On the geodynamics of the Alpine collisional granitoids from Central Anatolia: petrology,age and isotopic characteristics of the granitoids of the Ekecikdağ Igneous Association (Aksaray/Turkey)

Granitoids of the Ekecikda? Igneous Association (Central Anatolia/Turkey) are products of collisional–post-collisional magmatism in the Ekecikda? area. These granitoids are granodiorite, microgranite and leucogranite. Field relations of granodiorites with microgranites is obscured, but leucogranites intrude both rock types. Mean zircon laser ablation (LA)-ICP-MS ²⁰⁶Pb-²³⁸U ages of granodiorites and microgranites are 84.52 ± 0.93 Ma and 80.7 ± 1.6 Ma, respectively, and age of leucogranites is suggested as 80 Ma, based on field relations combined with ²⁰⁶Pb/²³⁸U and Rb-Sr ages. Crystallisation temperatures of granodiorites, microgranites and leucogranites are 728°C-848°C, 797°C-880°C, 704°C-809°C, respectively.

Geochemical characteristics including Sr-Nd isotopic evidences infer a non-cogenetic character, as there is a high crustal contribution in I-type granodiorite sources, a crustal source with insignificant and significant mantle inputs in S-type microgranites and leucogranites, respectively. LA-ICP-MS Lu-Hf isotope data from zircons reveal their crustal nature (εHf_(t): ?1.3 ± 0.5 to ?8.8 ± 0.5). Crustal melting linked to the Alpine thickening during the Late Cretaceous led to formation of heterogeneous sourced granitoids with crustal dominated sources in the Ekecikda? area. Understanding of the nature and evolution of collisional Ekecikda? granitoids is not only important to put contribution in the geodynamic evolution of Central Anatolia and surrounding Alpine area, but also to better understand systematics of collisional magmatic systems.     

The earliest Jurassic A-type granite in the Nanling Range of southeastern South China: petrogenesis and geological implications

The tectonic transition from the palaeo-Tethyan to palaeo-Pacific dynamic domains in the South China Block (SCB) is still a matter of debate. The A-type granites collected from the southeastern SCB offered an opportunity to illustrate this tectonic transition. This article records a set of petrographic, geochronological, and geochemical data for the Wengong granitic pluton from the eastern Nanling Range. LA-ICP-MS zircon U–Pb dating shows a crystallization age of 196.9 ± 4.4 Ma with ε_Hf(t) values ranging from +2.1 to +7.7. The samples have high SiO₂, Zr+Nb+Ce+Y, FeOt/MgO, Ga/Al, and Y/Nb and are depleted in Nb–Ta, Zr–Hf, Ba, Sr, Ti, and Eu, similar to those of the A₂-type granite. Their initial ⁸⁷Sr/⁸⁶Sr ratios range from 0.70885 to 0.70983 and the ε_Nd(t) values range from ?2.9 to ?1.1, close to those of the Early Palaeozoic mafic rocks in the southeastern SCB. The Wengong A₂-type granite was derived from partial melting of the mafic rocks underplated into the lower crust during the Early Palaeozoic.

The Mesozoic A-type granites in the southeastern SCB can be subdivided into 229–215 Ma (Late Triassic), 197–152 Ma (Jurassic), and 135–92 Ma (Cretaceous). They differ in geochemical and spatial distribution characteristics. The Late Triassic A-type granites were formed in the post-collision extensional setting associated with the palaeo-Tethyan dynamic domain, whereas the Cretaceous A-type granites were under the control of the palaeo-Pacific dynamic domain. The A-type granites were hardly exposed during the Late Triassic–Early Jurassic and Late Jurassic–Early Cretaceous. The Jurassic A-type granites were formed in the intra-plate extensional setting, a response to the tectonic transition from the palaeo-Tethyan to palaeo-Pacific dynamic domains. Thus, the occurrence of the Wengong A₂-type granite indicates that this tectonic transition possibly initiated at the earliest Early Jurassic.     

Neoproterozoic alkaline intrusive complex in the northwestern Yangtze Block,Micang Mountains region,South China: petrogenesis and tectonic significance

