Rock magnetic properties of Nihewan sediments at Xujiayao

Rock magnetic measurements of Nihewan sediments from Xujiayao section demonstrate that magnetite, hematite and maghemite are dominant remanent magnetization carriers. Monitoring the variations of magnetic susceptibility (MS) and saturating isothermal remanent magnetization (SIRM) at low temperature are the attractive ways of detecting the presence of magnetite, maghemitization and superparamagnetic grain sizes. Low-temperature MS investigations suggest that susceptibility enhancement for Xujiayao samples is mainly due to the remarkable presence of SD/MD magnetite to some degree though some magnetite grains have been partially oxidized at some depths. It is tentatively concluded that both SD/MD magnetite and hematite are of detrital origin and carry a characteristic remanent magnetization (ChRM), whereas maghemite can be attributed to be chemical origin, overprinting a reversed polarity component of Matuyama age.     

Sudden enhancement of sedimentation flux of~(210)Pb_(ex) as anindicator of lake productivity as exemplified by Lake Chenghai

Recent sediments in lakes and gulfs are a sensi-tive recorder of the information about environmentalchanges in the catchment areas during recent geologi-cal history. Precise determination of the ages of sedi-ments is the key to deciphering the environmental re-cords. The 210Pb dating technique and the markertechnique based on fallout radionuclide 137Cs havefound wide applications in sedimentation rate on atime scale of several tens to one hundred years, as wellas the varve chron…     

Rock temperatures as an indicator of weathering processes affecting rock art

To aid rock art conservation, rock temperatures have been monitored at different depths and at low (30 min) and high (1 min) acquisition rates in a painted rock shelter in the uKhahlamba‐Drakensberg Park (South Africa). Preliminary data for winter (cold and dry) show that in that season cryoclasty is unlikely to occur (rare subzero thermal events and probable reduced moisture availability) and thermal shocks are improbable (highest measured ΔT/Δt < 2 °C min^?1). High amplitude (about 30 °C) rock temperature cycles accompanied by reversals of the thermal gradient have been observed to occur almost daily and hint at the possibility of thermal stress fatigue. Copyright © 2006 John Wiley & Sons, Ltd.     

Identification of greigite in lake sediments and its magnetic significance

Detailed rock magnetic investigations and mineralogical analysis were conducted on lacustrine sediments recovered from Zoigê Basin, eastern Tibetan Plateau. Greigite, with fine and homogenous grain size, is found as a main magnetic carrier, which is suspected to be of biochemical origin. In contrast to some reports, greigite within the sediments is not oxidized even after exposure to air for a few years, which could be due to the fact that greigite is sealed by silicate.     

泥河湾盆地大长梁剖面河湖相沉积物的岩石磁学性质

以热磁分析为主,对中国北方泥河湾盆地更新世河湖相地层中灰绿色粉砂和灰黄色粉砂/细砂两种典型沉积物进行了详细的岩石磁学研究,有效确定了这两类沉积物中磁性矿物的种类、粒度特征以及加热过程中磁性矿物的变化过程和产物,并对其包含的古环境意义进行了初步探讨.灰绿色粉砂样品主要含有磁铁矿和赤铁矿两种磁性矿物,磁性相对较弱,颗粒相对较细;灰黄色粉砂/细砂主要含有磁铁矿和磁赤铁矿,磁性相对较强,颗粒相对较粗.在氩气环境中经700℃加热处理后,这两种沉积物中的绿泥石都分解,并生成超细粒（处于超顺磁和单畴颗粒区间）的磁铁矿,导致磁化率大幅升高.因此泥河湾盆地沉积物的热磁特征可以用来检测样品中绿泥石的相对含量,进而反映该地区化学风化作用强度的变化.此外,灰绿色粉砂样品中绿泥石含量比灰黄色粉砂/细砂样品的含量高,在氩气中加热后,磁化率升高幅度也较高,可能反映了化学风化相对较弱的沉积环境.     

