A tropical haze band in Titan’s stratosphere

Inspection of near-infrared images from Cassini’s Imaging Science Subsystem and Visual and Infrared Mapping Spectrometer have revealed a new feature in Titan’s haze structure: a narrow band of increased scattering by haze south of the equator. The band seems to indicate a region of very limited mixing in the lower stratosphere, which causes haze particles to be trapped there. This could explain the sharp separation between the two hemispheres, known as the north-south asymmetry, seen in images. The separation of the two hemispheres can also be seen in the stratosphere above 150 km using infrared spectra measured by Cassini’s Composite Infrared Spectrometer. Titan’s behaviour in the lower tropical stratosphere is remarkably similar to that of the Earth’s tropical stratosphere, which hints at possible common dynamical processes.     

Evidence for layered methane clouds in Titan’s troposphere

Layered methane clouds in Titan’s troposphere with an upper methane ice cloud, a lower liquid methane-nitrogen cloud, and a gap in between were suggested from in situ measurements and ground-based observations. Here we report laboratory investigations under conditions that mimic Titan’s troposphere providing a detailed picture of the cloud layers. A solid methane cloud with a nitrogen content of less than 14% and a liquid methane-nitrogen cloud with a nitrogen content of ∼30% form above ∼19 km and below ∼16 km altitude, respectively. Contrary to previous assertions, long-lived supercooled liquid methane-nitrogen droplets can be sustained in the region in between. The results demonstrate that a cloud gap could only form in the presence of high amounts of other traces species (ethane nuclei, tholin particles, etc.).     

Titan’s 5-μm window: observations with the Very Large Telescope

We report on mid-resolution (R∼2000) spectroscopic observations of Titan, acquired in November 2000 with the Very Large Telescope and covering the range 4.75-5.07 μm. These observations provide a detailed characterization of the CO (1-0) vibrational band, clearly separating for the first time individual CO lines (P10 to P19 lines of ¹³CO). They indicate that the CO/N₂ mixing ratio in Titan’s troposphere is 32±10 ppm. Comparison with photochemical models indicates that CO is not in a steady state in Titan’s atmosphere. The observations confirm that Titan’s 5-μm continuum geometric albedo is ∼0.06, and further indicates a ∼20% albedo decrease over 4.98-5.07 μm. Nonzero flux is detected at the 0.01 geometric albedo level in the saturated core of the ¹²CO (1-0) band, at 4.75-4.85 μm, providing evidence for backscattering on the stratospheric haze. Finally, emission lines are detected at 4.75-4.835 μm, coinciding in position with lines from the CO(1-0) and/or CO(2-1) bands. Matching them by thermal emission would require Titan’s stratosphere to be much warmer (by ∼ 25 K at 0.1 mbar) than indicated by the methane 7.7-μm emission and the Voyager radio-occultation. We show instead that a nonthermal mechanism, namely solar-excited fluorescence, is a more plausible source for these emissions. Improved observations and laboratory measurements on the vibrational-translational relaxation of CO are needed for further interpretation of these emissions in terms of a CO stratospheric mixing ratio.     

Small-scale composition and haze layering in Titan’s polar vortex

Fine scale layering of haze and composition in Titan’s stratosphere and mesosphere was investigated using visible/UV images from Cassini’s Imaging Science Sub-system (ISS) and IR spectra from Cassini’s Composite Infra-Red Spectrometer (CIRS). Both ISS and CIRS independently show fine layered structures in haze and composition, respectively, in the 150-450 km altitude range with a preferred vertical wavelength of around 50 km. Layers are most pronounced around the north polar winter vortex, although some weaker layers do exist at more southerly latitudes. The amplitude of composition layers in each trace gas profile is proportional to the relative enrichment of that species in the winter polar vortex compared to equatorial latitudes. As enrichment is caused by polar subsidence, this suggests a dynamical origin. We propose that the polar layers are caused by cross-latitude advection across the vortex boundary. This is analogous to processes that lead to ozone laminae formation around Earth’s polar vortices.     