Voluminous Neoproterozoic mafic–ultramafic, felsic, and alkaline intrusions are found in the northern Yangtze Block, South China. Here, we present whole-rock major and trace element, and Sr–Nd isotopic compositions, together with zircon U–Pb ages, for syenite and gabbro samples from the Shuimo–Zhongziyuan alkaline intrusive complex in the Micang Mountains region at the northwestern margin of the Yangtze Block. Zircon U–Pb dating yields crystallization ages for the Na- and K-rich Shuimo syenites of 869 ± 4 (MSWD = 0.85, 2σ) and 860 ± 5 Ma (MSWD = 0.47, 2σ), respectively, and for the Zhongziyuan gabbros of 753 ± 4 Ma (MSWD = 0.23, 2σ), indicating that the syenites and gabbros represent different stages of magmatism. The syenites include both Na- and K-rich types and have high values of the Rittman index (σ), and high SiO₂ and Na₂O + K₂O contents. These syenites are enriched in light rare earth elements (LREE) and large-ion lithophile elements (LILE), but depleted in high-field-strength elements (HFSE), with high (La/Yb)_N values and small negative and positive Eu anomalies (Eu/Eu* = 0.74–1.17). In contrast, the gabbros have lower SiO₂ and Na₂O + K₂O contents, are only slightly enriched in LREEs, are enriched in LILE but depleted in HFSEs, and have small negative and positive Eu anomalies (Eu/Eu* = 0.86–1.37). The syenites have low initial ⁸⁷Sr/⁸⁶Sr (0.703340) and ?_Nd(t) values (+1.9 to +7.7). The gabbros have relatively high initial ⁸⁷Sr/⁸⁶Sr (0.703562–0.704933) and positive ?_Nd(t) values (+1.6 to +4.5). These data suggest that the syenites and gabbros are isotopically similar and were largely derived from melts of depleted mantle. The syenites underwent significant fractional crystallization and small amounts of crustal contamination during magma evolution. In contrast, the gabbros were formed by partial melting (>15%) of a garnet lherzolite source and might also have experienced crustal assimilation. Taking into account the geochemical signatures and magmatic events, we propose that the Shuimo syenites formed in an intra-arc rifting setting, however, the Zhongziyuan gabbros were most likely produced in a subduction-related, continental margin arc setting during the Neoproterozoic, thus suggesting that the alkaline intrusive complex were formed by the arc-related magmatism in the Micang Mountains.     

Sedimentology in metamorphic rocks,the Willyama Supergroup,Broken Hill,Australia

In the upper greenschist to granulite grade rocks of the Willyama Supergroup at Broken Hill, Australia, earlier recognition of metamorphosed graded bedding in siliciclastic metasedimentary rocks led to interpretations of these rocks as deep-water turbidites. However, graded beds can also be deposited in shelfal environments below storm wave base. This study identified other tempestite features including wave oscillation ripples, hummocky cross-stratification and swaley cross-stratification indicating that deposition took place above the wave base of the larger storms.

Albitised metasedimentary rocks of the upper Thackaringa Group show structures such as swaley cross-stratification typical of shallow-water conditions above fair-weather wave base. Deposition of the Broken Hill Group commenced with muddy Allendale Metasediments conformable on the Thackaringa Group. The Ettlewood Calc-Silicate Member, originally a dolomitic, siliceous sediment, is interpreted as coastal sabkha indicating onset of a marine transgression. The Parnell Gneiss represents a volcanic or volcaniclastic interruption, heralding gradually increasing input of sand in the Freyers Metasediments reaching a maximum in middle Freyers Metasediments, followed by an abrupt reversion to mud, still influenced by wave action. An open marine shelf is interpreted, possibly 30 m deep (no more than 100 m) in the final stage of a developing rift. The Broken Hill Group terminated with the massive Hores Gneiss volcanic unit.

Sedimentation of the siliciclastic Sundown Group took place in similar conditions, commencing with a muddy interval overlying the Hores Gneiss. The shallowing produced by ～90 m thickness of volcanic/volcaniclastic Hores Gneiss was compensated by subsidence.

Paragon Group deposition commenced with substantial black mud, resulting from isolation from the sand supply and probably isolation from the sea. A fresh connection to the sea led first to the deposition of dolomitic carbonate (King Gunnia Calc-Silicate Member), then to deposition of parallel-laminated fine sand below wave base (upper Cartwrights Creek Metasediments), followed by ripple cross-laminated sand above wave base (Bijerkerno Metasediments). The Dalnit Bore Metasediments show abundant very thin graded silt–mud units possibly deposited below storm wave base, and thicker units of stacked wave oscillation ripples deposited above the wave base of larger storms.

The Broken Hill orebody is hosted by altered Broken Hill Group metasedimentary rocks deposited at water depths of ～30 m. Unless the ore fluid temperature was less than 150°C, it is likely that the orebody formed below the seafloor: at such shallow-water depths, the confining pressure would be inadequate to suppress boiling of hotter rising hydrothermal fluids.     

Regional thermo-rheological field related to granite emplacement in the upper crust: implications for the Larderello area (Tuscany,Italy)

We modelled thermo-rheological perturbations, related to the emplacement of a magmatic body in the upper crust. This approach was considered relevant for the areas characterized by elevated surface heat flow and chiefly for the geothermal fields. The numerical conductive thermal model applied to the Larderello geothermal area in Tuscany, allowed to constrain size, depth and timing of emplacement of the pluton. We inferred that the emplacement of a magmatic body, at a minimum depth of 3 km, having a horizontal extension of 14 km and a maximum thickness of 8 km, can reasonably reproduce the observed regional surface heat flow anomaly of the Larderello area, when 300 (± 100) kyr are elapsed from the magma emplacement. Even assuming an incremental growth, the first magma injection should not be older than 1 ± 0.3 Ma.

Results of the thermal model were used to set up a rheological model and to simulate the drifting of the brittle-ductile transition during the cooling of the pluton. A comparison with the K-horizon profile, a prominent seismic reflector in the Larderello area, was then performed. It was found that the K-horizon approximately corresponds with the pluton roof and with the current location of the brittle-ductile transition.     

