内蒙古黄岗梁锡铁多金属矿床层状夕卡岩的喷流沉积成因

内蒙古自治区黄岗梁矿床是大兴安岭中南段的一个大型Sn-Fe多金属矿床,燕山期火山侵入岩广泛出露,通过对矿床地球化学特征的系统研究,并结合矿床地质特征,得出的主要研究成果为:①与含微细浸染胶状锡的磁铁矿层共生的层状夕卡岩与海底火山活动关系密切,是一种很具特色的喷流岩;②REE地球化学特征表明,该矿床层状夕卡岩与典型岩浆热液接触交代夕卡岩存在较大差异,而与现代海底热流体和喷流型矿床及其共生的热水沉积岩有较大的相似性,应属热水喷流成因;③层状夕卡岩的碳、氧同位素组成关系可与许多沉积喷流型块状硫化物矿石及其共生的喷流岩相对比,暗示了两者具有相似的形成机理。     

大兴安岭南段锡的成矿作用：以黄岗-甘珠尔庙地区为例

大兴安岭南段是我国重要的锡多金属成矿集中区,为促进区域锡多金属找矿突破,以在黄岗-甘珠尔庙地区多年的野外调查研究工作为基础,运用年代学测试、化学分析及地质模型等方法,分析了区域锡的成矿作用。认为二叠统基底地层及锡林郭勒杂岩是成矿物质的初始来源,经历的变质过程具有进一步富集的作用,大部分锡矿均遭受了多期次的火山-岩浆活动,最终决定锡多金属成矿的是燕山期酸性岩浆-热液成矿作用。同时成矿作用还受到控岩控矿构造、围岩性质、氧化-还原条件、开放-封闭环境的制约,认为在氧化性花岗岩浆侵入钙质地层条件下成矿作用以铁锡为主;还原性岩浆在侵入具开放性特征的围岩时,成矿作用以花岗岩外带围岩中的热液型脉状锡矿为主,而在侵入具封闭性特征的围岩时,成矿作用以花岗岩内带岩浆凸起部位的花岗岩型锡矿为主。因此,建议将主攻矿种由铅锌调整为锡银,部署重砂及化探方法圈定异常,针对硫化矿体部署电法,针对隐伏岩体部署磁法与重力,还可部署烃、汞、氧气测量等非常规化探方法预测隐伏岩体。     

西秦岭造山带东段喷流沉积型铅锌矿床特征及其成矿模式——以徽县洛坝矿床为例

西秦岭造山带东段西成矿田内发育一系列泥盆纪的喷流沉积型（SEDEX）铅锌矿床,甘肃徽县洛坝铅锌矿床就是其中的代表型矿床之一。它产于中泥盆统安家岔组焦沟层上部,矿体分布受洛坝背斜和南、北两翼断裂控制,与地层产状基本一致,矿石主要为纹层状、层状、浸染状、块状构造。经过详细的显微构造和SEM扫描电镜分析,鉴定出与喷流沉积有关的通道构造、淬火构造等。矿床地球化学分析显示,该矿床赋矿围岩的Ba、As、Sb、B、Ag、Hg等喷流沉积指示元素值均较高,且两者均具有LREE相对富集、明显的Eu正异常和中等Ce正异常特征,对比表明,成矿流体中的REE主要继承赋矿围岩（硅质岩）。矿床包裹体及硫同位素分析表明：成矿温度为168~350℃,以中、高温为主;早期矿化硫化物的δ³⁴S值（平均9.8‰）明显大于晚期矿化硫化物的δ³⁴S值（平均5.6‰）,说明后期改造作用中有地层硫的参与。综合研究表明,该矿床为热水喷流沉积型铅锌矿床,后期又受到海西期-印支期的叠加改造,并确定该矿床为秦岭后造山期板内伸展热水喷流的产物,最后建立了洛坝铅锌矿床热水喷流沉积成矿模式。     

A Preliminary Study on Exhalative Mineralization in Permian Basins, the Southern Segment of the Da Hinggan Mountains, China – Case Studies of the Huanggang and Dajing Deposits–