Atomic and molecular hydrogen budget in Titan’s atmosphere

Using a one-dimensional model, we investigate the hydrogen budget and escape to space in Titan’s atmosphere. Our goal is to study in detail the distributions and fluxes of atomic and molecular hydrogen in the model, while identifying sources of qualitative and quantitative uncertainties. Our study confirms that the escape of atomic and molecular hydrogen to space is limited by the diffusion through the homopause level. The H distribution and flux inside the atmosphere are very sensitive to the eddy diffusion coefficient used above altitude 600 km. We chose a high value of this coefficient 1 × 10⁸ cm² s⁻¹ and a homopause level around altitude 900 km. We find that H flows down significantly from the production region above 500 km to the region [300-500] km, where it recombines into H₂. Production of both H and H₂ also occurs in the stratosphere, mostly from photodissociation of acetylene. The only available observational data to be compared are the escape rate of H deduced from Pioneer 11 and IUE observations of the H torus 1-3 × 10⁹ cm⁻² s⁻¹ and the latest retrieved value of the H₂ mole fraction in the stratosphere: (1.1 ± 0.1) × 10⁻³. Our results for both of these values are at least 50-100% higher, though the uncertainties within the chemical schemes and other aspects of the model are large. The chemical conversion from H to H₂ is essentially done through catalytic cycles using acetylene and diacetylene. We have studied the role of this diacetylene cycle, for which the associated reaction rates are poorly known. We find that it mostly affects C₄ species and benzene in the lower atmosphere, rather than the H profile and the hydrogen budget. We have introduced the heterogenous recombination of hydrogen on the surface of aerosol particles in the stratosphere, and this appears to be a significant process, comparable to the chemical processes. It has a major influence on the H distribution, and consequently on several other species, especially C₃H₄, C₄H₂ and C₆H₆. Therefore, this heterogenous process should be taken into account when trying to understand the stratospheric distribution of these hydrocarbons.     

Temporal variations of Titan’s middle-atmospheric temperatures from 2004 to 2009 observed by Cassini/CIRS

We use five and one-half years of limb- and nadir-viewing temperature mapping observations by the Composite Infrared Radiometer-Spectrometer (CIRS) on the Cassini Saturn orbiter, taken between July 2004 and December 2009 (L_S from 293° to 4°; northern mid-winter to just after northern spring equinox), to monitor temperature changes in the upper stratosphere and lower mesosphere of Titan. The largest changes are in the northern (winter) polar stratopause, which has declined in temperature by over 20 K between 2005 and 2009. Throughout the rest of the mid to upper stratosphere and lower mesosphere, temperature changes are less than 5 K. In the southern hemisphere, temperatures in the middle stratosphere near 1 mbar increased by 1-2 K from 2004 through early 2007, then declined by 2-4 K throughout 2008 and 2009, with the changes being larger at more polar latitudes. Middle stratospheric temperatures at mid-northern latitudes show a small 1-2 K increase from 2005 through 2009. At north polar latitudes within the polar vortex, temperatures in the middle stratosphere show a ∼4 K increase during 2007, followed by a comparable decrease in temperatures in 2008 and into early 2009. The observed temperature changes in the north polar region are consistent with a weakening of the subsidence within the descending branch of the middle atmosphere meridional circulation.     

The composition of liquid methane-nitrogen aerosols in Titan’s lower atmosphere from Monte Carlo simulations

Molecular level Monte Carlo simulations have been performed with various model potentials for the CH₄-N₂ vapor-liquid equilibrium at conditions prevalent in the atmosphere of Saturn’s moon Titan. With a single potential parameter adjustment to reproduce the vapor-liquid equilibrium at a higher temperature, Monte Carlo simulations are in excellent agreement with available laboratory measurements. The results demonstrate the ability of simple pair potential models to describe phase equilibria with the requisite accuracy for atmospheric modeling, while keeping the number of adjustable parameters at a minimum. This allows for stable extrapolation beyond the range of available laboratory measurements into the supercooled region of the phase diagram, so that Monte Carlo simulations can serve as a reference to validate phenomenological models commonly used in atmospheric modeling. This is most important when the relevant region of the phase diagram lies outside the range of laboratory measurements as in the case of Titan. The present Monte Carlo simulations confirm the validity of phenomenological thermodynamic equations of state specifically designed for application to Titan. The validity extends well into the supercooled region of the phase diagram. The possible range of saturation levels of Titan’s troposphere above altitudes of 7 km is found to be completely determined by the remaining uncertainty of the most recent revision of the Cassini-Huygens data, yielding a saturation of 100 ± 6% with respect to CH₄-N₂ condensation up to an altitude of about 20 km.     

