Phosphine absorption in the 5-μm window of Jupiter

Since the original suggestion by Gillett et al. (1969) it has generally been assumed that the region of partial transparency near 5 μm in Jupiter's atmosphere (the 5-μm window) is bounded by the v₄ NH₃ at 6.1 μm and the v₃ CH₄ band at 3.3 μm. New measurements of Jupiter and of laboratory phosphine (PH₃) samples show that PH₃ is a significant contributor to the continuum opacity in the window and in fact defines its short-wavelength limit. This has important implications for the use of 5-mu;m observations as a means to probe the deep atmospheric structure of Jupiter. The abundance of PH₃ which results from a comparison of Jovian and laboratory spectra is about 3 to 5 cm-am. This is five to eight times less than that found by Larson et al. [Astrophys. J. (1977) 211, 972–979] in the same spectral region, but is in good agreement with the result of Tokunaga et al. [Astrophys. J. (1979) 232, 603–615] from 10-μm observations.     

High resolution investigation of the 7 μm region of the ethane spectrum

Building upon previous studies, we re-investigated the ethane spectrum between 1330 and 1610 cm^?1 by combining unapodized spectra obtained at room temperature with a Bruker Fourier transform spectrometer (FTS) in Brussels and at 131 K with a Bruker FTS in Pasadena. The maximum optical path differences (MOPD) of the two datasets were 450 and 323.7 cm, corresponding to spectral resolutions of 0.0020 and 0.0028 cm^?1, respectively. Of the 15,000 lines observed, over 4592 transitions were assigned to the ν₆ (at 1379 cm^?1), ν₈ (at 1472 cm^?1), ν₄+ν₁₂ (at 1481 cm^?1) and 2ν₄+ν₉ (at 1388 cm^?1) bands, and another 1044 transitions were located for the ν₄+ν₈?ν₄ hot band (at 1472 cm^?1). Our new analysis included an improved implementation of the Hamiltonian calculation needed to interpret the complex spectral structures caused by numerous interactions affecting these four modes of vibration. From these results, we created the first line-by-line database containing the molecular parameters for over 20,000 ¹²C₂H₆ transitions at 7 μm.     

Cassini spectra and photometry 0.25-5.1 μm of the small inner satellites of Saturn

The nominal tour of the Cassini mission enabled the first spectra and solar phase curves of the small inner satellites of Saturn. We present spectra from the Visual Infrared Mapping Spectrometer (VIMS) and the Imaging Science Subsystem (ISS) that span the 0.25-5.1 μm spectral range. The composition of Atlas, Pandora, Janus, Epimetheus, Calypso, and Telesto is primarily water ice, with a small amount (∼5%) of contaminant, which most likely consists of hydrocarbons. The optical properties of the “shepherd” satellites and the coorbitals are tied to the A-ring, while those of the Tethys Lagrangians are tied to the E-ring of Saturn. The color of the satellites becomes progressively bluer with distance from Saturn, presumably from the increased influence of the E-ring; Telesto is as blue as Enceladus. Janus and Epimetheus have very similar spectra, although the latter appears to have a thicker coating of ring material. For at least four of the satellites, we find evidence for the spectral line at 0.68 μm that Vilas et al. [Vilas, F., Larsen, S.M., Stockstill, K.R., Gaffley, M.J., 1996. Icarus 124, 262-267] attributed to hydrated iron minerals on Iapetus and Hyperion. However, it is difficult to produce a spectral mixing model that includes this component. We find no evidence for CO₂ on any of the small satellites. There was a sufficient excursion in solar phase angle to create solar phase curves for Janus and Telesto. They bear a close similarity to the solar phase curves of the medium-sized inner icy satellites. Preliminary spectral modeling suggests that the contaminant on these bodies is not the same as the exogenously placed low-albedo material on Iapetus, but is rather a native material. The lack of CO₂ on the small inner satellites also suggests that their low-albedo material is distinct from that on Iapetus, Phoebe, and Hyperion.     

Hydrogen Dimer Features in the 2-μm Spectra of Saturn and Neptune

We report the detection of the (H₂)₂dimer in the atmospheres of Saturn and Neptune based on spectra of the fundamentalS₁(1) collision-induced band of H₂. The lines of this dimer are potentially useful for probing the (H₂)₂ortho–para ratio and its implications for atmospheric dynamical processes. We also report the detection of the (1–0)S₁(1) quadrupole absorption line of monomeric H₂in these spectra.     

