Chemical abundance analysis for the atmospheres of red giants in the Hercules moving group

The results of a comparative analysis of the kinematics, ages, and elemental abundances for 17 red giants in the Hercules moving group are presented. Model atmospheres are used to determine the parameters of the stellar atmospheres and the abundances of about 20 elements. The masses and ages of the stars are estimated, and the components of their Galactic velocities and the elements of their Galactic orbits are calculated. Our analysis demonstrates that the Hercules stream is a heterogeneous group of objects from the thin and thick disks.     

The age-metallicity relation in the thin disk of the galaxy

HST trigonometric distances, photometric metallicities, isochronic ages from the second revised version of the Geneva-Copenhagen survey, and uniform spectroscopic Fe and Mg abundances from our master catalog are used to construct and analyze the age-metallicity and age-relative Mg abundance relations for stars of the thin disk. The influences of selection effects are discussed in detail. It is demonstrated that the radial migration of stars does not lead to appreciable distortions in the age dependence of the metallicity. During the first several billion years of the formation of the thin disk, the interstellarmaterial in this disk was, on average, fairly rich in heavy elements (〈[Fe/H]〉 ≈ −0.2) and poorly mixed. However, the metallicity dispersion continuously decreased with age, from σ _[Fe/H] ≈ 0.22 to ≈0.13. All this time, the mean relative abundance of Mg was somewhat higher than the solar value (〈[Mg/Fe]〉 ≈ 0.1). Roughly four to five billion years ago, the mean metallicity began to systematically increase, while retaining the same dispersion; the mean relative Mg abundance began to decrease immediately following this. The number of stars in this subsystem increased sharply at the same time. These properties suggest that the star-formation rate was low in the initial stage of formation of the thin disk, but abruptly increased about four to five billion years ago.     

Relationship between the Elemental Abundances and the Kinematics of Galactic-Field RR Lyrae Stars

Data of our compiled catalog containing the positions, velocities, and metallicities of 415 RR Lyrae variable stars and the relative abundances [el/Fe] of 12 elements for 101 RR Lyrae stars, including four α elements (Mg, Ca, Si, and Ti), are used to study the relationships between the chemical and spatial–kinematic properties of these stars. In general, the dependences of the relative abundances of α elements on metallicity and velocity for the RR Lyrae stars are approximately the same as those for field dwarfs. Despite the usual claim that these stars are old, among them are representatives of the thin disk, which is the youngest subsystem of the Galaxy. Attention is called to the problem of lowmetallicity RR Lyrae stars. Most RR Lyrae stars that have the kinematic properties of thick disk stars have metallicities [Fe/H] < ?1.0 and high ratios [α/Fe] ≈ 0.4, whereas only about 10% of field dwarfs belonging to the so-called “low-metallicity tail” have this chemical composition. At the same time, there is a sharp change in [α/Fe] in RR Lyrae stars belonging just to the thick disk, providing evidence for a long period of formation of this subsystem. The chemical compositions of SDSS J1707+58, V455 Oph, MACHO176.18833.411, V456 Ser, and BPSCS 30339–046 do not correspond to their kinematics.While the first three of these stars belong to the halo, according to their kinematics, the last two belong to the thick disk. It is proposed that they are all most likely extragalactic, but the possible appearance of some of them in the solar neighborhood as a result of the gravitational action of the bar on field stars cannot be ruled out.     

Chemical composition of stars in the galactic halo

The chemical compositions of the atmospheres of six metal-poor stars are analyzed. Spectra with signal-to-noise ratios of no less than 100 and a resolution of R≈17 000 were obtained using the 6-m telescope of the Special Astrophysical Observatory of the Russian Academy of Sciences. The abundances of Li, O, α-process elements (Mg, Si, Ca, Ti), Na, K, Sc, iron-peak elements (Cr, Mn, Fe, Ni, Cu, Zn), and s-process elements (Y, Ba) are derived. The star G251-54 ([Fe/H]=?1.55, T _eff=5541 K, logg=3.58) is deficient in some elements compared to both stars with similar metallicities and the Sun. The atmosphere of G251-54 has the following elemental abundances relative to iron: [O/Fe]=+0.47, [α/Fe]≈?0.3, [Na/Fe]=?0.60, [Sc/Fe]=?0.57, [Cr, Ni, Fe]≈0, [Zn/Fe]=+0.16, [Cu/Fe]=?0.66, [Y/Fe]=?0.70, and [Ba/Fe]=?1.35. The remaining five stars have metallicities in the range ?1.6<[Fe/H]相似文献   

