Neues mathematisches Verfahren zur Charakterisierung unbekannter organischer Vielstoffgemische durch die Adsorptionsanalyse

The adsorption analysis, a process-technology-oriented analytical method, characterizes complex organic multicomponent mixtures with respect to their different adsorbability by a sorbent such as activated carbon. The analytical method is based on the determination of adsorption isotherms and their mathematical interpretation. So far, this interpretation has required the use of a large computer or a time-consuming computing program, in general. With the BASIC computing program “MAVIAS 10”, on the basis of the IAS theory a mathematical approach has been found which provides sufficient accuracy, demands low expenditure of time and makes the use of a small computer possible.     

“REMOTE SENSING”— AN EVALUATION OF ITS IMPACT ON EARTH SCIENCE—*

“Remote sensing” techniques have been used for many years as an exploration tool; broadly speaking, any method using sensors not directly connected to the earth's surface falls into this group. It is preferable, however, to use the term solely with reference to a number of new sensors which have recently become available to earth scientists for the detection of various radiations of the electromagnetic spectrum in the wave length range from 0.1 micron (UV) to some centimeters including the visible and infrared regions. Radiations artificially induced in the earth (active sensing) or spontaneous radiations (passive sensing) can be detected. Some of the bands investigated seem promising for application to geological surveys, especially using sensors on aircraft and satellites, which allow synoptic and large scale investigations. A brief account is given of the results already achieved and of future developments such as the ERTS and manned satellite (post Apollo) “earth observation” programmes. The potential role of Europe in the field is discussed. Details are given of some applications of thermal I.R. imagery to geological and vulcanological problems, with special emphasis on the research carried out in Italy.     

COMPARISON OF “AQUAFLEX” WITH CONVENTIONAL EXPLOSIVE FOR SEISMIC REFRACTION MEASUREMENTS AT SEA*

A seismic refraction line fired using conventional explosive charges was repeated using a seismic cord, “Aquaflex”. It was found that travel times and frequencies were the same for both kinds of source and that amplitudes from “Aquaflex” were comparable with those produced using conventional explosives more than ten times the weight. This advantage carries with it gains in cost and efficiency and reduces damage to fishing.     

Eine mathematische Methode zur Durchführung von Adsorptionsanalysen A Mathematical Method for Evaluation of Adsorption Analysis

Adsorption analysis is a method for describing an overall isotherm of a mixture of unknown composition such as natural organic substances or chemical industries wastewater by dividing into fictive components of different adsorbability. The adsorption behaviour of the fictive components is characterized by using the Freundlich isotherm. The competitive adsorption between these components is described by the Ideal Adsorbed Solution Theory (IAST). Usually, at given Freundlich parameters K and n, the initial concentrations of the fictive components must be adjusted in order to obtain a good fit between calculated and measured isotherm data points. The results of this adjustment depend to some extent on the minimization criteria. Previously, the modeling was done with empirical or numerical methods which required a lot of computation time and sometimes caused numerical problems which made the interpretation of the results difficult. This paper describes a mathematical method for the evaluation of isotherms by adsorption analysis.     

Scum in Nutrient Removal Plants: The Role of Carbon Sources in “Microthrix parvicella” Growth

Scum formation is a widespread problem in activated sludge nutrient removal plants. It often comes along with an excessive development of the filamentous bacterium “Microthrix parvicella” stabilizing the flotation process. As “M. parvicella” was found to depend on long‐chain fatty acids (LCFA) as sole carbon source not only in vitro but also in situ, some options of in‐situ substrate supply are discussed. Wastewater concentrations of fatty acids in the range of 2 to 15 mg L^‐1 and homologue concentrations from synthetic surfactant degradation below 10 mg L^‐1 rule out these substrates as source for excessive biomass production. They might, however, well be suitable for start‐up of a “M. parvicella” population. Build‐up of excessive biomass might rely on fatty acid supply originating in cell walls of lysed stationary phase bacteria of long residence time sludge fractions such as scum layers. Moreover, biogenic surfactants such as rhamnolipids have been proved to be an excellent carbon source for excessive biomass production in vitro.     

COMPUTER REPRESENTATION OF COMPLEX 3-D GEOLOGICAL STRUCTURES USING A NEW “SOLID MODELING” TECHNIQUE*

During our recent work with 3-D dynamic ray-tracing and velocity inversion problems, a new 3-D model generation system has been developed using a so-called “solid modeling” technique. The term “solid modeling” refers to the fact that the logical system governing the internal geometrical properties of the model describes the model as a combination of “solids” or “volumes” in 3-D space. In each of these volumes the physical parameters (such as seismic velocity, density) vary continuously. Discontinuous changes occur only across the model interfaces separating the volumes. The model is constructed by firstly forming a number of “simple volumes” from the given interfaces and then combining these simple volumes into more complex volumes which represent the physical volumes of the model. It is easy to make changes to the model, by adding volumes or subtracting volumes and perform more composite operations, all by simple use of Boolean expressions. Every time a model has been specified (or changed), the internal logic automatically carries out a check of physical consistency of the 3-D model space (no overlapping volumes, no holes). By including various types of coordinate transformations, different kinds of complex structures can be handled, such as salt domes and vertical and near vertical faulting.     