Molecular hydrogen in Titan’s atmosphere: Implications of the measured tropospheric and thermospheric mole fractions

The third most abundant species in Titan’s atmosphere is molecular hydrogen with a tropospheric/lower stratospheric mole fraction of 0.001 derived from Voyager and Cassini infrared measurements. The globally averaged thermospheric H₂ mole fraction profile from the Cassini Ion Neutral Mass Spectrometer (INMS) measurements implies a small positive gradient in the H₂ mixing ratio from the tropopause region to the lower thermosphere (∼950-1000 km), which drives a downward H₂ flux into Titan’s surface comparable to the H₂ escape flux out of the atmosphere (∼2 × 10¹⁰ cm⁻² s⁻¹ referenced to the surface) and requires larger photochemical production rates of H₂ than obtained by previous photochemical models. From detailed model calculations based on known photochemistry with eddy, molecular, and thermal diffusion, the tropospheric and thermospheric H₂ mole fractions are incompatible by a factor of ∼2. The measurements imply that the downward H₂ surface flux is in substantial excess of the speculative threshold value for methanogenic life consumption of H₂ (McKay, C.P., Smith, H.D. [2005], Icarus 178, 274-276. doi:10.1016/j.icarus.2005.05.018), but without the extreme reduction in the surface H₂ mixing ratio.     

Transient surface liquid in Titan’s polar regions from Cassini

Cassini RADAR images of Titan’s south polar region acquired during southern summer contain lake features which disappear between observations. These features show a tenfold increases in backscatter cross-section between images acquired one year apart, which is inconsistent with common scattering models without invoking temporal variability. The morphologic boundaries are transient, further supporting changes in lake level. These observations are consistent with the exposure of diffusely scattering lakebeds that were previously hidden by an attenuating liquid medium. We use a two-layer model to explain backscatter variations and estimate a drop in liquid depth of approximately 1-m-per-year. On larger scales, we observe shoreline recession between ISS and RADAR images of Ontario Lacus, the largest lake in Titan’s south polar region. The recession, occurring between June 2005 and July 2009, is inversely proportional to slopes estimated from altimetric profiles and the exponential decay of near-shore backscatter, consistent with a uniform reduction of 4 ± 1.3 m in lake depth.Of the potential explanations for observed surface changes, we favor evaporation and infiltration. The disappearance of dark features and the recession of Ontario’s shoreline represents volatile transport in an active methane-based hydrologic cycle. Observed loss rates are compared and shown to be consistent with available global circulation models. To date, no unambiguous changes in lake level have been observed between repeat images in the north polar region, although further investigation is warranted. These observations constrain volatile flux rates in Titan’s hydrologic system and demonstrate that the surface plays an active role in its evolution. Constraining these seasonal changes represents the first step toward our understanding of longer climate cycles that may determine liquid distribution on Titan over orbital time periods.     

Insolation in Titan’s troposphere

Seasonality in Titan’s troposphere is driven by latitudinally varying insolation. We show that the latitudinal distributions of insolation in the troposphere and at the surface, based on Huygens DISR measurements, can be approximated analytically with nonzero extinction optical depths τ, and are not equivalent to that at the top of the atmosphere (τ = 0), as has been assumed previously. This has implications for the temperature distribution and the circulation, which we explore with a simple box model. The surface temperature maximum and the upwelling arm of thermally-direct meridional circulation reach the midlatitudes, not the poles, during summertime.     