Nonlinear evolution of 3D-inertial Alfvén wave and turbulent spectra in Auroral region

In the present paper, we have investigated nonlinear interaction of three dimensional (3D) inertial Alfvén wave and perpendicularly propagating magnetosonic wave for low β-plasma (β?m _e /m _i ). We have developed the set of dimensionless equations in the presence of ponderomotive nonlinearity due to 3D-inertial Alfvén wave in the dynamics of perpendicularly propagating magnetosonic wave. Stability analysis and numerical simulation has been carried out to study the effect of nonlinear coupling on the formation of localized structures and turbulent spectra, applicable to auroral region. The results reveal that the localized structures become more and more complex as the nonlinear interaction progresses. Further, we have studied the turbulent spectrum which follows spectral index (～k ^?3.57) at smaller scales. Relevance of the obtained results has been shown with the observations received by various spacecrafts like FAST, Hawkeye and Heos 2.     

High-resolution 3-μm spectra of Jupiter: Latitudinal spectral variations influenced by molecules, clouds, and haze

We present latitudinally-resolved high-resolution (R = 37,000) pole-to-pole spectra of Jupiter in various narrow longitudinal ranges, in spectral intervals covering roughly half of the spectral range 2.86-3.53 μm. We have analyzed the data with the aid of synthetic spectra generated from a model jovian atmosphere that included lines of CH₄, CH₃D, NH₃, C₂H₂, C₂H₆, PH₃, and HCN, as well as clouds and haze. Numerous spectral features of many of these molecular species are present and are individually identified for the first time, as are many lines of and a few unidentified spectral features. In both polar regions the 2.86-3.10-μm continuum is more than 10 times weaker than in spectra at lower latitudes, implying that in this wavelength range the single-scattering albedos of polar haze particles are very low. In contrast, the 3.24-3.53 μm the weak polar and equatorial continua are of comparable intensity. We derive vertical distributions of NH₃, C₂H₂ and C₂H₆, and find that the mixing ratios of NH₃ and C₂H₆ show little variation between equatorial and polar regions. However, the mixing ratios of C₂H₂ in the northern and southern polar regions are ∼6 and ∼3 times, respectively, less than those in the equatorial regions. The derived mixing ratio curves of C₂H₂ and C₂H₆ extend up to the 10⁻⁶ bar level, a significantly higher altitude than most previous results in the literature. Further ground-based observations covering other longitudes are needed to test if these mixing ratios are representative values for the equatorial and polar regions.     

Retrieval and tentative indentification of the 3 μm spectral feature in Titan's haze

Recently, an unidentified 3.3-3.4 μm feature found in the solar occultation spectra of the atmosphere of Titan observed by Cassini/VIMS was tentatively attributed to the C-H stretching mode of aliphatic hydrocarbon chains attached to large organic molecules, but without properly extracting the feature from adjacent influences of strong CH₄ and weak C₂H₆ absorptions (Bellucci et al., 2009). In this work, we retrieve the detailed spectral feature using a radiative transfer program including absorption and fluorescent emission of both molecules, as well as absorption and scattering by haze particles. The spectral features of the haze retrieved from the VIMS data at various altitudes are similar to each other, indicating relatively uniform spectral properties of the haze with altitude. However, slight deviations observed near 127 km and above 300 km suggest inhomogeneity at these altitudes. We find that the positions of the major spectral peaks occur at 3.33-3.37 μm, which are somewhat different from the typical 3.3 μm aromatic or 3.4 μm aliphatic C-H stretches usually seen in the spectra of dust particles of the interstellar medium and comets. The peaks, however, coincide with those of the solid state spectra of C₂H₆, CH₄, and CH₃CN; and a broad shoulder from 3.37 to 3.50 μm coincides with those of C₅H₁₂ and C₆H₁₂ as well as those of typical aliphatic C-H stretches. This result combined with high-altitude (∼1000 km) haze formation process recently reported by Waite et al. (2007) opens a new question on the chemical composition of the haze particles. We discuss the possibility that the 3 μm feature may be due to the solid state absorption bands of these molecules (or some other molecules) and we advocate additional laboratory measurements for the ices of hydrocarbon and nitrogen-bearing molecules present in Titan's atmosphere for the identification of this 3 μm feature.     