Age and nature of 560–520 Ma calc-alkaline granitoids of Biarjmand,northeast Iran: insights into Cadomian arc magmatism in northern Gondwana

ABSTRACT

The Biarjmand granitoids and granitic gneisses in northeast Iran are part of the Torud–Biarjmand metamorphic complex, where previous zircon U–Pb geochronology show ages of ca. 554–530 Ma for orthogneissic rocks. Our new U–Pb zircon ages confirm a Cadomian age and show that the granitic gneiss is ~30 million years older (561.3 ± 4.7 Ma) than intruding granitoids (522.3 ± 4.2 Ma; 537.7 ± 4.7 Ma). Cadomian magmatism in Iran was part of an approximately 100-million-year-long episode of subduction-related arc and back-arc magmatism, which dominated the whole northern Gondwana margin, from Iberia to Turkey and Iran. Major REE and trace element data show that these granitoids have calc-alkaline signatures. Their zircon O (δ¹⁸O = 6.2–8.9‰) and Hf (–7.9 to +5.5; one point with εHf ~ –17.4) as well as bulk rock Nd isotopes (εNd(t) = –3 to –6.2) show that these magmas were generated via mixing of juvenile magmas with an older crust and/or melting of middle continental crust. Whole-rock Nd and zircon Hf model ages (1.3–1.6 Ga) suggest that this older continental crust was likely to have been Mesoproterozoic or even older. Our results, including variable zircon εHf(t) values, inheritance of old zircons and lack of evidence for juvenile Cadomian igneous rocks anywhere in Iran, suggest that the geotectonic setting during late Ediacaran and early Cambrian time was a continental magmatic arc rather than back-arc for the evolution of northeast Iran Cadomian igneous rocks.     

Petrogenesis of early Silurian intrusions in the Sanchakou area of Eastern Tianshan,Northwest China,and tectonic implications: geochronological,geochemical, and Hf isotopic evidence

ABSTRACT

Palaeozoic intrusions in Eastern Tianshan are important for understanding the evolution of the Central Asian Orogenic Belt (CAOB). The Sanchakou intrusions situated in Eastern Tianshan (southern CAOB), are mainly quartz diorite and granodiorite. A comprehensive study of zircon U–Pb ages, zircon trace elements, whole-rock geochemistry, and Lu–Hf isotopes were carried out for the Sanchakou intrusive rocks. LA-ICP-MS zircon U–Pb dating yielded crystallization ages of 439.7 ± 2.5 Ma (MSWD = 0.63, n = 21) for the quartz diorite, and 430.9 ± 2.5 Ma (MSWD = 0.21, n = 21) and 425.5 ± 2.7 Ma (MSWD = 0.04; n = 20) for the granodiorites. These data, in combination with other Silurian ages reported for the intrusive suites from Eastern Tianshan, indicate an early Palaeozoic magmatic event in the orogen. In situ zircon Hf isotope data for the Sanchakou quartz diorite shows ε_Hf(t) values of +11.2 to +19.6, and the two granodioritic samples exhibit similar ε_Hf(t) values from +13.0 to +19.5. The Sanchakou plutons show metaluminous to weakly peraluminous, arc-type geochemical and low-K tholeiite affinities, and display trace element patterns characterized by enrichment in K, Ba, Sr, and Sm, and depletion in Nb, Ta, Pb, and Ti. The geochemical and isotopic signatures indicate that the Sanchakou dioritic and granodioritic magmas were sourced from a subducted oceanic slab, and subsequently underwent some interaction with peridotite in the mantle wedge. Combined with the regional geological history, we suggest the Sanchakou intrusions formed due to the northward subduction of the Palaeo-Tianshan Ocean beneath the Dananhu–Tousuquan arc during early Silurian time.     

Late Holocene inter-annual temperature variability reconstructed from the δ18O of archaeological Ostrea angasi shells

Two multi-year oxygen isotope (δ¹⁸O) records were obtained from archaeological Ostrea angasi shells, confirming the potential of this species to provide valuable environmental records for the late Holocene period in southeastern Australia. High-resolution δ¹⁸O_shell samples from the O. angasi clearly display a seasonal variability, offering insight into past climate conditions in a region where such information is presently limited.

The oxygen isotope record in O. angasi reflects a combined temperature–salinity signal. Observations of δ¹⁸O_shell data from modern specimens are used as a point of reference to assist in decoupling these two influences, with the two archaeological samples compared with the δ¹⁸O_shell profile of four modern O. angasi. Assuming similar paleo- δ¹⁸O_water values at the collection sites, data from these archaeological shells present a record of temperatures during the period of their growth that are consistently lower than modern day, with mean annual temperatures ～2°C cooler.     

