Anti-clockwise P–T paths in the lower crust: an example from a kyanite-bearing regional aureole, George Sound, New Zealand

The George Sound Paragneiss (GSP) represents a rare Permo-Triassic unit in Fiordland that occurs as a km-scale pillar to gabbroic and dioritic gneiss of c . 120 Ma Western Fiordland Orthogneiss (WFO). It is distinguished from Palaeozoic paragneiss common in western Fiordland (Deep Cove Gneiss) by SHRIMP and laser-ablation U–Pb ages as young as c . 190 Ma and ¹⁷⁶Hf/¹⁷⁷Lu >0.2828 for detrital zircon grains. The Mesozoic age of the GSP circumvents common ambiguity in the interpretation of Cretaceous v. Palaeozoic metamorphic assemblages in the Deep Cove Gneiss. A shallowly dipping S₁ foliation is preserved in the GSP distal to the WFO, cut by 100 m scale migmatite contact zones. All units preserve a steeply dipping S₂ foliation. S₁ staurolite and sillimanite inclusions in the cores of metapelitic garnet grains distal to the WFO preserve evidence for prograde conditions of T  <   650 °C and P <  8 kbar. Contact aureole and S₂ assemblages include Mg-rich, Ca-poor cores to garnet grains in metapelitic schist that reflect WFO emplacement at ≈760 °C and ≈6.5 kbar. S₂ kyanite-bearing matrix assemblages and Ca-enriched garnet rims reflect ≈650 °C and ≈11 kbar. Poorly oriented muscovite–biotite intergrowths and rare paragonite reflect post-S₂ high- P retrogression and cooling. Pseudosection modelling in NCKFMASH defines a high- P anti-clockwise P–T history for the GSP involving: (i) mid- P amphibolite facies conditions; preceding (ii) thermal metamorphism adjacent to the WFO; followed by (iii) burial to high- P and (iv) high- P cooling induced by tectonic juxtaposition of cooler country rock.     

Metastable persistence of pelitic metamorphic assemblages at the root of a Cretaceous magmatic arc – Fiordland, New Zealand

Four aluminosilicate-bearing, amphibolite facies pelitic schists sampled from the root of the long-lived eastern Gondwana continental magmatic arc now exposed in southwest Fiordland, New Zealand, record remarkably different P–T–t histories. The four samples were collected from within 20 km of each other within the Fanny Bay Group and Deep Cove Gneiss near Dusky Sound. Integrated petrography, mineral chemistry, mineral equilibria modelling and in situ electron microprobe chemical dating of monazite shows that the sample of the Fanny Bay Group south of the Dusky Fault records a Carboniferous history with peak conditions of 4–4.5 kbar at 570–590 °C, while one sample of the Deep Cove Gneiss from Long Island records a Cretaceous history with apparent peak conditions of 7.5 kbar at 650 °C. Two other samples of the Deep Cove Gneiss from Resolution Island record mixed Carboniferous and Cretaceous histories with apparent peak conditions of 7 kbar at 650 °C and 3–7 kbar at 640–720 °C. The metapelitic schists on Resolution Island were intruded by arc magmas including the voluminous high- P Western Fiordland Orthogneiss, yet they lack mineralogical evidence of the Cretaceous high- P (>12 kbar) event. Analysis of water isopleths in a model system shows that the amount of water accommodated in the rock mineral assemblage increases with pressure. With the exhaustion of all free water, and without the addition of external water, these rocks persisted metastably within the deep arc during the high- P event. The emplacement of large volumes of diorite (i.e. the Western Fiordland Orthogneiss) into the root of the Early Cretaceous continental magmatic arc did not lead to regional granulite facies metamorphism of the country rock schists, as large volumes of amphibolite facies rock metamorphosed under medium- P conditions persisted metastably in the deep arc crust.     