Neutron-capture elements in halo,thick-disk,and thin-disk stars: Neodymium

We have derived the LTE neodymium abundances in 60 cool stars with metallicities [Fe/H] from 0.25 to ?1.71 by applying a synthetic-spectrum analysis to spectroscopic observations of NdII lines with a resolution of λ/Δλ?60 000 and signal-to-noise ratios of 100–200. We have improved the atomic parameters of NdII and blending lines by analyzing the corresponding line pro files in the solar spectrum. Neodymium is overabundant with respect to iron in halo stars, [Nd/Fe]=0.33±0.09, with the [Nd/Fe] ratio decreasing systematically with metallicity when [Fe/H]>?1. This reflects an onset of efficient iron production in type I supernovae during the formation of the thick disk. The [Nd/Ba] and [Nd/Eu] abundance ratios behave differently in halo, thick-disk, and thin-disk stars. The observed abundance ratios in halo stars, [Nd/Ba]=0.34±0.08 and [Nd/Eu]=?0.27±0.05, agree within the errors with the ratios of the elemental yields for the r-process. These results support the conclusion of other authors based on analyses of other elements that the r-process played the dominant role in the synthesis of heavy elements during the formation of the halo. The [Nd/Ba] and [Nd/Eu] ratios for thick-disk stars are almost independent of metallicity ([Nd/Ba]=0.28(±0.03)?0.01(±0.04) [Fe/H] and [Nd/Eu]=?0.13(±0.03)+0.05(±0.04) [Fe/H]) but are smaller in absolute value than the corresponding ratios for halo stars, suggesting that the synthesis of s-process nuclei started during the formation of the thick disk. The s-process is estimated to have contributed ?30% of the neodymium produced during this stage of the evolution of the Galaxy. The [Nd/Ba] ratio decreases abruptly by 0.17 dex in the transition from the thick to the thin disk. The systematic decrease of [Nd/Ba] and increase of [Nd/Eu] with increasing metallicity of thin-disk stars point toward a dominant role of the s-process in the synthesis of heavy elements during this epoch.     

Relationship between the velocity ellipsoids of galactic-disk stars and their ages and metallicities

The dependences of the velocity ellipsoids of F-G stars of the thin disk of the Galaxy on their ages and metallicities are analyzed based on the new version of the Geneva-Copenhagen Catalog. The age dependences of the major, middle, and minor axes of the ellipsoids, and also of the dispersion of the total residual velocity, obey power laws with indices 0.25, 0.29, 0.32, and 0.27 (with uncertainties ±0.02). Due to the presence of thick-disk objects, the analogous indices for all nearby stars are about a factor of 1.5 larger. Attempts to explain such values are usually based on modeling relaxation processes in the Galactic disk. Elimination of stars in the most numerous moving groups from the sample slightly reduces the corresponding indices (0.22, 0.26, 0.27, and 0.24). Limiting the sample to stars within 60 pc of the Sun, so that the sample can be considered to be complete, leaves both the velocity ellipsoids and their age dependences virtually unchanged. With increasing age, the velocity ellipsoid increases in size and becomes appreciablymore spherical, turns toward the direction of the Galactic center, and loses angular momentum. The shape of the velocity ellipsoid remains far from equilibrium. With increasing metallicity, the velocity ellipsoid for stars of mixed age increases in size, displays a weak tendency to become more spherical, and turns toward the direction of the Galactic center (with these changes occurring substantially more rapidly in the transition through the metallicity [Fe/H]≈−0.25). Thus, the ellipsoid changes similarly to the way it does with age; however, with decreasing metallicity, the rotational velocity about the Galactic center monotonically increases, rather than decreases (!). Moreover, the power-law indices for the age dependences of the axes depend on the metallicity, and display a maximum near [Fe/H] ≈−0.1. The age dependences of all the velocity-ellipsoid parameters for stars with equal metallicity are roughly the same. It is proposed that the appearance of a metallicity dependence of the velocity ellipsoids for thin-disk stars, recorded from the close to the Sun, is most likely due to the radial migration of stars.     