Triassic magmatism in the eastern part of the South China Block: Geochronological and petrogenetic constraints from Indosinian granites

The granitic dykes in the Badu Group,Zhejiang Province,South China provide important insights on tectonic setting and crustal evolution of the South China Block(SCB) and the Indochina Block during Triassic.Here we report LA-ICP-MS U-Pb data of granitic rocks from the Hucun and Kengkou which show early Triassic ages of 242 ± 2 and 232 ± 3 Ma,respectively,representing their timing of emplacement.The dyke rocks are enriched in K,Al,LREE,Rb,Th.U,and Pb.and are depleted in Nb,Ta,Sr,and Ti.The rocks are characterized by highly fractionated REE patterns with(La/Yb)N ratios of 28.46-38.07 with strong negative Eu anomalies(Eu/Eu* = 0.65-0.73).In situ Hf isotopic analyses of zircons from the Hucun granite yielded ε_(Hf)(t) values of-13.9 to-6.4 and two-stage depleted mantle Hf model ages of 1.68-2.15 Ga,which indicate that the magma was formed by partial melting of the Paleoproterozoic metasedimentary protoliths in the Cathaysia Block.The zircons from the Kengkou granite have ε_(Hf)(t) values ranging from 40.7 to 31.5 and yield two-stage depleted mantle Hf model ages of 0.99-2.49 Ga,indicating magma origin from a mixed source.The Hucun and Kengkou dykes,together with the Triassic A-type granites in SE China were probably generated during magmatism associated with crust-mantle decoupling along the convergent plate boundary between SCB and the Indochina Block.     

New Insights into Crustal Contributions to Large-volume Rhyolite Generation in the Mid-Tertiary Sierra Madre Occidental Province, Mexico, Revealed by U Pb Geochronology

Voluminous (3·9 x 10⁵ km³), prolonged (18 Myr) explosivesilicic volcanism makes the mid-Tertiary Sierra Madre Occidentalprovince of Mexico one of the largest intact silicic volcanicprovinces known. Previous models have proposed an assimilation–fractionalcrystallization origin for the rhyolites involving closed-systemfractional crystallization from crustally contaminated andesiticparental magmas, with <20% crustal contributions. The lackof isotopic variation among the lower crustal xenoliths inferredto represent the crustal contaminants and coeval Sierra MadreOccidental rhyolite and basaltic andesite to andesite volcanicrocks has constrained interpretations for larger crustal contributions.Here, we use zircon age populations as probes to assess crustalinvolvement in Sierra Madre Occidental silicic magmatism. Laserablation-inductively coupled plasma-mass spectrometry analysesof zircons from rhyolitic ignimbrites from the northeasternand southwestern sectors of the province yield U–Pb agesthat show significant age discrepancies of 1–4 Myr comparedwith previously determined K/Ar and ⁴⁰Ar/³⁹Ar ages from thesame ignimbrites; the age differences are greater than the errorsattributable to analytical uncertainty. Zircon xenocrysts withnew overgrowths in the Late Eocene to earliest Oligocene rhyoliteignimbrites from the northeastern sector provide direct evidencefor some involvement of Proterozoic crustal materials, and,potentially more importantly, the derivation of zircon fromMesozoic and Eocene age, isotopically primitive, subduction-relatedigneous basement. The youngest rhyolitic ignimbrites from thesouthwestern sector show even stronger evidence for inheritancein the age spectra, but lack old inherited zircon (i.e. Eoceneor older). Instead, these Early Miocene ignimbrites are dominatedby antecrystic zircons, representing >33 to 100% of the datedpopulation; most antecrysts range in age between 20 and 32 Ma.A sub-population of the antecrystic zircons is chemically distinctin terms of their high U (>1000 ppm to 1·3 wt %) andheavy REE contents; these are not present in the Oligocene ignimbritesin the northeastern sector of the Sierra Madre Occidental. Thecombination of antecryst zircon U–Pb ages and chemistrysuggests that much of the zircon in the youngest rhyolites wasderived by remelting of partially molten to solidified igneousrocks formed during preceding phases of Sierra Madre Occidentalvolcanism. Strong Zr undersaturation, and estimations for veryrapid dissolution rates of entrained zircons, preclude coevalmafic magmas being parental to the rhyolite magmas by a processof lower crustal assimilation followed by closed-system crystalfractionation as interpreted in previous studies of the SierraMadre Occidental rhyolites. Mafic magmas were more probablyimportant in providing a long-lived heat and material flux intothe crust, resulting in the remelting and recycling of oldercrust and newly formed igneous materials related to Sierra MadreOccidental magmatism. KEY WORDS: ignimbrite; rhyolite; Sierra Madre Occidental; Tertiary; U–Pb geochronology; zircon; antecryst; crustal melting     

Late Palaeoproterozoic Hekou Group in Sichuan,Southwest China: geochronological framework and tectonic implications