Evidence for melt migration enhancing recrystallization of metastable assemblages in mafic lower crust, Fiordland, New Zealand

A major arc batholith, the Western Fiordland Orthogneiss (WFO) in Fiordland, New Zealand, exhibits irregular, spatially restricted centimetre-scale recrystallization from two-pyroxene hornblende granulite to garnet granulite flanking felsic dykes. At Lake Grave, northern Fiordland, the composition and texture of narrow (<10–20 mm across) felsic dykes that cut the orthogneiss are consistent with an igneous origin and injection of melt to form orthogneiss migmatite. New U–Pb geochronology suggests that the injection of dykes and migmatization occurred at c . 115 Ma, during the later stages of arc magmatism. Recrystallization to garnet granulite is promoted by volatile extraction from the host two-pyroxene hornblende granulite via adjacent dykes and the patchy development of garnet granulite is left as a marker adjacent to the melt migration path. New mineral equilibria modelling suggests that a two-pyroxene hornblende assemblage is stable at <11 kbar, whereas a garnet granulite assemblage is stable at >12 kbar, suggesting that garnet granulite may have formed with <5 km crustal loading of the batholith. Although the garnet granulite assemblages signify that the WFO experienced high- P conditions, the very local nature of these textures indicates widespread metastability (>90%) of the two-pyroxene hornblende granulite assemblages. These results indicate the strongly metastable nature of assemblages in mafic lower arc crust during deep burial and demonstrate that the degree of reaction in the case of Fiordland is related to interaction with migrating melts.     

High-pressure metamorphism caused by magma loading in Fiordland, New Zealand

Cretaceous granulite facies metamorphism in the Fiordland area of New Zealand has distinctive mineralogical, textural and structural features that set it apart from most other regional metamorphic belts. The metamorphism, developed over a 30×150-km area and the consequence of a 20-km-thick increment to crustal thickness, is closely associated in space and time with a large plutonic complex, the Western Fiordland Orthogneiss (WFO). Although temperatures and pressures as high as 700  °C and 12  kbar were attained, the metamorphic overprint on earlier low-pressure assemblages is weak and incomplete. Little strain accompanied the metamorphism. The temperature threshold at which metamorphic recrystallization is recorded is over 500  °C. Zoned garnets are preserved at unusually high temperatures, indicating duration of metamorphism on the order of 10 times shorter than in most other regional terranes. This pattern of features bears close similarity to metamorphism in the Coast Plutonic Complex in North America, where a mechanism of 'magma loading' has been invoked. In Fiordland, the high-pressure metamorphism can be explained by depression of country rock under a crustal zone that is inflated by intrusion of the WFO. Regional structure of the WFO as a horizontally sheeted complex suggests that the pluton was emplaced by vertical displacement of country rock, and supports the magma loading model.     

Trace element partitioning during high-P partial melting and melt-rock interaction; an example from northern Fiordland, New Zealand

Pods of granulite facies dioritic gneiss in the Pembroke Valley, Milford Sound, New Zealand, preserve peritectic garnet surrounded by trondhjemitic leucosome and vein networks, that are evidence of high‐P partial melting. Garnet‐bearing trondhjemitic veins extend into host gabbroic gneiss, where they are spatially linked with the recrystallization of comparatively low‐P two‐pyroxene‐hornblende granulite to fine‐grained high‐P garnet granulite assemblages in garnet reaction zones. New data acquired using a Laser Ablation Inductively Coupled Plasma Mass Spectrometer (LA‐ICPMS) for minerals in various textural settings indicate differences in the partitioning of trace elements in the transition of the two rock types to garnet granulite, mostly due to the presence or absence of clinozoisite. Garnet in the garnet reaction zone (gabbroic gneiss) has a distinct trace element pattern, inherited from reactant gabbroic gneiss hornblende. Peritectic garnet in the dioritic gneiss and garnet in trondhjemitic veins from the Pembroke Granulite have trace element patterns inherited from the melt‐producing reaction in the dioritic gneiss. The distinct trace element patterns of garnet link the trondhjemitic veins geochemically to sites of partial melting in the dioritic gneiss.     

