东南亚巽他群岛埃达克岩的分布及斑岩型铜(金)矿成矿预测的地质准则

东南亚巽他群岛是新生代埃达克岩、类埃达克岩极其发育的地区。这些中酸性岩浆岩广泛见于几内亚岛上的中央山脉、巴布亚新几内亚的欧文-斯坦利推覆带、俾斯麦岛弧、布干维尔岛-所罗门岛弧、印度尼西亚苏拉威西、加里曼丹中部、班达岛弧,零星见于苏门答腊、爪哇等地。根据微量元素特征及REE曲线类型的特点,本区埃达克岩可以明显地划分为2种类型：第一种埃达克岩类型属于拉斑/钙-碱性系列,具有大洋岛弧的REE曲线特征（相当于O型埃达克岩）;第二种埃达克岩属于高钾钙-碱性系列,归于大陆埃达克岩（相当于C型埃达克岩）,形成于弧-陆碰撞带或碰撞后造山带。埃达克岩与浅成热液金属矿床和斑岩矿床的成矿作用有密切的关系,是世界级浅成热液和斑岩铜-金矿的容矿岩石。     

东南亚巽他群岛埃达克岩的分布及斑岩型铜(金)矿成矿预测的地质准则

东南亚巽他群岛是新生代埃达克岩、类埃达克岩极其发育的地区。这些中酸性岩浆岩广泛见于几内亚岛上的中央山脉、巴布亚新几内亚的欧文-斯坦利推覆带、俾斯麦岛弧、布干维尔岛-所罗门岛弧、印度尼西亚苏拉威西、加里曼丹中部、班达岛弧,零星见于苏门答腊、爪哇等地。根据微量元素特征及REE曲线类型的特点,本区埃达克岩可以明显地划分为2种类型：第一种埃达克岩类型属于拉斑/钙-碱性系列,具有大洋岛弧的REE曲线特征（相当于O型埃达克岩）;第二种埃达克岩属于高钾钙-碱性系列,归于大陆埃达克岩（相当于C型埃达克岩）,形成于弧-陆碰撞带或碰撞后造山带。埃达克岩与浅成热液金属矿床和斑岩矿床的成矿作用有密切的关系,是世界级浅成热液和斑岩铜-金矿的容矿岩石。     

东南亚新生代两类埃达克岩的分布、成因和含矿性

东南亚的巽他群岛-巴布亚新几内亚是新生代埃达克岩和类埃达克岩发育的地区。这些中酸性岩浆岩广泛见于印度尼西亚几内亚岛、苏拉威西和巴布亚新几内亚, 零星见于苏门答腊、班达岛弧、西爪哇和中加里曼丹等地。本区埃达克岩和类埃达克岩岩石类型分别属于岛弧拉斑钙碱性系列和高钾钙碱性系列, 以重稀土元素Y, Yb含量低(分别为Y ≤19 ×10-6和Yb ≤1.8 ×10-6)和高Sr值(＞355 × 10-6)为特征。微量元素蛛网图上有明显的Ba、K、Sr正异常峰和负的Th、Nb (Ta)异常谷。大离子亲石元素(LILE)和高场强元素(HFSE)相对富集。本区埃达克岩和类埃达克岩的构造位置为新生代缝合线附近的大洋岛弧和陆缘造山带, 可划分为两种成因类型:第一种为岛弧拉斑/钙碱性系列, 其REE配分模式属于大洋岛弧型, 见于现代大洋岛弧, 称为岛弧型(O-型)埃达克岩; 另一种为高钾钙碱性系列, 其REE配分模式属于大陆型, 产于大陆板块边缘造山带, 与弧-陆碰撞和后碰撞构造环境有成因联系, 见于大陆边缘, 称为大陆型(C-型)埃达克岩。 研究结果表明:大陆型(C-型)埃达克岩和类埃达克岩分布区域与世界级斑岩铜-金矿分布相一致, 而大洋岛弧型(O-型)主要与浅成热泉金矿和喷气型有成因联系。      