Revised magnesium abundances in galactic halo and disk stars

A differential analysis of the magnesium abundances in 61 F-K dwarfs and subgiants with metallicities ?2.6<[Fe/H]<+0.2 is performed based on published observational data. Fundamental parameters for 36 stars are determined: T _eff from V-K and V-R; logg from HIPPARCOS parallaxes, and [Fe/H] and ξ_t from Fe II lines. The computations allow for non-LTE effects in the formation of the Mg I lines. For most of the stars, the standard errors in the Mg abundances do not exceed 0.07 dex. The metallicity dependence of [Mg/Fe] is analyzed. Magnesium shows a constant overabundance relative to Fe of 0.46±0.06 dex for metallicities ?2.6<[Fe/H] $\overline {[Mg/Fe]} = + 0.22 dex$ ) compared to the [Mg/Fe] values for other stars with similar [Fe/H].     

Peculiarities of the abundances of neutron-capture elements in Galactic open clusters

The properties of the relative abundances of rapid and slow neutron-capture elements are studied using a catalog containing spectroscopic abundance determinations for 14 elements produced in various nuclear-synthesis processes for 90 open clusters. The catalog also contains the positions, ages, velocities, and elements of the Galactic orbits of the clusters. The relative abundances of both r-elements (Eu) and s-elements (Y, Ba, La, and Ce) in clusters with high, elongated orbits and in field stars of the Galactic thin disk display different dependences on metallicity, age, Galactocentric distance, and the elements of the Galactic orbits, supporting the view that these objects have different natures. In young clusters, not only barium, but also the three other studied s-elements display significantly higher relative abundances than field stars of the same metallicity. The relative abundances of Eu are lower in highmetallicity clusters ([Fe/H] > -0.1) with high, elongated orbits than in field giants, on average, while the [Eu/Fe] ratios in lower-metallicity clusters are the same as those in field stars, on average, although with a large scatter. The metallicity dependence of the [O, Mg/Eu] ratios in clusters with high, elongated orbits and in field stars are substantially different. These and other described properties of the Eu abundances, together with the properties of the abundances of primary a-elements, can be understood in a natural way if clusters with high, elongated orbits with different metallicities formed as a result of interactions of two types of high-velocity clouds with the interstellar medium of the Galactic disk: low-metallicity highvelocity clouds that formed from “primordial” gas, and high-metallicity clouds with intermediate velocities that formed in “Galactic fountains.”     

Peculiarities of α-element abundances in Galactic open clusters

A catalog compiling the parameters of 346 open clusters, including their metallicities, positions, ages, and velocities has been composed. The elements of the Galactic orbits for 272 of the clusters have been calculated. Spectroscopic determinations of the relative abundances, [el/Fe], for 14 elements synthesized in various nuclear processes averaged over data from 109 publications are presented for 90 clusters. The compiled data indicate that the relative abundances of primary α elements (oxygen and magnesium) exhibit different dependences on metallicity, age, Galactocentric distance, and the elements of the Galactic orbits in clusters with high, elongated orbits satisfying the criterion (Z_max² + 4e²)^1/2 > 0.40 and in field stars of the Galactic thin disk (Z_max is the maximum distance of the orbit from the Galactic plane in kiloparsec and e is the eccentricity of the Galactic orbit). Since no systematic effects distorting the relative abundances of the studied elements in these clusters have been found, these difference suggest real differences between clusters with high, elongated orbits and field stars. In particular, this supports the earlier conclusion, based on an analysis of the elements of the Galactic orbits, that some clusters formed as a result of interactions between high-velocity,metal-poor clouds and the interstellar mediumof theGalactic thin disk. On average, clusters with high, elongated orbits and metallicities [Fe/H] < -0.1 display lower relative abundances of the primary a elements than do field stars. The low [O, Mg/Fe] ratios of these clusters can be understood if the high-velocity clouds that gave rise to them were formed of interstellar material from regions where the star-formation rate and/or the masses of Type II supernovae were lower than near the Galactic plane. It is also shown that, on average, the relative abundances of the primary a elements are higher in relatively metal-rich clusters with high, elongated orbits than in field stars. This can be understood if clusters with [Fe/H] > -0.1 formed as a result of interactions between metal-rich clouds with intermediate velocities and the interstellar medium of the Galactic disk; such clouds could form from returning gas in a so-called “Galactic fountain.”     