Transformation of two-pyroxene hornblende granulite to garnet granulite involving simultaneous melting and fracturing of the lower crust, Fiordland, New Zealand

Granulite facies gabbroic and dioritic gneisses in the Pembroke Valley, Milford Sound, New Zealand, are cut by vertical and planar garnet reaction zones in rectilinear patterns. In gabbroic gneiss, narrow dykes of anorthositic leucosome are surrounded by fine‐grained garnet granulite that replaced the host two‐pyroxene hornblende granulite at conditions of 750 °C and 14 kbar. Major and trace element whole‐rock geochemical data indicate that recrystallization was mostly isochemical. The anorthositic veins cut contacts between gabbroic gneiss and dioritic gneiss, but change in morphology at the contacts, from the anorthositic vein surrounded by a garnet granulite reaction zone in the gabbroic gneiss, to zones with a septum of coarse‐grained garnet surrounded by anorthositic leucosome in the dioritic gneiss. The dioritic gneiss also contains isolated garnet grains enclosed by leucosome, and short planar trains of garnet grains linked by leucosome. Partial melting of the dioritic gneiss, mostly controlled by hornblende breakdown at water‐undersaturated conditions, is inferred to have generated the leucosomes. The form of the leucosomes is consistent with melt segregation and transport aided by fracture propagation; limited retrogression suggests considerable melt escape. Dyking and melt escape from the dioritic gneiss are inferred to have propagated fractures into the gabbroic gneiss. The migrating melt scavenged water from the surrounding gabbroic gneiss and induced the limited replacement by garnet granulite.     

Kyanite-paragonite-bearing assemblages, northern Fiordland, New Zealand: rapid cooling of the lower crustal root to a Cretaceous magmatic arc

Fiordland, New Zealand exposes the lower crustal root of an Early Cretaceous magmatic arc that now forms one of Earth's most extensive high‐P granulite facies belts. The Arthur River Complex, a dioritic to gabbroic suite in northern Fiordland, is part of the root of the arc, and records an Early Cretaceous history of emplacement, tectonic burial, and high‐P granulite facies metamorphism that accompanied partial melting of the crust. Late random intergrowths of kyanite, quartz and plagioclase partially pseudomorph minerals in the earlier high‐T assemblages of the Arthur River Complex, indicating high‐P cooling of an over thickened crustal root by c. 200 °C. The kyanite intergrowths are themselves partially pseudomorphed by paragonite, commonly in the presence of phengitic white mica. Biotite–plagioclase intergrowths that partially pseudomorph phengitic white mica and diopside–plagioclase intergrowths that partially pseudomorph jadeitic diopside, combined with published thermochronology results, are consistent with later rapid decompression. A short duration anticlockwise P–T path may be explained by the high‐P juxtaposition of comparatively cool upper crustal rocks following their tectonic burial and under thrusting during the waning stages of Early Cretaceous orogenesis. This was then followed by the decompression giving the rapid exhumation within 20 Myr of peak metamorphism, as suggested by the isotopic data.     

A corundum–quartz assemblage from the Eastern Ghats Granulite Belt,India: evidence for high P–T metamorphism?

Corundum+quartz-bearing assemblages occur in small lenses in granulite facies metapelites in Rayagada, north-central part of the Eastern Ghats Granulite Belt, India. Corundum porphyroblasts and quartz coexist with porphyroblastic almandine-rich garnet, hercynite spinel, ilmenite and magnetite. Corundum and quartz are separated by sillimanite or a composite corona consisting of sillimanite and garnet, whereas corundum shows sharp grain boundaries with spinel, ilmenite and magnetite. Porphyroblastic corundum contains prismatic sillimanite inclusions in which irregularly shaped quartz is enclosed. Two distinct reactions are inferred from the textural features: corundum+quartz=sillimanite and spinel+quartz=garnet+sillimanite. From the petrographical features, we infer that corundum–quartz–garnet–spinel was the peak metamorphic assemblage. Although large uncertainties exist regarding the positions of the respective reactions in P–T  space, from several published experimental results and theoretical calculations a peak metamorphic condition of 12  kbar and 1100  °C is estimated as the lower stability limit of the corundum–quartz assemblage. Decompression from the peak P–T  condition to c .  9  kbar, 950  °C is inferred.     

