Planetary Wave Periods in <Emphasis Type="Italic">foF</Emphasis>2 Time Variations Based on Winter Data from Kaliningrad Station in 2008−2010

The study presents the results of the analysis of the F2-layer critical frequency variations obtained for the winter periods of 2008–2010, during which sudden stratospheric warmings were observed. The data were obtained at Kaliningrad ionospheric station (54.6° N, 20° E) with the Parus digital ionosonde in standard sounding mode. The mean daily foF2 values were used in the analysis. The results of spectral analysis based on continuous wavelet transform showed that, during all of the warmings that occurred in 2008–2010, the foF2 time variations demonstrated the presence of wave processes with periods of approximately 5?6 days, as well as more extended processes with periods of ~10?13 and 23?30 days. These periods coincide with the characteristic periods of planetary waves observed in the mesosphere during sudden stratospheric warmings, while the 13- and 30-day periods can be conditioned by the influence of the Sun.     

Quasi-wave variations in <Emphasis Type="Italic">foEs</Emphasis> during stratospheric warmings of 2008–2010 according to data from Kaliningrad ionospheric station

The results of analysis of variations in the sporadic layer critical frequency (foEs) for winter periods of 2008–2010 in which sudden stratospheric warmings were observed are presented in the paper. The data were obtained at Kaliningrad ionospheric station (54.6° N, 20° E) by a Parus digital ionosonde under the usual sounding regime with an interval of 15 min. Daily mean values of foEs were used for the analysis. Solar and geomagnetic activity remained low during the periods under study, making it possible to relate the quasiwave time variations in foEs to the parameters of stratospheric warmings. The results of spectral analysis performed on the basis of continuous wavelet transform showed that, during all warmings occurring in 2008–2010, time variations in foEs show the presence of wave processes with a period of an order of 5 days and longer ones with a period of ~10—11 days. These periods coincide with characteristic periods of planetary waves observed in the atmosphere during sudden stratospheric warnings.     

Transport and the seasonal variation of ozone

The transport mechanisms responsible for the seasonal behavior of total ozone are deduced from the comparison of model results to stratospheric data. The seasonal transport is dominated by a combination of the diabatic circulation and transient planetary wave activity acting on a diffusively and photochemically determined background state. The seasonal variation is not correctly modeled as a diffusive process. The buildup of total ozone at high latitudes during winter is dependent upon transient planetary wave activity of sufficient strength to cause the breakdown of the polar vortex. While midwinter warmings are responsible for enhanced ozone transport to high latitudes, the final warming marking the transition from zonal mean westerlies to zonal mean easterlies is the most important event leading to the spring maximum. The final warming is not followed by reacceleration of the mean flow; so that the ozone transport associated with this event is more pronounced than that associated with midwinter warmings.     

Validation of Aura Microwave Limb Sounder water vapor and ozone profiles over the Tibetan Plateau and its adjacent region during boreal summer

We present validation studies of MLS V2.2 and V3.3 water vapor(WV) and ozone profiles over the Tibetan Plateau(Naqu and Lhasa) and its adjacent region(Tengchong) respectively by using the balloon-borne Cryogenic Frost point Hygrometer and Electrochemical Concentration Cell ozonesonde. Coincident in situ measurements were selected to compare the MLS V2.2 and V3.3 WV and ozone profiles for understanding the applicability of the two version MLS products over the region. MLS V2.2 and V3.3 WV profiles respectively show their differences within ?2.2±15.7%(n=74) and 0.3±14.9%(n=75) in the stratosphere at and above 82.5 h Pa. Accordingly, at 100 h Pa, the altitude approaching the tropopuase height, differences are within 9.8± 46.0%(n=18) and 23.0±45.8%(n=17), and they are within 21.5±90.6%(n=104) and 6.0±83.4%(n=99) in upper troposphere. The differences of MLS ozone are within ?11.7±16.3%(n=135, V2.2) and 15.6±24.2%(n=305, V3.3) at and above 82.5 h Pa. At 100 h Pa, they are within ?3.5±54.4%(n=27) and ?8.7±41.6%(n=38), and within 18.0±79.1%(n=47) and 34.2±76.6%(n=160) in the upper troposphere. The relative difference of MLS WV and ozone profile has significant oscillation and scatter at upper troposphere and lower stratosphere partly due to the stronger gradients of WV and ozone concentrations here as well the linear interpolation of sonde data for the intercomparison. At and below 70 h Pa, the relative differences of MLS ozone are significantly larger over Lhasa during the Tibetan Plateau "ozone valley" season, which is also the Asian Summer Monsoon period. The MLS ozone differences over the three sites are similar in their vertical distributions during that period. A simple linear correlation analysis between MLS and sonde profiles indicates that the sensitivity of MLS profile products is related to concentrations at each pressure level. The MLS V3.3 product sensitivity is slightly improved for WV at and above 82.5 h Pa, whereas it is not obvious for ozone. The possible factors contributing to the differences of the MLS profile products of WV and ozone are discussed.     