Observational constraints on potassium synthesis during the formation of stars of the Galactic disk

The non-LTE potassium abundances in the atmospheres of 33 Galactic-disk stars are derived and the parameters of the atmospheres of 23 of the stars are determined. Neglecting departures from LTE results in a systematic overestimation of the potassium abundances and an increase in their dispersion, even for differential analyses relative to the Sun. The non-LTE corrections are significant ((?0.2)–(?0.6) dex) and depend on the surface gravities and effective temperatures of the stars. The mean potassium abundance for a sample of ten stars with [Fe/H]～0.0 is in agreement with the solar and meteoritic abundances (log ? _⊙(K)=5.12). As the stellar metallicity increases from [Fe/H]=(?1.0) to (0.2) dex, the [K/Fe] ratio decreases systematically from 0.3 dex to ?0.1 dex. The derived dependence [K/Fe]-[Fe/H] is in agreement with the results of published model calculations of the chemical evolution of the Galaxy. This indicates the dominance of explosive oxygen burning in massive type II supernovae during the synthesis of potassium in the Galactic disk.     

A comparison of geochemical information obtained from two fluvial bed sediment fractions

 A total of 121 bed sediment samples were collected from a 5.8-km stretch of Manoa Stream, Hawaii. Samples were physically partitioned into two grain-size fractions, <63 μm and 63–125 μm, acid digested and analyzed by ICP-AES and FAAS. Non-parametric matched-pair statistical testing and correlation analysis were used to assess differences and strengths of association between the two fractions for Al, Ba, Cu, Fe, Mn, Ni, Pb, Ti and Zn. Results indicated statistically significant differences between fractions for all elements except Mn. Concentrations were significantly greater in the <63 μm fraction for Al, Cu, Pb, Ti and Zn, while Ba, Fe and Ni were higher in the 63–125 μm fraction. Though some elements had statistically significant differences between fractions (Al, Ba, Fe and Zn) percentage differences were in the range of analytical precision of the instrument and thus differences were not practically significant. Correlation analysis indicated strong positive associations for all elements between the two fractions (p<0.0001). Three contamination indices indicated similar degrees of pollution for each size fraction for four elements having an anthropogenic signal (Ba, Cu, Pb and Zn). The environmental information obtained from the 63–125 μm fraction was essentially equivalent to that from the <63 μm fraction. In this system it is clear that both bed sediment fractions indicate anthropogenic enrichment of trace metals, especially Pb, and further supports previous research that has found that aquatic sediments are critical median for tracing sources of pollution. Received: 17 August 1998 · Accepted: 30 October 1998     

Some problems in determining elemental abundances in the atmospheres of giants and dwarfs of the HR 1614 moving cluster

The atmospheric abundances of various chemical elements and other atmospheric parameters of four stars belonging to the HR 1614 moving cluster are determined and analyzed using a single technique. For three of the stars, the derived atmospheric parameters are typical of stars of their types, and their elemental abundances are close to those determined earlier for these and other stars of the moving cluster. However, the atmospheric parameters derived for the red dwarf HD 32147 would be more typical of a giant, and its metallicity is much lower than is characteristic of stars of this moving group.