兰州盆地渐新世沉积物岩石磁学性质探究

我国西北地区出露大量富含哺乳动物化石的"第三纪红层", 探明这些地层的岩石磁学特征对进一步开展磁性地层、环境磁学和古气候学研究具有重要意义. 本文对青藏高原东北缘兰州盆地渐新世地层进行了详细的岩石磁学研究, 分别确定了咸水河组下部砂岩和泥岩中磁性矿物含量、种类及其在加热过程中的转变; 并结合X射线衍射, 漫反射光谱和粒度分析等非磁学手段, 揭示了磁性矿物种类与沉积环境的关系. 结果表明, 剖面底部和顶部的砂岩为河道沉积, 磁性矿物含量较低, 主要为高矫顽力的赤铁矿和针铁矿; 中部泥岩为湖相沉积, 指示了一个相对稳定的静水沉积环境, 其磁性矿物含量比砂岩要高, 不仅含有高矫顽力的赤铁矿和针铁矿,也含有低矫顽力的磁铁矿. 在岩石磁学和环境磁学结果的基础上,结合野外考察和古生物证据, 我们推测兰州盆地在晚渐新世为半湿润半干旱的气候条件, 这为赤铁矿的生成提供了有利条件, 导致盆地中富含赤铁矿的红色泥岩广泛发育.     

渤海南部莱州湾Lz908孔沉积物的岩石磁学性质

亚洲大陆边缘海和陆表海在区域的物质和能量交换以及区域气候与环境演化过程中扮演了关键角色.磁性地层学和环境磁学方法是建立年代框架和环境演变序列的有效手段,但是,由于该地区边缘海和陆表海沉积物中磁性矿物来源十分复杂,磁性地层学和环境磁学研究的重要基础是要精细地解译沉积物的岩石磁学性质.为此,本文利用渤海南部莱州湾Lz908孔与钻孔附近的现代沉积物样品进行了详细的岩石磁学对比研究.结果显示,渤海南部沉积物中的磁性矿物主要是较粗颗粒(较大的准单畴至多畴)磁铁矿,还有少量磁赤铁矿,部分沉积物还含有赤铁矿和针铁矿,其中磁铁矿是特征剩磁的主要载体;莱州湾现代河流-海洋沉积物和钻孔样品之间的磁性特征无显著差异,说明莱州湾沉积物堆积之后尚未经历明显的沉积后期改造.     

An investigation into the source of magnetic minerals in some Finnish lake sediments

The source of magnetic minerals in the sediments of five Finnish lakes, which carry a palaeomagnetic record of the geomagnetic field, was found to be primary magnetite in the glacial drift of the catchments. The magnetite is concentrated in the central lake sediments. The ratio of haematite to magnetite was found to decrease in the progression drift-stream bedload-lake sediment. A consistent, temporal decrease of magnetic mineral concentration was found in all the lake sediments studied and is related to maturation of the soils and vegetation surrounding the lakes. This distinctive trend contrasts with that seen in Britain and is discussed in terms of man's influence on landscape development.     

Rock magnetic properties and palaeomagnetic results of sediments from a stone implement layer in the Bose Basin,Guangxi

Directional samples were taken to study rock magnetism and palaeomagnetic records from the Dong- sheng profile, which is 5 m thick and on the northwest edge of the Bose Basin. Mineralogy and rock magnetism of typical samples indicate that coarse granular titanomagnetite, and fine-grained hematite, superparamagnetic maghemite formed by pedogenesis are in the sediment, which has undergone many transformative processes during different stages of pedogenesis. Parallel samples were taken for thermal demagnetization (TH) (0 to 680℃) and alternating field (AF) demagnetization (0 to 80 mT) respectively. Experimental results of these two kinds of demagnetization illustrate that there are two or more magnetic components in the samples. Intensity of NRM decreases by almost 60% to 90% rapidly when the temperature ranges from 100℃ to 350℃, with a steady magnetic component. It is impossible to analyze the magnetic components at high temperature because those fluctuate widely when the temperature is higher than 400℃. Steady magnetic components from 100℃ to 350℃ indicate that the remanence was mainly carried by fine-grained hematite formed by pedogenesis, reflecting a change in the geomagnetic field while the magnetite was being oxidized into hematite by chemical weathering after deposition. The formative age of the sediments cannot be obtained by magnetic methods in this profile.     