The regional significance of Cretaceous magmatism and metamorphism in Fiordland, New Zealand, from U–Pb zircon geochronology

The western Fiordland Orthogneiss (WFO) is an extensive composite metagabbroic to dioritic arc batholith that was emplaced at c. 20–25 km crustal depth into Palaeozoic and Mesozoic gneiss during collision and accretion of the arc with the Mesozoic Pacific Gondwana margin. Sensitive high‐resolution ion microprobe U–Pb zircon data from central and northern Fiordland indicate that WFO plutons were emplaced throughout the early Cretaceous (123.6 ± 3.0, 121.8 ± 1.7, 120.0 ± 2.6 and 115.6 ± 2.4 Ma). Emplacement of the WFO synchronous with regional deformation and collisional‐style orogenesis is illustrated by (i) coeval ages of a post‐D1 dyke (123.6 ± 3.0 Ma) and its host pluton (121.8 ± 1.7 Ma) at Mt Daniel and (ii) coeval ages of pluton emplacement and metamorphism/deformation of proximal paragneiss in George and Doubtful Sounds. The coincidence emplacement and metamorphic ages indicate that the WFO was regionally significant as a heat source for amphibolite to granulite facies metamorphism. The age spectra of detrital zircon populations were characterized for four paragneiss samples. A paragneiss from Doubtful Sound shows a similar age spectrum to other central Fiordland and Westland paragneiss and SE Australian Ordovician sedimentary rocks, with age peaks at 600–500 and 1100–900 Ma, a smaller peak at c. 1400 Ma, and a minor Archean component. Similarly, one sample of the George Sound paragneiss has a significant Palaeozoic to Archean age spectrum, however zircon populations from the George Sound paragneiss are dominated by Permo‐Triassic components and thus are markedly different from any of those previously studied in Fiordland.     

P-T path determinations in the Tormes Gneissic Dome, NW Iberian Massif, Spain

The Tormes Gneissic Dome (TGD, NW sector of the Iberian Massif, Spain) is a high-grade metamorphic complex affected by a major episode of extensional deformation (D2). The syn-D2 P–T  path of the Lower Unit of the TGD was deduced from the analysis of reaction textures related to superimposed fabrics developed during exhumation, analysis of mineral zoning and thermobarometric calculations. It comprises an initial phase of decompression, determined using the tweequ thermobarometric technique, from 6.4–8.1 kbar at 735–750 °C (upper structural levels) and 7.2 kbar at 770 °C (lower structural levels) to 3.3–3.9 kbar and 645–680 °C. This evolution is consistent with the observed sequence of melting reactions and the generation of garnet- and cordierite-bearing anatectic granitoids. The later part of the syn-D2 P–T  path consisted of almost isobaric cooling associated with the thermal re-equilibration of the unit in the new structural position. This segment of the P–T  path is recorded by assemblages with And +Bt+Ms and Ms+ Chl +Ab related to the later mylonitic S2 fabrics, which indicate retrogression to low-amphibolite and greenschist facies conditions.     

Magmatic arc metamorphism: petrology and temperature history of metabasic rocks in the Coastal Cordillera of northern Chile