The Palaeoproterozoic Hekou Group, an outcrop along the SW-margin of the Yangtze Block, consists of volcanic and sedimentary rocks that experienced greenschist facies metamorphism and was intruded by gabbroic and granitic plutons. The sedimentary rocks consist of coarse to fine-grained siliciclastic and carbonate rocks including quartzite, mica schists, polymictic meta-conglomerates and marble, whereas volcanic rocks consist of sodic lava and pyroclastic rocks including albitites, interbeded metatuffs, and metabasalts. Metatuffs from five layers have zircon U–Pb age of 1710 ± 18 Ma (MSWD = 1.6), 1637 ± 7 Ma (MSWD = 0.65), 1601 ± 15 Ma (MSWD = 0.94), 1661 ± 7 Ma (MSWD = 1.4), and 1718 ± 11 Ma (MSWD = 0.3) and these ages show that the Hekou Group deposited at ~1.7–1.6 Ga. The high content of light rare earth element (LREE), the low content of highrare earth element (HREE) and negative Ti anomalies, relatively high content of incompatible fluid-insoluble elements (Nb, Ta, and Th), and the high varied εNd(t) values (?6.0 to +4.6) of the metavolcanic rocks show that these rocks are formed in back-arc basin. Our study also implies that the Yangtze Block also underwent subduction-related, continental margin accretion on its SW-margin during the growth of the Nuna supercontinent at ~1.7–1.6 Ga.     

Estimating Menard pressuremeter modulus and limit pressure from SPT in silty sand and silty clay soils. A case study in Mashhad,Iran

The Menard pressuremeter test is a relatively expensive in situ test, which generates useful information about the strength and deformation properties of any soil and weak rock, which is carried out in some projects. On the other hand, the SPT test is a rather inexpensive, simple and typical in situ test used to determine the engineering properties of silt, clay, sand, and fine gravel which is utilised in almost all projects.

In this study SPT blow counts (N₆₀) were correlated with pressuremeter modulus (E_PMT) and limit pressure (P_L) and empirical equations were proposed to estimate P_L and E_PMT from N₆₀ in silty sand and silty clay soils separately. These tests have been conducted during subway geotechnical investigation in Mashhad, Iran.

Moreover, in order to verify these empirical equations, they were compared with similar equations that have been proposed by other researchers. These comparisons display that in all equations a linear relationship exists between N₆₀ - E_PMT and N₆₀ - P_L. However, the line slopes are different so it can be concluded the line slopes are related to soil type and geological condition of an area. Thus, for each area a separate empirical equation must be presented.     

The Late Triassic Dengfuxian A-type granite,Hunan Province: age,petrogenesis, and implications for understanding the late Indosinian tectonic transition in South China

The Triassic (Indosinian) granites in the South China Block (SCB) have important tectonic significance for understanding the evolution of Eastern Asia. The Dengfuxian biotite granite in eastern Hunan Province, China, reported in this article, was recognized as Late Triassic (late Indosinian) weakly peraluminous A-type granite with a zircon laser ablation inductively coupled plasma mass spectrometry U–Pb age of 225.7 ± 1.6 Ma. It is enriched in F, Cs, Rb, Th, high field strength elements, and rare earth elements (REEs) and depleted in Ba, Sr, P, Ti, Nb, and Ta, with high Ga/Al ratios and zircon saturation temperatures. The Dengfuxian biotite granite shows high initial Sr isotope values (0.715932 to 0.716499) and negative ?_Nd(t) (?10.46 to ?9.67) and ?_Hf(t) (?9.92 to ?6.29) values, corresponding to the Nd model ages of 1.79 to 1.85 Ga and the Hf model ages of 1.65 to 1.88 Ga. It is proposed that the Dengfuxian biotite granite was derived from high-temperature partial melting of the Palaeoproterozoic lower crust undergoing granulitization. Some Late Triassic A-type granites were recently identified in the SCB with the ages between 202 and 232 Ma. These A-type granites have the same geochemical characteristics and petrogenesis as Dengfuxian A-type granite, and show A₂-subtype granite affinity. The Late Triassic A-type granite formed a NE-trending granite belt, which is consistent with the main NE-trending faults in the SCB. The formation of these A-type granites was in response to the subduction of the palaeo-Pacific plate underneath the SCB, and indicates an extensional tectonic environment in the SCB. Combined with previous studies on tectonic evolution, we suggest that there may be a tectonic transition inside the SCB from compression to extension at least from 225 to 230 Ma.     

Dating magmatic and hydrothermal processes using andradite-rich garnet U–Pb geochronometry

Andradite-rich garnet is a common U-bearing mineral in a variety of alkalic igneous rocks and skarn deposits, but has been largely neglected as a U–Pb chronometer. In situ laser ablation-inductively coupled plasma mass spectrometry U–Pb dates of andradite-rich garnet from a syenite pluton and two iron skarn deposits in the North China craton demonstrate the suitability and reliability of the mineral in accurately dating magmatic and hydrothermal processes. Two hydrothermal garnets from the iron skarn deposits have homogenous cores and zoned rims (Ad₈₆Gr₁₁ to Ad₉₈Gr₁) with 22–118 ppm U, whereas one magmatic garnet from the syenite is texturally and compositionally homogenous (Ad₇₀Gr₂₂ to Ad₇₇Gr₁₄) and has 0.1–20 ppm U. All three garnets have flat time-resolved signals obtained from depth profile analyses for U, indicating structurally bound U. Uranium is correlated with REE in both magmatic and hydrothermal garnets, indicating that the incorporation of U into the garnet is largely controlled by substitution mechanisms. Two hydrothermal garnets yielded U–Pb dates of 129 ± 2 (2σ; MSWD = 0.7) and 130 ± 1 Ma (2σ; MSWD = 0.5), indistinguishable from zircon U–Pb dates of 131 ± 1 and 129 ± 1 Ma for their respective ore-related intrusions. The magmatic garnet has a U–Pb age of 389 ± 3 Ma (2σ; MSWD = 0.6), consistent with a U–Pb zircon date of 388 ± 2 Ma for the syenite. The consistency between the garnet and zircon U–Pb dates confirms the reliability and accuracy of garnet U–Pb dating. Given the occurrence of andradite-rich garnet in alkaline and ultramafic magmatic rocks and hydrothermal ore deposits, our results highlight the potential utilization of garnet as a powerful U–Pb geochronometer for dating magmatism and skarn-related mineralization.     