History of kolno lake as revealed by the bed sediments

Conclusions En hiver 1965, on a fait un forage avec la sonde de Hiller à la profondeur de 0,60 m au milieu du lac Kolno qui est une réserve du cygne muet (Cygnus olor Gm.). On a analysé 92 épreuves du sédiment de fond au point de vue de sa structure, de sa teneur en eau, en chlorophylle non active, en matière organique, en fer, en azote, en calcium et en silice; de plus, on a déterminé son age absolu (C¹⁴). Il en résultait la caractéristique de la structure verticale des sédiments de fond et quelques périodes caractéristiques de la formation de ce lac. La première période d’une puissance du sédiment de 50 cm (4,70–4,20 m) se caractérise par un sédiment sablonneux contenant de petites quantités de chlorophylle non active, de matière organique et d’autres indicateurs montrant une extrêmement petite production. En commen?ant à une profondeur de 4,20 m, on observe de grands changements dans ce lac. La teneur en silice baisse de 90 jusqu’à 3%, la matière organique augmente de 2,1 à 7,6% jusqu’à plus de 50%, la teneur en calcium augmente également de quelques pour-cent jusqu’à 60%, de même que celle du fer et de la chlorophylle non active. La détermination de l’age absolu du sédiment de la couche entre 4,10 et 3,80 m, fait en 1965 au moyen de la méthode C¹⁴, a démontré que ces changements ont eu lieu il y a 6520±330 ans environ, ce qui correspond à la première moitié de la période atlantique. Ces sédiments montaient jusqu’à une profondeur de 2,20 m. Les sédiments de la période suivante d’une puissance de 80 cm (2,20–1,40 m) sont caractérisés par une plus grande teneur en chlorophylle non active, en matière organique, en azote et en fer. Ces valeurs élevées sont probablement dues à une plus grande production de la substance organique qui ne s’est pas décomposée totalement. Cette couche correspondrait à la période subboréale sèche et chaude. Les sédiments suivants (1,40–0,85 m) correspondent probablement à la période subatlantique dont le commencement se caractérisait par un climat plus froid et plus humide, comme il ressort de la figure 2. La période suivante commen?a par une rapide amélioration du climat (à une profondeur de 0,80 m), ce qui s’est manifesté par une augmentation considérable de la chlorophylle non active, de l’azote et du fer. Selon la classification généralement adoptée, ce sédiment correspondrait à la période néoboréale. Après cette période. le climat devenait de nouveau plus froid et plus humide, comme, à l’exception de petites déviations, il l’est resté jusqu’à nos jours.

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The research was subsidized by the Hydrobiological Committee and the Commission for the Protection of Nature and its Resources of the Polish Academy of Science.     

Phytoplankton as an indicator in estimating long-term changes in the water quality of large lakes

The long-term changes in the structure of phytoplankton in two large lakes of northwestern Russia—Onega and Imandra—are considered. Similar regularities in anthropogenic changes in the phytoplankton communities are found in both lakes. Despite the local nature of the lakes’ pollution, phytoplankton changes are traced within several tens of kilometers from the sources of wastewater discharge. The mass species of algae that are characteristic of the regions subjected to human impact are identified in both lakes.     

Unexpectedly old luminescence ages as an indicator of the origin of the upper Volga River valley sediments

Although the Upper Volga has been the focus of extensive research for several decades, its origin and evolution remain uncertain. According to the most popular model, the Upper Volga drainage network formed at the end of the last deglaciation (MIS 2); before that, the river basin was occupied by a large MIS2 proglacial lake. In this study we test this hypothesis by luminescence dating several fluvial terraces in the Upper Volga valley. Despite the expected late-MIS 2 age, our results show that quartz is in saturation, and the feldspar pIRIR₂₉₀ signal gives much older dates than expected (∼300–∼500 ka). We argue that, in most sections, feldspar was very likely to be well bleached prior to deposition. Thus, if the ages of sedimentary structures are overestimated, this could only result from sediment transport in darkness. It is widely accepted that the MIS 6 glaciation was the last to cover the Upper Volga basin, and so such conditions would be most easily attributed to a subglacial environment. But this explanation is confounded by the absence of till on top of most sections. The alternative explanation, that the ages accurately reflect last deposition, calls into question the well-established MIS 6 border on the Russian plain, and we conclude that further studies are required to resolve this inconsistency.     

