Spatial variations of the sodium/potassium ratio in Mercury’s exosphere uncovered by high-resolution spectroscopy

High-resolution spectroscopy of Mercury has been obtained with two different instruments in 2006: the EMMI instrument at the 3.6-m NTT telescope of ESO La Silla Chile and the ESPADON spectrograph at the 3.6-m CFHT telescope on top of Mauna Kea (Hawaii). The disk of the planet has been scanned for spatial variation of the exospheric species. The large spectral range and high resolution allow simultaneous measurements of the integrated column density of Na and K.We measure Na/K ratio between 80 and 400 with values between 60 and 90 when the telescope was pointed towards the subsolar region of Mercury’s disk and much larger value when we looked to other part of the exosphere. Moreover, we observed that the Na and K exospheres display very different spatial distributions. Even if these two species are probably ejected with very similar mechanisms from the surface, their differences in mass and sensitivity to solar pressure acceleration imply very different behavior in Mercury’s exosphere.     

Constraints on Mercury’s Na exosphere: Combined MESSENGER and ground-based data

We have used observations of sodium emission obtained with the McMath-Pierce solar telescope and MESSENGER’s Mercury Atmospheric and Surface Composition Spectrometer (MASCS) to constrain models of Mercury’s sodium exosphere. The distribution of sodium in Mercury’s exosphere during the period January 12-15, 2008, was mapped using the McMath-Pierce solar telescope with the 5″ × 5″ image slicer to observe the D-line emission. On January 14, 2008, the Ultraviolet and Visible Spectrometer (UVVS) channel on MASCS sampled the sodium in Mercury’s anti-sunward tail region. We find that the bound exosphere has an equivalent temperature of 900-1200 K, and that this temperature can be achieved if the sodium is ejected either by photon-stimulated desorption (PSD) with a 1200 K Maxwellian velocity distribution, or by thermal accommodation of a hotter source. We were not able to discriminate between the two assumed velocity distributions of the ejected particles for the PSD, but the velocity distributions require different values of the thermal accommodation coefficient and result in different upper limits on impact vaporization. We were able to place a strong constraint on the impact vaporization rate that results in the release of neutral Na atoms with an upper limit of 2.1 × 10⁶ cm⁻² s⁻¹. The variability of the week-long ground-based observations can be explained by variations in the sources, including both PSD and ion-enhanced PSD, as well as possible temporal enhancements in meteoroid vaporization. Knowledge of both dayside and anti-sunward tail morphologies and radiances are necessary to correctly deduce the exospheric source rates, processes, velocity distribution, and surface interaction.     

Limits to Mercury's magnesium exosphere from MESSENGER second flyby observations

The discovery measurements of Mercury's exospheric magnesium, obtained by the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) probe during its second Mercury flyby, are modeled to constrain the source and loss processes for this neutral species. Fits to a Chamberlain exosphere reveal that at least two source temperatures are required to reconcile the distribution of magnesium measured far from and near the planet: a hot ejection process at the equivalent temperature of several tens of thousands of degrees K, and a competing, cooler source at temperatures as low as 400 K. For the energetic component, our models indicate that the column abundance that can be attributed to sputtering under constant southward interplanetary magnetic field conditions is at least a factor of five less than the rate dictated by the measurements. Although highly uncertain, this result suggests that another energetic process, such as the rapid dissociation of exospheric MgO, may be the main source of the distant neutral component. If meteoroid and micrometeoroid impacts eject mainly molecules, the total amount of magnesium at altitudes exceeding ∼100 km is found to be consistent with predictions by impact vaporization models for molecule lifetimes of no more than two minutes. Though a sharp increase in emission observed near the dawn terminator region can be reproduced if a single meteoroid enhanced the impact vapor at equatorial dawn, it is much more likely that observations in this region, which probe heights increasingly near the surface, indicate a reservoir of volatile Mg being acted upon by lower-energy source processes.     

