Rare-Earth Abundances in Basalts and Metabasalts from the Troodos Massif,Cyprus

Abundances of some rare-earth elements (REE) in twelve pillow lavas from the Upper Pillow Lavas and Axis Sequence of the Troodos Massif are reported. The samples consist of three fresh basalts and nine zeolite facies metabasalts, metamorphosed at temperatures between 0 and 200° C. All give similar light rare-earth element (LREE) depleted patterns, indicating that hydrothermal metamorphism within this temperature range does not appreciably affect these REE patterns. The LREE depletion is consistent with a petrogenetic model in which Troodos formed at a spreading axis. Variations in profile shape indicate that mantle melting beneath the axis may have taken place during a series of discrete episodes.     

Tholeiitic and alkalic basalts of the oldest Pacific Ocean crust

Approximately 160 Ma old basaltic lavas obtained from ODP Site 801 in the Pigafetta Basin represent the first Jurassic oceanic crust recovered in the Pacific Ocean and the oldest in situ oceanic crust discovered anywhere. The basement consists of an upper alkali olivine basalt sequence and a lower tholeiitic sequence separated by a yellow Fe-rich hydrothermal sedimentary deposit. The aphyric and sparsely plagiodase-olivine±spinel phyric tholeiites exhibit depleted, open–system fractionated characteristics with trace element abundances and Pb–Nd isotopic compositions similar to normal mid-ocean ridge basalts (N-MORB). The aphyric alkali basalts, although showing some overlap in isotopic composition with MORB, exhibit strong similarities in terms of incompatible element abundances to ocean island basalts (OIB). They could represent either OIB-type off-axis volcanism or an alkalic event possibly associated with the waning stages of spreading axis volcanism in the Pigafetta Basin. All lavas have undergone low-grade anoxic smectite–carbonate alteration, although flows underlying the Fe-rich sediments have suffered hydrothermal alteration and fracturing.     

Petrogenesis of tholeiite associations in Kudi ophiolite (western Kunlun Mountains, northwestern China): implications for the evolution of back-arc basins

The Kudi ophiolite in the western Kunlun Mountains comprises harzburgites, dunites, cumulate dunites, cumulate pyroxenites and gabbros, diabase dikes, and pillow and massive lavas, and are fragments of a supra-subduction zone (SSZ) ophiolite from the Early Paleozoic. The extrusive rocks can be classified into three groups of tholeiites: back-arc basin (BAB) tholeiites, low-Ti island arc tholeiites (IAT), and LREE-enriched IAT, as shown by their distinctive geochemical characteristics. The SSZ-type mantle peridotites, the cumulate complex with arc tholeiite affinity, and BABB-type diabase dikes and basalts constitute an upper mantle and crustal section of a back-arc basin formed by coupling of MORB-type mantle upwelling with fluid efflux from slab devolatilization. The low-Ti IAT are characterized by low Ti and HFSE, and slightly U-shaped or LREE-depleted chondrite-normalized REE patterns, and represent melts derived from a depleted mantle source region (extraction of BABB magma) modified compositionally by fluids and/or melts from the subducting lithospheric slab during propagation and extension of the back-arc basin. We interpret the LREE-enriched IAT as products of closure of the back-arc basin because an interaction between the parental magma of this IAT and the mantle peridotites (formerly the upper mantle of the basin) in a newly formed mantle wedge had occurred.     

Volcanic evolution of the marginal and interarc basins

Volcanic evolution of the interarc and marginal basins is analysed using the available data on volcanics from the presently existent and ancient back-arc basins of the western Pacific and Mediterranean. It is shown that in early (pre-spreading) stages of back-arc rifting, the character of volcanism is determined by “maturity” of the adjacent island arc. It is predominantly alkaline or mildly alkaline for back-arc basins related to the island-arcs with high-potash calc-alkaline and shoshonitic volcanism. The back-arc alkaline and mildly alkaline basalts strongly differ from the continental and oceanic rift volcanoes by constantly lower Ti, Nb and Zr contents. Because of these features these basalts are akin to the basaltic members of the island-arc volcanic series. As the latter, they are generally strongly enriched in K₂O and LIL elements, whereas Na₂O reveals comparatively small variability. With initiation of spreading a sharp depression of K₂O, LIL and light REE occurs in the axial basalts of back-arc basins, that progressively approach the MORB composition. But even tholeiites from the most evolved basins that underwent a considerable spreading reveal slight but detectable geochemical peculiarities, indicating their island-arc affinities. Origin of the low-Ti alkaline basaltic magmas of the active continental margins is discussed.     