Galactic cosmic ray fluctuation parameter as an indicator of the degree of magnetic field inhomogeneity

The parameter of cosmic ray fluctuations, which indicates the degree of IMF inhomogeneity, was introduced in order to quantitatively describe the dynamics of the galactic cosmic ray (GCR) intensity fluctuations during the geoeffective phases of the 11-year cycle. The 5-min data of the high-latitude neutron monitor at Oulu station (Finland) during cycles 20–23 was used in the calculations. The nonrandom non-Gaussian character of the GCR fluctuation parameter is caused by the nonstationary semiannual variation reflecting the transient nonstationary oscillatory process of sign reversal of the general solar magnetic field. This transient oscillatory process is responsible for the maximal geoeffectiveness and duration of the phase of polarity reversal, which manifests itself in a sharp and deep GCR intensity minimum during the final stage of the field sign reversal. The invariant of the 11-year “amplitude-duration” cycle was confirmed on a new basis: the LF drift of the “low” cycle period was detected, which was observed in an increase in the duration of cycle 23 we anticipated.     

Rock magnetic properties of a loess-paleosol couple along an N-S transect in the Chinese Loess Plateau

We have conducted detailed rock magnetic experiments on samples from loess unit 8 (L8) and paleosol unit 8 (S8) in Jingbian, Yichuan and Duanjiapo loess sections along an N-S transect in the Chinese Loess Plateau. Major rock magnetic results are as follows: (i) An increase of high field susceptibility (χ_h) in the same level of loess or paleosol from north to south is observed, suggesting an enhancement of pedogenesis. (ii) The low field susceptibility(χL) in loess unit L8 is almost the same in three sections. In contrast, the χ_L of paleosol unit S8 in Yichuan is highest, and the χ_L of Duanjiapo is lower than that in Yichuan section, suggesting that there is not correlation between the χ_L and the degree of pedogenesis in loess-paleosols. (iii) With the increasing of χ_L, both the contents of the superparamagnetic (SP) and the ferrimagnetic grains in loess-paleosol increase, however, the enhancement of magnetic susceptibility is probably dependent more on the increase of the ferrimagnetic concentration than on a change in the grain size. (iv) The content of the maghemite in loess unit 8 increases from the northern to the southern part of the Chinese Loess Plateau, and is positively correlated with the pedogenesis of the loess.     

Tritium in atmospheric precipitation over the European territory of CIS as an indicator of climatic changes

Many-year observational data on the ³H content of mean monthly precipitation at the network of stations in eight natural-climatic belts of the European part of the CIS are studied. Relationships between ³H concentrations and the climatic characteristics are analyzed. The ratio of the ³H content of precipitation in July to that in December is shown to be the best indicator of the atmospheric moisture transfer. The regular variations in the ³H content of precipitation with time (1980–1994) recorded in different natural-climatic belts testify that the western source of atmospheric moisture intensified during the above period and the climate on the European territory of CIS became warmer.Translated from Vodnye Resursy, Vol. 32, No. 2, 2005, pp. 247–253.Original Russian Text Copyright © 2005 by Vlasova, Ferronskii.     