Monte Carlo modeling of sodium in Mercury’s exosphere during the first two MESSENGER flybys

We present a Monte Carlo model of the distribution of neutral sodium in Mercury’s exosphere and tail using data from the Mercury Atmospheric and Surface Composition Spectrometer (MASCS) on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft during the first two flybys of the planet in January and September 2008. We show that the dominant source mechanism for ejecting sodium from the surface is photon-stimulated desorption (PSD) and that the desorption rate is limited by the diffusion rate of sodium from the interior of grains in the regolith to the topmost few monolayers where PSD is effective. In the absence of ion precipitation, we find that the sodium source rate is limited to ∼10⁶-10⁷ cm⁻² s⁻¹, depending on the sticking efficiency of exospheric sodium that returns to the surface. The diffusion rate must be at least a factor of 5 higher in regions of ion precipitation to explain the MASCS observations during the second MESSENGER flyby. We estimate that impact vaporization of micrometeoroids may provide up to 15% of the total sodium source rate in the regions observed. Although sputtering by precipitating ions was found not to be a significant source of sodium during the MESSENGER flybys, ion precipitation is responsible for increasing the source rate at high latitudes through ion-enhanced diffusion.     

Orbital effects on Mercury’s escaping sodium exosphere

We present results from coronagraphic imaging of Mercury’s sodium tail over a 7° field of view. Several sets of observations made at the McDonald Observatory since May 2007 show a tail of neutral sodium atoms stretching more than 1000 Mercury radii (R_m) in length, or a full degree of sky. However, no tail was observed extending beyond 120 R_m during the January 2008 MESSENGER fly-by period, or during a similar orbital phase of Mercury in July 2008. Large changes in Mercury’s heliocentric radial velocity cause Doppler shifts about the Fraunhofer absorption features; the resultant change in solar flux and radiation pressure is the primary cause of the observed variation in tail brightness. Smaller fluctuations in brightness may exist due to changing source rates at the surface, but we have no explicit evidence for such changes in this data set. The effects of radiation pressure on Mercury’s escaping atmosphere are investigated using seven observations spanning different orbital phases. Total escape rates of atmospheric sodium are estimated to be between 5 and 13 × 10²³ atoms/s and show a correlation to radiation pressure. Candidate sources of Mercury’s sodium exosphere include desorption by UV sunlight, thermal desorption, solar wind channeled along Mercury’s magnetic field lines, and micro-meteor impacts. Wide-angle observations of the full extent of Mercury’s sodium tail offer opportunities to enhance our understanding of the time histories of these source rates.     

Source dependency of exospheric sodium on Mercury

Due to a large solar radiation effect, the sodium exosphere exhibits many interesting effects, including the formation of an extended corona and a tail-like structure. The current suite of observations allows us to study some physical properties of the sodium exosphere, such as the source rates and the interaction with the surface, both experimentally and theoretically. In order to quantify the complex variations in the sodium exosphere in more detail, we use an exospheric model with the Monte-Carlo method to examine the surface interactions of a sodium atom, including the surface thermal accommodation rate and the sticking coefficient. The source rates from different components, such as the photon stimulated desorption (PSD), the meteoroid impact vaporization (MIV), and the solar wind ion sputtering (IS), can be constrained by comparing our exospheric model calculations with the published observational data. The detected terminator to limb (TL) ratio on the disk and the tail production rate can be explained with no sticking effect and small thermal accommodation rates. We also examine the best fit of the MIV source evolution, through comparison with the disk-averaged emission. The resultant discrepancy between the observations and the model fit may reflect the surface variation in the sodium abundance. A comprehensive mapping of the surface geochemical composition of the surface by the MESSENGER and Bepi-Colombo missions should give us more information about the nature of this surface-bound exosphere.     