     

Optical spectra of three AGB stars

The basic parameters and detailed chemical compositions of three asymptotic giant branch stars with similar effective temperatures and surface gravities have been determined using CCD spectra obtained with the échelle spectrometers of the SAO 6-m telescope. The metallicity and chemical composition of the optical counterpart of the OH/IR star IRAS 18123 + 0511 have been derived for the first time. The abundance [X/H]_⊙ of the iron group elements (V, Cr, Fe) is ?0.45 dex. An overabundance of oxygen, [O/Fe]_⊙=1.44 dex, is detected in the atmosphere of this star. The abundances of s-process heavy elements are not enhanced, and are instead underabundant with respect to the metallicity: the average value of [X/Fe]_⊙ for Y, Zr, Ba, La, Ce, Pr, Nd is ?0.25. The derived abundances confirm that IRAS 18123 + 0511 is in the AGB stage of its evolution. The metallicity of the object, together with its radial velocity V _r=78.0 km/s and Galactic latitude |b|=11°, suggest that it belongs to the old disk population. The expansion velocity of the circumstellar envelope, V _exp≈21 km/s, is derived from the positions of circumstellar absorption bands. The set of parameters obtained for the low-metallicity, highlatitude supergiants BD + 18° 2757 and BD + 18° 2890 (with iron abundances [Fe/H]_⊙=2.10 and ?1.48, respectively) confirm that they are evolved halo stars, and probably UU Her-type stars.     

Subsystems of RR Lyrae variable stars in our Galaxy

We have used published, high-accuracy, ground-based and satellite proper-motion measurements, a compilation of radial velocities, and photometric distances to compute the spatial velocities and Galactic orbital elements for 174 RR Lyrae (ab) variable stars in the solar neighborhood. The computed orbital elements and published heavy-element abundances are used to study relationships between the chemical, spatial, and kinematic characteristics of nearby RR Lyrae variables. We observe abrupt changes of the spatial and kinematic characteristics at the metallicity [Fe/H]≈?0.95 and also when the residual spatial velocities relative to the LSR cross the critical value V _res≈290 km/s. This provides evidence that the general population of RR Lyrae stars is not uniform and includes at least three subsystems occupying different volumes in the Galaxy. Based on the agreement between typical parameters for corresponding subsystems of RR Lyrae stars and globular clusters, we conclude that metal-rich stars and globular clusters belong to a rapidly rotating and fairly flat, thick-disk subsystem with a large negative vertical metallicity gradient. Objects with larger metal deficiencies can, in turn, be subdivided into two populations, but using different criteria for stars and clusters. We suggest that field stars with velocities below the critical value and clusters with extremely blue horizontal branches form a spherical, slowly rotating subsystem of the protodisk halo, which has a common origin with the thick disk; this subsystem has small but nonzero radial and vertical metallicity gradients. The dimensions of this subsystem, estimated from the apogalactic radii of orbits of field stars, are approximately the same. Field stars displaying more rapid motion and clusters with redder horizontal branches constitute the spheroidal subsystem of the accreted outer halo, which is approximately a factor of three larger in size than the first two subsystems. It has no metallicity gradients; most of its stars have eccentric orbits, many display retrograde motion in the Galaxy, and their ages are comparatively low, supporting the hypothesis that the objects in this subsystem had an extragalactic origin.     

Sodium abundances in stellar atmospheres with differing metallicities

The non-LTE sodium abundances of 100 stars with metallicities ?3<[Fe/H]<0.3 are determined using high-dispersion spectra with high signal-to-noise ratios. The sodium abundances [Na/Fe] obtained are close to the solar abundance and display a smaller scatter than values published previously. Giants (logg<3.8) with [Fe/H]g>3.8) with metallicities ?2<[Fe/H]相似文献   

Status of anthropogenically induced metal pollution in the Kanpur-Unnao industrial region of the Ganga Plain, India