Titan’s atomic hydrogen corona

Based on measurements performed by the Hydrogen Deuterium Absorption Cell (HDAC) aboard the Cassini orbiter, Titan’s atomic hydrogen exosphere is investigated. Data obtained during the T9 encounter are used to infer the distribution of atomic hydrogen throughout Titan’s exosphere, as well as the exospheric temperature.The measurements performed during the flyby are modeled by performing Monte Carlo radiative transfer calculations of solar Lyman-α radiation, which is resonantly scattered on atomic hydrogen in Titan’s exosphere. Two different atomic hydrogen distribution models are applied to determine the best fitting density profile. One model is a static model that uses the Chamberlain formalism to calculate the distribution of atomic hydrogen throughout the exosphere, whereas the second model is a Particle model, which can also be applied to non-Maxwellian velocity distributions.The density distributions provided by both models are able to fit the measurements although both models differ at the exobase: best fitting exobase atomic hydrogen densities of n_H = (1.5 ± 0.5) × 10⁴ cm⁻³ and n_H = (7 ± 1) × 10⁴ cm⁻³ were found using the density distribution provided by both models, respectively. This is based on the fact that during the encounter, HDAC was sensitive to altitudes above about 3000 km, hence well above the exobase at about 1500 km. Above 3000 km, both models produce densities which are comparable, when taking into account the measurement uncertainty.The inferred exobase density using the Chamberlain profile is a factor of about 2.6 lower than the density obtained from Voyager 1 measurements and much lower than the values inferred from current photochemical models. However, when taking into account the higher solar activity during the Voyager flyby, this is consistent with the Voyager measurements. When using the density profile provided by the particle model, the best fitting exobase density is in perfect agreement with the densities inferred by current photochemical models.Furthermore, a best fitting exospheric temperature of atomic hydrogen in the range of T_H = (150-175) ± 25 K was obtained when assuming an isothermal exosphere for the calculations. The required exospheric temperature depends on the density distribution chosen. This result is within the temperature range determined by different instruments aboard Cassini. The inferred temperature is close to the critical temperature for atomic hydrogen, above which it can escape hydrodynamically after it diffused through the heavier background gas.     

The structure of Titan’s atmosphere from Cassini radio occultations

We present results from the two radio occultations of the Cassini spacecraft by Titan in 2006, which probed mid-southern latitudes. Three of the ingress and egress soundings occurred within a narrow latitude range, 31-34°S near the surface, and the fourth at 52.8°S. Temperature-altitude profiles for all four occultation soundings are presented, and compared with the results of the Voyager 1 radio occultation (Lindal, G.F., Wood, G.E., Hotz, H.B., Sweetnam, D.N., Eshleman, V.R., Tyler, G.L. [1983]. Icarus 53, 348-363), the HASI instrument on the Huygens descent probe (Fulchignoni, M. et al. [2005]. Nature 438, 785-791), and Cassini CIRS results (Flasar, F.M. et al. [2005]. Science 308, 975-978; Achterberg, R.K., Conrath, B.J., Gierasch, P.J., Flasar, F.M., Nixon, C.A. [2008b]. Icarus 194, 263-277). Sources of error in the retrieved temperature-altitude profiles are also discussed, and a major contribution is from spacecraft velocity errors in the reconstructed ephemeris. These can be reduced by using CIRS data at 300 km to make along-track adjustments of the spacecraft timing. The occultation soundings indicate that the temperatures just above the surface at 31-34°S are about 93 K, while that at 53°S is about 1 K colder. At the tropopause, the temperatures at the lower latitudes are all about 70 K, while the 53°S profile is again 1 K colder. The temperature lapse rate in the lowest 2 km for the two ingress (dawn) profiles at 31 and 33°S lie along a dry adiabat except within ∼200 m of the surface, where a small stable inversion occurs. This could be explained by turbulent mixing with low viscosity near the surface. The egress profile near 34°S shows a more complex structure in the lowest 2 km, while the egress profile at 53°S is more stable.     

Determining a tilt in Titan’s north-south albedo asymmetry from Cassini images

Analysis of Titan’s hemispheric brightness asymmetry from mapped Cassini images reveals an axis of symmetry that is tilted with respect to the rotational axis of the solid body. Twenty images taken from 2004 through 2007 show a mean axial offset of 3.8 ± 0.9° relative to the solid body’s pole, directed 79 ± 24° to the west of the sub-solar longitude. These values are consistent with recent measurements of an implied atmospheric spin axis determined from isothermal mapping by [Achterberg, R.K., Conrath, B.J., Gierasch, P.J., Flasar, F.M., Nixon, C.A., 2008. Icarus 197, 549-555].     