两类埃达克岩的含矿性和成因:东南亚地区与东太平洋带对比

新生代埃达克岩是一种新型的火成岩(Sr/Y≥20),多产出于大洋岛弧、大陆边缘造山带(东南亚地区)和陆缘火山弧环境(东太平洋带),依据REE配分模式可将其划分为2种成因类型:大洋型(O型)和大陆型(C型)。埃达克岩分别广泛分布于东南亚地区的菲律宾群岛、苏拉威西、中加里曼丹、印度尼西亚几内亚岛、巴布亚新几内亚至所罗门群岛一带,及东太平洋带的北美洲、墨西哥、中美洲、南美洲的北部至南部。研究表明:不同成因类型的埃达克岩具有不同的含矿性,反映各自岩浆源区不同。C型埃达克岩(La/Yb12)是俯冲海洋板块部分熔融叠加增厚的地壳底部部分熔融MASH(熔融-混染-储存-均一化)和AFC(混染-分异-结晶)作用的产物,多半与世界级斑岩铜金矿床共生;O型埃达克岩(La/Yb≤12)则与平缓俯冲的海洋板片部分熔融作用有关,在东南亚地区主要与浅成热泉金矿有成因联系。     

巴布亚新几内亚新生代两类埃达克岩的构造环境意义

本文根据新几内亚安山岩的化学分析数据与典型埃达克岩进行对比,讨论了巴布亚新几内亚埃达克岩的地球化学特征及其大地构造环境意义。对比结果表明:巴布亚新几内亚埃达克岩微量元素特征为高锶(一般>于400×10-6),Sr/Y比值平均>41.7,重稀土元素Y和Yb含量很低(分别为≤20×10-6和1.9×10-6)。在微量元素蛛网图上有Sr,Ba正异常峰和明显的Nb,Th负异常。稀土元素表现为LREE富集模式,(La/Yb)N比值平均为2.19~18.69。巴布亚新几内亚埃达克岩的M g#值>0.45,87Sr/86Sr值一般<0.7045与典型埃达克岩一相致。巴布亚新几内亚埃达克岩分别位于弧-陆碰撞带大地构造环境中的大洋岛弧和大陆边缘造山带中。埃达克岩的分布区域与世界级斑岩铜-金矿和浅成热泉金矿的成矿带的分布相一致。     

巴布亚新几内亚新生代埃达克岩的地球化学证据

本文根据对新几内亚火山岩的10个化学分析数据与典型埃达克岩进行对比,讨论了巴布亚新几内亚埃达克岩的地球化学特征.结果表明:巴布亚新几内亚埃达克岩微量元素特征为高锶(一般大于400×10-6),Sr/Y比值平均>41.7;在微量元素蛛网图上有Sr、Ba正异常峰和明显的Nb、Th负异常.Y和重稀土元素Yb含量很低(分别为≤20×10-6和1.9×10-6).稀土元素表现为LREE富集模式,La/Yb比值平均为9.3~27.8.巴布亚新几内亚埃达克岩的Mg#值>0.45;87Sr/86Sr一般小于0.7045.巴布亚新几内亚埃达克岩分别位于弧-陆碰撞带大地构造环境中的大洋岛弧和大陆边缘造山带中.埃达克岩的分布区域与世界级斑岩铜-金矿和浅成热泉金矿成矿带的分布相一致.     

新生代埃达克岩两种成因类型的含矿性和源区:西南太平洋带与东太平洋带的对比

埃达克岩是一种新型的火成岩(Sr/Y值≥20),形成于环太平洋带的大洋岛弧、大陆边缘造山带和陆缘火山弧环境,依据REE配分模式可将其划分为两种成因类型:大洋型(O-型)埃达克岩和大陆型(C-型)埃达克岩。西南太平洋带是世界上新生代埃达克岩和类埃达克岩广泛分布的地区之一。这些中酸性岩浆岩广泛分布于东南亚地区的菲律宾群岛、苏拉威西和加里曼丹中部、印度尼西亚几内亚岛和巴布亚新几内亚至所罗门群岛一带,零星见于班达岛弧、苏门答腊和西爪哇等地。研究结果表明:不同成因类型的埃达克岩具有不同的含矿性,反映各自来源于不同的岩浆岩源区。无论在西南太平洋带还是东太平洋带(智利),C-型埃达克岩(La/Yb值≥12)是俯冲板块的部分熔融作用叠加岩浆上侵过程中MASH(熔融-混染-储存-均一化)和AFC(混染-分异-结晶)作用的产物,与世界级斑岩铜-金矿床共生;而O-型埃达克岩(La/Yb比值≤12)则与俯冲的海洋平缓板块部分熔融作用有关,在西南太平洋带主要与浅成热泉金矿带和喷气型矿床有成因联系。     

