Total particulate mass in Enceladus plumes and mass of Saturn’s E ring inferred from Cassini ISS images

The eclipse mosaic (PIA08329) of the Saturn system, taken on September 15, 2006 when Cassini was in Saturn’s shadow, contains numerous color images of the Enceladus plume and the E ring at phase angles ranging from 173° to 179°. These forward-scattering observations sample the diffraction peak for particle radii in the 1–5 μm range. The phase angle dependence and total brightness are sensitive indicators of the total mass of solid material in the plume. We fit the data with a variety of particle shapes and size distributions, and find that the median radius of the equivalent-volume sphere is 3.1 μm, with an uncertainty of ±0.5 μm. The total mass of particles in the plume is (1.45 ± 0.5) × 10⁵ kg. We have not considered variations with altitude in the particle size and shape distribution, and we leave that for another paper. We find that the brightness of the E ring varies with position in the orbit, not only because of the viewing geometry, e.g., variations in phase angle, but also because of some unknown intrinsic variability. The total mass of solid material in the E ring is (12 ± 5.5) × 10⁸ kg. For the plume, the production rate of particles – the mass per unit time leaving the vents is 51 ± 18 kg s⁻¹. We estimate that 9% of these particles are escaping from Enceladus, implying lifetimes of ∼8 years for the E ring particles. Based on three comparisons with vapor amounts from ultraviolet spectroscopy, the ice/vapor ratio is in the range 0.35–0.70. This high ratio poses a problem for theories in which particles form by condensation from the gas phase, and could indicate that particles are formed as spray from a liquid reservoir.     

Europa's neutral cloud: morphology and comparisons to Io

Ground based observations of sodium escaping from Europa suggest the presence of an extended cloud of neutrals orbiting Jupiter. Using a Monte Carlo model we show that the large scale morphology differs from the sodium cloud at Io. At Europa, the trailing cloud is brighter and more extended than the leading cloud. We then use our results to consider the morphology of Europa's oxygen cloud.     

A primordial origin for the atmospheric methane of Saturn’s moon Titan

The origin of Titan’s atmospheric methane is a key issue for understanding the origin of the saturnian satellite system. It has been proposed that serpentinization reactions in Titan’s interior could lead to the formation of the observed methane. Meanwhile, alternative scenarios suggest that methane was incorporated in Titan’s planetesimals before its formation. Here, we point out that serpentinization reactions in Titan’s interior are not able to reproduce the deuterium over hydrogen (D/H) ratio observed at present in methane in its atmosphere, and would require a maximum D/H ratio in Titan’s water ice 30% lower than the value likely acquired by the satellite during its formation, based on Cassini observations at Enceladus. Alternatively, production of methane in Titan’s interior via radiolytic reactions with water can be envisaged but the associated production rates remain uncertain. On the other hand, a mechanism that easily explains the presence of large amounts of methane trapped in Titan in a way consistent with its measured atmospheric D/H ratio is its direct capture in the satellite’s planetesimals at the time of their formation in the solar nebula. In this case, the mass of methane trapped in Titan’s interior can be up to ∼1300 times the current mass of atmospheric methane.     

