesozoic- Cenozoic Basin： Evidence from Geochemistry of Sandstones

The geochemical composition of sandstones in the sedimentary basin is controlled mainly by the tectonic setting of the provenance, and it is therefore possible to reveal the tectonic setting of the provenance and the nature of source rocks in terms of the geochemical composition of sandstones. The major elements, rare-earth dements and trace elements of the Mesozoic-Cenozoic sandstones in the Lanping Basin are studied in this paper, revealing that the tectonic settings of the provenance for Mesozoic-Cenozoic sedimentary rocks in the Lanping Basin belong to a passive continental margin and a continental island arc. Combined with the data on sedimentary facies and palaeogeography, it is referred that the eastern part of the basin is located mainly at the tectonic setting of the passive continental margin before Mesozoic, whereas the western part may be represented by a continental island arc. This is compatible with the regional geology data. The protoliths of sedimentary rocks should be derived from the upper continental crust, and are composed mainly of felsic rocks, mixed with some andesitic rocks and old sediment components. Therefore, the Lanping Mesozoic-Cenozoic Basin is a typical continental-type basin. This provides strong geochemical evidence for the evolution of the paleo-Tethys and theb asin-range transition.     

Petrogenesis and Tectonic Implications of the Latest Cretaceous Intrusive Rocks from the Eastern Gangdese Belt, Southeast Tibet

The latest Cretaceous magmatic activity in the eastern segment of the Lhasa terrane provides important insights for tracking the magma source and geodynamic setting of the eastern Gangdese batholith, eastward of eastern Himalayan Syntaxis. Detailed petrological, geochemical and geochronological studies of the intrusive rocks (monzodiorites and granodiorites) of the eastern Gangdese batholith are presented with monzodiorites and granodiorites giving zircon U–Pb crystallization dates of 70–66 Ma and 71–66 Ma with εHf(t) values of ?4.8 to +6.2 and ?1.9 to +5.3, respectively. These rocks are metaluminous to weakly peraluminous I-type granites showing geochemically arc-related features of enrichment in LREEs and some LILEs, e.g., Rb, Th, and U, and depletion in HREEs and some HFSEs, e.g., Nb, Ta, and Ti. The rocks are interpreted to be derived from partial melting of mantle material and juvenile crust, respectively, which are proposed to be triggered by Neo-Tethyan slab rollback during northward subduction, with both experiencing ancient crustal contamination. The studied intrusive rocks formed in a transitional geodynamic setting caused by Neo-Tethyan oceanic flat subduction to slab rollback beneath the eastern Gangdese belt during the latest Cretaceous.     

Detrital Zircon U‐Pb Ages and Geochemistry of the Silurian to Permian Sedimentary Rocks in Central Inner Mongolia,China: Implications for Closure of the Paleo‐Asian Ocean

The Solonker suture zone has long been considered to mark the location of the final disappearance of the PaleoAsian Ocean in the eastern Central Asian Orogenic Belt(CAOB). However, the time of final suturing is still controversial with two main different proposals of late Permian to early Triassic, and late Devonian. This study reports integrated wholerock geochemistry and LA-ICP-MS zircon U-Pb ages of sedimentary rocks from the Silurian Xuniwusu Formation, the Devonian Xilingol Complex and the Permian Zhesi Formation in the Hegenshan-Xilinhot-Linxi area in central Inner Mongolia, China. The depositional environment, provenance and tectonic setting of the Silurian-Devonian and the Permian sediments are compared to constrain the tectonic evolution of the Solonker suture zone and its neighboring zones. The protoliths of the silty slates from the Xuniwusu Formation in the Baolidao zone belong to wacke and were derived from felsic igneous rocks with steady-state weathering, poor sorting and compositional immaturity. The protoliths of metasedimentary rocks from the Xilingol Complex were wackes and litharenites and were sourced from predominantly felsic igneous rocks with variable weathering conditions and moderate sorting. The Xuniwusu Formation and Xilingol Complex samples both have two groups of detrital zircon that peak at ca. 0.9–1.0 Ga and ca. 420–440 Ma, with maximum deposition ages of late Silurian and middle Devonian age, respectively. Considering the ca. 484–383 Ma volcanic arc in the Baolidao zone, the Xuxiniwu Formation represents an oceanic trench sediment and is covered by the sedimentary rocks in the Xilingol Complex that represents a continental slope sediment in front of the arc. The middle Permian Zhesi Formation metasandstones were derived from predominantly felsic igneous rocks and are texturally immature with very low degrees of rounding and sorting, indicating short transport and rapid burial. The Zhesi Formation in the Hegenshan zone has a main zircon age peak of 302 Ma and a subordinate peak of 423 Ma and was deposited in a back-arc basin with an early marine transgression during extension and a late marine regression during contraction. The formation also crops out locally in the Baolidao zone with a main zircon age peak of 467 Ma and a minor peak of 359 Ma, and suggests it formed as a marine transgression sedimentary sequence in a restricted extensional basin and followed by a marine regressive event. Two obvious zircon age peaks of 444 Ma and 280 Ma in the Solonker zone and 435 Ma and 274 Ma in Ondor Sum are retrieved from the Zhesi Formation. This suggests as a result of the gradual closure of the Paleo-Asian Ocean a narrow ocean sedimentary environment with marine regressive sedimentary sequences occupied the Solonker and Ondor Sum zones during the middle Permian. A restricted ocean is suggested by the Permian strata in the Bainaimiao zone. Early Paleozoic subduction until ca. 381 Ma and renewed subduction during ca. 310–254 Ma accompanied by the opening and closure of a back-arc basin during ca. 298–269 Ma occurred in the northern accretionary zone. In contrast, the southern accretionary zone documented early Paleozoic subduction until ca. 400 Ma and a renewed subduction during ca. 298–246 Ma. The final closure of the Paleo-Asian ocean therefore lasted at least until the early Triassic and ended with the formation of the Solonker suture zone.     