俯冲、碰撞、深断裂和埃达克岩与斑岩铜矿

无论是碰撞前的B型俯冲,还是碰撞后的A型俯冲,形成斑岩铜矿都必须要有洋壳或上地幔为主的物质参与.因此斑岩铜矿的初始锶值都小于0.708,超过0.708,则意味地壳物质的增多,将形成斑岩钼矿和斑岩钨锡矿.斑岩铜矿带常常与切穿地壳的深断裂带平行共生,并产于其上盘,在该地带往往发育壳幔混合以幔为主的深源花岗质浅成-超浅成小斑岩体.含铜斑岩和埃达克岩可能均为俯冲和交代产物,因而具有相似的特征,但到俯冲末期它们分道扬镳了.文章通过对冈底斯斑岩铜(钼、金和多金属)矿带的分析,来讨论俯冲、碰撞和深断裂带与斑岩铜矿的关系.同时也通过我国中央碰撞造山带仅发育斑岩钼矿,而缺乏斑岩铜矿,从而证明上地幔物质的加入对斑岩铜(金)矿的重要意义.     

黑龙江铁力鹿鸣斑岩型钼矿床埃达克岩的发现及其地质意义

鹿鸣钼矿是伊春-延寿成矿带内近年发现的大型斑岩钼矿,矿区主要出露含矿的二长花岗岩、花岗斑岩,不含矿的花岗闪长岩及似斑状花岗闪长岩四种岩性。二长花岗岩与花岗斑岩具有相似的低Sr高Y等地球化学特征,形成于194.8±0.7Ma~184Ma前后的早侏罗世,是斑岩型矿床的赋矿围岩。花岗闪长岩及似斑状花岗闪长岩含有暗色岩包体,主要为高钾钙碱性系列岩石,但以高Sr、低Y及富Na为特征,部分地球化学指标与中国东部埃达克岩极为相似,形成于176.2±2.1Ma并与辉钼矿Re-Os法获得的成矿年龄一致,被认定为斑岩型矿床的成矿母岩。高Sr和低Sr两类花岗岩形成于不同的构造背景,与中生代时期中国东部及其邻区几次重大地质事件密切相关。鹿鸣斑岩型钼矿床与中侏罗世太平洋板块俯冲在高氧逸度条件下熔融形成的埃达克质岩浆高侵位有关。鹿鸣矿区埃达克岩的发现表明中侏罗世太平洋板块已经发生了萎缩与消减,与之相关的岩浆作用及成矿应该具有广泛的区域性,扎实的岩石学工作可为区域更多斑岩型矿床的发现提供线索。     

大别山（北麓）斑岩型钼矿床成矿系列及成矿规律

大别山造山带.是秦岭褶皱带南东的组成部分,它与龟(山)-梅(山)断裂带、北东向断裂共同控制着豫南岩浆岩的分布.燕山期的中酸性岩基是成矿小岩体的母岩,而成矿小岩体又是斑岩型钼矿床的成矿母岩.燕山期中国东部在陆内俯冲作用下,岩石圈在挤压、伸展后表现减薄,引起软流圈抬升和地幔上涌,形成深源浅成型花岗岩.矿床类型与岩浆成分有关,表现出明显的成矿专属性.相同的构造-岩浆成矿作用,因空间位王的不同,形成了大别山的斑岩型钼矿床成矿系列.根据成矿系列.研究其斑岩型钼矿成矿规律,对大别山的钼、铜、铅、锌等多金属找矿有重大的指导意义.     

埃达克岩与Cu-Au成矿作用：有待深入研究的岩浆成矿关系

研究表明,环太平洋地区新生代斑岩铜矿和浅成热液金矿与同期的埃达克质岩浆活动存在密切的时空与成因联系。埃达克岩是许多世界级的斑岩铜矿的容矿岩,也是许多浅成热液矿化系统的成矿母岩浆。根据目前的研究,二者成因联系可能在于埃达克质岩浆的富流体、高氧逸度和基性源岩等固有属性,有利于Cu、Au等深源金属元素的萃取与富集成矿一因此,这可能是一种潜在的岩浆成矿专属性关系,但对产生这种关系的原因与机制仍然不十分清楚。这有待于今后深入开展成矿与无矿的埃达克岩、成矿的埃达克岩与非埃达克岩、无矿的埃达克岩与非埃达克岩等方面的对比研究,以揭示这种成矿专属性的本质。     