We investigated the metamorphic cooling history of underplated magmatic rocks at midcrustal depth. Granulites and amphibolites occur within the Jurassic magmatic belt of the Coast Range south of Antofagasta in northern Chile between 23°25' and 24°20' S. The protoliths of the metamorphic rocks are basic intrusions of Early Mesozoic age. They are part of the magmatically formed crust, and the essentially dry magmas were emplaced in an extensional regime. The granulites (clinopyroxene–orthopyroxene–plagioclase) show all stages of fabric development from magmatic to granoblastic fabrics. Pyroxene compositions were reset at temperatures around 800°  C independent of the stage of textural equilibration. The granulites were partially amphibolitized at upper amphibolite facies temperatures of 600–700°  C. Following cooling, a possible reheating to greenschist facies temperatures around 500°  C is indicated by prograde zoning in magnetite–ilmenite pairs. Mineral assemblages are not suitable for barometry, but a conservative estimation of the garnet-in reaction at given whole-rock compositions suggests maximum pressures in the granulite facies of around 5 kbar, and similar pressures are indicated by phengite barometry for the greenschist facies. The P–T  path of granulite–amphibolite metamorphism is one of slow cooling from magmatic temperatures with heterogeneous deformation. The thinning of the pre-Andean (Precambrian–Triassic) crust was apparently compensated by the magmatic underplating and this special tectonomagmatic setting caused the prolonged residence of the accreted rocks at midcrustal levels.     

Regional high-pressure metamorphism during intracratonic deformation: the Petermann Orogeny, central Australia

The Petermann Orogeny is a late Neoproterozoic to Cambrian ( c . 560–520  Ma) intracratonic event that affected the Musgrave Block and south-western Amadeus Basin in central Australia. In the Mann Ranges, within the central Musgrave Block, Mesoproterozoic granulite facies gneisses, granites and mafic dykes have been substantially reworked by deep crustal non-coaxial strain of late Neoproterozoic to early Cambrian age. Dolerite dykes have recrystallized to garnet granulite facies assemblages, associated with the development of a mylonitic fabric at P =12–13  kbar and T  =700–750 °C. Migmatization is restricted to discrete shear zones, which represent conduits for hydrous fluids during metamorphism. Peak metamorphism was followed by decompression to c . 7  kbar, reflecting exhumation of the terrane along the south-dipping Woodroffe Thrust. In scattered outcrops north of the Mann Ranges, peak metamorphism occurred at P =9–10  kbar and T  = c . 700 °C. The Woodroffe Thrust separates these deep crustal mylonites from granites that were metamorphosed during the Petermann Orogeny at P = c . 6–7  kbar and T  = c . 650 °C. The similarity in peak temperatures at different crustal levels implies an unusual thermal regime during this event. The existence of a relatively elevated geotherm corresponding with Th- and K-enriched granites that were in the mid-crust during the Petermann Orogeny suggests that radiogenic heat production may have substantially contributed to the thermal regime during metamorphism. This potentially has implications for the mechanisms by which intra-plate strain was localized during this event.     

Low-P / high-T metamorphism in the Okiep Copper District, western Namaqualand, South Africa

The Okiep Copper District, part of the 1.2–1.0 Ga high-grade terrane in western Namaqualand, is composed of a mid-Proterozoic supracrustal sequence and several pre- to post-orogenic intrusive suites affected by two high-grade events (M2a/M2b, M3) of Kibaran and one low-grade event (M4) of Pan-African age. Peak assemblages in quartz-bearing pelites are characterized either by garnet+cordierite coexisting with sillimanite/biotite, or by biotite+sillimanite±garnet; a difference controlled by bulk composition and variation in water activities (0.1–0.7) during dehydration melting. Maximum P–T conditions were reached during M2a coevally with the major deformational event (D2a) and are estimated at 750–820  °C and 5–6  kbar. A counterclockwise P–T  path is indicated by regionally occurring pseudomorphs of sillimanite after andalusite and by prograde reaction textures preserved as relics in M2a porphyroblasts. Two stages of retrograde metamorphism are distinguished: M2a garnet+cordierite-bearing assemblages were retrogressed to biotite+sillimanite+quartz (M2b) along discontinuous foliation planes and shear zones (D2b). Retrograde M3 corona assemblages formed at similar P–T  conditions (580–660  °C and 5.8±0.5  kbar) to the M2b assemblages but M3 crystallization postdates penetrative D2 deformation, intrusion of 1.06 Ga granitoids and formation of associated W–Mo deposits. It is concluded that: (a) Kibaran high-grade metamorphism in the Okiep Copper District is thermally punctuated and (b) reaction textures documenting apparent isobaric cooling of this low- P high- T  terrane must be interpreted with caution.     