Zircon Hf Isotopic Evidence for Mixing of Crustal and Silicic Mantle-derived Magmas in a Zoned Granite Pluton, Eastern Australia

Zircon Hf isotopic data from a zoned pluton of the Moonbi supersuite,New England batholith, eastern Australia, are consistent withmagma mixing between two silicic melts, each derived from isotopicallydistinct sources. Although zircons from three zones within theWalcha Road pluton give a U–Pb crystallization age of249 ± 3 Ma, zircon populations from each zone have arange in _Hf. Zircons from the mafic hornblende–biotitemonzogranite pluton margin and intermediate zones have _Hf +5to +11, whereas those from the more felsic centre of the plutonhave _Hf +7 to +16, representing a total variation of 11 _Hfunits. The Lu–Hf depleted mantle model ages range from650 to 250 Ma, with the younger zircons present only in thefelsic pluton centre. The variation in _Hf indicates the involvementof silicic melts from at least two sources, one a crustal componentwith a Neoproterozoic model age and the other a primitive mantle-derivedcomponent with model ages similar to the U–Pb crystallizationage of the pluton. The zircons reflect the isotopic compositionsof the different proportions of crustal-derived silicic melt,relative to mantle-derived silicic melt, between melt generationand final pluton construction. The Walcha Road pluton is consideredto have formed by incremental assembly of progressively morefelsic melt batches resulting from mixing, replenishment andcrystal–melt separation, with final pluton constructioninvolving mechanical concentration as zones of crystal mush.The zoned pluton and, more broadly, the Moonbi supersuite provideexamples of magma mixing by which the more silicic units havemore juvenile isotopic compositions as a result of increasingproportions of residual melt from basalt fractionation, relativeto crustal partial melt. KEY WORDS: Australia; granite magma mixing; zircon; zoned pluton; Hf isotopes     

Exploring for heavy minerals on Cape York Peninsula,Queensland, Australia

This paper describes the results of a preliminary study of the heavy mineral (HM) potential of the northwest coast of Cape York Peninsula in far north Queensland that was funded by the Queensland Government's Future Resources Program Industry Priorities Initiative. The study found that the northwest coast may have the potential to host world-class HM deposits. All the essential ingredients in a HM mineral system are present: fertile source rocks, effective transport mechanisms and abundant potential trap sites, particularly along the well-preserved Pleistocene coast.

The source rocks are Proterozoic metamorphic and Paleozoic granitic rocks of the Coen Inlier and Mesozoic sedimentary rocks of the Laura and Carpentaria basins, all of which crop out along the spine of the Peninsula. These rocks were exposed in the early Cenozoic and were vigorously eroded by seasonally active rivers throughout the Quaternary. Most of these rivers are currently carrying HM, and the zircon content in river sediments in the region is comparatively high. It is speculated that in the late Pleistocene HM delivered by rivers to the northwest coast were transported predominantly in a southwesterly direction, and trapped in the swash zone of prograding beaches. It is further speculated that at this time the coastline was deeply embayed with cliffs and headlands formed in bauxite, and that structural trap sites formed on the northeastern side of prominent headlands.

Pleistocene coastal sediments were partially reworked by Holocene coastal processes, and HM liberated by these processes may have been captured by prograding Holocene beach ridges. These Holocene beach ridges are not as extensive as the Pleistocene beach ridges but are more prominent, partly because they are less well vegetated. The Holocene coastline was probably more regular than the Pleistocene coastline, with fewer headlands to create structural traps. The modern coastline is relatively starved of river sediment because the Holocene and Pleistocene coastal sediments act as barriers to river flow.

It is recommended that ongoing exploration for HM in the region should focus on potential trap sites on the Pleistocene coast and that two sites, Vrilya Point and Jackson River, where structural traps may have been formed by coastal promontories, should be priority targets. It is also noted that if the exploration of Cape York Peninsula for HM deposits is to be effective, further research needs to be carried out into the geomorphological evolution of the west coast and, in particular, the role of cyclones in forming HM deposits in tropical climates.     