The generalized kinetic equation as a model for the nonlinear transfer in third-generation wave models

An alternative model for the nonlinear interaction term S_nl in spectral wave models, the so called generalized kinetic equation (Janssen J Phys Oceanogr 33(4):863–884, 2003; Annenkov and Shrira J Fluid Mech 561:181–207, 2006b; Gramstad and Stiassnie J Fluid Mech 718:280–303, 2013), is discussed and implemented in the third generation wave model WAVEWATCH-III. The generalized kinetic equation includes the effects of near-resonant nonlinear interactions, and is therefore able, in theory, to describe faster nonlinear evolution than the existing forms of S_nl which are based on the standard Hasselmann kinetic equation (Hasselmann J Fluid Mech 12:481–500, 1962). Numerical simulations with WAVEWATCH have been carried out to thoroughly test the performance of the new form of S_nl, and to compare it to the existing models for S_nl in WAVEWATCH; the DIA and WRT. Some differences between the different models for S_nl are observed. As expected, the DIA is shown to perform less well compared to the exact terms in certain situations, in particular for narrow wave spectra. Also for the case of turning wind significant differences between the different models are observed. Nevertheless, different from the case of unidirectional waves where the generalized kinetic equation represents a obvious improvement to the standard forms of S_nl (Gramstad and Stiassnie 2013), the differences seems to be less pronounced for the more realistic cases considered in this paper.     

Influence of aquatic plants on the hydrogen isotope composition of sedimentary long-chain n-alkanes in the Lake Qinghai region,Qinghai-Tibet Plateau

The hydrogen isotopic composition(δD) of leaf wax long-chain n-alkanes(C27, C29, and C31) from lacustrine sediments has been widely applied to reconstruct terrestrial paleoclimatic and paleohydrological changes. However, few studies have addressed whether the aquatic-derived n-alkanes can affect the δD values of lake sedimentary long-chain n-alkanes, which are usually regarded as a recorder of the terrestrial hydrological signals. Here we systematically investigated δD values of long-chain n-alkanes from modern aquatic plants, both near-shore and off-shore surface sediments, surrounding terrestrial plant litters, as well as river water and lake water in Lake Qinghai and its satellite lakes on the northeastern Qinghai-Tibet Plateau. Our data showed that(i) δD values of long-chain n-alkanes from aquatic plants varied from-184‰ to-132‰ for n-C27, from-183‰ to-138‰ for n-C29, and from-189‰ to-130‰ for n-C31, respectively, with no significant differences among the three n-alkanes homologues;(ii) δD values of long-chain n-alkanes from aquatic plants were generally more positive than those from surrounding terrestrial plants, possibly because that they recorded the D-enrichment of lake water in this semi-arid region;(iii) δD values of long-chain n-alkanes from surface sediments showed significant differences among the three n-alkanes homologues, due to the larger aquatic input of n-C27 to the sedimentary lipid pool than that of n-C31, and(iv) n-C27 δD values of near-shore aquatic plants and near-shore sediments are more negative than those from off-shore as a result of lower δD values of near-shore lake water. Our findings indicate that in this region(i) the offset between sedimentary n-C27 and n-C31 δD values(ΔδDC27-C31) could potentially be used to evaluate if sedimentary long-chain n-alkanes are derived from a single source;(ii) while δD values of n-C27 may be influenced by lake water hydrological changes, sedimentary n-C31 is derived predominantly from terrestrial plants and thus its δD can serve as a relatively reliable indicator for terrestrial paleoclimatic and paleohydrological reconstructions.     