How the Enceladus dust plume feeds Saturn’s E ring

Pre-Cassini models of Saturn’s E ring [Horányi, M., Burns, J., Hamilton, D., 1992. Icarus 97, 248-259; Juhász, A., Horányi, M., 2002. J. Geophys. Res. 107, 1-10] failed to reproduce its peculiar vertical structure inferred from Earth-bound observations [de Pater, I., Martin, S.C., Showalter, M.R., 2004. Icarus 172, 446-454]. After the discovery of an active ice-volcanism of Saturn’s icy moon Enceladus the relevance of the directed injection of particles for the vertical ring structure of the E ring was swiftly recognised [Juhász, A., Horányi, M., Morfill, G.E., 2007. Geophys. Res. Lett. 34, L09104; Kempf, S., Beckmann, U., Moragas-Klostermeyer, G., Postberg, F., Srama, R., Economou, T., Schmidt, J., Spahn, F., Grün, E., 2008. Icarus 193, 420-437]. However, simple models for the delivery of particles from the plume to the ring predict a too small vertical ring thickness and overestimate the amount of the injected dust.Here we report on numerical simulations of grains leaving the plume and populating the dust torus of Enceladus. We run a large number of dynamical simulations including gravity and Lorentz force to investigate the earliest phase of the ring particle life span. The evolution of the electrostatic charge carried by the initially uncharged grains is treated selfconsistently. Freshly ejected plume particles are moving in almost circular orbits because the Enceladus orbital speed exceeds the particles’ ejection speeds by far. Only a small fraction of grains that leave the Hill sphere of Enceladus survive the next encounter with the moon. Thus, the flux and size distribution of the surviving grains, replenishing the ring particle reservoir, differs significantly from the flux and size distribution of the particles freshly ejected from the plume. Our numerical simulations reproduce the vertical ring profile measured by the Cassini Cosmic Dust Analyzer (CDA) [Kempf, S., Beckmann, U., Moragas-Klostermeyer, G., Postberg, F., Srama, R., EconoDmou, T., Smchmidt, J., Spahn, F., Grün, E., 2008. Icarus 193, 420-437]. From our simulations we calculate the deposition rates of plume particles hitting Enceladus’ surface. We find that at a distance of 100 m from a jet a 10 m sized ice boulder should be covered by plume particles in 10⁵-10⁶ years.     

Plasma, plumes and rings: Saturn system dynamics as recorded in global color patterns on its midsize icy satellites

New global maps of the five inner midsize icy saturnian satellites, Mimas, Enceladus, Tethys, Dione, and Rhea, have been constructed in three colors (UV, Green and near-IR) at resolutions of 1 km/pixel. The maps reveal prominent global patterns common to several of these satellites but also three major color features unique to specific satellites or satellite subgroups. The most common features among the group are first-order global asymmetries in color properties. This pattern, expressed on Tethys, Dione and Rhea, takes the form of a ∼1.4-1.8 times enhancement in redness (expressed as IR/UV ratio) of the surface at the center of the trailing hemisphere of motion, and a similar though significantly weaker IR/UV enhancement at the center of the leading hemisphere. The peak in redness on the trailing hemisphere also corresponds to a known decrease in albedo. These double hemispheric asymmetries are attributable to plasma and E-ring grain bombardment on the trailing and leading hemispheres, respectively, for the outer three satellites Tethys, Dione and Rhea, whereas as E-ring bombardment may be focused on the trailing hemisphere of Mimas due to its orbital location interior to Enceladus. The maps also reveal three major deviations from these basic global patterns. We observe the previously known dark bluish leading hemisphere equatorial band on Tethys but have also discovered a similar band on Mimas. Similar in shape, both features match the surface patterns expected for irradiation of the surface by incident MeV electrons that drift in a direction opposite to the plasma flow. The global asymmetry on Enceladus is offset ∼40° to the west compared to the other satellites. We do not consider Enceladus in detail here, but the global distribution of bluish material can be shown to match the deposition pattern predicted for plume fallback onto the surface (Kempf, S., Beckmann, U., Schmidt, S. [2010]. Icarus 206, 446-457. doi:10.1016/j.icarus.2009.09.016). E-ring deposition on Enceladus thus appears to mask or prevent the formation of the lenses and hemispheric asymmetries we see on the other satellites. Finally, we observe a chain of discrete bluish splotches along the equator of Rhea. Unlike the equatorial bands of Tethys and Mimas, these splotches form a very narrow great circle ?10-km wide (north-to-south) and appear to be related to surface disruption, exposing fresh, bluish ice on older crater rims. This feature is unique to Rhea and may have formed by impact onto its surface of orbiting material.     

Obliquity tides do not significantly heat Enceladus

Recently, Tyler [Tyler, R.H., 2009. Geophys. Res. Lett. 36, L15205; Tyler, R., 2011. Icarus, 211, 770-779] proposed that the tide due to an obliquity of greater than 0.1° might drive resonant flow in a liquid ocean at Enceladus, and that dissipation of the ocean’s kinetic energy may be an alternate source for the observed global heat flux. While there is currently no measurement of Enceladus’ obliquity, dissipation is expected to drive the spin pole to a Cassini state. Under this assumption, we find that Enceladus should occupy Cassini state 1 and that the obliquity of Enceladus should be less than 0.0015° for values of the degree-2 gravity coefficient C_2,2 between 1.0 × 10⁻³ and 2.5 × 10⁻³. Unless there is a significant free obliquity or the gravity coefficient C_2,2 has been significantly overestimated, it is unlikely that obliquity-driven flow in a subsurface ocean is the source of the extreme heat on Enceladus.     