Chemical reactions in the Titan’s troposphere during lightning

In the lower troposphere of the Titan the temperature is about 90 K, therefore the chemical production of compounds in the CH₄/N₂ atmosphere is extremely slow. However, atmospheric electricity could provide conditions at which chemical reactions are fast. This paper is based on the assumption that there are lightning discharges in the Titan’s lower atmosphere. The temporal temperature profile of a gas parcel after lightning was calculated at the conditions of 10 km above the Titan’s surface. Using this temperature profile, composition of the after-lightning atmosphere was simulated using a detailed chemical kinetic mechanism consisting of 1829 reactions of 185 species. The main reaction paths leading to the products were investigated. The main products of lighting discharges in the Titan’s atmosphere are H₂, HCN, C₂N₂, C₂H₂, C₂H₄, C₂H₆, NH₃ and H₂CN. The annual production of these compounds was estimated in the Titan’s atmosphere.     

Probing Titan’s lower atmosphere with acousto-optic tuning

Narrow-band images of Titan were obtained in November 1999 with the NASA/GSFC- built acousto-optic imaging spectrometer (AImS) camera. This instrument utilizes a tunable filter element that was used within the 500- to 1050-nm range, coupled to a CCD camera system. The images were taken with the Mount Wilson 2.54-m (100 in.) Hooker telescope, which is equipped with a natural guide star adaptive optics system. We observed Titan at 830 and 890 nm and at a series of wavelengths across the 940-nm window in Titan’s atmosphere where the methane opacity is relatively low. We determined the absolute reflectivity (I/F) of Titan and fit the values at 940 nm to a Minnaert function at Titan’s equator and at −30° latitude (closer to the subsolar point) and obtained average values for the Minnaert limb-darkening slope, k, of 0.661 ± 0.007 and 0.775 ± 0.018, respectively. Comparison with models suggests that the equatorial value of k is consistent with rain removal of haze in the lower atmosphere. The higher value of k at −30° is consistent with the southern hemisphere being brighter than the equator. However, the fits are not unique. The data and models at 890 are consistent with no limb brightening or darkening at this wavelength either at the equator or at −30°.     

Latitudinal variations in Titan’s methane and haze from Cassini VIMS observations

We analyze observations taken with Cassini’s Visual and Infrared Mapping Spectrometer (VIMS), to determine the current methane and haze latitudinal distribution between 60°S and 40°N. The methane variation was measured primarily from its absorption band at 0.61 μm, which is optically thin enough to be sensitive to the methane abundance at 20-50 km altitude. Haze characteristics were determined from Titan’s 0.4-1.6 μm spectra, which sample Titan’s atmosphere from the surface to 200 km altitude. Radiative transfer models based on the haze properties and methane absorption profiles at the Huygens site reproduced the observed VIMS spectra and allowed us to retrieve latitude variations in the methane abundance and haze. We find the haze variations can be reproduced by varying only the density and single scattering albedo above 80 km altitude. There is an ambiguity between methane abundance and haze optical depth, because higher haze optical depth causes shallower methane bands; thus a family of solutions is allowed by the data. We find that haze variations alone, with a constant methane abundance, can reproduce the spatial variation in the methane bands if the haze density increases by 60% between 20°S and 10°S (roughly the sub-solar latitude) and single scattering absorption increases by 20% between 60°S and 40°N. On the other hand, a higher abundance of methane between 20 and 50 km in the summer hemisphere, as much as two times that of the winter hemisphere, is also possible, if the haze variations are minimized. The range of possible methane variations between 27°S and 19°N is consistent with condensation as a result of temperature variations of 0-1.5 K at 20-30 km. Our analysis indicates that the latitudinal variations in Titan’s visible to near-IR albedo, the north/south asymmetry (NSA), result primarily from variations in the thickness of the darker haze layer, detected by Huygens DISR, above 80 km altitude. If we assume little to no latitudinal methane variations we can reproduce the NSA wavelength signatures with the derived haze characteristics. We calculate the solar heating rate as a function of latitude and derive variations of ∼10-15% near the sub-solar latitude resulting from the NSA. Most of the latitudinal variations in the heating rate stem from changes in solar zenith angle rather than compositional variations.     