Compositions of Formosan basalts and aspects of their petrogeneses

Twenty-three basalts from northwestern Formosa were analyzed for Si, Ti, Al, Fe, Mg, Ca, Na, K, Rb, Sr, Hf, Co, Sc, Cr, Th, and 7 REE. Formosan alkalic basalts are generally similar to most alkalic basalts, and Formosan tholeiites are somewhat similar to island arc and continental tholeiites in terms of trends in K/Rb, Rb/Sr, K/Sr, and Ca/Sr ratios. Compared to most submarine tholeiites, Formosan tholeiites are enriched in Rb relative to K and Sr, and enriched in Sr relative to K and Ca. Both types of Formosan basalts show, relative to chondritic proportions, enrichments in light REE which smoothly decrease through the heavy REE. Their REE patterns are similar to those observed in Dogo-Oki alkalic basalts, Hawaiian basalts, and Deccan Plateau basalt, but differ strikingly from those of Japanese tholeiites and oceanic ridge basalts. These relationships and contrasts suggest that Formosan basalts originated in a plagioclase-free portion of the upper mantle and at greater depths that did Japanese tholeiites and oceanic ridge basalts.     

A Mid Cretaceous origin for the Galápagos hotspot: volcanological, petrological and geochemical evidence from Costa Rican oceanic crustal segments

The Quepos, Nicoya and Herradura oceanic igneous terranes in Costa Rica are conspicuous features of a Mid to Late Cretaceous regional magmatic event that encompasses similar terranes in Central America, Colombia, Ecuador and the Caribbean. The Quepos terrane (66?Ma), which consists of ol-cpx phyric, tholeiitic pillow lavas overlain by highly vesicular hyaloclastites, breccias and conglomerates, is interpreted as an uplifted seamount/ocean island complex. The Nicoya (～90?Ma) and Herradura terranes consist of fault-bounded sequences of sediments, tholeiitic volcanics (pillow lavas and massive sheet flows) and plutonic rocks. The volcanic rocks were emplaced at relatively high eruption rates in moderate to deep water, possibly forming part of an oceanic plateau. Major and trace element data from Nicoya/Herradura tholeiites indicate higher melting temperatures than inferred for normal mid-ocean-ridge basalts (MORB) and/or a different source composition. Sr–Nd–Pb isotopic ratios from all three terranes are distinct from MORB but resemble those from the Galápagos hotspot. The volcanological, petrological and geochemical data from Costa Rican volcanic terranes, combined with published age data, paleomagnetic results and plate tectonic reconstructions of this region, provide strong evidence for a Mid Cretaceous (～90Ma) age for the Galápagos hotspot, making it one of the oldest known, active hotspots on Earth. Our results also support an origin of the Caribbean Plate through melting of the head of the Galápagos starting plume.     