Western Fiordland orthogneiss: Early Cretaceous arc magmatism and granulite facies metamorphism,New Zealand

U-Pb isotopic analyses of zircons from a distinctive suite of previously undated granulite facies metaplutonic rocks, here termed the Western Fiordland Orthogneiss (WFO), in Fiordland, southwest New Zealand, indicate synkinematic magmatic emplacement between 120 and 130 Ma ago. These rocks were previously interpreted as possibly being of Precambrian age. Initial Pb and Sr ratios are consistent with arc/subduction related magmagenesis with little or no involvement of ancient continental crust. Subsequent high pressure (>12 kb) metamorphism of the WFO may reflect a major collision event involving crustal thickening by overthrusting of a >15 km thick sequence. Metamorphism ceased 116 Ma ago based on²⁰⁶Pb/²³⁸U ages of zircon from a retrogressed granulite. U-Pb isotopic analysis of apatite, along with previously published Rb/Sr mineral ages, indicate that final uplift and cooling to <300–400° C was largely completed by 90 Ma. The average uplift rate during this period is inferred to have been in excess of 1 mm/yr.Unmetamorphosed gabbronorites of the Darran Complex in eastern Fiordland, inferred by some investigators to be the granulite protolith, yield concordant U/Pb zircon ages of 137±1 Ma. U-Pb ages of apatite, and previously published K/Ar mineral ages indicate that these rocks experienced a rapid and simple cooling history lasting only a few million years. The high-grade WFO and unmetamorphosed Darran Complex are now separated by a profound structural break. However, the ages and similarities in initial Pb and Sr isotopic ratios suggest that both suites are products of the same Early Cretaceous cycle of subduction-related magmatism. The timing of Early Cretaceous magmatism and metamorphism, collision and resultant crustal thickening, and subsequent great uplift and erosion in Fiordland has important implications for terrane accretion and the evolution of relative plate motions along the New Zealand segment of the Gondwana margin.     

Temporal links between pluton emplacement,garnet granulite metamorphism,partial melting and extensional collapse in the lower crust of a Cretaceous magmatic arc,Fiordland, New Zealand

Garnet granulite facies mid‐to lower crust in Fiordland, New Zealand, provides evidence for pulsed intrusion and deformation occurring in the mid‐to lower crust of magmatic arcs. ²³⁸U‐²⁰⁶Pb zircon ages constrain emplacement of the ～595 km² Malaspina Pluton to 116–114 Ma. Nine Sm‐Nd garnet ages (multi‐point garnet‐rock isochrons) ranging from 115.6 ± 2.6 to 110.6 ± 2.0 Ma indicate that garnet granulite facies metamorphism was synchronous or near synchronous throughout the pluton. Hence, partial melting and garnet granulite facies metamorphism lasted <5 Ma and began within 5 Ma of pluton emplacement. Garnet granulite facies L‐S tectonites in the eastern part of the Malaspina Pluton record the onset of extensional strain and arc collapse. An Sm‐Nd garnet age and thermobarometric results for these rocks directly below the amphibolite facies Doubtful Sound shear zone provide the oldest known age for extension in Fiordland at ≥112.8 ± 2.2 Ma at ～920 °C and 14–15 kbar. Narrow high Ca rims in garnet from some of these suprasolidus rocks could reflect a ≤ 1.5 kbar pressure increase, but may be largely a result of temperature decrease based on the Ca content of garnet predicted from pseudosections. At peak metamorphic conditions >900 °C, garnet contained ～4000 ppm Ti; subsequently, rutile inclusions grew during declining temperature with limited pressure change. Garnet granulite metamorphism of the Malaspina Pluton is c. 10 Ma younger than similar metamorphism of the Pembroke Granulite in northern Fiordland; therefore, high‐P metamorphism and partial melting must have been diachronous for this >3000 km² area of mid‐to‐lower crust. Thus, two or more pulses of intrusion shortly followed by garnet granulite metamorphism and extensional strain occurred from north to south along the axis of the lower crustal root of the Cretaceous Gondwana arc.     