Equivalent widths of the 10-μm interstellar silicate feature and dust temperatures in infrared sources

For 22 infrared sources showing the 10-m silicate absorption band, the optical depths, dust temperatures and equivalent widths have been calculated for two assumed simple models.     

Is water-ice the carrier of the 3μm-absorption in infrared objects?

It is shown that Mie theory predictions of extinction for pure water-ice with the optical constant measured at 100 K do not fit in detail the observed ice absorption feature in infrared objects, although we attempt to explain the observations by considering size distribution and shape of the grains.In addition, based on a similarity between the ice band and the absorption band found in carbon stars, we feel it is questionable whether or not the ice band can really be attributed to the interstellar water-ice.     

The material of the interstellar dust and the surface of asteroids: A comparison of the spectral properties in the 0.3–1.1-μm range

From the data on bright stars of different spectral and luminosity classes from the 13-color photometry catalog, the selective extinction of light by the interstellar dust has been studied. The stars from the 1000-pc vicinity of the Sun were investigated. In the optical spectral range, the interstellar extinction curves show systematic deviations from the “λ^?1” law, which allows one to sort them into three types. The observed curves of the interstellar dust extinction were compared with the theoretical curves calculated from the reflectance spectra of the asteroids under the approximation of the Rayleigh particles. The calculated extinction curves for the surface material of D-type asteroids and the Tagish Lake carbonaceous chondrite agree rather well with the observed curves of the interstellar extinction of the first type.     

10-µm images and spectra of T Tauri stars

T Tauri stars are young stars usually surrounded by dusty disks similar to the one from which we believe our own Solar System formed. Most T Tauri stars exhibit a broad emission or absorption band between 7.5 and 13.5µm which is attributed to silicate grains in the circumstellar environment. We imaged three spatially resolved T Tauri binaries through a set of broadband filters which include the spectral region occupied by the silicate band. Two of these objects (T Tauri and Haro 6–10) are infrared companion systems in which one component is optically much fainter but contributes strongly in the infrared. Both infrared companions exhibit a deep silicate absorption which is not present in their primaries, indicating that they suffer very strong local extinction which may be due to an edge-on circumstellar disk or to a dense shell. We also took low resolution spectra of the silicate feature of two unresolved T Tauris to look for narrow features in the silicate band which would indicate the presence of specific minerals such as olivine. We observed GK Tau, for which Cohen and Witteborn (1985) reported a narrow emission feature at 9.7µm, but do not find evidence for this feature, and conclude that it is either time-dependent or an artifact of absorption by telluric ozone.Paper presented at the Conference onPlanetary Systems: Formation, Evolution, and Detection held 7–10 December, 1992 at CalTech, Pasadena, California, U.S.A.     

Photographic Observations of the Minor Planet (1) Ceres in Tashkent in 1951–1994

A procedure is described for remeasuring photographic plates with images of the minor planet (1) Ceres obtained in 1951–1994 with the Tashkent normal astrograph. To determine the observed spherical coordinates, the PPM catalog, based on the FK5 system, was used as a reference catalog. The calculation of the orbit of the minor planet (1) Ceres and the determination of the PPM zero-points and periodic errors on the basis of these observations yielded a unit weight error of 0.270. The derived coordinates and velocity components of (1) Ceres for J.D. = 2441600.5 are presented together with PPM zero-point and periodic-error-coefficient corrections. One of the results of the work is the high precision of the remeasured images, which makes it possible to use these observations, along with no less accurate observations of other selected minor planets, for determining corrections to the stellar coordinate system.     

Assessing the spatial variability of the ~3 μm OH/H2O absorption feature in CM2 carbonaceous chondrites