Abstract: The southern segment of the Da Hinggan Mountains is a well‐known tin–polymetallic metallogenic belt of North China with Jurassic‐Cretaceous volcanic–plutonic rocks widespread. Principally because of this, most of the deposits are regarded as epigenetic hydrothermal deposits in genetic connection with the Mesozoic magmatism. But nearly 90 % of the deposits occur in Permian strata, and show concordant stratiform mineralization with a spatial distribution constrained by sedimentary facies of the Permian strata. A close association between mineralization and Permian strata is recognizable. The Huanggang Fe‐Sn deposit was regarded as a standard skarn‐type deposit formed by magmatic hydrothermal solutions in connection with Mesozoic granites. But there are abundant fabrics indicating submarine hydrothermal exhalation both in magnetite ores and in skarns, including bedding/lamination, soft–deformation, synsedimentary brecciation, and collo‐form fabrics. The magnetite orebodies and skarn‐bodies are predominantly concordant stratiform, and extend nearly 20 km along certain stratigraphic horizon, that is, the upper section of the Lower‐Permian submarine volcanic rocks. The Mesozoic granitic rocks crosscut the magnetite and skarn zone. Instead of skarnization, they show strong greisenization associated with cassiterite‐quartz veins, distinct from the magnetite skarn‐ore with disseminated tin in the Permian rocks. The Dajing Sn‐polymetallic deposit is generally regarded as subvolcanic‐hydrothermal origin, principally because of the close spatial association between ores and some of the Mesozoic subvolcanic dikes (called rhyolitic porphyry). Detailed geological, fabric, petrographical and mineralogical study demonstrates that this very kind of subvolcanic rocks is actually a new type of exhalites (called ‘siderite‐sericite chert’ according to its mineral assemblage), formed by hydrothermal sedimentation during the evolution of the Later‐Permian lacustrine basin. There are, however, indeed some rhyolitic porphyry dikes that crosscut orebod–ies. The orebodies and their associated exhalite predate, and thus have no genetic relation, to the Mesozoic magmatic process. We thus conclude that subaqueous exhalative mineralization did occur during the basin evolution at the Permian time in the southern segment of the Da Hinggan Mountains, which is ignored and poorly understood, but might be as important as the hydrothermal mineralization connected with the Mesozoic magmatism.     

Metal deposits in the Da Hinggan Mountains,NE China: styles,characteristics, and exploration potential

The Da Hinggan Mountains mineral province (DHMP), northeastern China, is divided into three tectonic units and corresponding metallogenic belts. The tectonic units of the Da Hinggan Mountains are the Erguna fold zone on the northwest, the Hercynian fold zone on the north, and the Hercynian fold zone on the south. The corresponding metallogenic belts are the Erguna Cu-Pb-Zn-Ag-Mo-Au belt of the NW DHMP, the Cu-Pb-Zn-Mo-Fe-Au belt of the northern DHMP, and the Pb-Zn-Ag-Cu-Sn-Fe-Mo belt of the southern DHMP. Distinct ore bodies, mostly associated with Mesozoic granites and volcanics, comprise (1) hydrothermal vein deposits including Pb-Zn-Ag-(Cu) and W‐Sn-Cu, (2) exhalative (Pb-Zn-Ag, Cu) deposits, (3) porphyry (Cu, Au, Mo), (4) skarn (Fe, Zn, Cu), and (5) epithermal Au-Ag deposits. The hydrothermal veins are hosted by a range of different rock types, whereas the exhalative ores are confined to Permian strata. The porphyry deposits occur within granite porphyries. The epithermal deposits are related to Mesozoic volcanic-subvolcanic rocks and occur within superjacent igneous structures. The first type, represented by the Bairendaba deposit, shows many characteristics of hydrothermal deposits. The second type occurs in a Permian clastic-chemical sedimentary sequence. Most Fe-Zn-Cu deposits related to granites and granodiorites are skarns. Granodiorite and granite-related deposits are typical porphyry ores, formed during Hercynian and Mesozoic time. Promising metallogenic conditions and the recent discovery of many large metal deposits indicate that this mineral province has a great exploration potential.     