北祁连山奥陶纪弧后盆地火山岩浆成因

本文对北祁连山早古生代弧后盆地熔岩的岩石地球化学研究结果加以报道。样品的分布将南部弧后盆地拉伸最早阶段发育的岛弧裂谷化区和北部的弧后海底扩张区联系起来。熔岩的岩相学和地球化学特点反映了拉伸方式的改变,北部是典型的弧后盆地基性熔岩,向南则逐渐向岛弧熔岩过渡。海底扩张区以玻质(现已脱玻化)、少斑基性熔岩为特征,长英质熔岩和斑状基性熔岩产于南部岛弧裂谷化区。成熟岛弧部分(Y<20×10-6,TiO2<0.60%,Th/Yb>0.60)和弧后扩张区(Y>20×10-6,TiO2>1.0%,Th/Yb<0.60)在地球化学上相互有别。从由海底扩张形成的弧后盆地基性熔岩,向南经过逐渐与岛弧岩石相似的熔岩,直至裂谷区最南部的岛弧熔岩,它们的地球化学成分显示逐渐的变化。这种变化反映了弧后盆地形成过程中弧后盆地之下地幔对流方式和熔体产生作用的改变:从初始岛弧裂谷之下由消减板片俯冲引起的地幔下沉,转变为弧后海底扩张带之下的地幔上隆。早期岛弧裂谷阶段,裂谷轴捕获了岛弧岩浆流,从而使得喷出的熔岩在成分上与岛弧熔岩无法区分;随着弧后拉张继续,弧后盆地变宽,岛弧岩浆流逐渐离开裂谷轴,最终产生一个似洋中脊的减压熔融系统———弧后盆地岩浆系统。     

Basalts of the North Fiji Basin: the generation of back arc basin magmas by mixing of depleted and enriched mantle sources

Active spreading ridges in the North Fiji Basin range from well-developed stable ridges where largescale mantle upwelling is in progress to proto-ridges where spreading is incipient. South of 17°S, where the central ridge of the North Fiji Basin has a bathymetric profile normally expected of a fast-spreading, steadystate mid-ocean ridge, basalts are evolved N-type MORBs. North of 17°S, where the central ridge is propagating northward into old North Fiji Basin crust and spreading is in the initial stages, two types of basalt have been recovered: N-type MORBs from this northern arm of the central ridge are believed to be samples of older North Fiji Basin crust; basalts with transitional alkalic chemistry (up to 0.5% Ne in the Norm) and characterized by strong relative enrichments in Rb, Ba, K, Nb, La, Ce, Sr, P, Zr, and Ti are believed to be associated with incipient rifting. Among the latter group are compositions that are intermediate between transitional alkalic types and MORBs and these are geochemically similar to the back-arc basin (BABB) magma type defined by Sinton and Fryer (1987) from a study of Mariana back arc basin basalts. Dredges along the South Pandora Ridge, a transform zone characterized by short spreading segments, are dominated by basalts that are enriched in large-ion lithophile and high field strength minor and trace elements and compositions range from types resembling ocean island tholeiites to transitional alkalic varieties. Basalts from Rotuma are regarded as alkalic end-members of the South Pandora Ridge magmatic spectrum. In areas of the North Fiji Basin where relatively fast spreading must be accompanied by largescale asthenospheric upwelling, depleted (N-type) MORBs dominate, whereas in areas of slow mantle upwelling, or where some other tectonic effect (e.g. a transform fault) causes a transient thermal disturbance within the lithosphere or upper asthenosphere, enriched (alkalic) magmas either dominate or make a significant and noticeable contribution to the overall chemical characteristics of basalts being erupted. The MORBs have a depleted asthenospheric source, and the alkalic component is believed to derive from an enriched lithospheric or shallow asthenospheric source. The BABB magma type may simply be part of the spectrum of mixed magmas that can occur in the transitional tectonic settings represented by the early development of most back-arc basins.     

Evolution of the northwestern Iblean Mountains, Sicily: uplift, Plicocene/Pleistocene sea-level changes, paleoenvironment, and volcanism

