A spectroscopic comparison of HED meteorites and V-type asteroids in the inner Main Belt

V-type asteroids in the inner Main Belt (a < 2.5 AU) and the HED meteorites are thought to be genetically related to one another as collisional fragments from the surface of the large basaltic Asteroid 4 Vesta. We investigate this relationship by comparing the near-infrared (0.7-2.5 μm) spectra of 39 V-type asteroids to laboratory spectra of HED meteorites. The central wavelengths and areas spanned by the 1 and 2 μm pyroxene-olivine absorption bands that are characteristic of planetary basalts are measured for both the asteroidal and meteoritic data. The band centers are shown to be well correlated, however the ratio of areas spanned by the 1 and 2 μm absorption bands are much larger for the asteroids than for the meteorites. We argue that this offset in band area ratio is consistent with our currently limited understanding of the effects of space weathering, however we cannot rule out the possibility that this offset is due to compositional differences. Several other possible causes of this offset are discussed.Amongst these inner Main Belt asteroids we do not find evidence for non-Vestoid mineralogies. Instead, these asteroids seem to represent a continuum of compositions, consistent with an origin from a single differentiated parent body. In addition, our analysis shows that V-type asteroids with low inclinations (i < 6°) tend to have band centers slightly shifted towards long wavelengths. This may imply that more than one collision on Vesta’s surface was responsible for producing the observed population of inner belt V-type asteroids. Finally, we offer several predictions that can be tested when the Dawn spacecraft enters into orbit around Vesta in the summer of 2011.     

About mineral composition of geologic units in the northern hemisphere of Vesta

In the present paper we seek to understand the geologic diversity of units in the northern hemisphere of Vesta using HST observations (Binzel et al., 1997). First, we compare colors R(0.673 μm)/R(0.953 μm) and R(0.673 μm)/R(1.042 μm) of Vesta’s units with those of V-type asteroids (vestoids) as well as howardite, eucrite, and diogenite meteorites (HEDs). This comparative analysis showed that: (i) on the color-color plot, regions on Vesta are clustered whereas vestoids and HEDs cover a wide range in color; (ii) very few vestoids or HEDs fall into Vesta’s color region. This implies that Vesta’s units are more homogenous than most vestoids and HEDs examined here and material of the units are slightly different from that of vestoids and HEDs. Assuming reasonable choice of end-member materials, an optical model (Shkuratov et al., 1999) was used to simulate intimate mixtures of particles at the surface of Vesta’s units. Simulation of albedo, colors, and four-point spectra of Vesta’s units reveals that the rock-forming material is nearly equal for all units and has HED-like composition. Diversity of the units depends on the minor constituents such as chromite and a neutral phase. The western units contain more chromite and neutral phase than the eastern, consequently albedo of the western units is lower and their four-point spectra are flatter. Olivine and feldspar are also needed to give the best fit for the calculated and observed albedos and colors of Vesta’s units, but being in minor amount in Vesta’s rocks they play a secondary role in contributing to the optical properties of the units. Questions about the proportions of HED-like rock and the constituent called neutral phase remain open. Spectrophotometric studies of Vesta with both higher spatial and spectral resolution as expected from NASA’s Dawn mission are needed for resolving these problems.     

Ultraviolet spectroscopy of Asteroid (4) Vesta

We report a comprehensive review of the UV–visible spectrum and rotational lightcurve of Vesta combining new observations by Hubble Space Telescope and Swift Gamma-ray Burst Observatory with archival International Ultraviolet Explorer observations. The geometric albedos of Vesta from 220 nm to 953 nm are derived by carefully comparing these observations from various instruments at different times and observing geometries. Vesta has a rotationally averaged geometric albedo of 0.09 at 250 nm, 0.14 at 300 nm, 0.26 at 373 nm, 0.38 at 673 nm, and 0.30 at 950 nm. The linear spectral slope as measured between 240 and 320 nm in the ultraviolet displays a sharp minimum near a sub-Earth longitude of 20°, and maximum in the eastern hemisphere. This is consistent with the longitudinal distribution of the spectral slope in the visible wavelength. The photometric uncertainty in the ultraviolet is ∼20%, and in the visible wavelengths it is better than 10%. The amplitude of Vesta’s rotational lightcurves is ∼10% throughout the range of wavelengths we observed, but is smaller at 950 nm (∼6%) near the 1-μm band center. Contrary to earlier reports, we found no evidence for any difference between the phasing of the ultraviolet and visible/near-infrared lightcurves with respect to sub-Earth longitude. Vesta’s average spectrum between 220 and 950 nm can well be described by measured reflectance spectra of fine particle howardite-like materials of basaltic achondrite meteorites. Combining this with the in-phase behavior of the ultraviolet, visible, and near-infrared lightcurves, and the spectral slopes with respect to the rotational phase, we conclude that there is no global ultraviolet/visible reversal on Vesta. Consequently, this implies a lack of global space weathering on Vesta, as previously inferred from visible–near-infrared data.     