大兴安岭南部钠闪石流纹岩的岩石成因:年代学和地球化学证据

本文报道了在大兴安岭南部白音高老组新发现的钠闪石流纹岩的锆石U-Pb定年结果和岩石地球化学资料,以便揭示富碱钠闪石流纹岩的成因与区域构造演化.钠闪石流纹岩中锆石为自形-半自形的长柱状、短柱状,具有明显岩浆成因的震荡生长环带,结合其Th/U比值(1.2～1.9),暗示其为岩浆成因.锆石LA-ICP-MS U-Pb定年结果表明,其206Pb/238U年龄介于134 ～ 149Ma之间,其加权平均年龄为141Ma,表明钠闪石流纹岩形成于早白垩世早期.锆石εHf(t)=+9.07～+12.08,二阶段Hf模式年龄介于415 ～616Ma之间.岩石地球化学资料表明,钠闪石流纹岩以富硅、碱、铁质和贫钙、镁质为特征,在地球化学上,具有典型的A型流纹岩特征.该类岩石不仅具有高的稀土元素总量(REE=307×10-6～ 1395×10-6)、显著的Ce正异常(Ce/Ce* =6.52 ～ 18.6)和显著的Eu负异常(Eu/Eu*=0.007 ～0.009),而且表现出高场强元素(如Zr、Hf、Nb、Ta)的显著富集、大离子亲石元素(如Ba、Sr)的强烈亏损和很高的Ga/A1比值(104×Ga/Al =4.88～6.41).上述资料表明,钠闪石流纹岩的原始岩浆应是古俯冲蚀变洋壳部分熔融的产物,并形成于蒙古-鄂霍茨克缝合带闭合后的岩石圈伸展构造环境.     

Geology and Lead-Isotope Study of the Baiyinnuoer Zn-Pb-Ag Deposit, South Segment of the Da Hinggan Mountains, Northeastern China

The Baiyinnuoer deposit (32.74 Mt ore with grades of 5.44% Zn, 2.02% Pb and 31.36 g t^?1 Ag), the largest Zn‐Pb‐Ag deposit in northern China, is hosted by crystalline limestone and slate of the Early Permian Huanggangliang Formation. Detailed cross‐section mapping indicates stratigraphic and fold structural controls on the mineralization. The Zn‐Pb‐Ag mineralization is hosted predominantly by skarn, which occurs as bedding‐parallel lens that pinch out at the margins of the main economic zone. Three skarn stages are identified at the deposit: (i) garnet‐clinopyroxene; (ii) sulfides; and (iii) carbonate‐epidote. Lead isotopic compositions were determined for galena and sphalerite of the ores, whole rock samples of the Yanshanian granite and granodiorite, Permian marble and tuff, and Jurassic volcanic and subvolcanic rocks in and around the Baiyinnuoer area in order to discuss the sources of ore‐forming materials and the relationship between the ore formation and these whole rocks. Galena and sphalerite of the Baiyinnuoer ore have uniform isotopic ratios (²⁰⁶Pb/²⁰⁴Pb, 18.267–18.369; ²⁰⁷Pb/²⁰⁴Pb, 15.506–15.624; ²⁰⁸Pb/²⁰⁴Pb, 38.078–38.394) consistent with the granite and granodiorite (²⁰⁶Pb/²⁰⁴Pb, 18.252–18.346; ²⁰⁷Pb/²⁰⁴Pb, 15.504–15.560; ²⁰⁸Pb/²⁰⁴Pb, 38.141–38.320), whereas the ratios for Jurassic volcanic and subvolcanic rocks are variable and radiogenic (²⁰⁶Pb/²⁰⁴Pb, 18.468–18.614; ²⁰⁷Pb/²⁰⁴Pb, 15.521–15.557; ²⁰⁸Pb/²⁰⁴Pb, 38.304–38.375). These results indicate that the mineralization was not related to the Jurassic volcanism, but to the Yanshanian magmatism. The Permian strata may have a slight contribution to the mineralization. All features show that the Baiyinnuoer deposit is related to the Yanshanian granitic magmatism, and can be classified as a zinc‐lead‐silver skarn deposit.     