Magnetic portraits of Tethys and Rhea

The Cassini spacecraft made a single flyby each of Saturn's icy moons Tethys and Rhea in late 2005. The magnetic field observations from these flybys provide unique portraits of the magnetic properties of these moons. These are the first observations of interactions of these inert moons with the sub-magnetosonic plasma of Saturn's magnetosphere. Because the upstream field and plasma conditions are extremely stable, we are able to observe the interaction in great detail. One of the major findings of this study is that the region of plasma depletion is greatly elongated along the field direction in a sub-magnetosonic interaction. Based on the consideration of field aligned velocities of thermal ions, we show that overlapping particle shadow wings form downstream of an inert moon such that in each of the particle shadow wings, particles of specific field aligned velocities are depleted. Other major findings of this study are: (1) Tethys and Rhea are devoid of any internal magnetic field; (2) No induction generated field was observed, as expected because of the extremely weak primary inducing (time varying) field; (3) There is no appreciable mass-loading of Saturn's magnetosphere from Tethys and Rhea; (4) We predict that wave particles interactions would be generated that smooth out the phase space holes created by the moon/plasma interaction. These waves serve to isotropize the plasma distribution function.     

Enceladus: The likely dominant nitrogen source in Saturn's magnetosphere

The spatial distribution of N⁺ in Saturn's magnetosphere obtained from Cassini Plasma Spectrometer (CAPS) data can be used to determine the spatial distribution and relative importance of the nitrogen sources for Saturn's magnetosphere. We first summarize CAPS data from 15 orbits showing the spatial and energy distribution of the nitrogen component of the plasma. This analysis re-enforces our earlier discovery [Smith, H.T., Shappirio, M., Sittler, E.C., Reisenfeld, D., Johnson, R.E., Baragiola, R.A., Crary, F.J., McComas, D.J., Young, D.T., 2005. Geophys. Res. Lett. 32 (14). L14S03] that Enceladus is likely the dominant nitrogen source for Saturn's inner magnetosphere. We also find a sharp enhancement in the nitrogen ion to water ion ratio near the orbit of Enceladus which, we show, is consistent with the presence of a narrow Enceladus torus as described in [Johnson, R.E., Liu, M., Sittler Jr., E.C., 2005. Geophys. Res. Lett. 32. L24201]. The CAPS data and the model described below indicate that N⁺ ions are a significant fraction of the plasma in this narrow torus. We then simulated the combined Enceladus and Titan nitrogen sources using the CAPS data as a constraint. This simulation is an extension of the model we employed earlier to describe the neutral tori produced by the loss of nitrogen from Titan [Smith, H.T., Johnson, R.E., Shematovich, V.I., 2004. Geophys. Res. Lett. 31 (16). L16804]. We show that Enceladus is the principal nitrogen source in the inner magnetosphere but Titan might account for a fraction of the observed nitrogen ions at the largest distances discussed. We also show that the CAPS data is consistent with Enceladus being a molecular nitrogen source with a nitrogen to water ratio roughly consistent with INMS [Waite, J.H., and 13 colleagues, 2006. Science 311 (5766), 1419-1422], but out-gassing of other nitrogen-containing species, such as ammonia, cannot be ruled out.     

Titan’s atmosphere: An optimal gas mixture for aerosol production?