Global photometric properties of Asteroid (4) Vesta observed with Dawn Framing Camera

Dawn spacecraft orbited Vesta for more than one year and collected a huge volume of multispectral, high-resolution data in the visible wavelengths with the Framing Camera. We present a detailed disk-integrated and disk-resolved photometric analysis using the Framing Camera images with the Minnaert model and the Hapke model, and report our results about the global photometric properties of Vesta. The photometric properties of Vesta show weak or no dependence on wavelengths, except for the albedo. At 554 nm, the global average geometric albedo of Vesta is 0.38 ± 0.04, and the Bond albedo range is 0.20 ± 0.02. The bolometric Bond albedo is 0.18 ± 0.01. The phase function of Vesta is similar to those of S-type asteroids. Vesta’s surface shows a single-peaked albedo distribution with a full-width-half-max ∼17% relative to the global average. This width is much smaller than the full range of albedos (from ∼0.55× to >2× global average) in localized bright and dark areas of a few tens of km in sizes, and is probably a consequence of significant regolith mixing on the global scale. Rheasilvia basin is ∼10% brighter than the global average. The phase reddening of Vesta measured from Dawn Framing Camera images is comparable or slightly stronger than that of Eros as measured by the Near Earth Asteroid Rendezvous mission, but weaker than previous measurements based on ground-based observations of Vesta and laboratory measurements of HED meteorites. The photometric behaviors of Vesta are best described by the Hapke model and the Akimov disk-function, when compared with the Minnaert model, Lommel–Seeliger model, and Lommel–Seeliger–Lambertian model. The traditional approach for photometric correction is validated for Vesta for >99% of its surface where reflectance is within ±30% of global average.     

Constraints on Vesta's elemental composition: Fast neutron measurements by Dawn's gamma ray and neutron detector

Surface composition information from Vesta is reported using fast neutron data collected by the gamma ray and neutron detector on the Dawn spacecraft. After correcting for variations due to hydrogen, fast neutrons show a compositional dynamic range and spatial variability that is consistent with variations in average atomic mass from howardite, eucrite, and diogenite (HED) meteorites. These data provide additional compositional evidence that Vesta is the parent body to HED meteorites. A subset of fast neutron data having lower statistical precision show spatial variations that are consistent with a 400 ppm variability in hydrogen concentrations across Vesta and supports the idea that Vesta's hydrogen is due to long‐term delivery of carbonaceous chondrite material.     

First fragment of Asteroid 4 Vesta’s mantle detected

We report the first detection of a fragment of Asteroid (4) Vesta’s mantle in the near-Earth and main belt Vestoid populations. The near-infrared (NIR) spectrum of near-Earth Asteroid (237442) 1999 TA₁₀ shows band parameters, and inferred surface mineralogy, and pyroxene chemistry, similar to diogenite meteorites, which are believed to be fragments of (4) Vesta’s upper mantle. This strongly indicates that the impact that led to the excavation of 1999 TA₁₀ was deep enough to sample Vesta’s upper mantle and provides constraints on Vesta’s internal structure that can be verified by the Dawn mission.     

K‐Th‐Ti systematics and new three‐component mixing model of HED meteorites: Prospective study for interpretation of gamma‐ray and neutron spectra for the Dawn mission