The Late Miocene to Pleistocene evolution of the northwestern Iblean plateau (Sicily) is marked by a complex interplay of subaerial and submarine volcanism, subsidence and uplift, eustatic sea-level changes, and shallow-water carbonate and clay sedimentation. Volcanic activity occurred in distinct phases, differing drastically in volume, chemical composition, eruptive and depositional sites, and eruptive mechanisms. Six of the newly defined formations in the northwestern Iblean plateau are either entirely volcanic or contain significant amounts of volcanics. The eastern part of a shallow marine basin was filled completely by Late Pliocene tholeiitic lava flows (Militello Formation) that had advanced subaerially from the south–southeast. Lava deltas advanced southwestward on top of earlier pillow breccia debris flow deposits intertongued with soft Trubi marls and chalks. True submarine eruptions (Monte Caliella Formation) simultaneously produced densely packed pillow piles up to 250?m thick. Inferred water depths based on volcanologic and paleoecologic criteria of interbedded and overlying calcarenites agree well. Subsequent alkalic, more explosive Pleistocene volcanic eruptions (Poggio Vina Formation) changed from initially submarine to late subaerial indicating growth of edifices above sea level, sea-level rise, or land Subsidence by ca. 50?m. They and the latest Militello volcanics are interlayed with minor shallow-water calcarenites. The Poggio Vina volcanics were submerged during a second sea-level rise amounting to up to 100?m. The sea was generally shallow, i.e., <100?m deep, throughout most of the Late Pliocene and early Pleistocene. The Poggio Vina volcanism took place prior to the Emilian transgression. The sea-level rise might represent a continuation of the subsidence trend that caused the Lower Pliocene Trubi marine basin. Subaerial conditions were reached twice in the approximate time interval 1.9–1.6?Ma during phases of voluminous volcanism that outpaced subsidence. Uplift of approximately 600?m (Palagonia) to 950?m (Monte Lauro) occurred subsequent to emplacement of the Pleistocene alkalic volcanics. Bioclastic carbonates deposited concurrently with uplift drape a major fault scarp east of Palagonia with uplift rates in excess of 0.5?mm/a, provided most uplift occurred during ca. 1?Ma. Basinning continued beneath the half graben of the present Piana di Catania where volcanics several hundreds of meters thick – at least some of them alkalic in composition – occur at a depth of approximately 500–1500?m below the present surface. Quaternary uplift of the northwestern Iblean plateau may have been due to a major phase of underplating or rise of partially melted mantle. Composition of the volcanic rocks, total volume, and mass eruptive rates are well-correlated. The volumetrically very minor highly mafic Messinian nephelinites may have formed in response to Messinian lithosphere unloading following draining of the Mediterranean resulting in very low-degree partial melting. The nephelinitic to basanitic Poggio Inzerillo and Poggio Pizzuto pillow lavas may herald a major mantle decompression event, possibly the rise of a mantle diapir. The remarkably homogeneous bronzite-bearing, relatively SiO₂-rich Militello tholeiites, representing a very short-lived but voluminous eruptive phase, resemble E-MORB and reflect a major high-degree partial melting event. The Pleistocene Poggio Vina alkali basalts to nephelinites resemble the late-stage alkalic phase in intraplate magmatic systems. The Iblean cycle of a brief but intense phase of widespread tholeiites followed by alkali basaltic volcanism resembles that of Etna Volcano where widespread basal tholeiites erupted at approximately 0.5?Ma and were followed by (evolved) alkali basaltic lavas. The immediate cause-and-effect relationship between volcanism and tectonism remains speculative.     

The Stonyford Volcanic Complex: a Forearc Seamount in the Northern California Coast Ranges