Here we present the first quantitative study of the gas to solid particle conversion in a Radio Frequency dusty plasma experiment simulating the complex atmospheric reactivity on Titan.Analogs of Titan’s aerosols have been produced in different N₂-CH₄ gas mixtures. Using in situ mass spectrometry, it has been found that, by varying the initial methane concentration, aerosols could be produced in methane steady state concentrations similar to Titan’s atmospheric conditions. In our experiment, an initial ∼5% methane concentration is necessary to ensure a ∼1.5% methane steady state concentration in the plasma.The tholin mass production rate has been quantified as a function of the initial methane concentration. A maximum was found for a steady state CH₄ concentration in agreement with Titan’s atmospheric CH₄ concentrations. At this maximum, the tholin C/N ratio is about 1.45 and the carbon gas to solid conversion yield is about 35%.We have modeled the mass production rate by a parabolic function, highlighting two competitive chemical regimes controlling the tholin production efficiency: an efficient growth process which is proportional to the methane consumption, and an inhibiting process which opposes the growth process and dominates it for initial methane concentrations higher than ∼5%. To explain these two opposite effects, we propose two mechanisms: one involving HCN patterns in the tholins for the growth process, and one involving the increasing amount of atomic hydrogen in the plasma as well as the increase in aliphatic contributions in the tholins for the inhibiting process. This study highlights new routes for understanding the chemical growth of the organic aerosols in Titan’s atmosphere.     

The photochemical products of benzene in Titan’s upper atmosphere

The Cassini spacecraft detected benzene high in Titan’s atmosphere as well as the presence of large mass positive and negative ions. Previous work has suggested that these large mass ions could be composed of fused-ring polycyclic aromatic hydrocarbon compounds. These fused-ring PAHs, such as naphthalene and anthracene, are usually the result of high temperature processes that may not occur in Titan’s thin, cold, upper thermosphere. Here we suggest that a different class of aromatic compounds, polyphenyls, may be a better explanation of the data. Polyphenyls can grow to be large polymeric structures and could condense to form the aerosols seen in Titan’s cloud and hazes. They have similar properties to fused-ring PAHs (for example, electron affinity, ionization potential) and could be the negative ion species seen in the CAPS instrument data from the Cassini spacecraft.     

Characteristics of the dust-plasma interaction near Enceladus’ South Pole

We present RPWS Langmuir probe data from the third Enceladus flyby (E3) showing the presence of dusty plasma near Enceladus’ South Pole. There is a sharp rise in both the electron and ion number densities when the spacecraft traverses through Enceladus plume. The ion density near Enceladus is found to increase abruptly from about 10² cm⁻³ before the closest approach to 10⁵ cm⁻³ just 30 s after the closest approach, an amount two orders of magnitude higher than the electron density. Assuming that the inconsistency between the electron and ion number densities is due to the presence of dust particles that are collecting the missing electron charges, we present dusty plasma characteristics down to sub-micron particle sizes. By assuming a differential dust number density for a range in dust sizes and by making use of Langmuir probe data, the dust densities for certain lower limits in dust size distribution were estimated. In order to achieve the dust densities of micrometer and larger sized grains comparable to the ones reported in the literature, we show that the power law size distribution must hold down to at least 0.03 μm such that the total differential number density is dominated by the smallest sub-micron sized grains. The total dust number density in Enceladus’ plume is of the order of 10² cm⁻³ reducing to 1 cm⁻³ in the E-ring. The dust density for micrometer and larger sized grains is estimated to be about 10⁻⁴ cm⁻³ in the plume while it is about 10⁻⁶-10⁻⁷ cm⁻³ in the E-ring. Dust charge for micron sized grains is estimated to be about eight thousand electron charges reducing to below one hundred electron charges for 0.03 μm sized grains. The effective dusty plasma Debye length is estimated and compared with inter-grain distance as well as the electron Debye length. The maximum dust charging time of 1.4 h is found for 0.03 μm sized grains just 1 min before the closest approach. The charging time decreases substantially in the plume where it is only a fraction of a second for 1 μm sized grains, 1 s for 0.1 μm sized grains and about 10 s for 0.03 μm sized grains.     