Impacts as sources of the exosphere on Mercury

Chemical processes associated with meteoroid bombardment of Mercury are considered. Meteoroid impacts lead to production of metal atoms as well as metal oxides and hydroxides in the planetary exosphere. By using quenching theory, the abundances of the main Na-, K-, Ca-, Fe-, Al-, Mg-, Si-, and Ti-containing species delivered to the exosphere during meteoroid impacts were estimated. Based on a correlation between the solar photo rates and the molecular constants of atmospheric diatomic molecules, photolysis lifetimes of metal oxides and SiO are estimated. Meteoroid impacts lead to the formation of hot metal atoms (0.2-0.4 eV) produced directly during impacts and of very hot metal atoms (1-2 eV) produced by the subsequent photolysis of oxides and hydroxides in the exosphere of Mercury. The concentrations of impact-produced atoms of the main elements in the exosphere are estimated relative to the observed concentrations of Ca, assumed to be produced mostly by ion sputtering. Condensation of dust grains can significantly reduce the concentrations of impact-produced atoms in the exosphere. Na, K, and Fe atoms are delivered to the exosphere directly by impacts while Ca, Al, Mg, Si, and Ti atoms are produced by the photolysis of their oxides and hydroxides. The chemistry of volatile elements such as H, S, C, and N during meteoroid bombardment is also considered. Our conclusions about the temperature and the concentrations of impact-produced atoms in the exosphere of Mercury may be checked by the Messenger spacecraft in the near future and by BepiColombo spacecraft some years later.     

Self-consistent modelling of Mercury’s exosphere by sputtering, micro-meteorite impact and photon-stimulated desorption

A Monte-Carlo model of exospheres (Wurz and Lammer, 2003) was extended by treating the ion-induced sputtering process, photon-stimulated desorption, and micro-meteorite impact vaporisation quantitatively in a self-consistent way starting with the actual release of particles from the mineral surface of Mercury. Based on available literature data we established a global model for the surface mineralogy of Mercury and from that derived the average elemental composition of the surface. This model serves as a tool to estimate densities of species in the exosphere depending on the release mechanism and the associated physical parameters quantitatively describing the particle release from the surface.Our calculation shows that the total contribution to the exospheric density at the Hermean surface by solar wind sputtering is about 4×10⁷ m^-3, which is much less than the experimental upper limit of the exospheric density of 10¹² m^-3. The total calculated exospheric density from micro-meteorite impact vaporisation is about 1.6×10⁸ m^-3, also much less than the observed value. We conclude that solar wind sputtering and micro-meteorite impact vaporisation contribute only a small fraction of Mercury’s exosphere, at least close to the surface. Because of the considerably larger scale height of atoms released via sputtering into the exosphere, sputtered atoms start to dominate the exosphere at altitudes exceeding around 1000 km, with the exception of some light and abundant species released thermally, e.g. H₂ and He. Because of Mercury’s strong gravitational field not all particles released by sputtering and micro-meteorite impact escape. Over extended time scales this will lead to an alteration of the surface composition.     

Mercury surface composition: Integrating petrologic modeling and remote sensing data to place constraints on FeO abundance

A significant opaque component in Mercury’s crust is inferred based on albedo and spectral observations. Previous workers have favored iron-titanium bearing oxide minerals as the spectrally neutral opaque. A consequence of this hypothesis is that Mercury’s surface would have a high FeO content. An array of remote sensing techniques have not provided definitive constraints on the FeO content of Mercury’s surface. However, spectral observations have not detected a diagnostic 1 μm absorption band and have thus limited the FeO in coexisting silicates to <2 wt.% FeO. In this paper, we assess equilibrium among oxide and silicate minerals to constrain the distribution of iron between opaque oxides and silicates under a variety of environmental conditions. Equilibrium modeling is favored here because the geologic process that produced Mercury’s low-albedo intermediate terrain must have occurred globally, which favors a common widespread igneous process. Based on our modeling, we find that iron-rich ilmenite cannot occur with silicates that do not display a 1 μm absorption feature unless plagioclase abundances are high. However, such high plagioclase abundances are precluded by Mercury’s low albedo. Incorporating equilibrium crystallization modeling with spectral and albedo constraints we find the iron abundance of Mercury’s intermediate terrain is ?10 wt.% FeO. This intermediate iron composition matches constraints provided by visible albedo and total neutron absorption observed by MESSENGER. In fact, the total neutron absorption of mixtures of oxide, plagioclase, olivine and pyroxene for the oxide abundances estimated for Mercury, favor Mg-rich members of the ilmenite-geikielite solid-solution series. This work offers compositional constraints for Fe, Ti, and Mg that will be testable by various MESSENGER instrument data sets after it begins its orbital mission.     