Subduction and Collision of the Jinsha River Paleo-Tethys: Constraints from Zircon U-Pb Dating and Geochemistry of the Ludian Batholith in the Jiangda–Deqen–Weixi Continental Margin Arc

The Jiangda–Deqen–Weixi continental margin arc(DWCA) developed along the base of the Changdu–Simao Block and was formed as a result of the subduction of the Jinsha River Ocean Slab and the subsequent collision. The Ludian batholith is located in the southern part of the DWCA and is the largest batholith in northwest Yunnan. Granite samples from the Ludian batholith yield an early Middle Permian age of 271.0 ± 2.8 Ma. The geochemical data of the early Middle Permian granitoids show high Si2 O, low P2 O5 and MgO contents that belong to calc-alkaline series and peraluminous I-type rocks. Their εHf(t) values range from-5.01 to +0.58, indicating that they were formed by hybrid magmas related to the subduction of the Jinsha River Tethys Ocean. The monzonite and monzogranite samples yield Late Permian ages of 250.6 ± 1.8 Ma and 252.1 ± 1.3 Ma, respectively. The Late Permian granitoids are high-K calc alkaline and shoshonite series metaluminous I-type rocks. Their εHf(t) values range from-4.12 to-1.68 and from-7.88 to-6.64, respectively. The mixing of crustal and mantle melts formed the parental magma of the Late Permian granitoids. This study, combined with previous work, demonstrates the process from subduction to collision of the Jinsha River Paleo-Tethys Ocean.     

Petrogenesis and Tectonics of the Naruo Porphyry Cu(Au) Deposit Related Intrusion in the Duolong Area, Central Tibet

The Duolong area is the most important part of the Western Bangong-Nujiang Suture Zone porphyry Cu(Au) metallogenic belt, in Tibet, China. Here new detailed data are presented from LAICP-MS zircon U-Pb, whole-rock geochemical, and in-situ zircon Hf isotope analyses for igneous rocks in the large Naruo deposit(2.51 Mt of Cu and 82 t of Au) which is located ~2 km NE of the Duolong(Duobuza and Bolong) super-large gold-rich porphyry copper deposit. We integrated our results with previous research of other porphyry deposits in the Duolong area and have identified the timing, geodynamic setting, and petrogenesis of the mineralization-associated magmatic events. Based on the measurements, the Duolong area porphyry Cu(Au) deposit formations are associated with Early Cretaceous intermediate-felsic magmatism, which is consistent with U-Pb zircon ages of 120 Ma. All the main intrusive rocks in the ore-concentrated area have similar lithogeochemical characteristics; they show a relative enrichment in both light rare earth elements(LREEs) and large-ion lithophile elements(LILEs: Rb, Ba, K, etc.) and relative depletion in both heavy rare earth elements(HREEs) and high field strength elements(HFSEs: Nb, Ta, Zr, Hf, etc.). Moreover, the granite porphyry shows positive εHf(t) values between 1.38–7.37 suggesting that magmas were potentially derived from the partial melting of a depleted mantle wedge that had been metasomatized by subducted slab-derived fluids or melts. This paper points out that the formation of the porphyry-epithermal Cu(Au) deposit in the Duolong area was dominated by northward subduction of the Bangongco Tethys Plate beneath the Qiangtang block in the Early Cretaceous(124–114 Ma), when the subducted oceanic crust reached 50–70 km underground and generated different degrees of phase transformation, which lead to a melt produced by dehydration of amphibole minerals, a metasomatized mantle wedge, and induced mantle partial melting that produced the magma. Those deposits occurred in a continental arc tectonic setting, which is similar to the continental margin arc environment of the ocean-continent subduction setting of the Andes metallogenic belt in South America.     