Nitrile gas chemistry in Titan’s atmosphere

This work presents the first study of the gaseous products resulting from the partial dissociation of methane and nitrogen in the PAMPRE experimental setup simulating Titan’s atmospheric chemistry.Using cryogenic trapping, the gaseous products generated from the chemical reactions occurring in the reactor have been trapped. Analyses of these products by gas chromatography coupled to mass spectrometry have allowed the detection and identification of more than 30 reaction products. Most of them are identified as nitrile species, accompanied by aliphatic hydrocarbons and a few aromatics compounds. The observed species are in agreement with the data from the recent Cassini-Huygens mission as well as from other laboratory setups capable of dissociating nitrogen and methane. This work emphasizes the probable importance of nitrogen-bearing compounds in the chemistry taking place in Titan’s atmosphere.Furthermore, a quantification of mono-nitriles with saturated alkyl chains has been performed relatively to hydrogen cyanide and shows a power law dependence in their concentration. This dependence is consistent with the Cassini-INMS data and Titan’s photochemical models.An empirical relationship has been extracted from our experimental data: [C_xH_2x−1N] = 100x⁻⁵, where x is the number of carbon atoms in the nitrile molecule. This relationship can be directly used in order to foretell the concentration of heavier nitriles induced by chemistry in Titan’s atmosphere.     

Titan’s cloud seasonal activity from winter to spring with Cassini/VIMS

Since Saturn orbital insertion in July 2004, the Cassini orbiter has been observing Titan throughout most of the northern winter season (October 2002–August 2009) and the beginning of spring, allowing a detailed monitoring of Titan’s cloud coverage at high spatial resolution with close flybys on a monthly basis. This study reports on the analysis of all the near-infrared images of Titan’s clouds acquired by the Visual and Infrared Mapping Spectrometer (VIMS) during 67 targeted flybys of Titan between July 2004 and April 2010.The VIMS observations show numerous sporadic clouds at southern high and mid-latitudes, rare clouds in the equatorial region, and reveal a long-lived cloud cap above the north pole, ubiquitous poleward of 60°N. These observations allow us to follow the evolution of the cloud coverage during almost a 6-year period including the equinox, and greatly help to further constrain global circulation models (GCMs). After 4 years of regular outbursts observed by Cassini between 2004 and 2008, southern polar cloud activity started declining, and completely ceased 1 year before spring equinox. The extensive cloud system over the north pole, stable between 2004 and 2008, progressively fractionated and vanished as Titan entered into northern spring. At southern mid-latitudes, clouds were continuously observed throughout the VIMS observing period, even after equinox, in a latitude band between 30°S and 60°S. During the whole period of observation, only a dozen clouds were observed closer to the equator, though they were slightly more frequent as equinox approached.We also investigated the distribution of clouds with longitude. We found that southern polar clouds, before disappearing in mid-2008, were systematically concentrated in the leading hemisphere of Titan, in particular above and to the east of Ontario Lacus, the largest reservoir of hydrocarbons in the area. Clouds are also non-homogeneously distributed with longitude at southern mid-latitudes. The n = 2-mode wave pattern of the distribution, observed since 2003 by Earth-based telescopes and confirmed by our Cassini observations, may be attributed to Saturn’s tides.Although the latitudinal distribution of clouds is now relatively well reproduced and understood by the GCMs, the non-homogeneous longitudinal distributions and the evolution of the cloud coverage with seasons still need investigation. If the observation of a few single clouds at the tropics and at northern mid-latitudes late in winter and at the start of spring cannot be further interpreted for the moment, the obvious shutdown of the cloud activity at Titan’s poles provides clear signs of the onset of the general circulation turnover that is expected to accompany the beginning of Titan’s northern spring. According to our GCM, the persistence of clouds at certain latitudes rather suggests a ‘sudden’ shift in near future of the meteorology into the more illuminated hemisphere. Finally, the observed seasonal change in cloud activity occurred with a significant time lag that is not predicted by our model. This may be due to an overall methane humidity at Titan’s surface higher than previously expected.     

Laboratory kinetics of C2H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.     