Jurassic age volcanic rocks of the Stonyford volcanic complex(SFVC) comprise three distinct petrological groups based ontheir whole-rock geochemistry: (1) oceanic tholeiites; (2) transitionalalkali basalts and glasses; (3) high-Al, low-Ti tholeiites.Major and trace element, and Sr–Nd–Pb isotopic dataindicate that the oceanic tholeiites formed as low-degree partialmelts of normal mid-ocean ridge basalt (N-MORB)-source asthenospheresimilar in isotope composition to the East Pacific Rise today;the alkalic lavas were derived from an enriched source similarto that of E-MORB. The high-Al, low-Ti lavas resemble second-stagemelts of a depleted MORB-source asthenosphere that formed bymelting spinel lherzolite at low pressures. Trace element systematicsof the high-Al, low-Ti basalts show the influence of an enrichedcomponent, which overprints generally depleted trace elementcharacteristics. Tectonic discrimination diagrams show thatthe oceanic tholeiite and alkali suites are similar to present-daybasalts generated at mid-oceanic ridges. The high-Al, low-Tisuite resembles primitive arc basalts with an enriched, alkalibasalt-like overprint. Isotopic data show the influence of recycledcomponents in all three suites. The SFVC was constructed ona substrate of normal Coast Range ophiolite in an extensionalforearc setting. The close juxtaposition of the MORB-like olivinetholeiites with alkali and high-Al, low-Ti basalts suggestsderivation from a hybrid mantle source region that includedMORB-source asthenosphere, enriched oceanic asthenosphere, andthe depleted supra-subduction zone mantle wedge. We proposethat the SFVC formed in response to collision of a mid-oceanridge spreading center with the Coast Range ophiolite subductionzone. Formation of a slab window beneath the forearc duringcollision allowed the influx of ridge-derived magmas or themantle source of these magmas. Continued melting of the previouslydepleted mantle wedge above the now defunct subduction zoneproduced strongly depleted high-Al, low-Ti basalts that werepartially fertilized with enriched, alkali basalt-type meltsand slab-derived fluids. KEY WORDS: CRO; oceanic basalts; California     

Geodynamic significance of the Cretaceous pillow basalts from North Anatolian Ophiolitic Mélange Belt (Central Anatolia,Turkey): geochemical and paleontological constraints

The most widespread blocks within the Cretaceous ophiolitic mélange (North Anatolian ophiolitic mélange) in Central Anatolia (Turkey) are pillow basalts, radiolarites, other ophiolitic fragments and Jurassic-Cretaceous carbonate blocks. The pillow basalts crop out as discrete blocks in close relation to radiolarites and ophiolitic units in Cretaceous ophiolitic mélange.

The geochemical results suggest that analyzed pillow basalts are within-plate ocean island alkali basalts. The enrichment of incompatible elements (Nb, Ta, Light REE, Th, U, Cs, Rb, Ba, K) demonstrates the ocean island environment (both tholeiites and alkali basalts) and enriched MORB. Dated calcareous intrafills and biodetrital carbonates reveal an age span of Callovian—Early Aptian. The thin-shelled protoglobigerinids, belonging to the genus Globuligerina, in the calcareous intrafills between pillow basalt lobes indicates a Callovian—Barremian age interval, most probably, Valanginian to Late Barremian. The volcanic and radiolarite detritus-bearing orbitolinid—Baccinella biodetrital carbonates dated as Late Barremian-Early Aptian in age, were probably deposited around atolls and have a close relationship with the ocean island pillow basalts.

The results collectively support the presence of a seamount on the Neo-Tethyan oceanic crust during the Valanginian—Late Barremian and atolls during the Late Barremian-Early Aptian interval. The presence of an oceanic crust older than that seamount along the Northern Branch of Neo-Tethys is conformable with the geodynamic evolution of the Tethys.     