SHRIMP monazite and zircon geochronology of high-grade metamorphism in New Zealand

Ion microprobe dating of zircon and monazite from high-grade gneisses has been used to (1) determine the timing of metamorphism in the Western Province of New Zealand, and (2) constrain the age of the protoliths from which the metamorphic rocks were derived. The Western Province comprises Westland, where mainly upper crustal rocks are exposed, and Fiordland, where middle to lower crustal levels crop out. In Westland, the oldest recognisable metamorphic event occurred at 360–370 Ma, penecontemporaneously with intrusion of the mid-Palaeozoic Karamea Batholith (c. 375 Ma). Metamorphism took place under low-pressure/high-temperature conditions, resulting in upper-amphibolite sillimanite-grade metamorphism of Lower Palaeozoic pelites (Greenland Group). Orthogneisses of younger (Cretaceous) age formed during emplacement of the Rahu Suite granite intrusives (c. 110 Ma) and were derived from protoliths including Cretaceous Separation Point suite and Devonian Karamea suite granites. In Fiordland, high-grade paragneisses with Greenland Group zircon age patterns were metamorphosed (M1) to sillimanite grade at 360 Ma. Concomitant with crustal thickening and further granite emplacement, M1 mineral assemblages were overprinted by higher-pressure kyanite-grade metamorphism (M2) at 330 Ma. It remains unclear whether the M2 event in Fiordland was primarily due to tectonic burial, as suggested by regional recumbent isoclinal folding, or whether it was due to magmatic loading, in keeping with the significant volumes of granite magma intruded at higher structural levels in the formerly contiguous Westland region. Metamorphism in Fiordland accompanied and outlasted emplacement of the Western Fiordland Orthogneiss (WFO) at 110–125 Ma. The WFO equilibrated under granulite facies conditions, whereas cover rocks underwent more limited recrystallization except for high-strain shear zones where conditions of lower to middle amphibolite facies were met. The juxtaposition of Palaeozoic kyanite-grade rocks against Cretaceous WFO granulites resulted from late Mesozoic extensional deformation and development of metamorphic core complexes in the Western Province.     

Empirical calibration of the silica–Ca-tschermak's–anorthite (SCAn) geobarometer

The pressure-sensitive equilibrium among anorthite, quartz and the Ca-tschermak component in clinopyroxene (CaAl₂SiO₆; CaTs), CaAl₂SiOCpx6+SiOQtz2=CaAl₂Si₂OPl8 (SCAn) ,can be used as a geobarometer in granulites with the proper assemblage, and has been calibrated using mineral composition data from partial melting experiments of natural assemblages and from phase equilibrium experiments on the end-member CMAS system. The experimental data cover the P – T  range 4–32  kbar and 900–1400  °C. Linear least-squares regression analysis of the experimental data resulted in the following empirical expressions for pressure in terms of composition and temperature: P = 5.066 [±0.760]+ 1300 [±800] T  −ln K 276 [±16] · T  [±2.5  kbar]or P = 6.330 [±0.116]−ln K 301 [±9]· T  [±1.0  kbar] ,where K = a PlAn a CpxCaTs  .The first equation incorporates an enthalpy term, but is less accurate than the second equation, in which the enthalpy of reaction is ignored. Application of these expressions to natural and experimental equilibrium mineral assemblages demonstrates that the empirical barometers are applicable over a wide range of pressures (≥4  kbar), temperatures (≥700  °C) and bulk compositions (Mg#≥32.5).     