Investigation of local time dependence of Mercury's sodium exosphere based on a numerical simulation

Mercury has a surface-bounded exosphere (SBE) similar to that of the Moon. One of the atmospheric species, sodium, was found by ground-based observations to be the most prominent component. Mercury's sodium SBE is known to be non-uniform with respect to local time (LT) in low-latitude regions: the sodium column density in the dawn-side region is larger than that in the dusk-side region, and the sodium abundance is the largest in the morning-noon region. To reveal the production processes for the exosphere near Mercury's surface, the LT dependence of the exosphere was investigated through a numerical simulation. Three data sets of sodium column densities observed for the dawn-side hemisphere, observed by Sprague et al. [1997. Distribution and abundance of sodium in Mercury's atmosphere, 1985-1988. Icarus 12, 506-527], were compared with results simulated by a 3D Monte Carlo method, and the source rates and density of sodium of the planetary surface were estimated. In the simulation, the photon-stimulated desorption (PSD) and thermal desorption (TD) processes were assumed as the release mechanisms. The sodium source rates for the three data sets, at respective heliocentric distances of about 0.33, 0.42, and 0.44 AU, were estimated as 1-4×10⁸ Na/cm²/s with weak LT dependence. In contrast, the expected sodium surface density showed clear dependence on LT and the heliocentric distance. The sodium surface density decreases from early morning to noon by a few orders, and, particularly for large heliocentric distances, the surface is in a condition of sodium excess and depletion with respect to the surface sodium density assumed by Killen et al. [2004. Source rates and ion recycling rates for Na and K in Mercury's atmosphere. Icarus 171, 1-19] in the early morning and morning-noon regions, respectively. This study implies that the decrease in sodium surface density from the early morning to noon regions might produce the characteristic LT dependence in the low-latitude dawn-side region.     

Mercury and Moon He exospheres: Analysis and modeling

Helium is one of the first elements clearly identified in the lunar exosphere (Hoffman, J.H., Hodges, R.R., Johnson, F.S., Evans, D.E. [1973]. Proc. Lunar Sci. Conf. 3, 2865–2875). Apollo 17 measured the He density at the surface during four lunations. It confirmed the expected day to night asymmetry of the He exosphere with a maximum density near the dawn terminator on the nightside. Few years later, the first detection of Mercury’s He exosphere was successfully obtained by Mariner 10 (Broadfoot, A.L., Shemansky, D.E., Kumar, S. [1976]. Geophys. Res. Lett. 3, 577–580). These observations highlighted similar global distribution of the He exosphere at Mercury and at the Moon, but also significant differences that have never been convincingly explained.In this paper, we model the He exosphere at the Moon and Mercury with the same approach. The energy accommodation of the exospheric He particles interacting with the surface can be roughly constrained using Apollo 17 and Mariner 10 measurements. Neither a low energy accommodation, as suggested by Shemansky and Broadfoot (Shemansky, D.E., Broadfoot, A.L. [1977]. Rev. Geophys. 15, 491–499), nor a full energy accommodation, as suggested by Hodges (Hodges Jr., R.R. [1975]. The Moon, 14, 139–157), can fit all the observations. These observations and their modeling suggest a diurnal variation of the energy distribution of the He ejected from the surface that cannot be explained satisfactorily by any of the present theories on the gas–surface interaction in surface-bounded exospheres.     

