Are the clouds of venus sulfuric acid?

Water solutions of sulfuric acid, containing about 75% H₂SO₄ by weight, have a refractive index within 0.01 of the values deduced from polarimetric observations of the Venus clouds. These solutions remain liquid at the cloud temperature, thus explaining the spherical shape of the cloud particles (droplets). The equilibrium vapor pressure of water above such solutions is 0.01 that of liquid water or ice, which accounts for the observed dryness of the cloud region. Furthermore, H₂SO₄ solutions of such concentration have spectra very similar to Venus in the 8–13 μm region; in particular, they explain the 11.2 μm band. Cold sulfuric acid solutions also seem consistent with Venus spectra in the 3–4 μm region. The amount of acid required to make the visible clouds is quite small, and is consistent with both the cosmic abundance of sulfur and the degree of out-gassing of the planet indicated by known atmospheric constituents. Sulfuric acid occurs naturally in volcanic gases, along with known constituents of the Venus atmosphere such as CO₂, HCl, and HF ; it is produced at high temperature by reactions between these gases and common sulfate rocks. The great stability and low vapor pressure of H₂SO₄ and its water solutions explain the lack of other sulfur compounds in the atmosphere of Venus—a lack that is otherwise puzzling.Sulfuric acid precipitation may explain some peculiarities in Venera and Mariner data. Because sulfuric acid solutions are in good agreement with the Venus data, and because no other material that has been proposed is even consistent with the polarimetric and spectroscopic data, H₂SO₄ must be considered the most probable constituent of the Venus clouds.     

Sulfuric acid vapor and other cloud-related gases in the Venus atmosphere: Abundances inferred from observed radio opacity

Laboratory measurements of the microwave opacity of gaseous sulfuric acid under Venus atmospheric conditions indicate that it is an exceptionally strong absorber. They also suggest that its absorptivity has a surprisingly weak dependence on radio frequency, as compared with other common gaseous absorbers. Initial theoretical studies also indicate a large absorptivity and weak frequency dependence, although the measured opacity is several times the computed value, presumably due to deviations from Van Vleck-Weisskopf theory for pressures near and above about 1 atm. The absorbing characteristics of sulfuric acid vapor appear to reconcile what had been thought to be an inconsistency among measurements and deductions concerning the constituents of the atmosphere of Venus, and radio occultation, radar reflection, and radio emission measurements of its opacity. These and previous laboratory measurements of sulfur dioxide, water vapor, and carbon dioxide are used to model relative contributions to opacity as a function of height, in a way that is consistent with observations of the constituents and absorbing properties of the atmosphere. We conclude that sulfuric acid vapor is likely to be the principal microwave absorber in the 30- to 50-km-altitude range of the middle atmosphere of Venus. It would need to have a mixing ratio there of about 35 to 90 ppm if it were the sole absorber. Carbon dioxide, the predominant atmospheric gas, is the main absorber below about 30 km, while sulfur dioxide is an important but secondary absorber in both regions. Water vapor and cloud particulates appear to be only minor contributors to the total opacity. While gaseous sulfuric acid has not been directly measured in any of the in situ probe experiments (due to particular instrumental limitations), its presence at an abundance of the deduced order of magnitude is implied by these and other observations. We suggest that improved radio occultation measurements, in conjuction with high-resolution microwave emission observations and more detailed laboratory studies, could provide important data for investigating the sulfur compound chemistry in the atmosphere of Venus, and that the techniques and results may have application to the study of atmospheric conditions associated with acid rain on Earth.     