The “wave turbopause”

The “wave turbopause” is defined as the mesospheric altitude level where the temperature fluctuation field indicates a substantial increase in wave amplitudes in the vertical direction.The turbopause altitude is analyzed on the basis of four years of SABER data (2002–2005, Version 1.06). Substantial seasonal and latitudinal variations are found, with some interannual variability also present. Seasonal changes are annual at high latitudes, semi-annual at low latitudes, and a mixture of both at middle latitudes. Southern hemisphere data are similar as in the North if shifted by half a year. Latitudinal variations show a minimum in the tropics and two relative maxima at middle latitudes.The “wave turbopause” is found near to zero-wind lines or low-wind zones (zonal wind). It is compared to rocket and other measurements, and interesting similarities are obtained. The wave turbopause can also be found in the HAMMONIA GCM. A preliminary analysis shows results similar to those of the SABER measurements.     

A NEW METHOD OF CANCELLING MULTIPLE REFLECTIONS: “SOUSTON”*

Cancelling of multiple reflections by CDP stacking is generally incomplete. When the order of coverage is low, an improvement may be obtained by the use of special filters (e.g. Schneider et al: Geophysics 1965; D'Hoeraene: Geophysics 1966). But when the order of coverage is high, the efficiency of these filters is less obvious. On the other hand, the higher the order of coverage, the higher the efficiency in the solution presented. Schematically, our method includes three steps: Firstly: Searching for the multiple reflections. For this purpose Move Out corrections corresponding to the multiples are applied to each individual record, then CDP stacking is carried out. Secondly: Cleaning up of the individual records. “Decorrections” are firstly applied, then multiples are subtracted. For this, subtraction is weighed versus the energy of the multiples, that is to say versus the correlation between the original record and the pure multiple reflections. Thirdly: Normal processing with the cleaned records which have been obtained. The different steps of this method are illustrated with the help of theoretical examples. Its efficiency improvement in regard to normal CDP stacking is then demonstrated by means of true examples.     

Magmatismes basiques dits “orogeniques” et “anorogeniques” et teneurs entro2: Les associations “Isotitanees” et “anisotitanfes”

The patterns of variation of TiO₂ conent during magmatic evolution are different in the so called “orogenic” and “anorogenie” basic associations; these last terms, which are the cause of much misunderstanding, can be replaced by the terms “isotitaniferous” and “anisotitaniferous”.     

Pre‐ and post‐test mathematical modelling of a plan‐asymmetric reinforced concrete frame building

Pre‐ and post‐test analyses of the structural response of a three‐storey asymmetric reinforced concrete frame building were performed, aimed at supporting test preparation and performance as well as studying mathematical modelling. The building was designed for gravity loads only. Full‐scale pseudo‐dynamic tests were performed in the ELSA laboratory in Ispra. In the paper the results of initial parametric studies, of the blind pre‐test predictions, and of the post‐test analysis are summarized. In all studies a simple mathematical model, with one‐component member models with concentrated plasticity was employed. The pre‐test analyses were performed using the CANNY program. After the test results became available, the mathematical model was improved using an approach based on a displacement‐controlled analysis. Basically, the same mathematical model was used as in pre‐test analyses, except that the values of some of the parameters were changed. The OpenSees program was employed. Fair agreement between the test and numerical results was obtained. The results prove that relatively simple mathematical models are able to adequately simulate the detailed seismic response of reinforced concrete frame structures to a known ground motion, provided that the input parameters are properly determined. Copyright © 2006 John Wiley & Sons, Ltd.     

CARTOGRAPHIE DES “PSEUDO-RESISTIVITES APPARENTES’ PAR PROFILAGE TELLURIQUE-TELLURIQUE ASSOCIE A LA MAGNETO-TELLURIQUE *

The magneto-telluric and telluric-telluric profiling techniques are presented, and then a new method which combines these two techniques for mapping a parameter defined as the “apparent pseudo-resistivity”. The results obtained for the uranium structures in the Cluff Lake district (Saskatchewan Canada) indicate the use of these different techniques in the detection of zones of conduction for surface zones and for deeper zones, and demonstrate the advantages of these methods over the usual electrical methods in problems of structural research.     