Volatiles in pillow rim glasses from Loihi and Kilauea volcanoes,Hawaii

Volatiles and major elements in submarine glasses from Loihi seamount and Kilauea volcano. Hawaii were analyzed by high temperature mass spectrometry and the electron microprobe. Loihi glasses are subdivided into three groups: tholeiitic, transitional and alkali basalts. The glasses are evolved: Mg numbers range from 48–58. The alkalic lavas are the most evolved.Total volatiles range from 0.73 to 1.40 wt.%. H₂O shows a positive linear correlation with K₂O content [H₂O = 0.83 (± .09) K₂O + 0.08 (± .06)]. Concentrations of H₂O are higher in the alkalic lavas, but Cl and F abundances are highly variable. Variations in ratios of incompatible elements (K₂O, P₂O₅, H₂O) indicate that each group was derived from a distinct source. CO₂ contents range from 0.05 to 0.19 wt.% but show no systematic correlation with rock type or Mg #. A well-defined decrease in glass CO₂ content with increasing vesicularity is shown by the alkalic lavas. CO₂ may have been outgassed from the tholeiitic and transitional magmas prior to eruption during storage in a shallow magma chamber. Reduced carbon species (CO and CH₄) were found in small amounts in most of the alkalic samples. Although the redox histories of Hawaiian lavas are poorly known, these new data indicate the presence of a reduced source for Loihi magmas.The Kilauea tholeiitic glasses are evolved (Mg # 48.3 to 55) and have higher H₂O contents (av. 0.54 wt.%) than Loihi tholeiites (av. 0.42 wt.%) at the same Mg # (~55). Cl is distinctly lower in Kilauea glasses (0.01 wt.%) compared to Loihi glasses (0.09 wt.%). The data indicate significant source differences for the two volcanoes, consistent with results of other geochemical studies.Loihi tholeiites have distinctly higher ³He/⁴He ratios than Kilauea tholeiites and are the highest measured in submarine basalts (KURZ et al., 1983). These high ratios have been used to invoke a primitive source for Loihi basalts. The high Cl content of these basalts, the highest we have ever measured in submarine basalts, may be a fingerprint of this primitive source, as previously noted for Icelandic basalts (Schillinget al. 1980).     

Geochronology and Geochemistry of the Middle Proterozoic Aoyougou Ophiolite in the North Qilian Mountains,Northwestern China

The Aoyougou ophiolite lies in an early Palaeozoic orogenic belt of the western North Qilian Mountains, near the Aoyougou valley in Gansu Province, northwestern China. It consists of serpentinite, a cumulate sequence of gabbro and diorite, pillow and massive lavas, diabase and chert. Ages of 1840±2 Ma, 1783±2 Ma and 1784±2 Ma on three zircons from diabase, indicate an early Middle Proterozoic age. The diabases and basalts show light rare-earth element enrichment and have relatively high TiO2 contents, characteristic of ocean island basalts. All of the lavas have low MgO, Cr, Ni contents and Mg numbers indicating a more evolved character. They are believed to have been derived from a more mafic parental magma by fractionation of olivine, Cr-spinel and minor plagioclase. Based on the lava geochemistry and regional geology, the Aoyougou ophiolite was probably believed to have formed at a spreading centre in a small marginal basin. Subduction of the newly formed oceanic lithosphere in the Middle Proteroz     

Two magmatic series with island arc affinities within the vourinos ophiolite

Within the Vourinos ophiolite evidence of two magmatic series has been preserved in cognate cumulates and in effusive and hypabyssal rocks, which constitute the earlier Krapa sequence and the younger Asprokambo sequence. The Asprokambo dyke basic magmas which are poor in incompatible elements and relatively Ni and Cr rich, bear some resemblance to very low Ti basalts (transitional to boninites) found in subduction related arcs or interarc basins. Krapa series magmas from sills, massive and pillow lavas are best equated with low-K tholeiites of island arc suites. Compositions of Al- and Ti- poor Cpx in lavas from both series are comparable to those in island arc basalts, the Asprokambo Cpx being richer in Ca and Cr than those from Krapa.The large volume of cumulates from the Krapa sequence displays the following crystallization order: Ol±Sp, Cpx, Pl±Opx, Mt. Periodic influx of fresh magma batches into the magma chamber occurred mainly during the formation of the lower cumulates (wehrlite, Ol-clinopyroxenite and melagabbro). The upper cumulates, gabbronorite and leucogabbronorite with minor Mt-bearing gabbronorite, crystallized in the upper levels of a magma chamber which became progressively smaller with time. In the Asprokambo sequence, Ol+Sp, Opx, Cpx, PI and Amph are the successively crystallizing phases. The ortho to heteradcumulates consist of websterite, Pl-websterite, gabbronorite, amphibole bearing leuconorite, diorite and granophyre. In cumulates, especially in the lower Krapa sequence, significant subsolidus reaction was probably induced by the persistence of high geothermal gradients linked to continuous magmatism. Petrological features indicate that the evolution of the Krapa series is more compatible with an intermediate fractional/equilibrium crystallization history in an initially open system, whereas nearly perfect fractional crystallization in closed system may have occurred in the small Asprokambo magma chambers. Chemical variations in the lavas of both series can be explained in terms of crystallization of the observed cumulates. Significantly, the Asprokambo intrusives have igneous Mg-hornblende and vanadium bearing, chromian, aluminous titaniferous magnetite, crystallization of which is responsible for the calcalkaline evolutionary trend of these rocks. Major and trace element modelling necessitates a two stage model for the petrogenesis of the Vourinos parental melts, involving high-degree remelting of previously depleted mantle sources favoured by the influx of subduction derived hydrous fluids. The primary magmas parental to the Krapa and Asprokambo series could have been derived respectively by 20 and 30% equilibrium partial fusion of variably depleted lherzolitic sources, leaving residua having a harzburgitic to dunitic composition.     