The composition and vertical structure of the lower cloud deck on Venus

The opportunity to determine the planetwide temperature and cloud structure of Venus using radio occultation techniques arose with Pioneer Venus. Amplitude and Doppler data provided by the radio occultation experiment offered a unique and powerful means of examining the atmospheric properties in the lower cloud region.Absorption due to gaseous components of the atmosphere was subtracted from the measured absorption coefficient profiles before they were used to compute cloud mass contents. This absorption was found to represent a small part of the total absorption, depending on the latitude. In the main cloud deck, gaseous absorption contributes 10 to 20%, however, at the bottom of the detected absorption layer the sulfuric acid vapor contributes up to 100% due to increased vapor pressures. The clouds are the primary contributing absorbers in the 1- to 3-bar level of the Venus atmosphere. Below about 3 bars, depending on the latitude, absorption due to sulfuric acid vapor dominates.If a cloud particle model consisting of a solid nonabsorbing dielectric sphere with a concentric liquid sulfuric acid coating is invoked, the absorptivity of the particles increases from that of a pure sulfuric acid liquid sphere, and the mass content derived from the absorption coefficient profiles decreases. As the ratio of the core radius to the total radius (q) increases, absorption increases by more than a factor of 10 for high values of q. In the case of pure sulfuric acid droplets, the conductivity is sufficiently high that some of the field is excluded from the interior of the droplet thereby reducing the absorption. When a dielectric core of nonabsorbing material is introduced, the surface charge density is reduced and the absorption increases.The mass contents for all orbits in the equatorial region of Venus were calculated using values of q from 0 to 1. The resulting profiles match the probe mass content profiles at similar locations when a q of 0.97 is chosen.The wavelength dependence of the absorption for the spherical shell model varies with q from 1/λ² for pure liquid to λ^0.2 for a large core. A q of from 0.96 to 0.98 results in a wavelength dependence of 1/λ^1.0 to 1/λ^1.4 which matches the radio occultation absorption wavelength dependence and the microwave opacity wavelength dependence.Mass content profiles using a q of 0.97 were determined for occultations in the polar, collar, midlatitudinal, and equatorial regions assuming q remains constant over the planet. The results show considerable variability in both the level and the magnitude of the lower cloud deck. The cloud layer is lowest in altitude in the polar region. This might be expected as the temperature profile is cooler in the polar region than over the rest of the planet. The mass content is greatest in the polar and collar regions; however, many of the collar profiles were cut off due to fluctuations resulting from increased turbulence in the collar region. The mass contents are least dense in the midlatitude regions. There is a sharp lower boundary at about 1.5 bars in the equatorial and midlatitude regions and at about 2.5 bars in the polar region. Measurements made by the Particle Size Spectrometer and nephelometers also showed sharp lower cloud boundaries at this level.     

Initiation of Run-Out Flows on Venus by Oblique Impacts

A hypervelocity oblique impact results in a downrange-moving vapor cloud, a significant fraction of which is derived from the projectile. Since the vapor cloud expands to great extent and becomes very tenuous quickly on a planet with a thin or no atmosphere, it does not leave a well-defined geologic expression. The thick atmosphere of Venus, however, is sufficient to contain such a rapidly expanding vapor cloud. As a result of atmospheric interactions, impact vapor condenses and contributes to run-out flows around craters on Venus. Previous results of both laboratory experiments and simple semi-analytical calculations indicate that an impact-vapor origin can account for the morphology of run-out flows on Venus most consistently. However, the detailed dynamics and geologic record of downrange-moving impact vapor clouds in Venus's atmosphere are not understood quantitatively. To approach these problems, we carried out two-dimensional hydrocode calculations. Parametric studies of these hydrocode calculations yield simple scaling laws for both the total downrange travel distance and the final temperature of impact vapor clouds under conditions on Venus. Under typical impact conditions, impact vapor clouds travel downrange more than a crater radius prior to the completion of crater formation. Furthermore, the scaling law for the total travel distance is compared with observations for the downrange offset of the source regions of run-out flows around oblique craters. The results of this comparison suggest that energy/momentum-partitioning processes other than pure shock coupling may play important roles in hypervelocity impact at planetary scales. The results of hydrocode calculations also indicate that the terminal temperature of the impact vapor is close to the condensation temperatures of silicates, suggesting that two scenarios are possible for expected range of impact conditions: 1. Impact vapor condenses and forms run-out flows. 2. Impact vapor fails to condense and leaves no run-out flows. Consequently, natural variation in impact angle, velocity, and projectile composition may account for partial occurrence of run-out flows around impact craters on Venus.     