东南亚地区重要矿床地质特征及找矿潜力

东南亚地区矿产资源十分丰富,特别是铜、镍、铬、钾盐、铝土矿等矿产资源与中国有较强的互补性,受到中国地质学家和矿业界的广泛关注。东南亚地区总体矿产勘查、开发程度低,随着东南亚地区经济的快速发展和找矿技术方法的提高,该地区一大批新矿床的发现和一系列新矿山的陆续建成投产必将为全球经济发展和社会进步注入新的活力。通过对东南亚地区产出的大型-超大型或代表性重要矿床地质特征和分布规律进行总结,对其产出环境和找矿潜力进行讨论,旨在为中国地质学家、矿业企业了解该地区重要矿床的地质特征、时空分布规律、找矿潜力和找矿模型提供有益信息,为中国地勘单位和矿业企业"走出去",在东南亚地区开展综合性找矿评价提供参考依据,同时也为在中国西南三江成矿带开展勘查找矿工作提供对比依据。     

斑岩型和浅成低温热液型矿床成矿流体与找矿预测研究:以华南若干典型矿床为例

斑岩型和浅成低温热液型矿床是全球铜、钼、金、银的主要来源之一,具有重要经济价值。这两类矿床之间通常存在紧密的时空关系,对其成矿流体性质和演化的解剖不仅有利于探究金属沉淀机制,也有助于揭示两者之间的内在成因联系。本文在综述国内外重要研究前沿基础上,以中国华南富家坞斑岩型铜钼(金)矿、桐村斑岩钼矿,以及邱村和安村浅成低温热液金矿为例,系统总结了斑岩型和浅成低温热液型矿床流体特征、演化规律和金属沉淀机制、探讨了从斑岩型到浅成低温热液型流体演化的“气相迁移”模型,并以福建紫金山铜金矿床为例,介绍了应用流体填图进行找矿预测的实例。     

Geochronology and geochemistry of porphyritic intrusions in the Duolong porphyry and epithermal Cu-Au district,central Tibet: Implications for the genesis and exploration of porphyry copper deposits

The Duolong district in central Tibet hosts a number of porphyry as well as high sulfidation epithermal copper–gold deposits and prospects, associated with voluminous calc-alkaline volcanism and plutonism. In this study, we present new geochronological, geochemical, isotopic and mineralogical data for both economically mineralized and barren porphyritic intrusions from the Duobuza and Naruo porphyry Cu–Au deposits. Zircon U–Pb analyses suggest the emplacement of economically mineralized granodiorite porphyry and barren granodiorite porphyry at Naruo deposit took place at 119.8 ± 1.4 Ma and 117.2 ± 0.5 Ma, respectively. Four molybdenite samples from the Naruo deposit yield an isochron Re–Os age of 119.5 ± 3.2 Ma, indicating mineralization occurred synchronously with the emplacement of the early granodiorite porphyry. At Duobuza deposit, the barren quartz diorite porphyry intruded at 119.5 ± 0.7 Ma, and two economically mineralized intrusions intruded at 118.5 ± 1.2 Ma (granodiorite porphyry) and 117.5 ± 1.2 Ma (quartz diorite porphyry), respectively. Petrographic investigations and geochemical data indicate that all of the porphyritic intrusions were oxidized, water rich, and subduction-related calc-alkaline magmas. Zircons from the porphyritic intrusions have a wide range in the ε_Hf (0–11.1) indicating that they were sourced from mixing of mantle-derived mafic, and crust-derived felsic melts. Moreover, the variation of trace element content of plagioclase phenocrysts indicates that the magma chambers were recharged by mafic magmas.Comparison of the composition of amphibole phenocrysts indicates the porphyry copper–gold mineralization at Duolong was generated in magma chambers at low crystallization temperatures and pressures (754° to 791 °C, 59 M to 73 MPa, n = 8), and under highly oxidizing conditions (ΔNNO 2.2 to 2.7, n = 8). In contrast, barren intrusions were sourced from the magma chambers with higher crystallization temperatures and pressures (816° to 892 °C, 111 to 232 MPa, n = 22) that were less oxidizing (ΔNNO 0.6 to 1.6, n = 22). The requirement for a thermal contrast is supported by the declining of Ti content in magnetite crystals in barren intrusions (12,550 to 34,200 ppm) versus those from economically mineralized intrusions (600 to 3400 ppm). Moreover, the V content in magnetite crystals from economically mineralized intrusions (990 to 2510 ppm) is lower than those recorded from barren intrusions (2610 to 3510 ppm), which might reflect the variation in oxidation state of the magma. The calculated water solubility of the magma forming the economically mineralized intrusions (3.2–3.7 wt%) is lower than that of magma forming the barren intrusions (4.6–6.4 wt%). Based on the chemical–physical characteristics of economically mineralized magma, our study suggests that the development of porphyry Cu–Au mineralization at Duolong was initiated by shallow-level emplacement of a magma that crystallized at lower temperatures and pressures. Experimental studies show that copper and water solubilities in silicate melts decrease with falling temperatures and pressures, indicating metals and ore-forming fluids are more likely to be released from a magma reservoir emplaced at shallow crustal levels. We propose the magnetite might be a convenient exploration tool in the search for porphyry copper mineralization because the variations in Ti and V content of mineral concentrates and rock samples are indicative of barren versus mineralized intrusions.     