Paleomagnetic evidence for the emplacement mechanism of an enigmatic boulder accumulation on a coastal cliff top in New South Wales: implications for the Australian Megatsunami Hypothesis

Paleomagnetic sampling and measurement of a boulder accumulation on Little Beecroft Head on the Illawarra coastline of New South Wales was undertaken to evaluate potential emplacement mechanisms. This deposit is of central importance in the Australian Megatsunami Hypothesis (AMH) debate, but to date, there has been no unequivocal determination of its provenance. The most likely emplacement mechanisms are by slow collapse during denudation of overlying strata, storm wave overwash or a combination of these. Characteristic Remanent Magnetisation (ChRM) directions were obtained from 15 individual boulders and the in situ bedrock platform on which they currently rest. The in situ Permian bedrock has a normal polarity mean ChRM direction of D/I = 1.6°/–66.7° (α₉₅ = 5.2°; k = 33.9) that is statistically indistinguishable from the Present Earth Field direction at the site. The magnetisation is most likely due to Cenozoic/recent weathering, which is common in surficial rocks throughout the Sydney Basin. ChRM directions for the boulders are stable but scattered, although not random, and the mean boulder direction is indistinguishable in geographic (i.e. current in situ) coordinates, at the 5% significance level, from the mean direction of the in situ bedrock. Further statistical tests confirm that the scatter in the mean directions of the boulders and the in situ bedrock is different, at the 5% significance level, with the boulder mean being more scattered. At an individual boulder level, some blocks have mean ChRM directions that are statistically indistinguishable from the mean in situ rock ChRM direction, whereas others are distinguishable at the 5% significance level.

These results indicate that the boulders were magnetised prior to emplacement but were not moved far from their original positions during emplacement. The emplacement age is constrained to the last ca 780 000 years. These observations strongly support the hypothesis that the Little Beecroft Head boulder deposit was emplaced by a non-catastrophic mechanism, namely slow collapse during denudation of pre-existing cliff material or overtopping from severe storms, which occur regularly on the east coast of New South Wales. Even if a catastrophic wave were responsible, the results constrain the age of that event to be older than 780 000 years. Therefore, the results presented here are not supportive of the AMH as it currently stands. Further paleomagnetic work, on similar deposits along the Illawarra coastline and from elsewhere in Australia, is needed to evaluate the interpretations presented here.     

The role of mafic microgranular enclaves in the generation of Early Cretaceous granitic rocks of SE China: evidence from zircon U–Pb geochronology,geochemistry, and Hf isotopic data for the Liangnong pluton,eastern Zhejiang Province

In order to constrain the timing and petrogenesis of both the hosting rocks and the inner mafic microgranular enclaves (MMEs) of the Liangnong pluton, SE China, we have performed a series of bulk-rock geochemistry, zircon U–Pb, and Hf isotopic analysis, respectively. Zircon laser ablation–inductively coupled plasma–mass spectrometry U–Pb isotopic analysis yielded ages of 106.3 ± 1.1 Ma for the granodiorite and 103.9 ± 1.6 to 105 ± 1.8 Ma for monzogranite phases within the hosting pluton, as well as an age of 104.7 ± 0.8 Ma for the associated MMEs. The host rocks are metaluminous, have A/CNK values of 0.91–1.09, contain relatively high concentrations of SiO₂ and K₂O, are enriched in Rb, Th, Ba, Zr, and Hf, are depleted of Sr, P, Ti, Nd, and Ta, contain high concentrations of the rare earth elements (REE) and the light REE, and have moderately negative Eu anomalies (Eu*/Eu = 0.6–0.8). In comparison, the MMEs contain high concentrations of Al₂O₃, FeO, MgO, and TiO₂, are relatively enriched in Ba, U, and Sr, and are depleted in Th, Nd, and Zr. They have lower total REE concentrations and higher Eu*/Eu values than the hosting granites. The zircons within the hosting granites have Hf crustal model ages (T_DM^C) that show a peak at 1.29–1.85 Ga. Zircons within the MMEs have different εHf(t) values (–3.7 to +4.9) than the zircons within the hosting granites (–10.8 to –1.9). The results indicate that the MMEs and the hosting granites crystallized from magmas with different sources, thereby showing that the Early Cretaceous magmatism in the coastal areas of SE China was generated by the widespread injection of mantle-derived magmas caused by rollback of the subducting palaeo-Pacific Plate.     

U–Pb zircon,zircon Hf and whole-rock Sm–Nd isotopic constraints on the evolution of Paleoproterozoic rocks in the northern Gawler Craton