Abstract– The Dawn spacecraft carries a gamma‐ray and neutron detector (GRaND), which will measure and map the abundances of selected elements on the surface of asteroid 4 Vesta. We compare the variability of moderately volatile/refractory incompatible element ratios (K/Th and K/Ti) in howardite, eucrite, and diogenite (HED) meteorites with those in other achondrite suites that represent asteroidal crusts, because these ratios may be accurately measured by GRaND and likely reflect initial chemical compositions of the HED parent body. The K/Th and K/Ti variations can differentiate HED meteorites from angrites and some unique eucrite‐like lithologies. The results suggest that K, Th, and Ti abundances determined from GRaND data could not only confirm that Vesta is the parent body of HED meteorites but might also allow recognition of as‐yet unsampled compositional terranes on Vesta. Besides the K‐Th‐Ti systematics study, we propose a new three‐component mixing model for interpretation of GRaND spectra, required because the spatial resolution of GRaND is coarser than the spectral (compositional) heterogeneity of Vesta’s surface. The mixing model uses abundances of K, Ti, Fe, and Mg that will be analyzed more accurately than other prospective GRaND‐analyzed elements. We examine propagated errors due to GRaND analytical uncertainties and intrinsic errors that stem from an assumption introduced into the mixing model. The error investigation suggests that the mixing model can adequately estimate not only the diogenite/eucrite mixing ratio but also the abundances of most major and minor elements within the GRaND propagated errors.     

Geochemistry and petrology of howardite Miller Range 11100: A lithologically diverse piece of the Vestan regolith

The howardite‐eucrite‐diogenite (HED) clan of meteorites, which most likely originate from the asteroid Vesta, provide an opportunity to combine in‐depth sample analysis with the comprehensive remote‐sensing data set from NASA's recent Dawn mission. Miller Range (MIL) 11100, an Antarctic howardite, contains diverse rock and mineral fragments from common HED lithologies (diogenites, cumulate eucrites, and basaltic eucrites). It also contains a rare pyroxferroite‐bearing lithology—not recognized in HED until recently—and rare Mg‐rich (Fo_86‐91) olivine crystals that possibly represent material excavated from the Vestan mantle. Clast components underwent different histories of thermal and impact metamorphism before being incorporated into this sample, reflecting the diversity in geological histories experienced by different parts of Vesta. The bulk chemical composition and petrography of MIL 11100 suggest that it is akin to the fragmental howardite meteorites. The strong lithological heterogeneity across this sample suggests that at least some parts of the Vestan regolith show heterogeneity on the mm‐scale. We combine the outcomes of this study with data from NASA's Dawn mission and hypothesize on possible source regions for this meteorite on the surface of Vesta.     

Grain size of the surface regolith of asteroid 4 Vesta estimated from its reflectance spectrum in comparison with HED meteorites

Abstract— The grain-size distribution of the regolith of asteroid 4 Vesta has been estimated by comparing its reflectance spectra (0.3–2.6 μm) with those of HED meteorites. The finest grain-size separate (<25 μm) of a particular howardite has a reflectance spectrum most similar to Vesta's. In order to better simulate Vesta's surface mineralogy, reflectance spectra of those finest HED meteorite powders were linearly combined, and Vesta's spectrum was scaled for the best fit between them. Both the albedo and the shape of reflectance spectrum of Vesta were well reproduced by regional mixtures of the finest (<25 μm) powders of HED meteorites. The result suggests the heterogeneity of Vesta's surface and provides an estimate of the visible reflectance of Vesta that is close to its IRAS albedo. Thus, this suggests that fine grains can be generated and retained by relatively small bodies (Vesta is approximately 500 km in diameter).     

Quantified mineralogical evidence for a common origin of 1929 Kollaa with 4 Vesta and the HED meteorites

In this paper, we present the first correlation of derived mineral abundances of V-class Asteroid 1929 Kollaa, 4 Vesta, and the HED meteorites. We demonstrate that 1929 Kollaa has a basaltic composition consistent with an origin within the crustal layer of 4 Vesta, and show a plausible genetic connection between Kollaa and the cumulate eucrite meteorites. These data support the proposed delivery mechanism of HED meteorites to the Earth from Vesta, and provide the first mineralogical constraint derived from the observation of a small V-class, Vesta family asteroid on the crustal thickness of 4 Vesta.     