Mercury’s magnetosphere-solar wind interaction for northward and southward interplanetary magnetic field: Hybrid simulation results

Analysis of global hybrid simulations of Mercury’s magnetosphere-solar wind interaction is presented for northward and southward interplanetary magnetic field (IMF) orientations in the context of MESSENGER’s first two encounters with Mercury. The global kinetic simulations reveal the basic structure of this interaction, including a bow shock, ion foreshock, magnetosheath, cusp regions, magnetopause, and a closed ion ring belt formed around the planet within the magnetosphere. The two different IMF orientations induce different locations of ion foreshock and different magnetospheric properties: the dayside magnetosphere is smaller and cusps are at lower latitudes for southward IMF compared to northward IMF whereas for southward IMF the nightside magnetosphere is larger and exhibits a thin current sheet with signatures of magnetic reconnection and plasmoid formation. For the two IMF orientations the ion foreshock and quasi-parallel magnetosheath manifest ion-beam-driven large-amplitude oscillations, whereas the quasi-perpendicular magnetosheath shows ion-temperature-anisotropy-driven wave activity. The ions in Mercury’s belt remain quasi-trapped for a limited time before they are either absorbed by Mercury’s surface or escape from the magnetosphere. The simulation results are compared with MESSENGER’s observations.     

Identification and measurement of neutron-absorbing elements on Mercury’s surface

MESSENGER Neutron Spectrometer (NS) observations of cosmic-ray-generated thermal neutrons provide the first direct measurements of Mercury’s surface elemental composition. Specifically, we show that Mercury’s surface is enriched in neutron-absorbing elements and has a measured macroscopic neutron-absorption cross section of 45-81 × 10⁻⁴ cm²/g, a range similar to the neutron absorption of lunar basalts from Mare Crisium. The expected neutron-absorbing elements are Fe and Ti, with possible trace amounts of Gd and Sm. Fe and Ti, in particular, are important for understanding Mercury’s formation and how its surface may have changed over time through magmatic processes. With neutron Doppler filtering - a neutron energy separation technique based on spacecraft velocity - we demonstrate that Mercury’s surface composition cannot be matched by prior models, which have characteristically low abundances of Fe, Ti, Gd, and Sm. While neutron spectroscopy alone cannot separate the relative contributions of individual neutron-absorbing elements, these results provide strong new constraints on the nature of Mercury’s surface materials. For example, if all the measured neutron absorption were due to the presence of an Fe-Ti oxide and that oxide were ilmenite, then Mercury’s surface would have an ilmenite content of 7-18 wt.%. This result is in general agreement with the inference from color imaging and visible-near-infrared spectroscopy that Mercury’s overall low reflectance is consistent with a surface composition that is enriched in Fe-Ti oxides. The incorporation of substantial Fe and Ti in oxides would imply that the oxygen fugacity of basalts on Mercury is at the upper range of oxygen fugacities inferred for basalts on the Moon.     

Resolved spectroscopy of Mercury in the near-IR with SpeX/IRTF

We present resolved near-infrared spectra of Mercury scanning 70% of the surface in latitude and longitude from three separate observations, allowing us to perform a compositional investigation of its surface. By scanning the surface we find that all spectra in our sample are remarkably similar suggesting overall compositional homogeneity. We do, however, observe a slope difference between the spectra. These slope changes are most likely due to differences in the emission angle over different parts of the surface. We confirm the presence of a 1.1 μm feature that had been previously detected (Warell, J. et al. [2006]. Icarus 180, 281-291) and attributed to Ca-rich clinopyroxene. Finally, we investigated Mercury’s surface composition by comparing its spectrum with ground-based lunar spectra, lunar soil spectra collected in the laboratory, and analysis with a simple linear mixing model using various minerals as end-members. The result of this compositional investigation reveals that Mercury’s surface composition is likely to be quite different from the Moon’s. While low-Ca iron-rich pyroxenes are main surface components on the Moon (abundance varying from ∼5% to ∼35%), their abundance on Mercury may not exceed 5%. We also find that a Ca-rich clinopyroxene (in the hedenbergite-diopside series) is likely to be a main component of Mercury’s surface whereas this mineral is almost absent on the Moon. Our analysis also suggests the possible presence of olivine. We find that Mercury’s slope is less red than that of the Moon, in agreement with results from MESSENGER (McClintock, W.E., and 12 colleagues [2008]. Science 321, 62-65), and composition rather than variation of space weathering is likely the cause of this difference.     