 The Ganga Plain is one of the most densely populated regions and one of the largest groundwater repositories of the Earth. For several decades, the drainage basin of the Ganga Plain has been used for the disposal of domestic and industrial wastes which has adversely affected the quality of water, sediments and agricultural soils of the plain. The concentrations of Al, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sn, Zn and organic carbon were determined in river sediments and soils of the Ganga Plain in the Kanpur-Unnao industrial region in 1994 and 1995 (pre-monsoon period of April–May). High contents (maximum values) of C-org (12.0 wt. %), Cr (3.40 wt. %), Sn (1.92 wt. %), Zn (4000 mg/kg), Pb (646 mg/kg), Cu (408 mg/kg), Ni (502 mg/kg) and Cd (9.8 mg/kg) in sediments (<20 μm fraction); and C-org (5.9 wt. %), Cr (2.16 wt. %), Sn (1.21 wt %), Zn (975 mg/kg) and Ni (482 mg/kg) in soils (<20 μm) in the pre-monsoon period of 1994 were found. From 1994 to 1995 the contents of Fe and Sn in sediments increase whereas those of C-org, Cd, Cu, Ni and Zn decrease. Considering the analytical errors, Al, Co, Cr, Mn and Pb do not show any change in their concentrations. In soils, the contents of Cd, Fe and Sn increase whereas those of Ni decrease from 1994 to 1995. Aluminium, Co, Cr, Cu, Mn, Pb and Zn do not show any change in their concentrations from 1994 to 1995. About 90% of the contents of Cd, Cr and Sn; 50–75% of C-org, Cu and Zn; and 25% of Co, Ni and Pb in sediments are derived from the anthropogenic input in relation to the natural background values, whereas in soils this is the case for about 90% of Cr and Sn; about 75% of Cd; and about 25% of C-org, Cu, Ni and Zn. The sediments of the study area show enrichment factors of 23.6 for Cr, 14.7 for Cd, 12.2 for Sn, 3.6 for C-org, 3.2 for Zn, 2.6 for Cu and 1.6 for Ni. The soils are enriched with factors of 10.7 for Cr, 9.0 for Sn, 3.6 for Cd, 1.8 for Ni and 1.5 for Cu and Zn, respectively. Received: 3 March 1998 · Accepted: 15 June 1998     

Evolution of the velocity ellipsoids in the thin disk of the Galaxy and the radial migration of stars

Data from the revised Geneva-Copenhagen catalog are used to study the influence of radial migration of stars on the age dependences of parameters of the velocity ellipsoids for nearby stars in the thin disk of the Galaxy, assuming that the mean radii of the stellar orbits remain constant. It is demonstrated that precisely the radial migration of stars, together with the negative metallicity gradient in the thin disk, are responsible for the observed negative correlation between the metallicities and angular momenta of nearby stars, while the angular momenta of stars that were born at the same Galactocentric distances do not depend on either age or metallicity. The velocity components of the Sun relative to the Local Standard of Rest derived using data for stars born at the solar Galactocentric distance are (U _⊙, V _⊙, W _⊙) _LSR = (5.1 ± 0.4, 7.9 ± 0.5, 7.7 ± 0.2) km/s. The two coordinates of the apex of the solar motion remain equal to 〈l _⊙〉 = 70° ± 7° and 〈b _⊙〉 = 41° ± 2°, within the errors. The indices for the power-law age dependences of them ajor, middle, and minor semi-axes become 0.26±0.04, 0.32±0.03, and 0.07±0.03, respectively. As a result, with age, the velocity ellipsoid for thin-disk stars born at the solar Galactocentric distance increases only in the plane of the disk, remaining virtually constant in the perpendicular direction. Its shape remains far from equilibrium, and the direction of the major axis does not change with age: the ellipsoid vertex deviation remains constant and equal to zero within the errors (〈L〉 = 0.7° ± 0.6°, 〈B〉 = 1.9° ± 1.1°). Such a small increase in the velocity dispersion perpendicular to the Galactic plane with age can probably be explained by “heating” of the stellar system purely by spiral density waves, without a contribution from giant molecular clouds.     