大兴安岭南段海西期花岗岩类锆石U-Pb年龄、元素和Sr-Nd-Pb同位素地球化学:岩石成因及构造意义

大兴安岭南段位于华北板块与西伯利亚板块之间的缝合-造山带(中亚造山带)的东段,该区广泛分布有海西期花岗岩类。已有的年代学研究表明这些花岗岩类的侵位时代集中于320~240Ma,但对该区海西期花岗岩类岩石成因及成岩背景研究的一些关键问题的看法仍不一致且存在争论。本文选取大兴安岭南段拜仁达坝等10个典型地区的海西期花岗岩类为研究对象,对其进行系统的岩石学、锆石U-Pb年代学、元素和Sr-Nd-Pb同位素地球化学研究,以探讨岩浆作用的时间、岩石成因以及构造意义。锆石U-Pb定年表明,这些花岗岩类的侵位时间为323~240Ma。据地球化学特征,该区花岗岩类可分为两类:Ⅰ类花岗岩的SiO_262.00%,Al_2O_315.00%,MgO含量较低(均2.40%);其具有较高的Sr含量(最高达700×10~(-6))、低的Y和Yb含量(分别为≤18.1×10~(-6)和1.70×10~(-6))和较高的Sr/Y比值(均20),LREE相对HREE强烈富集,显示弱的Eu异常,与经典的埃达克岩的特征相似;Ⅱ类花岗岩的SiO_257.00%,MgO和Al2O3含量范围较大(分别为0.25%~4.12%和10.55%~16.58%),绝大多数样品显示高钾钙碱性特征,Sr含量相对较低(12.2×10~(-6)~334×10~(-6)),Y和Yb含量相对较高(分别为14.1×10~(-6)~40.1×10~(-6)和1.27×10~(-6)~4.58×10~(-6)),Eu异常明显,相对富集Rb、Th、K等大离子亲石元素,亏损Nb、Ti、P等高场强元素,可归为弧岩浆岩。Sr-Nd-Pb同位素结果表明,弧岩浆岩可能来源于交代(富集)地幔楔,而埃达克岩则来源于下地壳的熔融。综合前人研究认为,在晚泥盆世-中二叠世古亚洲洋洋内俯冲作用形成了区域上广泛发育的弧岩浆岩(弧下加厚地壳熔融形成~320Ma埃达克岩);晚二叠世-早三叠世,华北板块与西伯利亚板块碰撞缝合;之后至早-中三叠世,大量后碰撞花岗岩侵位,同时下地壳拆沉并熔融形成了本区250~240Ma埃达克岩。中亚造山带东段(至少大兴安岭地区)海西期造山及岩浆作用可能开始于晚泥盆世,结束于中三叠世,时间持续约140Myr,其造山作用显示独特性。     

大兴安岭南段锡矿成矿特征及找矿前景

大兴安岭南段是我国重要的铅锌银锡多金属成矿集中区,但长期以来找矿重点一直以铅锌银为主,锡矿基本没有列入重点找矿对象。近几年该地区锡矿找矿取得重大进展,相继发现了维拉斯托大型锡铷铌钽矿和园林子北山、边家大院中型锡矿等,显示锡矿勘探的良好前景。锡矿与铅锌银矿存在密切的时空关系,并具一定的矿化分带特征。前人通过矿床地质特征及成岩、成矿年代学研究,也论证了锡与铅锌银应属同一成矿系统的产物。本文基于这种认识,分析研究最新锡矿勘查和研究成果,充分利用区域锡地球化学异常资料,总结了该地区锡成矿地质特征、成矿规律,认为锡成矿地质体为晚侏罗世-早白垩世中酸性侵入岩体,锡矿产出的有利部位为岩体顶部、与围岩接触带、锡地球化学异常、铅锌银矿产地的深部,各项有利信息表明,区内锡矿具有很大资源潜力。据此,圈定了9个锡矿找矿远景区,其中赤峰克什克腾(黄岗、维拉斯托、拜仁达坝为代表)、白音诺尔-浩布高和查干哈达-先锋远景区锡资源潜力大,具有较好的找矿前景。     