Oxygen cyclotron harmonic waves observed using Van Allen Probes

Fine structured multiple-harmonic electromagnetic emissions at frequencies around the equatorial oxygen cyclotron harmonics are observed by Van Allen Probe A outside the core plasmasphere(L~5) off the magnetic equator(MLAT~.7.5°)during a geomagnetic storm. We find that the multiple-harmonic emissions have power spectrum density(PSD) peaks during 2–8equatorial oxygen gyroharmonics( f ~ n fO+, n=2–8), while the fundamental mode(n=1) is absent, implying that the harmonic waves are generated near the equator and propagate into the observation region. Additionally, these electromagnetic emissions are linearly polarized. Different from the equatorial noise emission that propagates considerably obliquely, these emissions have moderate wave normal angles(approximately 40°–60°), which predominately increase as the harmonic number increases.Considering their frequency and wave normal angle characteristics, it is suggested that these multiple-harmonic emissions play an important role in the dynamic variation of radiation belt electrons.     

Geochemical characteristics of light hydrocarbons in cracking gases from chloroform bitumen A,crude oil and its fractions

The composition characteristics of light hydrocarbons from crude oil, chloroform bitumen A, saturated hydrocarbon fraction, aromatic hydrocarbon fraction, and asphaltene fraction during cracking have been studied systematically. The results revealed that the content of n-alkanes, branched alkanes and cycloalkanes in light hydrocarbons from the samples gradually decreased as the simulation temperature increased, and finally almost depleted completely, while the abundance of methane, benzene and its homologues increased obviously and became the main products. The ratios of benzene/ n-hexane and toluene/n-heptane can be used as measures for oil cracking levels. Variation characteristics of maturity parameters of light hydrocarbons, for example, iC₄/nC₄, iC₅/nC₅, isoheptane value, 2,2-DMC₄/nC₆, and 2-MC₆+3-MC₆/nC₇ for different samples with increasing pyrolysis temperature, are consistent with those in petroleum reservoirs, indicating that these parameters may be efficient maturity index.     

Relation of the <Emphasis Type="Italic">F</Emphasis> region to stratospheric parameters: Possible relation to the atmospheric dynamics

Time variations in the correlation coefficient r(h, fo) between the h(100) stratospheric parameter and the foF2 ionospheric parameter for more than two solar activity cycles (1979–2004) are considered. It is obtained that, for daytime values of the correlation coefficient r(h, fo) when all available years are considered, the absolute value of r(h, fo) decreases in time; i.e., the correlation weakening from the 1980s to the 1990s. This weakening is interpreted as a weakening of the eastward winds in the MLT region of the atmosphere, where presumably a filtration of internal waves providing interrelation of various atmospheric layers occurs.     

Isolated bursts of irregular geomagnetic pulsations in the region of the dayside cusp

In this work, the results of comparative analysis of morphological regularities of right-polarized (R type) and left-polarized (L type) isolated bursts of ipcl pulsations (irregular pulsations continuous long period) with an anomalously large amplitude in the region of the daytime polar cusp, as well as conditions of their excitation, are presented. It has been found that R and L bursts are similar in the maximum amplitude level, wave packet duration, spectral composition, magnitude of ellipticity, diurnal variation shape, and other characteristics. At the same time, bursts of the R and L type are excited at different degrees of plasma turbulence in the generation region, at different IMF orientations in the plane of ecliptic, as well as in the plane perpendicular to it, and at different dynamics of the parameter β (characterizing the ratio of the thermal pressure to the magnetic pressure) and Alfvén Mach number Ma. It is supposed that the generation of isolated bursts of the R and L types can be related to the amplification of the plasma turbulence level due to the development of wind instability at the front boundary of the magnetosphere, and features of their polarization can be interpreted in the scope of the model of nonlinear propagation of Alfvén waves.     