“Amount effect” of water isotopes and quantitative analysis of post‐condensation processes

A numerical model is proposed that describes the interaction between raindrops and water vapour near the planetary boundary layer to explain the “amount effect”. This model relates the intensity to the isotopic composition of precipitation. The model resolves raindrop sizes, and explicitly includes: (1) the isotopic equilibration time of raindrops that is drop‐size dependent; (2) raindrop transit times through the atmosphere; and (3) the evolution of the isotopic composition of vapour at various rain rates. At high rain rate, the precipitation through a layer is less equilibrated with the vapour because the isotopic equilibration time is long compared to the fast transit time, and there is a preponderance of large drops, which take longer to equilibrate. The δ¹⁸O of vapour in the lower atmosphere becomes lower as a result of the interaction with these raindrops of low δ¹⁸O, and the degree of depletion of ¹⁸O is higher when precipitation rates are high. The model reproduces time‐series observations of isotopic composition of precipitation in Japan, and a vapour replenishment rate is inferred by either advection or evaporation of about 5% of the precipitation rate. The results could be the basis for a new parameterization of the isotopic equilibration for different precipitation types and rates in General Circulation Models (GCMs). When the model is applied to a GCM, this parameterization is important for places where precipitation occurs at cold temperatures (<15 °C). Copyright © 2007 John Wiley & Sons, Ltd.     

Application of the Clean Development Mechanism in the Sanitation Sector: “Proof of Concept”

Greenhouse gas emissions from the waste sector account for only 4% of the total production, with wastewater management accounting for accurately 8 to 10% of this contribution. Wastewater disposal and treatment activities, mainly contributes to non‐CO₂ gases such as methane (CH₄) and nitrous oxide (N₂O). Capturing or avoiding these emissions is thus both a concern and an opportunity. The clean development mechanism (CDM) offers an instrument to internalize global climate concerns into the design of wastewater treatment facilities. Properly designed facilities could improve effluent quality and optimize the abatement of greenhouse gas emissions, thus ensuring additional revenues to pay for capital, operation and maintenance costs and possibly justify higher levels of wastewater treatment. This document summarizes the experience of the “Rio Frio CDM project” in Colombia, as an example of what is achievable through the CDM application in wastewater treatment upgrade in developing countries. This document summarizes the scope of the project, the methodology used to establish current greenhouse emissions and future reductions, and the estimated financial results.     

Adsorption Characteristics of β‐Ionone in Water on Granular Activated Carbon

The adsorption performance of β‐ionone on four types of granular activated carbon (GAC) in water was investigated through batch experiments. The effect of initial β‐ionone concentrations and natural organic matter (NOM) adsorbed on GAC, adsorption kinetic and isothermal models were also studied. The results showed that four types of GAC all had good adsorption performance for β‐ionone, the equilibrium adsorption amount of the GAC employed was in the order of YK > GK > MZ‐A > MZ‐B. The adsorption amount increased with increasing initial concentrations. The presence of NOM could reduce adsorption of β‐ionone to a certain extent, and small molecular weight (MW) fractions (particularly <1000 Da) exhibited a remarkably competitive effect on the adsorption of β‐ionone. The experimental data showed good correlation with pseudo‐first‐order model. Furthermore, adsorption of β‐ionone on GAC fitted Freundlich, Langmuir, and Tempkin isotherms in the range of experimental concentrations, but followed Freundlich isothermal model most appropriate. The thermodynamic parameters were calculated by the results of the experiment, which showed adsorption of β‐ionone on GAC as being endothermic and spontaneous.     

A Method for Direct Assessment of the “Non Rainfall” Atmospheric Water Cycle: Input and Evaporation From the Soil

“Non rainfall” atmospheric water (dew, fog, vapour adsorption) supplies a small amount of water to the soil surface that may be important for arid soil micro-hydrology and ecology. Research into the direct effects of this water on soil is, however, lacking due to instrument and technical constraints. We report on the design, development, construction and findings of an automated microlysimeter instrument to directly measure this soil water cycle in Stellenbosch, South Africa during winter. Performance of the microlysimeter was satisfactory and results obtained were compared to literature and fell within the expected range. “Non rainfall” atmospheric water input into bare soil (river sand) was between 0.88 and 1.10?mm per night while evaporation was between 1.39 and 2.71?mm per day. The study also attempted to differentiate the composition of “non rainfall” atmospheric water and results showed that vapour adsorption contributed the bulk of this input.     