Meridional distribution of CH3C2H and C4H2 in Saturn’s stratosphere from CIRS/Cassini limb and nadir observations

Limb and nadir spectra acquired by Cassini/CIRS (Composite InfraRed Spectrometer) are analyzed in order to derive, for the first time, the meridional variations of diacetylene (C₄H₂) and methylacetylene (CH₃C₂H) mixing ratios in Saturn’s stratosphere, from 5 hPa up to 0.05 hPa and 80°S to 45°N. We find that the C₄H₂ and CH₃C₂H meridional distributions mimic that of acetylene (C₂H₂), exhibiting small-scale variations that are not present in photochemical model predictions. The most striking feature of the meridional distribution of both molecules is an asymmetry between mid-southern and mid-northern latitudes. The mid-southern latitudes are found depleted in hydrocarbons relative to their northern counterparts. In contrast, photochemical models predict similar abundances at north and south mid-latitudes. We favor a dynamical explanation for this asymmetry, with upwelling in the south and downwelling in the north, the latter coinciding with the region undergoing ring shadowing. The depletion in hydrocarbons at mid-southern latitudes could also result from chemical reactions with oxygen-bearing molecules.Poleward of 60°S, at 0.1 and 0.05 hPa, we find that the CH₃C₂H and C₄H₂ abundances increase dramatically. This behavior is in sharp contradiction with photochemical model predictions, which exhibit a strong decrease towards the south pole. Several processes could explain our observations, such as subsidence, a large vertical eddy diffusion coefficient at high altitudes, auroral chemistry that enhances CH₃C₂H and C₄H₂ production, or shielding from photolysis by aerosols or molecules produced from auroral chemistry. However, problems remain with all these hypotheses, including the lack of similar behavior at lower altitudes.Our derived mean mixing ratios at 0.5 hPa of (2.4 ± 0.3) × 10⁻¹⁰ for C₄H₂ and of (1.1 ± 0.3) × 10⁻⁹ for CH₃C₂H are compatible with the analysis of global-average ISO observations performed by Moses et al. (Moses, J.I., Bézard, B., Lellouch, E., Gladstone, G.R., Feuchtgruber, H., Allen, M. [2000a]. Icarus 143, 244-298). Finally, we provide values for the ratios [CH₃C₂H]/[C₂H₂] and [C₄H₂]/[C₂H₂] that can constrain the coupled chemistry of these hydrocarbons.     

Correlations between VIMS and RADAR data over the surface of Titan: Implications for Titan’s surface properties

We apply a multivariate statistical method to Titan data acquired by different instruments onboard the Cassini spacecraft. We have searched through Cassini/VIMS hyperspectral cubes, selecting those data with convenient viewing geometry and that overlap with Cassini/RADAR scatterometry footprints with a comparable spatial resolution. We look for correlations between the infrared and microwave ranges the two instruments cover. Where found, the normalized backscatter cross-section obtained from the scatterometer measurement, corrected for incidence angle, and the calibrated antenna temperature measured along with the scatterometry echoes, are combined with the infrared reflectances, with estimated errors, to produce an aggregate data set, that we process using a multivariate classification method to identify homogeneous taxonomic units in the multivariate space of the samples.In medium resolution data (from 20 to 100 km/pixel), sampling relatively large portions of the satellite’s surface, we find regional geophysical units matching both the major dark and bright features seen in the optical mosaic. Given the VIMS cubes and RADAR scatterometer passes considered in this work, the largest homogeneous type is associated with the dark equatorial basins, showing similar characteristics as each other on the basis of all the considered parameters.On the other hand, the major bright features seen in these data generally do not show the same characteristics as each other. Xanadu, the largest continental feature, is as bright as the other equatorial bright features, while showing the highest backscattering coefficient of the entire satellite. Tsegihi is very bright at 5 μm but it shows a low backscattering coefficient, so it could have a low roughness on a regional scale and/or a different composition. Another well-defined region, located southwest of Xanadu beyond the Tui Regio, seems to be detached from the surrounding terrains, being bright at 2.69, 2.78 and 5 μm but having a low radar brightness. In this way, other units can be found that show correlations or anti-correlations between the scatterometric response and the spectrophotometric behavior, not evident from the optical remote sensing data.     