The petrology and geochemistry of the Azores Islands

Forty lavas from the Azores Islands have been analyzed for ⁸⁷Sr/⁸⁶Sr ratios, major elements, first transition series metals, and LIL elements. The samples belong to the alkali basalt magma series but range from transitional hy-normative basalts from Terceira to basanitoids from Santa Maria. Differentiated lavas include both typical trachytes and comenditic trachytes and comendites. Major and trace element concentrations define smooth trends on variation diagrams, and these trends can be related to phases crystallizing in the rocks. Systematic interisland differences are also apparent in these variation diagrams. LIL element concentrations in island basalts are roughly twice as high as those in tholeiites from the adjacent Mid-Atlantic Ridge which transects the Azores Plateau. ⁸⁷Sr/⁸⁶Sr ratios in lavas from 6 of the 9 islands range from 0.70332 to 0.70354, a range similar to that found in tholeiites from the Mid-Atlantic Ridge transect of the Azores Plateau. This suggests that lavas from these islands and this portion of the Mid-Atlantic Ridge may be derived from a similar source. However, lavas from the islands of Faial and Pico have ⁸⁷Sr/⁸⁶Sr ratios up to 0.70394 and ratios in Sao Miguel lavas range up to 0.70525, suggesting basalts from these islands are derived from a chemically distinct source. Differences in the average LIL element concentrations of the least fractionated ridge tholeiites from the Azores Plateau and alkali basalts from the islands result from differences in extent of partial melting and residual mineralogy. The alkali basalts are derived by roughly half as much melting as are the tholeiites. Trace element concentrations in Azores peralkaline lavas preclude their derivation by partial melting of peridotitic mantle or basaltic crust; rather the data suggest they are produced by fractional crystallization of a basaltic parent.     

Stratigraphy and geochemistry of pillow basalts within the ophiolitic mélange of the Izmir–Ankara–Erzincan suture zone: implications for the geotectonic character of the northern branch of Neotethys

The Izmir-Ankara-Erzincan suture zone of Turkey is a broad zone of ophiolitic mélange containing numerous fragmented blocks ranging in age from Triassic to Cretaceous. Stratigraphic sequences for various mélange units are compared, together with the geochemistry of associated basaltic pillow lavas of Cretaceous age. A review of geochemical data for the pillow lavas demonstrate: (a) a dominant group of alkalic basalts with enriched incompatible elements, variable Zr/Y and Zr/Nb ratios, and (b) a range of tholeiitic basalts with slightly depleted to mildly enriched (normalized) rare earth patterns, (La/Yb)_N 0.4-3.0, and generally low Zr/Y ratios. The alkalic basalts can be chemically matched to Pacific Ocean seamounts, although the close association of red radiolarites and cherts suggests that many basalts represent the margins of such structures, rather than the main seamount edifice. Nd-Sr isotope data are typical for ocean island basalts and represent an admixture of a dominant EM-1 source and a depleted MORB-like source. Enhanced δ¹⁸O compositions are a consequence of submarine alteration and not crustal contamination. Tholeiitic compositions have affinities with both N- and E-type MORB, although most are probably representative of tholeiitic ocean islands. Overall the basalts are mainly representative of structures built on the ocean floor, rather than the oceanic crust itself, being scraped off the subducting crust and preserved in the mélange of the accretionary wedge.     