Vesta's mineralogical composition as revealed by the visible and infrared spectrometer on Dawn

The Dawn spacecraft mission has provided extensive new and detailed data on Vesta that confirm and strengthen the Vesta–howardite–eucrite–diogenite (HED) meteorite link and the concept that Vesta is differentiated, as derived from earlier telescopic observations. Here, we present results derived by newly calibrated spectra of Vesta. The comparison between data from the Dawn imaging spectrometer—VIR—and the different class of HED meteorites shows that average spectrum of Vesta resembles howardite spectra. Nevertheless, the Vesta spectra at high spatial resolution reveal variations in the distribution of HED‐like mineralogies on the asteroid. The data have been used to derive HED distribution on Vesta, reported in Ammannito et al. (2013), and to compute the average Vestan spectra of the different HED lithologies, reported here. The spectra indicate that, not only are all the different HED lithologies present on Vesta, but also carbonaceous chondritic material, which constitutes the most abundant inclusion type found in howardites, is widespread. However, the hydration feature used to identify carbonaceous chondrite material varies significantly on Vesta, revealing different band shapes. The characteristic of these hydration features cannot be explained solely by infalling of carbonaceous chondrite meteorites and other possible origins must be considered. The relative proportion of HEDs on Vesta's surface is computed, and results show that most of the vestan surface is compatible with eucrite‐rich howardites and/or cumulate or polymict eucrites. A very small percentage of surface is covered by diogenite, and basaltic eucrite terrains are relatively few compared with the abundance of basaltic eucrites in the HED suite. The largest abundance of diogenitic material is found in the Rheasilvia region, a deep basin, where it clearly occurs below a basaltic upper crust. However, diogenite is also found elsewhere; although the depth to diogenite is consistent with one magma ocean model, its lateral extent is not well constrained.     

Vesta and the HED meteorites: Mid‐infrared modeling of minerals and their abundances

Abstract— We demonstrate that the use of an established spectral deconvolution algorithm with mid‐infrared spectral libraries of mineral separates of varying grain sizes is capable of identifying the known mineral compositions and abundances of a selection of howardite, eucrite, and diogenite (HED) meteorite samples. In addition, we apply the same technique to mid‐infrared spectral emissivity measurements of Vesta that have been obtained from Cornell's Mid‐Infrared Asteroid Spectroscopy (MIDAS) Survey and the Infrared Space Observatory (ISO). Each Vesta measurement was made over a different range of longitudes. Our spectral deconvolution results to the Vesta spectra corroborate that Vesta's surface is howardite or eucrite‐like in composition and heterogeneous across its surface. The spectral fits produced by the linear deconvolution algorithm yields good results for the HED samples of known composition, thus giving us a high degree of confidence that our results for Vesta are valid.     

The origin of Vesta’s crust: Insights from spectroscopy of the Vestoids

High quality VNIR spectra of 15 Vestoids, small asteroids that are believed to originate from Vesta, were collected and compared to laboratory spectra and compositional data for selected HED meteorites. A combination of spectral parameters such as band centers, and factors derived from Modified Gaussian Model fits (band centers, band strengths, calculation of the low to high-Ca pyroxene ratio) were used to establish if each Vestoid appeared most like eucrite or diogenite material, or a mixture of the two (howardite). This resulted in the identification of the first asteroid with a ferroan diogenite composition, 2511 Patterson. This asteroid can be used to constrain the size of diogenite magma chambers within the crust of Vesta. The Vestoids indicate that both large-scale homogeneous units (>5 km) and smaller-scale heterogeneity (<1 km) exist on the surface of Vesta, as both monomineralogic (eucrite or diogenite material alone) and mixed (both eucrite and diogenite) spectra are observed. The small-scale of the variation observed within the Vestoid population is predicted by the partial melting model, which has multiple intrusions penetrating into the crust of Vesta. It is much more difficult to reconcile the observations here with the magma ocean model, which would predict much more homogeneous layers on a large-scale both at the surface and with depth.     

Mid-infrared lightcurve of Vesta

We present a thermal mid-infrared lightcurve of Asteroid 4 Vesta and use this to infer variations in thermophysical properties over the surface. Vesta was observed over three nights during the May 2007 opposition with the Infrared Telescope Facility on Mauna Kea. Mid-infrared observations are compared to a model based on the Standard Thermal Model which is draped over a Vesta shape model derived from Hubble Space Telescope observations.A visible lightcurve with similar aspect was used to estimate the albedo as Vesta rotates. Shape and albedo can explain some of the features observed in the mid-infrared lightcurve. However, variations in the thermophysical properties, such as the “beaming parameter,” over Vesta’s surface are required to completely explain the observations.In order to match the mid-infrared magnitudes observed of Vesta, a beaming parameter of ∼0.862 is required which is higher than other Main Belt Asteroids such as Ceres and Pallas (0.756), indicating a smoother and/or rockier surface on Vesta. Variations in the beaming parameter with longitude are invoked to reproduce the observed thermal variations. Surface materials with relatively high beaming values, indicating a smoother and/or rockier surface, in the eastern hemisphere of Vesta coincide with locations where impact excavations may have produced surfaces that are younger and brighter relative to the western hemisphere.     