Venus: Mesospheric hazes of ice,dust, and acid aerosols

We speculate on the origin and physical properties of haze in the upper atmosphere of Venus. It is argued that at least four distinct types of particles may be present. The densest and lowest haze, normally seen by spacecraft, probably consists of a submicron sulfuric acid aerosol which extends above the cloud tops (at ～70 km) up to ～80 km; this haze represents an extension of the upper cloud deck. Measurements of the temperature structure between 70 and 120 km indicate that two independent water ice layers may occasionally appear. The lower one can form between 80 and 100 km and is probably the detached haze layer seen in high-contrast limb photography. This ice layer is likely to be nucleated on sulfuric acid aerosols, and is analogous to the nacreous (stratospheric) clouds on Earth. At the Venus “mesopause” near 120 km, temperatures are frequently cold enough to allow ice nucleation on meteoric dust or ambient ions. The resulting haze (which is analogous to noctilucent clouds on Earth) is expected to be extremely tenous, and optically invisible. On both Earth and Venus, meteoric dust is present throughout the upper atmosphere and probably has similar properties.     

H2O-H2SO4 system in Venus' clouds and OCS, CO, and H2SO4 profiles in Venus' troposphere

A coupled problem of diffusion and condensation is solved for the H2SO4-H2O system in Venus' cloud layer. The position of the lower cloud boundary and profiles of the H2O and H2SO4 vapor mixing ratios and of the H2O/H2SO4 ratio of sulfuric acid aerosol and its flux are calculated as functions of the column photochemical production rate of sulfuric acid, phi H2SO4. Variations of the lower cloud boundary are considered. Our basic model, which is constrained to yield fH2O (30 km) = 30 ppm (Pollack et al. 1993), predicts the position of the lower cloud boundary at 48.4 km coinciding with the mean Pioneer Venus value, the peak H2SO4 mixing ratio of 5.4 ppm, and the H2SO4 production rate phi H2SO4 = 2.2 x 10(12) cm-2 sec-1. The sulfur to sulfuric acid mass flux ratio in the clouds is 1 : 27 in this model, and the mass loading ratio may be larger than this value if sulfur particles are smaller than those of sulfuric acid. The model suggests that the extinction coefficient of sulfuric acid particles with radius 3.7 micrometers (mode 3) is equal to 0.3 km-1 in the middle cloud layer. The downward flux of CO is equal to 1.7 x 10(12) cm-2 sec-1 in this model. Our second model, which is constrained to yield fH2SO4 = 10 ppm at the lower cloud boundary, close to the value measured by the Magellan radiooccultations, predicts the position of this boundary to be at 46.5 km, which agrees with the Magellan data; fH2O(30 km) = 90 ppm, close to the data of Moroz et al. (1983) at this altitude; phi H2SO4 = 6.4 x 10(12) cm-2 sec-1; and phi co = 4.2 x 10(12) cm-2 sec-1. The S/H2SO4 flux mass ratio is 1 : 18, and the extinction coefficient of the mode 3 sulfuric acid particles is equal to 0.9 km-1 in the middle cloud layer. A strong gradient of the H2SO4 vapor mixing ratio near the bottom of the cloud layer drives a large upward flux of H2SO4, which condenses and forms the excessive downward flux of liquid sulfuric acid, which is larger by a factor of 4-7 than the flux in the middle cloud layer. This is the mechanism of formation of the lower cloud layer. Variations of the lower cloud layer are discussed. Our modeling of the OCS and CO profiles in the lower atmosphere measured by Pollack et al. (1993) provides a reasonable explanation of these data and shows that the rate coefficient of the reaction SO3 + CO --> CO2 + SO2 is equal to 10(-11) exp(-(13,100 +/- 1000)/T) cm3/s. The main channel of the reaction between SO3 and OCS is CO2 + (SO)2, and its rate coefficient is equal to 10(-11) exp(-(8900 +/- 500)T)cm3/s. In the conditions of Venus' lower atmosphere, (SO)2 is removed by the reaction (SO)2 + OCS --> CO + S2 + SO2. The model predicts an OCS mixing ratio of 28 ppm near the surface.     