Trace element evidence for the origin of ocean island basalts: an example from the Austral Islands (French Polynesia)

The Austral Islands, a volcanic chain in the South-Central Pacific Ocean (French Polynesia) are composed mainly of alkali basalts and basanites with subordinate amounts of olivine tholeiites and strongly undersaturated rocks (phonolite foidites and phonolite tephrites). The basaltic rocks have geochemical features typical of oceanic island suites. The distribution of incompatible trace elements indicate that the lavas were derived from a heterogeneous mantle source. The chondrite-normalized patterns of the incompatible elements in basaltic rocks of the Austral Islands are complementary to those of island arc tholeiites. As supported by isotope data, the observed trace element heterogeneities of the source are probably due to mixing of the upper mantle with subducted oceanic crust from which island arc tholeiitic magma was previously extracted.     

Geochemistry and geodynamic significance of the dike series of the Aluchin ophiolite complex,Verkhoyansk-Chukotka fold zone,Northeast Russia

The Aluchin ophiolites represent a tectonomagmatic complex, the upper crustal part of which is made up of two dike series. One series includes diabases and gabbrodiabases, which are exposed in the Late Triassic Atamanov Massif (226 Ma) and subdivided into low-potassium, low and moderate-titanium varieties. In terms of rare-earth element (REE) distribution pattern, these rocks correspond to the mid-ocean ridge basalts (N-MORB). At the same time, trace element composition of some samples indicates the enrichment in subduction component (Ba, Th), as well as variable depletion in Ta, Nb and other high-field strength elements (HFSE), which leads us to conclude that these rocks were formed from melts similar to back-arc basin basalts (BABB) at a sufficiently mature stage of back-arc spreading. The diabases of other series form separate dike bodies (dike swarms) that cut across a mantle ultrabasic body in the northern part of the Aluchin Massif. The most part of these rocks reveal prominent island-arc signatures, primarily, REE and trace-element distribution patterns. At the same time, they are characterized by slightly elevated contents of titanium, nickel, and chromium, and low content of aluminum. On the basis of these data, the diabases of the Aluchin Massif can be regarded as BABB basalts with distinct island-arc characteristics, which are usually termed as arc-like member. The joint geochemical evolution of the two diabase series is well consistent with that of the rocks from different structures of the Mariana trough, which, together with compositional data, indicate that the studied dike series mark the initial and mature stages of the opening of the Late Triassic suprasubduction basin.     

Amsterdam Island,an isolated volcano in the southern Indian ocean

Twelve lavas have been sampled on Amsterdam Island, which is an extinct shield volcano located on a transform fault crossing the south-eastern branch of the Indian Ocean rise. Chemical analyses show that the lavas have mainly tholeiitic affinities, ranging from olivine tholeiites to plagioclase basalts with accumulation of bytownite. The high alumina lavas are similar to bytownite cumulates dredged from the Indian Ocean rise, and the low alumina lavas resemble tholeiites of Hawaii. The volcano appears to be in an early stage of evolution from oceanic ridge basalt to an alkaline volcano.     

Geochemistry of an ordovician basalt-trachybasalt-subalkaline/peralkaline rhyolite association from the Lleyn Peninsula,North Wales,U.K

The Caradoc volcanic rocks of the Lleyn Peninsula represent a major episode of rhyolite-dominated eruption (total volume up to 560 km³) within the Southern British Caledonides. New geochemical data reveal the original chemical characteristics of the basic, intermediate, and acid lavas. The basalts are interpreted as having predominantly within-plate character and are associated with intermediate lavas (trachybasalts) and high-Zr, originally peralkaline, trachytes, and rhyolites. A low-Zr, originally high-K, subalkalic group of rhyolites, and a basalt with transitional island arc tholeiite-MORB characteristics are unrelated to these lavas. The volcanic rocks are interpreted to have been erupted onto a complex, rapidly evolving, active continental margin dominated by crustal tension.