大兴安岭南段多金属矿成矿作用和找矿潜力

大兴安岭南段多金属成矿带位于中亚造山带东部贺根山断裂与西拉沐伦河断裂之间,处于古亚洲洋构造与古太平洋构造的叠加部位。具有双层结构特征(基底以二叠纪地层为主,盖层为侏罗纪早白垩世地层),发育了多期的构造、岩浆活动,以及众多的多金属矿床。区内矿床以多成矿元素共生、伴生为特点,按成矿作用特征划分为4个成矿系统(斑岩、矽卡岩、热液脉状、碱性花岗岩成矿系统)。斑岩成矿系统包括斑岩钼多金属、锡多金属2个亚成矿系统,矽卡岩成矿系统包括矽卡岩型铁锡、铅锌银2个亚成矿系统,热液脉状成矿系统包括银多金属、铜多金属、锡多金属3个亚成矿系统,碱性花岗岩成矿系统为稀有稀土成矿系统。大兴安岭南段多金属矿床形成于2个主要时期:晚二叠—世三叠纪、晚侏罗世—早白垩世。两期成矿作用均与花岗质岩浆活动密切相关,成矿物质来源既包括深部岩浆带来的物质,也包括区内地层,具有多来源特点。晚二叠—世三叠纪多金属矿床形成于古亚洲洋构造体系,晚侏罗世—早白垩世多金属矿床形成于古太平洋构造体系。优越的成矿地质条件及良好的地球物理与地球化学异常表明大兴安岭南段仍具有巨大的找矿潜力。     

大兴安岭南段黄岗梁地区早白垩世岩浆作用的时代、成因及其构造意义

大兴安岭南段黄岗梁地区早白垩世碎斑熔岩和钾长花岗岩代表大兴安岭南段最广泛的一次岩浆活动产物,二者LA-ICPMS锆石U-Pb年龄都为137.7±1.2Ma。该地区岩石大都具有高硅、钾,贫钙、镁,低铝的特点,体现了高度演化的高钾钙碱性-碱性系列特点;铝饱和指数显示其为准铝质-弱过铝质花岗岩。岩石稀土元素总量为116.98×10-6~350.51×10-6,具有强烈的负Eu异常,富集大离子亲石元素(如Rb、Ba、Th、U等)及高场强元素(如Nd、Zr、Hf等),亏损Ba、Sr、P、Ti、Nb等强不相容元素,显示出高分异I型花岗岩的特征。研究区早白垩世岩浆岩具有较高的全岩εNd(t)值(-0.8~+0.9)和正的锆石εHf(t)值(+1.9~+18.3),以及年轻的Nd模式年龄(993~855Ma)和Hf模式年龄(888~561Ma),表明其来源于新生的陆壳,可能有少量古老陆壳物质的参与。综合区域地质资料及大兴安岭南段的岩浆演化特征,这些早白垩世岩浆作用应形成于区域性伸展的构造背景,主体可能与蒙古-鄂霍茨克洋构造体系下的后造山伸展垮塌有关。     

大兴安岭中南段中生代中基性火山岩岩石学地球化学研究

大兴安岭中南段中生代火山岩的成因和形成时的构造背景涉及南蒙古-兴蒙造山带的后期构造演化及区内众多的铜、银多金属矿床的形成,因而对其成因的研究具有重要意义。在野外工作基础上,对大兴安岭中南段中生代中基性火山岩进行了较为系统的岩石学和元素地球化学研究。结果表明,火山岩的岩石类型为玄武粗安岩、粗面安山岩、英安岩及粗面岩,属钙碱性岩石系列;玄武粗安岩、粗面安山岩、英安岩及粗面岩的常量元素以富集SiO2,Na2O,K2O和亏损Fe2O3,FeO,MgO,CaO等为特征,微量元素以富集亲石元素和亏损铁族元素及Nb,Ta为特征;火山岩的稀土元素分配模式为轻稀土富集型;(^87Sr／^86Sr)．为0．7045～0．7077,且主要集中在0．7045～0．7055的区间内,εNd(t)多数为正值。火山岩是地幔物质部分熔融的产物,形成于张性构造环境,它们是天山一兴安造山带后造山期软流圈或地幔柱上涌所引起的岩石圈伸展作用、内蒙古-吉黑印支造山带造山期后的伸展作用和蒙古-鄂霍茨克残余洋“剪刀式”闭合所形成的拉张作用等综合效应的响应事件。     

大兴安岭南段毛登矿区阿鲁包格山岩体成岩成矿意义 ——锆石、角闪石和黑云母矿物学证据

毛登矿区位于内蒙古锡林浩特,是大兴安岭南段典型的锡钼铋多金属矿床.文章选择毛登矿区阿鲁包格山斑状二长花岗岩为研究对象,开展了高精度锆石U-Pb定年和锆石、角闪石、黑云母矿物学研究,以探讨成岩时代、岩浆结晶的物理化学条件及其对成矿的意义.研究显示,斑状二长花岗岩锆石U-Pb年龄(140±0.9)Ma,侵位于早白垩世;锆石...