The oxidation state of hydrothermal systems on early Enceladus

The discovery of CO₂, CH₄, and N₂ in a plume at Enceladus provides useful clues about the chemistry and evolution of this moon of Saturn. Here, we use chemical equilibrium and kinetic calculations to estimate the oxidation state of hydrothermal systems on early Enceladus, with the assumption that the plume's composition was inherited from early hydrothermal fluids. Chemical equilibrium calculations are performed using the CO₂/CH₄ ratio in the plume, and kinetic calculations are conducted using equations from fluid dynamics and chemical kinetics. Our results suggest that chemical equilibrium between CO₂ and CH₄ would have been reachable at temperatures above ∼200 °C in hydrothermal systems. The oxidation state of the hydrothermal systems would have been close to the pyrrhotite-pyrite-magnetite (PPM) or fayalite-magnetite-quartz (FMQ) redox buffer (i.e., terrestrial-like) if the plume's CO₂ and CH₄ equilibrated in hydrothermal systems long ago. As for minerals, we suggest that iron metal would have been oxidized to magnetite by the escape of H₂ from the early satellite. Our calculations also indicate that, assuming CO₂ and CH₄ reached chemical equilibrium, magnetite would not have been oxidized to hematite in hydrothermal systems, perhaps due to insufficient H₂ escape. It is shown that, if Enceladus accreted as much NH₃ as comets contain, the presence of N₂ and deficiency of NH₃ in the plume can be understood in the context of chemical equilibrium in the C-N-O-H system. We conclude by proposing an evolutionary hypothesis in which the fairly oxidized nature of the plume can be explained by a brief episode of oxidation caused by short-lived radioactivity. These suggestions can be rigorously tested by acquiring gravity and isotopic data in the future.     

The three-dimensional structure of Saturn's equatorial jet at cloud level

The three-dimensional structure of Saturn's intense equatorial jet from latitudes 8° N to 20° S is revealed from detailed measurements of the motions and spectral reflectivity of clouds at visible wavelengths on high resolution images obtained by the Cassini Imaging Science Subsystem (ISS) in 2004 and early 2005. Cloud speeds at two altitude levels are measured in the near infrared filters CB2 and CB3 matching the continuum (effective wavelengths 750 and 939 nm) and in the MT2 and MT3 filters matching two methane absorption bands (effective wavelengths 727 and 889 nm). Radiative transfer models in selective filters covering an ample spectral range (250-950 nm) require the existence of two detached aerosol layers in the equator: an uppermost thin stratospheric haze extending between the pressure levels ∼20 and 40 mbar (tropopause level) and below it, a dense tropospheric haze-cloud layer extending between 50 mbar and the base of the ammonia cloud (between ∼1 and 1.4 bar). Individual cloud elements are detected and tracked in the tropospheric dense haze at 50 and 700 mbar (altitude levels separated by 142 km). Between latitudes 5° N and 12° S the winds increase their velocity with depth from 265 m s⁻¹ at the 50 mbar pressure level to 365 m s⁻¹ at 700 mbar. These values are below the high wind speeds of 475 m s⁻¹ measured at these latitudes during the Voyager era in 1980-1981, indicating that the equatorial jet has suffered a significant intensity change between that period and 1996-2005 or that the tracers of the flow used in the Voyager images were rooted at deeper levels than those in Cassini images.     

A laboratory model of Saturn’s North Polar Hexagon

A hexagonal structure has been observed at ∼76°N on Saturn since the 1980s (Godfrey, D.A. [1988]. Icarus 76, 335-356). Recent images by Cassini (Baines, K., Momary, T., Roos-Serote, M., Atreya, S., Brown, R., Buratti, B., Clark, R., Nicholson, P. [2007]. Geophys. Res. Abstr. 9, 02109; Baines, K., Momary, T., Fletcher, L., Kim, J., Showman, A., Atreya, S., Brown, R., Buratti, B., Clark, R., Nicholson, P. [2009]. Geophys. Res. Abstr. 11, 3375) have shown that the feature is still visible and largely unchanged. Its long lifespan and geometry has puzzled the planetary physics community for many years and its origin remains unclear. The measured rotation rate of the hexagon may be very close to that of the interior of the planet (Godfrey, D.A. [1990]. Science 247, 1206-1208; Caldwell, J., Hua, X., Turgeon, B., Westphal, J.A., Barnet, C.D. [1993]. Science 206, 326-329; Sánchez-Lavega, A., Lecacheux, J., Colas, F., Laques, P. [1993]. Science 260, 329-332), leading to earlier interpretations of the pattern as a stationary planetary wave, continuously forced by a nearby vortex (Allison, M., Godfrey, D.A., Beebe, R.F. [1990]. Science 247, 1061-1063). Here we present an alternative explanation, based on an analysis of both spacecraft observations of Saturn and observations from laboratory experiments where the instability of quasi-geostrophic barotropic (vertically uniform) jets and shear layers is studied. We also present results from a barotropic linear instability analysis of the saturnian zonal wind profile, which are consistent with the presence of the hexagon in the North Pole and absence of its counter-part in the South Pole. We propose that Saturn’s long-lived polygonal structures correspond to wavemodes caused by the nonlinear equilibration of barotropically unstable zonal jets.     