U–Pb zircon analyses from a series of orthogneisses sampled in drill core in the northern Gawler Craton provide crystallisation ages at ca 1775–1750 Ma, which is an uncommon age in the Gawler Craton. Metamorphic zircon and monazite give ages of ca 1730–1710 Ma indicating that the igneous protoliths underwent metamorphism during the craton-wide Kimban Orogeny. Isotopic Hf zircon data show that 1780–1750 Ma zircons are somewhat evolved with initial ε_Hf values –4 to +0.9, and model ages of ca 2.3 to 2.2 Ga. Isotopic whole rock Sm–Nd values from most samples have relatively evolved initial ε_Nd values of –3.7 to –1.4. In contrast, a mafic unit from drill hole Middle Bore 1 has a juvenile isotopic signature with initial ε_Hf zircon values of ca +5.2 to +8.2, and initial ε_Nd values of ～+3.5 to +3.8. The presence of 1775–1750 Ma zircon forming magmatic rocks in the northern Gawler Craton provides a possible source for similarly aged detrital zircons in Paleoproterozoic basin systems of the Gawler Craton and adjacent Curnamona Province. Previous provenance studies on these Paleoproterozoic basins have appealed to the Arunta Region of the North Australian Craton to provide 1780–1750 Ma detrital zircons, and isotopically and geochemically similar basin fill. The orthogneisses in the northern Gawler Craton also match the source criteria and display geochemical similarities between coeval magmatism in the Arunta Region of the North Australian Craton, providing further support for paleogeographic reconstructions that link the Gawler Craton and North Australian Craton during the Paleoproterozoic.     

Origin and Evolution of Silicic Magmatism at Yellowstone Based on Ion Microprobe Analysis of Isotopically Zoned Zircons

The origin of large-volume Yellowstone ignimbrites and smaller-volumeintra-caldera lavas requires shallow remelting of enormous volumesof variably ¹⁸O-depleted volcanic and sub-volcanic rocks alteredby hydrothermal activity. Zircons provide probes of these processesas they preserve older ages and inherited ¹⁸O values. This studypresents a high-resolution, oxygen isotope examination of volcanismat Yellowstone using ion microprobe analysis with an averageprecision of ± 0·2 and a 10 µm spot size.We report 357 analyses of cores and rims of zircons, and isotopeprofiles of 142 single zircons in 11 units that represent majorYellowstone ignimbrites, and post-caldera lavas. Many zirconsfrom these samples were previously dated in the same spots bysensitive high-resolution ion microprobe (SHRIMP), and all zirconswere analyzed for oxygen isotope ratios in bulk as a functionof grain size by laser fluorination. We additionally reportoxygen isotope analyses of quartz crystals in three units. Theresults of this work provide the following new observations.(1) Most zircons from post-caldera low-¹⁸O lavas are zoned,with higher ¹⁸O values and highly variable U–Pb ages inthe cores that suggest inheritance from pre-caldera rocks exposedon the surface. (2) Many of the higher-¹⁸O zircon cores in theselavas have U–Pb zircon crystallization ages that postdatecaldera formation, but pre-date the eruption age by 10–20kyr, and represent inheritance of unexposed post-caldera sub-volcanicunits that have ¹⁸O similar to the Lava Creek Tuff. (3) Youngand voluminous 0·25–0·1 Ma intra-calderalavas, which represent the latest volcanic activity at Yellowstone,contain zircons with both high-¹⁸O and low-¹⁸O cores surroundedby an intermediate-¹⁸O rim. This implies inheritance of a varietyof rocks from high-¹⁸O pre-caldera and low-¹⁸O post-calderaunits, followed by residence in a common intermediate-¹⁸O meltprior to eruption. (4) Major ignimbrites of Huckleberry Ridge,and to a lesser extent the Lava Creek and Mesa Falls Tuffs,contain zoned zircons with lower-¹⁸O zircon cores, suggestingthat melting and zircon inheritance from the low-¹⁸O hydrothermallyaltered carapace was an important process during formation ofthese large magma bodies prior to caldera collapse. (5) The¹⁸O zoning in the majority of zircon core–rim interfacesis step-like rather than smoothly inflected, suggesting thatprocesses of solution–reprecipitation were more importantthan intra-crystalline oxygen diffusion. Concave-downward zirconcrystal size distributions support dissolution of the smallercrystals and growth of rims on larger crystals. This study suggeststhat silicic magmatism at Yellowstone proceeded via rapid, shallow-levelremelting of earlier erupted and hydrothermally altered Yellowstonesource rocks and that pulses of basaltic magma provided theheat for melting. Each post-caldera Yellowstone lava representsan independent homogenized magma batch that was generated rapidlyby remelting of source rocks of various ages and ¹⁸O values.The commonly held model of a single, large-volume, super-solidus,mushy-state magma chamber that is periodically reactivated andproduces rhyolitic offspring is not supported by our data. Rather,the source rocks for the Yellowstone volcanism were cooled belowthe solidus, hydrothermally altered by heated meteoric watersthat caused low ¹⁸O values, and then remelted in distinct pocketsby intrusion of basic magmas. Each packet of new melt inheritedzircons that retained older age and ¹⁸O values. This interpretationmay have significance for interpreting seismic data for crustallow-velocity zones in which magma mush and solidified areasexperiencing hydrothermal circulation occur side by side. Newbasalt intrusions into this solidifying batholith are requiredto form the youngest volcanic rocks that erupted as independentrhyolitic magmas. We also suggest that the Lava Creek Tuff magmawas already an uneruptable mush by the time of the first post-calderaeruption after 0·1 Myr of the climactic caldera-formingeruption. KEY WORDS: Yellowstone; oxygen isotopes; geochronology; isotope zoning; zircon; U–Pb dating; caldera; rhyolite; ion microprobe