Liquid content of the lower clouds of venus as determined from mariner 10 radio occultation

S-band (13.06-cm) and X-band (3.56-cm) radio occulation data obtained during the flyby of Venus by Mariner 10 on February 5, 1974 were analyzed to obtain the effects of dispersive microwave absorption by the clouds of Venus. The received power profiles were first corrected for the effects of refraction in the atmosphere of Venus, programmed changes in the pointing direction of the high-gain antenna, and limit-cycle motion of the spacecraft attitude control system. The resulting excess attenuation profiles presumbaly due to cloud absorption have been inverted discretely to obtain profiles of absorption coefficient at the two wavelenghts. The ratios of the absorptivities are consistent with a sulfuric acid-water mixture as the constituent of the absorbing clouds, having a sulfuric acid concentration of 75 ± 25%. Three absorption peaks are evident in the profiles at altitudes of 68, 60, and 48 km. With a sulfuric acid concentration of 75%, the upper cloud has a peak liquid content of 0.08 g/m³, and an integrated content of 0.024 g/cm², which corresponds roughly to terrestrial stratus or altostratus clouds. The major absorption layer has a peak of 1.1 g/m³ at an altitude of 48 km, with an integrated content of 0.5 g/cm², similar to that of terrestrial cumulus and cumulonimbus clouds. The absorption ratios for the middle cloud at 60 km are not consistent with a sulfuric acid-water mixture.     

Venus cloud microphysics

Because sulfuric acid does not wet sulfur, composite drops in the atmosphere of Venus cannot have sulfur “cores,” but must instead have sulfur coats. Both components then communicate with the vapor phase. Drops that are fully coated with sulfur are immune to coalescence; this sets a limit to growth that may explain “Mode 3” particles. The sulfur coating is probably responsible for the anomalously low refractive indices derived from entry-probe nephelometer data. There appears to be about an order of magnitude less elemental sulfur than sulfuric acid in the clouds.     

Properties of the clouds of Venus,as inferred from airborne observations of its near-infrared reflectivity spectrum

We have measured the shape and absolute value of Venus' reflectivity spectrum in the 1.2-to 4.0-μm spectral region with a circular variable filter wheel spectrometer having a spectral resolution of 1.5%. The instrument package was mounted on the 91-cm telescope of NASA Ames Kuiper Airborne Observatory, and the measurements were obtained at an altitude of about 41,000 feet, when Venus had a phase angle of 86°. Comparing these spectra with synthetic spectra generated with a multiple-scattering computer code, we infer a number of properties of the Venus clouds. We obtain strong confirmatory evidence that the clouds are made of a water solution of sulfuric acid in their top unit optical depth and find that the clouds are made of this material down to an optical depth of at least 25. In addition, we determine that the acid concentration is 84 ± 2% H_2SO4 by weight in the top unit optical depth, that the total optical depth of the clouds is 37.5 ± 12.5, and that the cross-sectional weighted mean particle radius lies between 0.5 and 1.4 μm in the top unit optical depth of the clouds. These results have been combined with a recent determination of the location of the clouds' bottom boundary [Marov et al., Cosmic Res.14, 637–642 (1976)] to infer additional properties about Venus' atmosphere. We find that the average volume mixing ratio of H₂SO₄ and H₂O contained in the cloud material both equal approximately 2× 10^?6. Employing vapor pressure arguments, we show that the acid concentration equals 84 ± 6% at the cloud bottom and that the water vapor mixing ratio beneath the clouds lies between 6 × 10^?4 and 10^?2.     