Evolution of high-Mg–Al granulites from Sunkarametta, Eastern Ghats, India: evidence for a lower crustal heating–cooling trajectory

A suite of high-Mg–Al granulites from Sunkarametta, Eastern Ghats Belt, India, shows contrasting prograde assemblages of extremely aluminous orthopyroxene+cordierite+sapphirine and similarly aluminous orthopyroxene+Ti-rich spinel in closely associated domains. Textural and compositional characteristics indicate that both were derived from prograde dehydration–melting of biotite–plagioclase–quartz-bearing protoliths. The former assemblage was stabilized at relatively more magnesian bulk composition. Geothermobarometric data and petrogenetic grid considerations place 'peak' metamorphic conditions at c. 950 °C and 9 kbar. Subsequent to peak metamorphism, the rocks cooled to c . 700–750 °C, with slight lowering of pressure, and the retrograde reactions also involved melt–solid interaction. The inferred P – T  trajectory is one of heating–cooling at lower crustal (25–30 km) depths.     

The assemblage diaspore+quartz in metamorphic rocks: a petrological, experimental and thermodynamic study

The upper pressure limit of pyrophyllite is given by the equilibria (i) pyrophyllite=diaspore+quartz and (ii) pyrophyllite=diaspore+coesite. High- P experimental investigations carried out to locate equilibrium (i) yield brackets between 497 °C/24.8  kbar and 535 °C/25.1  kbar, and between 500 °C/23  kbar and 540 °C/23  kbar. Equilibrium (ii) was bracketed at 550 °C between 26.0 and 28.3  kbar. In the experimental P–T  range, equilibria (i) and (ii) are metastable with respect to kyanite. A stable P–T  grid is calculated using thermodynamic data derived under consideration of the present experimental results. According to these data, the lower pressure limit of the assemblage diaspore+quartz according to equilibrium (i) range from about 12  kbar/300 °C to 20  kbar/430 °C (in the presence of pure water). The upper stability of diaspore+quartz is limited by the reaction diaspore+quartz=kyanite+H₂O at about 450 °C (nearly independent of pressure) and, to higher pressure, by the quartz=coesite transition. Equilibrium (ii) is metastable over the whole P–T  range.
Natural occurrences600.S of the diaspore–quartz assemblage in metamorphic rocks in Sulawesi, New Caledonia, Amorgos and the Vanoise are characterized by minerals indicative of high- P such as ferro-magnesiocarpholite, glaucophane, sodic pyroxene and lawsonite. The metamorphic P–T  conditions of these rocks are estimated to be in the range 300–400 °C, >8  kbar. These data are compatible with the derived P–T  stability field of the diaspore+quartz assemblage. We conclude that, in metamorphic rocks, diaspore+quartz is, as ferrocarpholite, an indicator for unusual low- T  /very high- P settings.     

Pressure–temperature conditions and retrograde paths of eclogites, garnet–glaucophane rocks and schists from South Sulawesi, Indonesia

High-pressure metamorphic rocks exposed in the Bantimala area, c . 40  km north-east of Ujung Pandang, were formed as a Cretaceous subduction complex with fault-bounded slices of melange, chert, basalt, turbidite, shallow-marine sedimentary rocks and ultrabasic rocks. Eclogites, garnet–glaucophane rocks and schists of the Bantimala complex have estimated peak temperatures of T  =580–630 °C at 18  kbar and T  =590–640 °C at 24  kbar, using the garnet–clinopyroxene geothermometer. The garnet–omphacite–phengite equilibrium is used to estimate pressures. The distribution coefficient K _D1=[( X _pyr)³( X _grs)⁶/( X _di)⁶]/[(Al/Mg)_M2,wm (Al/Si)_T2,wm]³ among omphacite, garnet and phengite is a good index for metamorphic pressures. The K _D1values of the Bantimala eclogites were compared with those of eclogites with reliable P–T  estimates. This comparison suggests that peak pressures of the Bantimala eclogites were P =18–24  kbar at T  =580–640 °C. These results are consistent with the P–T  range calculated using garnet–rutile–epidote–quartz and lawsonite–omphacite–glaucophane–epidote equilibria.