The near-IR spectrum of Titan modeled with an improved methane line list

We have obtained spatially resolved spectra of Titan in the near-infrared J, H and K bands at a resolving power of ∼5000 using the near-infrared integral field spectrometer (NIFS) on the Gemini North 8 m telescope. Using recent data from the Cassini/Huygens mission on the atmospheric composition and surface and aerosol properties, we develop a multiple-scattering radiative transfer model for the Titan atmosphere. The Titan spectrum at these wavelengths is dominated by absorption due to methane with a series of strong absorption band systems separated by window regions where the surface of Titan can be seen. We use a line-by-line approach to derive the methane absorption coefficients. The methane spectrum is only accurately represented in standard line lists down to ∼2.1 μm. However, by making use of recent laboratory data and modeling of the methane spectrum we are able to construct a new line list that can be used down to 1.3 μm. The new line list allows us to generate spectra that are a good match to the observations at all wavelengths longer than 1.3 μm and allow us to model regions, such as the 1.55 μm window that could not be studied usefully with previous line lists such as HITRAN 2008. We point out the importance of the far-wing line shape of strong methane lines in determining the shape of the methane windows. Line shapes with Lorentzian, and sub-Lorentzian regions are needed to match the shape of the windows, but different shape parameters are needed for the 1.55 μm and 2 μm windows. After the methane lines are modeled our observations are sensitive to additional absorptions, and we use the data in the 1.55 μm region to determine a D/H ratio of 1.77 ± 0.20 × 10⁻⁴, and a CO mixing ratio of 50 ± 11 ppmv. In the 2 μm window we detect absorption features that can be identified with the ν₅ + 3ν₆ and 2ν₃ + 2ν₆ bands of CH₃D.     

The ultraviolet reflectance of Enceladus: Implications for surface composition

The reflectance of Saturn’s moon Enceladus has been measured at far ultraviolet (FUV) wavelengths (115-190 nm) by Cassini’s Ultraviolet Imaging Spectrograph (UVIS). At visible and near infrared (VNIR) wavelengths Enceladus’ reflectance spectrum is very bright, consistent with a surface composed primarily of H₂O ice. At FUV wavelengths, however, Enceladus is surprisingly dark - darker than would be expected for pure water ice. Previous analyses have focused on the VNIR spectrum, comparing it to pure water ice (Cruikshank, D.P., Owen, T.C., Dalle Ore, C., Geballe, T.R., Roush, T.L., de Bergh, C., Sandford, S.A., Poulet, F., Benedix, G.K., Emery, J.P. [2005] Icarus, 175, 268-283) or pure water ice plus a small amount of NH₃ (Emery, J.P., Burr, D.M., Cruikshank, D.P., Brown, R.H., Dalton, J.B. [2005] Astron. Astrophys., 435, 353-362) or NH₃ hydrate (Verbiscer, A.J., Peterson, D.E., Skrutskie, M.F., Cushing, M., Helfenstein, P., Nelson, M.J., Smith, J.D., Wilson, J.C. [2006] Icarus, 182, 211-223). We compare Enceladus’ FUV spectrum to existing laboratory measurements of the reflectance spectra of candidate species, and to spectral models. We find that the low FUV reflectance of Enceladus can be explained by the presence of a small amount of NH₃ and a small amount of a tholin in addition to H₂O ice on the surface. The presence of these three species (H₂O, NH₃, and a tholin) appears to satisfy not only the low FUV reflectance and spectral shape, but also the middle-ultraviolet to visible wavelength brightness and spectral shape. We expect that ammonia in the Enceladus plume is transported across the surface to provide a global coating.