Antioxidants in the black mussel (Mytilus galloprovincialis) as an indicator of Black Sea coastal pollution

The biologically active compounds, antioxidant activities, and free radical scavenging effects of black mussel dry matter (Mytilus galloprovincialis)--(BMDM) were investigated. The extract from BMDM with absolute methanol (BMDMAMet) showed the strongest inhibition of lipid peroxidation as a function of its concentration, and was comparable to the antioxidant activity of butylated hydroxyanisole, at the same concentration of 0.2 mg/ml. The extract with 50%methanol/water (BMDM50%Met) had the weakest antioxidant activity, whereas other extracts such as 1.2 M HCl in 50%methanol/water (BMDM50%Met/HCl) exhibited an average inhibition of lipid peroxidation. BMDMAMet extract showed marked activities in free radical scavenging determined by beta-carotene bleaching (beta-carotene), nitric oxide (NO*) and 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonate) radical cation (ABTS*+ methods. The antioxidant activities of BMDMAMet extract determined beta-carotene, NO* and ABTS*+ methods showed the highest correlation coefficients (R2) such as 0.998, 0.9976 and 0.6103, respectively, with the presence of total polyphenols. BMDM50%Met had lower antioxidant ability than BMDM50%Met/HCl in different scavenging methods, indicating that the major antioxidant components in these extracts must be derived from the polyphenols. Correlation between proteins and antioxidants was very low (0.0318 and 0.0433). The mussel extracts from polluted areas have shown by all using methods higher antioxidant activity than from the clean ones. The results presented in this report indicate that the antioxidant activities of mussel extracts could possibly be an additional index of pollution characterization.     

Environmental changes reflected by the lake sediments of the South Hongshan Lake, Northwest Tibet

The 1.07-m long lake core with 1 cm interval cutting, which was obtained by drilling in the South Hongshan Lake of Northwest Tibet, was dated by the 210Pb and 137Cs methods, and a 150-year consecutive lake sedimentary sequence (1840─1997) with 1.4 year resolution was obtained. Some environmental proxies, such as the total organic carbon (TOC), total nitrogen (TN), ratio of TOC to TN (TOC/TN), trace chemistry elements (TCE), CaCO3, grain size, richness of ostracoda etc. showed that they are of well coincidence. These results implied that the environmental background varied from the cold-wet period in the late 19th century, to the warm-wet period from the end of the 19th century to the 1920s and to the warm-dry period since the 1920s. There were sub-variations since the 1920s: the cold-dry/warm-wet fluctuation from 1922 to 1960, the intensively warm-dry period since 1960 with a short cold-wet period in the mid-1970s to the end of the 1980s. The humid period from the mid-1970s to the end of the 1970s and the dry period beginning from the early 1980s were well documented by climatic data of the nearby weather station records while the grain size was well correlated to the annual precipitation. Compared with the records from Guliya ice core in the same area, the TOC proxy in the lake core indicating warm/cold conditions well corresponded to the ( 18O records representing temperature variations in the ice core. However, the proxies with dry/wet significance in the lake core were different from the variations of snow accumulation reflected by the ice core. It can be concluded that the chosen environmental proxies have clear environmental significance and the lake sediments can reflect climatic and environmental changes at high-resolution.     

Diploptene: an indicator of terrigenous organic carbon in Washington coastal sediments

The pentacyclic triterpene 17 beta(H),21 beta(H)-hop-22(29)-ene (diploptene) occurs in sediments throughout the Columbia River drainage basin and off the southern coast of Washington state in concentrations comparable to long-chain plantwax n-alkanes. The same relationship is evident for diploptene and long-chain n-alkanes in soils from the Willamette Valley. Microorganisms indigenous to soils and soil erosion are indicated as the biological source and physical process, respectively, for diploptene in coastal sediments. Similarity between the stable carbon isotopic composition (delta 13CPDB) of diploptene isolated from soil in the Willamette Valley (-31.2 +/- 0.3%) and from sediments deposited throughout the Washington coastal environment (-31.2 +/- 0.5%) supports this argument. Values of delta for diploptene in river sediments are variable and 8-17% lighter, indicating that an additional biological source such as methane-oxidizing bacteria makes a significant contribution to the diploptene record in river sediments. Selective biodegradation resulting from a difference in the physicochemical association within eroded particles can explain the absence of the more-13C-depleted form of diploptene in Washington coastal sediments, but this mechanism remains unproven.     