Effects of geomagnetic disturbances in power spectra of atmospheric waves in the dynamo region of the ionosphere

The dynamics of wave disturbances in the ionospheric E region in the band of periods of thermal tidal waves and waves of planetary scales (T = 48, 72, and 192 h) has been studied based on the variations in the horizontal component of the geomagnetic field, observed at Paratunka and Barrow observatories in September–October 1999. It has been found that, at midlatitudes during high geomagnetic activity, the intensity of oscillations in the power spectra with T = 24 and 12 h varies with a periodicity of 16 days different from the periodicity of changes in the ΣKp index. The maximal deviations of these periods from the values under quiet conditions coincide with the maximal changes in the ΣKp index. The variations in the 48–192 h band of periods (especially with T ～192 h) intensify simultaneously with increasing geomagnetic activity. The intensity of this harmonic is several times as high as that of the harmonic with T ～ 24 h. The periodicity of changes in the harmonics intensity within the 48–192 h band coincides with the periodicity of changes in the ΣKp index. In the polar ionosphere, the effect of high geomagnetic activity is observed as an increase in the variations with a quasi-period of T ～ 24 h and as an appearance of variations in the 48–192 h band with the periodicity coinciding with the maximums in the ΣKp index variations.     

Relation of the <Emphasis Type="Italic">F</Emphasis>2 region to stratospheric parameters: Dependence on magnetic activity in two solar cycles

The dependence of the correlation coefficient r(h, fo) between the stratospheric parameter h(100) and critical frequency foF2 revealed in the data of two solar cycles (1979–1989 and 1990–2000) on geomagnetic activity is analyzed. It is shown that the character of the r(h, fo) dependence on limitation on the Ap geomagnetic index is the same in both cycles but depends on the time of day and solar activity level for the given year. It is also found that there is a considerable difference in the absolute values of r(h, fo) between two cycles.     

Peculiarities of Rayleigh wave displacement in a transversely isotropic half space

We consider a transversely isotropic medium with vertical axis of symmetry (VTI). Rayleigh wave displacement components in a homogeneous VTI medium contain exp(±kr_jz), where z is the vertical coordinate, k is the wave number, and j?=?1, 2; r_j may be considered as depth-decay factor. In a VTI medium, r_j can be a real or imaginary as in an isotropic medium, or it can be a complex depending on the elastic parameters of the VTI medium; if complex, r₁ and r₂ are complex conjugates. In a homogeneous VTI half space, Rayleigh wave displacement is significantly modified with a phase shift when r_j changes from real to complex with variation of VTI parameters; at the transition, the displacement becomes zero when r₁?=?r₂. In a liquid layer over a VTI half space, Rayleigh waves are dispersive. Here, also Rayleigh wave displacement significantly modified with a phase shift when r_j changes from real to complex with a decrease of period. At very low period, phase velocity of Rayleigh waves becomes less than P-wave velocity in the liquid layer giving rise to Scholte waves (interface waves). The amplitudes of Scholte waves with a VTI half space are found to be significantly larger than those with an isotropic half space.     

Interaction of geometry and mechanical property of trapezoidal sedimentary basins with incident <Emphasis Type="Italic">SH</Emphasis> waves

This paper investigated the effects of basin geometry and material property on the response of 2D trapezoidal sediment-filled basin to incident plane SH waves. Ten basin configurations with different geometries were developed, and then their seismic responses to both Ricker wavelets and seismic records were simulated by using an explicit finite difference scheme. The definition of deep/shallow basin, the precondition for the observation of prominent surface waves and the influential area of edge effects of the shallow basin were discussed quantitatively in this study. The followings were concluded: in the common velocity contrast range (v _s1/v _s2 < 10), the fundamental frequency a basin with W/H > 3.0 can be estimated approximately by 1D theory. The complexity of peak ground acceleration distribution pattern, the width of the most affected section as well as the amplitude of ground motion in the Edge Region increase with incident frequency. Prominent surface waves can only be observed when the incident wavelength is shorter than the critical wavelength λ _c . The interaction between incident wave and basin dynamic property plays a dominant role on the peak ground acceleration amplitude while the interaction between incident wave and geometry plays a more significant role on the peak ground acceleration distribution. For very shallow basin, different areas along the basin width are affected to different extents. Only a limited area close to the basin edge is influenced significantly. It is more feasible to propose spectral aggravation factor for different surface zones respectively than a uniform constant as a tool to calibrate the 1D-based design spectrum so as to take the basin effects into account.     