Adakite-like signature of porphyry granitoid stocks in the Meiduk and Parkam porphyry copper deposits,NE of Shahr-e-Babak,Kerman, Iran: Constrains on geochemistry

The Middle Miocene porphyry granitoid stocks of Meiduk and Parkam porphyry copper deposits are intruded in the north-western part of the Dehaj-Sarduiyeh volcano-sedimentary belt in the south-eastern extension of the Urumieh-Dukhtar Magmatic Arc (UDMA) in Iran. The porphyritic to microgranular granitoids are mainly consist of quartz diorite, granodiorite and diorite. The whole rock geochemical analyses of these rocks reveals sub-alkaline, calc-alkaline, meta-peraluminous and I-type characteristics. Their geochemical characteristics such as Al₂O₃ content of 13.51–17.05 wt%, high Sr concentration (mostly >400 ppm), low Yb (an average of 0.74 ppm) and Y (an average of 9.02 ppm) contents, strongly differentiated REE patterns (La/Yb ≥ 20), lack of Eu anomaly (Eu/Eu¹ ≥ 1) are indicative of adakitic signature. Their enrichment in low field strength elements (LFSE) and conspicuous negative anomalies for Nb, Ta and Ti are typical of subduction related magmas. Detailed petrological studies and geochemical data indicated that Meiduk and Parkam porphyry granitoids were derived from amphibole fractionation of hydrous melts at a depth of >40 km in a post-collisional tectonic setting.     

论新疆伊犁浅成低温热液型金矿与斑岩型铜（钼金）矿的相随相伴规律

中亚成矿域中的斑岩型铜（钼金）矿,有别于滨太平洋区的斑岩铜矿,它们大部分是形成于大洋消亡之后,与A型俯冲或后碰撞阶段的构造岩浆作用有关,并非都形成于岛弧发展阶段,且常与浅成低温热液型金矿（产于陆相-亚陆相火山岩内）时间相随、空间相伴,两者属于一个统一的岩浆系统;浅部是浅成低温热液型金矿,深部是高温斑岩型铜（钼金）矿,其成矿特点表现出两者元素组合连续、过渡与转化,两者类型相随相伴。     

The characteristics,formation and exploration progress of the potash deposits on the Khorat Plateau,Thailand and Laos,Southeast Asia

The giant potash deposit on the Khorat Plateau is one of the most promising targets for exploitation of potassium salts. So far, many researches and geologic survey have been conducted on the giant potash deposits. Hence, it is necessary to make an overall review on the potash deposits. The potash deposit on the Khorat Plateau was formed during the Middle to Late Cretaceous, during which seawater was enriched in Ca²⁺ and depleted in SO₄^2- compared with those of modem seawater. In addition to seawater, continental water and hydrothermal fluids could have affected the evaporite basins. The seawater was probably derived from Tethys ocean, and the brine should have evaporated to some extent before entering into the basin systems based on the evidence of absence of carbonates and unproportionate sulphate compared with chloride salts. The paleo-climate during Middle to Late Cretaceous was characterized as high temperature and extremely arid environment, which is favourable for deposition of potassium-magnesium saline minerals. The major saline minerals are of anhydrite, halite, camallite, sylvite and, tachyhydrite, with trace amounts of borates. The resources of the potash deposit on the Khorat Plateau could be approximately as much as 400×10⁹ t of camallite and 7×10⁹ t of sylvite. The evaporite sequences have been deformed and altered by postdepositinal processes, including tectonic movements and chemical alteration. Salt domes were formed in the postdepositional processes. Based on the analyses of geophysical surveys and drilling projects, high-quality sylvinite ores are commonly found at the flanks of those salt domes due to incongruent dissolution of camallite. The future potential prospecting areas for the high-quality sylvinite ores would be on the edges of the Khorat Plateau.