Transport and sediment–water partitioning of trace metals in acid mine drainage: an example from the abandoned Kwangyang Au–Ag mine area, South Korea

Transport and sediment–water partitioning of trace metals (Cr, Co, Fe, Pb, Cu, Ni, Zn, Cd) in acid mine drainage were studied in two creeks in the Kwangyang Au–Ag mine area, southern part of Korea. Chemical analysis of stream waters and the weak acid (0.1 N HCl) extraction, strong acid (HF–HNO₃–HClO₄) extraction, and sequential extraction of stream sediments were performed. Heavy metal pollution of sediments was higher in Chonam-ri creek than in Sagok-ri creek, because there is a larger source of base metal sulfides in the ores and waste dump upstream of Chonam-ri creek. The sediment–water distribution coefficients (K _d) for metals in both creeks were dependent on the water pH and decreased in the order Pb ≈ Al > Cu > Mn > Zn > Co > Ni ≈ Cd. K _d values for Al, Cu and Zn were very sensitive to changes in pH. The results of sequential extraction indicated that among non-residual fractions, Fe–Mn oxides are most important for retaining trace metals in the sediments. Therefore, the precipitation of Fe(–Mn) oxides due to pH increase in downstream sites plays an important role in regulating the concentrations of dissolved trace metals in both creeks. For Al, Co, Cu, Mn, Pb and Zn, the metal concentrations determined by 0.1 N HCl extraction (Korean Standard Method for Soil Pollution) were almost identical to the cumulative concentrations determined for the first three weakly-bound fractions (exchangeable + bound to carbonates + bound to Fe–Mn oxides) in the sequential extraction procedure. This suggests that 0.1 N HCl extraction can be effectively used to assess the environmentally available and/or bioavailable forms of trace metals in natural stream sediments.     

Masses of RR Lyrae Stars with Different Chemical Abundances in the Galactic Field

The surface gravities and effective temperatures have been added to a compilative catalog published earlier, which includes the relative abundances of several chemical elements for 100 field RR Lyrae stars. These atmoshperic parameters and evolutionary tracks from the Dartmouth database are used to determine the masses of the stars and perform a comparative analysis of the properties of RR Lyrae stars with different chemical compositions. The masses of metal-rich ([Fe/H] > −0.5) RR Lyrae stars with thin disk kinematics are in the range (0.51−0.60)M_⊙. Only stars with initial masses exceeding 1M_⊙ can reach the horizontal branch during the lifetime of this subsystem. To become an RR Lyrae variable, a star must have lost approximately half of its mass during the red-giant phase. The appearance of such young, metal-rich RR Lyrae stars is possibly due to high initial helium abundances of their progenitors. According to the Dartmouth evolutionary tracks for Y = 0.4, a star with an initial mass as low as 0.8 M_⊙ could evolve to become an RR Lyrae variable during this time. Such stars should have lost (0.2−0.3)M_⊙ in the red-giant phase, which seems quite realistic. Populations of red giants and RR Lyrae stars with such high helium abundances have already been discovered in the bulge; some of these could easily be transported to the solar neighborhood as a consequence of perturbations due to inhomogeneities of the Galaxy’s gravitational potential.

     

Colloid formation and metal transport through two mixing zones affected by acid mine drainage near Silverton,Colorado

Stream discharges and concentrations of dissolved and colloidal metals (Al, Ca, Cu, Fe, Mg, Mn, Pb, and Zn), SO₄, and dissolved silica were measured to identify chemical transformations and determine mass transports through two mixing zones in the Animas River that receive the inflows from Cement and Mineral Creeks. The creeks were the dominant sources of Al, Cu, Fe, and Pb, whereas the upstream Animas River supplied about half of the Zn. With the exception of Fe, which was present in dissolved and colloidal forms, the metals were dissolved in the acidic, high-SO₄ waters of Cement Creek (pH 3.8). Mixing of Cement Creek with the Animas River increased pH to near-neutral values and transformed Al and some additional Fe into colloids which also contained Cu and Pb. Aluminium and Fe colloids had already formed in the mildly acidic conditions in Mineral Creek (pH 6.6) upstream of the confluence with the Animas River. Colloidal Fe continued to form downstream of both mixing zones. The Fe- and Al-rich colloids were important for transport of Cu, Pb, and Zn, which appeared to have sorbed to them. Partitioning of Zn between dissolved and colloidal phases was dependent on pH and colloid concentration. Mass balances showed conservative transports for Ca, Mg, Mn, SO₄, and dissolved silica through the two mixing zones and small losses (<10%) of colloidal Al, Fe and Zn from the water column.