Lithologic mapping of HED terrains on Vesta using Dawn Framing Camera color data

The surface composition of Vesta, the most massive intact basaltic object in the asteroid belt, is interesting because it provides us with an insight into magmatic differentiation of planetesimals that eventually coalesced to form the terrestrial planets. The distribution of lithologic and compositional units on the surface of Vesta provides important constraints on its petrologic evolution, impact history, and its relationship with vestoids and howardite‐eucrite‐diogenite (HED) meteorites. Using color parameters (band tilt and band curvature) originally developed for analyzing lunar data, we have identified and mapped HED terrains on Vesta in Dawn Framing Camera (FC) color data. The average color spectrum of Vesta is identical to that of howardite regions, suggesting an extensive mixing of surface regolith due to impact gardening over the course of solar system history. Our results confirm the hemispherical dichotomy (east‐west and north‐south) in albedo/color/composition that has been observed by earlier studies. The presence of diogenite‐rich material in the southern hemisphere suggests that it was excavated during the formation of the Rheasilvia and Veneneia basins. Our lithologic mapping of HED regions provides direct evidence for magmatic evolution of Vesta with diogenite units in Rheasilvia forming the lower crust of a differentiated object.     

Modeling the early evolution of Vesta

The early evolution of the asteroid Vesta has been extensively studied because of the availability of relevant data, especially important new studies of HED meteorites which originated from Vesta and the Dawn mission to Vesta in 2011–2012. These studies have concluded that an early melting episode led to the differentiation of Vesta into crust, mantle, and core. This melting episode is attributed to the decay of ²⁶Al, which has a half‐life of 7.17 × 10⁵ yr. This heating produced a global magma ocean. Surface cooling of this magma ocean will produce a solid crust. In this paper, we propose a convective heat‐transfer mechanism that effectively cools the asteroid when the degree of melting reaches about 50%. We propose that a cool solid surface crust, which is gravitationally unstable, will founder into the solid–liquid mix beneath and will very effectively transfer heat that prevents further melting of the interior. In this paper, we quantify this process. If Vesta had a very early formation, melting would commence at an age of about 1,30,000 yr, and solidification would occur at an age of about 10 Myr. If Vesta formed with a time delay greater than about 2 Myr, no melting would have occurred. An important result of our model is that the early melting episode is restricted to the first 10 Myr. This result is in good agreement with the radiometric ages of the HED meteorites.     

Compositional heterogeneity of Asteroid 4 Vesta’s southern hemisphere: Implications for the Dawn mission

High signal-to-noise, rotationally-resolved spectra of Asteroid 4 Vesta’s southern hemisphere from the 2007 opposition were used to constrain its compositional and mineralogical variations. The spectra were rotationally-phased using closely timed HST observations of Vesta by Li et al. (Li, J.-Y., McFadden, L.A., Thomas, P.C., Mutchler, M.J., Parker, J.Wm., Young, E.F., Russell, C.T., Sykes, M.V., Schmidt, B.E. [2010]. Icarus 208, 238–251). The average surface of Vesta’s southern hemisphere is analogous to a howardite or polymict eucrite assemblage similar to the northern hemisphere, although the band parameters are distinctly shifted towards the diogenite zone on the Band–Band plot. A few distinct compositional units were detected and they might be related to albedo features detected by Hubble Space Telescope (Li et al., 2010). We have identified two compositionally distinct regions overlaying the background surface. The first unit is a polymict eucrite and/or low-Ca eucrite compositional unit at 143° longitude that border the eucrite zone on the Band–Band plot and the second is a diogenite unit at 159°. While we did not detect any distinct olivine units as suggested by Gaffey (Gaffey, M.J. [1997]. Icarus 127, 130–157), we cannot rule out the possibility of smaller olivine-rich units that are below the detection limit of the instrumentation we used. Based on the analysis and the limitations of the data, we do not suggest that Vesta’s surface is olivine-free. Mean pyroxene chemistry estimates for both hemispheres broadly agree with one another (to within one-sigma) with the northern hemisphere ferrosilite (Fs) and wollastonite (Wo) values being slightly higher than southern hemisphere.     