Experimental study on the shear behavior of the interface between cushion materials and the concrete raft

Cushion is a layer of granular materials between the raft and the ground. The shear behavior of the interface between the cushion and the raft may influence the seismic performance of the superstructure. In order to quantify such influences, horizontal shear tests on the interfaces between different cushion materials and concrete raft under monotonic and cyclic loading were carried out. The vertical pressure P_v, material type and cushion thickness h_c were taken as variables. Conclusions include: 1) under monotonic loading, P_v is the most significant factor; the shear resistance P_(hmax) increases as P_v increases, but the normalized factor of resistance μ_n has an opposite tendency; 2) for the materials used in this study, μ_n varies from 0.40 to 0.70, the interface friction angle δ_s varies from 20° to 35°, while u_(max) varies from 3 mm to 15 mm; 3) under cyclic loading, the interface behavior can be abstracted as a "three-segment" back-bone curve, the main parameters include μ_n, the displacement u_1 and stiffness K_1 of the elastic stage, the displacement u_2 and stiffness K_2 of the plastic stage; 4) by observation and statistical analysis, the significance of different factors, together with values of K_1, K_2 and μ_n have been obtained.     

Resonant interaction between two planetary waves as a precursor for stratospheric warmings?

Stratospheric warmings are attributed to an enhanced planetary wave activity, occurring nearly each winter – at least in the northern hemisphere – with different strengths. The generation of stratospheric warmings is not totally understood. One of the most promising explanations is the interaction of planetary waves: in many cases, the amplitude of the quasi-stationary planetary wave 1 builds up, until it transmits its momentum and energy to the background wind field. The role of wave 2 is usually considered to be less important.Based on ERA-40 and DYANA temperature data (January–February 1990), we found evidence that a resonant wave–wave interaction between a travelling and a stationary wave 2 was responsible for a minor stratospheric warming in February 1990. The interaction being observed during four weeks can eventually be used as an indication for an upcoming stratospheric warming.     

Effect of geomagnetic and volcanic activity on the El Nino and La Nina phenomena

The monthly values of the southern atmospheric oscillation indices (SOI), the corresponding values of the Nino-3.4 index, the data on the onsets of intense volcanic eruptions from 1870 to 2002, the daily values of the Ap and AE indices and the IMF B _z component, and the data on cloudiness and wind characteristics at 14 Antarctic stations have been considered. The beginning of the warm El Nino current is observed after an increase in the amplitude of the Ap magnetic indices, which continues for more than five months. The beginning of the cold period of the La Nina southern atmospheric oscillation is as a rule related to a decrease in Ap. A change in atmospheric transparency caused by volcanic eruptions is often followed by the beginning of the cold period of the southern atmospheric oscillation (ENSO). A change in the wind system in the Antarctic Regions, related to a change in the temperature balance caused by variations in the solar wind parameters in the winter season, promotes a short-term disturbance of the circumpolar vortex and the beginning of the El Nino warm period.     

Preliminary study on the origin identification of natural gas by the parameters of light hydrocarbon

The light hydrocarbon composition of 209 natural gas samples and individual light hydrocarbon carbon isotopes of 53 natural gas samples from typical humic-sourced gas and sapropelic-sourced gas in the four basins of China have been determined and analyzed. Some identification parameters for humic-sourced gas and sapropelic-sourced gas are proposed or corrected. The differences of compound-specific δ ¹³C value of individual light hydrocarbon between humic-sourced gas and sapropelic-sourced gas have been founded. The humic-sourced gas has the distribution of δ ¹³C_benzene> ?24‰, δ ¹³C_toluene >?23‰, δ ¹³C_cyclohexane > ?24‰ and δ ¹³C_{methyl cyclohexane}> ?24‰, while the sapropelic-sourced gas has the distribution of δ ¹³C_benzene <?24‰, δ ¹³C_toluene< ?24‰, δ ¹³C_cyclohexane< ?24‰ and δ ¹³C_{methyl cyclohexane}< ?24‰. Among the components of C₇ light hydrocarbon compound, such as normal heptane (nC₇), methyl cyclohexane (MCH) and dimethyl cyclopentane (ΣDMCP), etc, relative contents of nC₇ and MCH are influenced mainly by the source organic matter type of natural gas. Therefore, it is suggested that the gas with relative content of nC₇ of more than 30% and relative content of MCH of less than 70% is sapropelic-sourced gas, while gas with relative content of nC₇ of less than 35% and relative content of MCH of more than 50% is humic-sourced gas. Among components of C_5–7 aliphatics, the gas with relative content of C_5–7 normal alkane of more than 30% is sapropelic-sourced gas, while the gas with relative content of C_5–7 normal alkane of less than 30% is humic-sourced gas. These paremeters have been suggested to identify humic-sourced gas and sapropelic-sourced gas.     