NEW FILTERING METHODS WITH “VIBROSEIS”*

In order to obtain high resolution correlograms, it is of importance amongst other things to get reflection signals with large bandwidth. An advantage of the VIBROSEIS *** *** Trade Mark and Service book of the Continental Oil Company.
method is that the frequencies radiated by the vibrators can be matched to the transmission response of the subsurface involved. By choosing the right frequency range, the highest possible amplitude and most favourable form may be given to the reflection signals. In a reflection correlogram, individual signals cannot be considered in isolation. Signals of different origin are interfering with one another. They very often have different amplitudes, so that it may be desirable in many cases to filter out events of certain apparent velocity. With the VIBROSEIS method this may be achieved quite simply. All frequencies of the noise signal are uniformly suppressed. The advantage is that noise signals, e.g. refraction signals, which cannot be sufficiently attenuated by wavelength filtering, may be completely eliminated by this velocity filtering without affecting the bandwith of the desired signal. The total dynamic range of the tape recording can be used for the registration of wanted events. To perform this kind of filtering several vibrators are necessary in the field; each of them is controlled by an individual signal. There is an unavoidable error of static and dynamic corrections which causes the results of reflection measurements to deteriorate when using multiple coverage. High frequency components especially are seriously affected by destructive interference. This difficulty can be avoided by using a VIBROSEIS signal with high frequency component amplitudes supported. For the probability of error of corrections a normal distribution is assumed. A smoothed amplitude characteristic may be achieved after stacking. The amplitude characteristic of seismic devices is commonly reduced to about 100 cps bandwidth. For further improvement of resolution of VIBROSEIS correlograms it is necessary to apply special filtering methods. This is of particular interest when any kind of gain control is used to display weak events more clearly. With increasing amplification the sidelobes of the strong signals may reach the size of the weak events. In order to eliminate this effect, the amplitude characteristic of the VIBROSEIS signal is adjusted for optimum suppression of side-lobes.     

“Site & region-specific” response spectra: a probabilistic approach

Design seismic forces depend on Peak Ground Acceleration (PGA) values and on the shape of Response Spectrum (RS) curves dictated by Building Codes or which need to be evaluated in every particular case. The PGA values and RS curves strictly depend on earthquake magnitude and distance, as well as on the regional and local geological conditions. At present, there is no doubt that it is necessary to construct so-called “Site & Region-specific” Building Code provisions reflecting the influence of different magnitude events at different distances that may occur during the life time of the construction, as well as the variety of local ground conditions. A scheme of Uniform Hazard Response Spectra and PGA estimation considering local site response is described in this paper. The assessments of these design parameters are obtained on the basis of Uniform Hazard Fourier spectra using the conception of “dominant earthquakes”. The effect of local geology is included by means of the soil/reference site spectral ratios.     

NEW FILTERING METHODS WITH “VIBROSEIS”*

In order to obtain high resolution correlograms, it is of importance amongst other things to get reflection signals with large bandwidth. An advantage of the VIBROSEIS *** *** Trade Mark and Service book of the Continental Oil Company.
method is that the frequencies radiated by the vibrators can be matched to the transmission response of the subsurface involved. By choosing the right frequency range, the highest possible amplitude and most favourable form may be given to the reflection signals. In a reflection correlogram, individual signals cannot be considered in isolation. Signals of different origin are interfering with one another. They very often have different amplitudes, so that it may be desirable in many cases to filter out events of certain apparent velocity. With the VIBROSEIS method this may be achieved quite simply. All frequencies of the noise signal are uniformly suppressed. The advantage is that noise signals, e.g. refraction signals, which cannot be sufficiently attenuated by wavelength filtering, may be completely eliminated by this velocity filtering without affecting the bandwith of the desired signal. The total dynamic range of the tape recording can be used for the registration of wanted events. To perform this kind of filtering several vibrators are necessary in the field; each of them is controlled by an individual signal. There is an unavoidable error of static and dynamic corrections which causes the results of reflection measurements to deteriorate when using multiple coverage. High frequency components especially are seriously affected by destructive interference. This difficulty can be avoided by using a VIBROSEIS signal with high frequency component amplitudes supported. For the probability of error of corrections a normal distribution is assumed. A smoothed amplitude characteristic may be achieved after stacking. The amplitude characteristic of seismic devices is commonly reduced to about 100 cps bandwidth. For further improvement of resolution of VIBROSEIS correlograms it is necessary to apply special filtering methods. This is of particular interest when any kind of gain control is used to display weak events more clearly. With increasing amplification the sidelobes of the strong signals may reach the size of the weak events. In order to eliminate this effect, the amplitude characteristic of the VIBROSEIS signal is adjusted for optimum suppression of side-lobes.     

基于模糊数学和分形理论的水淹层录井评价研究与应用

基于非线性数学方法,利用录井信息对储层水淹程度进行综合定量评价,是油藏开发方案设计和提高采收率研究等领域的重要研究内容.本文推导了水淹层录井评价的非线性理论模型,编制了水淹层评价软件.结合密闭取心资料,利用编制的软件对地化分析资料、热蒸发烃色谱资料、定量荧光分析资料、核磁共振录井资料、显微荧光薄片资料的水淹响应特征及规律进行分析研究,得到较好的结果.