Cosmic-ray exposure ages of diogenites and the recent collisional history of the howardite,eucrite and diogenite parent body/bodies

Abstract— We determined the cosmic-ray exposure age of 20 diogenites from measured cosmogenic noble gas isotopes and calculated production rates of ³He, ²¹Ne and ³⁸Ar. The production rates were calculated on the basis of the measured chemical composition and the cosmogenic ²²Ne/²¹Ne ratio of each sample. The shielding conditions of each sample were also checked on the basis of the measured ¹⁰Be and ²⁶AI concentrations. The exposure ages range from 6 to 50 Ma but do not form a continuous distribution: ten ages cluster at 21–25 Ma and four at 35–42 Ma. The two diogenite clusters coincide with the 22 Ma and 38 Ma peaks in the exposure age distribution of eucrites and howardites. After the selection from literature data of 32 eucrites and 11 howardites with reliable ages, we find a total of 23 howardite, eucrite and diogenite (HED) group meteorites at 20–25 Ma and 10 at 35–42 Ma. The shape of the two peaks is consistent with single impact events, and random number statistics show that they are statistically significant at the 99% level. Altogether, this provides strong evidence for two major impact events 22 Ma and 39 Ma ago. Although these two events can explain more than half of all HED exposure ages, it takes at least five impact events to explain all ages <50 Ma. An impact frequency of one per 10 Ma corresponds to projectiles of at least 2–4 km in diameter for Vesta and of 60–300 m for the 100× smaller Vesta-derived “vestoids.” Based on the HED exposure-age distribution, the size distribution of the main-belt asteroids and the difference in size between Vesta and the kilometer size vestoids, we favor Vesta as the major source of HED meteorites, although some of the meteorites may have been ejected from the vestoids rather than directly from Vesta.     

Geochemistry of 4 Vesta based on HED meteorites: Prospective study for interpretation of gamma ray and neutron spectra for the Dawn mission

Abstract— Asteroid 4 Vesta, believed to be the parent body of the howardite, eucrite, and diogenite (HED) meteorites, will be investigated by the Dawn orbiting spacecraft. Dawn carries a gamma ray and neutron detector (GRaND) that will measure and map some major‐ and trace‐element abundances. Drawing on HED geochemistry, we propose a mixing model that uses element ratios appropriate for the interpretation of GRaND data. Because the spatial resolution of GRaND is relatively coarse, the analyzed chemical compositions on the surface of Vesta will likely reflect mixing of three endmember components: diogenite, cumulate eucrite, and basaltic eucrite. Reliability of the mixing model is statistically investigated based on published whole‐rock data for HED meteorites. We demonstrate that the mixing model can accurately estimate the abundances of all the GRaND‐analyzed major elements, as well as of minor elements (Na, Cr, and Mn) not analyzed by this instrument. We also show how a similar mixing model can determine the modal abundance of olivine, and we compare estimated and normative olivine data for olivine‐bearing diogenites. By linking the compositions of well‐analyzed HED meteorites with elemental mapping data from GRaND, this study may help constrain the geological context for HED meteorites and provide new insight into the magmatic evolution of Vesta.     

Mineralogy of HED Meteorites Using the Modified Gaussian Model

The correlation between specific meteorites and asteroids is a long-standing problem. The best-known correlation seems to be the HED–Vesta, although several problems still remain to be solved. We report the spectral reflectance analysis (0.4–2.5 μm) of a set of HED meteorites, taken from the RELAB database and three V-type asteroids, taken from MIT-UH-IRTF Joint Campaign for NEO Reconnaissance. We used the Modified Gaussian Model to fit the spectra to a series of overlapping, modified Gaussian absorptions. The fitted individual bands are validated against established laboratory calibrations. With spectral resolution extending to the near-infrared, we are able to resolve the presence of both high-calcium pyroxene (HCP) and low-calcium pyroxene (LCP) and, thus, use the HCP/(HCP + LCP) ratios to remotely trace igneous processing on the parent asteroids. A search of this mineral provides a useful probe of differentiation. The high HCP/(HCP + LCP) ratios found require extensive differentiation of these asteroids and/or their primordial parent body. The degree of melting obtained for the eucrites, using the former ratio, is comparable with that obtained for all V-type asteroids here analyzed, suggesting a comparable geologic history.