H₂O and OH are readily detected in hydrated minerals in CM chondrites via reflectance spectroscopy due to their characteristic vibration absorptions at infrared wavelengths. Previous spectroscopic work on bulk powdered CM chondrites has shown that spectral parameters, like the wavelength position of the “3 μm absorption feature,” vary systematically with the extent to which the samples have been aqueously altered. However, it is yet unclear how these spectral features may vary across an intact meteorite chip when measured at spatial scales smaller than that of the individual components of the meteorite. Here, we explore the spatial variability of this spectral feature and others on intact CM2 chips which, unlike powders, retain their petrologic and textural characteristics. We also model the modal mineralogy of the bulk meteorite powders and correlate this with key spectral features, demonstrating that microscope Fourier transform infrared spectroscopic mapping provides a powerful, rapid, and non-destructive technique for assessing compositional diversity and variations in water–rock interactions in chondritic planetary materials. In all CM2 chondrites studied here, we find that variations in the position, shape, and strength of the 3 μm absorption feature reveal a single chondrite can exhibit as much spectral variation as the entire suite of CM2 chondrites. The observed variations in the position and shape of the 3 μm feature within individual CM2 chondrite chips suggest a range of alteration products (e.g., Mg-rich to Fe-rich phyllosilicates) are present and record sub-mm scale variations in the amount and/or chemistry of the altering fluids. The samples having experienced the most progressive aqueous alteration show the least amount of variability in features like the 3 μm absorption band minimum position, whereas the least altered samples exhibit the most variability. We also find that the bulk spectral signatures in the least altered samples appear to be biased toward the spectral signatures of clasts versus matrix. By extension, asteroid reflectance spectra exhibiting 3 μm absorption features consistent with those measured here may be interpreted in a similar framework in which the spectrum of what may appear to be the least altered asteroids represents an average that belies the true diversity of mineralogy and chemistry of the body.     

Organic material and the 2.5–4 μm spectra of galactic sources

The spectra of galactic infrared sources over the waveband 2.5–4 m provide clear evidence for an organic composition of interstellar grains.     

The clustering of Lα absorption lines in the QSO spectra

For nine published high-resolution QSO spectra a correlation analysis of their L forest lines has been performed. The two-point correlation functions show some quasi-periodic structure of magnitude ||0.3. Their characteristic separation along the line-of-sight amounts to s ₀=3×10^–3 or to s ₀=5×10^–3 for =1 and 0.2, respectively. Especially the distribution of nearest neighbouring line positions in two close QSO pairs allows for the interpretation that the absorption clouds lie in sheet-like structures as predicted by the pancake theory. The correlation data contain some hints on metal absorbers within the forest of unidentified lines.     

Hα emission stars in the region of IC 1396

155 H emission stars not catalogued earlier have been detected with the 60/90/180 cm Schmidt telescope of Konkoly Observatory in a field of 19.5 square degrees centred on theHii region IC 1396.UBVR photohraphic magnitudes were obtained for most of them. Equatorial coordinates for the epoch 1950.0 as well as identification charts are given. Space distribution of the emission stars and their connection with the association Cepheus OB 2 are briefly discussed.     

3- to 14-μm Spectroscopy of Comet C/1999 T1 (McNaught-Hartley)

We report spectroscopy of Comet C/1991 T1 (McNaught-Hartley) at 3-13 μm on January 31.62 and February 1.7 2001 UT (delta=1.29 AU, r=1.40 AU) using the broadband array spectrograph system on the IRTF. The spectrum showed a silicate emission feature extending about 20% above the continuum. Two emission features at 10.3 and 11.2 μm appeared above the silicate band, the latter seemingly indicative of crystalline olivine. The 10.3-μm feature is only a 1-2 sigma detection but if real could indicate the presence of hydrated silicates. The color temperature at 8-13 μm was 260±10 K, approximately 6% above the blackbody radiative equilibrium temperature of 235 K. The magnitude at [N] was 3.13±0.02. On the second night, the comet had brightened slightly ([N]=2.98±0.02) and the two prominent emission features were absent, although the silicate emission feature maintained its trapezoidal shape with shoulders at 9.5 and 11.2 μm.     

The 10- and 20-μm interstellar absorption bands: Comparison with the infrared spectrum of the Nogoya meteorite

For submicrometer-sized particles of the carbonaceous chondrite Nogoya and, for comparison purposes, also of terrestrial chamosite, the mass absorption coefficients have been derived from laboratory spectra for the wavenumber range 250–1300 cm^–1. Using these data the expected spectrum of an infrared source has been calculated under simple model assumptions and compared with the observed flux from the infrared source OH 26.5+0.6. Although certain discrepancies are left in the 20-m region it is concluded that phyllosilicates, especially such occurring in carbonaceous chondrites, are interesting candidates for the material of interstellar grains.     