Geochemistry of Late Mesozoic mafic dykes in western Fujian Province of China： Sr-Nd isotope and trace element constraints

The Bancun diabase dyke and the Bali hornblende gabbro dyke in western Fujian Province were emplaced in the Early and Late Cretaceous periods, respectively; the former is designated to calc-alkaline series and the latter to K-high-calc-alkaline rock series. Both the dykes are characterized by such geochemical characteristics as high Al and Na2O>K2O. As for the Bancun dyke, Al2O3=16.32%–17.54% and K2O/Na2O=0.65–0.77; as for the Bali dyke, Al2O3=16.89%–17.81% and K2O/Na2O=0.93–0.99. Both the Bancun and Bali mafic dykes are relatively enriched in LILE and LREE, but depleted in HSFE, displaying the geochemical characteristics of continental marginal arc, with high initial Sr isotopic ratios and low εNd (t) values. The (87Sr/86Sr)i ratios of the Bancun diabase dyke are within the range of 0.708556–0.70903 and their εNd (t) values vary between -6.8 and -6.3; those of the Bali hornblende dyke are within the range of 0.710726–0.710746 and their εNd (t) values are -4.7– -4.9, showing the characteristics of enriched mantle EM II. The isotope and trace element data showed that the mafic dykes have not experienced obvious crustal contamination, and metasomatism caused by subduction fluids is the main factor leading to LILE and LREE enrichments. The enriched mantle is the source region for the mafic dykes, and mixing of subduction fluid metasomatized enriched mantle and EM II-type mantle constituted the mantle source region of both the Bancun and Bali mafic dykes. Upwelling of the asthenosphere mantle provided sufficient heat energy for the generation of magmas. In accordance with the discrimination diagram of their tectonic settings as well as their trace element geochemical characteristics, it is considered that the dykes both at Bancun and Bali possess the characteristics of continental marginal arc, revealing the tectonic environment of formation of the mafic dykes, the continental dynamic background as an intraplate tensional belt in which the mafic dykes were emplaced. Meanwhile, it is also indicated that the tensional tectonic stress mechanism is responsible for the formation of the mafic dykes in western Fujian Province.     

What Happened in the Trans-North China Orogen in the Period 2560-1850 Ma？

The Trans-North China Orogen （TNCO） was a Paleoproterozic continent-continent collisional belt along which the Eastern and Western Blocks amalgamated to form a coherent North China Craton （NCC）. Recent geological, structural, geochemical and isotopic data show that the orogen was a continental margin or Japan-type arc along the western margin of the Eastern Block, which was separated from the Western Block by an old ocean, with eastward-directed subduction of the oceanic lithosphere beneath the western margin of the Eastern Block. At 2550-2520 Ma, the deep subduction caused partial melting of the medium-lower crust, producing copious granitoid magma that was intruded into the upper levels of the crust to form granitoid plutons in the low- to medium-grade granite-greeustone terranes. At 2530-2520 Ma, subduction of the oceanic lithosphere caused partial melting of the mantle wedge, which led to underplating of mafic magma in the lower crust and widespread mafic and minor felsic volcanism in the arc, forming part of the greenstone assemblages. Extension driven by widespread mafic to felsic volcanism led to the development of back-arc and/or intra-arc basins in the orogen. At 2520-2475 Ma, the subduction caused further partial melting of the lower crust to form large amounts of tonalitic-trondhjemitic-granodioritic （TTG） magmatism. At this time following further extension of back-arc basins, episodic granitoid magmatism occurred, resulting in the emplacement of 2360 Ma, -2250 Ma 2110-21760 Ma and -2050 Ma granites in the orogen. Contemporary volcano-sedimentary rocks developed in the back-arc or intra-are basins. At 2150-1920 Ma, the orogen underwent several extensional events, possibly due to subduction of an oceanic ridge, leading to emplacement of mafic dykes that were subsequently metamorphosed to amphibolites and medium- to high-pressure mafic granulites. At 1880-1820 Ma, the ocean between the Eastern and Western Blocks was completely consumed by subduction, and the dosing of the ocean led to the continent-arc-continent collision, which caused large-scale thrusting and isoclinal folds and transported some of the rocks into the lower crustal levels or upper mantle to form granulites or eclogites. Peak metamorphism was followed by exhumation/uplift, resulting in widespread development of asymmetric folds and symplectic textures in the rocks.     