Sudden enhancement of sedimentation flux of <Superscript>210</Superscript>Pb<Subscript>ex</Subscript> as an indicator of lake productivity as exemplified by Lake Chenghai

The fundamental assumption of ²¹⁰Pb sediment dating is the stable flux of ²¹⁰Pb_ex, which was derived from atmosphere and then transferred into sediments via lake water. When the sedimentation rate is relatively constant, the ²¹⁰Pb_ex activity in sediments will be exponentially reduced with sedimentation age. ²¹⁰Pb_ex in lake water is incorporated into sediments mainly via organic particulates. If the sedimentation flux of organic matter in lake water is suddenly increased, ²¹⁰Pb_ex will be significantly deposited and then transferred into sediments. On the one hand such sudden purification effect is obviously unfit for the fundamental assumption of ²¹⁰Pb dating; on the other hand, the sudden enhancement of ²¹⁰Pb_ex flux would be indicative of the conspicuous variation of primary productivity of lake water. This problem will be discussed in accordance with the variation trend of ²¹⁰Pb_ex in the vertical profile of recent sediments of Lake Chenghai, Yunnan Province. The sediment core was collected from the deep-water area of Lake Chenghai in June 1997. The vertical profile of ¹³⁷Cs activity is characterized by a tree-peak pattern. This profile gave reliable ages, and also showed the stability of sediment accumulation in the recent ten years. The vertical profile of ²¹⁰Pb_ex activity displays a specific distribution of peaks, and is similar to the vertical profile of C_org. This phenomenon seems to be related to the mechanism of constraining the transfer of ²¹⁰Pb_ex into lake sediments. The average atomic ratios of H_org/C_org and C_org/N_org in Lake Chenghai sediments are 5.51 and 7.04, respectively, indicating that the organic matter was predominantly derived from the remains of endogenic algae. In terms of the three-stage evolutionary characteristics of organic matter in sediments, i.e., “deposition-de-composition-accumulation”, the sedimentation fluxes (F(C_org)) of organic carbon (C_org) since 1970 were calculated by modeling. The sedimentation fluxes of ²¹⁰Pb_ex (F(²¹⁰Pb_ex)) in different years display good synchronous relations with the sedimentation flux of organic carbon (F(C_org)), especially in the years of 1972–1974 and 1986–1989. The variation of F(C_org) led to the variation of F(²¹⁰Pb_ex); the variation of F(²¹⁰Pb_ex) reflects, to some extent, the historical variation of lake productivity.     

Relative importance of dust inputs and aquatic biological production as sources of lake sediments in an oligotrophic lake in a semi‐arid area

The dustfall (DF) and mass sedimentation rate (MSR) in Lake Alchichica, Central Mexico, were studied from June 2006 to June 2008. DF ranged between 0·11–0·93 g m^?2 d^?1 in the warm and rainy season and 0·54–1·21 g m^?2 d^?1 in the cold and dry season. MSR varied from 0·52–2·40 g m^?2 d^?1 in the stratification season to 1·14–5·07 g m^?2 d^?1 in the circulation season. The timing of the highest fluxes of DF and MSR is most likely a product of several factors coinciding during the cold and dry season: (a) availability of dust sources and the presence of strong winds (>7·5 m s^?1) in the DF case, and (b) the circulation period of the lake and the availability of nutrients in the MSR case. As expected, the DF in Alchichica was high and similar to that found in other arid and semi‐arid areas. However, the MSR was higher than that reported for other oligotrophic lakes. Particles captured in the aerial traps consisted mainly of detrital minerals; in contrast, particles found in the water traps were mostly biogenic and, to a lesser extent, detrital minerals. The MSR was one to seven times higher than the DF. In spite of the oligotrophic status of Lake Alchichica, the large size of the settled phytoplankton (autochthonous, waterborne) is what leads to the high MSR, which surpasses the DF (allochthonous, airborne) derived from whirlwinds originating in easily eroded terrains that are characteristic of arid/semi‐arid areas. Our results indicate that caution must be taken in considering that the DF amount measured through DF collectors located at the lake shore does actually represent the DF entering into the lake. Copyright © 2010 John Wiley & Sons, Ltd.