Venusian middle-atmospheric dynamics in the presence of a strong planetary-scale 5.5-day wave

The middle atmospheric dynamics on Venus are investigated using a middle atmosphere general circulation model. The magnitude of the superrotation is sensitive to the amplitude of the planetary-scale waves. In particular, the critical level absorptions of the forced planetary-scale waves might contribute to the maintenance of the superrotation near the cloud base. In the case of strong 5.5-day wave forcing, the superrotation with zonal wind speed higher than 100 m s^?1 is maintained by the forced wave. Four-day and 5.5-day waves are found near the equatorial cloud top and base, respectively. The planetary-scale waves have a Y-shaped pattern maintained by the amplitude modulation in the presence of strong thermal tides.The polar hot dipole is unstable and its dynamical behavior is complex near the cloud top in this model. The dipole merges into a monopole or breaks up into a tripole when the divergent eddies with high zonal wavenumbers are predominant in the hot dipole region. A cold collar is partly enhanced by a cold phase of slowly propagating waves with zonal wavenumber 1. Although such a complex dipole behavior has not been observed yet, it is likely to occur under a dynamical condition similar to the present simulation. Thus, the dynamical approach using a general circulation model might be useful for analyzing Venus Express and ground-based observation data.     

Water vapor near the cloud tops of Venus from Venus Express/VIRTIS dayside data

Observations of the dayside of Venus performed by the high spectral resolution channel (–H) of the Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) on board the ESA Venus Express mission have been used to measure the altitude of the cloud tops and the water vapor abundance around this level with a spatial resolution ranging from 100 to 10 km. CO₂ and H₂O bands between 2.48 and 2.60 μm are analyzed to determine the cloud top altitude and water vapor abundance near this level. At low latitudes (±40°) mean water vapor abundance is equal to 3 ± 1 ppm and the corresponding cloud top altitude at 2.5 μm is equal to 69.5 ± 2 km. Poleward from middle latitudes the cloud top altitude gradually decreases down to 64 km, while the average H₂O abundance reaches its maximum of 5 ppm at 80° of latitude with a large scatter from 1 to 15 ppm. The calculated mass percentage of the sulfuric acid solution in cloud droplets of mode 2 (～1 μm) particles is in the range 75–83%, being in even more narrow interval of 80–83% in low latitudes. No systematic correlation of the dark UV markings with the cloud top altitude or water vapor has been observed.     

Net global thermal emission from the Venusian atmosphere

Improved calculations of net emission from the northern hemisphere of Venus are presented. These are based on temperature profiles, water vapor mixing ratio profiles, and cloud models retrieved in 120 solar-fixed latitude-longitude bins from infrared measurements in six spectral channels made over a period of 72 days by the orbiter infrared radiometer (OIR) instrument of the Pioneer Venus mission. Only carbon dioxide, sulfuric acid cloud, and water vapor are considered as significant sources of atmospheric opacity, and the role of the latter component is found to be minor. The sensitivity of the calculations to extreme alternative cloud models, measurement errors, and calibration errors is also discussed. Net emission is found to be only weakly dependent on latitude and longitude during the period of observation with the exception of the high-latitude polar collar region, where emission is low. Mean net emission from the northern hemisphere is 157.0 ± 6.9 W.m^?2, corresponding to an equivalent temperature of 229.4 ± 2.5°K. If this figure is characteristic of the whole planet and if thermal balance is assumed, the bolometric albedo of Venus is 0.762 ± 0.011. This value is consistent with the latest estimates within experimental error.     

Sulfur dioxide and other cloud-related gases as the source of the microwave opacity of the middle atmosphere of Venus

Spacecraft radio occultation measurements imply the presence of a nonuniformly mixed gaseous absorber within, but mostly below, the main cloud layer of sulfuric acid—water droplets measured by Pioneer-Venus. Preliminary considerations of the amount, distribution, and effects of sulfur dioxide and other gases, which apparently are associated with and produce the cloud, indicate that they constitute an important, and probably the predominant, source of the observed microwave opacity of the middle atmosphere of Venus.     