Geochronology, Geochemistry and Sr-Nd-Pb-Hf Isotopes of No. I Complex from the Shitoukengde Ni–Cu Sulfide Deposit in the Eastern Kunlun Orogen, Western China: Implications for the Magmatic Source, Geodynamic Setting and Genesis

The Shitoukengde Ni-Cu deposit, located in the Eastern Kunlun Orogen, comprises three mafic–ultramafic complexes, with the No. I complex hosting six Ni-Cu orebodies found recently. The deposit is hosted in the small ultramafic bodies intruding Proterozoic metamorphic rocks. Complexes at Shitoukengde contain all kinds of mafic-ultramafic rocks, and olivine websterite and pyroxene peridotite are the most important Ni-Cu-hosted rocks. Zircon U-Pb dating suggests that the Shitoukengde Ni-Cu deposit formed in late Silurian(426–422 Ma), and their zircons have εHf(t) values of-9.4 to 5.9 with the older T_(DM1) ages(0.80–1.42 Ga). Mafic-ultramafic rocks from the No. I complex show the similar rare earth and trace element patterns, which are enriched in light rare earth elements and large ion lithophile elements(e.g., K, Rb, Th) and depleted in heavy rare earth elements and high field strength elements(e.g., Ta, Nb, Zr, Ti). Sulfides from the deposit have the slightly higher δ~(34)S values of 1.9–4.3‰ than the mantle(0 ± 2‰). The major and trace element characteristics, and Sr-Nd-Pb and Hf, S isotopes indicate that their parental magmas originated from a metasomatised, asthenospheric mantle source which had previously been modified by subduction-related fluids, and experienced significant crustal contamination both in the magma chamber and during ascent triggering S oversaturation by addition of S and Si, that resulted in the deposition and enrichment of sulfides. Combined with the tectonic evolution, we suggest that the Shitoukengde Ni-Cu deposit formed in the post-collisional, extensional regime related to the subducted oceanic slab break-off after the Wanbaogou oceanic basalt plateau collaged northward to the Qaidam Block in late Silurian.     

Geochronology,Geochemistry and Petrogenesis of the Pungco Ophiolite,TibetEI北大核心CSCD

Although the middle section of the Bangong-Nujiang suture zone has been intensively investigated, its tectonic framework and evolution is still controversy. The Pungco ophiolite has a relative complete ophiolitic complex, which is an ideal specimen for studying this tricky problem. LA-ICP-MS U-Pb dating of zircons from the diabasic rock yielded an age of 159.0±2.1 Ma. This age suggests that the Pungco ophiolite was formed in the Late Jurassic, indicating the development of the Late Jurassic ophiolite in the third ophiolitic subzone. The whole-rock major and trace element compositions of diabasic and basaltic rocks exhibit mixed arc and N-MORB geochemical characteristics. Two diabasic samples have (87Sr/86Sr)i values of 0.7055 and 0.7063 and εNd(t) values of 11.28 and 11.84, respectively. The geochemical signatures and formation age of the Pungco ophiolite suggest that this ophiolite was probably produced in an active continental fore-arc setting. It originated from a N-MORB-like depleted mantle source with the involvement of subducted-slab fluids. Considering the regional geological background, the Pungco ophiolite was likely generated during the southward subduction of the Bangong-Nujiang Tethyan oceanic lithosphere beneath the Lhasa terrane, and belongs to a regional archipelagic arc-basin system together with the other Early Jurassic-Early Cretaceous ophiolites from the northern Tibet Lake district. © 2018, Science Press. All right reserved.     