Characterization of the negative carbon isotope shift in segment C2, its global implications as a harbinger of OAE1a

Lower Cretaceous C-isotope records show intermittent negative/positive spikes, and consistent patterns of coeval chemostratigraphic curves thus document shifts that signal simultaneous responses of temporal changes in the global carbon reservoir. The standard pattern registered by the δ ¹³C_org and δ ¹³C_carb in Lower Aptian sediments includes distinct isotope segments C1 to C8 (Menegatti et al., 1998). In the El Pui section, Organyà Basin, Spain, C-isotope segment C2 is the longest interval preceding segments C3–C6 associated with oceanic anoxic event 1a (OAE 1a), and reveals a distinct negative shift of ~1.8‰ to ~2.23‰ defining the C-isotope pattern within that interval. Total inorganic carbon (TIC), total organic carbon (TOC), δ ¹³C_org, microfacies, n-alkanes show no difference before, during, or after the negative inflection. The biomarkers indicate that organic matter (OM) mainly originates from algal/microbial sources because short-chain length homologues (≤nC₁₉) dominate. nC₂₀ through nC₂₅ indicate some contribution from aquatic vegetation, but little from higher plants (>nC₂₅), as also suggested by the terrestrial/aquatic ratio of n-alkanes or (TAR) = [(nC₂₇+nC₂₉+nC₃₁)/(nC₁₅+nC₁₇+nC₁₉)] (averages 0.085). We suggest that conjoint pulses of contemporaneous LIPs (Ontong Java) and massive explosive volcanism in northeast Asia, the Songliao Basin (SB-V), best conform to plausible causes of the negative intra-C2 carbon isotopic excursion (CIE) at that time. Because of its apparent common occurrence the intra-C2 inflection could be a useful marker harbinger to the more pronounced CIE C3, the hallmark of OAE1a.     

Long-period irregular pulsations under the conditions of a quiet magnetosphere

Simultaneous observations of high-latitude long-period irregular pulsations at frequencies of 2.0–6.0 mHz (ipcl) and magnetic field disturbances in the solar wind plasma at low geomagnetic activity (Kp ~ 0) have been studied. The 1-s data on the magnetic field registration at Godhavn (GDH) high-latitude observatory and the 1-min data on the solar wind plasma and IMF parameters for 2011–2013 were used in an analysis. Ipcl (irregular pulsations continuous, long), which were observed against a background of the IMF Bz reorientation from northward to southward, have been analyzed. In this case other solar wind plasma and IMF parameters, such as velocity V, density n, solar wind dynamic pressure P = ρV² (ρ is plasma density), and strength magnitude B, were relatively stable. The effect of the IMF Bz variation rate on the ipcl spectral composition and intensity has been studied. It was established that the ipcl spectral density reaches its maximum (~10–20 min) after IMF Bz sign reversal in a predominant number of cases. It was detected that the ipcl average frequency (f) is linearly related to the IMF Bz variation rate (ΔBz/Δt). It was shown that the dependence of f on ΔBz/Δt is controlled by the α = arctan(By/Bx) angle value responsible for the MHD discontinuity type at the front boundary of magnetosphere. The results made it possible to assume that the formation of the observed ipcl spectrum, which is related to the IMF Bz reorientation, is caused by solar wind plasma turbulence, which promotes the development of current sheet instability and surface wave amplification at the magnetopause.