An investigation of the SO2 content of the venusian mesosphere using SPICAV-UV in nadir mode

Using the SPICAV-UV spectrometer aboard Venus Express in nadir mode, we were able to derive spectral radiance factors in the middle atmosphere of Venus in the 170-320 nm range at a spectral resolution of R ? 200 during 2006 and 2007 in the northern hemisphere. By comparison with a radiative transfer model of the upper atmosphere of Venus, we could derive column abundance above the visible cloud top for SO₂ using its spectral absorption bands near 280 and 220 nm. SO₂ column densities show large temporal and spatial variations on a horizontal scale of a few hundred kilometers. Typical SO₂ column densities at low latitudes (up to 50°N) were found between 5 and 50 μm-atm, whereas in the northern polar region SO₂ content was usually below 5 μm-atm. The observed latitudinal variations follow closely the cloud top altitude derived by SPICAV-IR and are thought to be of dynamical origin. Also, a sudden increase of SO₂ column density in the whole northern hemisphere has been observed in early 2007, possibly related to a convective episode advecting some deep SO₂ into the upper atmosphere.     

A comparison of water vapor line parameters for modeling the Venus deep atmosphere

The discovery of the near infrared windows into the Venus deep atmosphere has enabled the use of remote sensing techniques to study the composition of the Venus atmosphere below the clouds. In particular, water vapor absorption lines can be observed in a number of the near-infrared windows allowing measurement of the H₂O abundance at several different levels in the lower atmosphere. Accurate determination of the abundance requires a good database of spectral line parameters for the H₂O absorption lines at the high temperatures (up to ∼700 K) encountered in the Venus deep atmosphere. This paper presents a comparison of a number of H₂O line lists that have been, or that could potentially be used, to analyze Venus deep atmosphere water abundances and shows that there are substantial discrepancies between them. For example, the early high-temperature list used by Meadows and Crisp [Meadows, V.S., Crisp, D., 1996. J. Geophys. Res. 101 (E2), 4595-4622] had large systematic errors in line intensities. When these are corrected for using the more recent high-temperature BT2 list of Barber et al. [Barber, R.J., Tennyson, J., Harris, G.J., Tolchenov, R.N., 2006. Mon. Not. R. Astron. Soc. 368, 1087-1094] their value of 45±10 ppm for the water vapor mixing ratio reduces to 27±6 ppm. The HITRAN and GEISA lists used for most other studies of Venus are deficient in “hot” lines that become important in the Venus deep atmosphere and also show evidence of systematic errors in line intensities, particularly for the 8000 to 9500 cm⁻¹ region that includes the 1.18 μm window. Water vapor mixing ratios derived from these lists may also be somewhat overestimated. The BT2 line list is recommended as being the most complete and accurate current representation of the H₂O spectrum at Venus temperatures.     

Cosmic ray ionization of lower Venus atmosphere

Cosmic ray particles passing through dense lower atmosphere of Venus decay giving rise to various charged and neutral particles. The flux and degradation of dominant cascade particles namely neutrinos and pions are computed and ionization contributions at lower altitudes are estimated. Using the height profile of pion flux, the muon flux is computed and used to estimate ionization at lower altitudes. It is shown that cosmic ray produced ionization descends to much lower altitudes intercepting the thickness of Venus cloud deck. The dynamical features of Venus cloud deck are used to allow the likely charging and charge separation processes resulting into cloud-to-cloud lightning discharges.     

The microwave absorption of SO2 in the Venus atmosphere

Sulfur dioxide has a strong and complex rotational spectrum in the microwave and far infrared regions. The microwave absorption due to SO₂ in a CO₂ mixture is calculated for conditions applicable to the Venus atmosphere. It is shown that at the concentrations detected by Pioneer-Venus in situ measurements, SO₂ may be expected to contribute significantly to the microwave opacity of the Venus atmosphere. In particular, SO₂ might provide the major source of opacity in the atmospheric region immediately below the main sulfuric acid cloud deck. The spectrum is largely nonresonant at the pressures where SO₂ is expected to occur, however.     