The photochemical products of benzene in Titan’s upper atmosphere

The Cassini spacecraft detected benzene high in Titan’s atmosphere as well as the presence of large mass positive and negative ions. Previous work has suggested that these large mass ions could be composed of fused-ring polycyclic aromatic hydrocarbon compounds. These fused-ring PAHs, such as naphthalene and anthracene, are usually the result of high temperature processes that may not occur in Titan’s thin, cold, upper thermosphere. Here we suggest that a different class of aromatic compounds, polyphenyls, may be a better explanation of the data. Polyphenyls can grow to be large polymeric structures and could condense to form the aerosols seen in Titan’s cloud and hazes. They have similar properties to fused-ring PAHs (for example, electron affinity, ionization potential) and could be the negative ion species seen in the CAPS instrument data from the Cassini spacecraft.     

Titan’s cloud seasonal activity from winter to spring with Cassini/VIMS

Since Saturn orbital insertion in July 2004, the Cassini orbiter has been observing Titan throughout most of the northern winter season (October 2002–August 2009) and the beginning of spring, allowing a detailed monitoring of Titan’s cloud coverage at high spatial resolution with close flybys on a monthly basis. This study reports on the analysis of all the near-infrared images of Titan’s clouds acquired by the Visual and Infrared Mapping Spectrometer (VIMS) during 67 targeted flybys of Titan between July 2004 and April 2010.The VIMS observations show numerous sporadic clouds at southern high and mid-latitudes, rare clouds in the equatorial region, and reveal a long-lived cloud cap above the north pole, ubiquitous poleward of 60°N. These observations allow us to follow the evolution of the cloud coverage during almost a 6-year period including the equinox, and greatly help to further constrain global circulation models (GCMs). After 4 years of regular outbursts observed by Cassini between 2004 and 2008, southern polar cloud activity started declining, and completely ceased 1 year before spring equinox. The extensive cloud system over the north pole, stable between 2004 and 2008, progressively fractionated and vanished as Titan entered into northern spring. At southern mid-latitudes, clouds were continuously observed throughout the VIMS observing period, even after equinox, in a latitude band between 30°S and 60°S. During the whole period of observation, only a dozen clouds were observed closer to the equator, though they were slightly more frequent as equinox approached.We also investigated the distribution of clouds with longitude. We found that southern polar clouds, before disappearing in mid-2008, were systematically concentrated in the leading hemisphere of Titan, in particular above and to the east of Ontario Lacus, the largest reservoir of hydrocarbons in the area. Clouds are also non-homogeneously distributed with longitude at southern mid-latitudes. The n = 2-mode wave pattern of the distribution, observed since 2003 by Earth-based telescopes and confirmed by our Cassini observations, may be attributed to Saturn’s tides.Although the latitudinal distribution of clouds is now relatively well reproduced and understood by the GCMs, the non-homogeneous longitudinal distributions and the evolution of the cloud coverage with seasons still need investigation. If the observation of a few single clouds at the tropics and at northern mid-latitudes late in winter and at the start of spring cannot be further interpreted for the moment, the obvious shutdown of the cloud activity at Titan’s poles provides clear signs of the onset of the general circulation turnover that is expected to accompany the beginning of Titan’s northern spring. According to our GCM, the persistence of clouds at certain latitudes rather suggests a ‘sudden’ shift in near future of the meteorology into the more illuminated hemisphere. Finally, the observed seasonal change in cloud activity occurred with a significant time lag that is not predicted by our model. This may be due to an overall methane humidity at Titan’s surface higher than previously expected.