Geochemistry and Provenance of Maastrichtian Clastic Rocks in the Dikmendede Formation of Orhaniye in Kazan-Ankara-Turkey Region

An integrated petrographic and geochemical study of the sandstones of the Maastrichtian-aged in the Orhaniye (Kazan-Ankara-Turkey) was carried out to obtain more information on their provenance, sedimentological history and tectonic setting. Depending on their matrix and mineralogical content, the Maastrichtian sandstones are identified as lithic arenite/wacke. The Dikmendede sandstones derived from types of provenances, the recycled orogen and recycled transitional. The chemical characteristics of the Dikmendede sandstones, i.e., fairly uniform compositions, high Th/U ratios (>3.0), negative Eu anomalies (Eu/Eu* 0.72–0.99) and Th/Sc ratios (mostly less than 1.0), favor the OUC (old upper continental crust) provenance for the Dikmendede sandstones. The SiO2/Al2O3, Th/Sc (mostly <1.0) and La/Sc (<4.0) ratios are; however, slightly lower than typical OUC, and these ratios may suggest a minor contribution of young arc-derived material. The rare earth element (REE) pattern, and La/Sc versus Th/Co plot suggests that these sediments were mainly derived from felsic source rocks. The Dikmendede sandstones have high Cr (123–294 ppm) and Ni (52–212 ppm) concentrations, Cr/Ni ratio of 1.93, and a medium correlation coefficient between Cr and Ni and corresponding medium to high correlation of both (Cr and Ni, respectively) elements with Co. These relationships indicate a significant contribution of detritus from ophiolitic rocks. As rare earth element data are available for the Dikmendede sandstones, the Eu/Eu* is compared with LaN/YbN. Samples plot in the area of overlapping between continental collision, strike-slip and continental arc basins. The predominantly felsic composition of the Dikmendede sandstones is supported by the REE plots, which show enriched light REE, negative Eu anomaly and flat or uniform heavy REE. The Dikmendede sandstones have compositions similar to those of the average upper continental crust and post-Archean Australian shales. This feature indicates that the sediments were derived mainly from the upper continental crust. The Dikmendede sandstones have chemical index of alteration (CIA) values of 28–49, with an average of 40 indicating a low degree of chemical weathering in the source area. The compositional immaturity of the analyzed sandstone samples is typical of subduction-related environments, and their SiO2/Al2O3 and K2O/Na2O ratios and Co, Sc, Th and Zr contents reflect their oceanic and continental-arc settings. The Dikmendede sandstones were developed as flysch deposits derived from mixed provenance in a collision belt.     

Timing of Anatexis within the Berere HTHP Complex Belt of Maevatanana Area, North-Central Madgascar, and its Geological Significance

The Berere HTHP Complex belt in Maevatanana area of north–central Madagascar formed in the ~ 2.5 Ga orogeny and underwent high temperature (up to 1050oC) and high pressure (up to 11.5 kbar) granulite facies metamorphism. Then a widespread anatexis took place and numerous widely distributed felsic leucosomes formed. The majority of these leucosomes are parallel to the schistosity of the complex or are present as stockworks, as thin layers, or as lenses at different scales in the host rocks. Here, we report new petrographic data, zircon LA-ICP-MS U-Pb ages, and Lu–Hf isotopic data for felsic leucosomes within this complex. Anatexis, as identified by the petrological study of felsic leucosomes in the field and in thin sections, involved initial ternary feldspar exsolving to produce antiperthite and a quartz + plagioclase ± K-feldspar + sericite mineral assemblage around feldspar grain boundaries. Dissolution is apparent along muscovite grain boundaries, and residual sericite is present around the margins of feldspar and quartz, all suggesting that anatexis was driven by reactions involving muscovite. Zircon U–Pb dating indicates that the felsic leucosomes within the complex formed at 2467–2369 Ma. The majority of samples have positive εHf(t) values, although a few have negative values, suggesting their formation from magmas predominantly sourced from the depleted mantle, possibly with the involvement of minor amounts of crustal materials. Two-stage Hf model ages and εHf(t) values for these samples are consistent with those for gneisses of the basement, indicating that the felsic leucosomes were formed by the anatexis of gneisses and both of their protolith formed during the formation of continental crust in Meso-Neoarchean (ca. 3.1–2.7 Ga). As such, the crystallization age of the felsic leucosome (~2.4 Ga) represents the timing of regional anatexis and a change to post-orogenic tectonism. And this anatexis is also corresponds to the thermal event in Dharwar craton in India which has a pronounced similar Precambrian geology with Madagascar, providing an important constraints on the correlation of the two continental fragments     

Provenance of Conglomerate and Sandstone from Early Permian Shoushangou Formation in Xi Ujimqin, Inner Mongolia: Implications for Understanding Paleo-Asian Ocean Subduction