Polarization studies of the Venus uv contrasts: Cloud height and haze variability

Polarimetry is able to show direct evidence for compositional differences in the Venus clouds. We present observations (collected during $\text{2}\text{1}\text{2}$ Venus years by the Pioneer Venus Orbiter) of the polarization in four colors of the bright and dark ultraviolet features. We find that the polarization is significantly different between the bright and dark areas. The data show that the “null” model of L. W. Esposito (1980, J. Geophys. Res.85, 8151–8157) and the “overlying haze” model of J. B. Pollack et al. (1980, J. Geophys. Res.85, 8223–8231) are insufficient. Exact calculations of the polarization, including multiple scattering and vertical inhomogeneity near the Venus cloud tops, are able to match the observations. Our results give a straightforward interpretation of the polarization differences in terms of known constituents of the Venus atmosphere. The submicron haze and uv absorbers are anticorrelated: for haze properties as given by K. Kawabata et al. (1980, J. Geophys. Res.85, 8129–8140) the excess haze depth at 9350 Å over the bright regions is Δτ_h = 0.03 ± 0.02. The cloud top is slightly lower in the dark features: the extra optical depth at 2700 Å in Rayleigh scattering above the darker areas is Δτ_R = 0.010 ± 0.005. This corresponds to a height difference of 1.2 ± 0.6 km at the cloud tops. The calculated polarization which matches our data also explains the relative polarization of bright and dark features observed by Mariner 10. The observed differential polarization cannot be explained by differential distribution of haze, if the haze aerosols have an effective size of 0.49 μm, as determined by K. Kawabata et al. (1982, submitted) for the aerosols overlying the Venus equator. We propose two models for the uv contrasts consistent with our results. In a physical model, the dark uv regions are locations of vertical convergence and horizontal divergence. In a chemical model, we propose that the photochemistry is limited by local variations in water vapor and molecular oxygen. The portions of the atmosphere where these constituents are depleted at the cloud tops are the dark uv features. Strong support for this chemical explanation is the observation that the number of sulfur atoms above the cloud tops is equal over both the bright and dark areas. The mass budget of sulfur at these altitudes is balanced between excess sulfuric acid haze over the bright regions and excess SO₂ in the dark regions.     

Light scattering in a spherical,exponential atmosphere,with applications to Venus

The problem of the reflection of light from an optically thick, spherical atmosphere in which the scatterers are distributed exponentially with a scale height small compared to the radius of the planet is discussed. Exact formal solutions are obtained for the single scattered component. Useful approximate analytic solutions, which also include multiply scattered light, are given. The results are applied to the analysis of the Mariner 10 limb and terminator images of Venus. The altitude of the “detached” haze layer discovered by Mariner 10 is at 79–85 km, but in places the haze exists above 100 km. This layer apparently is a stable, planetwide feature which forms at the top of the Pioneer Venus upper haze layer. It was similar in location, scale height, and thickness at the times of the two missions, in contrast to the lower, high-altitude haze which changed dramatically. We discuss two possibilities for the nature of the limb hazes. (1) The lower haze is probably the sulfuric acid cloud and the “detached” layer may be a separate water-ice haze. (2)The “detached” haze layer may not be separate at all, but part of the sulfuric acid haze, and the apparent “gap” at 75–80 km may be the source region of a broadband absorber. The spatial distribution of the strong near-UV absorber, which may be elemental sulfur as first suggested by B. Hapke and R. Nelson (1975, J. Atmos. Sci.32, 1212–1218), is examined in light of our results. Several arguments indicate that there is no nonabsorbing, overlying haze and that the UV absorber extends to the top of the haze 8layer.     

Modeling the effects of shear on the evolution of the holes in the condensational clouds of Venus

Near-infrared brightness temperature contrasts observed on the night side of Venus indicate variations in the size and distribution of particles in the lower and middle cloud decks. McGouldrick and Toon [McGouldrick, K., Toon, O.B., 2007. Icarus 191, 1-24] have shown that these changes can be explained by large-scale dynamics; in particular, that downdrafts may produce optical depth “holes” in the clouds. The lifetimes of these holes are observed to be moderately short, on the order of ten days. Here, we explore a simple model to better understand this lifetime. We have coupled a microphysical model of the Venus clouds with a simple, two-dimensional (zonal, vertical) kinematical transport model to study the effects of the zonal flow on the lifetime of the holes in the clouds. We find that although wind shear may be negligible within the cloud itself, the shear that is present near the top and the bottom of the statically unstable cloud region can lead to changes in the radiative-dynamical feedback which ultimately lead to the dissipation of the holes.