Outer Main Belt asteroids: Identification and distribution of four 3-μm spectral groups

This paper examines the distribution and the abundance of hydrated minerals (any mineral that contains H₂O or OH) on outer Main Belt asteroids spanning the 2.5 < a < 4.0 AU region. The hypothesis we are testing is whether planetesimals that accreted closer to the Sun experienced a higher degree of aqueous alteration. We would expect then to see a gradual decline of the abundance of hydrated minerals among the outer Main Belt asteroids with increasing heliocentric distance (2.5 < a < 4.0 AU). We measured spectra (0.8–2.5 μm and 1.9–4.1 μm) of 28 outer Main Belt asteroids using the SpeX spectrograph/imager at the NASA Infrared Telescope Facility (IRTF). We identified four groups on the basis of the shape and the band center of the 3-μm feature. The first group, which we call “sharp”, exhibits a sharp 3-μm feature, attributed to hydrated minerals (phyllosilicates). Most asteroids in this group are located in the 2.5 < a < 3.3 AU region. The second group, which we call “Ceres-like”, consists of 10 Hygiea and 324 Bamberga. Like Asteroid Ceres, these asteroids exhibit a 3-μm feature with a band center of 3.05 ± 0.01 μm that is superimposed on a broader absorption feature from ～2.8 to 3.7 μm. The third group, which we call “Europa-like”, includes 52 Europa, 31 Euphrosyne, and 451 Patientia. Objects in this group exhibit a 3-μm feature with a band center of 3.15 ± 0.01 μm. Both the Ceres-like and Europa-like groups are concentrated in the 2.5 < a < 3.3 AU region. The fourth group, which we call “rounded”, is concentrated in the 3.4 < a < 4.0 AU region. Asteroids in this group are characterized by a rounded 3-μm feature, attributed to H₂O ice. A similar rounded 3-μm feature was also identified in 24 Themis and 65 Cybele. Unlike the sharp group, the rounded group did not experience aqueous alteration. Of the asteroids observed in this study, 140 Siwa, a P-type, is the only one that does not exhibit a 3-μm feature. These results are important to constrain the nature and the degree of aqueous alteration in outer Main Belt asteroids.     

The source of widespread 3-μm absorption in Jupiter’s clouds: Constraints from 2000 Cassini VIMS observations

The Cassini flyby of Jupiter in 2000 provided spatially resolved spectra of Jupiter’s atmosphere using the Visual and Infrared Mapping Spectrometer (VIMS). A prominent characteristic of these spectra is the presence of a strong absorption at wavelengths from about 2.9 μm to 3.1 μm, previously noticed in a 3-μm spectrum obtained by the Infrared Space Observatory (ISO) in 1996. While Brooke et al. (Brooke, T.Y., Knacke, R.F., Encrenaz, T., Drossart, P., Crisp, D., Feuchtgruber, H. [1998]. Icarus 136, 1-13) were able to fit the ISO spectrum very well using ammonia ice as the sole source of particulate absorption, Sromovsky and Fry (Sromovsky, L.A., Fry, P.M. [2010]. Icarus 210, 211-229), using significantly revised NH₃ gas absorption models, showed that ammonium hydrosulfide (NH₄SH) provided a better fit to the ISO spectrum than NH₃, but that the best fit was obtained when both NH₃ and NH₄SH were present in the clouds. Although the large FOV of the ISO instrument precluded identification of the spatial distribution of these two components, the VIMS spectra at low and intermediate phase angles show that 3-μm absorption is present in zones and belts, in every region investigated, and both low- and high-opacity samples are best fit with a combination of NH₄SH and NH₃ particles at all locations. The best fits are obtained with a layer of small ammonia-coated particles (r ∼ 0.3 μm) overlying but often close to an optically thicker but still modest layer of much larger NH₄SH particles (r ∼ 10 μm), with a deeper optically thicker layer, which might also be composed of NH₄SH. Although these fits put NH₃ ice at pressures less than 500 mb, this is not inconsistent with the lack of prominent NH₃ features in Jupiter’s longwave spectrum because the reflectivity of the core particles strongly suppresses the NH₃ absorption features, at both near-IR and thermal wavelengths. Unlike Jupiter, Saturn lacks the broad 3-μm absorption feature, but does exhibit a small absorption near 2.965 μm, which resembles a similar jovian feature and suggests that both planets contain upper tropospheric clouds of sub-micron particles containing ammonia as a minor fraction.