Mercury’s magnetospheric magnetic field after the first two MESSENGER flybys

The “paraboloid” model of Mercury’s magnetospheric magnetic field is used to determine the best-fit magnetospheric current system and internal dipole parameters from magnetic field measurements taken during the first and second MESSENGER flybys of Mercury on 14 January and 6 October 2008. Together with magnetic field measurements taken during the Mariner 10 flybys on 29 March 1974 and 16 March 1975, there exist three low-latitude traversals separated in longitude and one high-latitude encounter. From our model formulation and fitting procedure a Mercury dipole moment of 196 nT ·  (where R_M is Mercury’s radius) was determined. The dipole is offset from Mercury’s center by 405 km in the northward direction. The dipole inclination to Mercury’s rotation axis is relatively small, ∼4°, with an eastern longitude of 193° for the dipole northern pole. Our model is based on the a priori assumption that the dipole position and the moment orientation and strength do not change in time. The root mean square (rms) deviation between the Mariner 10 and MESSENGER magnetic field measurements and the predictions of our model for all four flybys is 10.7 nT. For each magnetic field component the rms residual is ∼6 nT or about 1.5% of the maximum measured magnetic field, ∼400 nT. This level of agreement is possible only because the magnetospheric current system parameters have been determined separately for each flyby. The magnetospheric stand-off distance, the distance from the planet’s center to the inner edge of the tail current sheet, the tail lobe magnetic flux, and the displacement of the tail current sheet relative to the Mercury solar-magnetospheric equatorial plane have been determined independently for each flyby. The magnetic flux in the tail lobes varied from 3.8 to 5.9 MWb; the subsolar magnetopause stand-off distance from 1.28 to 1.43 R_M; and the distance to the inner edge of the current sheet from 1.23 to 1.32 R_M. The differences in the current systems between the first and second MESSENGER flybys are attributed to the effects of strong magnetic reconnection driven by southward interplanetary magnetic field during the latter flyby.     

The influence of Mercury’s inner core on its physical libration

As Mercury orbits the Sun, gravitational torques on its equatorial elliptical shape give rise to a planetary libration. The amplitude of Mercury’s libration, as determined from Earth-based radar speckle pattern observations, suggests that only the mantle participates in the motion. This indicates a decoupling between the core and the mantle, and therefore that the outermost part of the core must be fluid. If a solid inner core is present at the center of Mercury, the equatorial elliptical shape of the latter may become misaligned with that of Mercury’s mantle, leading to an internal gravitational torque between the two. If this torque is large, it may participate in the dynamics of Mercury’s libration. The goal of this work is to determine whether Mercury’s observed librations can be used to place constraints on the properties of its inner core. We present a comparison between predicted and observed librations for a range of interior models of Mercury, with various inner core sizes and fluid core densities. We show that a marginally better fit to observations can be achieved for interior models that have an inner core radius larger than 400 km. However, the improvement in fit is small, and it is not possible to draw robust conclusions on the size of Mercury’s inner core on the basis of existing libration data. Nevertheless, our study demonstrates that the influence of the inner core on the libration of Mercury could be detected with a decade worth of accurate observations.     

The calcium exosphere of Mercury

A tenuous calcium atmosphere at Mercury, principally seen in the polar regions, was first observed in July, 1998, using the High Resolution Echelle Spectrograph (HIRES) at the W.M. Keck I telescope (Bida et al., Nature 404, 159, 2000). We report four years of observations of the calcium exosphere of Mercury, confirming the initial findings of a very tenuous atmosphere. These observations show a persistent but spatially variable blue shift, indicating an excess velocity toward the observer of up to 3 km s⁻¹, with an average excess velocity of 2.2 km s⁻¹ above the south pole. In addition, the line profiles reveal a hot corona at the equivalent of 12,000-20,000 K in a thermalized atmosphere, indicating a large range of motion with respect to the observer. The calcium is not confined to the polar-regions: rare and low Ca abundance is seen in the equatorial regions. Strong emission was seen anti-sunward on 3 May 2002. Apparent weak emission on the sunward hemisphere may be due to scattered light from the surface, or may indicate a high latitude source. We show that the likely source of the calcium is either impact vaporization in the form of CaO and clusters, which are subsequently photo-dissociated, or ion-sputtering of atoms, molecules and ions. The column abundance is somewhat, but not strongly, correlated with solar activity. We predict a very hot (probably escaping) oxygen component to the hermean exosphere.     