During the Late Carboniferous to Early Permian, a rift was formed by post-collisional extension after ocean closure or an island arc-related basin formed by Paleo-Asian Ocean (PAO) subduction in the Xi Ujimqin area. Nevertheless, the closure time of the PAO is still under debate. Thus, to identify the origin of the PAO, the geochemistry and U-Pb age of zircons were analyzed for the extra-large deep marine, polymict clastic boulders and sandstones in the Shoushangou Formation within the basin. The analyses revealed magmatic activity and tectonic evolution. The conglomerates include megaclasts of granite (298.8 ± 9.1?Ma) and granodiorite porphyry (297.1 ± 3.1?Ma), which were deposited by muddy debris flow. Results of this study demonstrated that the boulders of granitoids have the geochemistry of typical I-type granite, characterized by low Zr + Nb + Ce + Y and low Ga/Al values. The granitoid boulders were formed in island arc setting, indicating the presence of arc magmatism in the area that is composed of the Late Carboniferous to Early Permian subduction-related granitoid in southern Xi Ujimqin. Multiple diagrams for determining sedimentary provenance using major and trace elements indicate that Shoushangou sediments originated from continental island arc-related felsic rocks. Detrital zircon U-Pb age cluster of 330–280?Ma was obtained, indicating input from granite, ophiolite, Xilin Gol complex, and Carboniferous sources to the south. The basin was geographically developed behind the arc during the Early Permian period because the outcropped intrusive rocks in the Late Carboniferous to Early Permian form a volcanic arc. The comprehensive analyses of source areas suggest that Shoushangou sediments developed in a backarc basin in response to the northward subduction of the PAO. The backarc basin and intrusive rocks, in addition to previously published Late Carboniferous to Early Permian magmatic rocks of arc unit in Xilin Gol, confirm the presence of an Early Permian trench-arc-basin system in the region, represented by the Baolidao arc and Xi Ujimqin backarc basin. This study highlights the importance and potential of combined geochemical and geochronological studies of conglomerates and sandstone for reconstructing the geodynamic setting of a basin.     

Geochemistry of sandstones from the Neoproterozoic Jinshanzhai Formation in northern Anhui Province, China: Provenance, weathering and tectonic setting

Sandstones from the Neoproterozoic Jinshanzhai Formation in northern Anhui Province, China, were analyzed for major oxides and trace elements to infer their provenance, the intensity of paleo-weathering of their source rocks and the depositional tectonic setting. Diagrams of (SiO2/20)-(Na2O+K2O)-(MgO+TiO2+FeO*), TiO2-Ni, Th-Hf-Co, Hf-La/Th and some ratios of elements indicate that felsic rocks constitute the source rocks in the provenance. The values of Chemical Index of Alteration (CIA) are low, which are considered to be affected by K-metasomatism. Whereas the high CIW (Chemical Index of Weathering) values indicate intensive weathering of the source material. Plots of sandstones on bivariate and triangle discriminant diagrams, as well as ICV (Index of Compositional Variation) values revealed that they were deposited on a passive continental margin or in an intra-plate basin. Our recent study, in combination with previous studies and the research progress of the Rodinia super continent, demonstrated that the convergence and extension of the Rodinia super continent were preserved by twice extension as expressed by petrological variation of the southeastern margin of the North China Craton (NCC) during the Neoproterozoic.     

Geochemical Features of the Two Early Paleozoic Ophiolitic Zones and Volcanic Rocks in the Central —Southern Tianshan Region ,Xinjiang

This paper deals with the geochemical features of the two Early Paleozoic ophiolite zones in the central-southem Tianshan region and the central Tianshan igneous rock belt between them.Study results suggest that the central Tianshan belt was an Ordovician volcanic arc with an affinity of continental crust, and the Kumux-Hongluhe ophiolitic zone that is located on the southern margin of central Tianshan has a crustal affinity to back-arc marginal sea.The Aqqikkudug-Weiya ophiolitic zone is an accretionary boundary between the Tuha continental block and the central Tianshan volcanic arc during Late Silurian to Devoniann;Ordovician ophi-olitic blocks,Silurian flysch sequence and HP metamorphic rock relics are distributed along the Aqqikkudug-Weiya zone.Geochemically,ophiolitic rocks in the Aqqikkudug-Weiya zone have an affinity to oceanic crust,reflecting a tectonic setting of paleo-trench or subduction zone .The Early Carboniferous red molasses were deposited unconformably on the pre-Carboniferous meta-mrophosed and ductile sheared volcanic and flysch rocks,providing an upper limit age of the central and southern Tianshan belts.