The variability of Mercury's exosphere by particle and radiation induced surface release processes

Mercury's close orbit around the Sun, its weak intrinsic magnetic field and the absence of an atmosphere (P_surface<1×10⁻⁸ Pa) results in a strong direct exposure of the surface to energetic ions, electrons and UV radiation. Thermal processes and particle-surface-collisions dominate the surface interaction processes leading to surface chemistry and physics, including the formation of an exosphere (N?10¹⁴ cm⁻²) in which gravity is the dominant force affecting the trajectories of exospheric atoms. NASA's Mariner 10 spacecraft observed the existence of H, He, and O in Mercury's exosphere. In addition, the volatile components Na, K, and Ca have been observed by ground based instrumentation in the exosphere. We study the efficiency of several particle surface release processes by calculating stopping cross-sections, sputter yields and exospheric source rates. Our study indicates surface sputter yields for Na between values of about 0.27 and 0.35 in an energy range from 500 eV up to 2 keV if Na⁺ ions are the sputter agents, and about 0.037 and 0.082 at an energy range between 500 eV up to 2 keV when H⁺ are the sputter agents and a surface binding energy of about 2 eV to 2.65 eV. The sputter yields for Ca are about 0.032 to 0.06 and for K atoms between 0.054 to 0.1 in the same energy range. We found a sputter yield for O atoms between 0.025 and 0.04 for a particle energy range between 500 eV up to 2 keV protons. By taking the average solar wind proton surface flux at the open magnetic field line area of about 4×10⁸ cm⁻² s⁻¹ calculated by Massetti et al. (2003, Icarus, in press) the resulting average sputtering flux for O is about 0.8-1.0×10⁷ cm⁻² s⁻¹ and for Na approximately 1.3-1.6×10⁵ cm⁻² s⁻¹ depending on the assumed Na binding energies, regolith content, sputtering agents and solar activity. By using lunar regolith values for K we obtain a sputtering flux of about 1.0-1.4×10⁴ cm⁻² s⁻¹. By taking an average open magnetic field line area of about 2.8×10¹⁶ cm² modelled by Massetti et al. (2003, Icarus, in press) we derive an average surface sputter rate for Na of about 4.2×10²¹ s⁻¹ and for O of about 2.5×10²³ s⁻¹. The particle sputter rate for K atoms is about 3.0×10²⁰ s⁻¹ assuming lunar regolith composition for K. The sputter rates depend on the particle content in the regolith and the open magnetic field line area on Mercury's surface. Further, the surface layer could be depleted in alkali. A UV model has been developed to yield the surface UV irradiance at any time and latitude over a Mercury year. Seasonal and diurnal variations are calculated, and Photon Stimulated Desorption (PSD) fluxes along Mercury's orbit are evaluated. A solar UV hotspot is created towards perihelion, with significant average PSD particle release rates and Na fluxes of about 3.0×10⁶ cm⁻² s⁻¹. The average source rates for Na particles released by PSD are about 1×10²⁴ s⁻¹. By using the laboratory obtained data of Madey et al. (1998, J. Geophys. Res. 103, 5873-5887) for the calculation of the PSD flux of K atoms we get fluxes in the order of about 10⁴ cm⁻² s⁻¹ along Mercury's orbit. However, these values may be to high since they are based on idealized smooth surface conditions in the laboratory and do not include the roughness and porosity of Mercury's regolith. Further, the lack of an ionosphere and Mercury's small, temporally and spatially highly variable magnetosphere can result in a large and rapid increase of exospheric particles, especially Na in Mercury's exosphere. Our study suggests that the average total source rates for the exosphere from solar particle and radiation induced surface processes during quiet solar conditions may be of the same order as particles produced by micrometeoroid vaporization. We also discuss the capability of in situ measurements of Mercury's highly variable particle environment by the proposed NPA-SERENA instrument package on board ESA's BepiColombo Mercury Planetary Orbiter (MPO).